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ioplastics magazine Vol. 6 ISSN 1862-5258<br />

Highlights<br />

Films Flexibles Bags | 14<br />

Consumer Electronics | 38<br />

Personality<br />

John Williams | 48<br />

November/December<br />

06 | 2011<br />

... is read in 91 countries


FKuR plastics – made by nature! ®<br />

Engineered Sustainability<br />

Mouse casing made from Biograde ®<br />

FKuR Kunststoff GmbH<br />

Siemensring 79<br />

D - 47877 Willich<br />

Phone: +49 2154 92 51-0<br />

Fax: +49 2154 92 51-51<br />

sales@fkur.com<br />

www.fkur.com<br />

For further information, contact your local partner:<br />

North America: sales.usa@fkur.com<br />

UK & Ireland: UK@fkur.com<br />

Italy:<br />

Italy@fkur.com<br />

France: France@fkur.com<br />

Scandinavia: Scan@fkur.com<br />

Israel:<br />

Israel@fkur.com


Editorial<br />

dear<br />

readers<br />

Even if the cover picture shows an example of a consumer electronics<br />

product that was launched only this year, this little mouse is the only<br />

consumer electronics example we have in this issue. On the other hand<br />

the second highlight that we had announced — films|flexibles|bags — is<br />

packed with articles, opinions and application news. Be it multilayer<br />

laminates, barrier solutions or the hot topic of plastic bags, there is<br />

plenty of new information and food for thought for you, our readers.<br />

We apologize that the ‘basics’ article about film blowing and blown film<br />

extrusion respectively, had to be postponed to a later issue. Instead we<br />

are happy to present another informative and basic ‘opinion’ article on<br />

the use of agricultural resources for materials production vs energy vs<br />

food or animal feed usage.<br />

And we are happy to congratulate Danone for winning the 6 th Bioplastics<br />

Award, this year for the first time awarded exclusively by bioplastics<br />

MAGAZINE. The ‘Bioplastics Oskar’ — as it was called by delegates of<br />

the conference — was given to the brand owners in recognition of their<br />

exceptional commitment to the use of bioplastics in the packaging of<br />

their leading brand products. The ceremony was part of the 6 th European<br />

Bioplastics Conference on November 22 nd and 23 rd in Berlin, Germany.<br />

Congratulations to European Bioplastics as well for a great conference<br />

with a new record of 420 delegates.<br />

The team of bioplastics MAGAZINE would like to thank all of you for your<br />

loyalty, be it as reader, author or advertiser. We wish you some relaxing<br />

days at the end of the year. Let’s continue a fruitful cooperation in 2012<br />

and see many of you at our 2 nd PLA World Congress on May 15 th and 16 th ,<br />

2012, in Munich, Germany.<br />

Follow us on twitter:<br />

twitter.com/bioplasticsmag<br />

Until then, we hope you enjoy reading bioplastics MAGAZINE<br />

Sincerely yours<br />

Michael Thielen<br />

Be our friend on Facebook:<br />

www.facebook.com/bioplasticsmagazine<br />

bioplastics MAGAZINE [06/11] Vol. 6 3


Content<br />

Award<br />

Bioplastics Award 2011 .......................... 10<br />

Events<br />

European Bioplastics Conference ................. 12<br />

Editorial ..........................3<br />

News .............................5<br />

Application News ..................34<br />

Event Calendar ....................52<br />

Bookstore ........................33<br />

Glossary .........................50<br />

Editorial Planner ..................58<br />

Companies in this issue ............58<br />

06|2011<br />

November/December<br />

Films | Flexibles | Bags<br />

Design Your Own Compostable Film ............... 14<br />

Longer Shelf Life in PLA Packaging ............... 18<br />

New Applications for BoPLA films ................. 20<br />

The Future of the Shopping Bag in Italy ............. 22<br />

Mulch Film Certified ............................ 24<br />

Biopolymer Coatings for Sustainable Packaging ..... 26<br />

‘Bagislation‘ in Europe .......................... 28<br />

Renewable Lightweight Coffee Pouches ............ 32<br />

Consumer Electronics<br />

Bioplastic Mouse added to Green Line .............. 38<br />

Report<br />

Bioplastics in Practical Use ...................... 40<br />

Basics<br />

Agricultural Resources for Bioplastics ............. 44<br />

Personality<br />

John Williams .................................. 48<br />

Imprint<br />

Publisher / Editorial<br />

Dr. Michael Thielen<br />

Samuel Brangenberg<br />

Layout/Production<br />

Mark Speckenbach, Julia Hunold<br />

Head Office<br />

Polymedia Publisher GmbH<br />

Dammer Str. 112<br />

41066 Mönchengladbach, Germany<br />

phone: +49 (0)2161 6884469<br />

fax: +49 (0)2161 6884468<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Media Adviser<br />

Elke Hoffmann, Caroline Motyka<br />

phone: +49(0)2161-6884467<br />

fax: +49(0)2161 6884468<br />

eh@bioplasticsmagazine.com<br />

Print<br />

Tölkes Druck + Medien GmbH<br />

47807 Krefeld, Germany<br />

Total Print run: 3,500 copies<br />

bioplastics magazine<br />

ISSN 1862-5258<br />

bioplastics magazine is published<br />

6 times a year.<br />

This publication is sent to qualified<br />

subscribers (149 Euro for 6 issues).<br />

bioplastics MAGAZINE is printed on<br />

chlorine-free FSC certified paper.<br />

bioplastics MAGAZINE is read<br />

in 91 countries.<br />

Not to be reproduced in any form<br />

without permission from the publisher.<br />

The fact that product names may not be<br />

identified in our editorial as trade marks is<br />

not an indication that such names are not<br />

registered trade marks.<br />

bioplastics MAGAZINE tries to use British<br />

spelling. However, in articles based on<br />

information from the USA, American<br />

spelling may also be used.<br />

Editorial contributions are always welcome.<br />

Please contact the editorial office via<br />

mt@bioplasticsmagazine.com.<br />

Envelopes<br />

A part of this print run is mailed to the readers<br />

wrapped in BoPLA envelopes sponsored by<br />

Taghleef Industries S.p.A., Maropack GmbH &<br />

Co. KGand SFV Verpackungen<br />

Cover<br />

Photo: Philipp Thielen<br />

4 bioplastics MAGAZINE [06/11] Vol. 6<br />

Follow us on twitter:<br />

http://twitter.com/bioplasticsmag<br />

Be our fan on Facebook:<br />

http://www.facebook.com/pages/bioplastics-MAGAZINE/103745406344904


News<br />

Thailand Preferred for Next Ingeo Plant<br />

NatureWorks LLC, from Minnetonka, Minnessota, USA<br />

announced in mid-October that Thailand’s largest chemical<br />

producer, PTT Chemical Public Company Limited (PTT<br />

Chemical) is investing US$150 million in NatureWorks.<br />

NatureWorks supplies its broad family of renewable Ingeo<br />

biopolymers to plastics and fibers markets worldwide. PTT<br />

Chemical’s investment in NatureWorks, until now wholly<br />

owned by Cargill, is subject to regulatory approval.<br />

“The Thai Government encourages an investment in<br />

green chemicals, and particularly bioplastics, which have<br />

high growth potential in the Southeast Asian market,” said<br />

Thailand‘s Minister of Energy H.E. Mr. Pichai Naripthaphan.<br />

“By attracting what could be the most advanced biopolymer<br />

processing plant in the world to Thailand, PTT Chemical has<br />

made a significant step in achieving Thailand’s strategic<br />

objectives of becoming a regional hub for green technologies<br />

and solutions.”<br />

“This is a significant investment by a leading chemical<br />

company, which will allow NatureWorks to continue its<br />

aggressive growth while expanding its capacity to meet global<br />

demand for bio-based products. PTT Chemical’s investment<br />

demonstrates a significant milestone in moving Ingeo biobased<br />

plastics and fibers to the polymer mainstream,” said<br />

Marc Verbruggen, president and chief executive officer<br />

of NatureWorks. “PTT Chemical’s investment supports<br />

NatureWorks intent to globalize its Ingeo manufacturing<br />

capability. We anticipate bringing the new plant online in 2015<br />

and expect to announce further details on this expansion<br />

later this year.”<br />

operating officer, Downstream Petroleum Business Group of<br />

PTT Public Company Limited. “PTT Chemical is keen to play a<br />

role in pioneering a world-scale bioplastics industry with the<br />

aim to become a global leader by 2020 and push Thailand to<br />

become an Asian bio-hub.”<br />

“PTT Chemical reinforces NatureWorks’ leadership position<br />

and proven track record in bringing cost effective biopolymer<br />

innovations to the global marketplace,” said Mr. Veerasak<br />

Kositpaisal, president and chief executive officer of PTT<br />

Chemical. “NatureWorks is currently the forefront producer<br />

of bio-based products with commercially viable production<br />

volumes, competitive costing and a global customer base.<br />

Our investment in the company and its Ingeo technology<br />

platform for plastics and fibers is in line with our long-term<br />

strategic green growth and diversification objectives.”<br />

Over the past several years, NatureWorks has seen steady<br />

25 to 30% increases in annual product demand. In the last<br />

two years, NatureWorks doubled its Ingeo supply availability<br />

by bringing online additional production capacity at its Blair,<br />

Neb., processing facility.<br />

“The proposed new Ingeo facility in Thailand would be<br />

NatureWorks’ second production plant,” Marc Verbruggen<br />

added. MT<br />

www.natureworksllc.com<br />

www.pttchemgroup.com<br />

“This investment will strengthen PTT Chemical’s green<br />

growth strategy towards sustainable development by<br />

integrating more renewable and environmentally friendly<br />

materials in its portfolio, while offering more green product<br />

choices to the customer to fulfill our responsibility as<br />

the ‘Power for a Sustainable Future’ for Thailand and all<br />

stakeholders,” said Mr. Nuttachat Charuchinda, the chief<br />

FKuR Exclusive Distributor of Green-PE in Europe<br />

Global biopolymer leader Braskem and bioplastics specialist FKuR have signed a distribution agreement for Green PE.<br />

Taking effect immediately (Nov. 2011), FKuR will be the official distribution partner for Braskem´s Green PE in Europe.<br />

“This new business field is another milestone that helps make our ‘FKuR - plastics made by nature ® ’ strategy a reality. As<br />

a leading player in the European bioplastics market we are happy to be part of Braskem’s innovative campaign for changing<br />

resource utilisation,” said Dr. Edmund Dolfen, FKuR’s CEO.<br />

“For Braskem, it was important to find a partner who has extensive knowledge in promoting bioplastic specialties in a<br />

commodity market,” declared Fabio Carneiro, Renewable Chemicals Commercial Officer at Braskem.<br />

With its European sales force, FKuR will be an additional technology and technical contact support, development advisor<br />

and logistic partner for Europe. Furthermore, tailor-made compounds made from Braskem’s Green PE will be available under<br />

FKuR’s brand name Terralene TM .<br />

www.braskem.com<br />

www.fkur.com<br />

bioplastics MAGAZINE [06/11] Vol. 6 5


News<br />

NatureWorks<br />

Received Award<br />

NatureWorks was recently honored with<br />

the 2011 Leader of Change Award from<br />

The Foundation for Social Change and<br />

the United Nations Office for Partnerships<br />

(UNOP).<br />

The Leader of Change award recognizes<br />

visionary executives of companies,<br />

financial institutions, and advocacy<br />

groups that have demonstrated an<br />

exemplary commitment to the pursuit of<br />

sustainability whereby environmental and<br />

social performance are embedded in the<br />

competitive strategy of the organization.<br />

“We named NatureWorks a leader<br />

of change, because the company<br />

demonstrates several compelling proof<br />

points,” explained Louise M. Guido, CEO<br />

of the Foundation for Social Change.<br />

“NatureWorks is not a longstanding,<br />

conventional company that decided to<br />

‘go green,’ this is a company actually<br />

founded – just 10 years ago – on the<br />

simple principle of selling sustainable<br />

performance products, giving<br />

contemporary industry a new way to do<br />

business and today’s consumer a new<br />

choice. And, as the Ingeo Earth Month<br />

project demonstrated, NatureWorks’<br />

early bet on environmental performance<br />

is clearly paying off.”<br />

NatureWorks joins a prestigious<br />

group of other 2011 Leader in Change<br />

award recipients, including Billabong,<br />

Domini Social Investment Fund, DSM,<br />

Green Mountain Coffee Roasters, Marks<br />

& Spencer, Philips Lighting, Seventh<br />

Generation and Unilever.<br />

“NatureWorks is founded on the very<br />

principles recognized by the 2011 Leader<br />

of Change Award,” said Steve Davies,<br />

marketing and public affairs director for<br />

NatureWorks, “Ingeo allows companies<br />

to do business differently – by opening<br />

the way for brands to bring innovative and<br />

sustainable products to their customers<br />

without compromising performance and<br />

appeal.” MT<br />

www.natureworksllc.com<br />

First Bio-based EPDM<br />

Rubber in the World<br />

LANXESS from Leverkusen, Germany is strengthening its commitment<br />

to produce premium synthetic rubbers from bio-based raw materials. The<br />

specialty chemicals company aims to commercially produce ethylenepropylene-diene<br />

monomer (EPDM) from bio-based ethylene by the end of<br />

the year. It will be the first form of bio-based EPDM rubber in the world.<br />

EPDM is conventionally produced using the petroleum-based raw<br />

materials ethylene and propylene. Alternatively, Lanxess plans to use<br />

ethylene derived purely from the renewable resource sugar cane. The<br />

company Braskem S.A. will supply the bio-based ethylene via pipeline to<br />

Lanxess’ existing EPDM plant in Triunfo, Brazil.<br />

“Lanxess’ ongoing search for alternatives to fossil fuels underlines its<br />

commitment to reducing CO 2<br />

emissions through sustainable production,”<br />

said Guenther Weymans, head of Lanxess’ Technical Rubber Products<br />

business unit. “We are very excited that our Brazilian plant will be the<br />

pioneer for bio-based EPDM.”<br />

“Lanxess will contribute to broaden our portfolio of renewable chemicals’<br />

clients. This agreement will bring the benefits of green ethylene to other<br />

important applications and markets. Lanxess has extensive automotive<br />

experience and an excellent reputation in this market, which makes it<br />

an ideal partner,” said Marcelo Nunes, Braskem’s Renewable Chemicals<br />

Director.<br />

Triunfo currently produces 40,000 tonnes per year of regular EPDM<br />

rubber and it is expected that the first batches of the product Keltan Eco will<br />

amount to several hundred tonnes. The company’s other EPDM production<br />

sites are based in Geleen, The Netherlands, Marl, Germany, and Orange,<br />

Texas, USA. All EPDM grades will be sold in the future under the brand<br />

name Keltan.<br />

EPDM is used above all in the automotive industry but also in the plastics<br />

modification, cable and wire, construction and oil additives industries. Its<br />

properties include very low density, good resistance to heat, oxidation,<br />

chemicals and weathering as well as good electrical insulation properties.<br />

In addition, Lanxess is already seeking alternative sources to produce<br />

the premium synthetic rubber product butyl rubber, which is used<br />

predominantly in the tire industry. Together with Colorado-based Gevo, Inc,<br />

