chapter 2 palladium catalysts in suzuki cross- coupling reaction

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Figure A.16. 1 H NMR of 3-phenylpyrid<strong>in</strong>e N 98
Figure A.17. 13 C NMR of 4-acetyl-4’-methoxybiphenyl O OCH 3 99
Page 1 and 2:
SHORT-TIME SUZUKI REACTIONS OF ARYL
Page 3 and 4:
ACKNOWLEDGEMENTS Firstly, I’d lik
Page 5 and 6:
ÖZET ARİL HALOJENÜRLERİN HAVA A
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3.2.2. Catalysts Anchored to Inorga
Page 9 and 10:
LIST OF FIGURES Figure Page Figure
Page 11 and 12:
Figure A.27. 13 C NMR of 4-cyanobip
Page 13 and 14:
CHAPTER 1 INTRODUCTION The palladiu
Page 15 and 16:
CHAPTER 2 PALLADIUM CATALYSTS IN SU
Page 17 and 18:
2.1.2. The Coordination Geometry of
Page 19 and 20:
R 1 R 1 4. Sonogashira Reaction: H
Page 21 and 22:
2.2.1. Mechanism of Suzuki Coupling
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As a result, organic group or hydri
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2.2.2.2. Halogen Effect Nearly all
Page 27 and 28:
found to be excellent complexes for
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R Table 2.2. Examples from literatu
Page 31 and 32:
L R Pd X R Pd L OR'' X L L + OR' R'
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omides and iodides is performed eff
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times for the transformation of a l
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R Br + (HO) 2B R' 5% Pd(OAc) 2 15%
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of insoluble solids are among the m
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could be reused multiple times. The
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3.2.2. Catalysts Anchored to Inorga
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SO 2NH N Pd SO 2 N SO 2 NH NH H O1.
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utilized them in Heck and Suzuki co
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Smith et al introduced the use of P
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• Complexes immobilized in zeolit
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3.3.3. Preparation of Zeolite-Suppo
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CHAPTER 4 EXPERIMENTAL STUDY 4.1. P
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temperature, the catalyst was recov
Page 59 and 60: amount of both reactant and product
Page 61 and 62: 4-Methoxybiphenyl: 1 H NMR (400 MHz
Page 63 and 64: 51 Table 4.1. Purification of coupl
Page 65 and 66: CHAPTER 5 RESULTS AND DISCUSSIONS I
Page 67 and 68: Table 5.2. The effect of base on Pd
Page 69 and 70: Table 5.4. The Optimization of Pd-N
Page 71 and 72: H 3COC Table 5.5. Effect of zeolite
Page 73 and 74: Table 5.6. Pd(NH3)4 2+ -loaded NaY
Page 75 and 76: The type of other organic co-solven
Page 77 and 78: yield was very low (Table 5.8, entr
Page 79 and 80: evealed excellent reactivity toward
Page 81 and 82: CHAPTER 6 CONCLUSIONS In this thesi
Page 83 and 84: REFERENCES Albisson, D.A., Bedford,
Page 85 and 86: Choudary, B.M., Madhi, S., Chowdari
Page 87 and 88: Heiden, M. Plenio, H. 2004. ‘‘H
Page 89 and 90: Coupling Reactions of Aryl Chloride
Page 91 and 92: Phan, N.T.S., Brown, D.H., Styring,
Page 93 and 94: Wolfe, J.P., Singer, R.A., Yang, B.
Page 95 and 96: Figure A.1. 13 C NMR of 1-phenylnap
Page 97 and 98: Figure A.3. 13 C NMR of 2-acetylbip
Page 99 and 100: Figure A.5 . 13 C NMR of 2-methoxyb
Page 101 and 102: Figure A.7. 13 C NMR of 2-methylbip
Page 103 and 104: Figure A.9. 13 C NMR of 2-phenylnap
Page 105 and 106: Figure A.11. 13 C NMR of 3-acetylbi
Page 107 and 108: Figure A.13. 13 C NMR of 3-methoxyb
Page 109: Figure A.15. 13 C NMR of 3-phenylpy
Page 113 and 114: Figure A.19. 13 C NMR of 4-methoxyb
Page 115 and 116: Figure A.21. 13 C NMR of 4-methylbi
Page 117 and 118: Figure A.23. 13 C NMR of 4-phenylbe
Page 119 and 120: Figure A.25. 13 C NMR of 4-acetylbi
Page 121 and 122: Figure A.27. 13 C NMR of 4-cyanobip
Page 123 and 124: Figure A.29. 13 C NMR of 4-nitrobip
Page 125 and 126: Figure A.31. 13 C NMR of 4-phenylan
Page 127 and 128: APPENDIX B MASS SPECTRUMS OF SUZUKI
Page 129 and 130: Figure B.2. Mass spectrum of 2-acet
Page 131 and 132: Figure B.4. Mass spectrum of 2-meth
Page 133 and 134: Figure B.6. Mass spectrum of 3-acet
Page 135 and 136: Figure B.8. Mass spectrum of 3-phen
Page 137 and 138: Figure B.10. Mass spectrum of 4-phe
Page 139 and 140: Figure B.12. Mass spectrum of 4-met
Page 141 and 142: Figure B.14. Mass spectrum of 4-cya
Page 143: Figure B.16. Mass spectrum of 4-met
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