API RP 581 - 3rd Ed.2016 - Add.2-2020 - Risk-Based Inspection Methodology
2.B-68 API RECOMMENDED PRACTICE 5812.B.8.6 FiguresStartNoIs material ofconstructioncarbon steel orlow alloy?YesNoIs material ofconstructionType 300Series SS?YesDetermine CorrosionRate using Tables2.B.8.2 and 2.B.8.3• Acid gas loading• HSAS• Amine type andConcentration• MaterialConsult with amaterials specialist.Determine estimated corrosionRate from Table 2.B.8.5.Determine multiplier fromTable 2.B.8.4.EstimatedCorrosion RateEstimated Corrosion Rate Xmultiplier.EstimatedCorrosion RateFigure 2.B.8.1—Amine Corrosion—Determination of Corrosion Rate2.B.92.B.9.1High Temperature OxidationDescription of DamageCorrosion due to high temperature oxidation occurs at temperatures above about 482 °C (900 °F) for carbonsteel and increasing higher temperatures for alloys. The metal loss occurs as a result of the reaction of metalwith oxygen in the environment. Typically, at temperatures just above the temperature where oxidationbegins to occur, a dense comparatively protective oxide forms on the surface that reduces the metal lossrate. The oxide scale tends to be significantly more protective as the chromium concentration in the metalincreases.2.B.9.2Basic DataThe data listed in Table 2.B.9.1 are required to determine the estimated corrosion rate for high temperatureoxidation service. If precise data have not been measured, a knowledgeable process specialist should beconsulted.2.B.9.3Determination of Corrosion RateThe steps required to determine the corrosion rate are shown in Figure 2.B.9.1. The corrosion rate may bedetermined using the basic data in Table 2.B.9.1 in conjunction with Tables 2.B.9.2 through 2.B.9.3.
RISK-BASED INSPECTION METHODOLOGY, PART 2, ANNEX 2.B—DETERMINATION OF CORROSION RATES 2.B-692.B.9.4 TablesTable 2.B.9.1—High Temperature Oxidation—Basic Data Required for AnalysisBasic DataMaterial of constructionMaximum metal temperature (°C :°F)CommentsDetermine the material of construction of this equipment/piping.Determine the maximum metal temperature. The tube metal temperature forfurnace tubes is the controlling factor.Table 2.B.9.2—High Temperature Oxidation—Estimated Corrosion Rate (mpy)MaterialMaximum Metal Temperature (°F)925 975 1025 1075 1125 1175 1225 1275 1325 1375 1425 1475CS 2 4 6 9 14 22 33 48 — — — —1 1 /4 Cr 2 3 4 7 12 18 30 46 — — — —2 1 /4 Cr 1 1 2 4 9 14 24 41 — — — —5 Cr 1 1 1 2 4 6 15 35 65 — — —7 Cr 1 1 1 1 1 2 3 6 17 37 60 —9 Cr 1 1 1 1 1 1 1 2 5 11 23 4012 Cr 1 1 1 1 1 1 1 1 3 8 15 30304 SS 1 1 1 1 1 1 1 1 1 2 3 4309 SS 1 1 1 1 1 1 1 1 1 1 2 3310 SS/HK 1 1 1 1 1 1 1 1 1 1 1 2800 H/HP 1 1 1 1 1 1 1 1 1 1 1 2Table 2.B.9.2M—High Temperature Oxidation—Estimated Corrosion Rate (mm/y)MaterialMaximum Metal Temperature (°C)496 524 552 579 607 635 663 691 718 746 774 802CS 0.05 0.1 0.15 0.23 0.36 0.56 0.84 1.22 — — — —1 1 /4 Cr 0.05 0.08 0.1 0.18 0.3 0.46 0.76 1.17 — — — —2 1 /4 Cr 0.03 0.03 0.05 0.1 0.23 0.36 0.61 1.04 — — — —5 Cr 0.03 0.03 0.03 0.05 0.1 0.15 0.38 0.89 1.65 — — —7 Cr 0.03 0.03 0.03 0.03 0.03 0.05 0.08 0.15 0.43 0.94 1.52 —9 Cr 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.05 0.13 0.28 0.58 1.0212 Cr 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.08 0.2 0.38 0.76304 SS 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.05 0.08 0.1309 SS 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.05 0.08310 SS/HK 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.05800 H/HP 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.05
- Page 247 and 248: RISK-BASED INSPECTION METHODOLOGY,
- Page 249 and 250: RISK-BASED INSPECTION METHODOLOGY,
- Page 251 and 252: RISK-BASED INSPECTION METHODOLOGY,
- Page 253 and 254: RISK-BASED INSPECTION METHODOLOGY,
- Page 255 and 256: RISK-BASED INSPECTION METHODOLOGY,
- Page 257 and 258: RISK-BASED INSPECTION METHODOLOGY,
- Page 259 and 260: RISK-BASED INSPECTION METHODOLOGY,
- Page 261 and 262: RISK-BASED INSPECTION METHODOLOGY,
