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ISSN 1862-5258<br />

Plant based Material for<br />

Eyeglass Lenses | 39<br />

March/April<br />

<strong>02</strong> | <strong>2016</strong><br />

Basics<br />

bioplastics MAGAZINE Vol. 11<br />

Design for Recyclability | 44<br />

Highlights<br />

Thermoforming / Rigid Packaging | 12<br />

Marine Pollution / Marine Degradation | 16<br />

Preview<br />

... is read in 92 countries


Editorial<br />

dear<br />

readers<br />

The first focus topic in this issue is Marine Pollution / Marine Degradation. We<br />

are all aware of the tremendous pollution of our oceans and waterways by plastic<br />

debris. And I assume we also all agree that the most obvious thing to do is to ensure<br />

no plastics end up in the oceans (or better still, in the environment at all),<br />

whether by preventing littering or improving waste management in general.<br />

It’s a problem that’s been a topic of endless discussion, with enough having<br />

already been said on the subject to fill any number of volumes. In this issue<br />

of bioplastics MAGAZINE we attempt to focus on the issues surrounding the<br />

biodegradability of certain plastics. Do biodegradable plastics offer potential<br />

for a solution – or at least for certain aspects of the problem? As I’m sure<br />

this topic will spark controversy and open up debate, we’re kicking off the<br />

discussion with this issue. Please feel free to send us your comments and<br />

views on the topic.<br />

In the Basics section, we cover the question: “What needs to be considered<br />

when designing a plastic product, in order to facilitate easy recycling at<br />

the end of its useful life?” For a comprehensive overview, we have included<br />

both conventional plastics and bioplastics with their particularities.<br />

If you are curious about what we were excited about in our first issues<br />

ten years ago, just flip to page 45, where we continue the new “blast from<br />

the past” series.<br />

And we’re launching yet another new series of articles under the title<br />

“Brand-Owner’s perspective on bioplastics and how to unleash their full potential”<br />

. See p. 33, where Michhael Knutzen of Coca-Cola shares his thoughts with us.<br />

Have you already downloaded our App for smartphones and tablets? Just go to<br />

Apple-Appstore or the Android Google Playstore and search for bioplastics. During<br />

our anniversary year, all our content can also be downloaded for free. This means that<br />

you can read bioplastics MAGAZINE and follow us on twitter on your mobile devices –<br />

wherever you are.<br />

The call for proposals for the 11 th Global Bioplastics Award (see page 55) is open!<br />

Please send us your suggestions: if you have seen or heard about any eligible services<br />

or products in the market that you really liked, whether your own or someone else’s,<br />

we’ll add these to our long list. The 11 th “Bioplastics Oscar” will be presented during<br />

the 11 th European Bioplastics Conference on November 29 th in Berlin, Germany.<br />

And finally, we’d like to remind you of our 4 th PLA World Congress in Munich,<br />

Germany on May 24 th and 25 th . The programme is now complete and may be found on<br />

page 10.<br />

We look forward to seeing you at one of the many upcoming events, and until then,<br />

enjoy reading bioplastics MAGAZINE.<br />

Sincerely yours<br />

Michael Thielen<br />

bioplastics MAGAZINE Vol. 11<br />

ISSN 1862-5258<br />

Plant based Material for<br />

Eyeglass Lenses | 39<br />

March/April<br />

<strong>02</strong> | <strong>2016</strong><br />

Basics<br />

Design for Recyclability | 44<br />

Highlights<br />

Thermoforming / Rigid Packaging | 12<br />

Marine Pollution / Marine Degradation | 16<br />

Preview<br />

... is read in 92 countries<br />

Follow us on twitter!<br />

www.twitter.com/bioplasticsmag<br />

Like us on Facebook!<br />

www.facebook.com/bioplasticsmagazine<br />

bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11 3


Content<br />

Imprint<br />

<strong>02</strong>|<strong>2016</strong><br />

March / April<br />

Thermoforming /<br />

Rigid Packaging<br />

12 Thermoforming and easy peel films<br />

14 a-PHA modified PLA for thermoforming<br />

Marine Pollution /<br />

Marine Degradation<br />

16 Plastics, biodegradation,<br />

and risk assessment<br />

18 Designing for biodegradability in ocean<br />

environment<br />

21 PHA – truly biodegradable<br />

22 Trash is mobile<br />

24 UNEP Report on biodegradable plastics<br />

& marine litter<br />

26 Statement of Open Bio to the UNEP report<br />

Report<br />

8 Bioplastics.online,<br />

finding the right bioplastics<br />

Events<br />

10 4 th PLA World Congress, programme<br />

28 Chinaplas Showguide & Preview<br />

Materials<br />

32 The 100 % bio-PET/polyester approach<br />

Analysis<br />

34 Breaking down complex assemblies<br />

From Science & Research<br />

40 HMF from chicory salad waste<br />

Basics<br />

42 Bioplastics packaging:<br />

design for a circular plastics economy<br />

44 Design for recyclability<br />

10 Years Ago<br />

45 IBAW industry association becomes<br />

European Bioplastics<br />

3 Editorial<br />

5 News<br />

33 Brand Owner’s View<br />

38 Application News<br />

46 Glossary<br />

50 Suppliers Guide<br />

53 Event Calendar<br />

54 Companies in this issue<br />

Publisher / Editorial<br />

Dr. Michael Thielen (MT)<br />

Karen Laird (KL)<br />

Samuel Brangenberg (SB)<br />

Head Office<br />

Polymedia Publisher GmbH<br />

Dammer Str. 112<br />

41066 Mönchengladbach, Germany<br />

phone: +49 (0)2161 6884469<br />

fax: +49 (0)2161 6884468<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Media Adviser<br />

Florian Junker<br />

phone: +49(0)2161-6884467<br />

fax: +49(0)2161 6884468<br />

f.junker@zuendgeber.com<br />

Chris Shaw<br />

Chris Shaw Media Ltd<br />

Media Sales Representative<br />

phone: +44 (0) 1270 522130<br />

mobile: +44 (0) 7983 967471<br />

Layout/Production<br />

Ulrich Gewehr (Dr. Gupta Verlag)<br />

Max Godenrath (Dr. Gupta Verlag)<br />

Print<br />

Poligrāfijas grupa Mūkusala Ltd.<br />

1004 Riga, Latvia<br />

bioplastics MAGAZINE is printed on<br />

chlorine-free FSC certified paper.<br />

Print run: 3,700 copies<br />

(plus 1000 copies printed in China for<br />

Chinaplas): Total print run: 4,700 copies<br />

bioplastics magazine<br />

ISSN 1862-5258<br />

bM is published 6 times a year.<br />

This publication is sent to qualified<br />

subscribers (149 Euro for 6 issues).<br />

bioplastics MAGAZINE is read in<br />

92 countries.<br />

Every effort is made to verify all<br />

Information published, but Polymedia<br />

Publisher cannot accept responsibility<br />

for any errors or omissions or for any<br />

losses that may arise as a result. No<br />

items may be reproduced, copied or<br />

stored in any form, including electronic<br />

format, without the prior consent of the<br />

publisher. Opinions expressed in articies<br />

do not necessarily reflect those of<br />

Polymedia Publisher.<br />

All articles appearing in bioplastics<br />

MAGAZINE, or on the website www.<br />

bioplasticsmagazine.com are strictly<br />

covered by copyright.<br />

bioplastics MAGAZINE welcomes contributions<br />

for publication. Submissions are<br />

accepted on the basis of full assignment<br />

of copyright to Polymedia Publisher<br />

GmbH unless otherwise agreed in advance<br />

and in writing. We reserve the right<br />

to edit items for reasons of space, clarity<br />

or legality. Please contact the editorial<br />

office via mt@bioplasticsmagazine.com.<br />

The fact that product names may not be<br />

identified in our editorial as trade marks<br />

is not an indication that such names are<br />

not registered trade marks.<br />

bioplastics MAGAZINE tries to use British<br />

spelling. However, in articles based on<br />

information from the USA, American<br />

spelling may also be used.<br />

Envelopes<br />

A part of this print run is mailed to the<br />

readers wrapped in I’m Green<br />

bio-polyethylene envelopes sponsored<br />

by FKuR Kunststoff GmbH, Willich,<br />

Germany<br />

Cover<br />

Photo: shutterstock/BestPhotoStudio<br />

Follow us on twitter:<br />

http://twitter.com/bioplasticsmag<br />

Like us on Facebook:<br />

https://www.facebook.com/bioplasticsmagazine


daily upated news at<br />

www.bioplasticsmagazine.com<br />

News<br />

France supports biobased & home-compostable bags<br />

European Bioplastics (EUBP), the association representing the bioplastics industry in Europe, welcomes the approval of the<br />

French implementation decree on single-use plastic bags, which was published by the French Ministry of Ecology, Sustainable<br />

Development and Energy last week on 1 February <strong>2016</strong>.<br />

“The decree sets out clear requirements for the reduction of single-use plastic bags in favor of biobased, biodegradable and<br />

home-compostable bags. This is an important measure and supports the efforts of EUBP to emphasise the essential role of<br />

bioplastics for the circular economy in Europe,” says Hasso von Pogrell, Managing Director of EUBP.<br />

In September last year, the French government notified the European Commission and its 27 EU colleague nations of its draft<br />

decree (décret) restricting use of plastics carrier bags in France. The decree, as part of the new law on Energy Transition and<br />

Green Growth, was intended as the instrument to implement the obligations on plastics bags that had been adopted by the<br />

French Assemblée Nationale to implement the EU requirements, and stated:<br />

“The decree defines the conditions for the application of the legislative provisions of the Environmental Code, aiming to ban<br />

the marketing of disposable plastic bags, with the exception, for bags other than carrier bags, of compostable bags that can be<br />

disposed of with household composting waste and which entirely or partially consist of bio-sourced materials.”<br />

On 21 December 2015, the European Commission formally issued a detailed letter to the French government objecting to<br />

parts of its draft decree to restrict the use of single use plastics carrier bags. As of 1 February, however, an implementation<br />

decree setting out the requirements and conditions in greater detail has been approved and will come into effect on 1 July<br />

<strong>2016</strong>. The decree applies to single-use carrier bags below a thickness of 50 µm, which will have to meet the requirements of<br />

the French standard for home composting and feature a biobased content of at least 30 %. The minimum biobased content<br />

will increase progressively to 40 % in 2018, 50 % in 2<strong>02</strong>0, and 60 % in 2<strong>02</strong>5. Appropriate bioplastics materials have been readily<br />

available on the market for quite some time, and manufacturers are eagerly waiting in the wings.<br />

Christophe Doukhi-de Boissoudy, president of French association Club Bio-plastiques comments: “We welcome the<br />

mobilisation of public authorities in order to finally achieve such a measure. It will allow biobased and biodegradable plastics<br />

stakeholders to harness the benefits of their research efforts to develop new biodegradable and compostable plastics that<br />

reduce our dependency on oil. The decree will help to reduce the plastic bags pollution as well as to revive economic activity for<br />

French plastics converters, as 90 % of fruit and vegetable bags are currently being imported.”<br />

The law makes France one of the first European countries to take concrete measures on plastic bags in favor of biobased and<br />

compostable bags in an effort to comply with the European Directive to reduce the consumption of lightweight plastic bags. It<br />

also underpins the benefits of separate collection of organic waste with biodegradable and compostable bags. The draft decree<br />

was amended to take the notions of the European Commission and the French State Council into account.<br />

“We expect the French decree to serve as an example for European legislation and to contribute to the increased demand of<br />

sustainable bioplastic solutions,” von Pogrell concluded. KL<br />

www.european-bioplastics.org<br />

Corbion PLA plant in Thailand<br />

Corbion has announced in early March that after completing the pre-engineering stage of its proposed 75,000 tonnes per<br />

year PLA polymerization plant in Thailand on schedule, the project is now moving into the basic engineering phase.<br />

The new plant will be located in Thailand, Rayong Province, at the existing Corbion site and will produce a complete portfolio<br />

of PLA polymers, ranging from standard PLA to high-heat resistant PLA. The company announced the project in 2014, citing<br />

strong customer interest in PLA as the motivation behind the investment, although at that time, Tjerk de Ruiter, CEO of Corbion,<br />

stressed that “we will only commence with this investment if we can secure at least one-third of plant capacity in committed<br />

PLA volumes from customers”.<br />

The pre-engineering phase commenced in 2015, after “the necessary technical and financial validation for such a plant” had<br />

been secured.<br />

Construction, which is expected to require capital expenditures of approximately EUR 65 million for the PLA plant and<br />

EUR 20 million for the lactide plant, is expected to start later this year with a targeted start-up in the second half of 2018.<br />

Additionally, Corbion will expand its existing lactide plant in Thailand by 25,000 tonnes per year. With this expansion the<br />

company will be able to serve both its own PLA plant and current and future lactide customers. The lactide expansion will also<br />

enable the production of a wider range of lactides than is currently possible.<br />

Corbion’s pre-marketing activities continue and a portfolio of PLA resins is commercially available for technical validation.<br />

Corbion will also continue to explore strategic opportunities as part of its PLA growth strategy. KL<br />

www.corbion.com<br />

bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11 5


News<br />

daily upated news at<br />

www.bioplasticsmagazine.com<br />

NatureWorks: methane as third-generation feedstock<br />

The new USD 1 million 771 m² (8,300 sqft) laboratory at NatureWorks world headquarters (Minnetonka, Minnesota, USA) is<br />

the latest milestone in the company’s multi-year program to commercialize a fermentation process for transforming methane,<br />

a potent greenhouse gas, into lactic acid, the building block of Ingeo PLA biopolymer. It includes the hiring of six scientists to<br />

staff the new facility.<br />

The methane to lactic acid research project began in 2013 as a joint effort between NatureWorks and Calysta Energy, Menlo<br />

Park, California, USA, to develop a fermentation biocatalyst. In 2014, laboratory-scale fermentation of lactic acid from methane<br />

utilizing a new biocatalyst was proven, and the United States Department of Energy awarded USD 2.5 million to the project. In<br />

<strong>2016</strong>, the opening of the new laboratory at NatureWorks headquarters marks another major advancement in the journey from<br />

proof of concept to commercialization.<br />

“A commercially viable methane to lactic acid conversion technology would be revolutionary,” said Bill Suehr, NatureWorks<br />

Chief Operating Officer.<br />

“It diversifies NatureWorks away from the current reliance on agricultural feedstocks, and with methane as feedstock, it<br />

could structurally lower the cost of producing Ingeo. It is exciting to envision a future where greenhouse gas is transformed<br />

into Ingeo-based compostable food serviceware, personal care items such as wipes and diapers, durable products such as<br />

computer cases and toys, films for wrapping fresh produce, filament for 3D printers, deli packaging, and more.”<br />

Based on the research collaboration between NatureWorks and Calysta, NatureWorks hopes to subsequently develop a<br />

2,223 m² (25,000 sqft) pilot plant in Minnesota by 2018 and hire an additional 15 employees. Within the next six years the<br />

company is looking at the possible construction of a USD 50 million demonstration project. It’s conceivable that within the next<br />

decade NatureWorks will bring online the first global-scale methane to lactic acid fermentation facility. KL<br />

www.natureworksllc.com | www.calysta.com<br />

Avantium and BASF: JV to make PEF<br />

BASF and Avantium announced in mid-March that they have signed a letter of intent and entered into exclusive negotiations<br />

to establish a joint venture (JV) for the production and marketing of furandicarboxylic acid (FDCA), as<br />

well as marketing of polyethylenefuranoate (PEF), based on this new chemical building block.<br />

The JV will use the YXY process ® developed by Avantium in its laboratories in Amsterdam and pilot<br />

plant in Geleen, Netherlands, for the production of biobased FDCA. It is intended to further develop<br />

this process as well as to construct a reference plant for the production of FDCA with an annual<br />

capacity of up to 50,000 tonnes per year at BASF’s Verbund site in Antwerp, Belgium. The aim is to<br />

build up world-leading positions in FDCA and PEF, and subsequently license the technology for<br />

industrial scale application.<br />

FDCA is the essential chemical building block for the production of PEF. Compared to PET,<br />

for instance, PEF is characterized by improved barrier properties for gases like carbon dioxide<br />

and oxygen. This can lead to longer shelf life of packaged products. Due to its higher mechanical<br />

strength, thinner PEF packaging can be produced, which means less material is required. This<br />

makes PEF particularly suitable for the production of certain food and beverage packaging, for<br />

example films and plastic bottles. After use, PEF can be recycled.<br />

“With the planned joint venture, we want to combine Avantium’s specific production technology<br />

and application know-how for FDCA and PEF with the strengths of BASF,” said Dr. Stefan Blank,<br />

President of BASF’s Intermediates division. “Of particular importance is our expertise in market<br />

development and large-scale production as an established and reliable chemical company in the<br />

business of intermediates and polymers,” Blank added.<br />

“The contemplated joint venture with BASF is a major milestone in the development and<br />

commercialization of this game-changing technology. Partnering with the number one chemical<br />

company in the world, provides us with access to the capabilities that are required to bring this<br />

technology to industrialization,” said Tom van Aken, Chief Executive Officer of Avantium.<br />

“The joint venture will further strengthen the global technology and establish the market<br />

leadership for FDCA and PEF. With BASF, we plan to start production of FDCA to enable the first<br />

commercial launch of this exciting bio-based material and to further develop and grow the market<br />

to its full potential.” KL/MT<br />

www.avantium.com | www.basf.com<br />

6 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11


News<br />

CO 2<br />

-based building block<br />

for PEF<br />

Stanford scientists have discovered a novel way to make PEF<br />

from carbon dioxide (CO 2<br />

) and inedible plant material, such as<br />

agricultural waste and grasses as a low-carbon alternative to PET.<br />

“Our goal is to replace petroleum-derived products with plastic<br />

made from CO 2<br />

,” said Matthew Kanan, an assistant professor of<br />

chemistry at Stanford. “If you could do that without using a lot of<br />

non-renewable energy, you could dramatically lower the carbon<br />

footprint of the plastics industry.”<br />

The scientists focused on the development of polyethylenefuranoate,<br />

or PEF. The properties of PEF, including their<br />

advantages over PET have been described manifold in bioplastics<br />

MAGAZINE. However, the plastics industry is trying hard to find a<br />

low-cost way to manufacture it at scale. The bottleneck has been<br />

figuring out a commercially viable way to produce the precursor<br />

FDCA sustainably.<br />

Instead of using sugar from corn to make FDCA, the Stanford<br />

team has been experimenting with furfural, a compound made<br />

from agricultural waste that has been widely used for decades.<br />

But making FDCA from furfural and CO 2<br />

typically requires<br />

hazardous chemicals that are expensive and energy-intensive to<br />

make. “That really defeats the purpose of what we’re trying to<br />

do,” Kanan said.<br />

The Stanford team’s approach has the potential to significantly<br />

reduce greenhouse emissions, Kanan said, because the CO 2<br />

required to make PEF could be obtained from fossil-fuel power<br />

plant emissions or other industrial sites. KL/MT<br />

http://news.stanford.edu/news/<strong>2016</strong>/march/low-carbon-bioplastic-030916.html<br />

Hybrid technology to<br />

make biobased nylon<br />

Engineers at Iowa State University have found a way to combine<br />

a genetically engineered strain of yeast and an electrocatalyst to<br />

efficiently convert sugar into a new type of nylon.<br />

Previous attempts to combine biocatalysis and chemical<br />

catalysis to produce biobased chemicals have resulted in low<br />

conversion rates. That’s usually because the biological processes<br />

leave residual impurities that harm the effectiveness of chemical<br />

catalysts.<br />

The engineers’ successful hybrid conversion process is<br />

described online and as the cover paper of the Feb. 12 issue of<br />

the journal “Angewandte Chemie International Edition”.<br />

“The ideal biorefinery pipelines, from biomass to the final<br />

products, are currently disrupted by a gap between biological<br />

conversion and chemical diversification. We herein report a<br />

strategy to bridge this gap with a hybrid fermentation and<br />

electrocatalytic process,” wrote lead authors Zengyi Shao and<br />

Jean-Philippe Tessonnier, Iowa State assistant professors of<br />

chemical and biological engineering who are also affiliated with<br />

the National Science Foundation Engineering Research Center<br />

for Biorenewable Chemicals (CBiRC) based at Iowa State. KL/MT<br />

www.news.iastate.edu/news/<strong>2016</strong>/<strong>02</strong>/08/biopolymers<br />

IKEA to move away<br />

from fossil plastics<br />

IKEA SUPPLY AG and Newlight Technologies have<br />

announced that they have entered into a supply<br />

collaboration, and technology license agreement<br />

that will supply IKEA with AirCarbon from Newlight’s<br />

commercial-scale production facilities and enable IKEA<br />

to produce AirCarbon thermoplastic under a technology<br />

license.<br />

Under the agreement, IKEA will purchase 50 % of<br />

the material from Newlight’s 23,000 tonnes per year<br />

plant in the United States, and subsequently IKEA has<br />

exclusive rights in the home furnishings industry to use<br />

Newlight’s carbon capture technology to convert biobased<br />

greenhouse gases, first from biogas and later<br />

from carbon dioxide, into AirCarbon thermoplastics for<br />

use in its home furnishing products. Both the companies<br />

will work together to identify and select the low cost<br />

carbon sources and development of the technology to<br />

use a range of renewable substrates, with a long term<br />

goal to develop capacities up to 453,000 tonnes per year.<br />

The AirCarbon plants are initially intended to run using<br />

biogas from landfills as their sole carbon feedstock<br />

inputs, with expansion into other AirCarbon feedstocks<br />

over time, such as carbon dioxide.<br />

Minh Nguyen Hoang,<br />

Category Manager<br />

of Plastics at IKEA of<br />

Sweden says: “IKEA<br />

wants to contribute<br />

to a transformational<br />

change in the industry<br />

and to the development<br />

of plastics made from<br />

renewable sources.<br />

In line with our<br />

sustainability goals, we are moving away from virgin fossil<br />

based plastic materials in favor of plastic produced from<br />

renewable sources such as biogas, sugar wastes, and other<br />

renewable carbon sources. We believe our partnership<br />

with Newlight has the potential, once fully scaled, to be<br />

an important component of our multi-pronged effort to<br />

provide IKEA’s customers with affordable plastics products<br />

made from renewable resources.”<br />

Added CEO of Newlight, Mark Herrema: “IKEA’s<br />

partnership with Newlight marks an important shift in<br />

how the world can make materials: from fossil fuels to<br />

captured carbon, from consumption to generation, from<br />

depletion to restoration. IKEA is a leader in the concept<br />

of harnessing its operations to improve the world, and<br />

we are proud to be a part of that effort.”<br />

IKEA’s long-term ambition is for all the plastic material<br />

used in their home furnishing products to be renewable<br />

or recycled material. The company is starting with their<br />

home furnishing plastic products, representing about<br />

40 % of the total plastic volume used in the IKEA range.”<br />

KL/MT<br />

www.ikea.com | www.newlight.com<br />

bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11 7


Report<br />

Bioplastics.online,<br />

finding the right bioplastics<br />

In the recent years there have been many developments worldwide in the field of bioplastics, both in biodegradable polymers<br />

and in biobased polymers and of course combinations of both. Many new exciting applications have been launched and the<br />

forecasts for biobased applications are looking extremely positive.<br />

Helian Polymers, based in Venlo, The Netherlands is a company specialized in the field of masterbatches, bioplastic<br />

compounds and materials for 3D Printing. Since 2003 Helian Polymers has been active developing both additives and<br />

compounds for bioplastics.<br />

This combined knowledge has led to the start of the company colorFabb, today a leading producer of 3D printing filaments<br />

from various engineered biopolymers, with great experience in online ordering and supplying systems with a sophisticated<br />

infrastructure.<br />

A new development of Helian Polymers is the soon to be launched online material platform called bioplastics.online. This<br />

web based platform is intended to support potential users of bioplastics to select the ideal type for a certain application and at<br />

the same time offering the opportunity to order initial quantities for test runs. On the other hand, it supports material suppliers<br />

to offer their various types and grades and – backed by Helian Polymer’s infrastructure – get initial test quantities supplied to<br />

interested customers.<br />

bioplastics.online will feature a wide variety of both biodegradable polymers and<br />

compounds as well as biobased polymers and composites. The focus of this platform<br />

is to bring initial ordering quantities to the market in a fast and transparent way, by<br />

partnering up with the leading manufacturers of bioplastics worldwide.<br />

The interactive website offers support to select the right bioplastic for a certain<br />

application using various categories and filters and eventually order small lots of<br />

25/50/100 kg for trial purposes. The materials will be send worldwide with DHL or<br />

UPS, including molded sample plaques (cf. photo) of the ordered materials.<br />

bioplastics.online is planned to go live mid of May this year. bioplastic MAGAZINE<br />

supports this new and unique initiative platform and acts as media partner. MT<br />

www.bioplastics.online<br />

8 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11


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data from the year 2012 to the latest data of 2014<br />

and the recently published data from European<br />

Bioplastics, the association representing the<br />

interests of Europe’s bioplastics industry.<br />

Bio-based drop-in PET and the new polymer<br />

PHA show the fastest rates of market growth.<br />

Europe looses considerable shares in total<br />

production to Asia. The bio-based polymer<br />

turnover was about € 11 billion worldwide<br />

in 2014 compared to € 10 billion in 2013.<br />

http://bio-based.eu/markets<br />

©<br />

15<br />

10<br />

5<br />

2011<br />

-Institut.eu | 2015<br />

2% of total<br />

polymer capacity,<br />

€11 billion turnover<br />

2012<br />

Epoxies<br />

PE<br />

2013<br />

PUR<br />

PBS<br />

2014<br />

CA<br />

PBAT<br />

2015<br />

PET<br />

PA<br />

<strong>2016</strong><br />

PTT<br />

PHA<br />

2017<br />

PEF<br />

2018<br />

Starch<br />

Blends<br />

EPDM<br />

PLA<br />

2019<br />

2<strong>02</strong>0<br />

Full study available at www.bio-based.eu/markets<br />

The nova-Institute carried out this study in<br />

collaboration with renowned international<br />

experts from the field of bio-based building<br />

blocks and polymers. The study investigates<br />

every kind of bio-based polymer and, for the<br />

second time, several major building blocks<br />

produced around the world.<br />

What makes this report unique?<br />

■ The 500 page-market study contains<br />

over 200 tables and figures, 96 company<br />

profiles and 11 exclusive trend reports<br />

written by international experts.<br />

■ These market data on bio-based building<br />

blocks and polymers are the main source<br />

of the European Bioplastics market data.<br />

■ In addition to market data, the report offers a<br />

complete and in-depth overview of the biobased<br />

economy, from policy to standards<br />

& norms, from brand strategies to<br />

environmental assessment and many more.<br />

■ A comprehensive short version<br />

(24 pages) is available for free at<br />

http://bio-based.eu/markets<br />

To whom is the report addressed?<br />

■ The whole polymer value chain:<br />

agro-industry, feedstock suppliers,<br />

chemical industry (petro-based and<br />

bio-based), global consumer<br />

industries and brands owners<br />

■ Investors<br />

■ Associations and decision makers<br />

Content of the full report<br />

This 500 page-report presents the findings of<br />

nova-Institute’s market study, which is made up<br />

of three parts: “market data”, “trend reports”<br />

and “company profiles” and contains over 200<br />

tables and figures.<br />

The “market data” section presents market<br />

data about total production capacities and the<br />

main application fields for selected bio-based<br />

polymers worldwide (status quo in 2011, 2013<br />

and 2014, trends and investments towards<br />

2<strong>02</strong>0). This part not only covers bio-based<br />

polymers, but also investigates the current biobased<br />

building block platforms.<br />

The “trend reports” section contains a total of<br />

eleven independent articles by leading experts<br />

Order the full report<br />

The full report can be ordered for 3,000 €<br />

plus VAT and the short version of the report<br />

can be downloaded for free at:<br />

www.bio-based.eu/markets<br />

NEW: Buy the trends reports separately!<br />

Contact<br />

Dipl.-Ing. Florence Aeschelmann<br />

+49 (0) 22 33 / 48 14-48<br />

florence.aeschelmann@nova-institut.de<br />

in the field of bio-based polymers. These trend<br />

reports cover in detail every important trend<br />

in the worldwide bio-based building block and<br />

polymer market.<br />

The final “company profiles” section includes<br />

96 company profiles with specific data<br />

including locations, bio-based building blocks<br />

and polymers, feedstocks and production<br />

capacities (actual data for 2011, 2013 and<br />

2014 and forecasts for 2<strong>02</strong>0). The profiles also<br />

encompass basic information on the companies<br />

(joint ventures, partnerships, technology and<br />

bio-based products). A company index by biobased<br />

building blocks and polymers, with list of<br />

acronyms, follows.


