11.02.2020 Views

Issue 03/2016

bioplasticsMAGAZINE_1603

bioplasticsMAGAZINE_1603

SHOW MORE
SHOW LESS

You also want an ePaper? Increase the reach of your titles

YUMPU automatically turns print PDFs into web optimized ePapers that Google loves.

Injection moulding<br />

By:<br />

Marco Neudecker<br />

Hans-Josef Endres<br />

Institute for Bioplastics & Biocomposites (IfBB)<br />

Hanover, Germany<br />

characteristics. Due to its filler content,<br />

however, it has the highest viscosity<br />

among all PLA materials in the tests.<br />

The highest flowability is indicated, as<br />

expected, for the PLA optimised for<br />

injection moulding applications.<br />

Variety of bioplastics<br />

Considering the variety of bioplastic<br />

materials, it is evident that they cover<br />

a range comparable to conventional<br />

plastics.<br />

PBS, Bio-PA, and Bio-PE are bioplastic<br />

materials with a flow behaviour similar<br />

to that of HDPE. Low viscosity and,<br />

thus, high flowability is shown for PHB,<br />

which is a good condition for molding<br />

even large components with a low wall<br />

thickness. Bio-PE, which is combined<br />

with 50 wt% natural fibres, shows low<br />

flowability and, just like the PLA filled<br />

with natural fibres, settles at the lower<br />

end of the parameters of comparison.<br />

The fibre-filled bioplastics are therefore<br />

not recommended for use in cases<br />

where low wall thickness is desired.<br />

Another point against it is that natural<br />

fibres tend to react to high shear forces<br />

by darkening or even by denaturation.<br />

Overall, the tests have revealed<br />

that bioplastics, with respect to their<br />

flow properties, already cover quite a<br />

broad range and possess attributes<br />

comparable to those of conventional<br />

plastics. Apart from the exceptions<br />

mentioned, they are suited for use in<br />

thin-wall components. Based on the<br />

findings from these tests, it will also<br />

be possible in the future to use specific<br />

bioplastics available as a substitute<br />

for conventional plastics, selected by<br />

their wall thickness dependent flow<br />

characteristics.<br />

Acknowledgement<br />

The authors express their gratitude<br />

to the German Federal Ministry of Food<br />

and Agriculture (BMEL) for funding this<br />

project.<br />

http://ifbb.wp.hs-hannover.de/<br />

verarbeitungsprojekt/<br />

Flow length [mm]<br />

900<br />

800<br />

700<br />

600<br />

500<br />

400<br />

300<br />

200<br />

100<br />

0<br />

0 0.5 1 1.5 2 2.5 3 3.5<br />

Wall thickness [mm]<br />

Fig. 1 Wall thickness dependent flow behaviour of conventional plastics<br />

Fig.2 Wall thickness dependent flow behaviour of PLA-based bioplastics<br />

Flow length [mm]<br />

Flow behaviour of conventional plastics<br />

Fig. 3 Wall thickness dependent flow behaviour of various bioplastics<br />

Flow length [mm]<br />

900<br />

800<br />

700<br />

600<br />

500<br />

400<br />

300<br />

200<br />

100<br />

Area of flow behaviour<br />

of conventional plastics<br />

0<br />

0 0.5 1 1.5 2 2.5 3 3.5<br />

Wall thickness [mm]<br />

900<br />

800<br />

700<br />

600<br />

500<br />

400<br />

300<br />

200<br />

100<br />

Flow behaviour of PLA-based bioplastics<br />

Area of flow behaviour<br />

of conventional plastics<br />

Area of flow behaviour<br />

of conventional PA<br />

Flow behaviour of various bioplastics<br />

Area of flow behaviour<br />

of conventional plastics<br />

Area of flow behaviour<br />

of conventional HDPE<br />

Area of flow behaviour<br />

of conventional PP nv<br />

0<br />

0 0.5 1 1.5 2 2.5 3 3.5<br />

Wall thickness [mm]<br />

Injection pressure = 645 bar<br />

PP nv<br />

T m<br />

= 200 °C<br />

T W<br />

= 30 °C<br />

PS<br />

T m<br />

= 260 °C<br />

T W<br />

= 30 °C<br />

HDPE<br />

T m<br />

= 180 °C<br />

T W<br />

= 30 °C<br />

PP hv<br />

T m<br />

= 200 °C<br />

T W<br />

= 30 °C<br />

PA<br />

T m<br />

= 260 °C<br />

T W<br />

= 80 °C<br />

Theoretical<br />

computing values<br />

In cooperation with UL TTC<br />

Injection pressure = 645 bar<br />

PLA injection moulding grade<br />

T m<br />

= 200 °C<br />

T W<br />

= 30 °C<br />

PLA fibre spinning grade<br />

T m<br />

= 200 °C<br />

T W<br />

= 30 °C<br />

PLA injection moulding grade 2<br />

T m<br />

= 200 °C<br />

T W<br />

= 30 °C<br />

PLLA<br />

T m<br />

= 200 °C<br />

T W<br />

= 30 °C<br />

PLA + 60 wt% NF<br />

T m<br />

= 200 °C<br />

T W<br />

= 30 °C<br />

Theoretical<br />

computing values<br />

In cooperation with UL TTC<br />

Injection pressure = 645 bar<br />

PHB<br />

T m<br />

= 210 °C<br />

T W<br />

= 30 °C<br />

Bio PE<br />

T m<br />

= 180 °C<br />

T W<br />

= 30 °C<br />

Bio PA<br />

T m<br />

= 250 °C<br />

T W<br />

= 90 °C<br />

PBS<br />

T m<br />

= 190 °C<br />

T W<br />

= 30 °C<br />

Bio PE + 50 wt% NF<br />

T m<br />

= 200 °C<br />

T W<br />

= 30 °C<br />

Theoretical<br />

computing values<br />

In cooperation with UL TTC<br />

bioplastics MAGAZINE [<strong>03</strong>/16] Vol. 11 23

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!