Lanxess is developing isobutene from renewable resources starting with<br />

corn. Isobutene is a key raw material needed in the manufacture of butyl<br />

rubber.<br />

Last year, Lanxess started up a new onsite<br />

power plant at its Brazilian site in Porto<br />

Feliz, which produces iron oxide pigments.<br />

The innovative, highly efficient cogeneration<br />

plant for the production of electricity and<br />

steam is powered by bagasse, a fibrous<br />

component of sugar cane that is left over<br />

after sugar production. Thanks to the use of<br />

this renewable, environmentally friendly raw<br />

material, energy can be produced on a CO 2<br />

-<br />

neutral basis for the site. MT<br />

www.lanxess.com<br />

www.braskem.com<br />

6 bioplastics MAGAZINE [06/11] Vol. 6


News<br />

New Additives for<br />

High-Performance<br />

Bioplastics<br />

Compared to conventional high-performance<br />

plastics, bioplastics have their limitations – among<br />

other things in terms of stability and strength. The<br />

Düsseldorf/Germany based chemical company<br />

Henkel and the compounder and biopolymer<br />

specialist Tecnaro from Ilsfeld-Auenstein, Germany<br />

have worked together to overcome these limitations.<br />

In cooperation with Tecnaro, Henkel has now<br />

succeeded in developing new high-performance<br />

polyamide additives based on renewable raw<br />

materials that can significantly improve the<br />

performance of bioplastics.<br />

Containing a large proportion of natural raw<br />

materials, the additives of Henkel’s Macromelt brand<br />

are ideal for the production of industrial plastics. This<br />

has become possible through the use of dimer fatty<br />

acids based on natural oils (e.g. rapeseed and tall<br />

oil). Along with a general increase in the proportion<br />

of bio-sourced ingredients, the new additives also<br />

have a positive impact on the performance profile<br />

of bioplastics. Impact resistance and fiber-matrix<br />

adhesion are much improved by these additives.<br />

Depending on the plastics formulation, the<br />

additives are capable of reducing processing<br />

temperature, in some cases considerably. This<br />

diminishes the stressing of the fibers employed, with<br />

a positive effect on stability and appearance.<br />

By developing Macromelt polyamide technology<br />

further, Henkel is thus helping to improve the quality<br />

and usability of bioplastics and paving the way for<br />

further high-end applications.<br />

Thanks to the many years of successful<br />

cooperation between Henkel and Tecnaro, tailored<br />

biopolymers and composites containing Macromelt<br />

additives are already expanding Tecnaro’s broad<br />

range of biomaterials<br />

www.henkel.com<br />

www.tecnaro.de<br />

New Institute<br />

Institute of Bioplastics and Biocomposites<br />

(IfBB) is now in business<br />

The manufacturing and the industrial use of bioplastics and<br />

biocomposites is one focus of research by Prof. Dr.-Ing. Hans-<br />

Josef Endres and his team at the University of Applied Sciences<br />

and Arts in Hanover, Germany.<br />

At Faculty II (Mechanical and Bioprocess Engineering) of this<br />

University the new ‘Institute of Bioplastics and Biocomposites’<br />

(IfBB) started work on November 1 st , 2011.<br />

The formation of the new institute can be seen as the result<br />

of the success enjoyed by previous research on bioplastics and<br />

biocomposites. With the new institute all further ambitions and<br />

projects can be expanded with less restriction.<br />

The production, usage and disposal of biopolymers, cellulose<br />

based natural fibres and thermoplastic composites are the<br />

main focus for the Institute of Bioplastics and Biocomposites.<br />

The scientists there are, as an example, working on applied<br />

processes of material development.<br />

There is a close cooperation between the new institute and<br />

industry with regard to all industrial processes along the whole<br />

process chain: chemical research, materials development,<br />

machine manufacturer and the bioplastics converting industry<br />

– all working closely together.<br />

For example in collaboration with Henkel the scientists have<br />

developed a correction pen. In the future bioplastics will be<br />

used more and more in other technical applications, such as<br />

in the automobile industry. Here there has been cooperation<br />

with Volkswagen in Wolfsburg for many years, as well as with<br />

KraussMaffei Technologies and KraussMaffei Berstorff in<br />

Hanover.<br />

The interest in bioplastics and biocomposites is growing<br />

continuously, and commanding the attention of politics, industry<br />

and consumers. Many products, for example food packages,<br />

beverage bottles and sports equipment, are now manufactured<br />

from biobased materials.<br />

Such applications will<br />

certainly be increasing during<br />

the next years, and for which<br />

the new Institute of Bioplastics<br />

and Biocomposites is in an<br />

excellent starting position.<br />

www.fh-hannover.de<br />

The fiber-matrix adhesion of bioplastics is much<br />

improved by the additives of the Macromelt brand.<br />

bioplastics MAGAZINE [06/11] Vol. 6 7


News<br />

USDA Grant to Develop<br />

Plant Containers<br />

Iowa State University, Ames, Iowa, USA has been awarded<br />

a grant by the U.S. Department of Agriculture to develop<br />

biorenewable and biodegradable containers for the specialty<br />

crop industry.<br />

The $1.9 million grant will be used to develop bioplastic<br />

containers as an alternative to petroleum-based pots. Bill<br />

Graves, professor of horticulture, will lead the research<br />

team that includes David Grewell, associate professor of<br />

agricultural and biosystems engineering and Center for<br />

Crops Utilization Research (CCUR) affiliate; Michael Kessler,<br />

associate professor of materials science and engineering<br />

and CCUR affiliate; James Schrader, assistant scientist<br />

in horticulture; and scientists at the University of Illinois;<br />

University of Nevada-Reno; and Ohio State University.<br />

Grewell, Schrader, and Kessler are also members of CCUR‘s<br />

Biopolymers & Biocomposites Research Team.<br />

The plant containers were produced by Grewell‘s research<br />

group in CCUR‘s Technology Transfer Pilot Plant using the<br />

150-ton hydraulic press. The containers are made of soy<br />

protein-based plastic.<br />

“Nearly all specialty crops, including bedding plants,<br />

tomatoes and other vegetables, and containerized shrubs<br />

and trees that are purchased for residential gardening and<br />

landscaping, are grown and marketed in petroleum-based,<br />

conventional plastic containers.Few of those are recycled or<br />

reused,” said Graves. “Our vision is to provide sustainable<br />

alternatives that can meet the needs of horticultural<br />

producers, and that will degrade harmlessly when installed<br />

with the plant in a garden.”<br />

An estimated $706 million could be saved annually by<br />

the specialty crop industry by converting from petroleumbased<br />

containers to bioplastic containers, Graves said. Other<br />

benefits include shifting resource revenue from foreign<br />

oil to domestic biorenewables and eliminating adverse<br />

environmental effects of petroleum-based plastics. MT<br />

First Sugar Cane<br />

based PHA<br />

Vinçotte recently awarded the ‘OK Biodegradable<br />

(in) Water’ certification to the MINERV ® PHA SC (Sugar<br />

Cane) bioplastics. This is the first and only biopolymer<br />

in the world made by the Italian company Bio on from<br />

Bologna, starting from sugar cane by-products.<br />

The certification confirms Minerv PHA SC’s complete<br />

biodegradability in water at ambient temperature. This<br />

new plastic can be used to make a wide range of rigid<br />

or flexible objects and to replace daily use products that<br />

are highly polluting and made from petroleum based<br />

conventional plastics, currently used to manufacture<br />

bottles, food packaging, auto parts, furnishings, fibres,<br />

packaging film and electronics and much more.<br />

Bio on develops new materials in the modern<br />

biotechnologies sector and this recognition completes<br />

the industrial research project, started in 2007, aimed at<br />

producing naturally biodegradable plastic, starting from<br />

sugar beets and, as of today, also from sugar cane. Until<br />

now both have mainly been used to produce edible sugar<br />

or biofuels. The idea is especially innovative since, for<br />

the first time in the world, PHA (polyhydroxyalkanoate)<br />

is obtained from molasses or intermediate sugar cane<br />

juices or from its by-products and not from oils or cereal<br />

starches like the majority of the biopolymers on the<br />

market today. Minerv PHA bioplastics are thus made<br />

from waste materials and not from products intended<br />

for food production. This, combined with their complete<br />

biodegradability in water, is the big environmental<br />

advantage of the bioplastics developed by Bio on.<br />

Minerv PHA SC has excellent thermal properties.<br />

Through the range of polymerisation, production<br />

requirements from -10°C to +180°C can be met, to be<br />

used with injection or extrusion methods. MT<br />

www.minerv.it/<br />

www.bio-on.it/<br />

www.biocom.iastate.edu/<br />

8 bioplastics MAGAZINE [06/11] Vol. 6


News<br />

Amsterdam ArenA (Photo: Bjørn Giesenbauer, CC-by-sa)<br />

Ajax Fans Sit on<br />

Sustainable Sugar<br />

Braskem recently established a partnership with<br />

Amsterdam ArenA, home of the famous soccer team<br />

Ajax Amsterdam in the Netherlands. The leading<br />

thermoplastic resin producer in the Americas will<br />

supply sugar-cane based polyethylene to be used in<br />

the production of seats for the multifunctional Dutch<br />

stadium. In addition to the 52,000 existing seats, two<br />

thousand new seats manufactured with Braskem‘s<br />

plastic made from bio-ethanol will be installed in the<br />

coming months. By the end of the next two years,<br />

all 54,000 seats will be made of plastic from 100%<br />

renewable raw material, using Brazilian technology.<br />

The installation of the ‘sugar seats’ - as these<br />

seats are being called - is part of the strategy to<br />

turn the Amsterdam ArenA into a landmark of the<br />

world‘s most sustainable capital. The stadium<br />

was inaugurated in 1996, and its remodel will not<br />

adversely affect the events happening in the stadium.<br />

The entire remodeling project follows sustainability<br />

guidelines. In 2015, the stadium wants to be<br />

ecologically neutral, producing no carbon footprint.<br />

“The use of Green Plastic at the Amsterdam ArenA<br />

is fully in line with Braskem‘s strategy of becoming<br />

the world‘s leading company in sustainable<br />

chemicals“, said Marcelo Nunes, Braskem‘s<br />

Renewable Chemicals Director. “Braskem‘s<br />

partnership with Station Amsterdam complements<br />

other alliances already consolidated in recent<br />

months, uniting companies that seek sustainable<br />

solutions“, added the executive. MT<br />

Synterra grade IM (left) and<br />

traditional PLA (right) after<br />

immersion in boiling water.<br />

Non-GMO PLA Wins<br />

Blue Tulip Award<br />

By mixing 100% pure PLLA with 100% PDLA, a fast cycle<br />

and heat-resistant injection mouldable PLA with very good<br />

temperature and impact properties is made that far exceeds<br />

the properties of the individual polymers. With a Heat Deflection<br />

Temperature (HDT B @ 0,45 N/mm²) of 123°C Synterra ® IM<br />

material performs much better than conventional PLA and the<br />

impact strength is comparable to that of ABS. After injection<br />

molding the IM material is able to withstand boiling water. With<br />

this development Synbra Technology sets a step in developing a<br />

new generation of high performance biopolymers.<br />

The polymerization of the optical isomers PLLA and PDLA<br />

takes place at Synbra Technology in Etten-Leur, the Netherlands,<br />

in a plant with a capacity of 5000 tonnes/annum, which was<br />

commissioned early 2011.<br />

Synbra Technology expects further growth in its PLA business<br />

as many brand-owners and retailers in Western Europe prefer to<br />

use bio-based and non-GMO PLA that is also heat-resistant.<br />

Shortly after introducing its Synterra IM material, Synbra<br />

Technology was awarded at the Accenture Blue Tulip Awards at<br />

the RAI Elicium, in Amsterdam, the Netherlands.<br />

“This Blue Tulip Award in the category ‘Making more out of less’<br />

is the ultimate reward for the entire team that participated in the<br />

successful development of our Synterra IM grade, which is made<br />

from Cradle to Cradle SM certified PLA,“ said Peter Matthijssen,<br />

Commercial Manager of Synbra Technology.<br />

In recognition of the purity of the raw materials used, the PLA<br />

of Synbra was Cradle to CradleSM certified by EPEA in Hamburg<br />

and is thus the first PLA in the world with this certification.<br />

Application of this PLA also improves various properties such as<br />

toughness and temperature resistance of several other bio-based<br />

recipes, in which PLA is an important constituent. MT<br />

www.biofoam.nl<br />

www.synbra.com<br />

bioplastics MAGAZINE [06/11] Vol. 6 9


Award<br />

And the Winner is …<br />

The 6 th Bioplastics Award, this year for the first time<br />

awarded exclusively by bioplastics MAGAZINE, went to<br />

Danone GmbH in recognition of their exceptional commitment<br />

to the use of bioplastics in the packaging of their<br />

leading brand products. Marianne Schweiger, Senior Packaging<br />

Development Engineer of Danone accepted the soughtafter<br />

award on November 22 nd during the 6 th European Bioplastics<br />

Conference in Berlin.<br />

The annual Bioplastics Award was established in 2006<br />

by the English trade publication European Plastics News.<br />

It recognises the special role played by a brand owner or<br />

single individual and acknowledges the contribution made by<br />

companies, products or services to the further development<br />

of bioplastics by way of specific innovation or imaginative<br />

marketing concepts. This year the 5-man panel of judges,<br />

from academia, the press and trade associations in America,<br />

Europe and Asia, selected Danone GmbH in Haar near Munich<br />

from a long list of first class ideas and innovations. The judges<br />

are of the view that Danone, as an international brand owner,<br />

made a significant contribution to moving bioplastics from a<br />

niche packaging product to a mass market product with the<br />

introduction of Activia and Actimel in bioplastic packaging<br />

(PLA and Green HDPE). This means that today more than half<br />

of the Danone products in the German market are packaged<br />

in bioplastics.<br />

It is one of Danone’s objectives to make a serious<br />

contribution to the reduction of greenhouse gases. One of the<br />

various measures which they have taken is the use of biobased<br />

or partially bio-based packaging. And here Danone are<br />

not concentrating on specific bioplastics but are choosing<br />

the most appropriate bioplastic for the job – be it up to 100%<br />

bio-based polyethylene, partially bio-based PET or 100% biobased<br />

PLA. “This action by Danone is pointing the way for<br />

marketers of branded products in Europe and worldwide”,<br />

commented Dr. Michael Thielen, spokesman for the judges,<br />

and publisher of bioplastics MAGAZINE.<br />

“We are very pleased about the award. A highly valued<br />

acknowledgement like this is wonderful confirmation of our<br />

achievement over years of research, and of our commitment<br />

in the field of bioplastics. We must get away from our<br />

dependence on petroleum and focus on packaging materials<br />

that come from renewable resources. We therefore hope that<br />

the award will motivate other companies to select bioplastics.<br />

It is only in this way that we will be able to establish a full<br />

recycling system, for example for PLA, and make full use of the<br />

material’s potential”, commented Dr. Andreas Knaut, Director<br />

Corporate Communications, Health and Sustainability.<br />

The plastic material from which the Actimel bottles<br />

are made is so-called ‘Green HDPE’. This polyethylene is<br />

chemically almost identical to conventional PE, yet is produced<br />

from sugar-cane based bioethanol, i.e it is produced totally<br />

from renewable resources and not from petroleum products.<br />

PLA, the material used for the new Activia yoghurt pots, is<br />

also made completely from renewable raw materials. The<br />

PLA (polylactic acid) is obtained from starch by fermentation<br />

and is also biodegradable. However with PLA Danone is not<br />

promoting the composting aspect but is encouraging other<br />

packaging manufacturers to also use PLA so that significantly<br />

large quantities come onto the market and make a PLA-to-<br />

PLA recycling plant an ecologically sound and economical<br />

proposition.<br />

www.danone.com<br />

(Photo: European Bioplastics)<br />

10 bioplastics MAGAZINE [06/11] Vol. 6


Award<br />

Info:<br />

Danone GmbH located in Haar,<br />

near Munich, is part of the Danone<br />

Group and in 2010 turned over<br />

589 million Euros in Germany<br />

with around 840 employees. For<br />

Germany Danone produces a wide<br />

range of fresh dairy products.<br />

The Danone Group is involved in<br />

a total of four product sectors in<br />

Germany: dairy products, water,<br />

baby foods, medical nutrition<br />

Register now:<br />

The conference will comprise<br />

high class presentations on<br />

• Latest developments<br />

• Market overview<br />

• High temperature behaviour<br />

• Barrier issues<br />

• Additives / Colorants<br />

• Applications<br />

• Reinforcements<br />

• End of life options<br />

The programme will be published<br />

soon at<br />

www.pla-world-congress.com<br />

Watch out for the<br />

‘Early Bird Offer’<br />

2 nd PLA World<br />

C o n g r e s s<br />

15 + 16 MAY 2012 * Munich * Germany<br />

Papers still welcome ...<br />

Deadline is Dec. 23, 2011<br />

send your proposal to<br />

mt@bioplasticsmagazine.com<br />

www.pla-world-congress.com Tel.: +49 (2161) 6884469<br />

bioplastics MAGAZINE [06/11] Vol. 6 11


Events<br />

Bernhard Bauske of WWF<br />

New Record at<br />

6 th European<br />

Bioplastics<br />

Conference<br />

More than 400 visitors came to Europe‘s leading bioplastics<br />

event<br />

The interest in bioplastics strongly increased over<br />

the year, noted the association European Bioplastics. This<br />

trend was once more confirmed by the attendance record<br />

at the 6th European Bioplastics Conference: more than<br />

400 visitors came to Berlin on 22 and 23 November to hear<br />

the 29 exciting speeches from renowned industry experts.<br />

Furthermore, the adjoining exhibition and networkingformats<br />

met with high response.<br />

With about 420 visitors from more than 250 companies and<br />

institutions from all over the world the European Bioplastics<br />

Conference once more established a record. Thereby, it<br />

remains the leading bioplastics industry event and the<br />

industry‘s information and networking plattform number<br />

one. This year, more than 80% of the participants came from<br />

Europe, 10% from Asia, and the better part of the remaining<br />

10% from North and South America.<br />

In his key-note speech Maurits van Tol, DSM Bio-based<br />

Products & Services, commented on the worldwide potential<br />

of bioplastics: “Mass production of bioplastics is around<br />

the corner, and such large scale plants with their better<br />

cost structure will increase the inroads of bioplastics in<br />

the relevant markets. The long awaited breakthrough of<br />

bioplastics in the worldwide market is near.“ Another positive<br />

comment came from Werner Ressing, Federal Ministry of<br />

Economics and Technology: “Bioplastics offer numerous<br />

opportunities to increase the economic value added of the<br />

German and European economy.“<br />

The presentations showcased the potential of bioplastics<br />

from several different perspectives. A number of innovations<br />

were introduced - new materials, additives and end-of-life<br />

approaches. The session on ‘bioplastics and sustainability‘<br />

gave insights into environmental communications as well as<br />

into certification concepts.<br />

A highlight of the 6 th European Bioplastics Conference was<br />

the ceremony of bioplastics MAGAZINE‘s Bioplastics Award“. In<br />

2011 the lucky winner was Danone. See page 10 for details.<br />

In view of the increased interest in bioplastics during the<br />

past year and the most successfull event Andy Sweetman,<br />

Chairman of European Bioplastics, offered a positive<br />

prediction for 2012: “The development of the bioplastics<br />

industry is picking up speed. We need clear framework<br />

conditions in Europe and a strong united voice to request<br />

them. 2012 the role and work of our industry association<br />

European Bioplastics will become more and more important<br />

in order to further our young industry. Established and<br />

leading formats such as the annual conference are of major<br />

importance to guarantee a rich and multi-facetted knowledge<br />

exchange about bioplastics.“<br />

www.european-bioplastics.org<br />

12 bioplastics MAGAZINE [06/11] Vol. 6


NPE2012, the world’s largest plastics conference, exposition and<br />

technology exchange, blasts into Orlando, Florida USA this April<br />

to reshape the future of our industry! Showcasing more than 2,000<br />

exhibitors, NPE is the only global event that allows you to:<br />

See large-scale, running machines in action<br />

Explore more than 2 million square feet<br />

of solutions for every segment of the<br />

plastics industry supply chain<br />

Discover new and emerging technologies<br />

among hundreds of on-site demos every day<br />

Meet 75,000 plastics professionals from more<br />

than 120 countries<br />

Access hundreds of timely programs, from business<br />

development to the latest technical advances<br />

Connect with the entire lifecycle of the plastics industry<br />

And much, much more!<br />

REGISTER NOW AT NPE.ORG<br />

Co-located at NPE2012:


Films|Flexibles|Bags<br />

Design Your<br />

Own Compostable Film<br />

Multi-layer systems increasing the opportunities for new markets<br />

By<br />

B. von Hansen<br />

J. Schmeling<br />

D. Winkelmann<br />

P. Zimmermann<br />

FKuR Kunststoff GmbH,<br />

Willich, Germany<br />

Plastics made from renewable resources offer new opportunities<br />

and possibilities for both flexible and durable packaging<br />

along with general e.g. injection moulding applications. Each<br />

day nature shows us well designed packaging solutions. These solutions<br />

can be used as a guideline and implemented in our industrial<br />

packaging world. Of course, we have different requirements<br />

for industrial packaging compared to nature. Most goods need to<br />

be transported, stored and protected against surrounding conditions<br />

and some need to withstand a long shelf life. Biopolymers,<br />

whether biodegradable, based on renewable resources, or both<br />

have a similar natural approach. But sometimes they do not fulfil<br />

all of the requirements necessary for industrial packaging, in particular<br />

the properties of high barrier and transparency.<br />

14 bioplastics MAGAZINE [06/11] Vol. 6


Films|Flexibles|Bags<br />

The packaging requirements for barrier properties are<br />

not even able to be achieved with polymers based on crude<br />

oil. For both conventional and bioplastics a co-extrusion or<br />

the lamination of different polymers is the key to fulfil these<br />

requirements of today’s packaging applications. Of course,<br />

it is still questionable if such high barriers are necessary<br />

but achieving such levels is state of the art in packaging<br />

technology. In order to enter new markets and increase the<br />

range of applications for bioplastics these resins must follow<br />

this trend and need to be co-extruded or laminated.<br />

Advantages of compostable multilayer<br />

systems for food packaging<br />

Plastics used for packaging represent around 39 %<br />

[Plastics Europe: Plastics – The Facts 2011] of the total<br />

plastic consumption and are by far the largest market<br />

segment of all plastics applications. The requirements for<br />

plastic films, especially for those used predominantly in food<br />

packaging, have been constantly rising over recent years and<br />

have now reached a level that can only be achieved by means<br />

of intelligent material combinations and well-engineered<br />

process procedures.<br />

In the beginning, biopolymers were mainly designed for<br />

applications such as waste bags and shoppers. Transparency<br />

was not a requirement. The content of renewable resources<br />

of these resins has been around 20 to 40 %. With the<br />

upgrading of properties, the range of applications made from<br />

biopolymers is constantly growing. In addition, the content of<br />

renewable resources in combination with compostability is<br />

gaining importance for all kinds of packaging applications.<br />

To enter new markets with biopolymers, new resins and<br />

compounds have to be created. The major requirements for<br />

such modern packaging include a high content of renewable<br />

resource materials (>50%) and compostability combined with<br />

good barrier properties and preferably transparency. On the<br />

one hand, barrier is a necessity for certain packaging, e. g.<br />

MAP (Modified Atmosphere Packaging) and other applications<br />

where an oxygen barrier is required. On the other hand, there<br />

are applications where high permeation and breathability are<br />

required, which is where Bio-Flex ® with its intelligent filler<br />

system allows up to perfection. Such applications include<br />

back sheet films for diapers along with fresh food packaging<br />

where transparency is often a key requirement. One of the<br />

largest advantages of compostable films is, whenever it is<br />

needed, packed goods and films can be disposed together<br />

or can be used in a fermentation plant without separating<br />

organic goods and films.<br />

In order to meet these challenges FKuR Kunststoff GmbH,<br />

Willich, and its cooperation partner Fraunhofer UMSICHT,<br />

Oberhausen, both Germany, have developed new Bio-Flex<br />

resins which exhibit outstanding characteristics when<br />

combined in a multilayer structure. The latest developments<br />

are focused on flexibility, transparency and a high content of<br />

renewable resources, whether in a mono or multilayer film<br />

structure.<br />

By co-extrusion it is possible to combine the clear and stiff<br />

material Bio-Flex A 4100 CL, used in the outer layers with the<br />

new transparent Bio-Flex F 2201 CL or translucent Bio-Flex<br />

S 1100 in the mid layer. As both resins are flexible and tough<br />

they are able to support Bio-Flex A 4100 CL in a multilayer<br />

structure. One of the main advantages is that the properties<br />

of this film can be adjusted by the variation of each layer. By<br />

using respective layer combinations, e.g. greater stiffness or<br />

more elasticity of the film, according to the final requirements,<br />

can be reached. This is shown in charts 1 and 2. By combining<br />

Bio-Flex A 4100 CL with F 2201 CL, the tensile modulus of<br />

A 4100 CL can be significantly reduced, while the elongation at<br />

break is still at the level of a pure F 2201 CL. The result of this<br />

is a 3-layer structure that not only offers superior toughness<br />

and flexibility, but at the same time high transparency.<br />

In addition to having high quality clarity, the content of<br />

renewable resource materials is outstanding for a blown film<br />

application. The content of renewable resource materials of a<br />

film made from Bio-Flex A 4100 CL / S 1100 / A 4100 CL is 30<br />

to 50%, depending on the structure, whereas with a film made<br />

from Bio-Flex A 4100 CL / F 2201 CL / A 4100 CL the content<br />

of renewable resources is between 60 to 80% depending on<br />

the final film structure. There are no transparent or flexible<br />

blown film types similar to the Bio-Flex resins available today.<br />

u<br />

Chart 1: Tensile Modulus of Bio-Flex mono and multilayer films<br />

(MD = machine direction, TD = transversal direction)<br />

Modulus of elasticity MD [MPa]<br />

2000<br />

1750<br />

1500<br />

1250<br />

Bio-Flex A 4100 CL / F 2201 CL / A 4100 CL<br />

(20 / 60 / 20 [%], 20µm)<br />

1000<br />

Bio-Flex F 2201 CL<br />

750<br />

Bio-Flex A 4100 CL / F 2201 CL<br />

A 4100 CL (15 / 70 / 15 [%], 20µm)<br />

500<br />

Bio-Flex S 1100<br />

0<br />

Bio-Flex A 4100 CL / S 1100 / A 4100 CL<br />

(20 / 60 / 20 [%], 20µm)<br />

Modulus of elasticity TD [MPa]<br />

Bio-Flex A 4100 CL<br />

| | | | | | |<br />

500 750 1000 1250 1500 1750 2000<br />

Chart 2: Elongation at Break of Bio-Flex mono and multilayer films<br />

Elongation at break MD [%]<br />

350<br />

300<br />

250<br />

200<br />

150<br />

100<br />

50<br />

0<br />

Bio-Flex A 4100 CL / S 1100 / A 4100 CL<br />

(20 / 60 / 20 [%], 20µm)<br />

Bio-Flex A 4100 CL<br />

Bio-Flex F 2201 CL<br />

Bio-Flex A 4100 CL / F 2201 CL / A 4100 CL<br />

(15 / 70 / 15 [%], 20µm)<br />

Bio-Flex A 4100 CL / F 2201 CL / A 4100 CL<br />

(20 / 60 / 20 [%], 20µm)<br />

Bio-Flex S 1100<br />

| | | | | |<br />

50 100 150 200 250 300 350<br />

Elongation at break TD [%]<br />

bioplastics MAGAZINE [06/11] Vol. 6 15


Films|Flexibles|Bags<br />

Multilayer made from Bio-Flex F 2110 / A 4100 CL / F 2110 Multilayer made from Bio-Flex A 4100 CL / Bio-Flex F 2110 /<br />