Events<br />

4 th PLA World Congress<br />

24 – 25 MAY <strong>2016</strong> MUNICH › GERMANY<br />

bioplastics MAGAZINE presents:<br />

3 rd PLA World Congress<br />

The PLA World Congress in Munich/Germany, organised by bioplastics MAGAZINE<br />

now for the 4 th time, is the must-attend 27 conference + 28 MAY for 2014 everyone MUNICH interested › GERMANY in PLA,<br />

its benefits, and challenges. The global conference offers high class presentations<br />

from top individuals in the industry from Europe, USA, New Zealand and China and<br />

also offers excellent networkung opportunities along with a table top exhibition.<br />

Please find below the programme. More details and a registration form can be<br />

found at the conference website<br />

www.pla-world-congress.com<br />

4 th PLA World Congress, programme<br />

Tuesday, May 24, <strong>2016</strong><br />

07:00-08:30 Registration, Welcome-Coffee<br />

08:30-08:45 Michael Thielen, Polymedia Publisher Welcome Remarks<br />

08:45-09:15 Constance Ißbrücker, European Bioplastics Keynote Speech: The current situation of PLA in Europe and globally<br />

09:15-09:40 Michael Carus, nova-Institute The role of PLA in the Bio-based Economy<br />

09:40-10:05 Ramani Narayan, Michigan State University Understanding the PLA molecule – From stereochemistry to applicability<br />

10:05-10:30 Udo Mühlbauer, Uhde Inventa-Fischer New features of Uhde Inventa-Fischer’s PLAneo ® process<br />

10:30-10:45 Q&A<br />

10:45-11:10 Coffee<br />

11:10-11:35 Mariagiovanna Vetere, NatureWorks Ingeo – developing new applications in a circular economy perspective<br />

11:35-12:00 Hugo Vuurens, Corbion Purac Latest application innovations in PLA bioplastics<br />

12:00-12:25 Björn Bergmann, Fraunhofer ICT InnoREX: European project reveals processing options for intensified PLA production<br />

12:25-12:40 Q&A<br />

12:40-13:45 Lunch<br />

13:45-14:10 Jan Henke, ISCC Sustainable supply chains for PLA production<br />

14:10-14:35 Patrick Zimmermann, FKuR Advanced PLA solutions<br />

14:35-15:00 Daniel Ganz, Sukano Sustainability without compromises – Discover a toolbox of solutions for PLA<br />

15:00-15:25 Chung-Jen (Robin) Wu, Supla Not just PLA, it is SUPLA<br />

15:25-15:40 Q&A<br />

15:40-16:00 Coffee<br />

16:00-16:25 Vittorio Bortolon, Plantura Italia Plantura, ecofriendly automotive biopolymer<br />

16:25-16.50 Amparo Verdú Solís , AIMPLAS New PLA based fibres for automotive interior applications<br />

16:50-17:00 Q&A<br />

17:00-17:30 Panel discussion (t.b.d.) PLA market development: chances, obstacles and challenges (t.b.c.)<br />

from 19:00 Bavarian Night Hofbräuhaus, Munich<br />

Wednesday, May 25, <strong>2016</strong><br />

08:50-09:00 Michael Thielen, Polymedia Publisher Welcome remarks, 2 nd day<br />

09:00-09:25 Jan Noordegraaf, Synbra An expanding update on BioFoam E-PLA foam applications<br />

09:25-09:50 Kate Parker, Biopolymer Network / Scion Functional bio based foam – expanding into new areas<br />

09:50-10:15 John Leung, Biosolutions Heat resistant PLA sheet foam<br />

10:15-10:40 Vasily Topolkaraev, Kimberly-Clark Novel Nanocellular PLA-polyolefin Hybrid Composites<br />

10:40-10:55 Q&A<br />

10:55-11:20 Coffee<br />

11:20-11:45 Antje Lieske, Fraunhofer IAP Development of industrially feasible structure variations of polylactide<br />

11:45-12:10 Gerald Schennink, Wageningen UR PLA for durable applications comparing PLA hybrids with nucleated PLA (t.b.c.)<br />

12:10-12:35 Nico Schmidt, Univ. App. Sc. Hamm-Lippstadt LED-Application<br />

12:35-13:00 Bert Lagrain, KU Leuven PLA: a perfect marriage between bio- and chemical technology<br />

13:00-13:15 Q&A<br />

13:15-14:15 Lunch<br />

14:15-14:40 Remy Jongboom, Biotec BIOPLAST 900, what else?<br />

14:40-15:05 Tanja Fell, Fraunhofer IVV Present and potential future recycling of PLA waste – Chances and opportunities<br />

15:05-15:30 Nikola Kocić, Südd. Kunststoffzentrum SKZ Degradation of PLA during long-term storage<br />

15:30-15:55 Ruud Rouleaux, Helian Polymers How to find the right bioplastic for your application?<br />

15:55-16:05 Q&A<br />

16:05-16:10 Michael Thielen, Polymedia Publisher Closing remarks<br />

Subject to changes, please visit the conference website<br />

10 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11


organized by<br />

4 th PLA World Congress<br />

24 – 25 MAY <strong>2016</strong> MUNICH › GERMANY<br />

is a versatile bioplastics raw<br />

PLA material from renewable resources.<br />

It is being used for films and rigid packaging,<br />

for fibres in woven and non-woven applications.<br />

Automotive industry<br />

and consumer electronics are thoroughly<br />

investigating and even already applying PLA.<br />

New methods of polymerizing, compounding<br />

or blending of PLA have broadened the range<br />

of properties and thus the range of possible<br />

applications.<br />

That‘s why bioplastics MAGAZINE is now<br />

organizing the 4 th PLA World Congress on:<br />

24 – 25 May <strong>2016</strong> in Munich / Germany<br />

Experts from all involved fields will share their<br />

knowledge and contribute to a comprehensive<br />

overview of today‘s opportunities and challenges<br />

and discuss the possibilities, limitations<br />

and future prospects of PLA for all kind of<br />

applications. Like the three congresses<br />

the 4 th PLA World Congress will also offer<br />

excellent networking opportunities for all<br />

delegates and speakers as well as exhibitors<br />

of the table-top exhibition.<br />

The team of bioplastics MAGAZINE is looking<br />

forward to seeing you in Munich.<br />

The conference will comprise high class presentations on<br />

› Latest developments<br />

› Market overview<br />

REGISTER NOW<br />

› High temperature behaviour<br />

› Blends and comounds<br />

› Additives / Colorants<br />

› Applications (film and rigid packaging, textile,<br />

automotive,electronics, toys, and many more)<br />

Contact us at: mt@bioplasticsmagazine.com<br />

for exhibition and sponsoring opportunities<br />

www.pla-world-congress.com<br />

› Fibers, fabrics, textiles, nonwovens<br />

› Reinforcements<br />

› End of life options<br />

(recycling,composting, incineration etc)<br />

Gold<br />

Sponsor:<br />

Silver<br />

Sponsor:<br />

Media<br />

Partner:<br />

Supported by:


Thermoforming / Rigid Packaging<br />

Thermoforming<br />

and easy peel films<br />

By:<br />

Warwick Armstrong<br />

General Manager<br />

Business Development and Marketing<br />

Plantic Technologies<br />

Altona, Victoria, Australia<br />

The growing trend of consumer awareness towards<br />

the impact of their actions on the environment has<br />

seen Plantic Technologies Ltd (Altona, Victora, Australia),<br />

a part of the Kuraray group, successful in supplying<br />

some of the world’s largest retailers and produces<br />

high barrier rigid bioplastic materials. Plantic’s thermoformable<br />

rigid bottom webs are providing a new class in<br />

ultra-high barrier films made from renewable<br />

and recyclable materials.<br />

Plantic Technologies has achieved a<br />

unique place in the world market<br />

for bioplastics through proprietary<br />

technology that<br />

delivers biodegradable<br />

and renewable<br />

sourced<br />

alternatives to<br />

conventional<br />

plastics based on<br />

corn and cassava,<br />

which is not genetically<br />

modified.<br />

Unlike other bioplastics<br />

companies who utilise<br />

organic materials but whose<br />

polymers are still developed in<br />

refineries, Plantic’s polymer as well as its<br />

raw material, are grown in a field. This means<br />

that the resins are derived from the natural occurring<br />

polymers in starch and converted in a proprietary process<br />

into materials that can be used as a packaging material.<br />

Starch is a naturally occurring polysaccharide consisting<br />

of the polymers amylose and amylopectin and used as an<br />

energy store in green plants. Larger amounts of starch<br />

are particularly found in cereal crops (such as corn, wheat<br />

and rice) and also tubers (such as potato and cassava).<br />

The entire process integrates the science of organic<br />

innovation with commercial and industrial productivity in<br />

a new way. The result is both a broad range of immediate<br />

performance and cost advantages, and long-term<br />

environmental and sustainability benefits.<br />

PLANTIC E, PLANTIC R, PLANTIC RE, PLANTIC<br />

ES AND PLANTIC EF represent the company’s flagship<br />

products for rigid and flexible packaging. These products<br />

are a direct replacement for conventional polymers and<br />

when compared with oil based products an independent<br />

assessment (carried out by Quantis – Environmental<br />

Life Cycle Assessment Consultants) found that Plantic’s<br />

products use up to 40 % less energy and provide a<br />

reduction in greenhouse gases by up to 70 %.<br />

Plantic HP, a fully biodegradable high barrier structure<br />

forms the core of all Plantic products and depending on<br />

the customer needs the outer skins can be made to seal<br />

onto conventional PE and PET sealing layers. Proving<br />

popular amongst retailers is one of the latest released<br />

products from Plantic: An easy peel skin pack range with<br />

the ability to seal to PET and PE top webs that is available<br />

in a wide range of colours and textures.<br />

Plantic R, a fully recyclable high barrier product is being<br />

used extensively for red meat applications. Plantic R seals<br />

to most traditional PET based top webs. This rigid<br />

product runs on all traditional thermoforming<br />

lines and gives the producer the opportunity<br />

to down gauge whilst achieving a higher<br />

barrier performance and stronger<br />

pack presentation.<br />

Plantic Technologies is<br />

supplying major supermarket<br />

customers<br />

in Australia, Europe<br />

and America<br />

in applications<br />

such as fresh case<br />

ready beef, pork, lamb<br />

and veal, smoked and<br />

processed meats, chicken,<br />

fresh pasta and cheese applications.<br />

Plantic’s products<br />

have proven to have exceptional<br />

gas barrier properties which dramatically<br />

extend the shelf life of the<br />

packaged product (for more details<br />

see bM 05/2015, pp. 40).<br />

Plantic Technologies is expanding<br />

rapidly and refining its technology to meet the ever growing<br />

global needs for more environmentally and performance<br />

efficient packaging materials. Plantic Technologies has<br />

released a new range of flexible materials with the same<br />

environmental and performance characteristics as their<br />

rigid based structures. These flexible options are proving<br />

already to be a preferred choice for many consumers,<br />

retailers and processors.<br />

“Plantic materials are not just about being a sustainable<br />

material, it has an ultra-high barrier that can improve<br />

the shelf life of a product, and reduce food waste. With<br />

Plantic materials you can have an enormous impact on<br />

value change and reduce the effects of climate change,<br />

both by reducing food waste and using more sustainable<br />

materials.” Brendan Morris Plantic Technologies Limited<br />

CEO and Managing Director said.<br />

www.plantic.com.au<br />

12 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11


World’s first, Plant-based<br />

High Refractive Index Material<br />

for Eyeglass Lenses,<br />

Do Green MR <br />

Mitsui Chemicals Inc. (MCI) has set out to contribute to society by<br />

providing innovative, high quality products and services to customers<br />

while maintaining harmony with the environment on a global scale.<br />

MCI has over 30 years of experience in the development and<br />

production of innovative optical lens materials for the global market,<br />

particularly with its thin & lightweight eyeglass lenses made from the<br />

“MR series” of high refractive index materials.<br />

with the SWANS program of Yamamoto Kogaku Co., Ltd., which has<br />

a history of designing sports products that offer comfort and<br />

performance, and Itoh Optical Industrial Co., Ltd., which has<br />

expertise in high-performance eyeglass lens manufacturing. The<br />

sunglasses were provided not only to participating athletes but also<br />

to referees at the triathlon and staff in the Executive Office. By<br />

sponsoring the event, MCI not only provided plant-based<br />

sunglasses, but also appealed to the social/ethical activities of the<br />

Do Green initiative. MCI’s support was widely praised by the people<br />

involved in the triathlon.<br />

MR-60 plant-based lenses in standard eyeglasses<br />

MCI has developed MR-60 , a plant-based high refractive index lens<br />

material for standard eyeglasses, by using a biomass-derived<br />

industrial isocyanate and a biomass-derived polythiol as well as a<br />

non-metallic catalyst for polymerization. In 2014, MR-60 was<br />

certified by the the United States Department of Agriculture (USDA)<br />

as a plant-derived product with a biomass of 57%. It was also<br />

certified by the Japan Organics Recycling Association (JORA) as a<br />

plant-derived product with a biomass of 30-40%. The ultra-high<br />

refractive index glass lens material MR-174 , which was previously<br />

available on the market, also acquired certification as a plant-derived<br />

product with a biomass of 82% from the USDA and as a<br />

plant-derived product with a biomass of 30-40% from the JORA in<br />

2014.<br />

(The degree of biomass from JORA is<br />

the ratio between fossil fuel-derived<br />

carbon and biomass-derived ingredients;<br />

the biomass degree from the USDA is<br />

the ratio between fossil fuel-derived<br />

carbon and biomass-derived carbon as<br />

tested according to ASTM-D6866-12.)<br />

MR-60 biomass certifications from<br />

USDA and JORA<br />

MR-60 plant-based lenses in sunglasses<br />

MCI launched the first activity of the Do Green initiative during<br />

October 27-29 th , 2015, with 153 farmers and residents of Gujarat,<br />

India. The Do Green initiative strives to solve vision related issues<br />

faced by farmers who produce the raw material of MCI’s<br />

plant-derived product. The Do Green initiative relies on cooperation<br />

with a local Indian optometrist and an eye care professional from the<br />

Japanese lens specialty store Lensya. ICA Japan, a registered NGO,<br />

and Holistic Child Development India, a local NGO in India, assisted<br />

with coordination. The Do Green initiative began as a way to<br />

contribute to society. MCI aims to connect manufacturers, retailers,<br />

and consumers with the message of the Do Green initiative through<br />

Do Green products.<br />

MCI’s Do Green products include the world’s only plant-derived<br />

poly-isocyanate STABiO ; Econykol , a polyol derived from castor oil<br />

from seeds that are grown in Gujarat,India; as well as the plant-based<br />

lens materials MR-60 and MR-174 . MCI is continuing to develop<br />

new Do Green plant-based materials.<br />

MCI was a sponsor of the “2015 World Triathlon Series Yokohama”<br />

held in Yokohama, Japan, an event which aimed to “contribute to<br />

society through sports” . The event utilized the sustainability<br />

management system standard ISO 20121. MCI made the decision to<br />

carry out joint development with Yokohama City on sunglasses made<br />

with MR-60 . The sunglasses were produced through collaboration<br />

Eye care professional conducting an<br />

eye exam with a machine<br />

Optometrist conducting an eye exam<br />

(Do Green initiative in India)<br />

MITSUI CHEMICALS EUROPE GmbH, Functional Chemicals Division<br />

Oststr. 34, 4<strong>02</strong>11 Dusseldorf, GERMANY, http://eu.mitsuichem.com/<br />

E-mail: MR-info@mcie.de, TEL: +49-211-1733277, FAX: +49-211-1719970<br />

Read more about MCI’s Do Green MR in “MR View No.7 & No.8” at the following URL.<br />

http://www.mitsuichem.com/special/mr/resources/mrview.htm


Thermoforming / Rigid Packaging<br />

a-PHA modified PLA<br />

for thermoforming<br />

Recent reports indicate an emerging market trend<br />

toward sustainable packaging options due to environmental<br />

awareness among consumers for alternatives<br />

with improved biodegradability. For instance, the<br />

Foodservice Packaging Institute’s 2015 Trends Report<br />

found that there was an increasing focus on compostable<br />

packaging and the expectation is that more companies<br />

will need to address the demand for sustainable<br />

packaging applications in the near future.<br />

PLA is one of the more commonly used biopolymers<br />

in industrial compostable applications. Because<br />

PLA is derived from renewable sources, it is a sought<br />

after solution for green packaging material. It is well<br />

understood that the physical properties of PLA can<br />

present challenges during processing as well as in<br />

the performance of finished articles. One problem is<br />

the inherent brittleness and relatively low toughness<br />

of PLA that can present challenges in adapting the<br />

biopolymer to new packaging applications. For example,<br />

petroleum-based performance modifiers diminish<br />

biobased content and at increased addition rates can<br />

compromise compostability. This underscores the need<br />

to identify new additives for PLA that improve properties<br />

while maintaining biobased content and industrial<br />

compostability.<br />

Metabolix, a leader in PHA (polyhydroxyalkanoate)<br />

technology, launched a new amorphous PHA (a-PHA)<br />

biopolymer material in 2015. This a-PHA specialty<br />

material is a high molecular weight, low T g<br />

rubber that<br />

extends the additive space for PHA materials. Metabolix<br />

has reported research demonstrating the use of its<br />

a-PHA as process aids and performance modifiers for<br />

PVC as well as performance modifiers for PLA. It should<br />

be noted that the results produced with a-PHA in PVC<br />

and PLA are far superior to those using semi-crystalline<br />

versions of PHA.<br />

Metabolix has shown that a-PHA is an effective modifier<br />

for PLA across a range of applications including food and<br />

consumer product packaging, film, food service ware,<br />

3D printing filament, fibers and nonwovens. In sheet and<br />

thermoforming applications specifically, adding a-PHA at<br />

low loading levels (such as less than 5 %) can eliminate<br />

the brittle fracture commonly associated with the edge<br />

trimming, conveying and cutting of extruded sheets and<br />

thermoformed parts. Adding a-PHA also increases the<br />

impact strength of the finished part, and at loading levels<br />

up to 10 %, an increase in toughness and ductility can be<br />

achieved to such an extent that it prevents brittle failure<br />

and splintering under impact load. Ultimately, a-PHA<br />

modified PLA shows an excellent balance of properties<br />

and is not limited to the 1 % loading limit of a noncompostable<br />

modifier per ASTM D6400.<br />

PLA modified with a-PHA represents an attractive<br />

option for producing thermoformed containers for food<br />

service ware. These containers have high biocontent<br />

and are industrially compostable, per ASTM D6400 and<br />

EN13432. Furthermore, the containers are strong, and<br />

because PHA and PLA are biopolymers with similar<br />

refractive indices, the containers retain a very high level<br />

of clarity.<br />

Consumers, brand owners and regulators continue to<br />

drive incentives to utilize sustainable packaging materials<br />

for carry out options as well as divert food waste from<br />

landfills. Companies looking to meet growing demands<br />

for compostable packaging<br />

options should explore<br />

a-PHA modified PLA<br />

materials as a solution<br />

for their food service and<br />

consumer packaging<br />

applications.<br />

www.metabolix.com<br />

By:<br />

Michael Andrews<br />

Director Product and Application Development<br />

Metabolix, Inc.<br />

Lowell, Massachussetts, USA<br />

14 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11


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Marine pollution / Marine degradation<br />

Plastics, biodegradation, and<br />

risk assessment<br />

Bioplastics: facts and perceptions<br />

After 25 years on the market, we ought to know a lot<br />

about bioplastics. Standardisation has exacted definitions<br />

for the term, testing methods have validated their proper<br />

recovery and, above all, industry has established a clear<br />

purpose for their intended use. However, despite these<br />

foundations, knowledge of what bioplastics actually are<br />

remains confined to small circles of experts while public<br />

opinion is at best confused. Under these circumstances,<br />

the spread of myths and misinformation can produce a<br />

ripple effect that threatens the acceptance of bioplastics<br />

as a whole. Some concepts are often misunderstood (e. g.<br />

bio-based is often synonymized with biodegradability<br />

(in this article we will use the term bioplastics to mean<br />

biodegradable plastics); the existence of standards is<br />

not properly valued, so much so that sometimes we see<br />

“biodegradable” plastics in quotation marks implying that<br />

the supposed biodegradability has yet to be demonstrated.<br />

Bioplastics and the marine environment<br />

The lack of clarity about bioplastics recently surfaced in<br />

discussions of marine litter. The problem of plastic marine<br />

debris is not new; careless waste management requires<br />

a serious investment in awareness, prevention, and<br />

recovery programs at global scales. However, bioplastics<br />

have been unwittingly dragged into the debate, with the<br />

misperception that they could easily solve the chronic<br />

problem of marine litter. The bioplastics industry does not<br />

consider biodegradability as a license for littering in the<br />

environment for several reasons that follow.<br />

The value of biodegradability<br />

Packaging and consumer products must have the<br />

potential to be recovered in some way at their end of<br />

use. In certain contexts, biodegradability allows recovery<br />

through organic recycling. This option is contemplated<br />

by the European Directive on Packaging [1] and it is<br />

beneficial whenever packaging is mixed with kitchen<br />

waste (biowaste). In fact the combination of plastic/<br />

biowaste is not recyclable: food dirties the plastic and<br />

plastics contaminate food. However the combination of<br />

bioplastic/biowaste is recyclable into compost. The CEN<br />

standard EN 13432 [2] identifies packaging for organic<br />

recycling but makes no claims of biodegradability in any<br />

other environment including the sea. The EN 13432 scope<br />

is crystal-clear; there is no room for misunderstanding.<br />

Biodegradable plastics and recycling<br />

The contamination of plastic recycling represents another<br />

issue that surfaces whenever a debate on bioplastics<br />

starts. What’s surprising is that technically speaking<br />

plastics recycling simply does not exist because the term<br />

plastics is a collective term including different materials<br />

that are incompatible with one another and can only be<br />

recycled separately. Cross contamination is always an<br />

impediment to recycling (e. g. non-biodegradable plastics<br />

interfere with recycling of biowaste). The management of<br />

end-of-life must comply with the specific features of each<br />

product and waste stream. Whenever separate collection<br />

is practiced, bioplastics are recoverable through organic<br />

recycling and incentivize proper waste management.<br />

Biodegradation in nature<br />

To avoid misleading communications, it is critical<br />

that the term biodegradable only be associated with<br />

the relevant degradation environment (where) and<br />

its associated conditions (how much and how long).<br />

In agriculture, tests specific to soil define mulch film<br />

Fig. 1:Testing degradation in an aquarium<br />

(photo: HYDRA Institute for Marine Sciences)<br />

Fig. 2: Testing biodegradation in sediment<br />

16 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11


Marine pollution / Marine degradation<br />

By:<br />

Francesco Degli Innocenti<br />

Ecology of Products and Environmental Communication<br />

Novamont,<br />

Novara, Italy<br />

biodegradation because this depositional environment<br />

is microbiologically different from composting. Similarly,<br />

tests specific to the marine environment are now under<br />

development (cf fig. 1). Novamont studied the behaviour<br />

of MATER-BI through ASTM [3] and ISO [4] test methods<br />

(cf fig. 2). Tests performed in marine sediments showed<br />

biodegradation (as CO 2<br />

evolution) in excess of 90 %<br />

(absolute or relative to cellulose) in less than one year;<br />

Certiquality (Certification Institute; Milan,) verified<br />

these results within the European Commission’s pilot<br />

program ETV [5]. These results are in agreement with<br />

previous findings [6].<br />

Biodegradability and risk assessment<br />

How should we interpret these very promising<br />

biodegradation data? Generally speaking, the<br />

environmental risk depends on the concentration of<br />

the environmental stressor and on its residence time<br />

in the environment. The lower the concentration and<br />

the shorter the residence time, the better. Bioplastics<br />

do not immediately disappear upon exposure to the<br />

sea. However, biodegradability is a factor that reduces<br />

the risk by reducing the stressor’s residence time.<br />

Therefore, on one hand the idea of solving the problem<br />

of plastics in the ocean just by shifting to bioplastics is<br />

unfounded. On the other hand, for those applications<br />

where accidental release is certain or very probable,<br />

biodegradability can become a means of decreasing<br />

the environmental risk. Materials that show full and<br />

relatively fast biodegradation may be suitable for plastic<br />

products known to wear down or become stranded<br />

(for example, fishing gear) and scatter into the sea.<br />

Bioplastics like MATER-BI materials hold promise for<br />

aquaculture professional applications (e. g. nets for<br />

mussels farming, cf. fig. 3) where the disposal of plastic<br />

waste is an inevitable outcome.<br />

Fig. 3: Mussel farming nets (Source unknown, found e. g. in<br />

presentations by ISPRA [7])<br />

www.novamont.com<br />

[1] European Parliament and Council Directive 94/62/EC of 20<br />

December 1994 on packaging and packaging waste<br />

[2] EN 13432:2000 Packaging. Requirements for packaging<br />

recoverable through composting and biodegradation. Test scheme<br />

and evaluation criteria for the final acceptance of packaging<br />

[3] ASTM D7991 – 15 Standard Test Method for Determining Aerobic<br />

Biodegradation of Plastics Buried in Sandy Marine Sediment under<br />

Controlled Laboratory Conditions<br />

[4] ISO/DIS 19679 Plastics — Determination of aerobic biodegradation<br />

of non-floating plastic materials in a seawater/sediment interface<br />

— Method by analysis of evolved carbon dioxide<br />

[5] http://iet.jrc.ec.europa.eu/etv/aerobic-biodegradation-mater-biaf03a0-and-mater-bi-af05s0-mater-bi-third-generation-undermarine<br />

