chapter 2 palladium catalysts in suzuki cross- coupling reaction
chapter 2 palladium catalysts in suzuki cross- coupling reaction
chapter 2 palladium catalysts in suzuki cross- coupling reaction
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Figure 3.17. Molecular model<strong>in</strong>g of the Pd complexes ([Pd(NH3)4] 2+ ,<br />
[Pd(OAc)2], [Pd(C3H5)Cl]2 <strong>in</strong> Na-Y zeolite us<strong>in</strong>g the CAChe TM<br />
software with extended MM2 molecular force field and<br />
molecular mechanics methods..................................................................... H42<br />
Figure 4.1. Preparation of [Pd(NH3)4] +2 -Y catalyst from NaY zeolite............................. H43<br />
Figure 4.2. The experimental set-up for Suzuki coupl<strong>in</strong>g <strong>reaction</strong>s................................. H45<br />
Figure.4.3. GC chromatogram of a selected Suzuki Reaction<br />
(4-bromoanisole and phenylboronic acid) ...................................................... H46<br />
Figure A.1. 13 C NMR of 1-phenylnaphthalene...................................................................83<br />
Figure A.2. 1 H NMR of 1-phenylnaphthalene…………………………………………....84<br />
Figure A.3. 13 C NMR of 2-acetylbiphenyl ........................................................................85<br />
Figure A.4. 1 H NMR of 2-acetylbiphenyl..........................................................................86<br />
Figure A.5. 13 C NMR of 2-methoxybiphenyl....................................................................87<br />
Figure A.6. 1 H NMR of 2-methoxybiphenyl .....................................................................88<br />
Figure A.7. 13 C NMR of 2-methylbiphenyl.......................................................................89<br />
Figure A.8. 1 H NMR of 2-methylbiphenyl........................................................................90<br />
Figure A.9. 13 C NMR of 2-phenylnaphthalene..................................................................91<br />
Figure A.10. 1 H NMR of 2-phenylnaphthalene.................................................................92<br />
Figure A.11. 13 C NMR of 3-acetylbiphenyl ......................................................................93<br />
Figure A.12. 1 H NMR of 3-acetylbiphenyl........................................................................94<br />
Figure A.13. 13 C NMR of 3-methoxybiphenyl..................................................................95<br />
Figure A.14. 1 H NMR of 3-methoxybiphenyl ...................................................................96<br />
Figure A.15. 13 C NMR of 3-phenylpyrid<strong>in</strong>e......................................................................97<br />
Figure A.16. 1 H NMR of 3-phenylpyrid<strong>in</strong>e.......................................................................98<br />
Figure A.17. 13 C NMR of 4-acetyl-4’-methoxybiphenyl ..................................................99<br />
Figure A.18. 1 H NMR of 4-acetyl-4’-methoxybiphenyl..................................................100<br />
Figure A.19. 13 C NMR of 4-methoxybiphenyl................................................................101<br />
Figure A.20. 1 H NMR of 4-methoxybiphenyl .................................................................102<br />
Figure A.21. 13 C NMR of 4-methylbiphenyl...................................................................103<br />
Figure A.22. 1 H NMR of 4-methylbiphenyl....................................................................104<br />
Figure A.23. 13 C NMR of 4-phenylbenzaldehyde ...........................................................105<br />
Figure A.24. 1 H NMR of 4-phenylbenzaldehyde ............................................................106<br />
Figure A.25. 13 C NMR of 4-acetylbiphenyl ....................................................................107<br />
Figure A.26. 1 H NMR of 4-acetylbiphenyl......................................................................108<br />
x