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ioplastics magazine Vol. 2 ISSN 1862-5258<br />

Special editorial Focus:<br />

Biodegradable bags<br />

Review K2007<br />

Düsseldorf | 8<br />

Logos, Part 6 | 36<br />

04 | 2007


Don’t worry,<br />

the raw material for Ecovio ®<br />

is renewable.<br />

Ecovio ® , a biodegradable plastic from the PlasticsPlus TM product line,<br />

is keeping up with the times when it comes to plastic bags and food<br />

packaging. Ecovio ® is made of corn starch, a renewable raw material,<br />

and it has properties like HD-PE, which translates into a double plus<br />

point for you. Films made of Ecovio ® are water-resistant, very strong<br />

and degrade completely in composting facilities within just a few weeks.<br />

www.ecovio.com<br />

I N N O VAT I O N R E L I A B I L I T Y PA R T N E R S H I P D I V E R S I T Y


Editorial<br />

dear readers<br />

Probably the most exciting event in the world of plastics processing and<br />

applications is the K-exhibition, which takes place every three years.<br />

This year, at the end of October, about 242,000 visitors from more than<br />

100 countries came to the exhibition in Düsseldorf, Germany. 3,130<br />

exhibitors presented their products, services and innovations, and<br />

bioplastics were a part – albeit a small part – of that mega event.<br />

More than 3,000 copies of bioplastics MAGAZINE were picked up from<br />

our booth in hall 7 by interested visitors. We were pleased to meet so<br />

many of you personally, and talk about so many different topics. We<br />

were really quite reluctant to leave the booth from time to time, but we<br />

too wanted to see the more than 40 companies exhibiting products such<br />

as resins, additives, machines and services related to bioplastics.<br />

But it was not only K‘2007 that caught our attention this fall. There was<br />

the 2nd European Bioplastics Conference in Paris and the Bioplastics<br />

Event in Cologne where the 2nd Bioplastics Awards were made to the<br />

innovative and well-deserving winners. And there were in fact many<br />

other bioplastics / biopackaging / bioresin events that our editorial<br />

team simply could not attend, but I am sure that these too made a<br />

significant contribution to disseminating information and promoting<br />

networking between the delegates.<br />

As well as many other topics from the bioplastics world, the markets,<br />

science, politics and so on, the special editorial focus in this issue of<br />

bioplastics MAGAZINE is ‘bags‘.<br />

I hope you enjoy reading this last issue of 2007. From<br />

2008 we will publish six issues per year and we look<br />

forward to your comments, editorial contributions and<br />

more exciting events where we can meet with you.<br />

Special editorial Focus:<br />

Biodegradable bags<br />

04 | 2007<br />

bioplastics MAGAZINE Vol. 2 ISSN 1862-5258<br />

Michael Thielen<br />

Publisher<br />

Review K2007<br />

Düsseldorf | 8<br />

Logos, Part 6 | 36<br />

bioplastics MAGAZINE [04/07] Vol. 2


Content<br />

Editorial 03<br />

News 05<br />

Suppliers Guide 39<br />

Events 42<br />

December 04|2007<br />

Review<br />

K’2007 Review 08<br />

2nd European Bioplastics Conference 14<br />

Bioplastics Awards 2007 16<br />

Special<br />

Shopping bags, that dissolve in hot water 18<br />

World‘s first biodegradable zipper bag 19<br />

Compostable shopping carrier bags 20<br />

Biobags: In-line production is the future 21<br />

Materials<br />

Lactide Monomers for the production of PLA 22<br />

Processing<br />

Oriented films continue their 25<br />

successful run – even with PLA<br />

From Science & Research<br />

From Waste 2 Gold: Making bioplastic 28<br />

products from biomass waste streams<br />

Opinion<br />

Biopolymers as an option for 32<br />

sustainability – Quo vadis?<br />

Mailbox<br />

Letter to the Editor 35<br />

Basics<br />

Logos Part 6 36<br />

Glossary 37<br />

Impressum<br />

Publisher / Editorial<br />

Dr. Michael Thielen<br />

Samuel Brangenberg<br />

Dr. Thomas Isenburg, Contributing Editor<br />

Layout/Production<br />

Mark Speckenbach, Jörg Neufert<br />

Head Office<br />

Polymedia Publisher GmbH<br />

Hackesstr. 99<br />

41066 Mönchengladbach, Germany<br />

phone: +49 (0)2161 664864<br />

fax: +49 (0)2161 631045<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Media Adviser<br />

Elke Schulte, Katrin Stein<br />

phone: +49(0)2359-2996-0<br />

fax: +49(0)2359-2996-10<br />

es@bioplasticsmagazine.com<br />

Print<br />

Tölkes Druck + Medien GmbH<br />

Höffgeshofweg 12<br />

47807 Krefeld, Germany<br />

Print run: 4,000 copies<br />

bioplastics magazine<br />

ISSN 1862-5258<br />

bioplastics magazine is published<br />

4 times in 2007 and 6 times a year from 2008.<br />

This publication is sent to qualified<br />

subscribers (149 Euro for 6 issues).<br />

bioplastics MAGAZINE is read<br />

in more than 80 countries.<br />

Not to be reproduced in any form<br />

without permission from the publisher<br />

The fact that product names may not<br />

be identified in our editorial as trade<br />

marks is not an indication that such<br />

names are not registered trade marks.<br />

bioplastics MAGAZINE tries to use British<br />

spelling. However, in articles based on<br />

information from the USA, American<br />

spelling may also be used.<br />

bioplastics MAGAZINE [04/07] Vol. 2


News<br />

Sustainability a key<br />

criterion for DuPont’s<br />

Packaging Award<br />

DuPont has announced that the packaging industry’s longest running,<br />

independently judged global innovation awards program has<br />

added a special emphasis on sustainability. Innovation in the journey<br />

toward sustainable packaging will now be a key consideration in addition<br />

to innovation in delivering quality packaging solutions.<br />

DuPont, being one of the first companies to publicly establish environmental<br />

goals 17 years ago, has broadened its sustainability commitments<br />

beyond internal footprint reduction to include market-driven<br />

targets for both revenue and research and development investment, as<br />

stated by the company. The goals are tied directly to business growth,<br />

specifically to the development of safer and environmentally improved<br />

new products for key global markets.<br />

The call for entries for the 20th DuPont Awards competition (closing<br />

Jan 31, 2008) was announced at the Sustainable Packaging Forum in<br />

Pittsburgh, Pa., by William F. Weber, vice president, DuPont Packaging.<br />

“Today there are strong drivers toward sustainable packaging including<br />

increasing consumer awareness, pull from brand owners and retailers,<br />

legislation and other factors. As a global leader in packaging materials<br />

and technologies, DuPont is working with customers on science-based<br />

packaging innovations that address consumer demands for performance<br />

and sustainability,” Weber said.<br />

“DuPont is committed to creating shareholder and societal value<br />

while reducing the environmental footprint in our value chains,” he<br />

continued. “Consistent with this commitment, the DuPont Packaging<br />

Awards now will honor materials, processing, technology and service<br />

achievements that demonstrate progress toward sustainability, while<br />

also meeting important market requirements for enhanced performance<br />

such as improved freshness, convenience and shelf appeal,” Weber<br />

said.<br />

A prestigious international jury panel contributed to the evaluation<br />

criteria for the 20th DuPont Packaging Awards. Factors such as innovation,<br />

enhanced performance, responsible sourcing, clean production<br />

and effective recovery will be considered in selecting the winners. As it<br />

was the case in the previous years also; the usage of a DuPont material,<br />

technology, process or service is not required for eligibility.<br />

In a collaboration to showcase packaging solutions that implement<br />

sustainability, information about entries in this year’s DuPont Awards<br />

will be posted online at the GreenBlue/Sustainable Packaging Coalition<br />

Design Library to be launched in early 2008. Capturing the innovations<br />

represented among these entries will support best practices throughout<br />

the packaging industry. GreenBlue is a nonprofit institute committed<br />

to sustainability by design and is home to the Sustainable Packaging<br />

Coalition, an industry working group recognized as the definitive<br />

resource for credible information about packaging sustainability.<br />

Potential growth<br />

for Australian<br />

bioproducts<br />

A range of biologically-based products,<br />

such as biodegradable plastics and packaging<br />

materials produced from plants instead<br />

of petroleum, offer new opportunities for<br />

Australian farmers.<br />

‘Biobased Products – Opportunities for<br />

Australian agricultural industries‘ is one of<br />

four new reports from the Rural Industries<br />

Research and Development Corporation<br />

(RIRDC) presenting a picture of the current<br />

status and future prospects for Australia’s<br />

biofuels and biobased product industries.<br />

The reports examine a range of issues relevant<br />

to government and policy-makers, the<br />

biofuels industry, the agricultural and livestock<br />

industries, scientists and consumers.<br />

“Research into the development of Australia’s<br />

biofuel and bioproducts industries<br />

has become an integral part of determining<br />

and securing our nation’s energy future,”<br />

said RIRDC Chair Mary Boydell. “We are<br />

particularly keen to identify new biobased<br />

industries that will complement, rather<br />

than compete with, food production,” she<br />

said. “There … are … products like plastics<br />

that are heavily reliant on petroleum. This<br />

research identifies potential replacements<br />

for fossil fuels with agricultural products<br />

like sugar, soybeans, woody crops and corn<br />

starch,” Ms Boydell added.<br />

www.rirdc.gov.au<br />

www.packaging.dupont.com<br />

www.greenblue.org<br />

bioplastics MAGAZINE [07/04] Vol. 2


News<br />

Photo: RacingThePlanet Limited (www.racingtheplanet.com)<br />

Novamont supported antarctic<br />

marathon runner<br />

The Italian marathon runner Francesco Galanzino joined six other athletes in<br />

crossing the coldest landmass in the world, racing over 250 km in temperatures<br />

ranging from -10 C° to -30°C. Starting out by sea from Argentina, they crossed<br />

the Southern Polar ice cap in 5 days, from 21 November to 1 December, 2007.<br />

Galanzino, wherever possible, replaced traditional plastics with biodegradable<br />

and compostable plastics. Novamont provided him with kits of single-use<br />

Mater-Bi tableware as well as sorted collection refuse bags. This allowed all<br />

refuse to be returned to Italy for intelligent disposal. Every kg of organic matter<br />

which is properly initiated in compositing allows for a saving of about 250gr in<br />

CO 2<br />

emissions, considerably reducing environmental impact.<br />

www.novamont.com<br />

www.4deserts/thelastdesert/<br />

Novomer raises<br />

$6.6 million to bring<br />

novel ‘eco-plastics‘<br />

to market<br />

Novomer Inc., a Cornell University spin-off founded<br />

in 2004, announced that it has raised US-$6.6<br />

million in series A funding. Physic Ventures co-led<br />

the financing in partnership with Flagship Ventures.<br />

The company is today pioneering a family of highperformance,<br />

biodegradable plastics, polymers and<br />

other chemicals from renewable substances such<br />

as carbon dioxide.<br />

Founded in 2004, Novomer’s technology is based<br />

on the discoveries of Professor Geoffrey Coates and<br />

his research group at Cornell University. Coates is<br />

an internationally recognized pioneer in the field of<br />

polymer science and a leading innovator in the increasingly<br />

vital arena of sustainable materials.<br />

The national trade magazine of the American<br />

Chemical Society wrote about Novomer‘s pioneering<br />

work: “Geoffrey W. Coates and his group at Cornell<br />

University have spent a decade developing catalysts<br />

to incorporate CO 2<br />

into polymers. Two successes,<br />

building on work by other groups dating back to the<br />

late 1960s, are β-diiminate zinc acetate and salen<br />

cobalt carboxylate complexes. These catalysts promote<br />

alternating copolymerization of various epoxides<br />

with CO 2<br />

to make biodegradable aliphatic polycarbonates.<br />

www.novomer.com<br />

Meredian Inc. announced<br />

acquisition of PHA<br />

technology from Procter<br />

& Gamble<br />

Meredian, Inc. a privately held corporation from Georgia, USA,<br />

announced the acquisition of an extensive intellectual property<br />

portfolio from The Procter & Gamble Company relating to Polyhydroxyalkanoate<br />

(PHA) technology. Procter & Gamble developed the<br />

technology through more than a decade of research, resulting in a<br />

highly functional and cost effective material, which will now be produced<br />

commercially by Meredian, Inc.<br />

“We are very pleased and excited to bring leading-edge, green<br />

technology to the marketplace,“ said S. Blake Lindsey, President of<br />

Meredian, Inc. “Meredian biopolymers combined with our existing<br />

DaniMer and Seluma biopolymers will enable us to provide synergies<br />

within these technology platforms and will result in one of the<br />

world‘s most versatile biopolymer product lines.“<br />

Harry Coleman, director of P&G‘s External Business Development<br />

adds, “As part of our open innovation strategy, P&G was seeking an<br />

enthusiastic company that could efficiently commercialize our intellectual<br />

property on polymers. We selected Meredian because of<br />

their dedication to biopolymers and strong ability to take our development<br />

work to the next level - delivering products to the market.<br />

We look forward to future collaboration with Meredian in this area.“<br />

Meredian expects to begin construction in 2008 on the first of four<br />

planned production facilities; the first will be located in the Southeastern<br />