[6] F. Degli Innocenti (2012) Single-use carrier bags: littering, bans and<br />

biodegradation in sea water. Bioplastic Magazine 042012 (vol 7):44-<br />

45<br />

[7] http://oceania.research.um.edu.mt/cms/calypsoweb/images/<br />

meeting2/catania-meeting/Andaloro.pdf<br />

bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11 17


Marine pollution / Marine degradation<br />

Designing for biodegradability<br />

in ocean environment<br />

A solution or exacerbating the solution?<br />

The Problem<br />

The issue of plastics and microplastics leaking into the<br />

oceans is the subject of much discussion and concern [1].<br />

Articles in print and electronic media document not only<br />

the unmanaged plastic waste entering the oceans but the<br />

negative impacts on the marine ecosystem as a whole<br />

[2 – 4].<br />

United Nations (UN) estimates suggest that 80 % of<br />

ocean plastic comes from land based sources, and the<br />

actual number is probably higher [1]. These estimates<br />

are based on the fact that most plastic waste is typically<br />

buoyant and that much of it could be found floating across<br />

the ocean in the large gyres. The remaining 20 % of<br />

ocean plastic is believed to originate from marine-based<br />

sources, such as oil rigs, fishing vessels, piers, and boats<br />

transporting freight or passengers.<br />

In a recent paper published in the high impact peer<br />

reviewed journal Science [5], we reported that in 2012, 4.8<br />

to 12.7 million tons of plastics leaked into oceans from<br />

land based mismanaged wastes in 192 countries located<br />

within 50 km of a coast – primarily from the developing<br />

countries of Asia. This is shown in detail in figure 1. The<br />

mismanaged plastic waste shown as blue bars goes<br />

from 31.9 million tons in 2010 to 69.9 million tons in 2<strong>02</strong>5<br />

without any intervention and business as usual. The red,<br />

green, and orange bars represent three different scenarios<br />

of mismanaged waste leakage into the oceans – 15 %,<br />

25 %, and 40 % for each of the years. Therefore, without<br />

any intervention, 10.4 to 27.7 million tons of mismanaged<br />

plastic waste in these costal countries will leak into the<br />

oceans by 2<strong>02</strong>5. These are conservative figures and other<br />

literature papers put this number much higher.<br />

Is marine biodegradability a solution or<br />

problem?<br />

In response, scientists and technologists in academe<br />

and industry are developing and introducing plastics<br />

for biodegradability in the marine environment as<br />

a solution to the problem of plastic pollution of the<br />

oceans. There are ASTM standards for determining<br />

the percent biodegradability in marine environment –<br />

ASTM D6691 is Standard Test Method for Determining<br />

Aerobic Biodegradation of Plastic Materials in the Marine<br />

Environment by a Defined Microbial Consortium or<br />

Natural Sea Water Inoculum; ASTM D7473-12 Standard<br />

Test Method for Weight Attrition of Plastic Materials<br />

in the Marine Environment by Open System Aquarium<br />

Incubations; a new Standard Test Method for Determining<br />

Aerobic Biodegradation of Plastics Buried in Sandy<br />

Marine Sediment under Controlled Laboratory Conditions.<br />

The operating temperatures for these laboratory scale<br />

test methods are around 23 to 28 °C. Certain PHA<br />

(polyhydroxyalkanoates) films show 80 %+ biodegradability<br />

in river water at 25 °C as shown in figure 2. Synthetic<br />

polyesters – polyethylene succinate, polyethylene adipate,<br />

and polybutylene adipate are biodegradable in river water<br />

at 25 °C as shown in figure 3.<br />

Fig. 1: Land based mismanaged plastic waste from 192 countries located within 50 km of a coast –<br />

primarily from the developing countries of Asia [5]<br />

80<br />

70<br />

60<br />

Mismanaged plastic waste (MMT/year)<br />

15% leakage to ocean<br />

25% leakage to ocean<br />

40% leakage to ocean<br />

50<br />

MMT<br />

40<br />

30<br />

20<br />

10<br />

0<br />

2010 2015 2<strong>02</strong>0 2<strong>02</strong>5<br />

Year<br />

18 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11


Marine pollution / Marine degradation<br />

By:<br />

Ramani Narayan<br />

Distinguished Professor,<br />

and Sayli Bote<br />

Research Assistant at Biobased Materials Research Group<br />

Michigan State University<br />

East Lansing, Michigan, USA<br />

However, the ocean (marine) environment is NOT<br />

a managed disposal environment like composting or<br />

anaerobic digestion which are sound end-of-life options<br />

for food and biowaste components of the solid waste<br />

stream along with truly and completely biodegradablecompostable<br />

plastics. Furthermore, ocean temperatures<br />

drop precipitously as you go down in depth (4 ° C on reaching<br />

2,000 m) and the ocean environment can be much different<br />

and less active than the lab test environment. So these<br />

marine biodegradable plastics (which show complete<br />

biodegradability in a lab test method) could remain in<br />

ocean environments for very long period of time and cause<br />

serious environmental impacts that have been recorded<br />

for ocean microplastic wastes.<br />

Therefore, designing for marine biodegradability is<br />

NOT A SOLUTION to plastics pollution in the ocean<br />

environment. The goal should be to prevent these<br />

plastics from entering the ocean environment in the first<br />

place. For products used in the marine environment like<br />

fishing nets, lobster pots, biodegradability may provide a<br />

value attribute so that if it is inadvertently lost and enter<br />

into the ocean environment they are utilizable as food by<br />

the microbial populations over a period of time. However,<br />

this cannot and should not be used for making marketing<br />

claims especially in Business to Consumer (B2C)<br />

communication. The marine biodegradability test method<br />

Standards are useful in evaluating the persistence, fate,<br />

and impact of plastics in the ocean environment but not to<br />

be used in marketing claims.<br />

Solution for microplastics in ocean<br />

environment and the role for biodegradability.<br />

Another major finding of the Science paper (5) is that<br />

reducing the amount of land based mismanaged wastes<br />

generated in these developing Asian countries would<br />

significantly reduce plastics waste entering into the<br />

oceans. For example:<br />

• Reducing mismanaged waste by 50 % in the Top 5<br />

countries corresponds to a 26 % reduction.<br />

• Reducing mismanaged waste by 50 % in Top 10<br />

countries corresponds to a 34 % reduction.<br />

• Reducing mismanaged waste by 50 % in Top 20<br />

countries corresponds to 45 % reduction.<br />

• Reducing mismanaged waste by 50 % in Top 35<br />

countries corresponds to 75 % reduction.<br />

Figure 4 schematically shows the effect of this reduction<br />

on the overall land based mismanaged waste generation<br />

(blue bar) – from 69.1million tons with zero intervention<br />

BOD-biodegradability (%)<br />

100<br />

80<br />

60<br />

40<br />

20<br />

P(3HB-co-36 % 3HP)<br />

P(3HB)<br />

P(3HP)<br />

0<br />

0 7 14 21 28<br />

Time (day)<br />

Fig. 2: Biodegradability of PHA (polyhydroxyalkanoates) films in<br />

river water at 250 °C<br />

Fig. 3: Biodegradability of synthetic polyesters in river water at<br />

25 °C [5]<br />

BOD-biodegradability (%)<br />

100<br />

80<br />

60<br />

40<br />

20<br />

Poly(ethyelene succinate)<br />

Poly(ethylene adipate)<br />

Poly(butylene adipate)<br />

Poly(butylene sebacate)<br />

0<br />

0 7 14 21 28<br />

Time (day)<br />

bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11 19


Marine pollution / Marine degradation<br />

in 2012 to 17.1 million tons in 2<strong>02</strong>5 by just reducing the<br />

mismanaged waste by 50 % in the top 35 countries. The red,<br />

green, and orange bars show the corresponding reductions<br />

in the amount of the mismanaged plastic waste entering the<br />

oceans based on 15 %, 25 %, and 40 % leakage – for example<br />

if one assumes the 15 % leakage scenario, the amount of<br />

plastic waste entering the oceans is reduced from 10.4 million<br />

tons to 2.1 million tons (red bar, figure 4).<br />

Therefore, developing systems to divert land based<br />

mismanaged plastic waste to managed end-of-life disposal<br />

systems like recycling, waste-to-energy, and composting or<br />

anaerobic digestors would prevent the mismanaged plastic<br />

waste from entering into the oceans. These efforts along with<br />

educational and consumer awareness messaging can clearly<br />

advance the goal to cleaner ocean environment.<br />

Conclusions<br />

Keep plastics out of the marine environment through:<br />

• Recover organics (biowastes) and compostable plastics<br />

through compostable and anaerobic digestion. Design for<br />

compostability/biodegradability in managed end-of-life disposal<br />

systems for single use, disposable, packaging and molded<br />

products and remove it from the mismanaged waste stream<br />

• Recover value plastics for mechanical or chemical<br />

recycling including waste to energy<br />

References<br />

1. Microplastics in the ocean: A global assessment, United Nations Joint<br />

Group of Experts on the Scientific Aspects of Marine Pollution (GESAMP),<br />

Working Group 40, 2015, gesamp.org.<br />

2. ‘Plastics, the environment and human health’ compiled by R. C.<br />

Thompson, C. J. Moore, F. S. vom Saal and S. H. Swan Phil. Trans. R. Soc.<br />

London, Ser. B 264 (2009) doi:10.1098/rstb.2009.0030<br />

3. A. A. Koelmans, E. Besseling, and E. M. Foekema, “Leaching of plastic<br />

additives to marine organisms,” Environmental Pollution, 2014, Volume<br />

187, pp. 49–54; C. K. Pham, E. Ramirez Llodra, C. H. S. Alt, T. Amaro, M.<br />

Bergmann, M. Canals, J. B. Company, J. Davies, G. Duineveld, F. Galgani,<br />

K. L. Howell, V. A. I. Huvenne, E. Isidro, D. O. B. Jones, G. Lastras, T.<br />

Morato, J. N. Gomes-Pereira, A. Purser, H. Stewart, I. Tojeira, X. Tubau, D.<br />

V. Rooij, and P. A. Tyler, “Marine litter distribution and density in European<br />

seas, from the shelves to deep basins,” PLoS ONE, 2014, Volume 9,<br />

Number 4; Y. C. Jang, J. Lee, S. Hong, J. Y. Mok, K. S. Kim, Y. J. Lee, H.<br />

W. Choi, H. Kang, and S. Lee, “Estimation of the annual flow and stock<br />

of marine debris in South Korea for management purposes,” Marine<br />

Pollution Bulletin, 2014, Volume 86, Numbers 1–2, pp. 505–11; Trash free<br />

seas report: Every piece, every person, every community matters; Results<br />

from the 2014 International Coastal Cleanup, Ocean Conservancy, 2015,<br />

oceanconservancy.org.<br />

4. C. M. Rochman, E. Hoh, T. Kurobe, and S. J. Teh, “Ingested plastic<br />

transfers hazardous chemicals to fish and induces hepatic stress,”<br />

Scientific Reports, 2013, Volume 3; C. M. Rochman, T. Kurobe, I.<br />

Flores, and S. J. Teh, “Early warning signs of endocrine disruption in<br />

adult fish from the ingestion of polyethylene with and without sorbed<br />

chemical pollutants from the marine environment,” Science of the Total<br />

Environment, 2014, Volume 493, pp. 656–61.<br />

5. Jenna R. Jambeck, Roland Geyer, Chris Wilcox, Theodore R. Siegler,<br />

Miriam Perryman, Anthony Andrady, Ramani Narayan, Kara Lavender Law,<br />

Science, Vol 347, <strong>Issue</strong> 6223, pg 768, 2015<br />

6. Y. Doi et al. Polym. Deg. & Stab., 51, 281, 1996<br />

Fig 4: Reducing mismanaged plastic waste by controlled managed waste systems reduces plastic waste<br />

leakage into ocean<br />

80<br />

70<br />

60<br />

Mismanaged plastic waste (MMT/year)<br />

15 % leakage to ocean<br />

25 % leakage to ocean<br />

40 % leakage to ocean<br />

50<br />

MMT<br />

40<br />

30<br />

20<br />

10<br />

0<br />

0 26 34 41 75<br />

Reduction (%)<br />

Magnetic<br />

for Plastics<br />

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20 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11


Marine pollution / Marine degradation<br />

PHA – truly biodegradable<br />

Most packaging will far outlast the useful life of any of<br />

the products they protect, causing a growing concern<br />

for packaging disposal due to the shortage of space<br />

for landfills. Furthermore, burning is not a sustainable option<br />

in many countries since some traditional plastics can create<br />

toxic fumes which cause damage to people’s health and the<br />

environment.<br />

The advantages of traditional plastics are widely recognized.<br />

The challenge is making materials that are just as effective<br />

while eliminating any detrimental effects to our planet. There<br />

is a tremendous amount of research in the area of bioplastics,<br />

with the promise of medium chain length (mcl) PHAs leading<br />

the way as a viable alternative to traditional polymers.<br />

To understand the difference between mcl PHAs and other<br />

biopolymer alternatives, it is helpful to understand what mcl<br />

PHA’s are and how they are made. Medium chain length PHA<br />

polyesters are produced by a natural bacterial fermentation<br />

process. Selected bacteria are fed natural food sources such<br />

as sugars, lipids, or fatty acids to produce PHAs granules as<br />

an energy reserve, much like humans store fat in their bodies.<br />

These granules are harvested by fracturing the cell walls of the<br />

host bacteria and separating the PHA granules from the cell<br />

debris. This highly controlled process yields polyesters within<br />

specific ranges of molecular weights, chain lengths, and comonomers<br />

allowing MHG to produce polymers with a wide<br />

array of physical and mechanical properties, including barrier<br />

properties suitable for food packaging. Extensive testing is<br />

currently underway with committed brand owners who are<br />

working to validate these materials in several manufacturing<br />

disciplines. Commercial launch of elected products will occur<br />

before the end of <strong>2016</strong>, with PHA being commercially available<br />