Bio-Flex A 4100 CL for deep freeze applications<br />

Opportunities through new Bio-Flex grades<br />

The combination of organically grown food with packaging<br />

made from sustainable bioplastics is a logical step and<br />

completes the overall sustainable message while providing<br />

consumers with the positive feeling of contributing to an ecofriendly<br />

environment.<br />

Compared to conventional plastics, bioplastics offer an<br />

alternative ‘end-of-life’ option. The ability to use bioplastics<br />

after their useful life in composting facilities or energy<br />

recovery systems are important factors. In particular,<br />

renewable plastics can contribute to the efficient utilization<br />

and conservation of our resources in terms of ‘renewble<br />

energy‘.<br />

The following practical examples will prove the expansion of<br />

the range of applications for bioplastics by means of efficient<br />

utilisation in multilayer systems. For both examples, the high<br />

content of natural resources (provided by Bio-Flex A 4100 CL)<br />

as well as the excellent strength and flexibility (provided by<br />

Bio-Flex F 2110) were the decisive factors for choosing a<br />

multilayer system made from Bio-Flex.<br />

• McCain uses a three layer combination made from Bio-<br />

Flex A 4100 CL / Bio-Flex F 2110 / Bio-Flex A 4100 CL for<br />

packaging of their ‘Bio-Ernte’ product line. This multilayer<br />

allows for the production of a very flexible and extensible<br />

film with a great stiffness also at low temperatures. (deep<br />

freeze)<br />

• A three layer system made from Bio-Flex F 2110 / Bio-<br />

Flex A 4100 CL / Bio-Flex F 2110 was used by Umbra<br />

Olii for wrapping their ‘Ecolive’ laundry soap, which is<br />

made from 100% natural olive. The film allows for a very<br />

appealing glossy surface along with a great toughness and<br />

chemical resistance as well as good barrier properties for<br />

a bioplastic.<br />

• One of the leading producers of napkins uses a three layer<br />

film made from Bio-Flex A 4100 CL / Bio-Flex F 2110 / Bio-<br />

Flex A 4100 CL for their compostable product line.<br />

Metallization as a possible solution to<br />

increase barrier<br />

The lower barrier of many bioplastics against water and<br />

oxygen, when compared to conventional plastics, can be<br />

improved by coating techniques such as metallization. Chart<br />

3 shows the improved barrier of a metallized Bio-Flex co-ex<br />

structure. Most notably, the oxygen barrier is highly improved<br />

which makes these films suitable for new applications in<br />

food packaging. Usually the layer thickness in metallization<br />

processes is below 0.1 µm. Therefore compostability/<br />

biodegradability of the final film structure can still be<br />

achieved. u<br />

Chart 3: Transmission rates of Bio-Flex films in comparison<br />

to other plastics (WVTR = Water Vapour Transmission Rate)<br />

350,0<br />

WVTR [g / (m 2 · d)]<br />

300,0<br />

250,0<br />

200,0<br />

150,0<br />

100,0<br />

50,0<br />

0<br />

PLA<br />

Bio-Flex A 4100 CL / F 2201 CL / A 4100 CL<br />

Bio-Flex F 2201 CL<br />

Bio-Flex A 4100 CL<br />

Testing conditions (25 µm film):<br />

H 2<br />

O: 23°C / 100% hum.<br />

O 2<br />

: 23°C / 0% hum.<br />

Metallized Bio-Flex<br />

A 4100 CL / F 2201 CL / A 4100 CL<br />

PET<br />

| | | | | | |<br />

250,0 500,0 750,0 1000,0 1250,0 1500,0 1750,0<br />

Oxygen [cm 3 / (m 2 · d)]<br />

PP<br />

16 bioplastics MAGAZINE [06/11] Vol. 6


Films|Flexibles|Bags<br />

Multilayer made from Bio-Flex<br />

A 4100 CL / F 2201 CL / A 4100 CL<br />

(In-House) Recycling of compostable<br />

multi-layer structures made from<br />

Bio-Flex<br />

To achieve an overall sustainable and cost effective<br />

multilayer product it is also necessary to recycle the<br />

production scrap (e.g. edge trims) and to use the<br />

regrinds in the middle layer of the film. Various Bio-<br />

Flex resins used in the layers could have an effect on<br />

the mechanical properties and optical appearance of<br />

the middle layer. Analysis have been done using the<br />

multilayer structure Bio-Flex A 4100 CL / F 2201 CL /<br />

A 4100 CL (with layer ratios 20 % / 60 % / 20 %) as<br />

this is the most commonly used structure containing<br />

multiple Bio-Flex types. As the production scrap<br />

will be added into the middle layer all of the trials<br />

carried out are only reflected upon this middle layer.<br />

It is assumed that as a maximum 20 % of production<br />

scrap will be used in this middle layer.<br />

Degradation of the biopolymers during the different<br />

production steps normally implies a higher melt flow<br />

and softer end product. Comparing the results of<br />

these trials it is shown that the amount of Bio-Flex<br />

A 4100 CL in the regrind compensates the negative<br />

effects of possible mechanical degradation. The<br />

results of the tensile test indicate a shifting of the<br />

properties in transversal direction (TD) and machine<br />

direction (MD), the tensile test results increase by 5%<br />

measuring in TD but decrease by 10 % in MD. The<br />

optical appearance of the film is still the same, as a<br />

reduction of the transparence and a decrease of the<br />

haze is not visible.<br />

Although the results of all tests have shown that<br />

the usage of regrind will not affect the properties<br />

negatively, it is recommended to processors to<br />

conduct own tests. Since the shear during production<br />

and recycling has a high influence on the material<br />

these results can vary and should be tested and<br />

reviewed independently. •<br />

Chart 4: Tensile Modulus of Bio-Flex mono layer,<br />

multilayer and recycled films<br />

Modulus of elasticity MD [MPa]<br />

1000<br />

750<br />

500<br />

250<br />

0<br />

www.fkur.com<br />

Bio-Flex A 4100 CL / F 2201 CL / A 4100 CL<br />

(20 / 60 / 20 [%], 20µm)<br />

| | | |<br />

250 500 750 1000<br />

Modulus of elasticity TD [MPa]<br />

Chart 5: Elongation at Break of Bio-Flex mono layer,<br />

multilayer and recycled films<br />

Modulus at break MD [MPa]<br />

400<br />

300<br />

200<br />

100<br />

0<br />

Bio-Flex F 2201 CL<br />

+ Recyclat<br />

Bio-Flex A 4100 CL / F 2201 CL / A 4100 CL<br />

(20 / 60 / 20 [%], 20µm)<br />

Elongation at break TD [MPa]<br />

Bio-Flex F 2201 CL<br />

+ Recyclat<br />

Bio-Flex F 2201 CL<br />

Bio-Flex F 2201 CL<br />

| | | | | | |<br />

50 100 150 200 250 300 350<br />

bioplastics MAGAZINE [06/11] Vol. 6 17


Films|Flexibles|Bags<br />

Longer Shelf Life<br />

in PLA Packaging<br />

Pepper and tomatoes stay longer fresh<br />

By<br />

Paolo Serafin<br />

Sales Manager NATIVIA<br />

Taghleef Industries<br />

San Giorgio di Nogaro, Italy<br />

Consumer awareness with regard to more sustainable<br />

packaging is also pushing the use of bioplastics in the<br />

fruit and vegetables market, but there’s more than just<br />

an environmental advantage. Taghleef Industries, manufacturer<br />

of BOPP and BOPLA films, in cooperation with EOSTA<br />

and Bio4Pack, commissioned a study on the shelf life of bell<br />

peppers and vine tomatoes packed in PLA vs PP to the Univeristy<br />

of Wageningen, which produced some very interesting<br />

results.<br />

PLA (polylactic acid) is emerging in the packaging industry<br />

as the most promising alternative to oil-based plastics,<br />

thanks to its performance, availability and versatility. It’s<br />

already in use in rigid packaging (injection molding), semirigid<br />

(thermoforming and blow molding) and flexibles (film).<br />

At Taghleef Industries Italy, PLA is extruded into sheet and<br />

sequentially oriented in machine and transversal direction, in<br />

a production process very similar to that of BoPET and BoPP.<br />

PLA film is heat sealable and used for packaging products on<br />

traditional horizontal and vertical form/fill sealing machines,<br />

as well as on twist wrap and overwrap machines. Recent<br />

developments have also seen the use of PLA films for windows<br />

on paper bags, adhesive tapes, paper lamination and labels.<br />

Eosta, the market leader in the organic fruit and vegetables<br />

market in Europe, have used PLA for many years for the<br />

thermoformed trays and overwrapping film in which they<br />

pack their products. Besides contributing to minimizing the<br />

environmental impact of their packaging, PLA gives Eosta<br />

the chance to differentiate themselves from the competition<br />

and offer a packaging solution which fits perfectly with their<br />

mission and target customers.<br />

Having noticed an improvement in the preservation of their<br />

products using PLA compared to the standard PP packaging,<br />

Eosta, Taghleef Industries and Bio4pack have decided to<br />

carry out a detailed analysis, and commissioned this task<br />

to Wageningen University, one of the most experienced in<br />

this field, choosing two of the most common products: bell<br />

peppers and vine tomatoes.<br />

The test:<br />

Samples of the peppers and tomatoes were taken from the<br />

same lot, making sure that the harvest date was the same for<br />

the whole batch. Peppers were packed using a horizontal FFS<br />

(Form Fill Seal) machine and macro-perforated transparent<br />

PLA and PP films. The same packaging films were used<br />

for the thermoformed trays containing the vine tomatoes.<br />

Packaging and storage were done under the same conditions<br />

for all samples, also simulating the conditions available in<br />

retail stores. Unpacked products were also included in the<br />

analysis for a complete comparison and reference.<br />

The monitored parameters were:<br />

VINE TOMATOES:<br />

• Firmness<br />

• Fruit rot<br />

• Dehydration of wood stem<br />

• Stem rotten<br />

• Colour<br />

BELL PEPPERS:<br />

• Firmness<br />

• Dehydration/wrinkling<br />

• Fruit rot<br />

• Stem rotten, and freshness<br />

18 bioplastics MAGAZINE [06/11] Vol. 6


Films|Flexibles|Bags<br />

Results:<br />

TOMATOES:<br />

As depicted in Fig. 1, PLA packaging contributed to<br />

delaying by approx. two days the crown and stem dehydration<br />

index, which emerged as the first aging sign of this product in<br />

comparison with the product packed in PP. This ageing factor<br />

is rather important, being clearly visible to the consumer.<br />

The other parameters did not show relevant differences and<br />

they all crossed the ‘acceptable’ threshold several days after<br />

the crown and stem index was negative, confirming that<br />

stem dehydration is the limiting parameter in the shelf life<br />

of tomatoes.<br />

PEPPERS:<br />

With regard to bell peppers, a positive effect of PLA was<br />

noticed in the firmness of the fruit when compared with PP<br />

(Fig. 2), but an improvement can also be observed on the stem<br />

index, which shows a slower degradation, remaining within<br />

the acceptable limits for 1-2 days longer than product packed<br />

in PP (Fig. 3). The other parameters did not show noticeable<br />

differences. In the case of peppers, dehydration (shrivelling)<br />

emerges at the same time as the limiting quality parameter<br />

for both PP and PLA, well before the others and even earlier<br />

if the product is unpacked. Nevertheless, this means that, as<br />

the use-by date gets closer, peppers packed in PLA will show<br />

a better stem and firmness compared to those packed in PP.<br />

Conclusions:<br />

From these tests it emerges quite clearly that unpacked<br />

product has a shorter shelf life.<br />

In general, it can be said that the most important<br />

parameters to be considered in the shelf life of tomatoes<br />

are degradation and dehydration of the stem, where PLA<br />

packaging has a positive effect, followed only later by the<br />

dehydration of the fruit. Tests confirmed that the shelf life of<br />

tomatoes packed in PP is 11 days, which becomes 13 days if<br />

they are packed with PLA.<br />

For peppers, the factor limiting the shelf life is dehydration<br />

of the fruit, where PLA and PP behave similarly, followed by<br />

the degradation of the stem and crown, where PLA shows a<br />

positive influence. Shelf life is therefore limited to 8-9 days<br />

for both packaging solutions. However, given the same age,<br />

peppers wrapped in PLA show a better stem.<br />

The next target on Taghleef Industries’ agenda is to make<br />

a similar test on washed and cut fresh produce, another<br />

growing application where PLA could play a role. Given the<br />

very short shelf life of such products (normally no longer than<br />

4-7 days), even 1-2 days extension would help considerably.<br />

www.ti-films.com<br />

www.eosta.com<br />

www.bio4pack.com<br />

Figure 1: Crown and Stem Index<br />

6.0<br />

Crown and stem index, [0-5]<br />

Firmness index, [02]<br />

Time, [day]<br />

Figure 3: Stem Index<br />

Stem index, [1-9]<br />

5.0<br />

4.0<br />

3.0<br />

2.0<br />

1.0<br />

0<br />

0 2 4 6 8 10 12 14<br />

Time, [Days]<br />

Figure 2: Firmness Index<br />

5.0<br />

4.5<br />

4.0<br />

3.5<br />

3.0<br />

2.5<br />

2.0<br />

1.5<br />

1.0<br />

0.5<br />

0<br />

0 2 4 6 8 10 12 14<br />

3.50<br />

3.00<br />

2.50<br />

2.00<br />

1.50<br />

1.00<br />

0.50<br />

0 2 4 6 8 10 12 14<br />

Time, [Days]<br />

PLA<br />

PP<br />

Ref.<br />

PLA<br />

PP<br />

Ref.<br />

PLA<br />

PP<br />

Ref.<br />

bioplastics MAGAZINE [06/11] Vol. 6 19


Films|Flexibles|Bags<br />

New Applications for<br />

BoPLA films<br />

Biaxially oriented PLA films are widely used on flexible<br />

packaging applications, as alternative to oil-based<br />

films like PE, PET, PP. Taghleef industries, in cooperation<br />

with various converters, is looking beyond traditional<br />

packaging, to explore new opportunities for its NATIVIA<br />

range of BoPLA (bi-axially oriented) films. Here’s a few examples:<br />

Adhesive tapes go green<br />

Logotape — a German manufacturer from Harrislee of<br />

specialty adhesive tapes, has developed ‘Bio tape’, a biobased<br />

alternative to traditional PP or PET products.<br />

The environmental advantages of PLA combined with these<br />

innovative and eco friendly tapes will help saving resources<br />

and minimize carbon footprint, without compromising on<br />

performance and processability vs traditional oil-based<br />

materials, thanks to the excellent mechanical properties<br />

of BoPLA films. Logotape is developing tapes that offer<br />

compostability of the film as well as the glue according to<br />

EN 13432.<br />

The PLA adhesive tapes are fully compatible with the paper<br />

and carton recycling process, can be printed and are available<br />

in white as well as transparent or brown.<br />

Bio-based and compostable self-adhesive<br />

labels<br />

Self adhesive labels are normally made of paper or films<br />

(PP, PE or PET), or a combination of these. They are an<br />

excellent, flexible, simple and cost-effective solution to<br />

provide information and appeal to the products, but in case<br />

of compostable packaging, traditional labels can be an issue.<br />

Bio4life from Bleiswijk, The Netherlands, has developed<br />

a self adhesive label made of Nativia BoPLA films, which<br />

allows all those brand owners who already use compostable<br />

packaging to label their product without the risk of breaching<br />

the norms on compostability. The BoPLA labels are coated<br />

with a compostable permanent adhesive, so that the complete<br />

labels are certified by DIN Certco according to EN 13432. The<br />

potential applications for such labels are numerous, like for<br />

example the tiny labels applied on fruits (apples, oranges,<br />

bananas…): same appeal and moisture resistance of oilbased<br />

plastics, but compostable altogether!<br />

20 bioplastics MAGAZINE [06/11] Vol. 6


group<br />

Let’s twist again<br />

Constantia Topepal, a leading packaging manufacturer in<br />

Spain, has developed a bio-based twist wrap material using<br />

a high gloss PLA film.<br />

This film can be used for candy, pralines, chocolate, and<br />

combines the excellent twist performance and appeal of a<br />

metalized film, with the environmental advantages of PLA.<br />

Nativia twist films have already been tested with excellent<br />

results on ACMA GD and Carle Montanari twist wrap<br />

machines<br />

bioplastics MAGAZINE & BoPLA films:<br />

perfect combination<br />

This issue of the bioplastics magazine (just like the last two<br />

issues) comes to the subscribers wrapped in a transparent<br />

bag made by Maropack and printed by SFV Verpackungen.<br />

This is the first commercial application of Nativia in the<br />

magazine market. In this<br />

case it’s a pre-made bag<br />

with adhesive strip, but tests<br />

performed in cooperation<br />

with SITMA, the world leader<br />

in printed media distribution<br />

systems have confirmed that<br />

the same films can be used on<br />

high speed automatic reel-fed<br />

wrapping machinery.<br />

www.ti–films.com<br />

www.logotape.de/<br />

www.compostiket.com<br />

www.constantia-tobepal.com<br />

High Quality Film Production:<br />

Efficiency, Productivity, Flexibility<br />

High uptime, throughput<br />

and raw material efficiency<br />

Fast product changes<br />

Easy operation and low<br />

maintenance<br />

Reduced manpower and<br />

energy consumption<br />

Excellent film quality<br />

www.brueckner.com<br />

bioplastics MAGAZINE [06/11] Vol. 6 21


Opinion<br />

The Future of the<br />

Shopping Bag in Italy<br />

Are newly developed, biodegradable and<br />

compostable polymers the ideal solution?<br />

By<br />

Stefano Facco<br />

New Business Development Director<br />

Novamont SpA<br />

Novara, Italy<br />

Currently we are facing a quite chaotic debate about the ideal<br />

solution for the incredible amount of disposable shopping<br />

bags used by consumers today. Recycling, environmental<br />

impact, re-use, littering and especially marine litter are<br />

some of the main keywords arising when this important topic is<br />

discussed.<br />

Some facts related to the use of such bags are quite impressive.<br />

In Italy, some 300 bags per year per capita are used, which<br />

corresponds roughly to 25% of the total European consumption,<br />

and corresponding to 100 billion units. About 2/3 of these products<br />

are imported from countries such as China, Indonesia or Thailand,<br />

where many of them are being produced under conditions which<br />

are not allowed in Europe. This creates an unfair competitive<br />

advantage. The recycling quota of post-consumer shopping bags<br />

is below 1% on a world-wide level, albeit in some countries the<br />

collection rate is much higher, but not all collected bags end up<br />

in recycling.<br />

At this point, I feel that beside the environmental discussion<br />

about raw materials and products, we should strongly bear<br />

in mind the fact that right now the plastic converting industry,<br />

especially the European companies producing bags and sacks,<br />

are not facing easy times. The competing converters, mainly<br />

located in the Asia/Pacific area, quite often accept commercial<br />

conditions which may be described as dumping conditions (on<br />

an EU level, only a few years ago, some anti-dumping measures<br />

were taken). Especially in the southern European region, where<br />

most of the European production was located, more and more<br />

medium and small size companies are struggling to survive.<br />

Taking these aspects into account, it really may be considered<br />

a natural reaction to somehow strengthen again our European<br />

industry by converting new families of polymers (also produced in<br />

the EU) locally. A fair competition would arise again, and the basis<br />

for a healthy economic growth.<br />

Furthermore, the use of renewable resources combined with<br />

the property of being B&C (biodegradable and compostable)<br />

would, in addition to the aspects related to the growth of local<br />

companies, help us to better deal with the scarcity of fossil raw<br />

materials and to add new end-of-life options such as the organic<br />

recycling of polymers.<br />

22 bioplastics MAGAZINE [06/11] Vol. 6


Films|Flexibles|Bags<br />

The new Italian decree, which came in force on January 1 st ,<br />

2011, imposing the use of B&C shopping bags, somehow<br />

perfectly supported the three major aspects I have described<br />

above: the strengthening of local or European enterprises,<br />

the use of renewable resources (as most of the polymers<br />

available on the market do contain a significant amount of<br />

renewable raw materials (RRMs)) and their compostability,<br />

which finally offers an end-of-life option which may help<br />

the Italian composting industry to get rid of some of the<br />

100,000 tonnes of plastic film pollutants sieved out during<br />

the composting process itself.<br />

The incredible speed with which major Italian B&C polymer<br />

producers (such as Novamont) and other European groups<br />

(such as BASF) were able to increase production capacity has<br />

enabled most of the traditional shopping bag converters to<br />

switch to these new materials in order to satisfy the growing<br />

market request. Due to the high technological level of these<br />

materials, the production switch was immediately carried out<br />

without loss of time and without additional investment.<br />

Major groups such as Matrica (ENI/Novamont JV),<br />

Roquette, Cereplast and other companies started, or<br />

have announced, huge investments in the production of<br />

monomers, intermediates and polymers based on RRMs or<br />

in compounding facilities. Therefore, the coming into force<br />

of this new decree not only boosted once more the optimism<br />

of local converters, but it also helped to attract huge<br />

investments in future-oriented technologies such as fully<br />

integrated biorefineries.<br />

Briefly summarizing the positive outcome of the new<br />

situation that we are experiencing in Italy, we may affirm<br />

that the composting industry is easily able to handle the<br />

increase and treatment of the new compostable shopping<br />

bags. Retailers have reduced consumption of shopping<br />

bags in general by 30% to 50%, which may be considered<br />

environmentally beneficial, converters are again increasing<br />

their production and replacing partially imported products,<br />

and new industrial investments have proven that investors<br />

believe firmly in the future of these new technologies.<br />

www.novamont.com<br />

bioplastics MAGAZINE [06/11] Vol. 6 23


Films|Flexibles|Bags<br />

Mulch Film<br />

Certified<br />

Novamont, Novara, Italy recently received the first certificate guaranteeing<br />

ecological quality of the Technical Resources for Organic and Sustainable<br />

Agriculture from ICEA for its mulching film in biodegradable<br />

Mater-Bi ® .<br />

ICEA, the Ethical and Environmental Certification Institute from Bologna, Italy,<br />

inspects and certifies firms respectful for the environment, workers‘ dignity<br />

and collective rights. With more than 300 experts inspecting over 13 thousand<br />

firms from 20 branches in various countries, ICEA is one of the most prominent<br />

inspection and certification bodies in the field of sustainable development.<br />

The institute has launched a specific certification scheme for the<br />

environmental performance of technical resources for organic and sustainable<br />

agriculture. Their main objective is to evaluate and reward the ability of technical<br />

resources in helping create a more sustainable agricultural system to improve<br />

the chemical, physical and biological characteristics of the land, as well as to<br />

reduce external water requirements. The regulations also aim to reduce the<br />

risk of the contamination and pollution of waters and soil caused by agricultural<br />

inputs and to obtain agricultural products free from chemical residues. ICEA<br />

certification is therefore intended to enhance and guarantee ecological quality<br />

requirements that go beyond the minimum requirements of current legislation;<br />

it is not intended to replace the authorisations currently required by the law.<br />

In order to certify the agricultural mulching film made from Mater-Bi,<br />

ICEA examined factors such as the composition and characteristics of the<br />

end product, the nature and origin of the raw materials used, the production<br />

process for the raw materials (Mater-Bi granulate) employed by Novamont, the<br />

manufacture of the end product (Mater-Bi film) and the end-of-life scenario.<br />

For Mater-Bi agricultural mulching film the Institute considered the<br />

fundamental aspects and characteristics of its application and end-oflife<br />

(considering the aspects under Technical Report CEN/TR 15822 for<br />

biodegradable plastics in or on soil, and (Italian) UNI standard 11183 which<br />

defines the requirements and test methods for biodegradable plastic materials<br />

at room temperature); aerobic biodegradation in the soil at the end of the crop<br />

cycle; the environmental safety of the product in terms of the release and<br />

dissemination of contaminants into the soil and eco-toxic effects in the soil<br />

after degradation.<br />

bioplastics MAGAZINE will have a closer look into mulch films in general in one<br />

of the coming issues — stay tuned… MT<br />

www.novamont.com<br />

www.icea.info<br />

24 bioplastics MAGAZINE [06/11] Vol. 6


Challenging Convention<br />

Biodegradability with exceptional<br />

seal integrity<br />

Renewable and high barrier<br />

Coloured and compostable<br />

Even higher performance<br />

achieved when combined with<br />

other biopolymers<br />

Variety of ‘end-of-life’ options<br />

www.NatureFlex.com<br />

use our imagination...