United States. Meredian plans to produce over 600 million<br />

pounds of biopolymers annually.<br />

www.meredianpha.com<br />

bioplastics MAGAZINE [07/04] Vol. 2


New study on<br />

‘Nanohybrid’ PHB<br />

News<br />

In its November issue ACS‘ Biomacromolecules, a bi-monthly<br />

journal, published a study on the development of a new biodegradable<br />

‘nanohybrid’ plastic, based on PHB (polyhydroxybutyrate). In<br />

this study, Pralay Maiti, Carl A. Batt, and Emmanuel P. Giannelis<br />

(all from the Department of Material Science and Engineering or<br />

the Department of Food Science, Cornell University, Ithaca, New<br />

York) compared the strength and biodegradation rates of a ‘hybrid‘<br />

of PHB which contains ‘nanoclays‘ (nanoparticles of clay) to<br />

‘conventional‘ PHB. It was observed that the modified PHB showed<br />

increased mechanical and thermal properties and decomposed<br />

faster than regular PHB. The biodegradation rate of the nanohybrid<br />

PHB is enhanced significantly in the presence of nanoclay. In<br />

about seven weeks the material decomposed almost completely,<br />

whereas the rate of biodegradation is quite slow in pristine PHB, as<br />

the researchers discovered.<br />

http://pubs.acs.org/cgi-bin/sample.cgi/bomaf6/<br />

2007/8/i11/html/bm700500t.html<br />

Biggest European<br />

WPC Congress<br />

After the great success of the First German WPC Congress in<br />

2005 (WPC=Wood-Plastic-Composites) the organiser, nova-Institut<br />

from Hürth, Germany, arranged the Second German WPC Congress<br />

on 4th and 5th of December 2007 in Cologne. About 350 participants<br />

from 24 countries saw presentations that were simultaneously<br />

translated into English. 30 companies showed their innovations in<br />

the accompanying exhibtion. Among the highlights of the event was<br />

the first WPC Innovations award and the introduction of a ‘certificate<br />

of quality‘ by the Association of the German Wood-Based Panels<br />

Industries (VHI). Even though the matrix in WPCs is still mainly<br />

made of polypropylene, an increasing number of developments also<br />

cover the use of biobased polymers as matrix components.<br />

www.wpc-kongress.de<br />

www.vhi.de<br />

Bio-coated paper<br />

cup range launched<br />

by Huhtamaki<br />

Huhtamaki‘s range of single-use BioWare cups,<br />

plates, containers and cutlery is now being completed<br />

with bio-coated paper cups for hot and cold<br />

drinks. The BioWare paper cup range is the first<br />

complete bio-coated paper hot and cold cup range<br />

launched in Europe, as the company stated. The<br />

bio-coating allows the paper cups to be composted<br />

in industrial composting facilities. Fibers for the paper<br />

cups come from sustainably managed forests<br />

and can be traced back to their origin. The cartonboard<br />

material has Forestry Stewardship Council‘s<br />

(FSC) chain of custody certificate.<br />

BioWare paper cups are as strong and rigid as<br />

conventional Huhtamaki heavy board cups. The<br />

complete range of hot and cold cups include cup<br />

sizes from 100ml to 500ml, making this range suitable<br />

for different beverages and drink sizes. Excellent<br />

customized printing and promotional options,<br />

but also attractive BioWare stock design with ‘compostable’<br />

printing, are available.<br />

Designed to fulfill the needs of various foodservice<br />

operators, BioWare products work in uses<br />

ranging from outdoor festivals and mass events to<br />

catering and daily food and beverage service. By using<br />

BioWare, restaurants and event organizers can<br />

combine the waste stream for packaging and food.<br />

www.huhtamaki.com<br />

bioplastics MAGAZINE [07/04] Vol. 2


Review<br />

show<br />

review<br />

K‘2007 the world‘s number 1 plastics and rubber fair<br />

In the last issue, we reported about the bioplastics related exhibits of a<br />

large number of companies, to be presented at K‘2007 in Düsseldorf Germany,<br />

from October 24 to 31, 2007. Together with this review, we try to give<br />

our readers a most complete overview about what K‘2007 offered in terms<br />

of bioplastics materials, machinery and applications.<br />

Arkema: Pebax Rnew<br />

Arkema unveiled<br />

latest innovations<br />

Well known for its many years of experience<br />

with Rilsan ® Polymaide 11 made from castor<br />

oil (see bM 01/2007) Arkema, Paris, France<br />

presented three new technical polymers produced<br />

from renewable raw materials. Pebax ®<br />

Rnew, a first range of thermoplastic elastomers<br />

based on the chemistry of polyamide 11<br />

produced from castor oil, offers properties<br />

such as lightweight, flex fatigue resistance<br />

and elasticity return, over a wide temperature<br />

range.<br />

Biostrength TM , an innovative impact modifier<br />

for biodegradable PLA allows converters<br />

to process the biobased resins using conventional<br />

equipment. These additives also impart<br />

to this new polymer made from renewable raw<br />

materials the necessary mechanical, optical<br />

and aesthetic properties to fulfill the requirements<br />

of the main intended markets.<br />

Also from 100% renewable raw materials<br />

is Platamid ® Rnew, a new concept for thermoplastic<br />

hotmelt adhesives. A new grade<br />

has been developed to fulfill two new market<br />

needs: reduced emissions as per standard<br />

VDA 278, and eco-design by using raw materials<br />

from 100% renewable raw materials.<br />

The power of nature<br />

BIOPLAST GmbH from Emmerich, Germany, a subsidiary of the Sphere<br />

Group and Stanelco plc, presented BIOPLAST ® , a new generation of thermoplastic<br />

and completely biodegradable materials. Its range of five major<br />

products covers a wide number of rigid and flexible product applications.<br />

BIOTEC‘s expertise lies in the know-how regarding blending and modifying<br />

such resins to special compounds and blends, concentrates and<br />

masterbatches. The materials are certified in accordance with DIN EN ISO<br />

9001:2000 and DIN EN ISO 14001:2004. This certification is audited by an<br />

independent certification agency annually.<br />

www.biotec.de<br />

Hishiecolo pipes, which<br />

return to soil<br />

Biodegradable plastic pipes and fittings from raw materials such as PLA<br />

were presented by Mitsubishi Plastics Inc from Hiratsuka-City, Japan. The<br />

pipes offer the same strength and impact properties as Mitsubishi‘s vinyl<br />

chloride ‚Hishi Pipes‘, but they biodegrade and undergo hydrolysis from<br />

water and microbes living in the natural world. Potential applications are<br />

temporary pipes for short term use, pipes where retrieval is difficult and<br />

pipes in areas where the natural environment is a concern (rainwater<br />

ducts, etc.). Mitsubishi expect a variety of other uses to appear.<br />

www.mpl.co.jp<br />

Flexible PU-foam with<br />

100% biobased polyol<br />

Mitsui Chemicals Polyurethanes from Nagaura, Japan presented flexible<br />

polyurethane foams with a polyol component made from 100% castor<br />

oil. The final polyurethane contains 70% polyol and 30% isocyanate. The<br />

main feature of this polyurethane foam is its low resilience property, which<br />

makes it ideal for use in pillows. Other polyurethane foams with a biobased<br />

content are rigid foams for insulation purposes. In these materials<br />

the polyol consists of 30% renewable raw materials.<br />

www.arkema.com<br />

www.mcpu.mitsui-chem.co.jp<br />

bioplastics MAGAZINE [07/04] Vol. 2


J.C. Grubisisch<br />

No<br />

rainforest to be cut for<br />

sugarcane production?<br />

bioplastics MAGAZINE reported about BRASKEM and the new<br />

bio-polyethylene based on ethanol from sugarcane in the last<br />

issue. However, once in a while people express their concerns<br />

about rainforests being uprooted for new agricultural space to<br />

grow sugarcane that is needed for the production of bio-ethanol.<br />

In a press conference at K‘2007, J.C. Grubisich, CEO of Braskem<br />

stated that in Brasil the rainforests are in the north of the vast<br />

country, whereas the sugarcane plantations are in the southeast.<br />

In addition, land and climate in the north – the rainforest<br />

area - isn’t appropriate for sugarcane production. At least for<br />

the time being, bio-ethanol production from sugarcane does not<br />

threaten the brasilian rainforests.<br />

www.braskem.com.br<br />

PLA Nanoalloy<br />

Toray Industries, Inc. presented a Polylactic Acid Nanoally<br />

with improved properties. A small amount of high performance<br />

polymer is finely dispersed at nanometer scale in PLA building<br />

a network structure. The new materials reach impact and heat<br />

resistance properties above those of PET, PS and even HI-PS.<br />

Potential applications are for example mobile phone charger or<br />

PC housings. Earlier this year Toray announced that it has successfully<br />

developed a plant fiber-reinforced PLA plastic with improved<br />

heat resistance, rigidity and moldability by compounding<br />

cellulose-based plant fibers with PLA. Able to withstand heat<br />

up to 150°C, which is the highest level in the world for biomass<br />

plastics, the newly developed plastic has double the rigidity of<br />

existing PLA plastics and has achieved significant reduction in<br />

the time required for molding.<br />

PLA - cast and<br />

biaxially oriented<br />

film equipment<br />

Review<br />

Brückner Formtec GmbH and Brückner Maschinenbau<br />

GmbH & Co. KG presented their equipment for<br />

converting thermoplastics including PLA into films.<br />

bioplastics MAGAZINE reported about cast film lines<br />

from Brückner Formtec in issue 01/2007. BOPLA (biaxially<br />

oriented PLA) films can be produced on machinery<br />

from Brückner Mashcinenbau (see page 25 in<br />

this issue).<br />

www.brueckner.com<br />

BASF polyamide 6.10<br />

based on castor oil<br />

A material developed, produced and marketed by<br />

BASF over fifty years ago in the pioneering phase of<br />

engineering plastics is undergoing a renaissance. At<br />

K‘2007 BASF unveiled Ultramid ® BALANCE, a polyamide<br />

6.10. This is based to the extent of about 60% on<br />

sebacic acid, a renewable raw material derived from<br />

castor oil.<br />

In the K-show preview we already mentioned Ecovio<br />

L foam materials based on of Ecoflex and polylactic<br />

acid (PLA). Ecovio L Foam’s content of PLA amounts<br />

to more than 75% in weight. According to the standard<br />

ASTM D6866 it has a “biobased content” of more than<br />

75% as well. This number describes the amount of biobased<br />

carbon atoms. BASF is anticipating its first production-scale<br />

amounts by early 2008, so that Ecovio L<br />

Foam will be introduced into the market among select<br />

partners over the course of 2008.<br />

www.basf.com<br />

BASF: Eccovio L foam<br />

www.toray.com<br />

For details about the exhibits of the following companies,<br />

see bioplastics MAGAZINE issue 03/2007:<br />

A. Schulman GmbH<br />

Clariant International AG<br />

Biomer<br />

FkuR Kunststoff GmbH<br />

Fraunhofer Umsicht<br />

Grafe Advanced Polymers GmbH<br />

M-Base Engineering + Software GmbH<br />

Novamont S.p.A.<br />

PolyOne<br />

Telles (Metabolix)<br />

Roll-o-matic<br />

Sukano Products Ltd.<br />

FAS converting machinery see page 21 in this issue<br />

bioplastics MAGAZINE [07/04] Vol. 2


Review<br />

Dow and Crystalsev:<br />

Polyethylene from<br />

ethanol<br />

The Dow Chemical Company, the world‘s largest producer<br />

of polyethylene, and Crystalsev, one of Brazil‘s largest<br />

ethanol players presented their plans for a world-scale<br />

facility to manufacture polyethylene from sugar cane.<br />

The two companies will form a joint venture in Brazil to<br />

design and build the first integrated facility of its scale in<br />

the world. Start of production is expected for 2011 with a<br />

capacity of 350,000 metric tons.<br />

www.dow.com<br />

www.crystalsev.com.br.<br />

Transforming<br />

modified natural materials<br />

into innovative<br />

applications<br />

VTT Technical Research Centre of Finland has built<br />

up extensive knowledge in modifying and adding new<br />

functions to natural polymers—such as starch, cellulose,<br />

and wood fibres—over the past 10 years. This work<br />

has resulted in a number of sustainable processes and<br />

commercial products, such as starch derivates for tailoring<br />

the surface properties of paper, starch-based<br />

pigments, water-based and hot-melt glues, injection<br />

moulding materials, dispersion formulations into coatings<br />

and adhesives as well as coating and matrix materials<br />

for the controlled release of ingedients.<br />

Gehr: extruded rods<br />

First in the world<br />

extruded rods made of<br />

biopolymer<br />

The family owned company GEHR, which is located in Mannheim,<br />

Germany, has extruded what is most probably the world’s<br />

first ‘biological rod’. PLA-L is the name of this biopolymer.<br />

PLA-L consists of Polylactide (PLA) and Lignin (= wood). With<br />

PLA-L, the worldwide leading company for extruded thermoplastics<br />

(POM, PVC, PEEK, etc), further expands its product<br />

range in rods. PLA-L is available in the diameters from 10 to<br />

40mm.<br />

PLA-L is a thermoplastic material based on renewable,<br />

ecologically harmless and biodegradable raw materials. Under<br />

appropriate conditions it can be disposed of by either industrial<br />

composting or by climate-neutral incineration. PLA-L<br />

exhibits good mechanical properties that are similar to ABS.<br />

It shows a high stiffness (modulus of elasticity is 2740 MPa)<br />

and good impact strength. It also exhibits a good resistance to<br />

polar media such as acids, bases and solvents. It can be used<br />

in temperatures from - 30 °C to + 60 °C.<br />

„You can hardly imagine the variety of applications“, says<br />

Bernhard Grosskinsky, head of the technical department at<br />

GEHR.<br />

„Because of its advantages with regards to its biodegradability<br />

and consequent low environmental impact, it is very<br />

likely that PLA-L can be used in the toy and agricultural industry<br />

as well as in mechanical engineering and the medical<br />

industry.“<br />

www.gehr.de<br />

Elastogran: matress<br />

www.vtt.fi<br />

Matress made of<br />

24% renewables<br />

Elastogran GmbH, a company of the BASF group presented<br />

Lupranol ® BALANCE. Through the application of a completely<br />

novel type of catalyst it has been possible for the first time to employ<br />

natural castor- oil in the production of low-emission flexible<br />

foam polyols. The new product is made up of 31% castor oil. A<br />

finished mattress made with Lupranol BALANCE contains up to<br />

24% by weight of castor oil, without impairing the performance<br />

of the foam. This very high percentage of renewable raw material<br />

in the finished product is a breakthrough in the realm of<br />

polyurethane base products.<br />

www.elastogran.de<br />

10 bioplastics MAGAZINE [07/04] Vol. 2


Biodegradable<br />

compound<br />

SAM-A C&I Corporation Ltd from Korea presented<br />

their advanced technology to improve physical properties,<br />

processability and chemical stability of biodegradable<br />

resins which have inherently fragile properties.<br />

SAM-A offers this by enhancing the compatibility of biodegradable<br />

resins, proper composition and development<br />

of additives based on many years of experience. SAM-A‘s<br />

biodegradable resins are composed of PLA and aliphatic<br />

polyester, environmentally friendly and biodegradable<br />

plastics and can replace traditional plastics because<br />

they offer excellent physical properties such as strength,<br />

heat stability and chemical resistance, as can be read in<br />

their K‘2007 brochure.<br />

www.samacni.co.kr<br />

3rd generation natural<br />

fibre composites<br />

At present Kareline Oy Ltd fom Joensuu, Finland say<br />

they have the widest range of bio-composites available<br />

in the market. These materials are based on PLA, but<br />

also natural fibre composites with a matrix of PP, PE,<br />

ABS, PS, POM are available. The natural fibre content<br />

varies between 20 to 55 wt-%.<br />

The reinforcing fibres used are wood-based cellulose<br />

fibres manufactured in the most ecologically advanced<br />

mills in the world. Wood raw material used in the process<br />

is environmentally certified.<br />

The Kareline ® composite granulates can be injection<br />

moulded in all standard thermoplastic injection moulding<br />

machines and tools. This material has already been<br />

in use all over the world in a wide variety of different<br />

machines and tools.<br />

www.kareline.fi<br />

Kareline: flexwood guitar<br />

Symphony in<br />

technology<br />

Reifenhäuser GmbH & Co. KG presented their machinery in<br />

Düsseldorf as well as in their premises in Troisdorf Germany.<br />

In the Technology Center in Troisdorf a premium 3-layer blown<br />

film line Filmtec 3-1700-IBC-RHS with IBC was shown among<br />

others. The flexible line concept with an excellent price/performance<br />

ratio features low-temperature screws and three<br />

REItorque extruders, so that the range of applications is completed<br />

by bio packaging.<br />

Processing of PLA material was be demonstrated on the<br />

high-performance thermoforming sheet line MIREX-W-3-<br />

130/80/50-1000. The series is available as mono or coex line<br />

for up to 7 layers.<br />

www.reifenhauser.com<br />

Review<br />

BioLog: product examples<br />

New compounding<br />

process for bioplastics<br />

BioLog GmbH from Queis, Germany have developed a new<br />

patented bioplastic based on starch, chitosan and polyester.<br />

It can be processed in film blowing (10-30 µm) e.g. for food<br />

packaging or in thicknesses of 30-200 µm for mulch films,<br />

bags, liners or covers. Monolayer as well as multilayer applications<br />

are possible. Furthermore extrusion blow moulding,<br />

thermoforming films, injection moulding applications such as<br />

planting pots, cups, cutlery etc. Foam applications for building<br />

industry and packaging applications round off the portfolio.<br />

In Düsseldorf, BioLog presented themselves at the booth of<br />

Reimelt Henschel MischSysteme GmbH from Kassel, Germany.<br />

They developed a new process for the compounding of<br />

BioLog material. A new screw design of the twin-screw extruder<br />

allows to process higher amounts of starch even with a<br />

higher moisture content.<br />

www.biolog-heppe.de<br />

www.reimelt-henschel.com<br />

bioplastics MAGAZINE [07/04] Vol. 2 11


Review<br />

PLA sheet material with<br />

better impact properties<br />

UK-based VitasheetGroup has developed a new range of biodegradable<br />

PLA based materials which offer greater impact resistance and<br />

improved processability — properties which are often challenging with<br />

PLA.<br />

ViForm Bio 9100 and ViPrint Bio 9100 offer the traditional benefits of<br />

PLA products — compostability, renewable resources origins, but have<br />

been modified so they will have a much better impact strength‚ improving<br />

overall durability of the material and affording excellent performance<br />

in die-cutting and folding.<br />

Biodegradable materials such as PLA are currently used in a number<br />

of applications ranging from food packaging to blisters, but until now<br />

have had little interest for producers of horticulture labels or cosmetic<br />

boxes due to issues with brittleness and folding ability.<br />

“What has traditionally limited the use of bio-degradable materials in<br />

certain applications has now become a thing of the past,“ says Stephane<br />

Jacquet, VitasheetGroup Business Manager for the Packaging and<br />

Graphic Arts sectors.<br />

ViForm Bio 9100 and ViPrint Bio 9100 are available in white and transparent<br />