to the general marketplace in 2018.<br />

Unlike most biopolymers available today, PHA is not just<br />

compostable in industrial composting plants. Although<br />

industrial compostability is a giant step in the right direction,<br />

the conditions must be conducive for hydrolysis to promote the<br />

polymer decomposition. PHA polymers degrade enzymatically<br />

and have a decomposition profile similar to cellulose.<br />

Virtually any environment that contain microbials will utilize<br />

PHA polymers as a food source and consume it. Thus PHA<br />

is, what MHG calls “truly biodegradable” – meaning it also<br />

degrades in a home composter as well as in soil, sweet- and<br />

sea water. These claims have been independently verified by<br />

the most recognized certification body in the world, Vinçotte<br />

International. Vinçotte awarded MHG all available certifications<br />

for safe biodegradation, including their first ever “OK Marine<br />

Biodegradable” certification, validating the legitimacy of the<br />

testing to recognized international standards.<br />

MHG is proud of achieving this milestone as a step toward<br />

helping the planet. Over the past years, the growing level of<br />

pollution contaminating the oceans has been highlighted<br />

in all traditional and social media. The ugly truth is that<br />

pollution is a blight on all environments wherever it occurs,<br />

and proven to be very difficult to control in some areas. MHG<br />

does include biodegradability as one of many attributes of<br />

this amazing new polymer. However, MHG in no way promotes<br />

or condones the improper disposal of any material. Only the<br />

brand owners can choose to best way to market the attributes<br />

of MHG polymers since they alone determine what features<br />

bring value to their brand or product. But when litter does<br />

occur and PHA materials inadvertently find their way into the<br />

ecosystem, PHA materials by MHG provide the final level of<br />

insurance, allowing microorganisms to return these polymers<br />

to the earth. Just like they would with any other natural food<br />

source in their environment.<br />

www.mhgbio.com<br />

By:<br />

John T. Moore<br />

Vice President- Business Development<br />

Meredian Holdings Group<br />

Bainbridge, Georgia, USA<br />

bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11 21


Marine pollution / Marine degradation<br />

Trash is mobile<br />

OK biodegradable MARINE certification<br />

By:<br />

Petra Michiels<br />

Contract Manager<br />

Vinçotte<br />

Vilvoorde, Belgium<br />

If gravity would not exist<br />

Trash is mobile. Certainly plastic items are usually very<br />

light and are transported by rivers and winds. Gravity brings<br />

garbage down to the sea level. If gravity would not exist, the<br />

floating trash islands at sea would not have grown to such<br />

vast extensions.<br />

The cause of marine debris is mainly located at land.<br />

Depending on the literature, land based sources account<br />

for 60 to 90 % of marine litter globally. Solving a problem by<br />

tackling its root is always more effective than just fighting its<br />

symptoms. Therefore the solution for marine debris has to be<br />

sought mostly at land.<br />

Prevention and remediation<br />

When it comes to solving problems, of whatever kind, this<br />

can be done either before the problem occurs: by prevention,<br />

or afterwards, by remediation.<br />

In the case of marine debris, prevention can be stimulated<br />

by market instruments such as subsidies or oppositely taxes,<br />

or a legal ban of certain materials. Also communication and<br />

education can change attitudes regarding litter. Any litter that<br />

is avoided, whether it is high in the mountains, in cities or at<br />

the sea shores, helps against the marine debris problem.<br />

Remediation is the removal of garbage. This can be done by<br />

active human intervention. Or if a material is biodegradable<br />

in a marine environment, it disappears without further<br />

interaction needed.<br />

Dread in perspective<br />

Marine biodegradable products are a very sensitive topic.<br />

The perceived dread is that it could accidently encourage<br />

people to litter at sea. However, this perception is based on<br />

the idea that marine debris is mainly created at sea. And<br />

also on the thought that people would indeed increase their<br />

littering when they know a product biodegrades. These are<br />

assumptions that need to be put in perspective.<br />

Scope of products<br />

When launching the OK biodegradable MARINE certification<br />

system in March 2015, the risk of misunderstandings amongst<br />

consumers was treated with high priority. Therefore in this<br />

certification system, a clear distinction is made between:<br />

(1) the certification of the claim of marine biodegradation and<br />

(2) the authorization to communicate about this certification.<br />

Only for a very limited group of products, authorization to<br />

communicate on the product about the OK biodegradable<br />

MARINE certificate is allowed. It concerns products that<br />

are actually used – and therefore unavoidably spilled – in<br />

the marine environment (e. g. fishing line, fishing baits, cull<br />

panel, etc.). For these products, marine biodegradability can<br />

actually be a real interest to their consumers.<br />

Mentioning the OK biodegradable MARINE logo on all<br />

other products that could possibly encourage the customer<br />

to marine littering is not allowed. For these products<br />

marine biodegradability is an unknown functionality with an<br />

intrinsic added value: if it inadvertently ends up in the marine<br />

environment, it will be utilized by microorganisms.<br />

Verification of the claim<br />

Marine biodegradability is an added value to any product<br />

or packaging regardless of where it is consumed. The<br />

chance that it eventually ends up at sea will always exist.<br />

Any supplier who invests in adding this functionality to his<br />

product or packaging should have the opportunity to have this<br />

information verified according to international standards. This<br />

22 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11


Marine pollution / Marine degradation<br />

verification is not only a reference to harmonize the claim<br />

but also offers the supplier the opportunity to distinguish<br />

his truly marine biodegradable product from any doubtful<br />

claim of his competitors.<br />

Therefore there is a need for a neutral verification<br />

system of the claim of marine biodegradability. In March<br />

2015 Vinçotte has launched the OK biodegradable MARINE<br />

certification system. Before a product can be certified,<br />

it is tested in four different ways, based on the following<br />

standards:<br />

• biodegradation: measured by oxygen consumption or<br />

CO 2<br />

production: OECD 306, ISO 16221, ASTM D6691<br />

• ecotoxicity: water quality is measured on aquatic<br />

organisms (daphnids, fish, algea, cyanobacteria, …<br />

according to the relevant OECD standards or OPPTS<br />

documents)<br />

• disintegration: in lack of an international standard, a<br />

set of requirements (delay, temperature, replicates,<br />

pass levels, …) is developed specifically for the OK<br />

biodegradable MARINE certification in cooperation with<br />

international experts<br />

• limits of heavy metals and fluor content: ISO 17088,<br />

and a limit for cobalt as defined in ASTM D6400<br />

To conclude<br />

It is hard to tell which remedy will be proven to be most<br />

effective against marine debris. Trash that has the inherent<br />

capacity of disappearing without human intervention is<br />

without no doubt a plus. Having said this, negative side effects<br />

e. g. possible confusion of consumers must not be overlooked.<br />

However the need for a unique verification system in order<br />

to avoid all sorts of claims regarding marine biodegradability<br />

is not in dispute.<br />

www.okbiodegradable.be<br />

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Subject to changes<br />

Call for Papers now open<br />

www.bioplastics-breakfast.com<br />

Contact: Dr. Michael Thielen (mt@bioplasticsmagazine.com)<br />

At the World‘s biggest trade show on plastics and rubber:<br />

K‘<strong>2016</strong> in Düsseldorf bioplastics will certainly play an<br />

important role again.<br />

On three days during the show from Oct 20 - 22, <strong>2016</strong><br />

bioplastics MAGAZINE will host a Bioplastics Business<br />

Breakfast: From 8 am to 12 noon the delegates get the<br />

chance to listen and discuss highclass presentations and<br />

benefit from a unique networking opportunity.<br />

The trade fair opens at 10 am.<br />

bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11 23


Marine pollution / Marine degradation<br />

UNEP Report<br />

on biodegradable plastics & marine litter<br />

Summarized and interpreted by<br />

Karen Laird and Michael Thielen<br />

Photo: Ludwig Tröller / CreativeCommons<br />

In November 2015 the United Nations Environment Programme<br />

(UNEP) published a report, entitled “Biodegradable<br />

Plastics and Marine Litter. Misconceptions,<br />

Concerns and Impacts on Marine Environments”.<br />

The objective of (the) briefing paper is to provide a<br />

concise summary of some of the key issues surrounding<br />

the biodegradability of plastics in the oceans, and whether<br />

the adoption of biodegradable plastics will reduce the<br />

impact of marine plastics overall [1].<br />

Plastic debris is ubiquitous in the marine environment,<br />

comes from a multitude of sources and is composed of a<br />

great variety of polymers and copolymers [1].<br />

It has been suggested that plastics considered to be<br />

biodegradable may play an important role in reducing the<br />

impact of ocean plastics. Environmental biodegradation is<br />

the partial or complete breakdown of a polymer as a result<br />

of microbial activity, into CO 2<br />

, H 2<br />

O and biomasses, as a<br />

result of a combination of hydrolysis, photodegradation<br />

and microbial action (enzyme secretion and within-cell<br />

processes). Although this property may be appealing, it is<br />

critical to evaluate the potential of ‘biodegradable’ plastics<br />

in terms of their impact on the marine environment, before<br />

encouraging wider use [1].<br />

The report found that complete biodegradation of plastics<br />

occurs in conditions that are rarely, if ever, met in marine<br />

environments, with some polymers requiring industrial<br />

composters and prolonged temperatures of above 50 °C<br />

to disintegrate. There is also limited evidence suggesting<br />

that labelling products as biodegradable increases the<br />

public’s inclination to litter, as some people are attracted<br />

by technological solutions as an alternative to changing<br />

behaviour. Labelling a product as biodegradable may be<br />

seen as a technical fix that removes responsibility from<br />

the individual, resulting in a reluctance to take action.<br />

As stated in the report, plastics most commonly used<br />

for general applications, such as polyethylene (PE),<br />

polypropylene (PP) and polyvinyl chloride (PVC) are not<br />

biodegradable in marine environments (nor in any other,<br />

MT). Polymers, which biodegrade under favourable<br />

conditions on land, such as acetyl cellulose (AcC),<br />

UN Photo Martine Perret<br />

24 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11


Marine pollution / Marine degradation<br />

polybutylene succinate (PBS), polycaprolactone (PCL),<br />

polyvinyl alcohol (PVA) and others are much slower to<br />

break up in the ocean and their widespread adoption<br />

is likely to contribute to marine litter and consequent<br />

undesirable consequences for marine ecosystems.<br />

“Recent estimates from UNEP have shown as much as<br />

20 million tonnes of plastic end up in the world’s oceans<br />

each year,” said Achim Steiner, Executive Director of the<br />

UN Environment Programme (UNEP) in a press release.<br />

“Once in the ocean, plastic does not go away, but breaks<br />

down into microplastic particles. This report shows there<br />

are no quick fixes, and a more responsible approach to<br />

managing the lifecycle of plastics will be needed to reduce<br />

their impacts on our oceans and ecosystems.”<br />

These microplastics have, in recent years, become a<br />

source of growing concern. Microplastics are particles<br />

up to five millimetres in diameter, that are either<br />

manufactured or created when plastic breaks down. Their<br />

ingestion has been widely reported in marine organisms,<br />

including seabirds, fish, mussels, worms and zooplankton.<br />

The UNEP study also analyzed the environmental<br />

impacts of oxo-degradable plastics, enriched with a pro<br />

oxidant, such as manganese, which precipitates their<br />

fragmentation. It found that in marine environments<br />

even this fragmentation is fairly slow and can take<br />

up to 5 years, during which products made from this<br />

type of plastic continue to pollute the ocean. Moreover,<br />

convincing evidence showing that oxo-degradable<br />

polymers completely biodegrade to CO 2<br />

and water after<br />

fragmentation is still lacking.<br />

According to UNEP, oxo-degradable plastics can pose<br />

a threat to marine ecosystems even after fragmentation.<br />

The report says it should be assumed that microplastics<br />

created in the fragmentation process remain in the ocean,<br />

where they can be ingested by marine organisms and<br />

facilitate the transport of harmful microbes, pathogens<br />

and algal species. The report also quotes a UK government<br />

review that stated that “oxo-degradable plastics did not<br />

provide a lower environmental impact compared with<br />

conventional plastics”. The recommended solutions for<br />

dealing with end-of-life oxo-degradable plastics were<br />

incineration (first choice) or landfill. In addition, the<br />

authors observed that: as the (oxo-degradable) plastics<br />

will not degrade for approximately 2 – 5 years, they will still<br />

remain visible as litter before they start to degrade.<br />

The report more or less confirms what many in the<br />

industry have known for a long time, and it contains<br />

important information for the public at large – both as<br />

regards oxo-degradable plastics and biodegradable<br />

plastics.<br />

Well-written and well-researched, the report is by<br />

no means an attack on biobased plastics, but rather an<br />

attempt to get a message out and to create awareness.<br />

As its authors put it: “Assessing the impact of plastics in<br />

the environment, and communicating the conclusions to<br />

a disparate audience is challenging. The science itself is<br />

complex and multidisciplinary. Some synthetic polymers<br />

are made from biomass and some from fossil fuels,<br />

and some can be made from either. Polymers derived<br />

from fossil fuels can be biodegradable. Conversely,<br />

some polymers made from biomass sources, such<br />

as maize, may be non-biodegradable. Apart from the<br />

polymer composition, material behaviour is linked to<br />

the environmental setting, which can be very variable in<br />

the ocean. The conditions under which biodegradable<br />

polymers will actually biodegrade vary widely.”<br />

And the report closes with the final conclusion: On the<br />

balance of the available evidence, biodegradable plastics<br />

will not play a significant role in reducing marine litter [1].<br />

[1] UNEP 2015. Biodegradable Plastics & Marine Litter. Misconceptions,<br />

Concerns and Impacts on Marine Environments. Nairobi.<br />

a pdf-version is available at bit.ly/1R7IALI<br />

Photo: M. Thielen,<br />

bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11 25


Marine pollution / Marine degradation<br />

Statement of Open Bio<br />

to the UNEP (2015) report on „Biodegradable Plastics and Marine Litter.<br />

Misconceptions, concerns and impacts on marine environments.”<br />

Executive summary<br />

While the Open- Bio consortium generally appreciates the<br />

UNEP report (cf. pp. 24 in this issue of bM) for its contributions<br />

to explaining and clarifying many aspects concerning the<br />

relation between different plastic materials and marine<br />

plastic litter, several aspects are criticized as well.<br />

• Both the summary and the conclusion simplify matters<br />

too much, thus inviting confusion by the public and<br />

policy makers.<br />

• Some of the final conclusions concerning the possible<br />

role of biodegradable plastics are not solution- oriented<br />

and remain rather pessimistic, whereas the main text<br />

offers several well- elaborated segments of the general<br />

topic, where solutions via market regulation, legislation,<br />

directed scientific research and industrial development<br />

could be achieved in relatively short time or may be<br />

readily adopted through political action.<br />

• The statements on rate of biodegradation and impact<br />

made by the report are not differentiated enough. More<br />

research is clearly needed.<br />

• In terms of communication and labelling, even more<br />

concise wording is needed and a strict distinction<br />

should be made between B2B communication and B2C<br />

communication in order to avoid litter.<br />

The Open- Bio statement furthermore offers some<br />

corrections to technical mistakes of the UNEP report and<br />

preliminary results from the project’s research.<br />

The Open- Bio group concludes that biodegradable<br />

plastics are not a solution to littering. Littering<br />

must be opposed by means of prevention, waste<br />

management (that includes separate collection and<br />

organic recycling of biodegradable plastics), public<br />

awareness, etc. On the other hand, plastics that<br />

are shown to be truly biodegradable in the marine<br />

environment could be profitably used in those<br />

applications where dispersion in the sea is certain or<br />

highly probable (e. g. fishing gear, fish farming gear,<br />

beach gear, paint, etc.).<br />

General considerations<br />

It is certain that littering needs to be avoided and<br />

reduced possibly to zero by all means (prevention,<br />

cutting waste streams, raising public awareness,<br />

etc.). But for certain applications it is inevitable that<br />

plastic products will enter the oceans, via rivers or<br />

e. g. by loss of fishing gear or wear of tourist beach<br />

equipment. Wouldn’t it be better if this litter was<br />

biodegradable? This is stated with always seeing that<br />

biodegradable litter is still litter, and should also be<br />

avoided at all means! However, it will at least not<br />

remain there forever, compared to non- biodegradable<br />

plastic litter.<br />

Rate of biodegradation and its risk assessment<br />

A point of critique concerns the frequently mentioned rate<br />

of (bio)degradation in the UNEP report. It is not differentiated<br />

between the inherent biodegradation rate of an industrial<br />

biodegradable material and the degradation rate of the item<br />

that finally ends up in the environment. The report states that<br />

biodegradable plastics do degrade under marine conditions<br />

but are much slower than in industrial composting, and<br />

also when tested in gastrointestinal fluids of a turtles, and<br />

will therefore still harm the marine environment. Most<br />

biodegradable plastics are not water- soluble. This means<br />

that the biodegradable plastic products will not immediately<br />

“disappear” when they reach the sea but persist in this<br />

environment for a given time (a residence time). By means of<br />

a risk assessment it is possible to characterize the magnitude<br />

of risks to ecological receptors (e.g. mammals, birds, fish,<br />

corals, microorganisms or even whole ecosystems) from the<br />

stressors, that may be present in the environment. Plastic<br />

items littered to the sea do have impact on several levels,<br />

some of which are well documented and some still lack<br />

scientific knowledge (GESAMP 2015, Bergmann et al. 2015).<br />

Impacts<br />

In terms of impact to the marine environment, little<br />

research has been completed comparing non- biodegradable<br />

and biodegradable plastics. There are scientific studies on<br />

the impacts of non- biodegradable litter and parts of the<br />

knowledge can be transferred to biodegradable litter, but<br />

not all of it. More research on the impact of biodegradable<br />

polymers is clearly needed. Therefore we think that the<br />

statement of the UNEP report is important, however a bit<br />

premature.<br />

The global perspective<br />

In the discussion we miss the global view and also more<br />

options for developing countries. Many have currently<br />

no (or insufficient) waste management infrastructures<br />

in place. But the plastic consumption in many of these<br />

countries (esp. China, Indonesia, India, etc.) are expected<br />

to rise tremendously in the coming years. In the case of<br />

mismanagement and the waste ending up in the ocean, it<br />

would not remain there forever when it is biodegradable<br />

under marine conditions.<br />

Recycling<br />

Biodegradable plastics do not hinder plastic recycling<br />

by being ‘biodegradable’ or ‘compostable’ (investigated<br />

by Open- Bio consortium, Task 6.4), but because recycling<br />

requires pure waste streams. Any contamination of a waste<br />

stream of a particular plastic (e. g. PE) with another type<br />

of polymer (whether it is biodegradable or not) requires<br />

good separation practices. Only so called ‘oxo- degradable’<br />

plastics pose a threat to plastic recycling by compromising<br />

the quality of the final product.<br />

26 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11


This is the short version - source:<br />

www.biobasedeconomy.eu/media/downloads/<strong>2016</strong>/<strong>02</strong>/16-<strong>02</strong>-01_<br />

Open-Bio-comment-on-UNEP-report-FINAL-short.pdf<br />

The long version is available at:<br />

bit.ly/1Ts8bCR<br />

Labelling<br />

The labelling of ‘oxo- degradable’ plastics as<br />

‘biodegradable’ or ‘compostable’ is not correct (see<br />

EN 13432:2000) because these materials simply<br />

fragment and do not biodegrade, no matter where<br />

their life cycle will end. Open- Bio confirms that a<br />

label or certification should be not misleading and<br />

should not lead to wrong behaviours. The information<br />

should preferably only be used at the industrial<br />

level to describe material properties to business<br />

partners, but not on a broad consumer level unless<br />

necessary. Based on the current state of knowledge<br />

we recommend also not to label a product for the<br />

general public unless necessary for the specific<br />

application, but to enforce by political means that<br />

those products which will certainly or probably end up<br />

in the marine environment need to be biodegradable<br />

in the specific marine environment of application. The<br />

Open- Bio team is currently working on an update of<br />

the standard methodology taking into account the<br />

current standards for marine biodegradation (see<br />

Open- Bio D5.5).<br />

First results from Open- Bio and further<br />

research<br />

First results from Open- Bio do confirm the<br />

statement of the report that degradation is slower<br />

under marine conditions than under composting<br />

conditions and that it depends on the material type<br />

and specific environmental conditions. The work<br />

within Open- Bio shows that the tested polymers do<br />

biodegrade under optimal laboratory conditions.<br />

Linking the lab data with the data we obtain from field<br />

and mesocosm experiments will allow us to validate<br />

the lab test. Further ecotoxicological tests should be<br />

added to the tests, which will provide more insight on<br />

the impact of biodegradation. The goal is to develop a<br />

test scheme and specifications (time and percentage<br />

of biodegradation, temperature range, etc.) for<br />

the biodegradation under marine conditions to be<br />

finalised by a standardisation organisation. That will<br />

provide policy makers and the industry with a good<br />

instrument to implement biodegradable polymers<br />

where they can be part of a concept to mitigate<br />

unavoidable marine litter.<br />

Polymers that are proven to be biodegradable<br />

in the marine environment can thus improve the<br />

situation in case plastic is not to be replaced by other<br />

materials, in concert with all possible measures like<br />

prevention, waste management, public awareness,<br />

etc. Summarising the mentioned points, we think that<br />

the public, mass- media, industry and policy makers<br />

have a great potential and possibilities to support the<br />

protection of the environment here. •<br />

RETHINKING<br />

PLASTICS<br />

29/30 November <strong>2016</strong><br />

Steigenberger Hotel Berlin<br />

SAVE<br />

THE<br />

DATE!<br />

For more information email:<br />

conference@european-bioplastics.org<br />

@EUBioplastics #eubpconf<strong>2016</strong><br />

www.conference.european-bioplastics.org<br />

bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11 27


Booth Company on Floorplan<br />

C8B05 Anhui Tianyi Environmental Protection Technology Co., Ltd.<br />

N3P11 AU CO., LTD. 1<br />

N3L09 BASF (China) Company Ltd. 2<br />

N3M15 bioplastics MAGAZINE 3<br />

N3A21 China XD Plastics Company Ltd.<br />

N3J61 Coating p. Materials co., Ltd.<br />

N1F01 Croda Europe Ltd<br />

N4F01 Dandong Ritian Nano Technology CO., LTD.<br />

N3S45 Doill Ecotec Co., Ltd., Korea 4<br />

N3S41 Dongguan Xinhai environmental protection material Co., Ltd. 5<br />

N2E51 Emery Oleochemicals HK LTD<br />

N3K01 EnerPlastics L.L.C. 6<br />

N1C21 Evonik Degussa (China) Co., Ltd.<br />

N3P59 Fukutomi Company Ltd.<br />

N4M01 Gema Elektro Plastik VE Elektronik San. Dis Tic. A.S.<br />

N3L05 GRABIO Greentech Corporation 7<br />

C9B51 GuangDong ShunDe LuHua Photoelectric New Mat. Ind.Co.<br />

N2R01 Hairma Chemicals (GZ) Ltd.<br />

N4L21 Hebei Jingu Plasticizer Co., LTD.<br />

N2S15 Jacobson van den Berg (Hong Kong) Ltd<br />

N3R41 Jetwell Trading Limited<br />

N3M19 Jiangsu Jinhe Hi-tech Co.,Ltd 8<br />

N3K15 Jiangsu Torise Biomaterials Co., Ltd 9<br />

C10F17 Jinan Shengquan Group Co.,Ltd<br />

N3L01 JinHui ZhaoLong High-Tech Co.,Ltd 10<br />

N1G41 Kingfa Science and Technology Co., Ltd<br />

N1G01 Kuraray (Shanghai) Co., Ltd<br />

C13F61 Lifeline Technologies<br />

C2E41 Maosheng Environmental Protection Technology Co.,Ltd<br />

N3M15 Matchexpo 3<br />

N3L07 Minima Technology Co., Ltd. 11<br />

N3L51 Miracll Chemicals Co., Ltd.<br />

N1E01 Mitsubishi Chemical Corporation<br />

N3K09 Natureworks LLC 12<br />

N1B01 Ngai Hing Hong Plastic Materials (HK) Ltd.<br />

N3K05 Polyalloy Inc. 13<br />

W1D55 Procotex Corporation<br />

N3P01 Proviron Functional Chemicals N.V. 14<br />

C11F41 Rajiv Plastic Industries<br />

N3K11 Reverdia 15<br />

N3L21 Roquette 16<br />

N2D41 Samyang Corporation<br />

N4J61 Shandong Jiqing Chemcal Co., Ltd.<br />

C8E51 Shanghai Xiner Low-carbon Environmental Technology Co., Ltd<br />

N4K09 Shenzhen All Technology Limited<br />

N3M11 Shenzhen Esun Industrial Co., Ltd. 17<br />

N3M17 Shenzhen Polymer Industry Association 30<br />

N1L25 Sukano Sdn Bhd<br />

N3M05 Suzhou Hanfeng New Material Co.,Ltd. 18<br />

N3S51 Suzhou Hydal Biotech Co.,Ltd 19<br />

N3S49 Suzhou Mitac Precision Technology Co., Ltd. 20<br />

N3M03 Taizhou Sudarshan New Material Co.,Ltd 21<br />

N1F41 Teijin Kasei (HK) Ltd<br />

N3S43 TÜV Rheinland (Shnghai) CO LTD 22<br />

N3L11 Uhde Inventa-Fischer GmbH 23<br />

W3M15 Wei Li Plastics Machinery (H.K.) Ltd<br />

C13A21 WeiFang Graceland Chemicals CO., LTD<br />

N3L15 Weihai Lianqiao New Material Science&Technology Co.,Ltd 24<br />

C14E51 Woosung Chemical CO.,Ltd.<br />

N3K21 Wuhan Huali Environmental Technology Co., Ltd. 25<br />

N3P51 Xinjiang Blue Ridge Tunhe Polyester co., ltD.<br />

N3M01 Yat Shun Hong Company Ltd 26<br />

C13A49 Yongxi Plastics Technology<br />

N3M21 Zhejiang Hangzhou Xinfu Pharmaceutical Co., Ltd 27<br />

N3K07 Zhejiang Hisun Biomaterials Co.,Ltd. 28<br />

N3P01 Zhejiang Pu Wei Lun Chemicals Co.,Ltd 14<br />

N3S29 Zhuhai Xunfeng Special Plastics Co. Ltd. 29<br />

Layout Plan courtesy Adsale Exhibition Service<br />

Show Guid<br />

19 20 4 22 5<br />

1 14<br />

17 26<br />

3<br />

bioplastics MAGAZINE<br />

30<br />

21<br />

8 18<br />

27<br />

BIOPLASTICS ZONE<br />

28 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11<br />

In this Show Guide you find the majority of compa<br />

compounds, additives, semi-finished products and<br />

this centerfold out of the magazine an


Show Preview<br />

CHINAPLAS <strong>2016</strong> Preview<br />

e<br />

23<br />

24<br />

10<br />

7<br />

11<br />

29<br />

15 6<br />

13<br />

9<br />

28<br />

CHINAPLAS, recognized as Asia’s No. 1 and theworld’s<br />

No. 2 plastics and rubber trade fair by the industry,<br />

will hold its 30 th edition in <strong>2016</strong> in Shanghai. To celebrate<br />

the reach of the milestone, there will be more attractions<br />

and celebration activities at the show for all to join!<br />

Looking back, when CHINAPLAS was held for the<br />

first time in Beijing in 1983, the exhibition area was only<br />

2,000 m², and 90 % of the exhibitors were from overseas.<br />

At that time, the production technology in China was still<br />

at a very low level, CHINAPLAS visitors mainly came to<br />

learn the advanced technologies from overseas countries.<br />

Today, China has become a big manufacturing country<br />

with strong production ability, and is exporting the most<br />

plastics and rubber machineries in recent years. In the<br />

past three decades, CHINAPLAS has been moving forward<br />

together with the Chinese market, and has developed into<br />

a platform for the showcase of both overseas technologies<br />

and Chinese machineries for export.<br />

16<br />

2<br />

25 12<br />

Hall N3<br />

The 30 th CHINAPLAS will be held from 25 to 28 April, <strong>2016</strong><br />

at the Shanghai New International Expo Centre, PR China,<br />

with an exhibition area over 240,000 m², and more than<br />

3,200 exhibitors are expected. The show is supported by a<br />

number of country and region pavilions, including Austrian,<br />

German, Italian, Japanese, Korean, Swiss, Taiwanese,<br />

and USA Pavilions. With broader range of exhibits, the<br />

number of theme zones will rise to sixteen, among which<br />

the “Automation Technology Zone”, “Composite & High<br />

Performance Materials Zone” and “Recycling Technology<br />

Zone” are all new to the coming show in Shanghai.<br />

Intelligent production lines and systems, industrial robots,<br />

high performance materials, composite materials, the<br />

latest and most complete recycling solutions as well as<br />

other plastics and rubber technology breakthroughs will be<br />

showcased under one roof.<br />

As in recent years, the setup of theme zones at<br />

Chinaplas is always a good indicator of market needs.<br />

Thus CHINAPLAS <strong>2016</strong> will again feature a Bioplastics<br />

Zone in Hall N3. If you visit Chinaplas make sure to visit<br />

the booth of bioplastics MAGAZINE in Hall N3 (booth N3M15).<br />

On the following pages you will find some short<br />

reports of some of the 66 exhibitors showing bioplastics<br />

related products or services, 30 of which are located in<br />

the Bioplastics Zone in hall N3. This preview will be<br />

complemented by a review in the next issue. MT<br />

nies offering bioplastic products, such as resins,<br />

much more. For your convenience, you can take<br />

d use it as your personal show guide<br />

bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11<br />

29


Show Preview<br />

Wuhan Huali<br />

Wuhan Huali will present PSM ® biodegradable<br />

& biobased plastics materials and finished<br />

products during Chinaplas <strong>2016</strong>. PSM bioplastics<br />

are made through modification and plasticization<br />

from renewable, natural materials, such as corn,<br />

potato, tapioca or wheat starch, bamboo cellulose<br />

and sugarcane. PSM biodegradable plastics are<br />

certified by third party certification bodies Vinçotte<br />

and DIN Certco, and obtained the OK Compost and<br />

Compostable certificates. PSM biobased plastics are<br />

also certified by Vinçotte with the OK-Biobased and<br />

received 4 stars (more than 80 %). PSM biodegradable<br />

and biobased plastic materials can be widely applied<br />

in film blowing, thermoforming, injection moulding<br />

and foaming processes.s.<br />

N3K21 25<br />

www.psm.com.cn | www.hlbio.com<br />

NatureWorks<br />

From 3D printer filaments to new ultra-high barrier<br />

film, NatureWorks showcase Ingeo polylactide.<br />

NatureWorks features 3D860 – a new Ingeo<br />

formulation for 3D PLA filament designed to provide<br />

impact resistance and heat resistance rivalling ABS<br />

and other styrenics in terms of performance and<br />

for use in home and business/industrial printing of<br />

durable parts, as well as for prototyping parts for<br />

durable injection molded goods. A number of new,<br />

innovative 3D printed products will be on display<br />

including print-it-yourself headphones and masks.<br />

NatureWorks also showcases a new ultra-high<br />

barrier Ingeo-based flexible substrate designed to<br />

keep processed foods fresh on store shelves. This<br />

is the first application of Ingeo for longer shelf life<br />

foods that are increasingly packaged in pouches.<br />

Other Ingeo biobased products on display include<br />

compostable food serviceware, nonwovens, fibers,<br />

films, rigid packaging, and toys and other injection<br />

molded or extruded durables.<br />

N3K09 12<br />

JinHui ZhaoLong<br />

JinHui ZhaoLong High Technology Co. Ltd is one of the largest<br />

biodegradable plastic enterprises in China with a 20,000 tonnes/<br />

annum PBAT production line. JinHui ZhaoLong are currently<br />

manufacturing ECOWORLD (PBAT) and ECOWILL which is a<br />

family of modified PBAT compounding materials that comprise<br />

Ecowill FS-0330 (Ecoworld PBAT blended with corn starch) and<br />

Ecowill FP-0330 (Ecoworld PBAT blended with PLA). After three<br />

years of development since its first establishment in 2012,<br />

JinHui ZhaoLong has now been able to provide qualified PBAT<br />

and PBAT compounds with high stability and consistency which<br />

have acquired numbers of certifications issued by both domestic<br />

and international authoritative certification bodies. Besides, the<br />

company has developed a large number of domestic and foreign<br />

high-quality upstream and downstream customers.<br />

N3L01 10<br />

www.ecoworld.jinhuigroup.com<br />

Kingfa<br />

Kingfa Sci. & Tech. Co. Ltd., established in 1993 and<br />

headquartered in Guangzhou, is a global leader in high<br />

performance modified plastic industry. Kingfa initiated its bio<br />

program in 2001 and decided to make ECOPOND ® a sub-brand<br />

in Kingfa.<br />

Ecopond provides a complete package solution for retailers,<br />

such as roll bags (for fish and meat), shopping bags and<br />

some other packaging films that directly contact with foods.<br />

Compostable waste bags provide a sanitary and convenient<br />

collection solution for organic waste management. With the<br />

development of E-commerce and environmental awareness,<br />

Ecopond also finds a huge potential market in packaging such as<br />

air-bubble bag and air cushion film.<br />

Kingfa intensely cooperates with the Chinese government and<br />

environmental research organizations to implement biodegradable<br />

mulch film experiments in different areas. An exclusive formula is<br />

designed for every area and different crops like potatoes, peanuts,<br />

corn, cottons, etc., taking various changing weather condition and<br />

soil condition into account. The experiments prove great success<br />

in many places with fruitful output of the crops.<br />

In 2014, Kingfa added 3D printing application to the Ecopond<br />

family and began the business with promotion of its highly renowned<br />

modified PLA series. Ecopond 3D printing raw materials are widely<br />

applied in the mainstream Fused Deposition Modeling (FDM).<br />

N1G41<br />

www.ecopond.com.cn<br />

www.natureworksllc.com<br />

30 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11


Show Preview<br />

Doill Ecotec<br />

Doill WPC (Wood-Plastic Composites) compounds are new<br />

eco-friendly materials in pellet form which are manufactured<br />

with a special binding technique using wood flour and<br />

thermoplastic polymers (PP, PE, ABS, ASA, PS, SAN, PMMA,<br />

PLA, etc). The materials are suitable for extrusion and<br />

injection molding with advanced woody feeling, excellent<br />

durability, excellent water-proof properties, easy molding<br />

characteristics, reducing CO 2<br />

, bio-based plastic materials<br />

and recycled to 100 %.<br />

Extrusion molding applications include decking, cladding,<br />

louver, sound-proof walls, floor, furniture, blinder, panels,<br />

foamed products, interior products, filaments for 3d printing,<br />

etc.. By injection molding the following applications can be<br />

produced: kitchen utensils, cutting board, food containers,<br />

food trays, flower boxes, hangers and scoops, cosmetic<br />

containers, automobile parts, industrial products, and much<br />

more.<br />

N3S45 4<br />

www.doillecotec.com<br />

Uhde Inventa-Fischer<br />

The Polymer Division of ThyssenKrupp Industrial<br />

Solutions AG focuses on the development, engineering<br />

and construction of efficient plant concepts and processes<br />

in the fields of monomers, intermediates, polymers and<br />

machinery.<br />

At Chinaplas <strong>2016</strong> ThyssenKrupp will present their<br />

latest innovations and developments in biobased polymers<br />

They believe in providing cost-efficient processes for<br />

the production of non-petroleum-based polymers, such<br />

as polylactic acid (PLA) and polybutylene succinate (PBS)<br />

as well as its monomers and intermediates lactic acid,<br />

succinic acid and lactide. to fulfill the vision of sustainably<br />

replacing a considerable amount of conventionally<br />

produced materials in the near future.<br />

ThyssenKrupp’s state-of-the-art technologies<br />

are backed by more than 50 years’ experience in<br />

the development, engineering and design of leading<br />

polymerization processes, as well as t h e<br />

engineering and construction<br />

of more than 400<br />

production plants<br />

throughout<br />

the world.<br />

N3L11<br />

23<br />

www.uhde-inventa-fischer.com<br />

Coating p. Materials Co.<br />

CPMC will present new eco-friendly solutions, targeted at synthetic leather and related<br />

industries. This bio-based calendaring grade TPU (Thermoplastic Polyurethane) can not only<br />

solve the problems caused in PVC and PU synthetic leather industries, but also have five<br />

advantages as the follows.<br />

CPMC’s TPU has many advantages including good physical properties, degradable, nontoxic<br />

and non-plasticizer. The process is eco-friendly and offers a high yield rate, and there<br />

is no DMF residue in the final products. As a result, the products can solve VOC emission<br />

problem effectively. The production technology of calendaring grade TPU for eco-friendly<br />

synthetic leather is the same as for PVC, existing PVC synthetic leather equipment can be used. The functions and features are<br />

similar to PVC/PU synthetic leather.<br />

Customers who upgrade use advanced these eco-friendly materials, can promote your brand values and increase<br />

consumers’brand image.<br />

The presented bio-based calendaring grade TPU for eco-friendly synthetic leather can be applied to furnishings industry,<br />

clothing industry, car industry, footwear industry and so on.<br />

N3J61<br />

www.coating.com.tw<br />

Oxo-fragmentable plastics<br />

And finally there are a number of companies offering oxo-fragmentable plastics such as EnerPlastics (N3K01) or Rajiv<br />

Plastic Industries (C11F41). However, as of yet, bioplastics MAGAZINE does not consider such products as bioplastics. We are still<br />

waiting for satisfactory scientifically backed evidence by internationally accepted independent laboratories, proving a complete<br />

biodegradation into water, carbon-dioxide and biomass without accelerating any measurement nor extrapolating any initially<br />

measured degradation. MT<br />

bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11 31


Materials<br />

The 100 % bio-PET/polyester<br />

approach<br />

The bio-PET bottle is now followed by a bio-PET T-shirt<br />

According to different forecasts of e.g. European Bioplastics<br />

or the Institute of Bioplastics and Biocomposites<br />

(IfBB), the bioplastic market will continue to grow in<br />

the next years with bio-PET 30 representing the lion’s share<br />

(> 75 %). 30 wt.% of this bio-PET 30 is represented by biobased<br />

mono ethylene glycol (MEG). In order to be able to produce<br />

100 % biobased PET, many different technologies for the<br />

production of PTA (purified terepthalic acid) or its precursor<br />

paraxylene (PX) are currently under development.<br />

Bio-PET 30<br />

Bio-PET 30 was introduced in 2009 and can by now be<br />

found in the marketplace used by brands such as Coca-Cola,<br />

Danone, Nestle etc. in more than 25 countries around the<br />

world. Bio-MEG is currently made from bio-ethylene which<br />

is dehydrated from ethanol and dropped into the current<br />

ethylene glycol production plants with co-production of DEG<br />

(di-ethylene glycol) and TEG (tri-ethylene glycol). Ethanol is<br />

well known to be made from fermentation of sugars including<br />

those from first and second generation biomass. Ethanol<br />

could also be converted from syngas (CO+H 2<br />

) which could as<br />

well be biobased if made from biomass.<br />

There are other routes under development to make bio-MEG<br />

from sugars and carbon dioxide (CO 2<br />

). For example, sugars<br />

could directly go under catalytic reactions to generate MEG,<br />

MPG (mono propylene glycol) and others. The key issue is<br />

how to make more MEG than MPG which could be made from<br />

glycerol and usually cheaper than MEG. While CO 2<br />

is used<br />

for MEG production, oxalic acid is formed as an intermediate<br />

after electrochemical reaction of CO 2<br />

and further reduced to<br />

MEG.<br />

100 % bio-PET/polyester<br />

The first batch of empty bottles made from 100 % bio-PET<br />

were demonstrated by Coca-Cola (PlantBottle) in 2014 with<br />

biobased PTA technology from Virent and Far Eastern New<br />

Century (FENC). Last year, at Milan Expo, the first 100 %<br />

bio-PET bottles filled with beverages were introduced; again<br />

made using bio-PX from Virent’s pilot scale production and via<br />

FENC’s conversions. At the Sustainable Plastics conference<br />

in Cologne on March 1 st , <strong>2016</strong>, FENC showed the world’s first<br />