Films|Flexibles|Bags<br />

Biopolymer Coatings for<br />

Sustainable Packaging<br />

By Klaus Noller<br />

Head of Material Development Department<br />

Fraunhofer-Institut für<br />

Verfahrenstechnik und Verpackung IVV<br />

Freising, Germany<br />

Whey powder (picture: ttz Bremerhaven)<br />

The Fraunhofer Institute for Process Engineering and Packaging<br />

IVV, Freising, Germany, has developed a packaging<br />

film having a barrier layer made of whey protein. This novel<br />

packaging film was developed as part of the EU funded „Wheylayer“<br />

project. Large quantities of whey arise during cheese manufacture<br />

and whey also contains antimicrobial substances which<br />

prolong the shelf-life of foods. The work of the Fraunhofer IVV<br />

involved optimizing the barrier properties to oxygen and water vapor<br />

and also the antimicrobial effect of the coating. In order to do<br />

this, very pure protein isolates were recovered from the whey. The<br />

film-forming properties of proteins from sweet and sour whey<br />

were optimized by chemical modification. The result was innovative<br />

protein formulations having a high barrier effect and excellent<br />

adhesion and resistance to mechanical stress. This means there<br />

is no longer a need to use synthetic barrier polymers to coat conventional<br />

packaging materials - these can be replaced by the new<br />

biopolymer made of whey protein. This reduces CO 2<br />

emissions<br />

and lowers the usage of material resources for production. The<br />

ability to subsequently dissolve the whey layer means that properly<br />

sorted recycling of the plastic film is possible. The multilayer<br />

film was manufactured using a patented roll-to-roll method. This<br />

processing method is a key precondition for fulfilling commercial<br />

criteria. The products and processes that have thus far been developed<br />

on a laboratory and pilot plant scale will be transferred to<br />

an industrial scale this year before the end of the project, meaning<br />

that the new whey layer material will soon be able to be used<br />

in the packaging sector.<br />

The Fraunhofer IVV is also developing coatings from renewable<br />

raw materials for paper which can be used, for example, for<br />

beverage packaging. The BioPaperCoating project, funded by the<br />

Federation of Industrial Research Associations (AiF), is developing<br />

biocoatings for paper and processes for their manufacture.<br />

The aim is to produce biocoatings on paper, paperboard, and<br />

cardboard for use as packaging for solid and liquid foods. These<br />

new packaging materials will replace the currently used plastics<br />

based on fossil raw materials, and especially polyethylene,<br />

in laminated packaging systems. The systems are based on<br />

compatible blends of polylactic acids and polyhydroxyalkanoates<br />

which combine the benefits of the individual components. At the<br />

Fraunhofer IVV the formulations are being tested for coating<br />

at near-industrial coating rates and are being optimized in<br />

collaboration with Fraunhofer UMSICHT. Other functionalities<br />

such as an extra co-extruded layer are also being added to the<br />

material system.<br />

26 bioplastics MAGAZINE [06/11] Vol. 6


Films|Flexibles|Bags<br />

The FlexPakRenew project, which is being funded under the<br />

7 th Framework Programme of the EU, is developing novel flexible<br />

papers with multilayer structures (50 to 90 g/m²) made entirely of<br />

renewable raw materials for food and non-food applications. The<br />

multilayer structures in combination with the latest developments<br />

in nanotechnology and surface coating allow barrier properties to<br />

be achieved that are equivalent to traditional plastic laminates and<br />

composites having medium and high barriers. Low permeability to<br />

water vapour and oxygen and to fats and flavours is the goal. The<br />

environmentally friendly manufacturing process and optimized<br />

recyclability or biodegradability of the material means that the<br />

emission of greenhouse gases is reduced. The Fraunhofer IVV<br />

is undertaking advanced development of the process of vacuum<br />

coating with SiOx and Al 2<br />

O 3<br />

in order to optimize the water vapour<br />

and oxygen barriers of the coated papers.<br />

www.ivv.fraunhofer.de<br />

OTR at 23°C and 50% RH (cm 3 / m 2 d bar)<br />

10000<br />

1000<br />

100<br />

10<br />

1<br />

0,1<br />

PE-HD PP<br />

BOPP<br />

COC<br />

PE-LD<br />

PVC-P<br />

PS<br />

PC<br />

0,01 | | | | | |<br />

0,01 0,1 1 10 100 1000<br />

PLA<br />

PVC-U<br />

PET<br />

PA 6<br />

PAN<br />

PEN<br />

Wheylayer<br />

PVDC<br />

EVOH, 44%<br />

EVOH, 38%<br />

EVOH, 32%<br />

(LCP)<br />

EVOH, 27%<br />

WVTR at 23°C; 85% RH (g/m 2 d)<br />

Oxygan and Water Vapour Transmission rate<br />

Cellulose<br />

bioplastics MAGAZINE [06/11] Vol. 6 27


Opinion<br />

‘Bagislation‘ in Europe<br />

Italy‘s bag ban challenges the (bio-) plastics industry<br />

Analysed by<br />

Harald Kaeb<br />

narocon InnovationConsulting<br />

Berlin, Germany<br />

Fig. 1: The negative consequences of<br />

littering triggered and heated up ‘bagislation‘<br />

Italy does it, Spain has planned it, the European Commission is<br />

considering it: the banning of non-biodegradable single-use<br />

carrier bags has become a ‘battlefield‘ of product legislation in<br />

Europe. For the first time ever legal regulation could exert a huge<br />

impact on the market and the development of technology for bioplastics<br />

in Europe. For manufacturers of biodegradable plastic<br />

resin Italy became the ‘promised land‘ and a magic blueprint for<br />

so-called ‘bagislation’ in Europe and abroad. However, the battlefield<br />

is peppered with strong incumbents, diverse interests, sustainability<br />

constraints, waste management obligations and, last but<br />

not least, a complex political and legal landscape. Italy‘s ban triggered<br />

a public debate and further action: EU authorities put it under<br />

scrutiny and they now are evaluating how to reduce the consumption<br />

of, and littering by, bags. In the past a bag ban was considered<br />

non-compliant with EU Directives - from a legal point nothing has<br />

changed since then. But as the political perception most likely has<br />

changed, will Italy‘s bag ban now be allowed? What are the arguments?<br />

Which ones are really convincing and practicable? I have<br />

been analysing this market and the relevant policies for years. This<br />

article provides a first assessment of the situation with focus on<br />

motives and actions. The author also points out the risks that the<br />

protagonists need to be aware of.<br />

Dealing with littering issues<br />

Most likely there is no other plastic product which is under so<br />

much (legal) pressure as the plastic bag today. A vigorous discussion<br />

about littering and over-consumption has led to measures aimed at<br />

a far-reaching reduction of single-use bags around the globe. From<br />

Bangladesh to China, from Tanzania to the Philippines – it seems<br />

that every country on this planet has introduced bans or regulations,<br />

or is at least discussing the subject. Google reveals 1.2 million<br />

results (searching ‘carrier bag ban’) and three million pictures<br />

(searching ‘bag littering’) - all within one second. The photograph of<br />

a turtle with a remnant of blue plastic film in its mouth has become<br />

the accusatory symbol against plastic bags.<br />

The damage caused by littering heated up the debate and gave it a<br />

spin towards biodegradability as a proposed solution. This used to be<br />

a forbidden ‘No-Go-Area’ for many good reasons: If the bioplastics<br />

industry were to advertise in this way, it would not take long for<br />

studies to prove the opposite: biodegradable and compostable bags<br />

floating in the sea, eaten by animals, wrapped around branches on<br />

trees, piling up on the ground and NOT biodegrading. It would be a<br />

disaster. A great opportunity to fuel ‘anti-bioplastics’ PR campaigns<br />

and damaging the whole concept of biodegradable and compostable<br />

plastics. Whatever the plastic product and material type, littering<br />

is anti-social behaviour which must not be encouraged by “it just<br />

disappears!” adverts. Only oxo-additive producers and users go that<br />

way and they are failing to build a market in Europe.<br />

28 bioplastics MAGAZINE [06/11] Vol. 6


Films|Flexibles|Bags<br />

Putting a price on carrier bags brings double<br />

benefits<br />

Most experts agree that the best way to fight littering is give a<br />

value to bags. The easiest way is to charge for them – no bags for<br />

free anymore! Many European food supermarkets charge for bags: A<br />

typical 50 µm (micron) loop handle PE bag is priced at 0.10 to 0.20 €<br />

(Bio-PE bags marketed at 0.15 to 0.25 €). Despite carrying a price of<br />

0.20 to 0.40 € compostable plastic bags are successfully introduced<br />

in more and more EU markets where no bans are in place. Their<br />

market share reaches up to 25% in German or Austrian grocery<br />

stores. The concept of selling bags and keeping a high margin has<br />

become a strong trend in Europe. When adding a price the stores<br />

often switch from free-of-charge 15 to 25 µm thin-gauge PE bags to<br />

40 to 50 µm bags. With a lot of benefits: the added weight prevents<br />

bags from blowing in the wind, the added performance (more kg<br />

loading capacity) turns the single-use bag into a reusable bag (used<br />

between 4 to 7 times, studies say). The number of bags per capita<br />

would drop from hundreds to a few dozen, or from more than two<br />

kilogrammes to less than one.<br />

This effect is a perfect contribution to the waste prevention goal<br />

which stands at the top of the EU waste hierarchy. Just by charging<br />

significantly for a bag the result is lower consumption and less<br />

littering. This concept is favoured by most of the food retailers. If<br />

it is objected to, then politicians are eager to enforce it: the Irish<br />

bag tax was a consequence of the objection of British retail stores<br />

to reducing the number of bags. The levy of 0.15 € per bag led to a<br />

90% reduction. In the UK Prime Minister Cameron recently warned<br />

the British retail sector to reduce bags - or taxation will be applied.<br />

He was not pleased with the weak results of a voluntary retail<br />

commitment. It seems it is only a matter of time until all carrier<br />

bags in the European food retail sector will be charged. Retailers<br />

love money and avoiding taxes.<br />

National and EU bag policies<br />

In 2005 the French government banned single-use carrier bags<br />

with the exception of biodegradable and compostable bags. This<br />

first attempt at a legal ban was not targeting littering, France had<br />

no big issues with it. The idea of the ‘Grenelle de l‘Environnement’<br />

was just to promote new outlets for feedstocks from French<br />

agriculture. Biodegradable and biobased bioplastics were regarded<br />

as an opportunity for French farmers and companies. Legislation<br />

was promoted despite the fact that there is little infrastructure for<br />

collecting bio-waste and composting in France. Whilst the European<br />

Commission (EC) blocked the enforcement of the French law the<br />

Italian one successfully came into force. u<br />

Fig 2: Lightweight bags blowing in the wind – they<br />

are much more of a litter problem than heavier ones<br />

(Photo: Kaeb)<br />

Fig. 3: Compostable bags conquer markets despite<br />

higher prices - even if ‘non-regulated’ (Photo: BASF)<br />

bioplastics MAGAZINE [06/11] Vol. 6 29


Opinion<br />

Fig. 4: Bags for fruits and vegetable are not included in<br />

bagislation. It is the perfect bio-waste bag (Photo: Kaeb)<br />

Both laws breach the principles of the European Packaging<br />

and Packaging Waste Directive and the EU trading and<br />

competition rules. However between 2005 and 2011 the public<br />

perception of bags has changed. Over the last two years<br />

television programmes, news and articles, and even movies,<br />

criticised overconsumption and its contribution to littering.<br />

Therefore, the EC did not directly react with a rejection of the<br />

Italian ban but with a public consultation. By August 15,000<br />

answers had arrived to questions that covered “the need for<br />

reduction, possible measures such as levies and bans, the<br />

need for differentiation between biodegradable and nonbiodegradable<br />

bags, EN 13432 standard and labelling issues“<br />

and more. DG Environment Commissioner Potocnik, who is<br />

currently responsible, is running an impact assessment on<br />

possible measures. As he made clear in his 2011 statements,<br />

the EC very likely will develop harmonised Europe-wide<br />

measures to reduce carrier bags and their environmental<br />

impact.<br />

The first reaction of the EU plastics industry to the Italian<br />

ban was, like the French case, heavy lobbying against a<br />

severe market distortion. But as the EC signalled “we will<br />

regulate bags“ the strategy changed and was turned into a<br />

self-regulation approach. In October 2011 European plastics<br />

industry organisations presented to the EU Commission<br />

an alternative to regulatory measures on plastic carrier<br />

bags. The draft proposal involves the whole value chain and<br />

has the objective of working towards more sustainable use<br />

of the plastic carrier bag in Europe by promoting reusable<br />

bags, avoiding bags being given for free and the use of more<br />

renewable and recycled materials in the production of new<br />

plastic carrier bags. While self-regulation is being discussed<br />

in the value chain Spain has come up with legislation similar<br />

to Italy. In a staged approach all single-use bags will be<br />

banned from 2018 onwards unless they are biodegradable<br />

and compostable according to EN 13432.<br />

The importance of waste management and<br />

recycling<br />

The very solid and valid argument for compostable<br />

shopping bags is that they will help to collect more bio-waste,<br />

e.g. food and garden waste. Diverting such waste from landfill<br />

or other recycling schemes is a significant contribution to<br />

better waste management and more efficient recycling. The<br />

precondition is to have established organic waste collection<br />

and recycling schemes. However, in many regions, e.g. in<br />

Southern and Eastern Europe, in France or the UK this<br />

infrastructure is hardly developed. The legal promotion of<br />

biodegradable bags occurs in countries where, at least in<br />

wider regions, composting is not well established (Southern<br />

Italy, Spain). There are huge differences when regarding<br />

the situation in EU countries. The consumption pattern is<br />

differing significantly from member state to member state.<br />

This includes the type of bag, the film gauge and the number<br />

of bags used, which is widely varying. For example in central<br />

and northern Europe, e.g. Germany, Denmark or Austria,<br />

carrier bags are rarely given away for free – resulting in<br />

low numbers of consumption. What is more, the available<br />

regional waste management and recycling infrastructure is<br />

ranging from ‘almost nothing in place’ to ‘far developed for all<br />

types of waste’. For PE carrier bags - the dominant product<br />

on the market - specific sorting and recycling schemes were<br />

developed and are working well in some EU countries. Any<br />

policy against PE bags would be a policy against recycling.<br />

Rather vigorous and negative debates earlier sensibilised the<br />

European bioplastics industry to the fact that the recycling of<br />

conventional plastics is an issue: when bioplastics interfere<br />

in a negative way with this view then a confrontation with the<br />

recyclers can be expected. As recycling is a strong pillar of<br />

the European sustainability and resource efficiency policies<br />

the end-of-life attributes will play a major role in future EU<br />

bagislation.<br />

30 bioplastics MAGAZINE [06/11] Vol. 6


Films|Flexibles|Bags<br />

Fig. 5: Bio-based PE bags are well recyclable and eco-efficient –<br />

but discriminated in Italy (Photo: Zabel / European Bioplastics)<br />

Environmental performance will be<br />

scrutinized<br />

This holds also true for the environmental performance<br />

of carrier bags which is building another corner stone when<br />

evaluating the concepts and designing the ‘most wanted’<br />

products. The available LCA results comparing different types<br />

of carrier bags concur, i.e. reusable and recyclable bags have a<br />

very good environmental profile. The less material is used for<br />

a bag of a certain load capacity, the more often it is reused and<br />

recycled, and the better will be the profile. Biobased PE bags<br />

from sugar cane perform very well according to this measure.<br />

However, as these are non-biodegradable bioplastics they<br />

suffer from the existing bag bans. Biodegradable plastics<br />

today yield rather low LCA credits from organic recycling<br />

compared to mechanical recycling. They would benefit from<br />

a calculation of the indirect (secondary) effect when diverting<br />

food waste from landfill or keeping recycling streams clean.<br />

This, however, is difficult to quantify.<br />

Many questions remain open<br />

There are many questions to be answered to find the best<br />

‘bag solution’ serving the needs of the environment and the<br />

businesses involved. Depending on the region and purpose<br />

of application different types of bags will be favoured.<br />

Biodegradable bags are no solution to littering but are great<br />

products for organic waste recovery. Biobased PE bags<br />

perfectly fit to the established plastic recycling schemes.<br />

In all regulations the scope and the definition of the bags<br />

concerned is a huge challenge: What is single-use, what<br />

is reusable, what is a bag for life? In the Italian or Spanish<br />

legislation single-use plastic bags are not exactly defined. It<br />

is known that very thin plastic t-shirt bags are used only once<br />

before ending up as waste bags, while loop-handle or griphole<br />

bags are used several times. Is there a maximum film<br />

gauge separating single-use from reusable?<br />

Only very good and very solid arguments covering littering,<br />

waste management and proof of sustainability will allow us<br />

to justify measures that have a strong impact on the market.<br />

Bans violate EU law and are most often being regarded as a<br />

too strong in terms of market distortion - even by industry<br />

organisations like European Bioplastics. Targets for bag<br />

reduction or taxes on specific bags might be more acceptable<br />

alternatives. A voluntary branch agreement and selfregulation<br />

can be an alternative to legislation if it achieves<br />

the same results for reaching the objectives in a smarter way.<br />

Charging for bags at a reasonable price seems to be a smart<br />

and effective measure.<br />

In Europe it can be expected that the process of sorting<br />

out the options will be systematic and sound. The bioplastics<br />

industry has very good arguments to get a good share of<br />

the 750,000 tonne market for plastic carrier bags. National,<br />

sectorial or even company related interests however most<br />

likely will not be good enough to develop or defend regulations<br />

that are not in line with the principles of legislation, sustainable<br />

development or competition. NGOs and those who see their<br />

stakes at risk most likely will take care for unredeemed<br />

promises and proclaim their findings in the media.<br />

www.narocon.com<br />

bioplastics MAGAZINE [06/11] Vol. 6 31


Films|Flexibles|Bags<br />

A lightweight coffee pouch made from<br />

renewable resources using NatureFlex<br />

from Innovia Films.<br />

Renewable<br />

Lightweight<br />

Coffee Pouches<br />

Today metal cans, glass jars and rigid plastic containers<br />

dominate instant coffee packaging, all of which are recyclable<br />

but none are made from renewable resources or offer<br />

compostability.<br />

The move to conventional flexible packaging began some<br />

time ago for many premium gourmet makers of ground<br />

coffee and coffee beans with some every day instant coffee<br />

brands mirroring this trend. Many of these lightweight packs<br />

are stand-up bags or pouches with some using vacuum<br />

packed blocks.<br />

Innovia Films, a leading innovator in filmic solutions for<br />

packaging, has developed a range of cellulose-based films<br />

that when laminated together with other bio materials, can<br />

provide a fully renewable filmic structure suitable for coffee<br />

pouches – NatureFlex.<br />

“Coffee producers are moving towards packaging which<br />

weighs less to save on transportation costs in the supply<br />

chain and to lower the product’s carbon footprint,” expressed<br />

Innovia Films Neil Banerjee, Market Developer – Cello.<br />

He continued “NatureFlex films offer a viable alternative to<br />

coffee producers who want a complete packaging structure<br />

that is lightweight and able to not only protect their product<br />

but at the same time is also compostable and made from<br />

renewable resources. This is the real point of differentiation<br />

for NatureFlex as existing laminate structures for lightweight<br />

coffee packaging can be difficult to dispose of except through<br />

landfill, whereas NatureFlex can be composted.”<br />

Typical comparison of conventional versus NatureFlex film<br />

structures:<br />

Existing Structure<br />

Flexible packaging for the roast and ground coffee and<br />

coffee bean market typically consists of a laminate structure<br />

made up of three layers:<br />

1. A reverse printed outer layer: 20μm BOPP (biaxially<br />

oriented PP) or 12μm PET<br />

2. A high barrier middle layer: 6-10μm Aluminium foil<br />

or 12μm metallised PET<br />

3. An inner sealant layer: 50-90μm Polyethylene<br />

The NatureFlex Solution<br />

Innovia’s NatureFlex films can be combined with other<br />

biopolymers by a converter, to produce a renewable<br />

alternative to the above structure.<br />

The comparison properties are highlighted in the graph<br />

below:<br />

Thickness / µm<br />

100<br />

90<br />

80<br />

70<br />

60<br />

50<br />

40<br />

30<br />

20<br />

10<br />

PET, 12 µm<br />