and gauges ranging from 300 micron to 650 micron.<br />

www.vitasheetgroup.com<br />

DuPont expands portfolio of<br />

renewably sourced polymers<br />

With Sorona ® EP thermoplastic resins, Hytrel ® RS thermoplastic<br />

elastomers, Biomax ® RS packaging resins and Selar ® VP breathable<br />

films DuPont presented in Düsseldorf a number of new plastics based<br />

on renewable resources.<br />

A key ingredient in Sorona EP is Bio-PDO which is made by DuPont<br />

and Tate & Lyle. Bio-PDO will be used in the two glass-reinforced grades<br />

of Sorona EP that will initially be available.<br />

Hytrel RS incorporates Cerenol renewably sourced polyol made with<br />

Bio-PDO. Initial grades of Hytrel RS will have a renewable content range<br />

of 25-50%.<br />

Biomax RS 1001 is a renewably sourced polytrimethyl terephthalate<br />

(PTT) offering aimed at rigid packaging applications such as injection<br />

molded containers, caps and consumer items such as media cases<br />

where it would replace polypropylene. Initial applications are targeted<br />

for cosmetics, food and consumer goods packaging. Biomax RS 1001<br />

incorporates has a renewable content of 35% with Bio-PDO as the key<br />

ingredient.<br />

Selar VP is a renewably sourced breathable film, designed for use in<br />

applications where foods need to respire, such as fresh fish and produce.<br />

It is up to 40% renewably sourced with the incorporation of a vegetable<br />

based fatty acid.<br />

www.dupont.com<br />

The “green”<br />

challenge<br />

For high-potential applications – ranging<br />

from refrigerator insulation to imitation<br />

forest floors Bayer MaterialScience from<br />

Leverkusen, Germany has now developed<br />

polyols (as component for polyurethanes)<br />

based up to 70% by weight on renewable raw<br />

materials to help cut down emissions.<br />

Polyurethane all-foam mattresses are currently<br />

very much in vogue and their market<br />

share has been rising for years. However, consumers<br />

would be unwilling to accept compromises<br />

in performance or above all durability.<br />

Following extensive development work, experts<br />

from Bayer MaterialScience were able<br />

to raise the properties of the „green“ foams<br />

up to the same high level as standard products.<br />

At K 2007, Bayer MaterialScience also<br />

presented a molded-foam part typically used<br />

in car seats. The polyol used for this was also<br />

based largely on renewable raw materials.<br />

Another exhibit on display was a high-end<br />

refrigerator. The proportion of renewable raw<br />

materials it uses is double that of conventional<br />

polyurethane insulating foam systems.<br />

Walking or running on a soft surface provides<br />

a more comfortable underfoot sensation.<br />

An artificial forest floor that Bayer MaterialScience<br />

has produced by combining a<br />

viscoelastic flexible polyurethane foam with<br />

textile overlays and a soft pile offers this feeling<br />

for your own bathroom. An extremely high<br />

volume of a polyol based on modified vegetable<br />

oils is used in the formulation without<br />

producing any adverse effect on technical<br />

properties such as tensile strength and durability.<br />

www.bayer.com<br />

Photo: Bayer<br />

12 bioplastics MAGAZINE [07/04] Vol. 2


Timberland shoesoles<br />

with renewable content in<br />

the polyol component<br />

Dow Footwear Solutions announced during K‘2007 that it will supply its<br />

VORALAST Soling System with renewable content to The Timberland Company<br />

for the Miōn ® Spring 2008 line of outdoor footwear. Dow Footwear Solutions<br />

is a business unit recently launched by The Dow Chemical Company<br />

and is a leading provider of innovative solutions to the footwear industry<br />

worldwide. „We are very excited about our development partnership with<br />

Timberland that has used our VORALAST R series system with renewable<br />

polyol content to deliver both a durable, water resistant polyurethane sole<br />

and an advance in sustainability,” said Antonio Batistini, Research & Development<br />

Director for Dow Footwear Solutions.<br />

www.dowfootwear.com<br />

PLA bottle blowing<br />

machinery<br />

Stretch blow moulding machines for the production of PLA bottles are part<br />

of the scope of supply of Sistec srl. from Pordenone, Italy. Their models SSB-<br />

02/03 are the ideal solution, versatile and easy to use, as a spokesman said.<br />

Sistec presented themselves on the stand of MAG Plastic SA in Hall 13, right<br />

next to SIG Corpoplast from Hamburg, Germany. SIG‘s BLOMAX machine series<br />

were the first to produce the PLA bottles of Biota (USA) and Belu (UK). In<br />

addition, sister company SIG Plasmax offers barrier coating systems to apply<br />

an inner layer of SiOx (glass) to both, PLA and PET bottles for enhanced barrier<br />

properties against water vapour, CO 2 and Oxygen.<br />

www.sistec-pn.it, www.sig.biz<br />

10mm twinscrew<br />

compounder<br />

An ideal solution for compounding minimal<br />

amounts of test compositions, for example of<br />

sensitive materials or with nano materials, is<br />

the 10 mm twinscrew compounder of Rondol<br />

from Stone, UK. Non Invasive mixing allows<br />

rapid batch mixing at a selected degree of<br />

specific energy allowing totally enclosed high<br />

shear or low shear mixing. The twinscrew<br />

compounding technique meets the essential<br />

requirements of<br />

• High torque dispersive mixing with optimised<br />

screw profiles<br />

• The capability of adding measured quantities<br />

of nano materials to melt stream<br />

• The facility to process small quantities<br />

• A small equipment ‘footprint’ to allow<br />

bench top/clean room installation<br />

www.rondol.com<br />

Eco-Smart TM hot runner<br />

system for PLA<br />

D-M-E, a Milacron company introduced Eco-Smart hot runner systems,<br />

which are ideaI for processing “green“ plastic resins - proven successful with<br />