100 % bio-polyester shirt. The weaving and dyeing properties<br />

of the 100 % bio-polyester fibres proved to be the same as<br />

those of petro based polyester. This is a great progress of<br />

FENC’s 100 % bio-polyester and shows the possible use of biobased<br />

PX/PTA for dropping in to many other all downstream<br />

polyester applications.<br />

100 % bio-PX/PTA technologies<br />

In Virent’s BioForming process sugar is catalytically<br />

converted into bio-PX. Another similar approach is the<br />

pyrolysis to crack biomass to BTX (mixture of benzene toluene<br />

xylene) which could be dropped into the petro refinery for<br />

PX separation. There are many other approaches to convert<br />

6-carbon (C6) sugars to bio-PX or PTA (C8).<br />

H 3<br />

C CH 3<br />

Paraxylene (PX), C8H10<br />

32 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11


Materials<br />

Si mple mathematics will help us to understand<br />

all these converting pathways. The first example is<br />

2+2+2+2=8 by using 3 ethylene molecules (CH 2<br />

+CH 2<br />

+CH 2<br />

)<br />

to synthesize hexene (C 6<br />

H 12<br />

) which could be further<br />

converted to PX via Diels-Alder reaction with ethylene<br />

and dehydration. Or hexene could be formed by addition<br />

reaction of isobutene and ethylene (C 4<br />

H 8<br />

+2CH 2<br />

=C 6<br />

H 12<br />

) as a<br />

part of 4+2+2=8 pathway with Diels-Alder and dehydration<br />

reactions. Next example is 2+6=8 by adding ethylene to<br />

sugar fermented muconic acid, 5-hydromethylfurfual<br />

(HMF) or HMF derivatives and then further chemically<br />

converted to PTA. The third calculation is 3+5 where<br />

lactic acid ester combined with bio-isoprene and function<br />

group transformation to di-acids. The last, but the least<br />

pathway is 4+4=8 by combining 2 isobutene to bio-PX with<br />

cyclization and oxidation steps. Of course, the subtraction<br />

instead of addition will work such as 10-2=8 which could be<br />

achieved by chemical oxidation to bio-PTA from limonene.<br />

While so many biological and/or chemical conversions of<br />

biomass/sugars to bio-PX/PTA, the winner of this 100 %<br />

bio-PX/PTA commercialization is still unknown, while the<br />

first commercial plant is the most difficult step due to the<br />

technology uncertainty of scaling up and a huge capital<br />

expenditure (CapEx), for much smaller scale compared to<br />

current petro-based PX/PTA plants.<br />

By:<br />

Fanny Liao<br />

Senior Vice President of RD<br />

Far Eastern New Century Corporation<br />

Taiwan<br />

www.fenc.com/index_en.aspx<br />

Brand Owners<br />

Brand-Owner’s perspective<br />

on bioplastics<br />

and how to unleash its full potential<br />

new<br />

series<br />

Inspired by a panel discussion during the 10 th European Bioplastics Conference in Berlin last November, bioplastics MAGAZINE<br />

is now starting a new series, titled Brand-Owner’s perspective on bioplastics and how to unleash its full potential.<br />

Here we ask brand owners for a short statement, quasi as a message to the bioplastics industry.<br />

The series starts with Michael W. Knutzen of The Coca-Cola Company, Atlanta, Georgia, USA:<br />

Innovation comes from inspiration, and at The Coca-Cola Company we<br />

are greatly inspired by the very people who drink our beverages.<br />

Our consumers expect us to deliver the beverages they know and love<br />

in a package that meets their needs such as convenience and safety,<br />

but also in a package that is environmentally considerate.<br />

Michael W. Knutzen,<br />

Global Program Director PlantBottle at<br />

The Coca-Cola Company<br />

PlantBottle packaging has been meeting consumer expectations<br />

since 2009. The first-ever fully recyclable PET plastic beverage bottle<br />

made partially from plants looks and functions just like traditional<br />

PET plastic, but has a lighter footprint on the planet and its scarce<br />

resources.<br />

bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11 33


Analysis<br />

Breaking down<br />

complex assemblies<br />

By:<br />

Callum Smith<br />

Beta Analytic<br />

London, UK<br />

Upon signing the Agriculture Act of 2014, US President<br />

Barack Obama said that it was an innovation bill.<br />

Among the myriad provisions in the bill, which encourages<br />

growth in the increasingly large biobased market, was<br />

an update to the USDA BioPreferred ® program’s guidelines<br />

concerning biobased content testing for complex assemblies.<br />

What are complex assemblies?<br />

Complex assemblies are products for which the percentage<br />

biobased carbon content cannot be determined from a single<br />

radiocarbon measurement, such as bicycle saddles, blenders<br />

and automobiles. Radiocarbon ( 14 C) is abundant in biomass<br />

and absent in petrochemicals so differentiation is readily<br />

made in products, but the analytical method is size limiting,<br />

so the shape and size of complex assemblies may require<br />

precise subsampling and calculations to derive a formulated<br />

percentage biobased carbon content.<br />

Biobased testing strategies for complex<br />

assemblies<br />

Conscious of the benefits of promoting the uptake of<br />

biobased intermediate ingredients in the market, the USDA<br />

has incorporated guidelines addressing biobased content<br />

testing for products in the BioPreferred program. Due to<br />

size or shape or chemical and physical properties, complex<br />

assemblies require special procedures. This will typically<br />

involve measuring individual components and mathematically<br />

deriving a single result or sub-sampling individual components<br />

and combining them in a mass proportion of the whole for a<br />

single result. In some difficult cases, such as oil-based paints<br />

where oil may be encapsulating calcium carbonate in a way<br />

that it cannot be effectively eliminated, the product may best<br />

be analysed prior to the addition of the carbonate filler.<br />

Darden Hood, President of Beta Analytic, a senior<br />

technical author of ASTM-D6866 and advisor to CEN and<br />

ISO committees on the use of radiocarbon remarks, “for<br />

100 grams of a complex assembly consisting of three solid<br />

components A, B, and C, where 50 grams is A, 20 grams is<br />

B and 30 grams is C the strategy is quite straightforward to<br />

overcome size limitation. Subsample 5 grams of A, 2 grams<br />

of B, 3 grams of C, and combine them for one radiocarbon<br />

analysis. In more difficult cases, discussion may be required<br />

to obtain the appropriate percentage biobased carbon result<br />

while working within the specifications of the standard. All<br />

organic carbon species need to be quantitatively recovered<br />

as CO 2<br />

from the product since each component may have a<br />

unique percentage biobased carbon content. Loss of any<br />

proportion of any one them will lead to an inaccurate result;<br />

requiring complicated lab procedures for materials such<br />

as hand sanitisers and solvent mixtures of highly different<br />

volatility. In the case of complex assemblies, close discussion<br />

with the laboratory promises to yield accurate and easily<br />

communicable data better than ever before. In turn, this<br />

should help to promote the production and consumption of<br />

biobased products, signalling an exciting new phase across<br />

all of the industries involved”.<br />

www.radiocarbon.com<br />

Key components of an Accelerator Mass Spectrometry system, used<br />

for counting cosmogenic radionuclides in organic matter<br />

Fictive, not existing example: A wristwatch could consist of:<br />

50 grams of bio-based Polyamide 6.10 (the housing), 20 grams<br />

of PLA (the glass) and 30 grams of biobased polyurethane (the<br />

wristband). The clockwork inside is assumed to be metal, and<br />

doesn’t count… (Photo: Marcin Bartkowiak)<br />

34 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11


Drive Innovation<br />

Become a Member<br />

Join university researchers and industry members<br />

to push the boundaries of renewable resources<br />

and establish new processes and products.<br />

www.cb2.iastate.edu<br />

See us at K <strong>2016</strong><br />

October 19-26, <strong>2016</strong><br />

Düsseldorf, Germany<br />

Hall 5, Booth C07-1


Application News<br />

Foodstuff packaging<br />

The compounder and plastics distributor FKuR Kunststoff<br />

GmbH, Willich, Germany, the film manufacturer Oerlemans<br />

Plastics BV, Genderen, the Netherlands, and the specialist<br />

foodstuffs packaging distributor BK Pac AB, Kristianstad,<br />

Sweden, are closely working together on expanding the<br />

possibilities for using bio-based plastics for sustainable<br />

foodstuffs film packaging.<br />

In this transnational cooperation project, FKuR is the<br />

distributor for the Green PE from the world-leading,<br />

Brazilian biopolymer manufacturer Braskem which is used<br />

to produce the film. This 100 % recyclable, sugar cane-based<br />

polyethylene helps to reduce the environmental impact caused<br />

by greenhouse gases because using renewable raw materials<br />

binds up to 2.15 tonnes of atmospheric CO 2<br />

for each tonne of<br />

Green PE. And since the plastic is not biodegradable, this CO 2<br />

remains bound in the plastic over the entire product life cycle.<br />

In the next step, Oerlemans Plastics uses the Braskem<br />

bio-based PE supplied by FKuR in its two production sites in<br />

Genderen and Giessen in the Netherlands to produce highquality<br />

flexible films.<br />

The printed and perforated films produced from Green<br />

PE are sent to the Scandinavian distributor BK Pac, which<br />

specialises in packaging materials such as films, trays,<br />

bags, carton boxes etc. for vegetables, fruit, meat and other<br />

foodstuffs. Being a local company, BK is highly familiar with<br />

the requirements of its customers and the market and can<br />

therefore feed valuable information back into the value chain<br />

which can be used for further development and innovation.<br />

Since the introduction of the product line based on Braskem’s<br />

Green PE, the three companies have been continuously<br />

working together on extending and further developing the<br />

line with the aim of promoting this bio-based plastic as<br />

a sustainable alternative on the Scandinavian market. As<br />

Patrick Zimmermann, Marketing & Distribution Manager at<br />

FKuR Kunststoff, says: “Our successful collaboration with<br />

Oerlemans Plastics and BK Pac is typical of our continuous<br />

search for ways of increasing product sustainability by using<br />

renewable resources. It is also a model for many further<br />

possible national and multinational cooperative projects.<br />

It clearly demonstrates the potential of such projects to<br />

conserve resources and help to maintain an environmental<br />

balance while at the same time generating economic benefits<br />

along the entire value chain by using Green PE.”<br />

www.fkur-biobased.com | www.oerlemansplastics.nl<br />

| www.bkpac.se<br />

Bioplastic for furniture<br />

In JELUPLAST ® , the German company JELU-WERK<br />

presents a novel and versatile material for furniture<br />

making. Like plastic, Jeluplast can be moulded threedimensionally<br />

and offers wide scope for design, yet it<br />

possesses the positive attributes of wood. Jeluplast thus<br />

attains higher rigidity and flexural strength than plastics.<br />

In its appearance, feel and smell, the new material closely<br />

resembles wood, delivering creative design and usage<br />

opportunities for designers and the furniture industry.<br />

Due to its special properties, this versatile material is<br />

suitable both for outdoor and indoor use. Jeluplast is free<br />

from formaldehyde, chlorine, phenol, plasticisers and PVC.<br />

It can be processed, for instance, to make high-quality<br />

seating shells, decorative elements or feet for shelves<br />

and cabinets using injection moulding. By means of<br />

compression moulding, the bioplastic can be processed to<br />

produce stable boards for the substructure of upholstered<br />

furniture, for example, and for shelving, side and back walls<br />

as well as for cabinet doors. Panels and injection moulded<br />

parts from Jeluplast can be glued, bolted, dyed, coated and<br />

welded.<br />

Furniture made from Jeluplast is also suitable for<br />

damp interiors, such as bathrooms, kitchens and saunas,<br />

because it is resistant to moisture. The bioplastic’s weather<br />

resistance makes it an attractive material for outdoor<br />

applications too. It is suitable for garden furniture, exterior<br />

railings, fences, wall cladding and decking boards.<br />

Bioplastic with consistent running properties<br />

Jeluplast consists of food-safe thermoplastic and natural<br />

fibres. The proportion of natural fibres can be set individually<br />

between 50 and 70 %. Depending on the type of plastic,<br />

Jeluplast consists up to 100 % of sustainable materials.<br />

The properties of the plastic used determine whether<br />

the end product is long-lasting or biodegradable. The<br />

properties can be further adjusted by means of additives.<br />

Flame retardants can be added as well as additives that<br />

make the material more resistant to moisture.<br />

Jelu-Werk offers biocomposites based on polyethylene,<br />

polypropylene, thermoplastic starch (TPS), polylactides<br />

(PLA) and other plastics. The fibres used are wood<br />

fibres and cellulose fibres. Compounding helps the WPC<br />

granulates from Jelu to achieve higher compression and to<br />

be processed better. The bioplastic has consistent running<br />

properties on the machine, facilitating a higher output.<br />

Jeluplast can be processed by injection moulding, extrusion,<br />

compression moulding, blow moulding or foaming. MT<br />

www.jelu-werk.com<br />

36 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11


SUSTPACK <strong>2016</strong><br />

BUSINESS MADE SUSTAINABLE<br />

Visit us at Sustpack <strong>2016</strong><br />

Chicago, IL<br />

11 - 13 April <strong>2016</strong><br />

Renewable . Ambient Compostable Plastic . FCN Approved<br />

First 30 60 120 180<br />

30<br />

day days<br />

60<br />

days<br />

120 180<br />

days days<br />

Excellent Heat<br />

sealability<br />

Heat resistance up to<br />

100 C<br />

Runs well with<br />

LDPE machine<br />

*This test was conducted under natural condition in Bangkok, Thailand.<br />

Dreaming of naturally compostable bioplastic ? Here is the answer.<br />

BioPBS is revolutionary in bioplastic technology by excelling 30°C compostable and being essentially bio-based in accordance<br />

with OK COMPOST (EN13432), OK COMPOST HOME marks, BPI (ASTM D6400) for composting and DIN CERTCO for biobased<br />

products. It is compostable without requiring a composting facility and no adverse effects on the environment.<br />

BioPBS is available in various grades, which can be applied in a wide range of end use applications ranking from paper<br />

packaging, flexible packaging, agricultural film, and injection molding. It provides non-process changing solution to<br />

achieve better results in your manufacturing needs, retains the same material quality, and can be processed in existing<br />

machine as good as conventional material. In comparison with other bioplastics, BioPBS is excellent heat properties<br />

both heat sealability and heat resistance up to 100 °C. In addition to those benefits, it is only few compostable polymers<br />

complying with food contact of U.S.FCN NO.1574, EU 10/2011 and JHOSPA.<br />

8C084/8C085<br />

8C083<br />

BioPBS is available in various grades that conform to the following international standards for composting and biobased.<br />

For more information<br />

PTTMCC Biochem : +66 (2) 2 140 3555 / info@pttmcc.com<br />

MCPP Germany GmbH : +49 (0) 152 018 920 51 / frank.steinbrecher@mcpp-europe.com<br />

MCPP France SAS : +33 (0) 6 07 22 25 32 / fabien.resweber@mcpp-europe.com<br />

PTT MCC Biochem Co., Ltd. A Joint Venture Company of PTT and Mitsubishi Chemical Corporation<br />

555/2 Energy Complex Tower, Building B, 14th Floor, Vibhavadi Rangsit Road, Chatuchak, Bangkok 10900, Thailand<br />

T: +66 (0) 2 140 3555 I F: +66(0) 2 140 3556 I www.pttmcc.com


Application News<br />

Bio-PET Solar control<br />

window films<br />

Toray Plastics (America), Inc., the only United States<br />

manufacturer of polypropylene, polyester, metallized,<br />

and bio-based films, has developed a bio-based biaxially<br />

oriented polyester film for use in the manufacture<br />

of solar control window films for commercial and<br />

residential applications.<br />

New Lumirror brand BioView PET film is manufactured<br />

with Toray’s proprietary sustainable resin blends, which<br />

are made with approximately 30 % renewable feedstock.<br />

The new BioView bio-based film is a multi-layer structure<br />

with surface and optical qualities that are strictly controlled<br />

by Toray’s proprietary coextrusion technology. It is notable<br />

for its very low haze, excellent handling and processing<br />

characteristics, and high scratch resistance. BioView offers<br />

a performance that is equal to that of traditional solar<br />

window films during solar film manufacturing, installation,<br />

and use in technically demanding applications that require<br />

exceptional optical clarity.<br />

First PLA wine bottle<br />

Bodega Matarromera (Valladolid, Spain) has successfully<br />

completed the development of a new sustainable bottle<br />

for their wines. It is a packaging manufactured from PLA,<br />

and it is the first bottle manufactured with this<br />

material to reproduce the design of traditional<br />

glass bottles for wine, with some main<br />

advantages: it is lighter (50 grams)<br />

fully-recyclable and has a lower<br />

environmental impact<br />

in its manufacturing<br />

process.<br />

AIMPLAS, the Plastics Technology<br />

Centre (Valencia,<br />

Spain), has been<br />

subcontracted by Bodega<br />

Matarromera<br />

within this project<br />

to design the new sustainable<br />

bottles, as well as<br />

the preform mould<br />

and the blowing<br />

mould to produce<br />

them. In addition,<br />

AIMPLAS has also<br />

carried out the characterisation of<br />

the new packaging<br />

that, thanks to an<br />

inner coating with<br />

silicon oxide, has<br />

proven to offer a considerable<br />

improvement of barrier properties<br />

against different gases.<br />

This project has<br />

counted on the funds<br />

of the programme EEA GRANTS, funded<br />

by Norway, Iceland and Liechtenstein, as well as by the<br />

Ministry of Science and Innovation from Spain through<br />

CDTI. The research is framed within the company’s<br />

commitment with environmental sustainability, what will<br />

allow a differentiation and increase of competitiveness<br />

in new markets with a high environmental awareness<br />

as well, as the Nordic countries and specifically the<br />

Scandinavian airlines. MT<br />

www.aimplas.com | www.grupomatarromera.com<br />

Toray Plastics is a major producer of traditional films,<br />

made with or without UV protection, used for solar window<br />

film applications. The company has been on the leading<br />

edge of bio-based resin technology and plans to produce<br />

polyester film to be used in the manufacture of solar<br />

control window film that is made entirely of sustainable<br />

feedstock. A patent is pending for the new film.<br />

“This is a very exciting development for window film<br />

technology and for the commercial and residential<br />

building markets,” says Milan Moscaritolo, Senior Sales<br />

and Marketing Director of the Lumirror Division. “The<br />

construction industry continues to look for innovative ways<br />

to help developers reduce energy costs. Creating a film that<br />

lessens the impact on the environment, without sacrificing<br />

solar protection performance, was the natural next step in<br />

the evolution of the technology. The BioView film represents<br />

a perfect marriage between an environment-friendly film<br />

and an energy-saving application.” KL<br />

www.toraytpa.com<br />

38 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11


Application News<br />

Biobased sunglasses for Yokohama World Triathlon<br />

Mitsui Chemicals Inc. (MCI), headquartered in Toyko, Japan has developed<br />

MR-60, a plant-based high refractive index lens material for standard<br />

eyeglasses, by using a biomass-derived industrial isocyanate and a biomassderived<br />

polythiol as well as a non-metallic catalyst for polymerization. In 2014,<br />

MR-60 was certified by the United States Department of Agriculture (USDA) as a<br />

plant-derived product with a biomass of 57 %.<br />

Last year MCI was a sponsor of the World Triathlon Series Yokohama held in Yokohama, Japan, an event which aimed to<br />

“contribute to society through sports”. The event utilized the sustainability management system standard ISO 20121. In a joint<br />

development with Yokohama City MCI developed sunglasses made with MR-60 for athletes, referees and staff in the Executive<br />

Office of the Triathlon event. The sunglasses were produced in close collaboration with the SWANS program of Yamamoto<br />

Kogaku Co., Ltd., a company that has a history of designing sports products that offer comfort and performance, and Itoh<br />

Optical Industrial Co., Ltd., who have expertise in high-performance eyeglass lens manufacturing.<br />

Both companies accomplished the project in a real short period of time. Itoh Optical Industrial, who was involved in the lens<br />

development had to overcome challenges with the non-metallic catalyst being used for the lens material. However, together<br />

with Yamamoto Kogaku and Mitsui Chemicals the project could be successfully<br />

finished. Mr. Masakazu Honda of Itoh Optical Industrial said in MCI’s customer<br />

Journal MR View [1] that in addition to high functionality and high quality they were<br />

now also involved in looking at a low environmental burden.<br />

Yamamoto Kogaku has worked on numerous products in the field of sports<br />

eyewear with the brand called SWANS. Together with the other project partners,<br />

Yamamoto Kogaku also succeeded in mastering challenges such as the unknown<br />

drilling and cutting characteristics of MR-60 [1].<br />

And the article in MR View continues that the project partners learned that “those<br />

taking part in a triathlon were earnestly looking for suitable sunglasses” and “the<br />

functions required of sports sunglasses are slightly different when running or<br />

riding a bicycle.” [1]<br />

By sponsoring the event, MCI not only provided plant-based sunglasses, but also<br />

appealed to the social/ethical activities of the Do Green initiative. MCI’s support<br />

was widely praised by the people involved in the triathlon. MT<br />

[1] MR View issue No7, September 2015,<br />

http://www.mitsuichem.com/special/mr/resources/img/mrview_v07_en.pdf<br />

www.mitsuichem.com<br />

Ikea’s alternative for polystyrene<br />

Looking for eco-friendlier packaging, the Swedish furniture and retail giant Ikea has recently announced their intention to<br />

use an organic, mushroom-based packaging for its flat-pack furniture and thus to move away from polystyrene foams.<br />

Developed by New York based company Ecovative, Mushroom ® Packaging is made using mycelium, or rather mushroom<br />

roots, which functions similar to the roots of other plants. Mycelium fastens the fungus to the ground and absorbs nutrients<br />

(cf. bioplastics MAGAZINE issue 01/2014).<br />

Already known for its use as a biobased building material, mycelium is beneficial because it grows quickly into a dense<br />