Aluminium Foil, 7 µm<br />

Polyethylene, 60µm<br />

NatureFlex 20N<br />

Printable, transparent barrier<br />

NatureFlex 20N921M<br />

Metallised high barrier layer<br />

Bio-Polymer sealant layer<br />

High seal strength and integrity<br />

PET, 12 µm<br />

Metallised<br />

Polyester, 12 µm<br />

Polyethylene, 60µm<br />

Clear<br />

NatureFlex NK,<br />

20 µm<br />

Metallised<br />

NatureFlex,<br />

20 µm<br />

Biopolymer<br />

Sealant,<br />

50 µm<br />

0 Standard Packaging 1 Standard Packaging 2 NatureFlex based<br />

Bio-Laminate<br />

NatureFlex films comply with standards for compostable<br />

packaging, including EN13432, AS4736 and ASTM D6400.<br />

Depending on the individual films selected, the finished<br />

laminate structure could be certified compostable to the<br />

same standards subject to appropriate ink, print design and<br />

adhesive choices. If required, the pouches can be vented or a<br />

fully compostable zip closure could be added.<br />

Neil Banerjee explained “We are happy to work with coffee<br />

manufacturers to ensure that they get the right laminate<br />

structure to protect their product all they need to do is<br />

contact us.”<br />

www.innoviafilms.com<br />

32 bioplastics MAGAZINE [06/11] Vol. 6


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Application News<br />

New Laminate<br />

Centroplast Spa from Meldola, Italy has a long and robust<br />

story in producing flexible packaging for the food industry.<br />

They are conscious of the importance to offer a sustainable<br />

packaging, with a significant reduction of the environmental<br />

impact, to food end-users.<br />

This is the reason why Centroplast, since years, has been<br />

searching solutions with a lower environmental impact.<br />

Now Centroplast is presenting to the market a new type<br />

of compostable packaging, satisfying different packaging<br />

requirements to achieve the same shelf life properties for the<br />

packed goods. However, compared with standard solutions<br />

no special settings on the production lines are required.<br />

This packaging has been developed using films<br />

compostable according to the EN 13432 standard.<br />

Regarding this project the R&D Manager Stefania<br />

Milandri explained that the development was carried out in<br />

collaboration with the main suppliers of raw materials and<br />

films. This led to a two layer laminate with high mechanical<br />

properties and excellent machinability in complex<br />

applications.<br />

The outer layer of consists of Ingeo PLA. It is laminated<br />

using a special adhesive to an inner layer which itself is<br />

coextruded from two different materials. This coextruded<br />

layer combines again PLA with a ‘new bioplastics’ derived<br />

from starch. More details were not disclosed at this time due<br />

to a proprietary recipe. This layer, however, gives the laminate<br />

a very good sealing strength, so that the packaging can hold<br />

even heavy products, such as rice and dried food.<br />

The adhesive used to laminate the two layers is completely<br />

compostable, providing at the same time a perfect bonding<br />

between the layers.<br />

In addition to the above mentioned compostable laminate,<br />

Centroplast has developed another laminate made out<br />

of paper with metalized poly-lactic acid for other food<br />

applications. MT<br />

www.centroplast.it<br />

Eco-Labels for<br />

Biobottles<br />

As a result of the extensive research in the field of<br />

environmental sustainability, Goglio Cofibox S.p.A.,<br />

leader in the production of flexible laminates for the<br />

packaging of food products from Cadorago, Italy has<br />

developed a new eco-friendly label in PLA for its client<br />

Fonti di Vinadio SpA. The label is being applied on<br />

Sant’Anna PLA bottles, the first eco-friendly bottles that<br />

biodegrade within 80 days.<br />

The label has been developed to work with the reel<br />

fed technology, the most common one in the beverage<br />

market thanks to its high speed labeling, and it is<br />

suitable for all common standard gluing systems. Labels<br />

are available in thickness starting from 30µm.<br />

Furthermore, the transparency of the film is highly<br />

appreciated in the mineral water market, since it<br />

guarantees perfect clarity in the see through graphics in<br />

a mono-web structure.<br />

The PLA resin used for the label, Ingeo by<br />

NatureWorks, assures excellent film performances<br />

even on those equipment which up to today have used<br />

‘traditional’ materials.<br />

In addition to this, Goglio Cofibox has developed<br />

exclusive bio inks to be used for printings on eco-friendly<br />

materials which, thanks to the Company’s 10-colors<br />

print rotogravure technology, allow to manufacture<br />

tailor-made, eye-catching printing effects on 100% green<br />

labels. The inks are certified compostable by Vinçotte<br />

and do of course not contain any toxic substances or<br />

heavy metals.<br />

This is one more example of Goglio Group’s flexible<br />

innovations towards environmentally friendly products.<br />

MT<br />

www.gogliocofibox.com<br />

34 bioplastics MAGAZINE [06/11] Vol. 6


Application News<br />

Hoses Made from Biobased<br />

Raw Materials<br />

NORRES Schlauchtechnik from Gelsenkirchen, Germany<br />

is a leading manufacturer of industrial hoses, hose systems<br />

and other innovative, high-performance plastic products.<br />

The company has formulated a corporate sustainability<br />

strategy which specifies that all Norres products should<br />

be developed according to certain basic principles. One of<br />

these principles is that defined hose types should be made<br />

from bio-based raw material sources.<br />

Norres has a number of hose types that are either<br />

manufactured from a ‘bioplastic’ raw material as standard<br />

or can be supplied as variants made from raw materials<br />

based on derivatives. Castor oil is a typical example of the<br />

derivatives used for this purpose. The share of the bioplastic<br />

in each product is in the region of 20 to 50%, depending<br />

on the hardness and the nature of the synthetic material.<br />

The mechanical properties and chemical resistances of<br />

bioplastic raw materials are not significantly different from<br />

those of the standard Norres types, and they represent<br />

an altogether competitive option. Moreover, several<br />

Norres hoses are made using raw materials with a low<br />

environmental impact based on the life cycle assessment<br />

(LCA), in other words with a good ecobalance. The focus<br />

is on bioplastic monomers derived from renewable raw<br />

materials for polyesters, polyamides, polyurethanes and<br />

vinyl polymers. Hoses produced using these materials are<br />

offered as an alternative to the standard products. The<br />

Protapw ® PUR 335 MHF FLAT, Airduc ® PUR 350 MHF and<br />

Airduc ® PUR 355 are among the hose types. MT<br />

www.norres.com<br />

Biodegradable Bags<br />

for Home Compost<br />

Concern about the environment ranks high on Flexico’s<br />

R&D agenda. Always keen to contribute to a better world<br />

and curb waste, Flexico is adding new biodegradable bags<br />

for home compost to its Biopryl range, which already<br />

includes biodegradable bags for industrial compost. The<br />

Flexico group is a French company created in 1950 with five<br />

production sites and six subsidiaries in France Germany,<br />

UK, Spain, Italy, Switzerland, Romania.<br />

Benefits for the community are twofold: with this<br />

biodegradation system, packaging can be collected together<br />

with the green waste by the community and turned into<br />

compost. At home, the end user, can place the packaging<br />

in their home compost together with other organic waste.<br />

The biodegradable Biopryl bags for home compost are<br />

made of compostable films, using renewable material<br />

(such as starch and vegetable oils) and biodegradable<br />

co-polyesters, all complying with standard EN 13432 and<br />

authenticated ‘OK Home Compost’ by Laboratory Vinçotte.<br />

No genetically modified plants (GMO) are being used for the<br />

production.<br />

Home Compost biodegradable Biopryl bags are produced<br />

with or without a drawstring closure. They are particularly<br />

useful as packaging for bioproducts such as cotton, but also<br />

for textile, fresh produce, and cosmetics. Biopryl bags offer<br />

a high water vapour transmission rate but a good barrier<br />

against oxygen. This means moisture can escape faster,<br />

fresh produce is less susceptible to mold and to oxidation<br />

and stay fresh for a longer period of time. MT<br />

www.flexico.fr<br />

36 bioplastics MAGAZINE [06/11] Vol. 6


Joint Approach<br />

Innovia Films, Cumbria, UK and Sappi Fine Paper<br />

Europe, Brussels, Belgium have joined forces to<br />

demonstrate potential laminate structures, using their<br />

respective products, suitable for end users in the food,<br />

confectionery and pharmaceutical industries. These<br />

laminates provide technical functionality in addition<br />

to being made from renewable resources and offering<br />

compostability – a focus which many packaging end<br />

users are keen to pursue.<br />

Both companies recognise that the best end-of-life<br />

options for flexible paper/film laminates are either<br />

industrial, home composting or ultimately anaerobic<br />

digestion which turns waste into a useful energy source,<br />

compared to current landfill or incineration solutions.<br />

Innovia Films with its NatureFlex product range,<br />

brings its unique expertise in manufacturing renewable<br />

and compostable cellulose-based films with tailored<br />

moisture and barrier properties.<br />

Sappi brings its expertise in manufacturing flexible<br />

packaging papers and now offers coated and uncoated<br />

compostable paper options; Algro ® Nature is a unique<br />

compostable one side coated paper; Leine ® Nature is an<br />

uncoated equivalent, which is also compostable.<br />

The Sappi and Innovia products have been<br />

independently tested and have received the ‘OK<br />

Compost Home’ certification by Vinçotte, and also the<br />

compostability DIN E13432 certification by DIN CERTCO.<br />

Innovia Films and Sappi have now started trials with<br />

converters to demonstrate the capabilities of such<br />

laminates in terms of sustainability and technical<br />

packaging solutions. Trials have been made on both<br />

extrusion and adhesive laminate systems, targeting<br />

end users who are seeking alternatives to existing noncompostable<br />

structures.<br />

John Fell, Global Marketing Director for Innovia<br />

Films commented “Both companies are committed to<br />

evolving this joint partnership and will announce future<br />

developments of sustainable packaging solution, based<br />

on renewable and recyclable forest products, as and<br />

when they become available.”<br />

Shaping the future<br />

of biobased plastics<br />

www.purac.com/bioplastics<br />

www.innoviafilms.com<br />

www.sappi.com<br />

Laminate pack<br />

structure<br />

(used here for<br />

packaging dried soup)<br />

bioplastics MAGAZINE [06/11] Vol. 6 37


Consumer Electronics<br />

Bioplastic Mouse added<br />

to Green Line<br />

Fujitsu is extending their portfolio of ’Green IT TM ’ products.<br />

The KBPC PX ECO keyboard with bioplastic components<br />

has been available for quite some time already.<br />

bioplastics MAGAZINE reported about it in its issues on 03/2010<br />

and 05/2010. Earlier this year, Fujitsu Technology Solutions<br />

GmbH from Munich, Germany, a subsidiary of the Japanese<br />

Fujitsu Limited, added an optical USB mouse to their Green IT<br />

line of products. “The environmentally friendly keyboard was<br />

and still is quite successful in the market so it was only a<br />

logical step to introduce a mouse,” said Christian Sandmeier,<br />

Senior Product Manager Accessories of Fujitsu.<br />

Like the keyboard, the optical USB mouse M440 with a<br />

resolution of 1000 dpi features a housing and 3 keys made<br />

of BIOGRADE ® C 7500, a cellulose acetate compound from<br />

FKuR in Willich, Germany. The 100% biodegradable material<br />

is predominantly composed of natural resource materials<br />

and completely recyclable. In addition, the mouse features<br />

halogen free circuit boards along with a PVC free cable.<br />

“One of the many advantages of using Biograde was the<br />

fact that existing injection moulding tools could be used,”<br />

explained Christoph Lohr, injection moulding expert working<br />

in the department of Applications Technology at FKuR. Thus,<br />

the existing manufacturer could produce the mouse without<br />

any problems. All necessary requirements for electronic<br />

devices, which include computer equipment, could be fulfilled<br />

(e.g. fire tests). In Germany, a special glow wire test is required<br />

whereas in other countries the UL94HB flammability test has<br />

to be met. All of these tests were passed without adding any<br />

special flame retardant additives. A colour masterbatch with<br />

a biobased carrier allows the colourisation of the mouse at<br />

a very high quality. The black version of the mouse can be<br />

laser-marked, also without the need for any additives.<br />

In addition to its ergonomic design for right and left handed<br />

users, due to the special properties of Biograde the haptic<br />

appearance of the mouse is very pleasant. This is quite<br />

important, as many users spend hours and hours with their<br />

hands in direct contact to the mouse, a fact that must not be<br />

neglected. Also, Biograde offers a ‘self-polishing’ effect, as<br />

Christoph Lohr explained. This means that small dents and<br />

scratches will disappear after a while, simply by touching<br />

and using it. The Swedish computer magazine ‘PC för Alla’<br />

tested the mouse and certified its robustness: “The mouse<br />

is as durable, hard-wearing and robust as other mice made<br />

from hard plastics”.<br />

With a reduction of oil based plastics of about 66 tonnes per<br />

year the ‘green’ mouse obviously is the best companion for<br />

the ‘green’ keyboard, as stated on Fujitsu’s website.<br />

Beside the environmental benefits, quality design<br />

and superior performance what’s the best benefit to the<br />

consumer? Both the keyboard and mouse are sold at a retail<br />

price comparable to ‘conventional‘ products.<br />

www.fujitsu.com<br />

www.fkur.com<br />

Our cover kitty cat Olivia<br />

likes ‘organic food‘ ...<br />

Her comment: „Miaouw“<br />

38 bioplastics MAGAZINE [06/11] Vol. 6


Polylactic Acid<br />

Uhde Inventa-Fischer has expanded its product portfolio to include the innovative stateof-the-art<br />

PLAneo ® process. The feedstock for our PLA process is lactic acid, which can<br />

be produced from local agricultural products containing starch or sugar.<br />

The application range of PLA is similar to that of polymers based on fossil resources as<br />

its physical properties can be tailored to meet packaging, textile and other requirements.<br />

Think. Invest. Earn.<br />

Uhde Inventa-Fischer GmbH<br />

Holzhauser Strasse 157–159<br />

13509 Berlin<br />

Germany<br />

Tel. +49 30 43 567 5<br />

Fax +49 30 43 567 699<br />

Uhde Inventa-Fischer AG<br />

Via Innovativa 31<br />

7013 Domat/Ems<br />

Switzerland<br />

Tel. +41 81 632 63 11<br />

Fax +41 81 632 74 03<br />

marketing@uhde-inventa-fi scher.com<br />

www.uhde-inventa-fi scher.com<br />

Uhde Inventa-Fischer


Report<br />

Polylactic acid is a<br />

polymer which is made of<br />

renewable raw materials<br />

and is available in<br />

the market on an<br />

industrial scale.<br />

(Photo: ecopuls)<br />

Bioplastics in Practical Use<br />

A project by the Austrian Plastics Cluster<br />

providesexperience with PLA<br />

This article is an excerpt from a comprehensive report<br />

of the Austrian Plastics Cluster.<br />

Bioplastics: From the Lab to the<br />

Product Shelves<br />

An EU project led by the St. Pölten office of the Austrian<br />

plastics cluster has developed practical knowledge in the<br />

use of bioplastics which has been further extended thanks<br />

to the participation of numerous industry partners.<br />

A number of food producing companies process products<br />

from organic farms. They could improve the sustainability of<br />

their overall product if the films that are used for packaging<br />

were also made from renewable raw materials. Within<br />

a CORNET project (COllective Research NETwork), from<br />

1998 to 2001, practical knowledge in this subject has been<br />

developed, and now many companies benefit from it.<br />

Initiated by ecoplus, the business agency of Lower<br />

Austria and supported by the government of Lower Austria<br />

an application was submitted for financial support. Eleven<br />

institutes from six European countries, as well as a large<br />

number of company partners (20 from Austria alone),<br />

finally came together to pursue the common goal. “We<br />

want to learn how to deal with bioplastics,” says Alexander<br />

Komenda, who managed the entire project for the plastics<br />

cluster. The participating companies invest in the project, but<br />

each Euro from an Austrian company has been quadrupled<br />

by the Austrian Research Promotion Agency FFG. Overall<br />

the project volume totals 1.6 million Euros.<br />

In addition, the project was limited to material already<br />

available in the market and produced on a significant scale.<br />

Another definition set the benchmark for the project even<br />

higher, namely that any material used, including additives,<br />

must be biodegradable.<br />

Everyone Does What He Does Best<br />

Based on this general framework, the participants<br />

started to develop a project structure. Each of the countries<br />

involved, together with the respective scientific partner, took<br />

the lead in a different field.<br />

The experts in materials selection came from France,<br />

with the ‘Institut National des Sciences Appliquées’. It<br />

was important to take into account a series of physical<br />

properties which are essential to the processability and the<br />

practical use of bioplastics. Different applications require<br />

permeability or barrier towards certain gases, others need<br />

resistance to temperatures exceeding 60°C.<br />

The German ‘Institute for Polymers’ (DKI) was in charge<br />

of testing the raw materials. At the beginning it had to be<br />

decided whether standard test procedures for conventional<br />

plastics were applicable to bioplastics. Some methods had to<br />

be adapted to the special characteristics of the biopolymer.<br />

However, the results of these tests were necessary to<br />

characterise the materials to be used for the subsequent<br />

project phases. As Komenda says, “All participants were<br />

given large amounts of the same material in order to<br />

achieve comparable results.”<br />

The Slovenian ‘Tool & Die Development Center’ took the<br />

lead in processing the bioplastics on machines which are<br />

commonly used in the production of packaging, in close<br />

cooperation with the industry partners<br />

40 bioplastics MAGAZINE [06/11] Vol. 6


The Polish institute ‘Cobro’ coordinated the tests of<br />

the new packaging materials in order to identify their<br />

behaviour under particular stress situations (e.g. bumping<br />

and banging during transport in trucks). Experts from the<br />

Austrian Research Institute for Chemistry and Technology<br />

(OFI) examined whether the packaging material made of<br />

polylactic acid (PLA) meets the special requirements of the<br />

food sector.<br />

Finally, ‘Celabor’ from Belgium was in charge of testing<br />

thermoformed plastic films from the waste-management<br />

end of the supply chain, as well as life-cycle analysis. This<br />

is a hot issue, as the ecological balance is one of the main<br />

arguments for the use of bioplastics.<br />

The challenge was to develop a transparent, easily<br />

adaptable report, which would withstand technical<br />

discussions and allow an emotional discussion to be seen<br />

from a more objective point of view. One option was to<br />

clearly identify certain measurable parameters such as the<br />

portion of carbon from renewable raw materials, which can<br />

be determined by radiocarbon dating.<br />

Application Food Packaging<br />

Now a stage has been reached where the raw material,<br />

PLA, can be characterised regarding its processability as<br />

a packaging material. It is known that it will be difficult to<br />

<br />

improve diffusion barriers without moving on to multilayer<br />

<br />

systems. It is known on which parameters temperature<br />

<br />

stability depends. It is known how to design production<br />

<br />

processes in order to obtain a usable product. In addition,<br />

<br />

knowledge has been distributed among the participating<br />

companies. “Ultimately it is important to create a product <br />

which a company can sell. Then the companies will need <br />

people to manufacture the product and we from the cluster<br />

will have done a good job,” Komenda summarises. It is<br />

exactly to this objective that the cooperation with the food<br />

cluster is committed.<br />

PLA – Properties of the Material and How<br />

to Improve Them<br />

PLA is available in different qualities in the market.<br />

A specific task of the CORNET project dealt with the<br />

properties of the materials and developed the basis for<br />

their improvement with suitable additives, guided by INSA<br />

Lyon. u<br />

Photo: ecoplus<br />

bioplastics MAGAZINE [06/11] Vol. 6 41


Report<br />

Photo: ecoplus<br />

Methods of Material - Characterisation for PLA<br />

The properties of PLA depend on its molecular structure. One of the<br />

task groups has developed methods which enable an accurate and reliable<br />

characterisation of this structure, guided by DKI-Darmstadt.<br />

Processing of PLA<br />

Learning to use a new type of plastic primarily means learning to process<br />

it. This task group conducted extensive tests on the processing of PLA,<br />

using different procedures and various different products. In this process a<br />

number of surprising discoveries were made!<br />

What was particularly fascinating about this task was the gradual gain<br />

in knowledge about the properties of the biopolymer, not least because<br />

its producers, the bacteria, do not disclose all of their secrets of chirality.<br />

