Issue 03/2016
bioplasticsMAGAZINE_1603
bioplasticsMAGAZINE_1603
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Basics<br />
Avoiding confusion between<br />
biodegradable and<br />
compostable<br />
By:<br />
Pau Balaguer<br />
Project manager<br />
ITENE Research Center<br />
Paterna, Spain<br />
The terms biodegradable and compostable can be quite<br />
confusing words. Both words define biological processes<br />
but these concepts have often been misused in the<br />
field of marketing, leading to confusion. Any new products<br />
claimed to be compostable should be certified according to<br />
standardized testing methods and need to be identified with<br />
well-recognized logos promoted by several well-positioned<br />
entities.<br />
In recent years and mainly in the packaging sector, there<br />
has been a rising trend in replacing traditional plastics such<br />
as polyethylene and polypropylene by biodegradable materials<br />
in order to reduce the generation of packaging waste. With<br />
this regard certain bioplastics and cellulosic materials can be<br />
used.<br />
Bioplastics encompasses a whole family of materials which<br />
differ from conventional plastics insofar as that they are<br />
biobased, biodegradable, or both (fig. 1).<br />
Biobased means that the material or product is (partly)<br />
derived from renewable resources. According to their origin,<br />
biobased polymers can be grouped into three classes [2, 3]:<br />
(i) Polymers extracted directly from biomass, (ii) polymers<br />
synthesized from monomers obtained from biomass, and (iii)<br />
polymers produced by microorganisms.<br />
The first type of biobased polymers includes those based<br />
on polysaccharides (starch, cellulose…), and proteins (wheat<br />
gluten, soy protein, gelatin…). The second group of biopolymers<br />
covers a wide range of materials, such as poly (lactic acid)<br />
(PLA), produced from lactic acid obtained by fermentation of,<br />
for example, sugar cane; biopolyethylene (BioPE), from the<br />
polymerization of ethylene produced from bioethanol; and<br />
bio-polyurethanes, incorporating polyols of vegetable origin.<br />
The third type refers to biopolymers that are produced directly<br />
by microorganisms, such as polyhydroxyalkanoates (PHA) [4].<br />
However, not all of them are biodegradable.<br />
The term biodegradable refers to a chemical process during<br />
which microorganisms that are available in the environment<br />
convert materials into natural substances such as water,<br />
carbon dioxide and biomass. There are diverse environments<br />
for biodegradation of materials, such as soil, water, marine<br />
environment, digester plants, household composting units,<br />
and industrial composting facilities.<br />
Regarding packaging waste, composting appears to be<br />
a feasible solution for its recovery reducing the need for<br />
final disposal (e. g. in landfill) of used packaging of those<br />
materials that meet specific requirements. To be considered<br />
as compostable a material or product have to undergo<br />
degradation by biological processes during composting<br />
to yield carbon dioxide, water, inorganic compounds, and<br />
biomass at a rate consistent with other known compostable<br />
materials, and must not leave any (visible or invisible) or even<br />
toxic residues.<br />
Following the definition of the terms biodegradable<br />
and compostable, any product can be biodegradable, but<br />
what really matters is the time frame in which a material<br />
is biodegraded and in which environment. Compostable<br />
thus restricts the term fixing both aspects, and deals with<br />
other important aspects such as material characteristics,<br />
disintegration degree, and quality of the resulting compost.<br />
Then it is important to remark that all compostable<br />
materials are biodegradable, but not all biodegradable<br />
materials are compostable.<br />
Many unsubstantiated claims to biodegradability and<br />
compostability were made in the past as a consequence of<br />
Figure 1. Biobased and biodegradable plastics [1]<br />
FROM RENEWABLE RESOURCES<br />
Figure 2. Compostability logos given by<br />
Vinçotte and DIN-Certco: OK COMPOST and Seedling and by<br />
DIN-Certco: Industrial Compostable.<br />
The Seedling is a trademark owned by European Bioplastics<br />
NOT DEGRADABLE<br />
bio-PE, bio-PA<br />
cellulose-acetate<br />
bio-polyisoprene<br />
PLA<br />
PHA (PHB...)<br />
TPS<br />
Celluloseregenerates<br />
BIODEGRADABLE /<br />
COMPOSTABLE<br />
no bioplastics<br />
PE-LD, PE-HD<br />
PP, PA, PS<br />
PVC, EVOH,<br />
oxo-fragmentable<br />
blends<br />
certain Co-<br />
Polyesters<br />
(e.g. PBAT),<br />
Polycaprolacton,<br />
PVA,...<br />
FROM FOSSIL RAW MATERIALS<br />
42 bioplastics MAGAZINE [<strong>03</strong>/16] Vol. 11