API RP 581 - 3rd Ed.2016 - Add.2-2020 - Risk-Based Inspection Methodology
3.A-14 API RECOMMENDED PRACTICE 5813.A.3.8 TablesTable 3.A.3.1—List of Representative Fluids Available for Level 1 Consequence MethodologyRepresentativeFluidExamples of ApplicableMaterialsMolecularWeightNormal Boiling PointAutoignitionTemperature°C °F °C °FC1-C2Methane, ethane, ethylene, LNG,fuel gas23 −125 −193 558 1,036C3-C4 Propane, butane, isobutane, LPG 51 −21 −6.3 369 696C5 Pentane 72 36 97 284 544C6-C8Gasoline, naptha, light straightrun, heptane100 99 210 223 433C9-C12 Diesel, kerosene 149 184 364 208 406C13-C16Jet fuel, kerosene, atmosphericgas oil205 261 502 202 396C17-C25 Gas oil, typical crude 280 344 651 202 396C25+Residuum, heavy crude, lube oil,seal oil422 527 981 202 396Water Water 18 100 212 N/A N/ASteam Steam 18 100 212 N/A N/AAcid Acid, caustic 18 100 212 N/A N/AH2 Hydrogen only 2 −253 −423 400 752H2S Hydrogen sulfide only 34 −59 −75 260 500HF Hydrogen fluoride 20 20 68 17,760 32,000CO Carbon monoxide 28 −191 −312 609 1,128DEE Diethyl ether 74 35 95 160 320HCl Hydrogen chloride 36 −85 −121 N/A N/ANitric acid Nitric acid 63 121 250 N/A N/ANO2 Nitrogen dioxide 90 135 275 N/A N/APhosgene Phosgene 99 83 181 N/A N/ATDI Toluene diisocyanate 174 251 484 620 1,148Methanol Methanol 32 65 149 464 867PO Propylene oxide 58 34 93 449 840Styrene Styrene — — — — —EEAEthylene glycol monoethyl etheracetate132 156 313 379 715EE Ethylene glycol monoethyl ether 90 135 275 235 455EG Ethylene glycol 62 197 387 396 745EO Ethylene oxide 44 11 51 429 804
RISK-BASED INSPECTION METHODOLOGY, PART 3, ANNEX 3.A—BASIS FOR CONSEQUENCE METHODOLOGY 3.A-15Table 3.A.3.2—Assumptions Used When Calculating Liquid Inventories Within EquipmentEquipmentDescriptionProcess columns(may be treated astwo or three items)— top half— middle section— bottom halfAccumulators anddrumsComponentTypeCOLTOPCOLMIDCOLBTMDRUMExamplesDistillation columns, FCC mainfractionator, splitter tower,debutanizer, packed columns(see Note 1), liquid/liquidcolumns (see Note 2)OH accumulators, feed drums,HP/LP separators, nitrogenstorage drums, steamcondensate drums, three-phaseseparators (see Note 3)KO pots and dryers KODRUM Compressor KOs, fuel gas KOdrums, flare drums, air dryers(see Note 5)CompressorsPumpsHeat exchangersFin fan air coolersCOMPCCOMPRPUMP1SPUMP2SPUMPRHEXSSHEXTSFINFAN TUBEFINFANHEADERCentrifugal and reciprocatingcompressorsPumpsShell and tube exchangersTotal condensers, partialcondensers, vapor coolers, andliquid coolers (see Note 4)Default Liquid Volume Percent25 %25 %37 %These default values are typical of trayeddistillation columns and consider liquidholdup at the bottom of the vessel as well asthe presence of chimney trays in the uppersections50 % liquidTypically, two-phase drums are liquid levelcontrolled at 50 %10 % liquidMuch less liquid inventory expected in KOdrumsNegligible, 0 %100 % liquid50 % shell-side, 25 % tube-side25 % liquidFilters FILTER 100 % fullPiping PIPE-xx 100 % full, calculated for Level 2methodologyReactors REACTOR Fluid reactors (see Note 6),fixed-bed reactors (see Note 7),mole-sieves15 % liquidNOTE 1 Packed columns will typically contain much less liquid traffic than trayed columns. Typical liquid volume percentagesfor packed columns are 10 % to 15 %.NOTE 2 For liquid/liquid columns, such as amine contactors, caustic contactors, and lube or aromatics extractors, where asolvent or other fluid is brought into direct contact with the process fluid (e.g. TEG and BTX in an aromatics extractor), the liquidvolume percentage will be much higher. Consideration should be given to the amount of each fluid in the vessel and whether ornot the fluid composition includes both fluids in the mixture composition.NOTE 3 For three-phase separators, such as desalters and OH drums with water boots, the liquid volume percentage may belower than 50 %, depending on how much of the second liquid phase (typically water) is present and whether or not the fluidcomposition includes both liquid phases in the mixture composition.NOTE 4 Most air coolers are two-phase and only partially condense vapors. Even A/Cs that totally condense the vapor streamrequire the majority of the heat transfer area (and volume) to cool the vapors to their dew point and condense to liquid. Typically,only the final pass (less rows of tubes than other passes) will be predominately liquid. A liquid volume of 25 % should still beconservative for all A/Cs except liquid coolers.NOTE 5 For flue gas KO drums and air dryers, the liquid volume percentage is typically negligible. Consideration should be givento reducing the liquid volume percentage to 0 %.NOTE 6 Fluidized reactors can have up to 15 % to 25 % of the available vessel volume taken up by catalyst. The remainingavailable volume is predominately vapor. A liquid volume of 15 % should still be conservative.NOTE 7 Fixed-bed reactors can have up to 75 % of the available vessel volume taken up by hardware and catalyst. Theremaining volume will typically be 50 % liquid and 50 % vapor. An assumed liquid volume of 15 % of the overall available vesselvolume should still be conservative.