A generally noticeable feature were the substantial differences between<br />

the various commercial types, which were seen above all in different<br />

molar mass distributions and represented significant differences in the<br />

applicability of the products. Extreme examples, in which PLA could be<br />

processed at 300°C without showing any noteworthy degradation reactions,<br />

are countered by cases in which discolouration became visible even under<br />

normal conditions.<br />

Testing Products Made of PLA<br />

Packaging products made of PLA have to meet the same requirements<br />

as packaging made from conventional plastics. Generally PLA can be<br />

processed without problems. However, processing, like additives, can have<br />

a significant influence on whether a future packaging development will<br />

meet the desired requirements. For example all processors have to find<br />

out whether drying of the raw material is necessary or not. Runners or<br />

gates for example cannot simply be re-used. The presence of expiry dates<br />

on PLA granulates and products will take some getting used to for plastics<br />

processors. But that’s how ‘bio’ works!<br />

PLA in Contact with Food<br />

One of the CORNET project’s topics was the use of PLA packaging in<br />

the food industry. A work group within the project examined whether PLA<br />

meets all of the requirements regarding contact with food, guided by OFI<br />

Vienna.<br />

PLA packaging appears to be particularly suitable for high-price and niche<br />

segments, such as organic products with a limited shelf life or fermented<br />

dairy products. Future research projects could analyse the influence of<br />

special additives and the combination with other biodegradable materials<br />

in greater detail.<br />

(Photo: Naku)<br />

a.komenda@ecoplus.at<br />

The Life Cycle of PLA<br />

When products made from PLA reach the end of their useful life various<br />

questions arise: How is the material disposed of? Can it be composted?<br />

Does PLA have an advantage over conventional plastics throughout its entire<br />

life cycle? This part of the project was guided by CELABOR of Belgium.<br />

To summarise in frank terms: There is the green advantage, but it’s not<br />

as big as it seems.<br />

Biopolymers will guide us to a green future, but it will be only one part of<br />

a general and massive change. The most important part is the human being<br />

himself and his wealth. MT<br />

The complete report can be downloaded from www.bio-packing.at<br />

42 bioplastics MAGAZINE [06/11] Vol. 6


Opinion<br />

Agricultural Resources<br />

for Bioplastics<br />

Feedstock for bio-based plastics today and tomorrow<br />

By<br />

Michael Carus<br />

CEO nova-Institute<br />

Achim Raschka<br />

biotech expert at the<br />

nova-Institute<br />

Hürth, Germany<br />

1 st and 2 nd generation crops: Pros and cons<br />

To produce bio-based plastics there is a broad spectrum of feedstock options. Today biobased<br />

plastics are mainly based on sugar, starch, plant oil and natural rubber, the so-called<br />

first generation feedstock. Because of potential competition with food and animal feed<br />

politicians and scientists have introduced, in the last ten years, the idea of using lignocellulose<br />

feedstock by transforming it into fermentable sugar (whether this will have less impact on<br />

food security will be discussed below). Lignocellulose means wood, short rotation coppice<br />

such as poplar, willow or miscanthus, or lignocellulose containing agricultural by-products.<br />

Another option is to use by-products which contain sugar and starch.<br />

The following table shows the pros and cons for different feedstock options:<br />

Criteria<br />

Yield per hectare in terms of<br />

fermentable sugar equivalents<br />

Green House Gas Emissions for<br />

biomass derived Bio-based Plastics<br />

(cradle to factory gate)<br />

First Generation<br />

(Sugar, Starch, Oil,<br />

Natural Rubber)<br />

Second Generation<br />

(Lignocellulose – Wood and<br />

Short Rotation Coppice)<br />

Broad range, but more or less on the same level<br />

Broad range, but more or less on the same level<br />

Technical maturity Very high Still a lot to do<br />

Economically competitive<br />

Secure supply with raw materials<br />

at a reasonable price<br />

Not yet (except for specific<br />

properties)<br />

Competing for food, animal<br />

feed and bioenergy<br />

Not yet<br />

Competition with bioenergy<br />

and traditional industrial<br />

material use<br />

By-products from<br />

agriculture and forestry<br />

If the by-products have no markets<br />

yet, this means an extra yield<br />

Very low, because of the<br />

methodology of LCA<br />

Depending on the content<br />

of the by-product<br />

Not yet, but close<br />

Still a huge potential for<br />

inefficiently used by-products, or<br />

even those not used at all<br />

Direct competition with food and feed Yes No No<br />

Indirect competition to food and feed Yes – on land use No<br />

Emergency reserve for food and feed Yes No No<br />

Feedstock for Bio-based<br />

Plastics and Composites<br />

(source: nova-Institute)<br />

Second Generation<br />

Lignocellulose<br />

Saccharification<br />

First Generation<br />

Sugar Starch Plant Oil<br />

Natural<br />

Rubber<br />

feedstock<br />

Natural<br />

Fibres<br />

Wood<br />

Timber<br />

Byproducts<br />

Lignin<br />

Wood Plastics<br />

Composites<br />

for example<br />

bagasse<br />

Natural Fibres<br />

Reinforced<br />

Plastics<br />

Compressionmoulded<br />

parts<br />

Biobased Plastics<br />

thermoplastics or thermosets<br />

biodegradable or permanent<br />

Elastomers<br />

biomaterials<br />

Carbon Fibre<br />

44 bioplastics MAGAZINE [06/11] Vol. 6


Opinion<br />

The table shows in a clear way that there is no easy answer.<br />

Are second generation feedstocks really a better solution?<br />

To answer this question on a solid scientific base nova will<br />

conduct a multi-client study in 2012/2013: What is the best<br />

sustainable feedstock to generate fermentable sugar?<br />

Interested companies and associations can still join the<br />

advisory board.<br />

Non-food discussion<br />

Forced by the public discussion during the food crisis in<br />

2008 politics and industry gave a very simple answer to the<br />

potential food versus industry conflict: Industry should only<br />

use non-food crops as feedstock.<br />

From our point of view the question of food versus non-food<br />

crops for industry is itself oversimplified and misleading. The<br />

real questions and conflict are different:<br />

• Question 1: Are there - in the EU, in the member states<br />

or in the region – free agricultural areas left, which are<br />

not necessary for food and animal feed, domestic use and<br />

export? If yes (and in many regions the answer is yes),<br />

continue:<br />

• Question 2 (the real question): How can we use these free<br />

areas for industry with the highest resource efficiency and<br />

the highest climate protection?<br />

• In many cases food crops will best fulfil these criteria -<br />

just because they have been specially cultivated to produce<br />

maximum yields over many, many years and all logistics<br />

are established.<br />

• Food crops for industry can also serve as an emergency<br />

reserve for food and feed supply – second generation<br />

lignocellulose cannot! This is exactly what is happening<br />

this year in Brazil. The Brazilian government has reduced<br />

the bioethanol fuel quota to save sugar for the demanding<br />

food and feed market.<br />

So ‘No food crops for industry’ can lead to a misallocation<br />

of agriculture resources. We need a comprehensive concept<br />

for feedstock for food, feed, industrial material use and<br />

bioenergy.<br />

The amount of land needed to grow<br />

feedstock for bio-based plastics -<br />

How much is needed, and how much will<br />

be needed in the future?<br />

Both answers to the above questions show how the<br />

agricultural area is used today. Most of the arable land is<br />

used for animal feed (69%), followed by food (17%), material<br />

use (7%, including bio-based plastics) and finally bioenergy<br />

(3.5%). The data on biomass in tonnes look slightly different<br />

and the main reasons are different yields per hectare<br />

for different crops, dedicated to certain applications. For<br />

example cotton, the leading crop for industrial material use,<br />

has considerably lower yields than most of the energy crops.<br />

Using the recent data from Prof. Endres (FH Hannover)<br />

and European Bioplastics, today (2010) about 724,000 tonnes<br />

of bio-based plastics are produced, and this will increase to<br />

1.71 million tonnes by 2015. According to a rough average<br />

estimation 2.5 tonnes of bio-based plastics can be produced<br />

per hectare and per year. This means that crops for bio-based<br />

plastics were grown on 290,000 hectares (0.02% of global<br />

arable land) in 2010 and will be grown on 684,000 hectares<br />

(0.05%) in 2015.<br />

To substitute all 250 million tonnes of plastics in the world<br />

with bio-based plastics will demand 100 million hectares<br />

or 7% of the global arable land. This will only happen when<br />

crude oil is really scarce and very expensive. Then solar<br />

and wind energy will also be taking over the energy sector,<br />

including bioenergy, so these arable areas will be set free for<br />

bio-based chemicals and plastics.<br />

Global land use for food production and renewable resources 2008<br />

(source: nova-Institute)<br />

Use of harvested agricultural biomass worldwide (2008)<br />

(source: nova-Institute)<br />

Total land area<br />

world wide<br />

13.4 bn. ha<br />

cities, residental area,<br />

0.2<br />

road and rail<br />

Arable land<br />

world wide<br />

5.0 bn. ha<br />

Cropland<br />

world wide<br />

1,500 mn. ha<br />

Total biomass ca.<br />

10 billion tonnes<br />

Biomass for<br />

industrial material<br />

use 4,3 %<br />

Biomass for energy<br />

use 3,7 %<br />

waste land (deserts,<br />

mountains, ...)<br />

4.3<br />

3.55<br />

pastures<br />

260<br />

Food<br />

18 %<br />

Food<br />

forest<br />

3.9<br />

1.030<br />

Feed<br />

agricultural<br />

area<br />

5.0<br />

1.45<br />

cropland<br />

today<br />

55<br />

100<br />

Bioenergy<br />

Material use<br />

74 %<br />

Feed<br />

in bn. ha<br />

in bn. ha<br />

in mn. ha<br />

Allocation of biomass to production target (main product).<br />

Respective amounts include raw materials and by products,<br />

even if their use fall into a different category.<br />

bioplastics MAGAZINE [06/11] Vol. 6 45


Opinion<br />

Is there enough land for food, animal feed,<br />

bioenergy and industrial material use,<br />

including bio-based plastics?<br />

Due to increasing demand for food and animal feed, and<br />

also bioenergy and industrial material use, the crucial<br />

question is how to increase the biomass production – in<br />

a sustainable way. But how to increase the agricultural<br />

feedstock worldwide?<br />

1. Increasing the yields<br />

The tremendous potential for increasing yields in the<br />

developing countries is hindered by lack of technology and<br />

infrastructure, unfavourable agricultural policies such as<br />

no access to credits, an insufficient transmission of price<br />

incentives, poorly enforced land rights.<br />

2. Expansion of arable land<br />

Some 0.6 (nova 2008) to 1.6 billion (FAO 2009) hectares<br />

could be added to the current 1.4 billion hectares of crop<br />

land (excluding forests, urban areas, protected areas). The<br />

figure shows that even in the year 2020 more than 200<br />

million hectares of free arable land will be available.<br />

The solution to points 1 and 2 are: Political reforms and<br />

huge investment in agro-technologies. Compared to these<br />

potentials, the impact of GMO on the increase of biomass<br />

production will stay low.<br />

On the other hand there is also a huge potential for saving<br />

biomass:<br />

• To switch from meat to vegetarian food would set free a<br />

huge amount of arable land for other uses. To get proteins<br />

from cattle demands 40 to 50 times the biomass input<br />

compared with proteins obtained from wheat or soya.<br />

• To reduce food losses will also set free huge amounts of<br />

arable land: The results of a recent study showed that<br />

roughly one-third of food produced for human consumption<br />

is lost or wasted globally, which amounts to about 1.3 billion<br />

tonnes per year.<br />

• Finally solar energy, which will be fully competitive in 10 to<br />

15 years, is 40 to 50 times more land efficient compared<br />

with bioenergy (and biofuels) and also will mainly use non<br />

arable land. This will also release huge areas of arable<br />

land, today used by bioenergy.<br />

So the conclusion is, yes, there is enough feedstock – but<br />

… due to the results of different nova studies, there will be<br />

only enough feedstock for industrial material use including<br />

bio-based plastics, if:<br />

• we are able to activate strongly the potentially free areas<br />

(0.6 – 1.6 billion hectares) for agriculture and to increase<br />

the productivity in developing countries - that means huge<br />

investment and political reforms,<br />

• we switch to more vegetarian food and also reduce losses<br />

in the food chain,<br />

• we switch from bioenergy to solar and wind energy and<br />

significantly increase the use of solar and wind energy,<br />

• we establish a new policy for equal support of bioenergy<br />

and industrial material use based on their efficiency,<br />

GHG reduction/hectare and employment/hectare (‘level<br />

playing field’ – for more information please look at<br />

www.bio-based.eu/policy/en).<br />

Otherwise ‘Food & Feed First’, high subsidies for bioenergy<br />

and increasing population and meat consumption could<br />

mean: No feedstock left for high-volume industrial material<br />

use, bio-based chemistry and bio-based plastics.<br />

Summary<br />

In principle there are sufficient and sustainable biomass<br />

resources available for food, animal feed, bioenergy and<br />

industrial material use, including bio-based plastics but<br />

we should change and optimize the biomass allocation and<br />

therefore the political framework. And we should invest in<br />

agriculture, and, not forgetting political reforms in the rural<br />

areas of the world, optimizing our food habits to sustainability<br />

and switching from bioenergy to solar energy – to secure a<br />

sufficient and sustainable supply of biomass for bio-based<br />

products also for the next 100 years and further.<br />

www.nova-institute.eu<br />

Available<br />

rainfed<br />

arable land<br />

(cropland)*<br />

3.300<br />

100<br />

Residential area;<br />

road and rail (ca. 3%)<br />

1.500<br />

Cropland<br />

today<br />

800<br />

Potential<br />

forest land<br />

570<br />

‘Free’ agricultural area in 2006 and the global demand of area 2020<br />

(source: nova-Institute)<br />

‘Free’<br />

agricultural<br />

area in<br />

2006**<br />

570<br />

year 2006 year 2020<br />

The global demand on land use in 2020:<br />

➊ Increasing demand of food per capita due to an<br />

increase in purchasing power (more meat, ...)<br />

➋ Increasing demand of food due to<br />

population growth<br />

➌ Residential area, road and rail<br />

➍ Biofuel in the most important Biofuel countries***<br />

ca. 96 mn. ha<br />

ca. 64 mn. ha<br />

ca. 32 mn. ha<br />

ca. 18 mn. ha<br />

∑ 210 mn. ha<br />

➊<br />

➋<br />

➌<br />

➍<br />

in mn. ha<br />

in mn. ha<br />

330<br />

Protected area (ca. 10%)<br />

in mn. ha<br />

* FAO 2000 indicates a potential of 4.2 bn. ha<br />

** De facto parts of the ‘free’ crop lands could be considerably disadvantageous<br />

in terms of natural recources or market access<br />

*** The calculation is based on OECD-FAO 2007: It is assured that most of the recourses are from<br />

the demand region; yield increase of 1/%a, extrapolation of production from 2006 to 2020<br />

46 bioplastics MAGAZINE [06/11] Vol. 6


BIOADIMIDE TM IN BIOPLASTICS.<br />

EXPANDING THE PERFORMANCE OF BIO-POLYESTER.<br />

2011<br />

B E S T<br />

P R A C T I C E S<br />

AWA R D<br />

Global Bioplastics Additives<br />

New Product Innovation Award<br />

Whatever is beautiful. Whatever is meaningful. Whatever brings you happiness.<br />

May it be yours this holiday season and throughout the coming year.<br />

Whatever requirements move your world:<br />

We will move them with you.<br />

www.rheinchemie.com<br />

www.bioadimide.com


Personality<br />

Photo:<br />

European<br />

Bioplastics<br />

bM: What is your educational background?<br />

JW: At the university I studied chemistry and then started<br />

to work for Henkel. I did my PhD in polymer chemistry later,<br />

whilst I was already working in the industry.<br />

bM: What is your professional function today?<br />

JW: I’m the Head of materials at the NNFCC, the UK’s<br />

National Centre for Biorenewable energy, fuels and materials.<br />

And materials here cover all renewable materials including<br />

plastics, fibres, composites, wood etc.<br />

bM: How did you ‘come to’ bioplastics?<br />

John Williams<br />

JW: I came to bioplastics when I worked in R&D on adhesives<br />

and surface coatings. In the early 1990’s I worked on a Joint<br />

Venture with Zeneca on ‘Biopol’, a PHA-resin, which indeed<br />

reached the supermarket shelves in form of a Wella shampoo<br />

bottle. That’s how I came across bioplastics and ever since I<br />

have dabbled with it.<br />

bM: When were you born?<br />

JW: I was born in September 1961 in Widnes, a<br />

small town in what was then Lancashire, in the UK.<br />

bM: Where do you live today and how long have you<br />

lived there?<br />

JW: Today I live right in the middle of the historic<br />

city of York and we moved there about 5 months ago.<br />

Before that I lived on a farm in Lincolnshire.<br />

iBIB 2012<br />

International Business Directory for Innovative<br />

Bio-based Plastics and Composites<br />

Pictures: nova-Institut, Sainsbury’s, Proganic<br />

www.bio-based.eu/iBIB<br />

Book now: www.bio-based.eu/iBIB<br />

For the 2 nd time worldwide:<br />

An entire overview of all suppliers of bio-based plastics and composites!<br />

In spring 2012 iBIB 2012 the second international directory of major suppliers of biobased<br />

plastics and composites will be published. Becoming an iBIB 2012 participant will<br />

enable you to reach about 20,000 potential industrial clients from all over the world.<br />

The print version will be distributed by the publishers and partners at trade fairs,<br />

exhibitions and conferences worldwide<br />

The PDF-version will be distributed widely by email and websides<br />

Online-database with detailed index to reach your supplier in a target oriented way<br />

iBIB 2012 : 250 pages – 100 companies, associations, R&D – 20 countries<br />

Book your page(s) now at: www.bio-based.eu/iBIB<br />

Deadline: 15 th January 2012 – Publication Date: 14 th March 2012<br />

bM: What do you consider more important: ‘biobased’ or<br />

‘biodegradable’?<br />

JW: Biobased. Biodegradability is a function of a material<br />

that you might require or you might not. Biobased is the basis<br />

for the whole bioeconomy process.<br />

bM: What has been your biggest achievement (in terms of<br />

bioplastics) so far?<br />

JW: I think it’s raising awareness of the materials, their<br />

properties, their markets and the sustainability issues and<br />

providing the context for their growth.<br />

bM: What are your biggest challenges for the future?<br />

JW: The biggest challenge, I think, is the next step. To<br />

convince the main players to more rapidly adopt more of these<br />

materials.<br />

bM: What is your family status?<br />

JW: I have two daughters, 17 and 19 years old from my first<br />

marriage. I have a new partner, Sandra and actually we are<br />

going to get married next year.<br />

bM: What is your favorite movie?<br />

I like ‘Spy Game’, with Robert Redford and Brad Pitt from<br />

2001.<br />

bM: What is your favorite book?<br />

JW: I have a lot of books on military history but my favourite<br />

fiction stories are espionage like,‘Tinker, Tailor, Soldier, Spy’. It<br />

is a British spy novel by John le Carré from the mid Seventies.<br />

bM: What is your favorite (or your next) vacation location?<br />

JW: I love to go to Turkey, but next we go to South Africa.<br />

bM: What do you eat for breakfast on a Sunday?<br />

JW: Bacon-sandwich and coffee…the bacon has to be nice<br />

and crispy!<br />

bM: What is your ‘slogan’?<br />

In cooperation with<br />

Publisher<br />

JW: One of my favourites is:<br />

“You only live once, but if you work it right, once is enough”<br />

nova-Institute GmbH | Chemiepark Knapsack | Industriestrasse 300 | D-50354 Hürth<br />

48 Dominik bioplastics Vogt MAGAZINE | Phone: [06/11] +49 (0)2233 Vol. 64814 – 49 | dominik.vogt@nova-institut.de


Basics<br />

Glossary 2.0<br />

In bioplastics MAGAZINE again and again<br />

the same expressions appear that some of our readers<br />

might (not yet) be familiar with. This glossary shall help<br />

with these terms and shall help avoid repeated explanations<br />

Bioplastics (as defined by European Bioplastics<br />

e.V.) is a term used to define two different<br />

kinds of plastics:<br />

a. Plastics based on renewable resources (the<br />

focus is the origin of the raw material used)<br />

b. → Biodegradable and compostable plastics<br />

according to EN13432 or similar standards<br />

(the focus is the compostability of the final<br />

product; biodegradable and compostable<br />

plastics can be based on renewable (biobased)<br />

and/or non-renewable (fossil) resources).<br />

Bioplastics may be<br />

- based on renewable resources and biodegradable;<br />

- based on renewable resources but not be<br />

biodegradable; and<br />

- based on fossil resources and biodegradable.<br />

Aerobic - anaerobic | aerobic = in the presence<br />

of oxygen (e.g. in composting) | anaerobic<br />

= without oxygen being present (e.g. in<br />

biogasification, anaerobic digestion)<br />

[bM 06/09]<br />

Amorphous | non-crystalline, glassy with unordered<br />

lattice<br />

Amylopectin | Polymeric branched starch<br />

molecule with very high molecular weight (biopolymer,<br />

monomer is → Glucose)<br />

[bM 05/09]<br />

Amylose | Polymeric non-branched starch<br />

molecule with high molecular weight (biopolymer,<br />

monomer is → Glucose) [bM 05/09]<br />

Biodegradable Plastics | Biodegradable<br />

Plastics are plastics that are completely assimilated<br />

by the → microorganisms present a<br />

defined environment as food for their energy.<br />

The carbon of the plastic must completely be<br />

converted into CO 2<br />

during the microbial process.<br />

For an official definition, please refer to<br />

the standards e.g. ISO or in Europe: EN 14995<br />

Plastics- Evaluation of compostability - Test<br />

scheme and specifications.<br />

[bM 02/06, bM 01/07]<br />

Blend | Mixture of plastics, polymer alloy of at<br />

least two microscopically dispersed and molecularly<br />

distributed base polymers.<br />

Bisphenol-A (BPA) | Monomer used to produce<br />

different polymers. BPA is said to cause<br />

health problems, due to the fact that is behaves<br />

like a hormone. Therefore it is banned<br />

for use in children’s products in many countries.<br />

updated<br />

such as ‘PLA (Polylactide)‘ in various articles.<br />

Readers who would like to suggest better or other explanations to be added to the list, please contact the editor.<br />

