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API RP 581 - 3rd Ed.2016 - Add.2-2020 - Risk-Based Inspection Methodology

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RISK-BASED INSPECTION METHODOLOGY, PART 3—CONSEQUENCE OF FAILURE METHODOLOGY 3-65

Table 4.14—Toxic Impact Criteria for Toxic Chemicals

Toxic Component

Probit Parameters

A B N

IDLH

(ppm)

AEGL3-10

(ppm)

AEGL3-30

(ppm)

AEGL3-60

(ppm)

EPA Toxic

Endpoint

(mg/L)

ERPG-

3

Acrolein −9.93 2.05 1.00 2 — — — 0.50 —

Acrylonitrile −29.42 3.01 1.43 85 — — — 0.08 75

Aluminum trichloride −14.65 2.00 1.00 — — — — — —

Ammonia −35.90 1.85 2.00 10 — — — 0.14 750

Benzene −109.8 5.30 2.00 500 — — — 1,000

Bromine −9.04 0.92 2.00 3 — — — 0.01 5

Carbon monoxide −37.98 3.70 1.00 1,200 1,700 600 330 — 500

Carbon tetrachloride −6.29 0.41 2.50 200 — — — — 750

Chlorine −8.29 0.92 2.00 10 — 28 20 0.01 20

Ethylene glycol

monoethyl ether

−15.54 1.00 2.00 — — — — — —

Ethylene oxide −6.21 1.00 1.00 800 — — — — —

Formaldehyde −12.24 1.30 2.00 20 — — — 0.01 25

Hydrogen chloride −16.85 2.00 1.00 50 620 210 100 0.03 150

Hydrogen cyanide −29.42 3.01 1.43 50 27 21 15 — 25

Hydrogen fluoride −48.33 4.853 1.00 30 170 62 44 —

Hydrogen sulfide −31.42 3.01 1.43 100 76 60 50 — 100

Methanol — — — — 15,000 15,000 7,900 —

Methyl bromide −56.81 5.27 1.00 — — — — — 200

Methyl isocyanate −5.64 1.64 0.65 — — — — — —

Nitric acid −5.48 1.00 2.00 — — — — — —

Nitrogen dioxide −13.79 1.40 2.00 20 — — — — —

Phosgene −19.27 3.69 1.00 2 3.6 1.5 0.75 — —

Propylene oxide −7.415 0.509 2.00 400 — — — 0.59 750

Styrene — — — 700 — — — — 1,000

Sulphur dioxide −15.67 2.10 1.00 100 — — — — —

Toluene −6.79 0.41 2.50 500 1,600 900 630 — —

Toluene

diisocyanate

−4.49 1.00 2.00 — — — — — —

NOTE Shaded areas in the above table designate toxic fluids and toxic impact criteria modeled in the Level 1 consequence analysis

described in Section 4.9. In the Level 2 consequence analysis, all data can be considered for all other fluids and toxic impact criteria.

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