PLA. Eco-Smart Hot Runner Systems provide an ecological molding advantage.<br />

D-M-E is qualifying additional polymers as they become available.<br />

Key Advantages of Eco-Smart Hot Runner Systems:<br />

• Uninterrupted material flow path for reduced shear<br />

• Corrosion-resistant components<br />

• Front-removable heaters and thermocouples for easy system maintenance<br />

• Thermal isolation component design for improved performance<br />

• Superior thermal control from machine nozzle to moulded part surface<br />

Masterbatches<br />

for PLA<br />

Masterbatched for PLA were shown by<br />

VANETTI MASTERBATCHES from Marnate,<br />

Italy. The masterbatches for PLA granulate<br />

are particularly recommended for film extrusion.<br />

Continuous research in this field, in cooperation<br />

with University Politecnico Milano,<br />

Italy, will allow the range of masterbatches to<br />

be expanded in compliance with the standards<br />

requested in the various fields of application.<br />

Certification according to EN 13432 is expected<br />

for the end of this year.<br />

www.vanettimaster.com<br />

www.dme.net<br />

bioplastics MAGAZINE [07/04] Vol. 2 13


Review<br />

2 nd European Bioplastics<br />

Conference<br />

in Disneyland Paris<br />

Dr. Harald Käb<br />

The 2nd European Bioplastics Conference has proven to<br />

be the place to be in bioplastics industry. 360 bioplastics<br />

professionals from 29 countries met in Paris at the largest<br />

bioplastics event ever in Europe that was organised<br />

for the second time by the industry association European<br />

Bioplastics.<br />

Record attendance of delegates, speakers and exhibitors<br />

The number of delegates as well as the comprehensive<br />

exhibition showed the relevance of the promising industry.<br />

The delegates followed the presentations of 45 speakers<br />

about material novelties, biopackaging innovations, consumer<br />

insights, political frameworks to end of life options<br />

in alternating plenary and parallel sessions.<br />

The exhibition room, where 26 exhibiting companies<br />

showcased their latest products and developments, provided<br />

a unique environment for extended networking.<br />

Keynotes on bioplastics<br />

The first plenary session was opened by a welcome<br />

adress of Dr. Harald Käb, Chairman of European Bioplastics<br />

and Christophe Doukhi-de Boissoudy, Chairman of the<br />

French Clubbioplastiques. Käb introduced the challenges<br />

for the future bioplastics development: „Sufficient material<br />

supply will be a very basic parameter for the future<br />

of bioplastics. This can be achieved by utilising existing<br />

production capacities to the full, building up new production<br />

sites by known and yet unknown market players and<br />

broadening the scope of materials and material properties.“<br />

Also waste management will play a crucial role as<br />

well as material developments.<br />

„The bioplastics industry is at a cutting edge. Fortunately,<br />

politics become more and more aware of the potential<br />

of reducing dependency on crude oil not only for fuels but<br />

also in material use of renewable ressources.“ The representative<br />

of the French Ministry of Agriculture, Julien<br />

Turienne, took up the thread and explained the French<br />

policies for bio-based products, which are motivated by<br />

14 bioplastics MAGAZINE [07/04] Vol. 2


Review<br />

360 bioplastics experts 26 exhibitors<br />

their advantages, i.e. the substitution of non renewable<br />

resources, the improvement of innovation and competitiveness<br />

and the preservation and creation of jobs in agriculture<br />

and agro-industry. Amongst the French actions<br />

are the proposal to prefer bioplastic bags regulated by law<br />

(which was rejected by the European Commission due to<br />

the free trade and packaging directive; France now works<br />

on transforming these measures in incentive measures,<br />

e.g. ecotax).<br />

Production capacities<br />

European Bioplastics estimates the global production<br />

capacities of bioplastics to sextuple until 2011. The shares<br />

of the three material classes synthetic/biodegradable,<br />

biobased/biodegradable and biobased/non-biodegradable<br />

are expected to change significantly towards biobased/<br />

nonbiodegradable bioplastics. While their share is about<br />

12% in 2007 (of a total production capacity of 262.000<br />

tonnes/year), in 2011 the share of biobased/non-biodegradable<br />

bioplastics will be almost 40% of total capacity.<br />

The overall capacity will increase to 766.000 tonnes/year<br />

in 2009 to about 1.500.000 tonnes/year in 2011.<br />

European Bioplastics bases its estimations on publicly<br />

available announcements that have been published in the<br />

last months as well as on information gathered amongst<br />

their members. Provided a positive access to capital markets<br />

and thus investments production capacities can grow<br />

even faster.<br />

Material properties and material types<br />

To capture an even broader application range than today<br />

some bioplastics need to improve their material properties.<br />

Basically, this applies for barrier properties and heat<br />

resistance. Usual PLA softens at a temperature of about<br />

60°C and is not deployable for several applications. According<br />

to a manufacturer, PLA composed from D- and L-<br />

lactic acid shall be heat resistant up to 175°C. Thus, PLA<br />

will become applicable for e.g. micro-wave suitable products.<br />

According to several studies PLA bottles have a large<br />

growth potential. To capture more applications the barrier<br />

properties need improvement.The high permeability of<br />

water vapour for instance reduces the shelf-life. However,<br />

it is expected that new PLA types and barrier solutions will<br />

widen the scope of applications very soon. It is likely that<br />

new bioplastic materials and an increasing availability of<br />

bioplastics will accelerate product innovations.<br />

Waste management and bioplastics treatment<br />

Waste management will be a key success factor of bioplastics<br />

in two different ways. On the one hand, for compostable<br />

plastic products it is crucial to have composting<br />

infrastructures in place. That’s the reason why European<br />

Bioplastics advocates for a separate collection of organic<br />

and residual waste and for installing composting sites<br />

across Europe. In the EU, organic waste accounts for<br />

around 38% of municipal waste. This amounts to around<br />

120 million tonnes of organic waste per year, with the potential<br />

to obtain over 50 million tonnes of compost annually<br />

(in EU 25).<br />

On the other hand European Bioplastics is strongly supporting<br />

an adequate treatment of bioplastics given the<br />

quantities of the material. Organizing the most optimized<br />

waste management system is dependent on local infrastructures<br />

for collection and recycling, local and regional<br />

regulations, the total volume on the market available and<br />

the composition of waste streams.<br />

With both bioplastics and biopackaging in their infancy,<br />

the development of the market should not be delayed even<br />

though the most optimal recovery systems have often not<br />

been recognized by local authorities. The risks associated<br />

with existing recovery schemes should be monitored.<br />

These will be limited at this time given the relatively small<br />

volumes that currently enter the market. Once volumes<br />

reach a critical mass, waste management systems which<br />

make most sense from an environmental and economic<br />

point of view can be set up. Over time, recycling may be<br />

the best option for certain bioplastics, especially if a homogenous<br />

stream can be organized such as in place for<br />

plastic bottles.<br />

www.european-bioplastics.org<br />

bioplastics MAGAZINE [07/04] Vol. 2 15


Review<br />

Bioplastics Awards 2007<br />

The second Bioplastics Awards took place together<br />

with the ninth Bioplastics conference<br />

in Cologne, Germany, on December 5 th . Organised<br />

by European Plastics News, an audience of<br />

around 100 people attended the event to witness the<br />

recognition of some of the best bioplastics developments<br />

and applications.<br />

Launched in 2006, the Bioplastics Awards are intended<br />

to raise the profile of bioplastics, which, although<br />

a developing market, is still very much a niche.<br />

The result is that the sector’s achievements tend to be<br />

overshadowed by innovations in the mainstream packaging<br />

and plastics industries.<br />

The seven categories of the Bioplastics Awards intend<br />

to change all that, providing a platform to promote<br />

the innovative ideas that are driving the bioplastics<br />

market forward.<br />

EPN Editor and Conference manager, Chris Smith,<br />

said: “The 2007 Bioplastics Awards come at an important<br />

time for the bioplastics industry as we are seeing<br />

new and important developments not only in traditional<br />

compostable bioplastics but also in bio-sourced<br />

versions of traditional polymers, such as PE, PA, PU<br />

and TPEs. When this industry looks back in 10 years<br />

or so we might say that 2007 marked the beginning<br />

of a new renewable era in bioplastics production and<br />

application.”<br />

www.bpevent.com<br />

Nominees & Winners<br />

Category<br />

Best Innovation<br />

in Bioplastics<br />

Best Bioplastics<br />

Processor<br />

Best Bioplastics<br />

Application –<br />

Packaging<br />

Nominees & Winners<br />

Braskem, Brazil<br />

(Polyethylene from ethanol derived from<br />

sugar cane)<br />

Dow Polyurethanes, USA<br />

(Renuva range of bio-derived polyols,<br />

derived from vegetable oils)<br />

Merquinsa Mercados Quimicos, Spain<br />

(Pearlthane ECO TPUs, with 40 – 49%<br />

renewable contents)<br />

Teijin, Japan<br />

(BioFront PLA fibres with a melting point<br />

of 210°C)<br />

Amcor Flexibles, UK<br />

(heat sealable VFFS film using Mater-bi<br />

and much more)<br />

Leoplast, Italy<br />

(High quality PLA cases and packaging<br />

for the cosmetics industry)<br />

Treofan, Germany<br />

(Production of Biophan PLA films)<br />

Alcan Packaging, Ireland<br />

(Lamination of a range of fully compostable<br />

printed film products using PLA and<br />

Mater-bi)<br />

Alcan Packaging, Ireland<br />

(first fully printable laminate of Natureflex<br />

cellulose and Mater-bi, which can be<br />

home composted)<br />

Amcor Flexibles, UK<br />

(heat sealable VFFS Mater-bi film for<br />

packaging of Sainsbury’s So Organic<br />

salad potato range)<br />

Coopbox Europe, Italy<br />

(Naturalbox PLA foamed PLA tray and<br />

capping film meat packaging system)<br />

Wiedmer AG, Switzerland<br />

(Compostable PCO28 closure in Mater-bi<br />

resin for packaging of still beverages)<br />

16 bioplastics MAGAZINE [07/04] Vol. 2


Photos: European Plastics News<br />

Review<br />

Category<br />

Nominees & Winners<br />

Category<br />

Nominees & Winners<br />

Best Bioplastics<br />

Application –<br />

Non-Packaging<br />

WIP, Italy<br />

(Lov’N range of biodegradable hypoallergenic<br />

sanitary pads, exploiting the<br />

breathability of Mater-bi to retain moisture<br />

and keep the skin dry while moisture<br />

is absorbed by three PLA Ingeo fibre<br />

filtering layers)<br />

Arkema, France<br />

(Use of Pebax Renew in the Wave Creation<br />

training shoe by Mizuno of Japan)<br />

Elastogran, Germany<br />

(Use of bio-derived polyurethane resins<br />

in the Elastocoast coastal erosion defence<br />

system)<br />

NEC Corporation, Japan<br />

(Use of kenaf fibre reinforced PLA in a<br />

mobile phone casing)<br />

Teijin, Japan<br />

(Use of BioFront heat resistant PLA<br />

fibres in automotive prototype seat<br />

Best Bioplastics<br />

Retailer<br />

Delhaize, Belgium<br />

(One of the longest standing supporters<br />

of bioplastics, Delhaize has used more<br />

than 7 million PLA salad packs over the<br />

past two years replacing more than 120<br />

tonnes of traditional plastics. This year<br />

it switched its single-use carrier bags<br />

to starch-based plastics, estimating it<br />

will use 100 tonnes of the resins over the<br />

first 12 months. The group is also working<br />

with its national retail association<br />

FEDIS and waste association Fost-Plus<br />

to develop suitable end-of-life options)<br />

Sainsbury’s Supermarkets, UK<br />

(The 2006 winner in this category,<br />

Sainsbury’s environmental packaging<br />

approach continues to set the standard<br />

in the UK retail sector)<br />

Wal-Mart, US<br />

(Not a company with the greatest record<br />

on sustainability, Wal-Mart’s conversion<br />

to sustainable thinking and launch of its<br />

environmental scorecard have has really<br />

kick-started interest in bioplastics in the<br />

Best Bioplastics<br />

Marketing<br />

Initiative<br />

Excellent Packaging & Supply, US<br />

(provides customers with assistance in<br />

selecting the right product for its needs,<br />

The company is also highly active in the<br />

US in promoting organised composting<br />

schemes, without which many biodegradable<br />

products make little sense)<br />

Alcan Packaging, Ireland<br />

(Promotion of its fully customisable<br />

laminated packaging film materials)<br />

Novamont, Italy<br />

(Supply of two million sets of Mater-bi<br />

disposable tableware for the Loreto<br />

Agorà dei Giovani two-day eco-meeting<br />

in Italy, which was addressed by the<br />

Pope)<br />

Personal<br />

Contribution<br />

to Bioplastics<br />

NOTE:<br />

The Personal<br />

Contribution<br />

award is made<br />

by EPN alone.<br />

Martin K Patel<br />

(Martin Patel is not, perhaps, seen by<br />

many as part of the bioplastics industry,<br />

but the work he has been doing over the<br />

past 15 years in the techno-economic<br />

analysis of energy saving and emission<br />

reductions achievable through new and<br />

existing industrial biotechnologies is<br />

likely to become hugely important in the<br />

years to come.)<br />

bioplastics MAGAZINE [07/04] Vol. 2 17


Special<br />

Shopping bags, that<br />

dissolve in hot water<br />

Figure 1: degradation in soil after 3 months<br />

Headquartered Singapore, Biostarch Technology<br />

Pte Ltd was registered in 2004. However the Biostarch<br />

journey began with research in 1998. The<br />

technological process to produce the Biostarch biopolymer<br />

film was registered for international patent in 2005.<br />

The manufacturing headquarter is in Beijing, China.<br />

According to a company‘s spokesman, Biostarch offers<br />

a cost-effective, EN13432 certified, OK Compost mark approved,<br />

100% compostable biopolymer shopping bag solution<br />

and film for packaging. Biostarch products also meet<br />

the American ASTM-6400-99 Standard for Compostable<br />

Plastics and Australian AS4736-2006 Biodegradable<br />

Standard.<br />

Features<br />

The unique biodegradable and compostable nature of<br />

the Biostarch film is demonstrated by its ability to be dissolved<br />

in hot water. The rapid disintegration in a natural<br />

environment can be seen in fig. 1, showing a Biostarch<br />

bag before and after 3 months in the soil of an Australian<br />

garden.<br />

Other features include the following:<br />

• Comparable strength to conventional plastic bags<br />

• Made principally from the renewable resource corn<br />

starch<br />

• Does not contain the conventional plastic constituents<br />

such as polyethylene and polypropylene<br />

• Can be re-used (encouraged)<br />

• Ideally suited for dry goods but tolerates short term<br />

exposure to moisture.<br />

Shopping Bags<br />

For supermarkets, retail and department stores,<br />

Bio-starch Bags provide a variety of solutions:<br />

• Bio-Fresh bags on a roll, with perforation for easy<br />

separation. Ideal for fruit and vegetables.<br />

• Bio-Light, a lightweight bag for dry goods.<br />

• Bio-Mist, a lightweight bag for moist/refrigerated<br />

goods.<br />

• Bio-Multi, a heavy duty flexi loop bag for dry goods<br />

• Bio-Max, a grip hold bag ideal for retail outlets and<br />

department stores<br />

Film for Packaging and Plastic Converters<br />

Biostarch film is ideal for the packaging of dry goods<br />

and rolls are also available for plastic converters to<br />

manufacture bags to their own specifications. Biostarch<br />

film can be processed on conventional plastic bag<br />

manufacturing equipment with some adjustments.<br />

Biostarch‘s Vision<br />

Biostarch recognizes the environmental hazard<br />

caused by plastic bags and products. „We believe that<br />

government, business and environmental groups and<br />

individuals all need to work together to solve this problem,”<br />

says Dr. Jian Mao, CEO of Biostarch Technology.<br />

„Changes in patterns of behaviour are essential and<br />

the provision of certified biodegradable, 100% compostable<br />

biopolymer alternatives is mandatory,” he<br />

adds. Biostarch is excited to be able to be a part of the<br />

solution by offering a cost effective alternative to plastic<br />

bags and packaging and a more environmentally<br />

responsible alternative to paper bags. Together we can<br />

make a difference.<br />

www.biostarch.com<br />

18 bioplastics MAGAZINE [07/04] Vol. 2


Special<br />

Paperflex-Bio; paper plus bioplastic film<br />

Zipper-Bio bag<br />

World‘s first<br />

biodegradable zipper bag<br />

Forapack, an Italian flexible packaging films converter<br />

from Poggiofiorito, has expanded its product<br />

range of ready-made bags and pouches with a new<br />

series for food producers and retailers. The three product<br />

lines follow the approved design and application but<br />

are made completely of biodegradable and compostable<br />

material.<br />

The Bagflex-F-Bio line consists of bags and pouches<br />

made from a single web of bioplastic film, such as PLA,<br />

Materbi, Naturflex and the like. These bags are hot-wire<br />

sealed, and can be custom-printed and micro-perforated.<br />

The Bagflex-HS-Bio series of bags and pouches is made<br />

from a laminate composed of Kraft paper and a bioplastic<br />

film. They come in a wide range of options, e.g. with or<br />

without die-punched handle or custom-printed. The Kraft<br />

paper is available in white or havana colour. The bioplastic<br />

film can be PLA, Materbi or Natureflex, depending on the<br />

application. Organic adhesives are used between the two<br />