[*: bM ... refers to more comprehensive article previously published in bioplastics MAGAZINE)<br />

BPI | Biodegradable Products Institute, a notfor-profit<br />

association. Through their innovative<br />

compostable label program, BPI educates<br />

manufacturers, legislators and consumers<br />

about the importance of scientifically based<br />

standards for compostable materials which<br />

biodegrade in large composting facilities.<br />

Carbon neutral | Carbon neutral describes<br />

a product or process that has a negligible<br />

impact on total atmospheric CO 2<br />

levels. For<br />

example, carbon neutrality means that any<br />

CO 2<br />

released when a plant decomposes or<br />

is burnt is offset by an equal amount of CO 2<br />

absorbed by the plant through photosynthesis<br />

when it is growing.<br />

Catalyst | substance that enables and accelerates<br />

a chemical reaction<br />

Cellophane | Clear film on the basis of → cellulose.<br />

Cellulose | Polymeric molecule with very high<br />

molecular weight (biopolymer, monomer is<br />

→ Glucose), industrial production from wood<br />

or cotton, to manufacture paper, plastics and<br />

fibres.<br />

CEN | Comité Européen de Normalisation<br />

(European organisation for standardization)<br />

Compost | A soil conditioning material of decomposing<br />

organic matter which provides nutrients<br />

and enhances soil structure.<br />

[bM 06/08, 02/09]<br />

Compostable Plastics | Plastics that are biodegradable<br />

under ‘composting’ conditions:<br />

specified humidity, temperature, → microorganisms<br />

and timefame. Several national<br />

and international standards exist for clearer<br />

definitions, for example EN 14995 Plastics -<br />

Evaluation of compostability - Test scheme<br />

and specifications.<br />

[bM 02/06, bM 01/07]<br />

Composting | A solid waste management<br />

technique that uses natural process to convert<br />

organic materials to CO 2<br />

, water and humus<br />

through the action of → microorganisms.<br />

When talking about composting of bioplastics,<br />

usually industrial composting in a managed<br />

composting plant is meant [bM 03/07]<br />

Compound | plastic mixture from different<br />

raw materials (polymer and additives)<br />

[bM 04/10)<br />

Copolymer | Plastic composed of different<br />

monomers.<br />

Cradle-to-Gate | Describes the system<br />

boundaries of an environmental →Life Cycle<br />

Assessment (LCA) which covers all activities<br />

from the ‘cradle’ (i.e., the extraction of raw<br />

materials, agricultural activities and forestry)<br />

up to the factory gate<br />

Cradle-to-Cradle | (sometimes abbreviated<br />

as C2C): Is an expression which communicates<br />

the concept of a closed-cycle economy,<br />

in which waste is used as raw material<br />

(‘waste equals food’). Cradle-to-Cradle is not<br />

a term that is typically used in →LCA studies.<br />

Cradle-to-Grave | Describes the system<br />

boundaries of a full →Life Cycle Assessment<br />

from manufacture (‘cradle’) to use phase and<br />

disposal phase (‘grave’).<br />

Crystalline | Plastic with regularly arranged<br />

molecules in a lattice structure<br />

Density | Quotient from mass and volume of<br />

a material, also referred to as specific weight<br />

DIN | Deutsches Institut für Normung (German<br />

organisation for standardization)<br />

DIN-CERTCO | independant certifying organisation<br />

for the assessment on the conformity<br />

of bioplastics<br />

Dispersing | fine distribution of non-miscible<br />

liquids into a homogeneous, stable mixture<br />

Elastomers | rigid, but under force flexible<br />

and elastically formable plastics with rubbery<br />

properties<br />

EN 13432 | European standard for the assessment<br />

of the → compostability of plastic<br />

packaging products<br />

Energy recovery | recovery and exploitation<br />

of the energy potential in (plastic) waste for<br />

the production of electricity or heat in waste<br />

incineration pants (waste-to-energy)<br />

Enzymes | proteins that catalyze chemical<br />

reactions<br />

Ethylen | colour- and odourless gas, made<br />

e.g. from, Naphtha (petroleum) by cracking,<br />

monomer of the polymer polyethylene (PE)<br />

European Bioplastics e.V. | The industry association<br />

representing the interests of Europe’s<br />

thriving bioplastics’ industry. Founded<br />

in Germany in 1993 as IBAW, European Bioplastics<br />

today represents the interests of over<br />

70 member companies throughout the European<br />

Union. With members from the agricultural<br />

feedstock, chemical and plastics industries,<br />

as well as industrial users and recycling<br />

companies, European Bioplastics serves as<br />

both a contact platform and catalyst for advancing<br />

the aims of the growing bioplastics<br />

industry.<br />

Extrusion | process used to create plastic<br />

profiles (or sheet) of a fixed cross-section<br />

consisting of mixing, melting, homogenising<br />

and shaping of the plastic.<br />

Fermentation | Biochemical reactions controlled<br />

by → microorganisms or enyzmes (e.g.<br />

the transformation of sugar into lactic acid).<br />

FSC | Forest Stewardship Council. FSC is an<br />

independent, non-governmental, not-forprofit<br />

organization established to promote the<br />

responsible and sustainable management of<br />

the world’s forests.<br />

Gelatine | Translucent brittle solid substance,<br />

colorless or slightly yellow, nearly tasteless<br />

and odorless, extracted from the collagen inside<br />

animals‘ connective tissue.<br />

50 bioplastics MAGAZINE [06/11] Vol. 6


Basics<br />

Glucose | Monosaccharide (or simple sugar).<br />

G. is the most important carbohydrate (sugar)<br />

in biology. G. is formed by photosynthesis or<br />

hydrolyse of many carbohydrates e. g. starch.<br />

Granulate, granules | small plastic particles<br />

(3-4 millimetres), a form in which plastic is<br />

sold and fed into machines, easy to handle<br />

and dose.<br />

Humus | In agriculture, ‘humus’ is often used<br />

simply to mean mature → compost, or natural<br />

compost extracted from a forest or other<br />

spontaneous source for use to amend soil.<br />

Hydrophilic | Property: ‘water-friendly’, soluble<br />

in water or other polar solvents (e.g. used<br />

in conjunction with a plastic which is not water<br />

resistant and weather proof or that absorbs<br />

water such as Polyamide (PA).<br />

Hydrophobic | Property: ‘water-resistant’, not<br />

soluble in water (e.g. a plastic which is water<br />

resistant and weather proof, or that does not<br />

absorb any water such as Polyethylene (PE)<br />

or Polypropylene (PP).<br />

IBAW | → European Bioplastics<br />

Integral Foam | foam with a compact skin and<br />

porous core and a transition zone in between.<br />

ISO | International Organization for Standardization<br />

JBPA | Japan Bioplastics Association<br />

LCA | Life Cycle Assessment (sometimes also<br />

referred to as life cycle analysis, ecobalance,<br />

and → cradle-to-grave analysis) is the investigation<br />

and valuation of the environmental<br />

impacts of a given product or service caused.<br />

[bM 01/09]<br />

Microorganism | Living organisms of microscopic<br />

size, such as bacteria, funghi or yeast.<br />

Molecule | group of at least two atoms held<br />

together by covalent chemical bonds.<br />

Monomer | molecules that are linked by polymerization<br />

to form chains of molecules and<br />

then plastics<br />

Mulch film | Foil to cover bottom of farmland<br />

PBS | Polybutylene succinate, a 100% biodegradable<br />

polymer, made from (e.g. bio-BDO)<br />

and succinic acid, which can also be produced<br />

biobased.<br />

PC | Polycarbonate, thermoplastic polyester,<br />

petroleum based, used for e.g. baby bottles<br />

or CDs. Criticized for its BPA (→ Bisphenol-A)<br />

content.<br />

PCL | Polycaprolactone, a synthetic (fossil<br />

based), biodegradable bioplastic, e.g. used as<br />

a blend component.<br />

PE | Polyethylene, thermoplastic polymerised<br />

from ethylene. Can be made from renewable<br />

resources (sugar cane via bio-ethanol)<br />

[bM 05/10]<br />

PET | Polyethylenterephthalate, transparent<br />

polyester used for bottles and film<br />

PGA | Polyglycolic acid or Polyglycolide is a<br />

biodegradable, thermoplastic polymer and<br />

the simplest linear, aliphatic polyester. Besides<br />

ist use in the biomedical field, PGA has<br />

been introduced as a barrier resin [bM 03/09]<br />

PHA | Polyhydroxyalkanoates are linear polyesters<br />

produced in nature by bacterial fermentation<br />

of sugar or lipids. The most common<br />

type of PHA is → PHB.<br />

PHB | Polyhydroxybutyrate (better poly-3-hydroxybutyrate),<br />

is a polyhydroxyalkanoate<br />

(PHA), a polymer belonging to the polyesters<br />

class. PHB is produced by micro-organisms<br />

apparently in response to conditions of physiological<br />

stress. The polymer is primarily a<br />

product of carbon assimilation (from glucose<br />

or starch) and is employed by micro-organisms<br />

as a form of energy storage molecule to<br />

be metabolized when other common energy<br />

sources are not available. PHB has properties<br />

similar to those of PP, however it is stiffer and<br />

more brittle.<br />

PHBH | Polyhydroxy butyrate hexanoate (better<br />

poly 3-hydroxybutyrate-co-3-hydroxyhexanoate)<br />

is a polyhydroxyalkanoate (PHA),<br />

Like other biopolymers from the family of the<br />

polyhydroxyalkanoates PHBH is produced by<br />

microorganisms in the fermentation process,<br />

where it is accumulated in the microorganism’s<br />

body for nutrition. The main features of<br />

PHBH are its excellent biodegradability, combined<br />

with a high degree of hydrolysis and<br />

heat stability.<br />

[bM 03/09, 01/10, 03/11]<br />

PLA | Polylactide or Polylactic Acid (PLA) is a<br />

biodegradable, thermoplastic, linear aliphatic<br />

polyester from lactic acid. Lactic acid is made<br />

from dextrose by fermentation. Bacterial fermentation<br />

is used to produce lactic acid from<br />

corn starch, cane sugar or other sources.<br />

However, lactic acid cannot be directly polymerized<br />

to a useful product, because each polymerization<br />

reaction generates one molecule<br />

of water, the presence of which degrades the<br />

forming polymer chain to the point that only<br />

very low molecular weights are observed.<br />

Instead, lactic acid is oligomerized and then<br />

catalytically dimerized to make the cyclic lactide<br />

monomer. Although dimerization also<br />

generates water, it can be separated prior to<br />

polymerization. PLA of high molecular weight<br />

is produced from the lactide monomer by<br />

ring-opening polymerization using a catalyst.<br />

This mechanism does not generate additional<br />

water, and hence, a wide range of molecular<br />

weights are accessible.<br />

[bM 01/09]<br />

Plastics | Materials with large molecular<br />

chains of natural or fossil raw materials, produced<br />

by chemical or biochemical reactions.<br />

Renewable Resources | agricultural raw materials,<br />

which are not used as food or feed, but<br />

as raw material for industrial products or to<br />

generate energy<br />

Saccharins or carbohydrates | Saccharins or<br />

carbohydrates are name for the sugar-family.<br />

Saccharins are monomer or polymer sugar<br />

units. For example, there are known mono-,<br />

di- and polysaccharose. → glucose is a monosaccarin.<br />

They are important for the diet and<br />

produced biology in plants.<br />

Semi-finished products | plastic in form of<br />

sheet, film, rods or the like to be further processed<br />

into finshed products<br />

Sorbitol | Sugar alcohol, obtained by reduction<br />

of glucose changing the aldehyde group<br />

to an additional hydroxyl group. S. is used as<br />

a plasticiser for bioplastics based on starch.<br />

Starch | Natural polymer (carbohydrate)<br />

consisting of → amylose and → amylopectin,<br />

gained from maize, potatoes, wheat, tapioca<br />

etc. When glucose is connected to polymerchains<br />

in definite way the result (product) is<br />

called starch. Each molecule is based on 300<br />

-12000-glucose units. Depending on the connection,<br />

there are two types → amylose and →<br />

amylopectin known.<br />

[bM 05/09]<br />

Starch derivate | Starch derivates are based<br />

on the chemical structure of → starch. The<br />

chemical structure can be changed by introducing<br />

new functional groups without changing<br />

the → starch polymer. The product has<br />

different chemical qualities. Mostly the hydrophilic<br />

character is not the same.<br />

Starch-ester | One characteristic of every<br />

starch-chain is a free hydroxyl group. When<br />

every hydroxyl group is connect with ethan<br />

acid one product is starch-ester with different<br />

chemical properties.<br />

Starch propionate and starch butyrate |<br />

Starch propionate and starch butyrate can be<br />

synthesised by treating the → starch with propane<br />

or butanic acid. The product structure<br />

is still based on → starch. Every based → glucose<br />

fragment is connected with a propionate<br />

or butyrate ester group. The product is more<br />

hydrophobic than → starch.<br />

Sustainable | An attempt to provide the best<br />

outcomes for the human and natural environments<br />

both now and into the indefinite future.<br />

One of the most often cited definitions of sustainability<br />

is the one created by the Brundtland<br />

Commission, led by the former Norwegian<br />

Prime Minister Gro Harlem Brundtland.<br />

The Brundtland Commission defined sustainable<br />

development as development that ‘meets<br />

the needs of the present without compromising<br />

the ability of future generations to meet<br />

their own needs.’ Sustainability relates to the<br />

continuity of economic, social, institutional<br />

and environmental aspects of human society,<br />

as well as the non-human environment).<br />

Sustainability | (as defined by European<br />

Bioplastics e.V.) has three dimensions: economic,<br />

social and environmental. This has<br />

been known as “the triple bottom line of<br />

sustainability”. This means that sustainable<br />

development involves the simultaneous pursuit<br />

of economic prosperity, environmental<br />

protection and social equity. In other words,<br />

businesses have to expand their responsibility<br />

to include these environmental and social<br />

dimensions. Sustainability is about making<br />

products useful to markets and, at the same<br />

time, having societal benefits and lower environmental<br />

impact than the alternatives currently<br />

available. It also implies a commitment<br />

to continuous improvement that should result<br />

in a further reduction of the environmental<br />

footprint of today’s products, processes and<br />

raw materials used.<br />

Thermoplastics | Plastics which soften or<br />

melt when heated and solidify when cooled<br />

(solid at room temperature).<br />

Thermoplastic Starch | (TPS) → starch that<br />

was modified (cooked, complexed) to make it<br />

a plastic resin<br />

Thermoset | Plastics (resins) which do not<br />

soften or melt when heated. Examples are<br />

epoxy resins or unsaturated polyester resins.<br />

WPC | Wood Plastic Composite. Composite<br />

materials made of wood fiber/flour and plastics<br />

(mostly polypropylene).<br />

Yard Waste | Grass clippings, leaves, trimmings,<br />

garden residue.<br />

bioplastics MAGAZINE [06/11] Vol. 6 51


Event Calendar<br />

Event Calendar<br />

You can meet us!<br />

Please contact us in<br />

advance by e-mail.<br />

Feb. 06-08, 2012<br />

The 2012 Packaging Conference<br />

OARIA Resort at CityCenter, Las Vegas, Nevada, USA.<br />

www.thepackagingconference.com/<br />

Feb. 20-22, 2012<br />

Innovation Takes Root 2012<br />

Omni ChampionsGate Resort in Orlando, Florida, USA.<br />

www.innovationtakesroot.com<br />

Feb.28-29, 2012<br />

Solpack 1.0<br />

Munich, Germany<br />

www.solpack.de<br />

March 13-14, 2012<br />

World Biofuels Markets<br />

Rotterdam, The Netherlands<br />

www.worldbiofuelsmarkets.com<br />

March 14-15, 2012<br />

5th International Congress on Bio-based Plastics<br />

and Composites<br />

Cologne, Germany<br />

www.biowerkstoff-kongress.de<br />

March 20-22, 2012<br />

Green Polymer Chemistry<br />

Maritim Hotel, Cologne, Germany<br />

www.amiplastics.com<br />

March 27-30, 2012<br />

BioPlastek 2012<br />

Westin Arlington Gateway, Arlington, VA, USA<br />

http://bioplastek.com<br />

March 29-30, 2012<br />

Sus Pack 2012<br />

Conference on Sustainable Packaging<br />

Cologne, Germany<br />

www.suspack.eu<br />

April 1-5, 2012<br />

NPE 2012<br />

Orlando, USA<br />

www.npe.org<br />

April 18-21, 2012<br />

Chinaplas 2012<br />

Shanghai, China<br />

www.chinaplasonline.com<br />

visit bioplastics MAGAZINE<br />

at booth 58047<br />

19-20 April 2012<br />

2 nd Congress on biodegradable polymer packaging<br />

Sala Aurea, Camera di Commercio, Parma (Italy)<br />

www.biopolpack.unipr.it.<br />

23-24 April, 2012<br />

Biopolymer World Congress<br />

NH Laguna Palace Hotel, Mestre-Venice (Italy)<br />

www.biopolymerworld.com<br />

March 26-27, 2012<br />

EcoPack Systems<br />

Cologne, Germany<br />

www.ecopack-conference.com/<br />

May 8-9, 2012<br />

Bioplastics Compounding & Processing<br />

The Hilton Downtown Miami, Miami, Florida, USA<br />

www.amiplastics-na.com<br />

May 9-10, 2012<br />

5. BioKunststoffe<br />

Hannover, Germany<br />

www.hanser-tagungen.de/<br />

May 15-16, 2012<br />

2 nd PLA World Congress<br />

presented by bioplastics MAGAZINE<br />

Holiday Inn City Center, Munich Germany<br />

www.pla-world-congress.com<br />

May 16-18, 2012<br />

SPE Bioplastic Materials Conference<br />

Renaissance Seattle Hotel, Seattle, Washington USA<br />

www.4spe.org<br />

June 13-15, 2012<br />

BioPlastics: The Re-Invention of Plastics<br />

Hilton - Downtown, San Francisco, USA<br />

www.BioPlastix.com<br />

June 19-20, 2012<br />

Biobased materials<br />

WPC, Natural Fibre and other innovative<br />

Composites Congress<br />

Fellbach, near Stuttgart, Germany<br />

www.nfc-congress.com<br />

Oct. 2-4, 2012<br />

BioPlastics – The Re-Invention of Plastics<br />

Caesars Palace Hotel, Las Vegas, USA<br />

www.InnoPlastSolutions.com<br />

52 bioplastics MAGAZINE [04/11] Vol. 6


A Collaborative Biopolymers Forum<br />

for the Global Ingeo Community<br />

February 20 - 22, 2012<br />

Orlando, FL<br />

Omni Orlando Resort<br />

www.omniorlandoresort.com<br />

www.innovationtakesroot.com<br />

Global companies collaborate and share successful Ingeo <br />

products and applications at Innovation Takes Root 2012<br />

Stonyfield Farm and other major international corporations will present how<br />

they have successfully incorporated Ingeo bio-based products into their<br />

brands at the collaborative, biennial biopolymers forum.<br />

The conference will include unique presentations and exhibitions for<br />

companies actively pursuing Ingeo applications and those desiring to learn<br />

more about this growing class of biopolymers. Company representatives will<br />

also discuss how they envision sustainable practices to change business in<br />

the future.<br />

Sessions include:<br />

• Advances in Ingeo Packaging Films<br />

• Ingeo in Fibers and Non-Wovens<br />

• Expanding Ingeo Applications in<br />

Durable Products<br />

• Growth of Ingeo Lactides and<br />

Lactide Derivatives<br />

• Just added! Emerging Markets<br />

and Technologies<br />

• Driving Economics to Sustainable<br />

Commercialization<br />

• Opportunities in Food Service and<br />

Food Packaging<br />

• Legislative and Regulatory Issues<br />

Who should attend?<br />

• Academia<br />

• Brands<br />

• Editors & Journalists<br />

• Green Marketers<br />

• Packaging Professionals<br />

• Process Engineers<br />

• Product Designers<br />

• Product & Process Developers<br />

• Researchers<br />

• Retailers<br />

• Sustainability Managers<br />

Exhibitor & sponsorship<br />

opportunities available<br />

Contact: Andy Ziadi<br />

Tel. 952-562-3303 /<br />

Toll free. 855-562-3300<br />

andrea_ziadi@natureworksllc.com<br />

Innovation Takes Root 2012<br />

Let us know you’re coming on LinkedIn!<br />

Follow us on Twitter for the most up to<br />

date conference info @natureworksllc<br />

Full day seminar:<br />

The Future for Bioplastics Feedstocks<br />

by Jim Lunt & Associates<br />

Pre-conference workshop:<br />

Adhesives and Key Essentials for Laminating<br />

Biopolymer Films into Flexible Packaging<br />

Ingeo, and the Ingeo logo are trademarks or registered trademarks of NatureWorks LLC in the USA and other countries.