material, which can then be easily moulded into custom shaped packaging.<br />

For Ikea, the lifecycle of the material also plays a role. Joanna<br />

Yarrow, head of sustainability for Ikea told the Telegraph that Ikea<br />

was looking at introducing mycelium packaging because “a lot of<br />

products come in polystyrene, traditionally, which can’t be – or is<br />

very difficult to – recycle.” While polystyrene is a non-biodegradable<br />

plastic, mycelium packaging will biodegrade naturally within a<br />

few weeks, if disposed of properly in a dedicated composting<br />

environment.<br />

Ikea confirmed it was looking at working with Ecovative, who are<br />

leaders in the field for innovating with mushroom materials. MT<br />

www.ecovativedesign.com<br />

bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11 39


From Science and Research<br />

HMF from<br />

chicory salad<br />

waste<br />

800,000 tonnes: That’s how much waste in the form<br />

of chicory roots is generated during the production<br />

of chicory salad in Europe per year. Currently, after<br />

harvesting the chicory salad, the roots are disposed of<br />

in composting or biogas plants. What a waste, thought<br />

two researchers of the University of Hohenheim,<br />

Germany. Because these roots can be used to generate<br />

hydroxymethylfurfural (HMF), a basic material in the<br />

future plastics industry.<br />

The biennial chicory plant only spends the first five<br />

months on the fields. In mid-October the leaves are<br />

mulched and the roots are harvested, stored in a cool<br />

place, and then brought to special growing rooms.<br />

Only there will the new buds, the future chicory salad,<br />

sprout.<br />

Fig. 1: 30 % of the chicory plant can be used for making HMF<br />

(Source: Wikipedia/Rasbak)<br />

But in contrast to the food production, at the<br />

University of Hohenheim the focus lies primarily on the<br />

non-edible root. “The root makes out approximately<br />

30 % of the plant (cf. fig.1). The stored carbohydrates<br />

are not fully used for the formation of the buds and<br />

valuable reserve substances remain. However, the<br />

roots can only be used once for chicory growing and<br />

have to be thrown away after the buds are harvested”,<br />

explains agricultural biologist Dr. Judit Pfenning.<br />

Polyamides, polyester, or plastic bottles<br />

Prof. Andrea Kruse, of the Institute for Agricultural<br />

Engineering at Univ. Hohenheim explains what they<br />

do: “On the rack in figure 2 you can see pencil-sized<br />

stainless steel tube reactors. These are filled with<br />

chopped chicory roots and water. After adding diluted<br />

acid into the ultra-stable pressure container, it is heated<br />

up to a temperature of 200 °C.” This results in a watery<br />

product which is then processed in further proprietary<br />

steps to produce unpurified hydroxymethylfurfural<br />

(HMF) in the form of yellow-brown crystalline powder.<br />

This is a precursor to form furandicarboxylic acid<br />

(FDCA), identified by the US Department of Energy (DoE)<br />

as one of the 12 most important platform chemicals.<br />

FDCA serves as a raw material for polyamides (e. g.<br />

for nylon stockings), for polyesters, polyurethanes or –<br />

more concrete – to make PEF (polyethylene furanoate).<br />

PEF can for example be used for the production of<br />

bottles, as a biobased alternative to PET.<br />

Chicory-made HMF as part of bioeconomy<br />

As part of a previous research project Kruse already<br />

found a way to extract the basic chemical HMF from<br />

fructose. However, she is of the opinion that chicory<br />

roots as a source are more elegant. After all: “Fructose<br />

40 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11


From Science and Research<br />

is edible. There are better uses for<br />

it than extracting HMF.” This is not<br />

the case for chicory roots. “Until<br />

now, they were waste.”<br />

The challenge: storage and<br />

quality of the roots<br />

The project poses a challenge:<br />

“The root is only of interest for<br />

the industry if we can guarantee<br />

permanent quality,” explains Prof.<br />

Kruse.<br />

To this end, the technical<br />

chemist cooperates with the<br />

plant scientist Judit Pfenning<br />

from the Department of General<br />

Crop Farming. “In general, the<br />

conditions are very good,” explains<br />

Pfenning, “because the consumer<br />

who wants to eat the chicory<br />

also has very high and consistent<br />

quality expectations. That is why<br />

only roots of very high quality are<br />

transferred from the fields into<br />

the commercial growing rooms<br />

operating with water-forcing<br />

techniques.”<br />

Another research aspect: How<br />

the roots can be stored without<br />

going bad. The problem is that<br />

chicory is a seasonal business.<br />

However, suppliers of the chemical<br />

industry want permanent<br />

deliveries in order to be able to<br />

constantly use their plants.<br />

“This project can only be carried<br />

out through interdisciplinary<br />

cooperation,” emphasize the<br />

scientists. One the one hand the<br />

project includes quality control,<br />

growing trials, and storage<br />

experiments, and on the other<br />

hand laboratory experiments and<br />

conversion technology. MT<br />

www.uni-hohenheim.de<br />

Fig. 2: Chicory waste can be used as a source for different plastics,<br />

e. g. nylon or PEF for bottles (Photo: Univ. Hohenheim)<br />

Fig. 3: Chicory is harvested from special growing rooms.<br />

(Source: Wikipedia/slick)<br />

bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11 41


Basics<br />

Bioplastics packaging:<br />

design for a circular<br />

plastics economy<br />

By:<br />

Hasso von Pogrell<br />

Managing Director<br />

European Bioplastics<br />

Berlin, Germany<br />

Applying the principles of a circular economy from<br />

the onset to the design stage of bioplastic materials<br />

and packaging solutions offers a competitive edge<br />

for the bioplastics industry. Today, packaging is the single<br />

largest field of application for bioplastics with currently<br />

70 % (1.2 million tonnes) of the global bioplastics production<br />

capacity, forecast to reach 80 % (6.5 million tonnes) in<br />

2019. The increase in demand is mainly driven by a growing<br />

awareness of society’s impact on the environment as well<br />

as the continuous advancements and innovations in new<br />

materials and applications. Yet, their true value lies in their<br />

characteristic of being derived from renewable resources<br />

and being recyclable as secondary raw materials that reenter<br />

the circular economy by design.<br />

Renewable feedstock<br />

Biobased plastics have the unique advantage over<br />

conventional plastics to reduce the dependency on<br />

limited fossil resources and to reduce greenhouse gas<br />

emissions or even be carbon neutral. Biobased plastics<br />

are partly or fully derived from biobased resources that<br />

are sustainably sourced and regrow on an annual basis,<br />

such as sugarcane, corn, or sugar beet. Moreover, first<br />

successful projects explore the possibilities to create<br />

bioplastics from non-food crops and waste products that<br />

promise to become an efficient resource in the mid- and<br />

long-term. By replacing the fossil content in plastics with<br />

plant-based content, carbon is taken from the atmosphere<br />

and bound in the material. These biobased materials are<br />

then used to manufacture a broad range of products with a<br />

potentially neutral or even negative carbon footprint, many<br />

of which are durable and can be reused or easily recycled<br />

many times. Consequently, biobased plastics can help the<br />

EU to meet its 2<strong>02</strong>0 targets of greenhouse gas emissions<br />

reduction.<br />

Closed resource cycle<br />

Bioplastics can make a considerable contribution to<br />

increased resource efficiency through a closed resource<br />

cycle and use cascades, especially if biobased materials<br />

and products are being either reused or recycled and<br />

eventually used for energy recovery (i.e. renewable<br />

energy). Bioplastics are suitable for a broad range of endof-life<br />

options with the overwhelming part of the volumes<br />

of bioplastics produced today already being recycled<br />

alongside their conventional counterparts where separate<br />

recycling streams for certain material types exist (e.g.<br />

biobased PE in the PE-stream or biobased PET in the<br />

PET stream). Furthermore, compostability is an add-on<br />

property of certain types of bioplastics that offers additional<br />

waste treatment options at the end of a product’s life.<br />

Biodegradable products, such as compostable biowaste<br />

bags, food packaging, or cutlery can easily be treated<br />

together with organic waste in industrial composting<br />

plants and are thus diverted from landfills and turned into<br />

valuable compost. This way, bioplastics can contribute to<br />

higher recycling quotas in the EU, a more efficient waste<br />

management, and the transition to a circular economy.<br />

Improved product performance<br />

The bioplastics industry has come up with numerous<br />

innovative technical and material solutions. Besides being<br />

biobased and therefore reducing the carbon footprint<br />

of a product, biobased plastics also offer new material<br />

properties for an improved performance, including<br />

enhanced breathability, increased material strength, and<br />

improved optical properties. Some new materials offer<br />

multiple functionalities combined in one material, such as<br />

PBS-based materials or functional biodegradable coating<br />

materials for example, where only one film will be needed<br />

to protect the good or food.<br />

Bioplastics are essential for the transition to a<br />

circular economy<br />

Our industry strongly supports the principles of the<br />

European Commission’s Circular Economy Proposal, which<br />

for the first time links the bioeconomy and circular economy,<br />

and which aims to treat waste as a valuable resource and<br />

make Europe’s economy cleaner and more competitive.<br />

The proposal outlines measures to cut resource use,<br />

reduce waste, and to enable true circularity across Europe<br />

by setting clear measures, methodologies, and standards.<br />

The European Commission’s Action plan ‘Closing the loop<br />

– An EU action plan for the Circular Economy’ in particular<br />

aims to incentivise the production of more durable, easier<br />

to repair, reuse, and recycle products. A corresponding<br />

revision of the Ecodesign Directive is already underway<br />

and a proposal is soon to be expected. In this context,<br />

European Bioplastics supports the position of the Ellen<br />

MacArthur foundation and the World Economy Forum in<br />

their report on the ‘New Plastics Economy’, which states<br />

that recyclability alone is not sufficient enough to create<br />

circularity and resource efficient products. Ecodesign<br />

requirements should also take efficient use of feedstock<br />

and efficient waste management solutions into account.<br />

True ecodesign is only possible if the notion of circularity<br />

is implemented. Focussing only on recyclability falls short<br />

of what it desired to achieve. Given the still too high quota<br />

of landfilling in the EU and the comparatively low quota of<br />

recycling, there is an urgent need for a more comprehensive<br />

approach to the problem: In order to provide an incentive<br />

to drastically reduce waste, while at the same time support<br />

renewable energy (e.g. biogas) and increase secondary raw<br />

42 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11


Basics<br />

materials (i.e. compost), separate waste<br />

collection has to become binding for all<br />

EU Member States as soon as possible,<br />

including and in particular separate<br />

biowaste collection. Secondly, we need<br />

legal measures to reduce and eventually<br />

phase-out landfill, the earlier the better.<br />

The European Commission’s Circular<br />

Economy Proposal addresses all stages<br />

of the product life cycle and a range of<br />

responsible economic sectors, including<br />

product design. Yet, in order to be able<br />

to harness the many benefits of the<br />

‘design for circularity’ it is essential to<br />

acknowledge the contributions of biobased<br />

materials to the circular economy by<br />

promoting biobased and biodegradable<br />

packaging and facilitating a level playing<br />

field and equal access for all sectors using<br />

biomass. Secondly, we need to drastically<br />

improve the waste collection infrastructure<br />

across Europe and to get better at diverting<br />

valuable material streams away from<br />

landfills.<br />

www.european-bioplastics.org<br />

Life cycle of bioplastics (EUBP)<br />

BIO MEETS<br />

PLASTICS.<br />

The specialists in plastic recycling systems.<br />

An outstanding technology for recycling both<br />

bioplastics and conventional polymers<br />

CHOOSE THE NUMBER ONE.<br />

bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11 43


Basics<br />

Design for recyclability<br />

By Michael Thielen<br />

Plastic recycling not only plays a vital role in increasing<br />

resource efficiency, it is essential for the transition to a<br />

circular economy. While reduce and reuse obviously take<br />

priority over recycling in the waste hierarchy, recycling is the<br />

next preferred option to be pursued. Ideally, plastics should<br />

be mechanically recycled as often as is feasible prior to their<br />

“final” recycling in the form of incineration (waste-to-energy<br />

recycling) or – where possible – composting or anaerobic digestion<br />

(biological recycling). Mechanical recycling refers to<br />

the various mechanical processes – including grinding or<br />

milling and subsequent melting – used to recover waste plastics<br />

and ultimately to produce regranulate from which new<br />

products can be injection moulded, extruded, thermoformed,<br />

blow moulded or otherwise produced. However, it is fair to say<br />

that the recyclability of any product is to a very large extent<br />

dictated by the way the product is designed. Design decisions,<br />

such as materials selection, the methods of assembly, labeling<br />

techniques, decorating techniques, and the like, all have<br />

a very significant influence on the ability to recycle a product<br />

or its constituent materials [1].<br />

All plastic products<br />

Regardless of whether a plastic product is made from<br />

conventional plastics or from biobased and/or biodegradable<br />

plastics, there are a number of factors to be considered with<br />

regard to recyclability.<br />

Standard material identification: A variety of different<br />

material marking systems<br />

are used to identify the<br />

material from which a<br />

plastic item or component<br />

is manufactured. [1]<br />

Thermoplastics are the materials of choice, since only<br />

this group of plastics can be mechanically recycled without<br />

significant changes occurring in the properties of the materials.<br />

However, depending on the specific type of thermoplastic, the<br />

properties of these plastics can also undergo changes, both<br />

major and minor, over successive recycling loops (changes<br />

in molecular weight distribution, chemical structure, color,<br />

additive effectiveness, etc.). [1]<br />

Minimize the number of components and minimize the<br />

variety of used materials: Use snap fits (e.g. for CD jewel<br />

cases) and living hinges (e.g. for shower gel caps). If a second<br />

material is needed, for example for multi-shot mouldings, try<br />

to choose two materials that can be recycled together (e.g.<br />

PC, PBT and ABS) or that all can be biodegraded (such as PLA<br />

and PBAT). [1]<br />

Avoid the use of colour pigments or use the smallest<br />

possible amount, as these will subsequently not be able to<br />

be removed from a compound. “The fewer pigments you<br />

use, the lighter the colour of the recyclate will be and thus<br />

the broader the range of potential future applications,” says<br />

Michael Scriba, general manager of recycling company mtm<br />

(Niedergebra, Germany), in the recent issue of K-Profi [2]. “If<br />

pigments must be used, use light colours,” he adds. He also<br />

noted that fillers, such as chalk, may not be beneficial for a<br />

recycling process, as they modify the density of a material and<br />

hinder a gravimetric separation of plastics [2].<br />

Another important topic are labels. Paper labels and<br />

glues should be avoided. “Plastic/glue/paper combinations<br />

are difficult to separate,” says Scriba. “During the washing<br />

process, the paper absorbs water, the fibres clump together<br />

and lead to high temperature development in the extrusion<br />

process which can then lead to undesired odor and stains in<br />

the recyclate” [2]. Hence in-mould labeling, with plastic labels<br />

made from the same plastic as the labelled product itself, are<br />

to be preferred.<br />

Design for easy disassembly is recommended for multicomponent<br />

products, for example by means of snap fits or<br />

screws. Again: use recycling friendly labels and attachments.<br />

Avoid coatings and glues [1].<br />

Biodegradable plastics<br />

All of the aspects mentioned above certainly also apply in<br />

respect of biodegradable plastics. Many biodegradable plastics<br />

can be mechanically recycled. The most important additional<br />

aspect is that all components (e. g. all layers of a multilayer<br />

laminate or coextruded product) must be biodegradable.<br />

Make sure that colour masterbatches (pigments and carrier)<br />

are biodegradable, as well. The same is true for labels and<br />

glues.<br />

Biobased plastics<br />

The above mentioned recommendations also hold true with<br />

regard to biobased plastics. After they have undergone as<br />

many as possible mechanical recycling cycles, the preferred<br />

end-of-life solution for these plastics is incineration [3]. In a<br />

well-managed waste-to-energy incineration plant, biobased<br />

plastics are a kind of a renewable energy source.<br />

And finally, exactly the same technical, logistical and<br />

economic conditions for mechanical recycling apply in the<br />

case of bioplastics as for conventional plastics. Basically,<br />

all bioplastics can be technically identified and separated<br />

from the waste stream. This means that the volume of a<br />

particular type of plastic in the waste plastics determines<br />

whether separation is economical or not. From the point of<br />

view of waste logistics, therefore, separability is not the issue<br />

– the bottleneck is the fact that the amounts of bioplastics<br />

are simply too small for recycling to offer an economically<br />

profitable option [3, 4].<br />

[1] Bonten, C.: personal consultation, Feb <strong>2016</strong><br />

[2] Regel, K.: “Verpackungen brauchen ein recyclingfreundliches Design”,<br />

K-Profi, 1-2/<strong>2016</strong>, pp20<br />

[3] Endres, H.-J.: personal consultation, March <strong>2016</strong><br />

[4] Bellusova, D., Endres H.-J.: Mechanisches Recycling und Stabilisierung<br />

von Biokunststoffen, VDI Technikforum „Einsatz und Verarbeitung von<br />

Biokunststoffen“, Berlin, 30.09. - 01.10.2015<br />

44 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11


Published in bioplastics MAGAZINE<br />

10 YEARS AGO<br />

new<br />

series<br />

10 years ago<br />

In March <strong>2016</strong>, Dr. Harald Kaeb says:<br />

“I chaired and managed the association from 1999 to 2009, during a period of strong growth<br />

and fundamental changes. It turned into a multi-sectorial international business organisation,<br />

covering biodegegradable, compostable and non-biodegradable durable plastics and products.<br />

We started media work and advocacy, everything grew like sugarcane. It was very exciting.”<br />

News<br />

<strong>2016</strong><br />

The industrial platform for bioplastics and biodegradable polymers,<br />

IBAW, has re-named itself to become “European Bioplastics”. The new<br />

name expresses the geographic focus of its work and the emphasis<br />

placed on the role of renewable raw materials in production of plastics<br />

with regard to sustainable development and innovation. The members<br />

of IBAW have decided with a very large majority on the new name and<br />

have developed new statutes to prepare the organisation for the future.<br />

Dr. Harald Kaeb<br />

Chairman of European Bioplastics<br />

IBAW industry<br />

association becomes<br />

European Bioplastics<br />

Since its foundation in 1993, the association has undergone dynamic<br />

development. Founded as an industrial working group to define compostability<br />

and biodegradability of plastics, IBAW developed into body<br />

representing the interests of the bioplastics and biodegradable polymers<br />

industry. The association comprises today companies from different<br />

sectors: agricultural feedstock companies, producers of polymer<br />

building blocks and plastics additives, plastics<br />

producers and converters, industrial end users, as<br />

well as service providers in the form of consulting,<br />

research and waste management companies. The<br />

number of member companies has increased from<br />

35 to 56 within the past 18 months.<br />

As a multi-sector association, European Bioplastics<br />

represents all issues within the product life cycle<br />

– from the cradle to the grave or even back to the<br />

cradle. All types of applications are covered. The association<br />

will deal not only with biodegradable polymer products, that<br />

comply with the EN 13432 standard, but also with those that are nonbiodegradable<br />

but based on renewable raw materials.<br />

The mission of the association is to support and promote<br />

- the growth and use of renewable raw materials in products and applications<br />

- innovation leading to lower environmental impact of durable and<br />

non-durable plastic products<br />

- independent third party certification and product labelling based on<br />

the EN 13432 standard, if biodegradability and compostability are<br />

claimed<br />

- separate collection of organic waste including compostable products,<br />

and composting<br />

- the identification and evaluation of other eco-efficient end-of-life options<br />

European Bioplastics will support the market introduction of renewable<br />

and biodegradable polymer products. This includes establishment<br />

of proper framework conditions and the communication of reliable upto-date<br />

information. On June 19 the association will introduce itself<br />

in Brussels, in November it will organise a two-day conference at the<br />

same location. More information is to be found on its website.<br />

www.european-bioplastics.org<br />

8 bioplastics [06/01] Vol. 1<br />

bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11 45


Basics<br />

Glossary 4.2 last update issue <strong>02</strong>/<strong>2016</strong><br />

In bioplastics MAGAZINE again and again<br />

the same expressions appear that some of our readers<br />

might not (yet) be familiar with. This glossary shall help<br />

with these terms and shall help avoid repeated explanations<br />

such as PLA (Polylactide) in various articles.<br />

Bioplastics (as defined by European Bioplastics<br />

e.V.) is a term used to define two different<br />

kinds of plastics:<br />

a. Plastics based on → renewable resources<br />

(the focus is the origin of the raw material<br />

used). These can be biodegradable or not.<br />

b. → Biodegradable and → compostable<br />

plastics according to EN13432 or similar<br />

standards (the focus is the compostability of<br />

the final product; biodegradable and compostable<br />

plastics can be based on renewable<br />

(biobased) and/or non-renewable (fossil) resources).<br />

Bioplastics may be<br />

- based on renewable resources and biodegradable;<br />

- based on renewable resources but not be<br />

biodegradable; and<br />

- based on fossil resources and biodegradable.<br />

1 st Generation feedstock | Carbohydrate rich<br />

plants such as corn or sugar cane that can<br />

also be used as food or animal feed are called<br />

food crops or 1 st generation feedstock. Bred<br />

my mankind over centuries for highest energy<br />

efficiency, currently, 1 st generation feedstock<br />

is the most efficient feedstock for the production<br />

of bioplastics as it requires the least<br />

amount of land to grow and produce the highest<br />

yields. [bM 04/09]<br />

2 nd Generation feedstock | refers to feedstock<br />

not suitable for food or feed. It can be either<br />

non-food crops (e.g. cellulose) or waste materials<br />

from 1 st generation feedstock (e.g.<br />

waste vegetable oil). [bM 06/11]<br />

3 rd Generation feedstock | This term currently<br />

relates to biomass from algae, which – having<br />

a higher growth yield than 1 st and 2 nd generation<br />

feedstock – were given their own category.<br />

It also relates to bioplastics from waste<br />

streams such as CO 2<br />

or methane [bM <strong>02</strong>/16]<br />

Aerobic digestion | Aerobic means in the<br />

presence of oxygen. In →composting, which is<br />

an aerobic process, →microorganisms access<br />

the present oxygen from the surrounding atmosphere.<br />

They metabolize the organic material<br />

to energy, CO 2<br />

, water and cell biomass,<br />

whereby part of the energy of the organic material<br />

is released as heat. [bM 03/07, bM <strong>02</strong>/09]<br />

Since this Glossary will not be printed<br />

in each issue you can download a pdf version<br />

from our website (bit.ly/OunBB0)<br />

bioplastics MAGAZINE is grateful to European Bioplastics for the permission to use parts of their Glossary.<br />

Version 4.0 was revised using EuBP’s latest version (Jan 2015).<br />

[*: bM ... refers to more comprehensive article previously published in bioplastics MAGAZINE)<br />