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RISK-BASED INSPECTION METHODOLOGY, PART 3, ANNEX 3.A—BASIS FOR CONSEQUENCE METHODOLOGY 3.A-15
Table 3.A.3.2—Assumptions Used When Calculating Liquid Inventories Within Equipment
Equipment
Description
Process columns
(may be treated as
two or three items)
— top half
— middle section
— bottom half
Accumulators and
drums
Component
Type
COLTOP
COLMID
COLBTM
DRUM
Examples
Distillation columns, FCC main
fractionator, splitter tower,
debutanizer, packed columns
(see Note 1), liquid/liquid
columns (see Note 2)
OH accumulators, feed drums,
HP/LP separators, nitrogen
storage drums, steam
condensate drums, three-phase
separators (see Note 3)
KO pots and dryers KODRUM Compressor KOs, fuel gas KO
drums, flare drums, air dryers
(see Note 5)
Compressors
Pumps
Heat exchangers
Fin fan air coolers
COMPC
COMPR
PUMP1S
PUMP2S
PUMPR
HEXSS
HEXTS
FINFAN TUBE
FINFAN
HEADER
Centrifugal and reciprocating
compressors
Pumps
Shell and tube exchangers
Total condensers, partial
condensers, vapor coolers, and
liquid coolers (see Note 4)
Default Liquid Volume Percent
25 %
25 %
37 %
These default values are typical of trayed
distillation columns and consider liquid
holdup at the bottom of the vessel as well as
the presence of chimney trays in the upper
sections
50 % liquid
Typically, two-phase drums are liquid level
controlled at 50 %
10 % liquid
Much less liquid inventory expected in KO
drums
Negligible, 0 %
100 % liquid
50 % shell-side, 25 % tube-side
25 % liquid
Filters FILTER 100 % full
Piping PIPE-xx 100 % full, calculated for Level 2
methodology
Reactors REACTOR Fluid reactors (see Note 6),
fixed-bed reactors (see Note 7),
mole-sieves
15 % liquid
NOTE 1 Packed columns will typically contain much less liquid traffic than trayed columns. Typical liquid volume percentages
for packed columns are 10 % to 15 %.
NOTE 2 For liquid/liquid columns, such as amine contactors, caustic contactors, and lube or aromatics extractors, where a
solvent or other fluid is brought into direct contact with the process fluid (e.g. TEG and BTX in an aromatics extractor), the liquid
volume percentage will be much higher. Consideration should be given to the amount of each fluid in the vessel and whether or
not the fluid composition includes both fluids in the mixture composition.
NOTE 3 For three-phase separators, such as desalters and OH drums with water boots, the liquid volume percentage may be
lower than 50 %, depending on how much of the second liquid phase (typically water) is present and whether or not the fluid
composition includes both liquid phases in the mixture composition.
NOTE 4 Most air coolers are two-phase and only partially condense vapors. Even A/Cs that totally condense the vapor stream
require the majority of the heat transfer area (and volume) to cool the vapors to their dew point and condense to liquid. Typically,
only the final pass (less rows of tubes than other passes) will be predominately liquid. A liquid volume of 25 % should still be
conservative for all A/Cs except liquid coolers.
NOTE 5 For flue gas KO drums and air dryers, the liquid volume percentage is typically negligible. Consideration should be given
to reducing the liquid volume percentage to 0 %.
NOTE 6 Fluidized reactors can have up to 15 % to 25 % of the available vessel volume taken up by catalyst. The remaining
available volume is predominately vapor. A liquid volume of 15 % should still be conservative.
NOTE 7 Fixed-bed reactors can have up to 75 % of the available vessel volume taken up by hardware and catalyst. The
remaining volume will typically be 50 % liquid and 50 % vapor. An assumed liquid volume of 15 % of the overall available vessel
volume should still be conservative.