Suppliers Guide<br />

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Tel.: +49 2161 6884467<br />

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Stay permanently listed in the<br />

Suppliers Guide with your company<br />

logo and contact information.<br />

For only 6,– EUR per mm, per issue you<br />

can be present among top suppliers in<br />

the field of bioplastics.<br />

For Example:<br />

1. Raw Materials<br />

Showa Denko Europe GmbH<br />

Konrad-Zuse-Platz 4<br />

81829 Munich, Germany<br />

Tel.: +49 89 93996226<br />

www.showa-denko.com<br />

support@sde.de<br />

FKuR Kunststoff GmbH<br />

Siemensring 79<br />

D - 47 877 Willich<br />

Tel. +49 2154 9251-0<br />

Tel.: +49 2154 9251-51<br />

sales@fkur.com<br />

www.fkur.com<br />

PSM Bioplastic NA<br />

Chicago, USA<br />

www.psmna.com<br />

+1-630-393-0012<br />

50<br />

10<br />

60<br />

20 70<br />

30 80<br />

39<br />

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160<br />

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190<br />

200<br />

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220<br />

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250<br />

260<br />

270<br />

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Polymedia Publisher GmbH<br />

Dammer Str. 112<br />

41066 Mönchengladbach<br />

Germany<br />

Tel. +49 2161 664864<br />

Fax +49 2161 631045<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Sample Charge:<br />

39mm x 6,00 €<br />

= 234,00 € per entry/per issue<br />

Sample Charge for one year:<br />

6 issues x 234,00 EUR = 1,404.00 €<br />

The entry in our Suppliers Guide is<br />

bookable for one year (6 issues) and<br />

extends automatically if it’s not canceled<br />

three month before expiry.<br />

www.facebook.com<br />

www.issuu.com<br />

www.twitter.com<br />

www.youtube.com<br />

DuPont de Nemours International S.A.<br />

2 chemin du Pavillon<br />

1218 - Le Grand Saconnex<br />

Switzerland<br />

Tel.: +41 22 171 51 11<br />

Fax: +41 22 580 22 45<br />

plastics@dupont.com<br />

www.renewable.dupont.com<br />

www.plastics.dupont.com<br />

Zhejiang Hangzhou Xinfu<br />

Pharmaceutical Co., Ltd<br />

Tel.: +86 13809644115<br />

www.xinfupharm.com<br />

johnleung@xinfupharm.com<br />

1.1 bio based monomers<br />

PURAC division<br />

Arkelsedijk 46, P.O. Box 21<br />

4200 AA Gorinchem -<br />

The Netherlands<br />

Tel.: +31 (0)183 695 695<br />

Fax: +31 (0)183 695 604<br />

www.purac.com<br />

PLA@purac.com<br />

1.2 compounds<br />

API S.p.A.<br />

Via Dante Alighieri, 27<br />

36065 Mussolente (VI), Italy<br />

Telephone +39 0424 579711<br />

www.apiplastic.com<br />

www.apinatbio.com<br />

www.cereplast.com<br />

US:<br />

Tel: +1 310.615.1900<br />

Fax +1 310.615.9800<br />

Sales@cereplast.com<br />

Europe:<br />

Tel: +49 1763 2131899<br />

weckey@cereplast.com<br />

Kingfa Sci. & Tech. Co., Ltd.<br />

Gaotang Industrial Zone, Tianhe,<br />

Guangzhou, P.R.China.<br />

Tel: +86 (0)20 87215915<br />

Fax: +86 (0)20 87037111<br />

info@ecopond.com.cn<br />

www.ecopond.com.cn<br />

FLEX-262/162 Biodegradable<br />

Blown Film Resin!<br />

Natur-Tec ® - Northern Technologies<br />

4201 Woodland Road<br />

Circle Pines, MN 55014 USA<br />

Tel. +1 763.225.6600<br />

Fax +1 763.225.6645<br />

info@natur-tec.com<br />

www.natur-tec.com<br />

Transmare Compounding B.V.<br />

Ringweg 7, 6045 JL<br />

Roermond, The Netherlands<br />

Tel. +31 475 345 900<br />

Fax +31 475 345 910<br />

info@transmare.nl<br />

www.compounding.nl<br />

1.3 PLA<br />

Shenzhen Brightchina Ind. Co;Ltd<br />

www.brightcn.net<br />

www.esun.en.alibaba.com<br />

bright@brightcn.net<br />

Tel: +86-755-2603 1978<br />

1.4 starch-based bioplastics<br />

Limagrain Céréales Ingrédients<br />

ZAC „Les Portes de Riom“ - BP 173<br />

63204 Riom Cedex - France<br />

Tel. +33 (0)4 73 67 17 00<br />

Fax +33 (0)4 73 67 17 10<br />

www.biolice.com<br />

Jean-Pierre Le Flanchec<br />

3 rue Scheffer<br />

75116 Paris cedex, France<br />

Tel: +33 (0)1 53 65 23 00<br />

Fax: +33 (0)1 53 65 81 99<br />

biosphere@biosphere.eu<br />

www.biosphere.eu<br />

Grace Biotech Corporation<br />

Tel: +886-3-598-6496<br />

No. 91, Guangfu N. Rd., Hsinchu<br />

Industrial Park,Hukou Township,<br />

Hsinchu County 30351, Taiwan<br />

sales@grace-bio.com.tw<br />

www.grace-bio.com.tw<br />

1.5 PHA<br />

Division of A&O FilmPAC Ltd<br />

7 Osier Way, Warrington Road<br />

GB-Olney/Bucks.<br />

MK46 5FP<br />

Tel.: +44 1234 714 477<br />

Fax: +44 1234 713 221<br />

sales@aandofilmpac.com<br />

www.bioresins.eu<br />

Telles, Metabolix – ADM joint venture<br />

650 Suffolk Street, Suite 100<br />

Lowell, MA 01854 USA<br />

Tel. +1-97 85 13 18 00<br />

Fax +1-97 85 13 18 86<br />

www.mirelplastics.com<br />

Tianan Biologic<br />

No. 68 Dagang 6th Rd,<br />

Beilun, Ningbo, China, 315800<br />

Tel. +86-57 48 68 62 50 2<br />

Fax +86-57 48 68 77 98 0<br />

enquiry@tianan-enmat.com<br />

www.tianan-enmat.com<br />

54 bioplastics MAGAZINE [06/11] Vol. 6


Suppliers Guide<br />

2. Additives/Secondary raw materials<br />

4. Bioplastics products<br />

Arkema Inc.<br />

Functional Additives-Biostrength<br />

900 First Avenue<br />

King of Prussia, PA/USA 19406<br />

Contact: Connie Lo,<br />

Commercial Development Mgr.<br />

Tel: 610.878.6931<br />

connie.lo@arkema.com<br />

www.impactmodifiers.com<br />

Sukano AG<br />

Chaltenbodenstrasse 23<br />

CH-8834 Schindellegi<br />

Tel. +41 44 787 57 77<br />

Fax +41 44 787 57 78<br />

www.sukano.com<br />

3. Semi finished products<br />

3.1 films<br />

Taghleef Industries SpA, Italy<br />

Via E. Fermi, 46<br />

33058 San Giorgio di Nogaro (UD)<br />

Contact Frank Ernst<br />

Tel. +49 2402 7096989<br />

Mobile +49 160 4756573<br />

frank.ernst@ti-films.com<br />

www.ti-films.com<br />

alesco GmbH & Co. KG<br />

Schönthaler Str. 55-59<br />

D-52379 Langerwehe<br />

Sales Germany: +49 2423 402 110<br />

Sales Belgium: +32 9 2260 165<br />

Sales Netherlands: +31 20 5037 710<br />

info@alesco.net | www.alesco.net<br />

3.1.1 cellulose based films<br />

The HallStar Company<br />

120 S. Riverside Plaza, Ste. 1620<br />

Chicago, IL 60606, USA<br />

+1 312 385 4494<br />

dmarshall@hallstar.com<br />

www.hallstar.com/hallgreen<br />

Rhein Chemie Rheinau GmbH<br />

Duesseldorfer Strasse 23-27<br />

68219 Mannheim, Germany<br />

Phone: +49 (0)621-8907-233<br />

Fax: +49 (0)621-8907-8233<br />

bioadimide.eu@rheinchemie.com<br />

www.bioadimide.com<br />

Huhtamaki Forchheim<br />

Sonja Haug<br />

Zweibrückenstraße 15-25<br />

91301 Forchheim<br />

Tel. +49-9191 81203<br />

Fax +49-9191 811203<br />

www.huhtamaki-films.com<br />

www.earthfirstpla.com<br />

www.sidaplax.com<br />

www.plasticsuppliers.com<br />

Sidaplax UK : +44 (1) 604 76 66 99<br />

Sidaplax Belgium: +32 9 210 80 10<br />

Plastic Suppliers: +1 866 378 4178<br />

INNOVIA FILMS LTD<br />

Wigton<br />

Cumbria CA7 9BG<br />

England<br />

Contact: Andy Sweetman<br />

Tel. +44 16973 41549<br />

Fax +44 16973 41452<br />

andy.sweetman@innoviafilms.com<br />

www.innoviafilms.com<br />

Postbus 26<br />

7480 AA Haaksbergen<br />

The Netherlands<br />

Tel.: +31 616 121 843<br />

info@bio4pack.com<br />

www.bio4pack.com<br />

bioplastics MAGAZINE [06/11] Vol. 6 55


Suppliers Guide<br />

6. Equipment<br />

8. Ancillary equipment<br />

6.1 Machinery & Molds<br />

9. Services<br />

Cortec® Corporation<br />

4119 White Bear Parkway<br />

St. Paul, MN 55110<br />

Tel. +1 800.426.7832<br />

Fax 651-429-1122<br />

info@cortecvci.com<br />

www.cortecvci.com<br />

FAS Converting Machinery AB<br />

O Zinkgatan 1/ Box 1503<br />

27100 Ystad, Sweden<br />

Tel.: +46 411 69260<br />

www.fasconverting.com<br />

Osterfelder Str. 3<br />

46047 Oberhausen<br />

Tel.: +49 (0)2861 8598 1227<br />

Fax: +49 (0)2861 8598 1424<br />

thomas.wodke@umsicht.fhg.de<br />

www.umsicht.fraunhofer.de<br />

European Bioplastics e.V.<br />

Marienstr. 19/20<br />

10117 Berlin, Germany<br />

Tel. +49 30 284 82 350<br />

Fax +49 30 284 84 359<br />

info@european-bioplastics.org<br />

www.european-bioplastics.org<br />

10.2 Universities<br />

Eco Cortec®<br />

31 300 Beli Manastir<br />

Bele Bartoka 29<br />

Croatia, MB: 1891782<br />

Tel. +385 31 705 011<br />

Fax +385 31 705 012<br />

info@ecocortec.hr<br />

www.ecocortec.hr<br />

Molds, Change Parts and Turnkey<br />

Solutions for the PET/Bioplastic<br />

Container Industry<br />

284 Pinebush Road<br />

Cambridge Ontario<br />

Canada N1T 1Z6<br />

Tel. +1 519 624 9720<br />

Fax +1 519 624 9721<br />

info@hallink.com<br />

www.hallink.com<br />

Institut für Kunststofftechnik<br />

Universität Stuttgart<br />

Böblinger Straße 70<br />

70199 Stuttgart<br />

Tel +49 711/685-62814<br />

Linda.Goebel@ikt.uni-stuttgart.de<br />

www.ikt.uni-stuttgart.de<br />

Michigan State University<br />

Department of Chemical<br />

Engineering & Materials Science<br />

Professor Ramani Narayan<br />

East Lansing MI 48824, USA<br />

Tel. +1 517 719 7163<br />

narayan@msu.edu<br />

Minima Technology Co., Ltd.<br />

Esmy Huang, Marketing Manager<br />

No.33. Yichang E. Rd., Taipin City,<br />

Taichung County<br />

411, Taiwan (R.O.C.)<br />

Tel. +886(4)2277 6888<br />

Fax +883(4)2277 6989<br />

Mobil +886(0)982-829988<br />

esmy@minima-tech.com<br />

Skype esmy325<br />

www.minima-tech.com<br />

NOVAMONT S.p.A.<br />

Via Fauser , 8<br />

28100 Novara - ITALIA<br />

Fax +39.0321.699.601<br />

Tel. +39.0321.699.611<br />

www.novamont.com<br />

Roll-o-Matic A/S<br />

Petersmindevej 23<br />

5000 Odense C, Denmark<br />

Tel. + 45 66 11 16 18<br />

Fax + 45 66 14 32 78<br />

rom@roll-o-matic.com<br />

www.roll-o-matic.com<br />

MANN+HUMMEL ProTec GmbH<br />

Stubenwald-Allee 9<br />

64625 Bensheim, Deutschland<br />

Tel. +49 6251 77061 0<br />

Fax +49 6251 77061 510<br />

info@mh-protec.com<br />

www.mh-protec.com<br />

6.2 Laboratory Equipment<br />

narocon<br />

Dr. Harald Kaeb<br />

Tel.: +49 30-28096930<br />

kaeb@narocon.de<br />

www.narocon.de<br />

nova-Institut GmbH<br />

Chemiepark Knapsack<br />

Industriestrasse 300<br />

50354 Huerth, Germany<br />

Tel.: +49(0)2233-48-14 40<br />

Fax: +49(0)2233-48-14 5<br />

Bioplastics Consulting<br />

Tel. +49 2161 664864<br />

info@polymediaconsult.com<br />

University of Applied Sciences<br />

Faculty II, Department<br />

of Bioprocess Engineering<br />

Heisterbergallee 12<br />

30453 Hannover, Germany<br />

Tel. +49 (0)511-9296-2212<br />

Fax +49 (0)511-9296-2210<br />

hans-josef.endres@fh-hannover.de<br />

www.fakultaet2.fh-hannover.de<br />

WEI MON INDUSTRY CO., LTD.<br />

2F, No.57, Singjhong Rd.,<br />

Neihu District,<br />

Taipei City 114, Taiwan, R.O.C.<br />

Tel. + 886 - 2 - 27953131<br />

Fax + 886 - 2 - 27919966<br />

sales@weimon.com.tw<br />

www.plandpaper.com<br />

President Packaging Ind., Corp.<br />

PLA Paper Hot Cup manufacture<br />

In Taiwan, www.ppi.com.tw<br />

Tel.: +886-6-570-4066 ext.5531<br />

Fax: +886-6-570-4077<br />

sales@ppi.com.tw<br />

MODA : Biodegradability Analyzer<br />

Saida FDS Incorporated<br />

3-6-6 Sakae-cho, Yaizu,<br />

Shizuoka, Japan<br />

Tel : +81-90-6803-4041<br />

info@saidagroup.jp<br />

www.saidagroup.jp<br />

7. Plant engineering<br />

Uhde Inventa-Fischer GmbH<br />

Holzhauser Str. 157 - 159<br />

13509 Berlin, Germany<br />

Tel. +49 (0)30 43567 5<br />

Fax +49 (0)30 43567 699<br />

sales.de@thyssenkrupp.com<br />

www.uhde-inventa-fischer.com<br />

10. Institutions<br />

10.1 Associations<br />

BPI - The Biodegradable<br />

Products Institute<br />

331 West 57th Street, Suite 415<br />

New York, NY 10019, USA<br />

Tel. +1-888-274-5646<br />

info@bpiworld.org<br />

56 bioplastics MAGAZINE [06/11] Vol. 6


Subscription<br />

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*If you return this form or subscribe online with promotion code before December 31, 2011, you‘ll get a nice daypack-rucksack. Every 10th new suscriber will get a watch.


Companies in this issue<br />

Company Editorial Advert Company Editorial Advert<br />

A & O FilmPAC 55<br />

ACMA GD 21<br />

Adsale (Chinplas) 41<br />

Ajax Amsterdam 9<br />

Alesco 56<br />

API 55<br />

Arkema 56<br />

BASF 23, 29<br />

Bio On 8<br />

Bio4Life 20<br />

Bio4Pack 18 56<br />

Biosphere 55<br />

BPI 57<br />

Braskem 5, 6, 9 35<br />

Brückner 21<br />

Carle Montanari 21<br />

Celabor 41<br />

Centroplast 34<br />

Cereplast 55<br />

Cobro 41<br />

Constantia Topepal 21<br />

Cortec 37, 57<br />

Danone 3, 10, 11<br />

Deutsches Kunststoff-Institut (DKI) 40<br />

DSM 11<br />

Du Pont 55<br />

Ecomann 49<br />

ecoplus 40<br />

Eosta 18<br />

European Bioplastics 10, 11 57<br />

European Plastics News 10<br />

FAS Converting 57<br />

FH Hannover 7 57<br />

FH Hannover (IfBB) 7<br />

FKuR 5, 14, 38 2, 55<br />

Flexico 36<br />

Fraunhofer IVV 26<br />

Fraunhofer UMSICHT 26 57<br />

Fujitsu 38<br />

Goglio Cofibox 34<br />

Grace biotec 55<br />

Hallink 57<br />

HallStar 56<br />

Henkel 7, 48<br />

Huhtamaki 56<br />

ICEA 24<br />

IKT Uni Stuttgart 57<br />

Innovia Films 32, 37 25, 56<br />

Institut Nationale des Sciences Apliquées 40<br />

Institute of Bioplastics & Biocomposites 7<br />

Iowa State University 8<br />

Kingfa 55<br />

Lanxess 6<br />

Limagrain 55<br />

Logotape 20<br />

Lower Austrian Plastics Cluster 40<br />

Mann+Hummel 57<br />

Maropack 21<br />

McCain 16<br />

Michigan State University 57<br />

Minima 57<br />

Naku 42<br />

narocon 28 57<br />

NatureWorks 5, 6, 34 53<br />

Natur-Tec 55<br />

NNFCC 48<br />

Norres 36<br />

nova-Institut 44 57<br />

Novamont 22, 24 57, 60<br />

Plastic Suppliers 56<br />

President Pck. 57<br />

PSM 55<br />

PTT Chemical 5<br />

Purac 37<br />

PURAC 37, 55<br />

Rhein Chemie 47, 56<br />

Roll-o-matic 57<br />

Saida 57<br />

Sant‘Anna 34<br />

Sappi Fine papers 37<br />

SFV Verpackungen 21<br />

Shenzhen Brightchina 55<br />

Showa Denko 55<br />

Slovenian Tool and Development Centre 40<br />

SPI (NPE) 12<br />

Sukano 56<br />

Synbra Technology 9<br />

Taghleef Industries 18, 20 56<br />

Tecnaro 7<br />

Telles 55, 59<br />

Tianan Biologic 55<br />

Transmare 55<br />

Uhde Inventa-Fischer 38, 57<br />

Umbra Olii 16<br />

USDA 8<br />

Wei Mon 43, 57<br />

Wuhan Huali (PSM) 27<br />

Xinfu 55<br />

Editorial Planner 2012<br />

Issue Month pub-date deadline Editorial Focus (1) Editorial Focus (2) Basics Event / Fair<br />

01/2012 Jan/Feb 06.02.12 06.01.12 ed.<br />

20.01.12 ad.<br />

Automotive Foam PLA NPE 2012 (Preview)<br />

02/2012 Mar/Apr 02.04.12 02.03.12 ed.<br />

16.03.12 ad.<br />

03/2012 May/Jun 04.06.12 04.05.12 ed.<br />

18.05.12 ad.<br />

04/2012 Jul/Aug 06.08.12 06.07.12 ed.<br />

20.07.12 ad.<br />

Rigid Packaging Additives /<br />

Masterbatches<br />

Injection Moulding<br />

Bioplastics from Waste<br />

streams<br />

Natural Fibre<br />

composites<br />

Blow moulding<br />

Thermoforming<br />

Castor Oil for<br />

Bioplastics<br />

Bioplastics from<br />

Protein<br />

Chinaplas (Preview)<br />

NPE 2012 (Review)<br />

Chinaplas (Review)<br />

Subject to changes<br />

58 bioplastics MAGAZINE [06/11] Vol. 6


A real sign<br />

of sustainable<br />

development.<br />

There is such a thing as genuinely sustainable development.<br />

Since 1989, Novamont researchers have been working<br />

on an ambitious project that combines the chemical industry,<br />

agriculture and the environment: “Living Chemistry for<br />

Quality of Life”. Its objective has been to create products<br />

with a low environmental impact. The result of Novamont’s innovative<br />

research is the new bioplastic Mater-Bi ® .<br />

Mater-Bi ® is a family of materials, completely biodegradable and compostable<br />

which contain renewable raw materials such as starch and vegetable oil derivates.<br />

Mater-Bi ® performs like traditional plastics but it saves energy, contributes<br />

to reducing the greenhouse effect and at the end of its life cycle, it closes<br />

the loop by changing into fertile humus. Everyone’s dream has become a reality.<br />

Living Chemistry for Quality of Life.<br />

www.novamont.com<br />

Inventor of the year 2007<br />

Mater-Bi ® : certified biodegradable and compostable.

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