Anaerobic digestion | In anaerobic digestion,<br />

organic matter is degraded by a microbial<br />

population in the absence of oxygen<br />

and producing methane and carbon dioxide<br />

(= →biogas) and a solid residue that can be<br />

composted in a subsequent step without<br />

practically releasing any heat. The biogas can<br />

be treated in a Combined Heat and Power<br />

Plant (CHP), producing electricity and heat, or<br />

can be upgraded to bio-methane [14] [bM 06/09]<br />

Amorphous | non-crystalline, glassy with unordered<br />

lattice<br />

Amylopectin | Polymeric branched starch<br />

molecule with very high molecular weight<br />

(biopolymer, monomer is →Glucose) [bM 05/09]<br />

Amylose | Polymeric non-branched starch<br />

molecule with high molecular weight (biopolymer,<br />

monomer is →Glucose) [bM 05/09]<br />

Biobased | The term biobased describes the<br />

part of a material or product that is stemming<br />

from →biomass. When making a biobasedclaim,<br />

the unit (→biobased carbon content,<br />

→biobased mass content), a percentage and<br />

the measuring method should be clearly stated [1]<br />

Biobased carbon | carbon contained in or<br />

stemming from →biomass. A material or<br />

product made of fossil and →renewable resources<br />

contains fossil and →biobased carbon.<br />

The biobased carbon content is measured via<br />

the 14 C method (radio carbon dating method)<br />

that adheres to the technical specifications as<br />

described in [1,4,5,6].<br />

Biobased labels | The fact that (and to<br />

what percentage) a product or a material is<br />

→biobased can be indicated by respective<br />

labels. Ideally, meaningful labels should be<br />

based on harmonised standards and a corresponding<br />

certification process by independent<br />

third party institutions. For the property<br />

biobased such labels are in place by certifiers<br />

→DIN CERTCO and →Vinçotte who both base<br />

their certifications on the technical specification<br />

as described in [4,5]<br />

A certification and corresponding label depicting<br />

the biobased mass content was developed<br />

by the French Association Chimie du Végétal<br />

[ACDV].<br />

Biobased mass content | describes the<br />

amount of biobased mass contained in a material<br />

or product. This method is complementary<br />

to the 14 C method, and furthermore, takes<br />

other chemical elements besides the biobased<br />

carbon into account, such as oxygen, nitrogen<br />

and hydrogen. A measuring method has<br />

been developed and tested by the Association<br />

Chimie du Végétal (ACDV) [1]<br />

Biobased plastic | A plastic in which constitutional<br />

units are totally or partly from →<br />

biomass [3]. If this claim is used, a percentage<br />

should always be given to which extent<br />

the product/material is → biobased [1]<br />

[bM 01/07, bM 03/10]<br />

Biodegradable Plastics | Biodegradable Plastics<br />

are plastics that are completely assimilated<br />

by the → microorganisms present a defined<br />

environment as food for their energy. The<br />

carbon of the plastic must completely be converted<br />

into CO 2<br />

during the microbial process.<br />

The process of biodegradation depends on<br />

the environmental conditions, which influence<br />

it (e.g. location, temperature, humidity) and<br />

on the material or application itself. Consequently,<br />

the process and its outcome can vary<br />

considerably. Biodegradability is linked to the<br />

structure of the polymer chain; it does not depend<br />

on the origin of the raw materials.<br />

There is currently no single, overarching standard<br />

to back up claims about biodegradability.<br />

One standard for example is ISO or in Europe:<br />

EN 14995 Plastics- Evaluation of compostability<br />

- Test scheme and specifications<br />

[bM <strong>02</strong>/06, bM 01/07]<br />

Biogas | → Anaerobic digestion<br />

Biomass | Material of biological origin excluding<br />

material embedded in geological formations<br />

and material transformed to fossilised<br />

material. This includes organic material, e.g.<br />

trees, crops, grasses, tree litter, algae and<br />

waste of biological origin, e.g. manure [1, 2]<br />

Biorefinery | the co-production of a spectrum<br />

of bio-based products (food, feed, materials,<br />

chemicals including monomers or building<br />

blocks for bioplastics) and energy (fuels, power,<br />

heat) from biomass.[bM <strong>02</strong>/13]<br />

Blend | Mixture of plastics, polymer alloy of at<br />

least two microscopically dispersed and molecularly<br />

distributed base polymers<br />

Bisphenol-A (BPA) | Monomer used to produce<br />

different polymers. BPA is said to cause<br />

health problems, due to the fact that is behaves<br />

like a hormone. Therefore it is banned<br />

for use in children’s products in many countries.<br />

BPI | Biodegradable Products Institute, a notfor-profit<br />

association. Through their innovative<br />

compostable label program, BPI educates<br />

manufacturers, legislators and consumers<br />

about the importance of scientifically based<br />

standards for compostable materials which<br />

biodegrade in large composting facilities.<br />

Carbon footprint | (CFPs resp. PCFs – Product<br />

Carbon Footprint): Sum of →greenhouse<br />

gas emissions and removals in a product system,<br />

expressed as CO 2<br />

equivalent, and based<br />

on a →life cycle assessment. The CO 2<br />

equivalent<br />

of a specific amount of a greenhouse gas<br />

is calculated as the mass of a given greenhouse<br />

gas multiplied by its →global warmingpotential<br />

[1,2,15]<br />

46 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11


Basics<br />

Carbon neutral, CO 2<br />

neutral | describes a<br />

product or process that has a negligible impact<br />

on total atmospheric CO 2<br />

levels. For<br />

example, carbon neutrality means that any<br />

CO 2<br />

released when a plant decomposes or<br />

is burnt is offset by an equal amount of CO 2<br />

absorbed by the plant through photosynthesis<br />

when it is growing.<br />

Carbon neutrality can also be achieved<br />

through buying sufficient carbon credits to<br />

make up the difference. The latter option is<br />

not allowed when communicating → LCAs<br />

or carbon footprints regarding a material or<br />

product [1, 2].<br />

Carbon-neutral claims are tricky as products<br />

will not in most cases reach carbon neutrality<br />

if their complete life cycle is taken into consideration<br />

(including the end-of life).<br />

If an assessment of a material, however, is<br />

conducted (cradle to gate), carbon neutrality<br />

might be a valid claim in a B2B context. In this<br />

case, the unit assessed in the complete life<br />

cycle has to be clarified [1]<br />

Cascade use | of →renewable resources means<br />

to first use the →biomass to produce biobased<br />

industrial products and afterwards – due to<br />

their favourable energy balance – use them<br />

for energy generation (e.g. from a biobased<br />

plastic product to →biogas production). The<br />

feedstock is used efficiently and value generation<br />

increases decisively.<br />

Catalyst | substance that enables and accelerates<br />

a chemical reaction<br />

Cellophane | Clear film on the basis of →cellulose<br />

[bM 01/10]<br />

Cellulose | Cellulose is the principal component<br />

of cell walls in all higher forms of plant<br />

life, at varying percentages. It is therefore the<br />

most common organic compound and also<br />

the most common polysaccharide (multisugar)<br />

[11]. Cellulose is a polymeric molecule<br />

with very high molecular weight (monomer is<br />

→Glucose), industrial production from wood<br />

or cotton, to manufacture paper, plastics and<br />

fibres [bM 01/10]<br />

Cellulose ester | Cellulose esters occur by<br />

the esterification of cellulose with organic<br />

acids. The most important cellulose esters<br />

from a technical point of view are cellulose<br />

acetate (CA with acetic acid), cellulose propionate<br />

(CP with propionic acid) and cellulose<br />

butyrate (CB with butanoic acid). Mixed polymerisates,<br />

such as cellulose acetate propionate<br />

(CAP) can also be formed. One of the most<br />

well-known applications of cellulose aceto<br />

butyrate (CAB) is the moulded handle on the<br />

Swiss army knife [11]<br />

Cellulose acetate CA | → Cellulose ester<br />

CEN | Comité Européen de Normalisation<br />

(European organisation for standardization)<br />

Certification | is a process in which materials/products<br />

undergo a string of (laboratory)<br />

tests in order to verify that the fulfil certain<br />

requirements. Sound certification systems<br />

should be based on (ideally harmonised) European<br />

standards or technical specifications<br />

(e.g. by →CEN, USDA, ASTM, etc.) and be<br />

performed by independent third party laboratories.<br />

Successful certification guarantees<br />

a high product safety - also on this basis interconnected<br />

labels can be awarded that help<br />

the consumer to make an informed decision.<br />

Compost | A soil conditioning material of decomposing<br />

organic matter which provides nutrients<br />

and enhances soil structure.<br />

[bM 06/08, <strong>02</strong>/09]<br />

Compostable Plastics | Plastics that are<br />

→ biodegradable under →composting conditions:<br />

specified humidity, temperature,<br />

→ microorganisms and timeframe. In order<br />

to make accurate and specific claims about<br />

compostability, the location (home, → industrial)<br />

and timeframe need to be specified [1].<br />

Several national and international standards<br />

exist for clearer definitions, for example EN<br />

14995 Plastics - Evaluation of compostability -<br />

Test scheme and specifications. [bM <strong>02</strong>/06, bM 01/07]<br />

Composting | is the controlled →aerobic, or<br />

oxygen-requiring, decomposition of organic<br />

materials by →microorganisms, under controlled<br />

conditions. It reduces the volume and<br />

mass of the raw materials while transforming<br />

them into CO 2<br />

, water and a valuable soil conditioner<br />

– compost.<br />

When talking about composting of bioplastics,<br />

foremost →industrial composting in a<br />

managed composting facility is meant (criteria<br />

defined in EN 13432).<br />

The main difference between industrial and<br />

home composting is, that in industrial composting<br />

facilities temperatures are much<br />

higher and kept stable, whereas in the composting<br />

pile temperatures are usually lower,<br />

and less constant as depending on factors<br />

such as weather conditions. Home composting<br />

is a way slower-paced process than<br />

industrial composting. Also a comparatively<br />

smaller volume of waste is involved. [bM 03/07]<br />

Compound | plastic mixture from different<br />

raw materials (polymer and additives) [bM 04/10)<br />

Copolymer | Plastic composed of different<br />

monomers.<br />

Cradle-to-Gate | Describes the system<br />

boundaries of an environmental →Life Cycle<br />

Assessment (LCA) which covers all activities<br />

from the cradle (i.e., the extraction of raw materials,<br />

agricultural activities and forestry) up<br />

to the factory gate<br />

Cradle-to-Cradle | (sometimes abbreviated<br />

as C2C): Is an expression which communicates<br />

the concept of a closed-cycle economy,<br />

in which waste is used as raw material<br />

(‘waste equals food’). Cradle-to-Cradle is not<br />

a term that is typically used in →LCA studies.<br />

Cradle-to-Grave | Describes the system<br />

boundaries of a full →Life Cycle Assessment<br />

from manufacture (cradle) to use phase and<br />

disposal phase (grave).<br />

Crystalline | Plastic with regularly arranged<br />

molecules in a lattice structure<br />

Density | Quotient from mass and volume of<br />

a material, also referred to as specific weight<br />

DIN | Deutsches Institut für Normung (German<br />

organisation for standardization)<br />

DIN-CERTCO | independant certifying organisation<br />

for the assessment on the conformity<br />

of bioplastics<br />

Dispersing | fine distribution of non-miscible<br />

liquids into a homogeneous, stable mixture<br />

Drop-In bioplastics | chemically indentical<br />

to conventional petroleum based plastics,<br />

but made from renewable resources. Examples<br />

are bio-PE made from bio-ethanol (from<br />

e.g. sugar cane) or partly biobased PET; the<br />

monoethylene glykol made from bio-ethanol<br />

(from e.g. sugar cane). Developments to<br />

make terephthalic acid from renewable resources<br />

are under way. Other examples are<br />

polyamides (partly biobased e.g. PA 4.10 or PA<br />

6.10 or fully biobased like PA 5.10 or PA10.10)<br />

EN 13432 | European standard for the assessment<br />

of the → compostability of plastic<br />

packaging products<br />

Energy recovery | recovery and exploitation<br />

of the energy potential in (plastic) waste for<br />

the production of electricity or heat in waste<br />

incineration pants (waste-to-energy)<br />

Environmental claim | A statement, symbol<br />

or graphic that indicates one or more environmental<br />

aspect(s) of a product, a component,<br />

packaging or a service. [16]<br />

Enzymes | proteins that catalyze chemical<br />

reactions<br />

Enzyme-mediated plastics | are no →bioplastics.<br />

Instead, a conventional non-biodegradable<br />

plastic (e.g. fossil-based PE) is enriched<br />

with small amounts of an organic additive.<br />

Microorganisms are supposed to consume<br />

these additives and the degradation process<br />

should then expand to the non-biodegradable<br />

PE and thus make the material degrade. After<br />

some time the plastic is supposed to visually<br />

disappear and to be completely converted to<br />

carbon dioxide and water. This is a theoretical<br />

concept which has not been backed up by<br />

any verifiable proof so far. Producers promote<br />

enzyme-mediated plastics as a solution to littering.<br />

As no proof for the degradation process<br />

has been provided, environmental beneficial<br />

effects are highly questionable.<br />

Ethylene | colour- and odourless gas, made<br />

e.g. from, Naphtha (petroleum) by cracking or<br />

from bio-ethanol by dehydration, monomer of<br />

the polymer polyethylene (PE)<br />

European Bioplastics e.V. | The industry association<br />

representing the interests of Europe’s<br />

thriving bioplastics’ industry. Founded<br />

in Germany in 1993 as IBAW, European<br />

Bioplastics today represents the interests<br />

of about 50 member companies throughout<br />

the European Union and worldwide. With<br />

members from the agricultural feedstock,<br />

chemical and plastics industries, as well as<br />

industrial users and recycling companies, European<br />

Bioplastics serves as both a contact<br />

platform and catalyst for advancing the aims<br />

of the growing bioplastics industry.<br />

Extrusion | process used to create plastic<br />

profiles (or sheet) of a fixed cross-section<br />

consisting of mixing, melting, homogenising<br />

and shaping of the plastic.<br />

FDCA | 2,5-furandicarboxylic acid, an intermediate<br />

chemical produced from 5-HMF.<br />

The dicarboxylic acid can be used to make →<br />

PEF = polyethylene furanoate, a polyester that<br />

could be a 100% biobased alternative to PET.<br />

Fermentation | Biochemical reactions controlled<br />

by → microorganisms or → enyzmes (e.g.<br />

the transformation of sugar into lactic acid).<br />

FSC | Forest Stewardship Council. FSC is an<br />

independent, non-governmental, not-forprofit<br />

organization established to promote the<br />

responsible and sustainable management of<br />

the world’s forests.<br />

bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11 47


Basics<br />

Gelatine | Translucent brittle solid substance,<br />

colorless or slightly yellow, nearly tasteless<br />

and odorless, extracted from the collagen inside<br />

animals‘ connective tissue.<br />

Genetically modified organism (GMO) | Organisms,<br />

such as plants and animals, whose<br />

genetic material (DNA) has been altered<br />

are called genetically modified organisms<br />

(GMOs). Food and feed which contain or<br />

consist of such GMOs, or are produced from<br />

GMOs, are called genetically modified (GM)<br />

food or feed [1]. If GM crops are used in bioplastics<br />

production, the multiple-stage processing<br />

and the high heat used to create the<br />

polymer removes all traces of genetic material.<br />

This means that the final bioplastics product<br />

contains no genetic traces. The resulting<br />

bioplastics is therefore well suited to use in<br />

food packaging as it contains no genetically<br />

modified material and cannot interact with<br />

the contents.<br />

Global Warming | Global warming is the rise<br />

in the average temperature of Earth’s atmosphere<br />

and oceans since the late 19th century<br />

and its projected continuation [8]. Global<br />

warming is said to be accelerated by → green<br />

house gases.<br />

Glucose | Monosaccharide (or simple sugar).<br />

G. is the most important carbohydrate (sugar)<br />

in biology. G. is formed by photosynthesis or<br />

hydrolyse of many carbohydrates e. g. starch.<br />

Greenhouse gas GHG | Gaseous constituent<br />

of the atmosphere, both natural and anthropogenic,<br />

that absorbs and emits radiation at<br />

specific wavelengths within the spectrum of<br />

infrared radiation emitted by the earth’s surface,<br />

the atmosphere, and clouds [1, 9]<br />

Greenwashing | The act of misleading consumers<br />

regarding the environmental practices<br />

of a company, or the environmental benefits<br />

of a product or service [1, 10]<br />

Granulate, granules | small plastic particles<br />

(3-4 millimetres), a form in which plastic is<br />

sold and fed into machines, easy to handle<br />

and dose.<br />

HMF (5-HMF) | 5-hydroxymethylfurfural is an<br />

organic compound derived from sugar dehydration.<br />

It is a platform chemical, a building<br />

block for 20 performance polymers and over<br />

175 different chemical substances. The molecule<br />

consists of a furan ring which contains<br />

both aldehyde and alcohol functional groups.<br />

5-HMF has applications in many different<br />

industries such as bioplastics, packaging,<br />

pharmaceuticals, adhesives and chemicals.<br />

One of the most promising routes is 2,5<br />

furandicarboxylic acid (FDCA), produced as an<br />

intermediate when 5-HMF is oxidised. FDCA<br />

is used to produce PEF, which can substitute<br />

terephthalic acid in polyester, especially polyethylene<br />

terephthalate (PET). [bM 03/14, <strong>02</strong>/16]<br />

Home composting | →composting [bM 06/08]<br />

Humus | In agriculture, humus is often used<br />

simply to mean mature →compost, or natural<br />

compost extracted from a forest or other<br />

spontaneous source for use to amend soil.<br />

Hydrophilic | Property: water-friendly, soluble<br />

in water or other polar solvents (e.g. used<br />

in conjunction with a plastic which is not water<br />

resistant and weather proof or that absorbs<br />

water such as Polyamide (PA).<br />

Hydrophobic | Property: water-resistant, not<br />

soluble in water (e.g. a plastic which is water<br />

resistant and weather proof, or that does not<br />

absorb any water such as Polyethylene (PE)<br />

or Polypropylene (PP).<br />

Industrial composting | is an established<br />

process with commonly agreed upon requirements<br />

(e.g. temperature, timeframe) for transforming<br />

biodegradable waste into stable, sanitised<br />

products to be used in agriculture. The<br />

criteria for industrial compostability of packaging<br />

have been defined in the EN 13432. Materials<br />

and products complying with this standard<br />

can be certified and subsequently labelled<br />

accordingly [1,7] [bM 06/08, <strong>02</strong>/09]<br />

ISO | International Organization for Standardization<br />

JBPA | Japan Bioplastics Association<br />

Land use | The surface required to grow sufficient<br />

feedstock (land use) for today’s bioplastic<br />

production is less than 0.01 percent of the<br />

global agricultural area of 5 billion hectares.<br />

It is not yet foreseeable to what extent an increased<br />

use of food residues, non-food crops<br />

or cellulosic biomass (see also →1 st /2 nd /3 rd<br />

generation feedstock) in bioplastics production<br />

might lead to an even further reduced<br />

land use in the future [bM 04/09, 01/14]<br />

LCA | is the compilation and evaluation of the<br />

input, output and the potential environmental<br />

impact of a product system throughout its life<br />

cycle [17]. It is sometimes also referred to as<br />

life cycle analysis, ecobalance or cradle-tograve<br />

analysis. [bM 01/09]<br />

Littering | is the (illegal) act of leaving waste<br />

such as cigarette butts, paper, tins, bottles,<br />

cups, plates, cutlery or bags lying in an open<br />

or public place.<br />

Marine litter | Following the European Commission’s<br />

definition, “marine litter consists of<br />

items that have been deliberately discarded,<br />

unintentionally lost, or transported by winds<br />

and rivers, into the sea and on beaches. It<br />

mainly consists of plastics, wood, metals,<br />

glass, rubber, clothing and paper”. Marine<br />

debris originates from a variety of sources.<br />

Shipping and fishing activities are the predominant<br />

sea-based, ineffectively managed<br />

landfills as well as public littering the main<br />

land-based sources. Marine litter can pose a<br />

threat to living organisms, especially due to<br />

ingestion or entanglement.<br />

Currently, there is no international standard<br />

available, which appropriately describes the<br />

biodegradation of plastics in the marine environment.<br />

However, a number of standardisation<br />

projects are in progress at ISO and ASTM<br />

level. Furthermore, the European project<br />

OPEN BIO addresses the marine biodegradation<br />

of biobased products.[bM <strong>02</strong>/16]<br />

Mass balance | describes the relationship between<br />

input and output of a specific substance<br />

within a system in which the output from the<br />

system cannot exceed the input into the system.<br />

First attempts were made by plastic raw material<br />

producers to claim their products renewable<br />

(plastics) based on a certain input<br />

of biomass in a huge and complex chemical<br />

plant, then mathematically allocating this<br />

biomass input to the produced plastic.<br />

These approaches are at least controversially<br />

disputed [bM 04/14, 05/14, 01/15]<br />

Microorganism | Living organisms of microscopic<br />

size, such as bacteria, funghi or yeast.<br />

Molecule | group of at least two atoms held<br />

together by covalent chemical bonds.<br />

Monomer | molecules that are linked by polymerization<br />

to form chains of molecules and<br />

then plastics<br />

Mulch film | Foil to cover bottom of farmland<br />

Organic recycling | means the treatment of<br />

separately collected organic waste by anaerobic<br />

digestion and/or composting.<br />

Oxo-degradable / Oxo-fragmentable | materials<br />

and products that do not biodegrade!<br />

The underlying technology of oxo-degradability<br />

or oxo-fragmentation is based on special additives,<br />

which, if incorporated into standard<br />

resins, are purported to accelerate the fragmentation<br />

of products made thereof. Oxodegradable<br />

or oxo-fragmentable materials do<br />

not meet accepted industry standards on compostability<br />

such as EN 13432. [bM 01/09, 05/09]<br />

PBAT | Polybutylene adipate terephthalate, is<br />

an aliphatic-aromatic copolyester that has the<br />

properties of conventional polyethylene but is<br />

fully biodegradable under industrial composting.<br />

PBAT is made from fossil petroleum with<br />

first attempts being made to produce it partly<br />

from renewable resources [bM 06/09]<br />

PBS | Polybutylene succinate, a 100% biodegradable<br />

polymer, made from (e.g. bio-BDO)<br />

and succinic acid, which can also be produced<br />

biobased [bM 03/12].<br />

PC | Polycarbonate, thermoplastic polyester,<br />

petroleum based and not degradable, used<br />

for e.g. baby bottles or CDs. Criticized for its<br />

BPA (→ Bisphenol-A) content.<br />

PCL | Polycaprolactone, a synthetic (fossil<br />

based), biodegradable bioplastic, e.g. used as<br />

a blend component.<br />

PE | Polyethylene, thermoplastic polymerised<br />

from ethylene. Can be made from renewable<br />

resources (sugar cane via bio-ethanol) [bM 05/10]<br />

PEF | polyethylene furanoate, a polyester<br />

made from monoethylene glycol (MEG) and<br />

→FDCA (2,5-furandicarboxylic acid , an intermediate<br />

chemical produced from 5-HMF). It<br />

can be a 100% biobased alternative for PET.<br />

PEF also has improved product characteristics,<br />

such as better structural strength and<br />

improved barrier behaviour, which will allow<br />

for the use of PEF bottles in additional applications.<br />

[bM 03/11, 04/12]<br />

PET | Polyethylenterephthalate, transparent<br />

polyester used for bottles and film. The<br />

polyester is made from monoethylene glycol<br />

(MEG), that can be renewably sourced from<br />

bio-ethanol (sugar cane) and (until now fossil)<br />

terephthalic acid [bM 04/14]<br />

PGA | Polyglycolic acid or Polyglycolide is a biodegradable,<br />

thermoplastic polymer and the<br />

simplest linear, aliphatic polyester. Besides<br />

ist use in the biomedical field, PGA has been<br />

introduced as a barrier resin [bM 03/09]<br />

PHA | Polyhydroxyalkanoates (PHA) or the<br />

polyhydroxy fatty acids, are a family of biodegradable<br />

polyesters. As in many mammals,<br />

including humans, that hold energy reserves<br />

in the form of body fat there are also bacteria<br />

that hold intracellular reserves in for of<br />

of polyhydroxy alkanoates. Here the microorganisms<br />

store a particularly high level of<br />

48 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11


Basics<br />

energy reserves (up to 80% of their own body<br />

weight) for when their sources of nutrition become<br />

scarce. By farming this type of bacteria,<br />

and feeding them on sugar or starch (mostly<br />

from maize), or at times on plant oils or other<br />

nutrients rich in carbonates, it is possible to<br />

obtain PHA‘s on an industrial scale [11]. The<br />

most common types of PHA are PHB (Polyhydroxybutyrate,<br />

PHBV and PHBH. Depending<br />

on the bacteria and their food, PHAs with<br />

different mechanical properties, from rubbery<br />

soft trough stiff and hard as ABS, can be produced.<br />

Some PHSs are even biodegradable in<br />

soil or in a marine environment<br />

PLA | Polylactide or Polylactic Acid (PLA), a<br />

biodegradable, thermoplastic, linear aliphatic<br />

polyester based on lactic acid, a natural acid,<br />

is mainly produced by fermentation of sugar<br />

or starch with the help of micro-organisms.<br />

Lactic acid comes in two isomer forms, i.e. as<br />

laevorotatory D(-)lactic acid and as dextrorotary<br />

L(+)lactic acid.<br />

Modified PLA types can be produced by the<br />

use of the right additives or by certain combinations<br />

of L- and D- lactides (stereocomplexing),<br />

which then have the required rigidity for<br />

use at higher temperatures [13] [bM 01/09, 01/12]<br />

Plastics | Materials with large molecular<br />

chains of natural or fossil raw materials, produced<br />

by chemical or biochemical reactions.<br />

PPC | Polypropylene Carbonate, a bioplastic<br />

made by copolymerizing CO 2<br />

with propylene<br />

oxide (PO) [bM 04/12]<br />

PTT | Polytrimethylterephthalate (PTT), partially<br />

biobased polyester, is similarly to PET<br />

produced using terephthalic acid or dimethyl<br />

terephthalate and a diol. In this case it is a<br />

biobased 1,3 propanediol, also known as bio-<br />

PDO [bM 01/13]<br />

Renewable Resources | agricultural raw materials,<br />

which are not used as food or feed,<br />

but as raw material for industrial products<br />

or to generate energy. The use of renewable<br />

resources by industry saves fossil resources<br />

and reduces the amount of → greenhouse gas<br />

emissions. Biobased plastics are predominantly<br />

made of annual crops such as corn,<br />

cereals and sugar beets or perennial cultures<br />

such as cassava and sugar cane.<br />

Resource efficiency | Use of limited natural<br />

resources in a sustainable way while minimising<br />

impacts on the environment. A resource<br />

efficient economy creates more output<br />

or value with lesser input.<br />

Seedling Logo | The compostability label or<br />

logo Seedling is connected to the standard<br />

EN 13432/EN 14995 and a certification process<br />

managed by the independent institutions<br />

→DIN CERTCO and → Vinçotte. Bioplastics<br />

products carrying the Seedling fulfil the<br />

criteria laid down in the EN 13432 regarding<br />

industrial compostability. [bM 01/06, <strong>02</strong>/10]<br />

Saccharins or carbohydrates | Saccharins or<br />

carbohydrates are name for the sugar-family.<br />

Saccharins are monomer or polymer sugar<br />

units. For example, there are known mono-,<br />

di- and polysaccharose. → glucose is a monosaccarin.<br />

They are important for the diet and<br />

produced biology in plants.<br />

Semi-finished products | plastic in form of<br />

sheet, film, rods or the like to be further processed<br />

into finshed products<br />

Sorbitol | Sugar alcohol, obtained by reduction<br />

of glucose changing the aldehyde group<br />

to an additional hydroxyl group. S. is used as<br />

a plasticiser for bioplastics based on starch.<br />

Starch | Natural polymer (carbohydrate)<br />

consisting of → amylose and → amylopectin,<br />

gained from maize, potatoes, wheat, tapioca<br />

etc. When glucose is connected to polymerchains<br />

in definite way the result (product) is<br />

called starch. Each molecule is based on 300<br />

-12000-glucose units. Depending on the connection,<br />

there are two types → amylose and →<br />

amylopectin known. [bM 05/09]<br />

Starch derivatives | Starch derivatives are<br />

based on the chemical structure of → starch.<br />

The chemical structure can be changed by<br />

introducing new functional groups without<br />

changing the → starch polymer. The product<br />

has different chemical qualities. Mostly the<br />

hydrophilic character is not the same.<br />

Starch-ester | One characteristic of every<br />

starch-chain is a free hydroxyl group. When<br />

every hydroxyl group is connected with an<br />

acid one product is starch-ester with different<br />

chemical properties.<br />

Starch propionate and starch butyrate |<br />

Starch propionate and starch butyrate can be<br />

synthesised by treating the → starch with propane<br />

or butanic acid. The product structure<br />

is still based on → starch. Every based → glucose<br />

fragment is connected with a propionate<br />

or butyrate ester group. The product is more<br />

hydrophobic than → starch.<br />

Sustainable | An attempt to provide the best<br />

outcomes for the human and natural environments<br />

both now and into the indefinite future.<br />

One famous definition of sustainability is the<br />

one created by the Brundtland Commission,<br />

led by the former Norwegian Prime Minister<br />

G. H. Brundtland. The Brundtland Commission<br />

defined sustainable development as<br />

development that ‘meets the needs of the<br />

present without compromising the ability of<br />

future generations to meet their own needs.’<br />

Sustainability relates to the continuity of economic,<br />

social, institutional and environmental<br />

aspects of human society, as well as the nonhuman<br />

environment).<br />

Sustainable sourcing | of renewable feedstock<br />

for biobased plastics is a prerequisite<br />

for more sustainable products. Impacts such<br />

as the deforestation of protected habitats<br />

or social and environmental damage arising<br />

from poor agricultural practices must<br />

be avoided. Corresponding certification<br />

schemes, such as ISCC PLUS, WLC or Bon-<br />

Sucro, are an appropriate tool to ensure the<br />

sustainable sourcing of biomass for all applications<br />

around the globe.<br />

Sustainability | as defined by European Bioplastics,<br />

has three dimensions: economic, social<br />

and environmental. This has been known<br />

as “the triple bottom line of sustainability”.<br />

This means that sustainable development involves<br />

the simultaneous pursuit of economic<br />

prosperity, environmental protection and social<br />

equity. In other words, businesses have<br />

to expand their responsibility to include these<br />

environmental and social dimensions. Sustainability<br />

is about making products useful to<br />

markets and, at the same time, having societal<br />

benefits and lower environmental impact<br />

than the alternatives currently available. It also<br />

implies a commitment to continuous improvement<br />

that should result in a further reduction<br />

of the environmental footprint of today’s products,<br />

processes and raw materials used.<br />

Thermoplastics | Plastics which soften or<br />

melt when heated and solidify when cooled<br />

(solid at room temperature).<br />

Thermoplastic Starch | (TPS) → starch that<br />

was modified (cooked, complexed) to make it<br />

a plastic resin<br />

Thermoset | Plastics (resins) which do not<br />

soften or melt when heated. Examples are<br />

epoxy resins or unsaturated polyester resins.<br />

Vinçotte | independant certifying organisation<br />

for the assessment on the conformity of bioplastics<br />

WPC | Wood Plastic Composite. Composite<br />

materials made of wood fiber/flour and plastics<br />

(mostly polypropylene).<br />

Yard Waste | Grass clippings, leaves, trimmings,<br />

garden residue.<br />

References:<br />

[1] Environmental Communication Guide,<br />

European Bioplastics, Berlin, Germany,<br />

2012<br />

[2] ISO 14067. Carbon footprint of products -<br />

Requirements and guidelines for quantification<br />

and communication<br />

[3] CEN TR 15932, Plastics - Recommendation<br />

for terminology and characterisation<br />

of biopolymers and bioplastics, 2010<br />

[4] CEN/TS 16137, Plastics - Determination<br />

of bio-based carbon content, 2011<br />

[5] ASTM D6866, Standard Test Methods for<br />

Determining the Biobased Content of<br />

Solid, Liquid, and Gaseous Samples Using<br />

Radiocarbon Analysis<br />

[6] SPI: Understanding Biobased Carbon<br />

Content, 2012<br />

[7] EN 13432, Requirements for packaging<br />

recoverable through composting and biodegradation.<br />

Test scheme and evaluation<br />

criteria for the final acceptance of packaging,<br />

2000<br />

[8] Wikipedia<br />

[9] ISO 14064 Greenhouse gases -- Part 1:<br />

Specification with guidance..., 2006<br />

[10] Terrachoice, 2010, www.terrachoice.com<br />

[11] Thielen, M.: Bioplastics: Basics. Applications.<br />

Markets, Polymedia Publisher,<br />

2012<br />

[12] Lörcks, J.: Biokunststoffe, Broschüre der<br />

FNR, 2005<br />

[13] de Vos, S.: Improving heat-resistance of<br />

PLA using poly(D-lactide),<br />

bioplastics MAGAZINE, Vol. 3, <strong>Issue</strong> <strong>02</strong>/2008<br />

[14] de Wilde, B.: Anaerobic Digestion, bioplastics<br />

MAGAZINE, Vol 4., <strong>Issue</strong> 06/2009<br />

[15] ISO 14067 onb Corbon Footprint of<br />

Products<br />

[16] ISO 14<strong>02</strong>1 on Self-declared Environmental<br />

claims<br />

[17] ISO 14044 on Life Cycle Assessment<br />

bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11 49


Suppliers Guide<br />

1. Raw Materials<br />

AGRANA Starch<br />

Bioplastics<br />

Conrathstraße 7<br />

A-3950 Gmuend, Austria<br />

technical.starch@agrana.com<br />

www.agrana.com<br />

Jincheng, Lin‘an, Hangzhou,<br />

Zhejiang 311300, P.R. China<br />

China contact: Grace Jin<br />

mobile: 0086 135 7578 9843<br />

Grace@xinfupharm.com<br />

Europe contact(Belgium): Susan Zhang<br />

mobile: 0032 478 991619<br />

zxh0612@hotmail.com<br />

www.xinfupharm.com<br />

Kingfa Sci. & Tech. Co., Ltd.<br />

No.33 Kefeng Rd, Sc. City, Guangzhou<br />

Hi-Tech Ind. Development Zone,<br />

Guangdong, P.R. China. 510663<br />

Tel: +86 (0)20 6622 1696<br />

info@ecopond.com.cn<br />

www.ecopond.com.cn<br />

FLEX-162 Biodeg. Blown Film Resin!<br />

Bio-873 4-Star Inj. Bio-Based Resin!<br />

Simply contact:<br />

Tel.: +49 2161 6884467<br />

suppguide@bioplasticsmagazine.com<br />

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Suppliers Guide with your company<br />

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For only 6,– EUR per mm, per issue you<br />

