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3. FOOD ChEMISTRy & bIOTEChNOLOGy 3.1. Lectures

3. FOOD ChEMISTRy & bIOTEChNOLOGy 3.1. Lectures

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Chem. Listy, 102, s265–s1311 (2008) Food Chemistry & Biotechnology<br />

fatty acids ratios varied from <strong>3.</strong>96 to 10.62 for the total lipid<br />

extracts. For the studied ESF’s, these ratios varied from 2.64<br />

to <strong>3.</strong>44.<br />

The polyunsaturated fatty acids were the most abundant<br />

out of the unsaturated fatty acids of TLE’s, in all studied oils,<br />

except for peanut oil. The polyunsaturated/monounsaturated<br />

fatty acids ratios ranged from 0.92 to 4.49 for the analyzed<br />

TLE’s and from 1.83 to <strong>3.</strong>06 for ESF’s, respectively.<br />

S t e r o l C o m p o s i t i o n<br />

The predominant phytosterols in all four samples were<br />

sitosterol, campesterol and ∆5-avenasterol (see Table I).The<br />

proportion of free and esterified sterols varied widely among<br />

samples (see Fig. 2.). In all oils except sesame oil, most of the<br />

β-sitosterol was esterified.<br />

Conclusions<br />

The determination of fatty acids and sterols’ composition<br />

is essential for the analytical assessment of the quality,<br />

s621<br />

origin, extraction method, refining procedure and possible<br />

adulteration of the vegetable oils.<br />

REFEREnCES<br />

1. Christie W. W.: Gas Chromatography and Lipids. The<br />

Oily Press Ltd., Glasgow 1989.<br />

2. Abidi S. L.: J. Chromatogr. A 935, 173 (2001).<br />

<strong>3.</strong> Phillips K. M., Ruggio D. M., Toivo J.I., Swank M.A.,<br />

Simpkins A. H.: J. Food Comp. Anal. 15, 123 (2002).<br />

4. Phillips K. M., Ruggio D. M., Ashraf-Khorassani M.: J.<br />

Agric. Food Chem. 53, 9436 (2005).<br />

5. Yang B., Karlsson R. M., Oksman P. H., Kallio H.P.: J.<br />

Agric. Food Chem. 49, 5620 (2001).<br />

6. Dubois V., Breton S., Linder M., Fanni J., Parmentier<br />

M.: Eur. J. Lipid Sci. Tehnol. 109, 710 (2007).<br />

7. Beardsell D., Francis J., Ridley D.: J. Food Lipids 9, 1<br />

(2002).

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