layers to allow for 100% biodegradability. In this respect,<br />

Forapack also carries out flexo printing in up to eight colours<br />

with water-based inks. As required the central film is<br />

produced opaque or transparent to show the contents.<br />

The Paperflex-Bio series of bags and pouches consists<br />

of a laminate of paper plus a bioplastic film, with or without<br />

a central „window“. In comparison with the abovementioned<br />

products Paperflex-Bio is produced in reels for<br />

automatic packaging machine applications.<br />

The Zipper-Bio bags are made of paper laminate plus<br />

biodegradable compostable plastic laminates. Its unique<br />

feature is the world‘s first re-closable zippers made of<br />

biodegradable plastic (a Forapack exclusive speciality),<br />

making the contents watertight and airtight. The applica-<br />

tion of the biodegradable zipper to a bag or pouch made<br />

of biodegradable compostable laminate is a Forapack patent.<br />

One of the latest developments is a PLA film with enhanced<br />

oxygen barrier properties to protect the contents<br />

from oxidation. It was developed in collaboration with<br />

an Italian barrier film producer. Barrier enhancement is<br />

obtained by applying a very thin layer of a special, highly<br />

transparent and food-grade lacquer onto the film surface.<br />

The barrier film is converted as a single web (Bagflex-F-Bio)<br />

or alternatively Forapack laminates it to paper<br />

(Bagflex-HS-Bio and Paperflex-Bio) resulting in a biodegradable<br />

laminate that ensures better protection for the<br />

product, and offers a longer shelf life.<br />

All mentioned products are being tested by independent<br />

laboratories and the results will show full comparability<br />

with the properties of fossil oil based plastic films,<br />

including conformity to food contact regulations, machineability,<br />

transparency, natural permeability, long shelflife<br />

and antifog properties. Beside ensuring the necessary<br />

hygiene and food protection, Forapack promises that the<br />

new packaging solutions to be a valid marketing tool and<br />

offer distributors, food producers and final consumers a<br />

number of additional features that rarely come with other<br />

packaging solutions.<br />

www.forapack.it<br />

bioplastics MAGAZINE [07/04] Vol. 2 19


Special<br />

Article contributed by Christian Garaffa,<br />

Marketing Department, Project Manager<br />

Waste Management Area.<br />

After Ireland, San Francisco and Oakland in California,<br />

Modbury in Britain, the debate on disposable<br />

carrier bags has recently moved to London. Many<br />

other countries and cities are looking to introduce or already<br />

have some form of ban, tax, levy or some voluntary<br />

agreement on throwaway shopping bags (e.g. France or<br />

Italy).<br />

The question is always the same: how to manage the<br />

environmental issue posed by non biodegradable carrier<br />

bags? The common logic permeating the different choices<br />

is always the one dictated by the waste hierarchy: prevent,<br />

reuse, recover, dispose of.<br />

Factors like an intensive communication to the consumers<br />

and the introduction of reusable bags “for life”<br />

which can be used for several times before they are finally<br />

thrown away or given back to the store, are an essential<br />

part of this schemes.<br />

Compostable shopping<br />

carrier bags: what is the<br />

logic for their contribution<br />

to the environment?<br />

How do compostable carrier bags place themselves into<br />

this picture?<br />

www.novamont.com<br />

Compostable carriers can actually be a powerful aid to<br />

waste minimization and recovery policies especially there<br />

were organic waste collection schemes are to be set up<br />

or are already in place. In order for such schemes to be<br />

successful they must be hygienic for both consumer and<br />

collection crews and be as convenient as possible. The<br />

best way to ensure both these criteria is for consumers<br />

to line their kitchen caddy with a compostable liner which<br />

can then be tied and placed in the larger container. Using<br />

liners in this fashion not only keeps the system clean and<br />

hygienic from kitchen to collection to treatment facility,<br />

but by being simple to use, they also lead to higher levels<br />

of participation and subsequently greater amounts of food<br />

waste are recovered and less material is landfilled.<br />

A proper communication and the possibility for the<br />

householder to easily identify the compostable bags are<br />

completing the picture for this kind of schemes which are<br />

able to recover as much as 90% of the kitchen organics<br />

present in the household waste.<br />

20 bioplastics MAGAZINE [07/04] Vol. 2


Special<br />

Article contributed by Jonas Hellström,<br />

Marketing & After Sales Manager,<br />

FAS Converting Machinery AB, Ystad, Sweden<br />

Biobags: in-line<br />

production is the future<br />

The Scandinavian company BioBag International A/S,<br />

headquartered in Askim, Norway has great faith in<br />

the future. They have a long experience of making<br />

plastic bags and have used converting machines from FAS<br />

Converting Machinery AB, Ystad, Sweden for more than 15<br />

years. About three years ago BioBag International started<br />

to specialise in making plastic bags which are 100% biodegradable<br />

and compostable (according to standards such<br />

as EN 13432 or ASTM D6400) and which can be recycled or<br />

incinerated with a neutral greenhouse gas impact. Converting<br />

material from the Italian company Novamont into<br />

bags in-line on a machine from FAS is a very cost-effective<br />

way of making bags on a roll.<br />

”We believe in the future of this project”, says Jorn Johansen,<br />

president and CEO at BioBag International. Many<br />

people are becoming more aware of how important it is<br />

to take care of our Earth. BioBag International A/S has<br />

activities in 18 countries and the list of products is long. In<br />

Belgium for example, BioBag has a business arrangement<br />

with Jemaco nv. (also a customer of FAS), regarding the<br />

marketing and production of high quality bio-products.<br />

Jorn Johansen appreciates the quality of the machines<br />

and the good service from FAS, which fit well in this environmentally<br />

friendly future.<br />

Bag production in-line using the film blowing process<br />

is well known, and has been improved over the years by<br />

FAS, followed by other machine suppliers, as pointed out<br />

by Jonas Hellstrom, Marketing Manager at FAS.<br />

Especially with the combination of tensionless sealing<br />

and sealing from both sides, FAS perforation and sealing<br />

units are the ideal equipment to process biodegradable<br />

products. The FAS sealing system is one of the few that<br />

can handle a wide variety of film materials, e.g. all kinds<br />

of PE from HD to LD, recycled plastics and biodegradable<br />

materials, without any special adjustments required.<br />

In addition to the above-mentioned features, the FAS<br />

perforating and sealing units offer the benefits of constant<br />

or intermittent heating and adjustable seal pressure,<br />

which has proven to give many producers advantages<br />

when running different products on the same machine.<br />

The in-line process of film blowing and bag production<br />

brings a number of additional benefits, such as faster<br />

quality control of the plastic film, no capital locked up in<br />

storage for master rolls or floor space, and a better cash<br />

flow. And - thanks to converting a warm film which enables<br />

thick film to fold easily and the final winding to be<br />

easier – the final products often just look better.<br />

When it comes to total machine investment cost, an<br />

in-line set-up offers advantages over an off-line solution.<br />

One reason is a simpler blown film unit, as there is no<br />

need for a rotating head or winding equipment when running<br />

in-line.<br />

Other costs for a producer are the handling of master<br />

rolls and for the personnel needed to run the machines.<br />

In an in-line environment less operators are needed compared<br />

to an off-line set-up, which also provides financial<br />

benefits.<br />

As one of the biggest bag producers in Europe once<br />

said: “Produce this morning – deliver in the afternoon -<br />

and invoice tomorrow! That´s the key to success!”.<br />

www.fasconverting.se<br />

bioplastics MAGAZINE [07/04] Vol. 2 21


Materials<br />

Lactide<br />

Monomers<br />

for the<br />

production<br />

Article contributed by Hans van der Pol, Marketing Manager,<br />

PURAC biochem BV, Gorinchem, the Netherlands<br />

of PLA<br />

So far the focus for bioplastics developments has<br />

been in particular on the environmental and<br />

social elements. To make PLA sustainable on<br />

the long-term it is now crucial that the economic sustainability<br />

is secured. L- and D-lactide produced with<br />

PURAC technology in combination with PURAC’s value<br />

proposition for the value-chain members will allow<br />

PLA to become an attractive economic reality.<br />

Accelerating PLA potential<br />

Although many PLA applications have been developed<br />

over the last years, PLA is currently in short<br />

supply. In order for the bioplastics market to grow at<br />

the pace dictated by the customer demand, there is a<br />

need for a higher level of PLA supply. The main factors<br />

hampering the growth in supply are PLA product quality<br />

and the availability of an economically sustainable<br />

production technology as part of the PLA value-chain.<br />

The key factor in this chain is the technology to produce<br />

high purity, polymer grade, lactic acid with high<br />

carbohydrate efficiency – the core expertise of PURAC,<br />

whose technology has been optimized over decades.<br />

PLA for packaging applications was developed in the<br />

nineties but it is not until very recently that the value<br />

chain for PLA applications has been seriously expanded.<br />

The Kyoto protocol and the associated trading<br />

schemes for carbon dioxide certificates are providing<br />

companies with real incentives to reduce their carbon<br />

dioxide emissions by investing in more environmentally<br />

benign technologies and products. Bioplastics and<br />

bio-fuels are at the forefront of this trend.<br />

Market opportunities<br />

With improvements in PLA supply and quality as<br />

well as development of value added applications it is<br />

expected that the market for PLA can grow to a level<br />

of several hundreds of ktons over the next 10 years.<br />

The bioplastics industry is still in a very early stage of<br />

its development. Institutional, legal and policy framework<br />

conditions are adjusted continuously in order to<br />

stimulate a continuous growth of sustainable materials.<br />

The market for traditional polymers is over 250<br />

mio tons and growing. Many framework conditions for<br />

these traditional polymers actually act as barriers for<br />

the new polymers. The bioplastics industry has grown<br />

so far without the huge subsidies heaped upon bioethanol.<br />

The opportunities to capitalize on this are immense.<br />

The total consumption of biodegradable polymers<br />

stood at around 140 ktons in 2006, with packaging representing<br />

31% of the total consumption. The projected<br />

growth for PLA in this segment is estimated 23%<br />

per year.<br />

With improvements in technology, higher value added<br />

applications such as fibers and engineering plastics<br />

can be developed. Such higher value added applications<br />

are important to turn a bio-based economy into<br />

reality, as it will improve the economic sustainability of<br />

the value-proposition.<br />

Retailers and brand-owners recognize possibilities<br />

to capitalize on the sustainability trend by re-branding<br />

their image as an environmentally conscious company<br />

22 bioplastics MAGAZINE [07/04] Vol. 2


Materials<br />

by incorporating innovative bio-based packaging<br />

solutions into their product lines. This allows them<br />

to create additional added value to their customers,<br />

who are also becoming more environmentally<br />

conscious.<br />

The use of annually renewable resources as a<br />

feed-stock is the main driving force behind sustainable<br />

plastics in the 21st century. Biodegradability<br />

of PLA packaging materials is an advantage<br />

in those countries that have an industrial composting<br />

infrastructure in place. However, no material<br />

can find a sustainable position in the market without<br />

the right functional attributes. For many applications<br />

the biodegradability has no added value,<br />

and PLA is perfectly stable under normal use conditions.<br />

Added value<br />

The added value of PLA polymers comes in the<br />

first place from its unique combination of properties,<br />

such as very high optical clarity, good mechanical<br />

properties, gas and water barrier properties,<br />

etc.. These properties can be influenced<br />

and further improved or modified by value added<br />

polymer technologies, such as compounding, copolymerization,<br />

combining materials or films with<br />

different properties or applying nano-technologies.<br />

Properties that will need improvement to make the<br />

polymer applicable to high-end applications are<br />

its heat deformation temperature and its impact<br />

strength. For bottle applications for example the<br />

gas barrier properties needs improvement.<br />

PLA Value proposition<br />

Due to its strong technology position in lactic<br />

acid, moving one step further in the value-chain is<br />

a logical step for PURAC. This enables polymerand<br />

plastics producers to make the step into PLA<br />

bioplastics. PURAC itself has in-depth experience<br />

with PLA in the relatively small, but high value<br />

added market of medical-grade lactide monomers<br />

and polymers.<br />

The scale to economically produce lactide is<br />

much bigger than the scale to economically produce<br />

PLA. In PURAC’s concept, polymer producers<br />

will not need to invest in complex lactide technology,<br />

but can focus instead on their core expertise:<br />

adding value through the production of specialized<br />

PLA (co-)polymers. By allowing PLA producers to<br />

bioplastics MAGAZINE [07/04] Vol. 2 23


Materials<br />

invest in smaller scale plants, the efficiency of PLA<br />

production can be enhanced by focusing on dedicated<br />

grades for certain application areas. Further<br />

value can be added to these (co-) polymers by compounding<br />

them into plastics and using nano- and<br />

other technologies to improve the properties.<br />

PURAC allows polymer producers to add value<br />

in a revolutionary new way by offering two types<br />

of lactide (L-lactide and D-lactide). By combining<br />

these lactides in new and unconventional ways, the<br />

improvement of the PLA heat-stability – one of its<br />

key issues – can become a reality.<br />

PURAC will deploy a business model, where lactide<br />

is manufactured at an advantageous scale and<br />

offered as a premium quality, competitively positioned<br />

product to PLA producers. Based on this<br />

lactide monomer customers will be able produce<br />

superior quality polymer. This business concept allows<br />

medium size and starting PLA companies to<br />

be competitive in the PLA market.<br />

The production of lactide is integrated into the<br />

manufacturing of lactic acid and as such different<br />

grades will be either processed or marketed<br />

through PURAC’s global sales network. PURAC<br />

partners do not have to concern themselves with<br />

the production of lactic acid or lactide and hence<br />

will see a reduced risk profile for the investment,<br />

product management, logistics and warehousing<br />

and operation of facilities.<br />

Outlook<br />

The flexible production unit in PURAC production<br />

site in Spain will be used for lactide production<br />

for selected partners early 2008. This unit will<br />

be extended with the required steps to make high<br />

quality lactide shippable to selected customers all<br />

over the world. The investment path leads to the<br />

industrial scale availability of a lactide production<br />

unit in Thailand.<br />

Since the availability of D(-) lactid acid is essential<br />

for the highest PLA grades, PURAC’s lactic acid<br />

production unit in Spain is being revamped into a<br />

high quality D(-) production plant. The product will<br />

also become available as D-lactide for PDLA production.<br />

PURAC has commenced a focused application<br />

development effort to support customers in<br />

their use of lactide and D(-) products.<br />

www.purac.com<br />

24 bioplastics MAGAZINE [07/04] Vol. 2


Practically everybody uses them to protect sensitive<br />

goods – high-quality stretched plastics are<br />

undoubtedly the number one within the world of<br />

packaging material. More and more they are replacing<br />

paper, cardboard, tin foil and other materials. Upon applying<br />

a particular process, mono- or biaxial orientation, the<br />

films obtain a wealth of advantageous properties, due to a<br />

change in the morphology of the film’s molecular structure:<br />

• excellent mechanical properties, e.g. stiffness, tear,<br />

shock or puncture resistance<br />

• impermeability to moisture and water vapour<br />

• high resistance to oils, fats and solvents, as well as to<br />

heat and cold<br />

• dimensional stability and scratch resistance<br />

• attractive glossy appearance, thanks to brilliant surface<br />

quality and high transparency<br />

• excellent convertibility, printability and sealability.<br />

Packaging has become a key marketing tool at the point<br />

of sales. As a result, customers in supermarkets and<br />

stores are placing greater emphasis on attractive packaging.<br />

This leads to a greater demand for a variety of speciality<br />

films:<br />

• co-extruded multi-layer structures, up to 7 layers for<br />

ultra-high barrier<br />

• shrink film and sleeves for trendy, full body sleeves<br />

• ultra-high barrier film for lamination<br />

• bio-degradable films for environmental protection and<br />

sustainability<br />

• BOPA (bi-axially oriented Polyamide) film highly suitable<br />

for freezable and cookable (microwavable) packaging<br />