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For Example:<br />

Showa Denko Europe GmbH<br />

Konrad-Zuse-Platz 4<br />

81829 Munich, Germany<br />

Tel.: +49 89 93996226<br />

www.showa-denko.com<br />

support@sde.de<br />

PTT MCC Biochem Co., Ltd.<br />

info@pttmcc.com / www.pttmcc.com<br />

Tel: +66(0) 2 140-3563<br />

MCPP Germany GmbH<br />

+49 (0) 152-018 920 51<br />

frank.steinbrecher@mcpp-europe.com<br />

MCPP France SAS<br />

+33 (0) 6 07 22 25 32<br />

fabien.resweber@mcpp-europe.com<br />

1.1 bio based monomers<br />

Corbion Purac<br />

Arkelsedijk 46, P.O. Box 21<br />

4200 AA Gorinchem -<br />

The Netherlands<br />

Tel.: +31 (0)183 695 695<br />

Fax: +31 (0)183 695 604<br />

www.corbion.com/bioplastics<br />

bioplastics@corbion.com<br />

62 136 Lestrem, France<br />

Tel.: + 33 (0) 3 21 63 36 00<br />

www.roquette-performance-plastics.com<br />

FKuR Kunststoff GmbH<br />

Siemensring 79<br />

D - 47 877 Willich<br />

Tel. +49 2154 9251-0<br />

Tel.: +49 2154 9251-51<br />

sales@fkur.com<br />

www.fkur.com<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

39 mm<br />

Polymedia Publisher GmbH<br />

Dammer Str. 112<br />

41066 Mönchengladbach<br />

Germany<br />

Tel. +49 2161 664864<br />

Fax +49 2161 631045<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

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three month before expiry.<br />

www.facebook.com<br />

www.issuu.com<br />

www.twitter.com<br />

www.youtube.com<br />

DuPont de Nemours International S.A.<br />

2 chemin du Pavillon<br />

1218 - Le Grand Saconnex<br />

Switzerland<br />

Tel.: +41 22 171 51 11<br />

Fax: +41 22 580 22 45<br />

www.renewable.dupont.com<br />

www.plastics.dupont.com<br />

Tel: +86 351-8689356<br />

Fax: +86 351-8689718<br />

www.ecoworld.jinhuigroup.com<br />

ecoworldsales@jinhuigroup.com<br />

Evonik Industries AG<br />

Paul Baumann Straße 1<br />

45772 Marl, Germany<br />

Tel +49 2365 49-4717<br />

evonik-hp@evonik.com<br />

www.vestamid-terra.com<br />

www.evonik.com<br />

1.2 compounds<br />

API S.p.A.<br />

Via Dante Alighieri, 27<br />

36065 Mussolente (VI), Italy<br />

Telephone +39 0424 579711<br />

www.apiplastic.com<br />

www.apinatbio.com<br />

BIO-FED<br />

Branch of AKRO-PLASTIC GmbH<br />

BioCampus Cologne<br />

Nattermannallee 1<br />

50829 Cologne, Germany<br />

Tel.: +49 221 88 88 94-00<br />

info@bio-fed.com<br />

www.bio-fed.com<br />

NUREL Engineering Polymers<br />

Ctra. Barcelona, km 329<br />

50016 Zaragoza, Spain<br />

Tel: +34 976 465 579<br />

inzea@samca.com<br />

www.inzea-biopolymers.com<br />

PolyOne<br />

Avenue Melville Wilson, 2<br />

Zoning de la Fagne<br />

5330 Assesse<br />

Belgium<br />

Tel.: + 32 83 660 211<br />

www.polyone.com<br />

1.3 PLA<br />

Shenzhen Esun Ind. Co;Ltd<br />

www.brightcn.net<br />

www.esun.en.alibaba.com<br />

bright@brightcn.net<br />

Tel: +86-755-2603 1978<br />

50 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11


Suppliers Guide<br />

1.4 starch-based bioplastics<br />

Limagrain Céréales Ingrédients<br />

ZAC „Les Portes de Riom“ - BP 173<br />

63204 Riom Cedex - France<br />

Tel. +33 (0)4 73 67 17 00<br />

Fax +33 (0)4 73 67 17 10<br />

www.biolice.com<br />

BIOTEC<br />

Biologische Naturverpackungen<br />

Werner-Heisenberg-Strasse 32<br />

46446 Emmerich/Germany<br />

Tel.: +49 (0) 2822 – 92510<br />

info@biotec.de<br />

www.biotec.de<br />

Grabio Greentech Corporation<br />

Tel: +886-3-598-6496<br />

No. 91, Guangfu N. Rd., Hsinchu<br />

Industrial Park,Hukou Township,<br />

Hsinchu County 30351, Taiwan<br />

sales@grabio.com.tw<br />

www.grabio.com.tw<br />

1.5 PHA<br />

PolyOne<br />

Avenue Melville Wilson, 2<br />

Zoning de la Fagne<br />

5330 Assesse<br />

Belgium<br />

Tel.: + 32 83 660 211<br />

www.polyone.com<br />

2. Additives/Secondary raw materials<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

3. Semi finished products<br />

3.1 films<br />

Infiana Germany GmbH & Co. KG<br />

Zweibrückenstraße 15-25<br />

91301 Forchheim<br />

Tel. +49-9191 81-0<br />

Fax +49-9191 81-212<br />

www.infiana.com<br />

Natur-Tec ® - Northern Technologies<br />

4201 Woodland Road<br />

Circle Pines, MN 55014 USA<br />

Tel. +1 763.404.8700<br />

Fax +1 763.225.6645<br />

info@natur-tec.com<br />

www.natur-tec.com<br />

NOVAMONT S.p.A.<br />

Via Fauser , 8<br />

28100 Novara - ITALIA<br />

Fax +39.0321.699.601<br />

Tel. +39.0321.699.611<br />

www.novamont.com<br />

President Packaging Ind., Corp.<br />

PLA Paper Hot Cup manufacture<br />

In Taiwan, www.ppi.com.tw<br />

Tel.: +886-6-570-4066 ext.5531<br />

Fax: +886-6-570-4077<br />

sales@ppi.com.tw<br />

6. Equipment<br />

6.1 Machinery & Molds<br />

Uhde Inventa-Fischer GmbH<br />

Holzhauser Strasse 157–159<br />

D-13509 Berlin<br />

Tel. +49 30 43 567 5<br />

Fax +49 30 43 567 699<br />

sales.de@uhde-inventa-fischer.com<br />

Uhde Inventa-Fischer AG<br />

Via Innovativa 31, CH-7013 Domat/Ems<br />

Tel. +41 81 632 63 11<br />

Fax +41 81 632 74 03<br />

sales.ch@uhde-inventa-fischer.com<br />

www.uhde-inventa-fischer.com<br />

9. Services<br />

Osterfelder Str. 3<br />

46047 Oberhausen<br />

Tel.: +49 (0)208 8598 1227<br />

Fax: +49 (0)208 8598 1424<br />

thomas.wodke@umsicht.fhg.de<br />

www.umsicht.fraunhofer.de<br />

Institut für Kunststofftechnik<br />

Universität Stuttgart<br />

Böblinger Straße 70<br />

70199 Stuttgart<br />

Tel +49 711/685-62814<br />

Linda.Goebel@ikt.uni-stuttgart.de<br />

www.ikt.uni-stuttgart.de<br />

TianAn Biopolymer<br />

No. 68 Dagang 6th Rd,<br />

Beilun, Ningbo, China, 315800<br />

Tel. +86-57 48 68 62 50 2<br />

Fax +86-57 48 68 77 98 0<br />

enquiry@tianan-enmat.com<br />

www.tianan-enmat.com<br />

Metabolix, Inc.<br />

Bio-based and biodegradable resins<br />

and performance additives<br />

21 Erie Street<br />

Cambridge, MA <strong>02</strong>139, USA<br />

US +1-617-583-1700<br />

DE +49 (0) 221 / 88 88 94 00<br />

www.metabolix.com<br />

info@metabolix.com<br />

Taghleef Industries SpA, Italy<br />

Via E. Fermi, 46<br />

33058 San Giorgio di Nogaro (UD)<br />

Contact Emanuela Bardi<br />

Tel. +39 0431 627264<br />

Mobile +39 342 6565309<br />

emanuela.bardi@ti-films.com<br />

www.ti-films.com<br />

4. Bioplastics products<br />

Molds, Change Parts and Turnkey<br />

Solutions for the PET/Bioplastic<br />

Container Industry<br />

284 Pinebush Road<br />

Cambridge Ontario<br />

Canada N1T 1Z6<br />

Tel. +1 519 624 9720<br />

Fax +1 519 624 9721<br />

info@hallink.com<br />

www.hallink.com<br />

6.2 Laboratory Equipment<br />

MODA: Biodegradability Analyzer<br />

SAIDA FDS INC.<br />

143-10 Isshiki, Yaizu,<br />

Shizuoka,Japan<br />

Tel:+81-54-624-6260<br />

Info2@moda.vg<br />

www.saidagroup.jp<br />

narocon<br />

Dr. Harald Kaeb<br />

Tel.: +49 30-28096930<br />

kaeb@narocon.de<br />

www.narocon.de<br />

nova-Institut GmbH<br />

Chemiepark Knapsack<br />

Industriestrasse 300<br />

50354 Huerth, Germany<br />

Tel.: +49(0)2233-48-14 40<br />

E-Mail: contact@nova-institut.de<br />

www.biobased.eu<br />

1.6 masterbatches<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

Minima Technology Co., Ltd.<br />

Esmy Huang, Marketing Manager<br />

No.33. Yichang E. Rd., Taipin City,<br />

Taichung County<br />

411, Taiwan (R.O.C.)<br />

Tel. +886(4)2277 6888<br />

Fax +883(4)2277 6989<br />

Mobil +886(0)982-829988<br />

esmy@minima-tech.com<br />

Skype esmy325<br />

www.minima-tech.com<br />

7. Plant engineering<br />

EREMA Engineering Recycling<br />

Maschinen und Anlagen GmbH<br />

Unterfeldstrasse 3<br />

4052 Ansfelden, AUSTRIA<br />

Phone: +43 (0) 732 / 3190-0<br />

Fax: +43 (0) 732 / 3190-23<br />

erema@erema.at<br />

www.erema.at<br />

Bioplastics Consulting<br />

Tel. +49 2161 664864<br />

info@polymediaconsult.com<br />

bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11 51


Suppliers Guide<br />

9. Services (continued)<br />

UL International TTC GmbH<br />

Rheinuferstrasse 7-9, Geb. R33<br />

47829 Krefeld-Uerdingen, Germany<br />

Tel.: +49 (0) 2151 5370-333<br />

Fax: +49 (0) 2151 5370-334<br />

ttc@ul.com<br />

www.ulttc.com<br />

European Bioplastics e.V.<br />

Marienstr. 19/20<br />

10117 Berlin, Germany<br />

Tel. +49 30 284 82 350<br />

Fax +49 30 284 84 359<br />

info@european-bioplastics.org<br />

www.european-bioplastics.org<br />

10.2 Universities<br />

Michigan State University<br />

Department of Chemical<br />

Engineering & Materials Science<br />

Professor Ramani Narayan<br />

East Lansing MI 48824, USA<br />

Tel. +1 517 719 7163<br />

narayan@msu.edu<br />

10.3 Other Institutions<br />

Simply contact:<br />

Tel.: +49 2161 6884467<br />

suppguide@bioplasticsmagazine.com<br />

Stay permanently listed in the<br />

Suppliers Guide with your company<br />

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For Example:<br />

10. Institutions<br />

10.1 Associations<br />

BPI - The Biodegradable<br />

Products Institute<br />

331 West 57th Street, Suite 415<br />

New York, NY 10019, USA<br />

Tel. +1-888-274-5646<br />

info@bpiworld.org<br />

IfBB – Institute for Bioplastics<br />

and Biocomposites<br />

University of Applied Sciences<br />

and Arts Hanover<br />

Faculty II – Mechanical and<br />

Bioprocess Engineering<br />

Heisterbergallee 12<br />

30453 Hannover, Germany<br />

Tel.: +49 5 11 / 92 96 - 22 69<br />

Fax: +49 5 11 / 92 96 - 99 - 22 69<br />

lisa.mundzeck@fh-hannover.de<br />

http://www.ifbb-hannover.de/<br />

Biobased Packaging Innovations<br />

Caroli Buitenhuis<br />

IJburglaan 836<br />

1087 EM Amsterdam<br />

The Netherlands<br />

Tel.: +31 6-24216733<br />

http://www.biobasedpackaging.nl<br />

Polymedia Publisher GmbH<br />

Dammer Str. 112<br />

41066 Mönchengladbach<br />

Germany<br />

Tel. +49 2161 664864<br />

Fax +49 2161 631045<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Sample Charge:<br />

39mm x 6,00 €<br />

= 234,00 € per entry/per issue<br />

39 mm<br />

Sample Charge for one year:<br />

6 issues x 234,00 EUR = 1,404.00 €<br />

The entry in our Suppliers Guide is<br />

bookable for one year (6 issues) and<br />

extends automatically if it’s not canceled<br />

three month before expiry.<br />

www.eiha-conference.org<br />

13 th International Conference of the European Industrial Hemp Association (EIHA)<br />

1 – 2 June <strong>2016</strong><br />

Rheinforum, Wesseling near Cologne (Germany)<br />

Conference language: English<br />

International Conference<br />

of the European Industrial<br />

Hemp Association (EIHA)<br />

www.eiha-conference.org<br />

++ Cultivation ++ Processing ++ Economy ++ Sustainability ++ Innovation ++<br />

Source: Hempro, Hemcore, NPSP Composites (2), Hemp Technology<br />

52 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11<br />

Don’t miss the biggest industrial hemp event in <strong>2016</strong> – worldwide!


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end a scan of your<br />

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Empack <strong>2016</strong> (with Biobased Village)<br />

12.04.<strong>2016</strong> - 14.04.<strong>2016</strong> - Utrecht, The Netherlands<br />

bit.ly/1m03cuf<br />

3 rd Bioplastic Materials Topical Conference<br />

19.04.<strong>2016</strong> - 21.04.<strong>2016</strong> - Bloomington, (MN) USA<br />

www. www.eiseverywhere.com/ehome/130808?eb=227133<br />

Chinaplas <strong>2016</strong><br />

25.04.<strong>2016</strong> - 28.04.<strong>2016</strong> - Shanghai, China<br />

www.ChinaplasOnline.com<br />

can meet us<br />

SINAL - les rencontres profesionnelles du biosourcé<br />

24.05.<strong>2016</strong> - 25.05.<strong>2016</strong> - Châlons-en-Champagne, France<br />

www.sinal-exhibition.eu<br />

Bio-based Chemicals / Biobased Products <strong>2016</strong><br />

24.05.<strong>2016</strong> - 25.05.<strong>2016</strong> - Amsterdam, The Netherlands<br />

http://www.biobasedproductsworld.com/europe<br />

Jan/Feb<br />

01 | <strong>2016</strong><br />

4 th PLA World Congress<br />

organized by bioplastics MAGAZINE<br />

24 - 25. 05.<strong>2016</strong> - Munich, Germany<br />

ISSN 1862-5258<br />

Basics<br />

ISSN 1862-5258<br />

Public Procurement | 34<br />

Highlights<br />

Automotive | 12<br />

Foam | 30<br />

May 2006<br />

ISSN 1862-5258<br />

Plant based Material for<br />

Eyeglass Lenses | 39<br />

March/April<br />

<strong>02</strong> | <strong>2016</strong><br />

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Biobased Products Europe<br />

25 - 26. 05.<strong>2016</strong> - Amsterdam, The Netherlands<br />

http://www.biobasedproductsworld.com/europe<br />

Innovation and Sustainability in Consumer Packaging<br />

23.06.<strong>2016</strong> - Seoul, South Korea<br />

http://atlatitude.com/w/?tag=research<br />

ISBP-<strong>2016</strong><br />

26.09.<strong>2016</strong> - 29.09.<strong>2016</strong> - Madrid, Spain<br />

bioplastics MAGAZINE Vol. 11<br />

Vol. 1<br />

bioplastics magazine<br />

Top Talk:<br />

Interview with Helmut Traitler,<br />

VP Packaging of Nestlé | 10<br />

bioplastics MAGAZINE Vol. 11<br />

Basics<br />

Design for Recyclability | 44<br />

Highlights<br />

Thermoforming / Rigid Packaging | 12<br />

Marine Pollution / Marine Degradation | 16<br />

Preview<br />

www.isbp<strong>2016</strong>.com/home<br />

3 rd Bioplastics Buisiness Breakfast @ K‘<strong>2016</strong><br />

organized by bioplastics MAGAZINE<br />

20 - 22.10.<strong>2016</strong> - Düsseldorf, Germany<br />

www.bioplastics-breakfast.com<br />

+<br />

... is read in 92 countries<br />

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10.11.<strong>2016</strong> - 11.11.<strong>2016</strong> - Alicante, Spain<br />

http://bioplastics.conferenceseries.com/<br />

or<br />

11 th European Bioplastics Conference<br />

29.11.<strong>2016</strong> - 30.11.<strong>2016</strong>- Berlin, Germany<br />

http://www.european-bioplastics.org/events/eubp-conference/<br />

Mention the promotion code ‘watch‘ or ‘book‘<br />

and you will get our watch or the book 3)<br />

Bioplastics Basics. Applications. Markets. for free<br />

1) Offer valid until 30 April <strong>2016</strong><br />

3) Gratis-Buch in Deutschland nicht möglich, no free book in Germany<br />

bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11 53


Companies in this issue<br />

Company Editorial Advert Company Editorial Advert Company Editorial Advert<br />

Agrana Starch Thermoplastics 50<br />

AIMPLAS 10,38<br />

Anhui Tianyi Env. Protection Techn. 28<br />

API 50<br />

AU CO. 28<br />

Avantium 6<br />

BASF 6,28<br />

Beta Analytic 34<br />

Biobased Packaging Innovations 52<br />

BIO-FED 50<br />

Biopolymer Network / Scion 10<br />

Biosolutions 10<br />

Biotec 10 51<br />

BK Pac 36<br />

Bodega Matarromera 38<br />

BPI 52<br />

Braskem 36<br />

Calysta Energy 6<br />

Center for Biopl. and Biocomposites 35<br />

China XD Plastics Company 28<br />

Club Bioplastique 5<br />

Coating p. Materials 28<br />

Coca-Cola 32<br />

ColorFABB 8<br />

Corbion 5,10 50<br />

Croda Europe 28<br />

Dandong Ritian Nano Technology 28<br />

Danone 32<br />

Doill Ecotec 28<br />

Dongguan Xinhai env. prot. material 28<br />

DuPont 50<br />

Emery Oleochemicals HK 28<br />

EnerPlastics 28<br />

EREMA 43,51<br />

European Bioplastics 5,10,32,42,45 27,52<br />

Evonik 28 50<br />

Far Eastern New Century 32<br />

FKuR 10,36 2,5<br />

Fraunhofer IAP 10<br />

Fraunhofer ICT 10<br />

Fraunhofer IVV 10<br />

Fraunhofer UMSICHT 51<br />

Fukutomi Company 28<br />

Gema Elektro Plastik . 28<br />

GRABIO Greentech Corporation 28 51<br />

Grafe 50,51<br />

GuangDong ShunDe LuHua 28<br />

Hairma Chemicals (GZ) 28<br />

Hallink 51<br />

Hebei Jingu Plasticizer 28<br />

Helian Polymers 8, 10<br />

Ikea 7,39<br />

Infiana Germany 51<br />

Institut für Biopl. & Biocomposites 32 52<br />

Iowa State University 7<br />

ISCC 10<br />

Itoh Optical Ind. 39<br />

Jacobson van den Berg (Hong Kong) 28<br />

Jelu Werk 36<br />

Jetwell Trading Limited 28<br />

Jiangsu Jinhe Hi-tech 28<br />

Jiangsu Torise Biomaterials 28<br />

Jinan Shengquan Group 28<br />

JinHui ZhaoLong 28 50<br />

Kimberly-Clark Corporation 10<br />

Kingfa 50<br />

Kingfa Science and Technology 28<br />

KU Leuven 10<br />

Kuraray 12,28<br />

Lifeline Technologies 28<br />

Limagrain Céréales Ingrédients 51<br />

Maosheng Env. Protection Technology 28<br />

Matchexpo 28<br />

Meredian Holdings Group 21<br />

Metabolix 14 51<br />

Michigan State University 10,18 52<br />

Minima Technology 28 51<br />

Miracll Chemicals 28<br />

Mitsubishi Chemical Corporation 28<br />

Mitsui 39 13<br />

mtm 44<br />

narocon 51<br />

NatureWorks 6,10,28<br />

Natur-Tec 51<br />

Nestlé 32<br />

Newlight Technologies 7<br />

Ngai Hing Hong Plastic Materials (HK) 28<br />

nova-Institute 10 9,51<br />

Novamont 16 51,56<br />

NSF 35<br />

NUREL Engineering Polymers 50<br />

Oerlemans Plastics 36<br />

Open-Bio 26<br />

Plantic 12<br />

Plantura Italia 10<br />

plasticker 20<br />

Polyalloy Inc. 28<br />

PolyOne 50,51<br />

President Packaging 51<br />

Procotex Corporation 28<br />

Proviron Functional Chemicals 28<br />

PTT MCC Biochem 37,51<br />

Rajiv Plastic Industries 28<br />

Reverdia 28<br />

Roquette 28 50<br />

Saida 51<br />

Samyang Corporation 28<br />

Shandong Jiqing Chemcal 28<br />

Shanghai Xiner Low-carbon 28<br />

Shenzhen All Technology Limited 28<br />

Shenzhen Esun Industrial 28 50<br />

Shenzhen Polymer Industry Ass. 28<br />

Showa Denko 50<br />

Stanford University 7<br />

Süddeutsches Kunststoffzentrum SKZ 10<br />

Sukano 10,28<br />

Supla 10<br />

Suzhou Hanfeng New Material 28<br />

Suzhou Hydal Biotech 28<br />

Suzhou Mitac Precision Technology 28<br />

Synbra 10<br />

Taghleef Industries 51<br />

Taizhou Sudarshan New Material 28<br />

Teijin Kasei (HK) 28<br />

TianAn Biopolymer 51<br />

Toray Plastics 38<br />

TÜV Rheinland (Shanghai) 28<br />

Uhde Inventa-Fischer 10,28 51<br />

UL International TTC 52<br />

UNEP 24<br />

Univ. Hohenheim 40<br />

Univ. Stuttgart (IKT) 51<br />

University of Ap. Sc. Hamm-Lippstadt 10<br />

Vinçotte 22<br />

Virent 32<br />

Wageningen UR 10<br />

Wei Li Plastics Machinery (H.K.) 28<br />

WeiFang Graceland Chemicals 28<br />

Weihai Lianqiao New M at. Sc.& Techn. 28<br />

Woosung Chemical 28<br />

Wuhan Huali Environmental Technology 28<br />

Xinjiang Blue Ridge Tunhe Polyester 28<br />

Yamamoto Kogaku 39<br />

Yat Shun Hong Company 28<br />

Yongxi Pplastics Technology 28<br />

Zhejiang Hangzhou Xinfu Pharmaceutical 28 50<br />

Zhejiang Hisun Biomaterials 28<br />

Zhejiang Pu Wei Lun Chemicals 28<br />

Zhuhai Xunfeng Special Plastics 28<br />

Editorial Planner<br />

<strong>2016</strong><br />

<strong>Issue</strong> Month Publ.-Date<br />

edit/advert/<br />

Deadline<br />

Editorial Focus (1) Editorial Focus (2) Basics<br />

03/<strong>2016</strong> May/Jun 06 Jun <strong>2016</strong> 06 May <strong>2016</strong> Injection moulding Joining of bioplastics<br />

(welding, glueing etc),<br />

Adhesives<br />

PHA (update)<br />

04/<strong>2016</strong> Jul/Aug 01 Aug <strong>2016</strong> 01 Jul <strong>2016</strong> Blow Moulding Toys Additives<br />

Trade-Fair<br />

Specials<br />

Chinaplas<br />

Review<br />

05/<strong>2016</strong> Sep/Oct 04 Oct <strong>2016</strong> <strong>02</strong> Sep <strong>2016</strong> Fiber / Textile /<br />

Nonwoven<br />

Polyurethanes /<br />

Elastomers/Rubber<br />

Co-Polyesters<br />

K'<strong>2016</strong> preview<br />

06/<strong>2016</strong> Nov/Dec 05 Dec <strong>2016</strong> 04 Nov <strong>2016</strong> Films / Flexibles /<br />

Bags<br />

Consumer & Office<br />

Electronics<br />

Certification - Blessing<br />

and Curse<br />

K'<strong>2016</strong> Review<br />

54 bioplastics MAGAZINE [<strong>02</strong>/16] Vol. 11


PRESENTS<br />

<strong>2016</strong><br />

THE ELEVENTH ANNUAL GLOBAL AWARD FOR<br />

DEVELOPERS, MANUFACTURERS AND USERS OF<br />

BIOBASED AND/OR BIODEGRADABLE PLASTICS.<br />

Call for proposals<br />

Enter your own product, service or development, or nominate<br />

your favourite example from another organisation<br />

Please let us know until August 31 st<br />

1. What the product, service or development is and does<br />

2. Why you think this product, service or development should win an award<br />

3. What your (or the proposed) company or organisation does<br />

Your entry should not exceed 500 words (approx. 1 page) and may also<br />

be supported with photographs, samples, marketing brochures and/or<br />

technical documentation (cannot be sent back). The 5 nominees must be<br />

prepared to provide a 30 second videoclip<br />

More details and an entry form can be downloaded from<br />

www.bioplasticsmagazine.de/award<br />

The Bioplastics Award will be presented during the<br />

11 th European Bioplastics Conference<br />

November 29-30, <strong>2016</strong>, Berlin, Germany<br />

supported by<br />

Sponsors welcome, please contact mt@bioplasticsmagazine.com


www.novamont.com<br />

BIODEGRADABLE AND COMPOSTABLE BIOPLASTIC<br />

CONTROLLED, innovative, GUARANTEED<br />

EcoComunicazione.it<br />

QUALITY OUR TOP PRIORITY<br />

Using the MATER-BI trademark licence<br />

means that NOVAMONT’s partners agree<br />

to comply with strict quality parameters and<br />

testing of random samples from the market.<br />

These are designed to ensure that films<br />

are converted under ideal conditions<br />

and that articles produced in MATER-BI<br />

meet all essential requirements. To date<br />

over 1000 products have been tested.<br />

THE GUARANTEE<br />

OF AN ITALIAN BRAND<br />

MATER-BI is part of a virtuous<br />

production system, undertaken<br />

entirely on Italian territory.<br />

It enters into a production chain<br />

that involves everyone,<br />

from the farmer to the composter,<br />

from the converter via the retailer<br />

to the consumer.<br />

USED FOR ALL TYPES<br />

OF WASTE DISPOSAL<br />

MATER-BI has unique,<br />

environmentally-friendly properties.<br />

It is biodegradable and compostable<br />

and contains renewable raw materials.<br />

It is the ideal solution for organic<br />

waste collection bags and is<br />

organically recycled into fertile<br />

compost.<br />

r8_03.<strong>2016</strong>

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