API RP 581 - 3rd Ed.2016 - Add.2-2020 - Risk-Based Inspection Methodology

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2.B-68 API RECOMMENDED PRACTICE 5812.B.8.6 FiguresStartNoIs material ofconstructioncarbon steel orlow alloy?YesNoIs material ofconstructionType 300Series SS?YesDetermine CorrosionRate using Tables2.B.8.2 and 2.B.8.3• Acid gas loading• HSAS• Amine type andConcentration• MaterialConsult with amaterials specialist.Determine estimated corrosionRate from Table 2.B.8.5.Determine multiplier fromTable 2.B.8.4.EstimatedCorrosion RateEstimated Corrosion Rate Xmultiplier.EstimatedCorrosion RateFigure 2.B.8.1—Amine Corrosion—Determination of Corrosion Rate2.B.92.B.9.1High Temperature OxidationDescription of DamageCorrosion due to high temperature oxidation occurs at temperatures above about 482 °C (900 °F) for carbonsteel and increasing higher temperatures for alloys. The metal loss occurs as a result of the reaction of metalwith oxygen in the environment. Typically, at temperatures just above the temperature where oxidationbegins to occur, a dense comparatively protective oxide forms on the surface that reduces the metal lossrate. The oxide scale tends to be significantly more protective as the chromium concentration in the metalincreases.2.B.9.2Basic DataThe data listed in Table 2.B.9.1 are required to determine the estimated corrosion rate for high temperatureoxidation service. If precise data have not been measured, a knowledgeable process specialist should beconsulted.2.B.9.3Determination of Corrosion RateThe steps required to determine the corrosion rate are shown in Figure 2.B.9.1. The corrosion rate may bedetermined using the basic data in Table 2.B.9.1 in conjunction with Tables 2.B.9.2 through 2.B.9.3.

RISK-BASED INSPECTION METHODOLOGY, PART 2, ANNEX 2.B—DETERMINATION OF CORROSION RATES 2.B-692.B.9.4 TablesTable 2.B.9.1—High Temperature Oxidation—Basic Data Required for AnalysisBasic DataMaterial of constructionMaximum metal temperature (°C :°F)CommentsDetermine the material of construction of this equipment/piping.Determine the maximum metal temperature. The tube metal temperature forfurnace tubes is the controlling factor.Table 2.B.9.2—High Temperature Oxidation—Estimated Corrosion Rate (mpy)MaterialMaximum Metal Temperature (°F)925 975 1025 1075 1125 1175 1225 1275 1325 1375 1425 1475CS 2 4 6 9 14 22 33 48 — — — —1 1 /4 Cr 2 3 4 7 12 18 30 46 — — — —2 1 /4 Cr 1 1 2 4 9 14 24 41 — — — —5 Cr 1 1 1 2 4 6 15 35 65 — — —7 Cr 1 1 1 1 1 2 3 6 17 37 60 —9 Cr 1 1 1 1 1 1 1 2 5 11 23 4012 Cr 1 1 1 1 1 1 1 1 3 8 15 30304 SS 1 1 1 1 1 1 1 1 1 2 3 4309 SS 1 1 1 1 1 1 1 1 1 1 2 3310 SS/HK 1 1 1 1 1 1 1 1 1 1 1 2800 H/HP 1 1 1 1 1 1 1 1 1 1 1 2Table 2.B.9.2M—High Temperature Oxidation—Estimated Corrosion Rate (mm/y)MaterialMaximum Metal Temperature (°C)496 524 552 579 607 635 663 691 718 746 774 802CS 0.05 0.1 0.15 0.23 0.36 0.56 0.84 1.22 — — — —1 1 /4 Cr 0.05 0.08 0.1 0.18 0.3 0.46 0.76 1.17 — — — —2 1 /4 Cr 0.03 0.03 0.05 0.1 0.23 0.36 0.61 1.04 — — — —5 Cr 0.03 0.03 0.03 0.05 0.1 0.15 0.38 0.89 1.65 — — —7 Cr 0.03 0.03 0.03 0.03 0.03 0.05 0.08 0.15 0.43 0.94 1.52 —9 Cr 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.05 0.13 0.28 0.58 1.0212 Cr 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.08 0.2 0.38 0.76304 SS 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.05 0.08 0.1309 SS 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.05 0.08310 SS/HK 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.05800 H/HP 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.05

2.B-68 API RECOMMENDED PRACTICE 581

2.B.8.6 Figures

Start

No

Is material of

construction

carbon steel or

low alloy?

Yes

No

Is material of

construction

Type 300

Series SS?

Yes

Determine Corrosion

Rate using Tables

2.B.8.2 and 2.B.8.3

• Acid gas loading

• HSAS

• Amine type and

Concentration

• Material

Consult with a

materials specialist.

Determine estimated corrosion

Rate from Table 2.B.8.5.

Determine multiplier from

Table 2.B.8.4.

Estimated

Corrosion Rate

Estimated Corrosion Rate X

multiplier.

Estimated

Corrosion Rate

Figure 2.B.8.1—Amine Corrosion—Determination of Corrosion Rate

2.B.9

2.B.9.1

High Temperature Oxidation

Description of Damage

Corrosion due to high temperature oxidation occurs at temperatures above about 482 °C (900 °F) for carbon

steel and increasing higher temperatures for alloys. The metal loss occurs as a result of the reaction of metal

with oxygen in the environment. Typically, at temperatures just above the temperature where oxidation

begins to occur, a dense comparatively protective oxide forms on the surface that reduces the metal loss

rate. The oxide scale tends to be significantly more protective as the chromium concentration in the metal

increases.

2.B.9.2

Basic Data

The data listed in Table 2.B.9.1 are required to determine the estimated corrosion rate for high temperature

oxidation service. If precise data have not been measured, a knowledgeable process specialist should be

consulted.

2.B.9.3

Determination of Corrosion Rate

The steps required to determine the corrosion rate are shown in Figure 2.B.9.1. The corrosion rate may be

determined using the basic data in Table 2.B.9.1 in conjunction with Tables 2.B.9.2 through 2.B.9.3.

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