• mono-axial shrink films for bundles and labels<br />

Orientation methods<br />

The orientation methods applied to manufacture such<br />

films are the film blowing process and the tenter frame<br />

process. Blown film extrusion process is based on the<br />

principle of extruding a tube having a thickness that is 40<br />

– 50 times thicker than that of the film to be produced.<br />

As part of the tenter frame process, the cast film derived<br />

from plastic granulate by means of extrusion is stretched<br />

in longitudinal and transverse direction to attain the required<br />

film dimensions. This film is then processed either<br />

sequentially or simultaneously in order to obtain a very<br />

thin, high-rigid end film. Sequential lines first stretch the<br />

cast film in machine direction through a system of rollers.<br />

This stretching is achieved by different speeds between<br />

groups of rolls. Then the film enters the tenter, an ovenlike<br />

device, which uses two endless chains to grip and<br />

stretch the web in transverse direction on diverting rails.<br />

Simultaneous systems stretch the film in both directions<br />

at the same time. The limited yield and inflexibility<br />

of mechanical solutions led to the development of LISIM ®<br />

Oriented<br />

films continue<br />

their<br />

Processing<br />

successful<br />

run – even<br />

with PLA<br />

Article contributed by Christian Aigner,<br />

Marketing Manager, Brückner Maschinenbau<br />

GmbH & Co. KG, Siegsdorf, Germany<br />

Photo: Treofan<br />

bioplastics MAGAZINE [07/04] Vol. 2 25


Processing<br />

°C<br />

1 : 2.0 - 3.5<br />

1 : 3.0 - 5.0<br />

Sequential BO stretching line - TDO inlet<br />

Typical temperatures during BOPLA process<br />

technology, which uses linear motors driving clips without<br />

chain connections. This drive principle, also used on the<br />

“Transrapid” (Germany’s high-speed monorail train using<br />

magnetic levitation), allows a new level of freedom to be<br />

obtained when manufacturing high quality film in fast and<br />

extremely flexible production.<br />

Biodegradable oriented film is gaining great<br />

interest<br />

Excellent properties in stiffness, transparency, gloss,<br />

and dead-fold retention, combined with the environmental<br />

benefits clearly emphasize the breadth of its appeal for<br />

use in consumer packaging applications.<br />

• As an alternative to cellophane in: confectionery twist<br />

wrap, premium wrapping for flowers, toiletries and<br />

prestige gifts<br />

• Bags for compost and garden refuse, as well as agricultural<br />

mulch films to replace paper (when wet strength<br />

is required)<br />

• Multi-layer films for packaging uses, especially food<br />

• Lamination films where cellulose acetate can be replaced<br />

• Co-extruded structures with low temperature heat seal<br />

layers and/or flavor and aroma barriers where properties<br />

allow layer simplification or replacement of nylons<br />

• Shrink sleeve films and high modulus label films<br />

• Non-fogging films for fresh produce packaging<br />

Key performance indicators of Brückner’s stretching<br />

lines for biodegradable film<br />

Due to the fact that PLA resin is sensitive to humidity,<br />

special raw material handling and extrusion technology<br />

is needed. Particularly in the storage system, Brückner’s<br />

line layouts include silos with humidity protection. Resin<br />

dryers guarantee the resin’s low moisture content prior<br />

to extrusion.<br />

For the extrusion, Brückner utilizes their over ten year’s<br />

worth of experience in twin screw technology. Benefit: no<br />

additional material drying is needed. The special screw<br />

design creates uniform melt properties. Stainless steel<br />

melt pipes, polymer filters with short dwell times, static<br />

mixers and a three-layer adapter block designed for PLA<br />

are essential to the entire process.<br />

The pinning and stretching properties of PLA are very<br />

similar to the behavior of PET. Therefore, an electrostatic<br />

pinning device is needed to fix the extruded sheet to the<br />

chill roll. A shockless speed variation is realized with a<br />

drive motor concept, which assures a constant take off<br />

speed. A special roll design guarantees a temperature accuracy<br />

of ± 1 K (Kelvin) across the roll surface.<br />

The MDO (machine direction orienter) is equipped with<br />

the same drive technology.<br />

Special drive functions called MSD (MD soft drive system)<br />

assure a “scratch-free” surface of the MD stretched<br />

film. The elongation ratios in machine direction (MD) are<br />

in a range of 2 - 3.5.<br />

The stretching ratios within the transversal direction<br />

(TD) are around 3 to 5. The TDO (transversal direction orienter)<br />

is characterized by accurate and adjustable air distribution<br />

and a reliable chain track system.<br />

Stretching profile<br />

1.767 mm Die<br />

Neck-in<br />

80 mm<br />

Neck-in<br />

120 mm<br />

Clip Range<br />

30 mm<br />

7. 435 mm<br />

1.687 mm Castfilm<br />

1.567 mm MD Film<br />

6.600 mm<br />

Edge trim 150 mm<br />

26 bioplastics MAGAZINE [07/04] Vol. 2


CF-PLA<br />

BOPLA (2,2 x 6,0)<br />

s-BOPLA (4,5 x 5,2)<br />

220<br />

180<br />

3510<br />

4110<br />

5155<br />

4616<br />

Processing<br />

180<br />

180<br />

120<br />

3000<br />

3050<br />

90<br />

100<br />

70<br />

53<br />

52<br />

17<br />

6<br />

MD<br />

TD<br />

MD<br />

TD<br />

MD<br />

TD<br />

Tensile Strength<br />

[N/mm²]<br />

Elongation at Break<br />

[%]<br />

E-Modulus<br />

[N/mm²]<br />

Mechanical<br />

Properties<br />

Improvement of mechanical properties by biaxial stretching<br />

Sequential BO streching line - Winder<br />

The stretched film needs to be surface treated and the<br />

thickness gauge must be measured. Brückner’s stateof-the-art<br />

treatment systems and scanning devices combined<br />

with a ultra-fast die-bolt system guarantee highest<br />

surface properties and a constant gauge throughout the<br />

complete production.<br />

The winder winds up the final treated film on steel<br />

reels.<br />

Criteria like winding tension, roll profile, roll density and<br />

perfect roll build-up are essential for the further process<br />

steps. Technologies like LIWIND ® (winding technology with<br />

linear motors), tension control systems and winder oscillation<br />

systems are essential for perfect further processing.<br />

The output of such a state-of-the-art stretching line is<br />

1,300 kg/h, with the end film having a thickness range between<br />

15 and 50 µm.<br />

Unique technology center<br />

Brückner‘s experience in processing PLA using an orientation<br />

process is based on their worldwide unique technology<br />

center.<br />

The variety of stretching methods, ranging from monoaxial<br />

to sequential and simultaneous stretching, gave the<br />

possibility to run PLA in each production mode.<br />

Produced PLA film:<br />

• MOPLA (mono-axially oriented PLA) shrink film for<br />

sleeves applications<br />

• BOPLA (bi-axially oriented PLA) thin film<br />

• BOPLA thick film for thermoformapplications<br />

(190 – 350 µm)<br />

All produced film types displayed improved film properties<br />

after the stretching process.<br />

Considering that cast – PLA is brittle and inflexible the<br />

stretching process made the final film flexible, while at the<br />

same time improving its tensile strength and E-modulus.<br />

The final film exhibited excellent dead fold and twist<br />

wrap properties.<br />

The simultaneous stretching mode also presented<br />

amazing results.<br />

Sequentially, PLA can be processed with a MD ration of<br />

2.2 and a TD ration of 6.0. The main challenge in this line<br />

configuration is the maximum pinning speed.<br />

The use of simultaneous technology is completely<br />

changing the situation. Stretching ratios of 4.5 times 5.2<br />

are no longer a problem. Therefore, line output can be dramatically<br />

increased. In addition, film properties were better<br />

when compared to the sequential stretching process.<br />

• Mechanical properties<br />

• Sealing properties (by using a low sealing skin layer)<br />

• Adjustable shrink properties due to the special process<br />

• Better optical quality (no scratches, higher gloss)<br />

Overall, the PLA tests at Brückner’s technology center<br />

were surprisingly successful and they gained a lot of new<br />

experience and insight from these trials. The successful<br />

thermoform application tests for the thick film were carried<br />

out at Brückner’s new Group Company Kiefel GmbH<br />

in Freilassing, Germany.<br />

More PLA technology from Brückner Group<br />

Brückner Formtec, supplier of cast film and sheet extrusion<br />

lines, developed a process to produce PLA film<br />

and sheet for rigid packaging in a very cost effective way<br />

by increasing productivity through high outputs and high<br />

speeds. Highlights of the line concepts are: Twin screw<br />

extrusion for highest efficiency, outputs of up to 2,000 kg/<br />

h, speeds of up to 75 m/min, thickness range from 250 µm<br />

up to 1,200 µm, proven pinning technology, especially suitable<br />

for inline processed high volume applications.<br />

www.brueckner.com<br />

bioplastics MAGAZINE [07/04] Vol. 2 27


From Science & Research<br />

Reactor contents transfer<br />

From Waste 2 Gold: Making<br />

bioplastic products from<br />

biomass waste streams<br />

Article contributed by Dr Alan Fernyhough,<br />

Unit Manager of the Bioplastics Engineering<br />

Group, Scion, Rotorua, New Zealand<br />

New Zealand is widely regarded as pristine and<br />

uncluttered. But the country has waste management<br />

challenges just like everywhere else. A large<br />

volume of these wastes arise from its prolific agricultural,<br />

forestry and horticultural sectors. Innovative research<br />

programmes aimed at turning these organic wastes into<br />

high-value bioplastic products are being run by Scion, a<br />

Crown Research Institute based in Rotorua, at the heart<br />

of New Zealand’s green hinterland. At Scion, teams working<br />

on wastewater and environmental (bio)technologies<br />

have come together with those working on biopolymers,<br />

and materials formulation and processing technologies to<br />

create a suite of technology options for converting wastes<br />

into bioplastic related products. The programmes include<br />

turning wastes into bioplastics, or into functional additives<br />

for use in bioplastics, or directly into processed bioplastics<br />

products.<br />

Dr Trevor Stuthridge is the leader of the ‘Waste 2 Gold‘<br />

programme, an overarching framework developed by Scion<br />

for turning wastes into valuable products. He explains<br />

why this research is of vital interest to a nation focused on<br />

minimising waste:<br />

“New Zealanders landfill the equivalent of 872 kg of solid<br />

waste per year per person – one of the highest per capita<br />

rates in the OECD (Organisation for Economic Co-operation<br />

and Development). Our primary industries contribute<br />

55% of this total; a major proportion is organic material<br />

28 bioplastics MAGAZINE [07/04] Vol. 2


From Science & Research<br />

which can generate methane, a potent greenhouse gas<br />

(GHG), and harmful leachates.”<br />

In a bid to help minimise GHG emissions, New Zealand<br />

has implemented a Waste Management Strategy that aims<br />

to see 95% of these industrial organic wastes re-directed<br />

from landfills by 2010. Dr Stuthridge believes that New<br />

Zealand’s primary sectors can best meet this challenge<br />

by actively exploiting the intrinsic worth of their organic<br />

wastes.<br />

“The only effective way to provide incentives for minimising<br />

liquid and solid wastes and redirecting organic<br />

material from landfills is to ensure that the resource has<br />

an economic value. The ‘Waste 2 Gold‘ initiative is proactively<br />

generating sustainable solutions, which will simultaneously<br />

help to increase revenues, reduce costs and add<br />

value to businesses,” he says.<br />

Carbon-rich industrial wastes, such as those from the<br />

pulp and paper, food processing, and biorefinery sectors<br />

are low cost, high volume feedstocks that are ideal<br />

for sustainable production of biopolymers, fine chemicals<br />

and biofuels. Microbial biotechnologies and chemical<br />

functionalisation technologies are under development by<br />

Scion scientists who are exploring ways of utilising these<br />

feedstocks.<br />

One project involves the use of mixed and/or pure cultures<br />

of bacteria that directly fix nitrogen from the atmosphere,<br />

allowing them to remediate carbon-rich wastes<br />

from these sources, without the need for additional costly<br />

chemicals, and convert the carbon into useful products.<br />

Dr Stuthridge explains that a novel function of these nitrogen-fixing<br />

bacteria is their ability to store excess carbon<br />

in the form of polyhydroxyalkanoates (PHAs, >50% of<br />

dry cell mass).<br />

“We are exploiting this characteristic to produce biopolymers<br />

and biopolymer composites from industrial waste<br />

streams. Given that feedstock costs can comprise over<br />

60% of manufacturing costs, this type of process is expected<br />

to offer substantial economic advantages.”<br />

Nitrogen fixation processes produce very low ecological<br />

footprints since no supplemental nitrogen needs to<br />

be added to achieve microbial growth. This approach can<br />

give a 35% saving in operational costs over conventional<br />

bioconversion methods. In addition, very low nutrient final<br />

wastewater discharges are achieved, amounting to over<br />

90% reductions in nitrogen and phosphorus over conventional<br />

methods. Finally, these aerobic nitrogen fixation<br />

processes have a lower oxygen demand than normal systems,<br />

offering a 25% saving in aeration energy costs.<br />

“Of course, in the case of solid wastes, there is a requirement<br />

to make them more easily accessible for microbial<br />

bioconversion”, explains Dr Stuthridge. “Here, we<br />

are integrating proprietary green chemistry-based technologies<br />

that break down the solid organic material, such<br />

Bacteria with PHA<br />

Biodegradable pots<br />

bioplastics MAGAZINE [07/04] Vol. 2 29


From Science & Research<br />

as proteins, lipids and polymeric carbohydrates, into<br />

readily degradable feedstocks for the bacteria.”<br />

The ‘Waste 2 Gold‘ framework demands a multi-disciplinary<br />

approach, encompassing microbiology, bioprocess<br />

engineering, biomaterials chemistry, polymer<br />

engineering, and ecotoxicology. Advanced biomaterial<br />

engineering concepts also enhance these opportunities<br />

by taking the bioplastics from bacteria and integrating<br />

functional attributes, such as programmed degradation<br />

and biofunctional additives.<br />

The author of this article is leader of the Biomaterials<br />

Engineering Group and leads many of the bioplastic<br />

pro-duct developments at Scion. They are functionalising<br />

selected wastes, and mixing benign solid wastes<br />

from other sources (such as the horticultural, food<br />

processing and agricultural sectors), with renewableresourced-based<br />

plastics, and selected additives, to<br />

create a range of novel biopolymer products. These<br />

products include controlled-release fertilisers, biodegradable<br />

plant pots, panels, packaging materials, and<br />

other moulded plastic products.<br />

As future disposal options become more limited, these<br />

technologies will provide a viable alternative for not only<br />

reducing waste, but for utilising it as a valuable resource.<br />

Though the initial interest has been from commodity<br />

based product developments, we increasingly see greater<br />

interest in accessing functional attributes of particular<br />

pro-cessed or functionalised wastes in bioplastic products.<br />

This is leading to a range of advanced performance<br />

bioplastic product developments.<br />

Scion has taken this concept outside the lab to some<br />

leading New Zealand plastics processors and has also<br />

worked to directly involve those who generate much of<br />

New Zealand’s organic wastes. Scientists have conducted<br />

surveys to assess primary industry processing activities<br />

within New Zealand and to identify current waste production<br />

and disposal patterns. The surveys highlighted the<br />

availability of high-volume, good quality waste streams,<br />

with producers indicating a clear desire for better options<br />

to use this waste.<br />

This need led to the formation of a partnership between<br />

Scion and a number of major pulp and paper and horticultural<br />

producers and processors to explore opportunities<br />

for developing new products from these waste streams.<br />

This partnership exploits a ‘Waste 2 Gold‘ ‘hotspot’ based<br />

in the Bay of Plenty region, where significant volumes of<br />

the ideal raw materials are available to this programme.<br />

The fledgling regional initiative may be a model for extension<br />

into other sectors in New Zealand as scientists<br />

develop ways of making bio-derived plastics and biobased<br />

composites out of a range of organic wastes from<br />

kiwifruit to cow dung.<br />

“From a purely economic perspective, industrial<br />

wastes can no longer be considered ‘wastes’ but rather<br />

‘untapped resources’. While reducing the amount of<br />

waste generated is the first priority, even the most efficient<br />

manufacturing processes create surplus materials.<br />

The future sustainability of industrial production depends<br />

on the smart utilisation of these residues,” Dr Stuthridge<br />

concludes.<br />

30 bioplastics MAGAZINE [07/04] Vol. 2


Our Covergirl Maria says:“ I‘ve known<br />

about these biodegradable bags made<br />

from starch. But I like the idea that<br />

scientist try to make bioplastics even<br />

from waste.“<br />

Week 1<br />

Week 2<br />

Week 3<br />

Week 4<br />

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Up to 70% Bio-based With<br />

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and polyethylene films. This patent pending breakthrough<br />

meets ASTM D6400 and DIN V 54 900. EcoWorks ® 70<br />

does not contain polyethylene or starch but relies heavily<br />

on renewable, bio-based polyester from corn. 100%<br />

biodegradable, it turns into water and carbon dioxide in<br />

commercial composting.