- Page 263 and 264: RISK-BASED INSPECTION METHODOLOGY,
- Page 265 and 266: RISK-BASED INSPECTION METHODOLOGY,
- Page 267 and 268: RISK-BASED INSPECTION METHODOLOGY,
- Page 269 and 270: RISK-BASED INSPECTION METHODOLOGY,
- Page 271 and 272: RISK-BASED INSPECTION METHODOLOGY,
- Page 273 and 274: RISK-BASED INSPECTION METHODOLOGY,
- Page 275 and 276: RISK-BASED INSPECTION METHODOLOGY,
- Page 277 and 278: RISK-BASED INSPECTION METHODOLOGY,
- Page 279 and 280: RISK-BASED INSPECTION METHODOLOGY,
- Page 281 and 282: RISK-BASED INSPECTION METHODOLOGY,
- Page 283 and 284: RISK-BASED INSPECTION METHODOLOGY,
- Page 285 and 286: RISK-BASED INSPECTION METHODOLOGY,
- Page 287 and 288: RISK-BASED INSPECTION METHODOLOGY,
- Page 289 and 290: RISK-BASED INSPECTION METHODOLOGY,
- Page 291 and 292: RISK-BASED INSPECTION METHODOLOGY,
- Page 293 and 294: RISK-BASED INSPECTION METHODOLOGY,
- Page 295 and 296: RISK-BASED INSPECTION METHODOLOGY,
- Page 297: RISK-BASED INSPECTION METHODOLOGY,
- Page 301 and 302: RISK-BASED INSPECTION METHODOLOGY,
- Page 303 and 304: RISK-BASED INSPECTION METHODOLOGY,
- Page 305 and 306: RISK-BASED INSPECTION METHODOLOGY,
- Page 307 and 308: RISK-BASED INSPECTION METHODOLOGY,
- Page 309 and 310: RISK-BASED INSPECTION METHODOLOGY,
- Page 311 and 312: RISK-BASED INSPECTION METHODOLOGY,
- Page 313 and 314: RISK-BASED INSPECTION METHODOLOGY,
- Page 315 and 316: RISK-BASED INSPECTION METHODOLOGY,
- Page 317 and 318: RISK-BASED INSPECTION METHODOLOGY,
- Page 319 and 320: RISK-BASED INSPECTION METHODOLOGY,
- Page 321 and 322: RISK-BASED INSPECTION METHODOLOGY,
- Page 323 and 324: RISK-BASED INSPECTION METHODOLOGY,
- Page 325 and 326: RISK-BASED INSPECTION METHODOLOGY,
- Page 327 and 328: RISK-BASED INSPECTION METHODOLOGY,
- Page 329 and 330: RISK-BASED INSPECTION METHODOLOGY,
- Page 331 and 332: RISK-BASED INSPECTION METHODOLOGY,
- Page 333 and 334: RISK-BASED INSPECTION METHODOLOGY,
- Page 335 and 336: RISK-BASED INSPECTION METHODOLOGY,
- Page 337 and 338: RISK-BASED INSPECTION METHODOLOGY,
- Page 339 and 340: RISK-BASED INSPECTION METHODOLOGY,
- Page 341 and 342: RISK-BASED INSPECTION METHODOLOGY,
- Page 343 and 344: RISK-BASED INSPECTION METHODOLOGY,
- Page 345 and 346: RISK-BASED INSPECTION METHODOLOGY,
- Page 347 and 348: RISK-BASED INSPECTION METHODOLOGY,
2.B-68 API RECOMMENDED PRACTICE 581
2.B.8.6 Figures
Start
No
Is material of
construction
carbon steel or
low alloy?
Yes
No
Is material of
construction
Type 300
Series SS?
Yes
Determine Corrosion
Rate using Tables
2.B.8.2 and 2.B.8.3
• Acid gas loading
• HSAS
• Amine type and
Concentration
• Material
Consult with a
materials specialist.
Determine estimated corrosion
Rate from Table 2.B.8.5.
Determine multiplier from
Table 2.B.8.4.
Estimated
Corrosion Rate
Estimated Corrosion Rate X
multiplier.
Estimated
Corrosion Rate
Figure 2.B.8.1—Amine Corrosion—Determination of Corrosion Rate
2.B.9
2.B.9.1
High Temperature Oxidation
Description of Damage
Corrosion due to high temperature oxidation occurs at temperatures above about 482 °C (900 °F) for carbon
steel and increasing higher temperatures for alloys. The metal loss occurs as a result of the reaction of metal
with oxygen in the environment. Typically, at temperatures just above the temperature where oxidation
begins to occur, a dense comparatively protective oxide forms on the surface that reduces the metal loss
rate. The oxide scale tends to be significantly more protective as the chromium concentration in the metal
increases.
2.B.9.2
Basic Data
The data listed in Table 2.B.9.1 are required to determine the estimated corrosion rate for high temperature
oxidation service. If precise data have not been measured, a knowledgeable process specialist should be
consulted.
2.B.9.3
Determination of Corrosion Rate
The steps required to determine the corrosion rate are shown in Figure 2.B.9.1. The corrosion rate may be
determined using the basic data in Table 2.B.9.1 in conjunction with Tables 2.B.9.2 through 2.B.9.3.