Opinion<br />

Article contributed by<br />

Miriam Wehrli, Project Manager and<br />

Dr. Markus A. Meier, Head Market Platform Packaging<br />

Market Platform Packaging, Ciba Inc., Basel, Switzerland<br />

Biopolymers as an<br />

option for sustainability<br />

– Quo vadis?<br />

Sustainability has become the new buzzword<br />

in our modern and environmentally aware<br />

society. Government authorities, organizations<br />

and companies all over the world are increasingly<br />

coming up with initiatives to improve<br />

sustainable development while striking the right<br />

balance between environmental, social and economic<br />

concerns.<br />

Specifically relating to the packaging market, the<br />

focus is on reducing carbon footprint and in this<br />

regard, biopolymers are consistently in the spotlight.<br />

When compared to traditional plastics, these<br />

new types of emerging polymers bring numerous<br />

modified properties such as a higher water-vapor<br />

transmission rate (WVTR) and biodegradability.<br />

The latter, however, often leads to confusion and<br />

consumers too often do not know how to deal with<br />

this new feature, what makes them unsure of the<br />

real benefits of biopolymers.<br />

Do we need biodegradable polymers?<br />

Biodegradability is an attribute which is often<br />

associated on the one hand with environmental<br />

friendliness but on the other hand, also with<br />

instability of the polymer and low performance.<br />

Currently biodegradability is frequently used as a<br />

marketing tool, although not all aspects of biodegradability<br />

are known and therefore hardly foreseeable.<br />

32 bioplastics MAGAZINE [07/04] Vol. 2


Opinion<br />

Life-cycle: Oil-based polymers<br />

Net CO 2<br />

Exploration Refinery Use Collection<br />

Incineration<br />

with energy recovery<br />

0<br />

Recycling<br />

+<br />

+<br />

Life-cycle: Biopolymers<br />

Growth Processing Use Collection<br />

Incineration<br />

with energy recovery<br />

-<br />

Recycling<br />

+<br />

0<br />

No significant difference between polymers<br />

Net CO 2 production (+)<br />

Overall target: CO 2<br />

reduction by process optimization<br />

Figure 1: CO 2 balance<br />

comparison of oil-based<br />

polymers and biopolymers.<br />

Legend:<br />

+ : CO 2<br />

production and release to the atmosphere (emission),<br />

- : CO 2<br />

elimination of plants during growth (photosynthesis),<br />

0 : CO 2<br />

neutral (overall no emission nor elimination)<br />

Already today we are confronted with headlines pointing<br />

at the rising prices for corn tortillas in Mexico due to<br />

increasing demand of bio-resources causing corn shortages.<br />

Feedstock and farmland for biopolymers are in<br />

competition with biofuels as well as land capacity which<br />

could be used to feed people. The benefits of biopolymers<br />

capable of being chemically recycled rather than composted<br />

are therefore obvious. Collecting industrial and<br />

post consumer waste of polylactic acid (PLA), for instance,<br />

and converting it back to lactic acid by depolymerization<br />

results again in a purified base material for the polylactic<br />

acid production. In doing so, corn production, corn wet<br />

milling and fermentation could be avoided and leading to<br />

an overall reduction of costs and energy consumption.<br />

Furthermore, when considering the high efforts presently<br />

made to improve the mechanical and technical properties<br />

of biopolymers, future biopolymer solutions will<br />

most probably end up losing the biodegradability at the<br />

expense of strength. In essence, the development of biobased<br />

polymers should target a polymer which is recyclable<br />

rather than biodegradable.<br />

Carbon footprint<br />

In this context, the main driver for biopolymers on the<br />

market turns out to be the fact that they are based on<br />

renewable raw materials. This is presumably linked with<br />

the increasing pressure to reduce the environmental impact<br />

of products and furthermore to comply with internal<br />

sustainability commitments. Biopolymer resin producers<br />

especially enhance their life cycle studies by purchasing<br />

renewable energy credits, but this option is certainly independent<br />

of the polymer produced.<br />

For the time being, Ciba’s market analysis in collaboration<br />

with Pira International and life cycle assessment<br />

(LCA) studies of biopolymers in cooperation with the Swiss<br />

Federal Institute of Technology (ETH Zurich) show neither<br />

clear advantages nor disadvantages of biopolymers compared<br />

with traditional mineral oil based polymers.<br />

As processing, use, collection and even waste management<br />

(except composting) do so far not show significant<br />

difference and are comparable for all kind of polymers in<br />

terms of energy demand and greenhouse gas emissions,<br />

a fully greenhouse gas neutral option (from cradle-tograve)<br />

can only be achieved by using renewable resources.<br />

Even if 100% recycling could be feasible, traditional plastics<br />

would still need crude oil as a feedstock and therefore<br />

release net CO 2 to the atmosphere.<br />

So, the long-term vision for a sustainable solution<br />

points to biopolymers which are 100% recyclable. If this<br />

is considered not feasible, then at least incineration with<br />

heat recovery should be the option and not composting, in<br />

which, neither energy nor base material can be recovered<br />

(destroying value).<br />

Alternatives – biobased polyethylene (PE)<br />

Biopolymers like PLA and starch-based solutions still<br />

show performance drawbacks in end-use packaging applications<br />

compared with traditional polymers. While the<br />

higher WVTR of biopolymers could be a benefit for several<br />

fresh produce packaging applications, they then shortly<br />

bioplastics MAGAZINE [07/04] Vol. 2 33


Opinion<br />

reach their limits due to e.g. insufficient heat stability,<br />

brittleness and relatively low gas barriers for other<br />

applications.<br />

Alternatively, there are companies like Dow and<br />

Braskem planning to make polyethylene from sugar<br />

cane. The advantages of this approach are that PE is<br />

already fully established in the market and the properties<br />

for processing and applications are well known.<br />

Even the waste streams do already exist and there<br />

will be no issue of contamination, since the bio-based<br />

polymer is chemically identical with its oil-based analog.<br />

At least short- to mid-term, the bio-based PE could<br />

be a viable alternative to PLA and starch-based biopolymers<br />

and it remains to be seen which solution<br />

will win recognition long-term.<br />

Role of raw material suppliers<br />

Ciba continuously strives for superior performance<br />

and is committed to contribute to long-term sustainable<br />

development. Regarding biopolymers simply as<br />

a new type of polymer on the market, Ciba is committed<br />

to learn more about these new materials. The<br />

company is capitalizing on its expertise in polymers,<br />

colorants and additives to support the development<br />

of biopolymers by improving their technical performance<br />

through additives, focusing on testing compatibility<br />

with polymers and recycling rather than biodegradability.<br />

Beyond the interests in the embryonic biopolymer<br />

market, Ciba offers a wide range of sustainable solutions<br />

for plastics and paper/paperboard packaging.<br />

Consequently Ciba‘s contribution to sustainable<br />

packaging will not only concentrate on additives and<br />

colorants for biopolymers, but also include strength<br />

solutions which allow significant light-weighing of<br />

packaging as well as improvement of recycled resin<br />

performance.<br />

There will be no standard solution eliminating all<br />

present and future concerns. Rather, the point is to<br />

find individual ways to change general attitudes and<br />

develop technologies to balance environmental, economic<br />

and social aspects of sustainability in order to<br />

ensure the same quality of life also for future generations.<br />

www.ciba.com<br />

34 bioplastics MAGAZINE [07/04] Vol. 2


Mailbox<br />

!<br />

!<br />

Dear Editor,<br />

It is always with great interest that we read bioplastics MAGAZINE as<br />

it brings together a vital collection of news and views in bioplastics, an<br />

industry that we at NatureWorks LLC are deeply committed to. In a recent<br />

editorial in the 03/2007 issue it was suggested that availability in general<br />

of NatureWorks ® biopolymer is causing signs of hesitation in the market.<br />

This is an inaccurate statement and we feel this is an appropriate the time<br />

to bring greater clarity on our current manufacturing position.<br />

Due to the strong and unexpected market growth throughout 2006,<br />

NatureWorks channeled available biopolymer in a secure and strategic<br />

way to our existing partners by carefully mapping supply chains and material<br />

flows. At the same time we reported that NatureWorks LLC continued<br />

to increase production volume by de-bottlenecking production in our<br />

Blair, NE, facility and as a result we are able to secure all existing end<br />

user demands. Today we are also in a position to support and develop<br />

new opportunities, confirming the continued and robust market growth<br />

for NatureWorks biopolymer applications.<br />

In all of what we do, NatureWorks seeks to include our core values<br />

around sustainability and responsibility meaning that we are actively<br />

seeking and having dialogue with key stakeholders to make sure everyone’s<br />

effort follows the same approach.<br />

I think most people close to this industry are aware of our peer reviewed<br />

eco-profiles that have been updated and published recently to reflect key<br />

progress made in this field, as well as position papers laying out our response<br />

to issues such as feedstock sourcing, waste management and our<br />

overall environmental footprint. Our colleague, Erwin Vink, will elaborate<br />

on this in a paper that will be included in the next issue.<br />

As people around the globe are working to make us less dependent on<br />

fossil raw materials, the use of bioplastics contributes to this in a meaningful<br />

way and bio-packaging solutions are a valuable way to demonstrate<br />

this important evolution.<br />

We are more than happy to provide more details around any of these<br />

topics and we welcome innovative companies to bring their own responsible<br />

products to market and join the growing assortment of applications<br />

based on NatureWorks biopolymer and marketed as Ingeo innovations.<br />

These include not only a complete range of biopackaging solutions but<br />

also high value durable goods such as cosmetics and electronics, as well<br />

as a full range of Ingeo fiber applications.<br />

Please do not hesitate to contact us should you require further details.<br />

Regards,<br />

Mark Vergauwen – Commercial Director Europe, NatureWorks LLC<br />

bioplastics MAGAZINE [07/04] Vol. 2 35


Basics<br />

Logos Part 6:<br />

A number of products made from bioplastics are already on<br />

the market. Almost all of them are labelled with some kind of<br />

a logo that tells the consumer about the special character of<br />

the plastic material used. In this series of articles the logos<br />

and their background are introduced by bioplastics MAGAZINE.<br />

Here we address such questions as: What is the origin and<br />

history of a logo? What does it mean? Which type of legislation<br />

or regulation is it concerned with?<br />

In previous issues bioplastics MAGAZINE introduced six<br />

different logos that inform consumers about the biodagradability<br />

or compostability of packaging and other products<br />

made of bioplastics.<br />

Before we start a new series in 2008, where we introduce<br />

logos informing about the biobased origin of bioplastics products,<br />

we‘d like to summarize the compostable/biodegradable<br />

logos in the following table.<br />

But also in future issues, we will inform our readers about<br />

all modifications, consolidations or cooperations which might<br />

arise about the existing logos.<br />

Logo Name Association Meaning Certifying institute(s) Countries<br />

Compostability<br />

Mark, called<br />

„the Seedling“<br />

(bM 01/2006)<br />

The “Compostable”<br />

logo of BPI<br />

(bM 02/2006)<br />

The “OK Compost”<br />

logo<br />

(bM 01/2007)<br />

European<br />

Bioplastics<br />

www.europeanbioplastics.org<br />

Biodegradable<br />

Products Institute,<br />

USA<br />

www.bpiworld.org<br />

Vinçotte, Belgium<br />

www.vincotte.com<br />

compostable bioplastic<br />

products according to<br />

EN 13432, ASTM<br />

D 6400, ISO 17088<br />

compostable products<br />

according to ASTM D<br />

6400 (Compostable<br />

Plastics) or ASTM<br />

D6868 (Compostable<br />

Packaging)<br />

compostable bioplastic<br />

packaging according to<br />

EN 13432<br />

DIN-Certco (D),<br />

The Composting<br />

Association (UK),<br />

Keurmerk Instituut (NL),<br />

Cobro (PL).<br />

(others to follow)<br />

BPI<br />

Vinçotte, Belgium<br />

Germany, Switzerland, the<br />

Netherlands, Poland and the<br />

United Kongdom.<br />

In Austria the label is used in<br />

model projects in Linz and St.<br />

Pölten. European Bioplastics<br />

promotes the use of product<br />

certification and the use of a<br />

unified label in Europe<br />

USA, Canada<br />

Belgium, France<br />

The Finnish Apple<br />

(bM 02/2007)<br />

Finnish Solid Waste<br />

Association, FSWA<br />

www.jly.fi<br />

mainly for compostable<br />

biowaste bags,<br />

certified in line with EN<br />

13432<br />

Finnish Solid Waste<br />

Association, FSWA<br />

Finnland<br />

The Norwegian<br />

Apple<br />

(bM 02/2007)<br />

Avfall Norge (Waste<br />

Management Norway,<br />

formerly NRF)<br />

www.avfallnorge.no<br />

mainly for compostable<br />

biowaste bags,<br />

certified in line with EN<br />

13432<br />

Avfall Norge<br />

(Waste Management<br />

Norway, formerly NRF)<br />

Norway<br />

“GreenPla”<br />

logo Japan<br />

(bM 03/2007)<br />

Japan BioPlastics<br />

Association(JBPA)<br />

www.jbpaweb.net<br />

Biodegradability according<br />

to Japanese<br />

and international<br />

standards such as ISO<br />

14851, 14852, 14855<br />

Japan BioPlastics<br />

Association (JBPA)<br />

Japan<br />

36 bioplastics MAGAZINE [07/04] Vol. 2


Basics Glossary<br />

Glossary<br />

Readers who know better explanations<br />

or who would like to suggest<br />

other explanations to be added<br />

to the list, please contact the editor.<br />

[*: bM ... refers to more comprehensive<br />

article previously published in<br />

bioplastics MAGAZINE)<br />

In bioplastics MAGAZINE again<br />

and again the same expressions<br />

appear that some of our readers<br />

might (not yet) be familiar with.<br />

This glossary shall help with<br />

these terms and shall help avoid<br />

repeated explanations such as<br />

„PLA (Polylactide)“ in various<br />

articles.<br />

Amylopectin<br />

Polymeric branched starch molecule with very high molecular<br />

weight (biopolymer, monomer is à Glucose).<br />

Amyloseacetat<br />

Linear polymeric glucose-chains are called à amylose.<br />

If this compound is treated with ethan acid one product is<br />

amylacetat. The hydroxyl group is connected with the organic<br />

acid fragment.<br />

Amylose<br />

Polymeric non-branched starch molecule with high molecular<br />

weight (biopolymer, monomer is à Glucose).<br />

Biodegradable Plastics<br />

Biodegradable Plastics are plastics that are completely<br />

assimilated by the à microorganisms present a defined environment<br />

as food for their energy. The carbon of the plastic<br />

must completely be converted into CO 2<br />

.during the microbial<br />

process. For an official definition, please refer to the standards<br />

e.g. ISO or in Europe: EN 14995 Plastics- Evaluation<br />

of compostability - Test scheme and specifications. [bM*<br />

02/2006 p. 34f, bM 01/2007 p38].<br />

Blend<br />

Mixture of plastics, polymer alloy of at least two microscopically<br />

dispersed and molecularly distributed base polymers.<br />

Cellophane<br />

Clear film on the basis of à cellulose.<br />

Cellulose<br />

Polymeric molecule with very high molecular weight (biopolymer,<br />

monomer is à Glucose), industrial production<br />

from wood or cotton, to manufacture paper, plastics and<br />

fibres.<br />

Compost<br />

A soil conditioning material of decomposing organic<br />

matter which provides nutrients and enhances soil<br />

structure.<br />

Compostable Plastics<br />

Plastics that are biodegradable under “composting“<br />

conditions: specified humidity, temperature, à microorganisms<br />

and timefame. Several national and international<br />

standards exist for clearer definitions, for example<br />

EN 14995 Plastics - Evaluation of compostability<br />

- Test scheme and specifications [bM 02/2006 p. 34f, bM<br />

01/2007 p38].<br />

Composting<br />

A solid waste management technique that uses natural<br />

process to convert organic materials to CO 2<br />

, water<br />

and humus through the action of à microorganisms.<br />

Copolymer<br />

Plastic composed of different monomers.<br />

Fermentation<br />

Biochemical reactions controlled by à microorganisms<br />

or enyzmes (e.g. the transformation of sugar into<br />

lactic acid).<br />

Gelatine<br />

Translucent brittle solid substance, colorless or<br />

slightly yellow, nearly tasteless and odorless, extracted<br />

from the collagen inside animals‘ connective tissue.<br />

Glucose<br />

Monosaccharide (or simple sugar). G. is the most<br />

important carbohydrate (sugar) in biology. G. is formed<br />

by photosynthesis or hydrolyse of many carbohydrates<br />

e. g. starch.<br />

bioplastics MAGAZINE [07/04] Vol. 2 37


Basics Glossary<br />

Humus<br />

In agriculture, “humus“ is often used simply to mean<br />

mature à compost, or natural compost extracted from<br />

a forest or other spontaneous source for use to amend<br />

soil.<br />

Hydrophilic<br />

Property: “water-friendly“, soluble in water or other<br />

polar solvents (e.g. used in conjunction with a plastic<br />

which is not waterresistant and weatherproof or that<br />

absorbs water such as Polyamide (PA)).<br />

Hydrophobic<br />

Property: “water-resistant“, not soluble in water (e.g.<br />

a plastic which is waterresistant and weatherproof, or<br />

that does not absorb any water such as Polethylene (PE)<br />

or Polypropylene (PP)).<br />

Microorganism<br />

Living organisms of microscopic size, such as bacteria,<br />

funghi or yeast.<br />

PCL<br />

Polycaprolactone, a synthetic (fossil based), biodegradable<br />

bioplastic, e.g. used as a blend component.<br />

PHA<br />

Polyhydroxyalkanoates are linear polyesters produced<br />

in nature by bacterial fermentation of sugar or lipids.<br />

The most common type of PHA is à PHB.<br />

PHB<br />

Polyhydroxyl buteric acid (better poly-3-hydroxybutyrate),<br />

is a polyhydroxyalkanoate (PHA), a polymer belonging<br />

to the polyesters class. PHB is produced by micro-organisms<br />

apparently in response to conditions of<br />

physiological stress. The polymer is primarily a product<br />

of carbon assimilation (from glucose or starch) and is<br />

employed by micro-organisms as a form of energy storage<br />

molecule to be metabolized when other common<br />

energy sources are not available. PHB has properties<br />

similar to those of PP, however it is stiffer and more<br />

brittle.<br />

PLA<br />

Polylactide, a bioplastic made of polymerised lactic<br />

acid.<br />

Saccharins or carbohydrates<br />

Saccharins or carbohydrates are name for the sugar-family.<br />

Saccharins are monomer or polymer sugar<br />

units. For example, there are known mono-, di- and<br />

polysaccharose. à glucose is a monosaccarin. They are<br />

important for the diet and produced biology in plants.<br />

Sorbitol<br />

Sugar alcohol, obtained by reduction of glucose changing<br />

the aldehyde group to an additional hydroxyl group. S. is<br />

used as a plasticiser for bioplastics based on starch .<br />

Starch<br />

Natural polymer (carbohydrate) consisting of à amylose<br />

and à amylopectin, gained from maize, potatoes, wheat,<br />

tapioca etc. When glucose is connected to polymer-chains<br />

in definite way the result (product) is called starch. Each<br />

molecule is based on 300 -12000-glucose units. Depending<br />

on the connection, there are two types à amylose and<br />

à amylopectin known.<br />

Starch (-derivate)<br />

Starch (-derivates) are based on the chemical structure<br />

of à starch. The chemical structure can be changed by<br />

introducing new functional groups without changing the<br />

à starch polymer. The product has different chemical qualities.<br />

Mostly the hydrophilic character is not the same.<br />

Starch-ester<br />

One characteristic of every starch-chain is a free hydroxyl<br />

group. When every hydroxyl group is connect with ethan acid<br />

one product is starch-ester with different chemical properties.<br />

Starch propionate and starch butyrate<br />

Starch propionate and starch butyrate can be synthesis<br />

by treating the à starch with propane or butanic acid. The<br />

product structure is still based on à starch. Every based<br />

à glucose fragment is connected with a propionate or butyrate<br />

ester group. The product is more hydrophobic than<br />

à starch.<br />

Sustainable<br />

An attempt to provide the best outcomes for the human<br />

and natural environments both now and into the indefinite<br />

future. One of the most often cited definitions of sustainability<br />

is the one created by the Brundtland Commission,<br />

led by the former Norwegian Prime Minister Gro Harlem<br />

Brundtland. The Brundtland Commission defined sustainable<br />

development as development that „meets the needs of<br />

the present without compromising the ability of future generations<br />

to meet their own needs.“ Sustainability relates to<br />

the continuity of economic, social, institutional and environmental<br />

aspects of human society, as well as the non-human<br />

environment).<br />

Thermoplastics<br />

Plastics which soften or melt when heated and solidify<br />

when cooled (solid at room temperature).<br />

Yard Waste<br />

Grass clippings, leaves, trimmings, garden residue.<br />

38 bioplastics MAGAZINE [07/04] Vol. 2


Simply contact:<br />

Tel.: +49-2359-2996-0 or suppguide@bioplasticsmagazine.com<br />

Suppliers Guide<br />

Stay permanently listed in the Suppliers Guide with your company logo and contact information.<br />

For only 6,– EUR per mm, per issue you can be present among top suppliers in the field of bioplastics.<br />

1. Raw Materials<br />

1.1 bio based monomers<br />

1.3 PLA<br />

1.4 starch-based bioplastics<br />

2. Additives /<br />

Secondary raw materials<br />

4. Bioplastics products<br />

Du Pont de Nemours International S.A.<br />

2, Chemin du Pavillon, PO Box 50<br />

CH 1218 Le Grand Saconnex,<br />

Geneva, Switzerland<br />

Phone: + 41(0) 22 717 5176<br />

Fax: + 41(0) 22 580 2360<br />

thomas.philipon@che.dupont.com<br />

www.packaging.dupont.com<br />

1.2 compounds<br />

BIOTEC Biologische<br />

Naturverpackungen GmbH & Co. KG<br />

Werner-Heisenberg-Straße 32<br />

46446 Emmerich<br />

Germany<br />

Tel.: +49 2822 92510<br />

Fax: +49 2822 51840<br />

info@biotec.de<br />

www.biotec.de<br />

Du Pont de Nemours International S.A.<br />

2, Chemin du Pavillon, PO Box 50<br />

CH 1218 Le Grand Saconnex,<br />

Geneva, Switzerland<br />

Phone: + 41(0) 22 717 5176<br />

Fax: + 41(0) 22 580 2360<br />

thomas.philipon@che.dupont.com<br />

www.packaging.dupont.com<br />

3. Semi finished products<br />

3.1 films<br />

natura Verpackungs GmbH<br />

Industriestr. 55 - 57<br />

48432 Rheine<br />

Tel.: +49 5975 303-57<br />

Fax: +49 5975 303-42<br />

info@naturapackaging.com<br />

www.naturapackagign.com<br />

Veriplast Holland BV<br />

Stadhoudersmolenweg 70<br />

NL - 7317 AW Apeldoorn<br />

www.veripure.eu<br />

Info@veripure.eu<br />

R.O.J. Jongboom Holding B.V.<br />

Biopearls<br />

Damstraat 28<br />

6671 AE Zetten<br />

The Netherlands<br />

Tel.: +31 488 451318<br />

Mob: +31 646104345<br />

info@biopearls.nl<br />

www.biopearls.nl<br />

BIOTEC Biologische<br />

Naturverpackungen GmbH & Co. KG<br />

Werner-Heisenberg-Straße 32<br />

46446 Emmerich<br />

Germany<br />

Tel.: +49 2822 92510<br />

Fax: +49 2822 51840<br />

info@biotec.de<br />

www.biotec.de<br />

Plantic Technologies GmbH<br />

Heinrich-Busold-Straße 50<br />

D-61169 Friedberg<br />

Germany<br />

Tel: +49 6031 6842 650<br />

Tel: +44 794 096 4681 (UK)<br />

Fax: +49 6031 6842 656<br />

info@plantic.eu<br />

www.plantic.eu<br />

1.5 PHA<br />

1.6 masterbatches<br />

PolyOne<br />

Avenue Melville Wilson, 2<br />

Zoning de la Fagne<br />

5330 Assesse<br />

Belgium<br />

Tel.: + 32 83 660 211<br />

info.color@polyone.com<br />

www.polyone.com<br />

Maag GmbH<br />

Leckingser Straße 12<br />

58640 Iserlohn<br />

Germany<br />

Tel.: + 49 2371 9779-30<br />

Fax: + 49 2371 9779-97<br />

shonke@maag.de<br />

www.maag.de<br />

Treofan Germany GmbH & Co. KG<br />

Am Prime Parc 17<br />

65479 Raunheim<br />

Tel +49 6142 200-0<br />

Fax +49 6142 200-3299<br />

www.biophanfilms.com<br />

www.earthfirstpla.com<br />

www.sidaplax.com<br />

www.plasticsuppliers.com<br />

Sidaplax UK : +44 (1) 604 76 66 99<br />

Sidaplax Belgium: +32 9 210 80 10<br />

Plastic Suppliers: +1 866 378 4178<br />

4.1 trays<br />

5. Traders<br />

5.1 wholesale<br />

6. Machinery & Molds<br />

Molds, Change Parts and Turnkey<br />

Solutions for the PET/Bioplastic<br />

Container Industry<br />

284 Pinebush Road<br />

Cambridge Ontario<br />

Canada N1T 1Z6<br />

Tel.: +1 519 624 9720<br />

Fax: +1 519 624 9721<br />

info@hallink.com<br />

www.hallink.com<br />

SIG Corpoplast GmbH & CO. KG<br />

Meiendorfer Str. 203<br />

22145 Hamburg, Germany<br />

Tel. +49-40-679-070<br />

Fax +49-40-679-07270<br />

sigcorpoplast@sig.biz<br />

www.sigcorpoplast.com<br />

7. Plant engineering<br />

FKuR Kunststoff GmbH<br />

Siemensring 79<br />

D - 47 877 Willich<br />

Tel.: +49 (0) 2154 9251-26<br />

Tel.: +49 (0) 2154 9251-51<br />

patrick.zimmermann@fkur.de<br />

www.fkur.de<br />

Transmare Compounding B.V.<br />

Ringweg 7, 6045 JL<br />

Roermond, The Netherlands<br />

Phone: +31 (0)475 345 900<br />

Fax: +31 (0)475 345 910<br />

info@transmare.nl<br />

www.compounding.nl<br />

Sukano Products Ltd.<br />

Chaltenbodenstrasse 23<br />

CH-8834 Schindellegi<br />

Phone +41 44 787 57 77<br />

Fax +41 44 787 57 78<br />

www.sukano.com<br />

1.7 reinforcing fibres/fillers<br />

made from RRM<br />

3.1.1 cellulose based films<br />

INNOVIA FILMS LTD<br />

Wigton<br />

Cumbria CA7 9BG<br />

England<br />

Contact: Andy Sweetman<br />

Tel.: +44 16973 41549<br />

Fax: +44 16973 41452<br />

andy.sweetman@innoviafilms.com<br />

www.innoviafilms.com<br />

Uhde Inventa-Fischer GmbH<br />

Holzhauser Str. 157 - 159<br />

13509 Berlin<br />

Germany<br />

Tel.: +49 (0)30 43567 5<br />

fax: +49 (0)30 43567 699<br />

sales.de@thyssenkrupp.com<br />

www.uhde-inventa-fischer.com<br />

8. Ancillary equipment<br />

9. Services<br />

10. Research institutes /<br />

Universities<br />

bioplastics MAGAZINE [07/03] Vol. 2 39


Companies in this issue<br />

Company Editorial Advert<br />

Afvall Norge 36<br />

Alcan Packaging 16<br />

Amcor Flexibles 16<br />

Arkema 8,17<br />

BASF 9 2<br />

Bayer Material Science 12<br />

Biobag International 21<br />

Biodegradable Products Institute (BPI) 36<br />

BioLog 11<br />

Bioplastics24 31<br />

Biostarch 18<br />

Biotec 8 39<br />

Braskem 9,16<br />

Brückner 9, 25<br />

Ciba 32<br />

Clubbioplastique 14<br />

Cobro 36<br />

Coopbox Europe 16<br />

Cornell University, Ithaca, New York) 7<br />

Cortec 31<br />

Crystalsev 10<br />

Delhaize 17<br />

DIN Certco 36<br />

D-M-E 13<br />

Dow 10,13, 16<br />

Du Pont de Nemours 5, 12 39<br />

Elastogran 10,17<br />

ETH Zürich 33<br />

European Bioplastics 14<br />

European Plastics News 16<br />

Excellent Packaging & Supply 17<br />

FAS Converting Machinery 21<br />

Finnish Solid Waste Assiciation (FSWA) 36<br />

FkuR 39<br />

Forapack 19<br />

Gehr 10<br />

Greenblue 5<br />

Hallink 39<br />

Huhtamaki 7<br />

Innovia Films 39<br />

Japan BioPlastics Association (JBPA) 36<br />

Jemaco 21<br />

Kareline 11<br />

Keurmerk Instituut 36<br />

Leoplast 16<br />

Maag 39<br />

Meredian 6<br />

Merquinsa Mercados Quimicos 16<br />

Mitsubishi Plastics 8<br />

Company Editorial Advert<br />

Mitsui Chemicals 8<br />

natura 39,43<br />

Natureworks 35<br />

NEC Corporation 17<br />

nova Institut 7<br />

Novamont 6, 17, 20 44<br />

Novomer 6<br />

Pira International 33<br />

Plantic Technologies 39<br />

Plasticker 31<br />

Plasticsuppliers 39<br />

PolyOne 39<br />

Procter & Gamble 6<br />

Purac 22<br />

R.O.J. Jongboom Holding B.V., Biopearls 39<br />

Reifenhäuser 11<br />

Reimelt Henschel MischSysteme 11<br />

Rondol 13<br />

Rural Industries Research and Development 5<br />

Corporation (RIRDC)<br />

Sainsbury’s Supermarkets 17<br />

SAM-A C&I 11<br />

Scion 28<br />

Sidaplax 39<br />

SIG Corpoplast 13 39<br />

SIG Plasmax 13<br />

Sistec 13<br />

Sphere 8<br />

Stanelco 8<br />

Sukano Products 39<br />

Tejin 16<br />

The Composting Association 36<br />

Timberland 13<br />

Toray Industries 9<br />

Transmare Compounding 39<br />

Treofan 16<br />

Treofan Germany 39<br />

Uhde Inventa-Fischer 39<br />

Vanetti Materbatches 13<br />

Veriplast 39<br />

Vinçotte 36<br />

Vitasheet 12<br />

VTT Technical Research Center 10<br />

Wal-Mart 17<br />

Wiedmer 16<br />

WIP 17<br />

Next Issue<br />

For the next issue of bioplastics MAGAZINE<br />

(among others) the following subjects are scheduled:<br />

Topics:<br />

Foamed bioplastics<br />

End of life options<br />

Basics:<br />

Sustainability<br />

Logos (7)<br />

Next issues:<br />

01/08 January 2008<br />

02/08 March 2008<br />

03/08 April 2008<br />

04/08 June 2008<br />

05/08 September 2008<br />

40 bioplastics MAGAZINE [04/07] Vol. 2


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bioplastics MAGAZINE [04/07] Vol. 2 41


Events<br />

Event-Calendar<br />

February, 18-20, 2008<br />

Agricultural Film 2008<br />

Fira Palace Hotel, Barcelona, Spain<br />

www.amiplastics.com<br />

March 3-4, 2008<br />

3rd International Seminar on Biodegradable Polymers<br />

Valencia, Spain<br />

http://www.azom.com/details.asp?newsID=7345<br />

April 1-3, 2008<br />

JEC Composites Paris<br />

including biobasesd polymers and natural fibers<br />

Paris, France<br />

www.jeccomposites.com<br />

April 22-23, 2008<br />

„Connecting comPETence“: PETnology Europe 2008<br />

Düsseldorf/Neuss , Germany, prior to Interpack<br />

http://www.petnology.com<br />

April 24-30, 2008<br />

Interpack - 2008<br />

and here:<br />

Bioplastics in Packaging<br />

The interpack 2008 Group Exhibition<br />

Düsseldorf, Germany<br />

www.european-bioplastics.org<br />

www.interpack.com<br />

meet bioplastics MAGAZINE here<br />

June 18-19, 2008<br />

7th Global WPC and Natural Fibre Composites<br />

Congress and Exhibition<br />

Kongress Palais, Stadthalle, Kassel, Germany<br />

www.wpc-nfk.de<br />

42 bioplastics MAGAZINE [04/07] Vol. 2


natura means<br />

business<br />

natura packaging develops and markets<br />

innovative, 100% biodegradable<br />

packaging solutions. Our Europewide<br />

activities can be divided into three main<br />

categories;<br />

• Fruit and vegetable packaging<br />

• Waste management<br />

(including the MaxAir system)<br />

• Shopping bags (including our<br />

popular ‘happy bag’)<br />

Let natura help you get the most<br />

out of your business.<br />

Call +49 (0)5975 30357<br />

or send an e-mail to<br />

info@naturapackaging.com.<br />

Industriestraße 55 - 57 48432 Rheine Tel. : +49 (0)5975/303-57 Fax. : +49 (0)5975/303-42 Email : info@naturapackaging.com<br />

w w w . n a t u r a p a c k a g i n g . c o m


A real sign<br />

of sustainable<br />

development.<br />

There is such a thing as genuinely sustainable development.<br />

Since 1989, Novamont researchers have been working<br />

on an ambitious project that combines the chemical<br />

industry, agriculture and the environment: “Living<br />

Chemistry for Quality of Life”. Its objective has been to<br />

create products that have a low environmental impact.<br />

The innovative result of Novamont’s research is the new<br />

bioplastic Mater-Bi ® .The Mater-Bi ® polymer comes from maize starch and<br />

other vegetable starches; it is completely biodegradable and compostable.<br />

Mater-Bi ® performs like plastic, but it saves energy, contributes to reducing<br />

the greenhouse effect, and at the end of its life cycle, it closes the loop by<br />

changing into fertile humus. Everyone’s dream has become a reality.<br />

Living Chemistry for Quality of Life.<br />

www.novamont.com<br />

Mater-Bi ® : certified and recommended biodegradability and compostability.

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