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Blow Moulding<br />

Bio-packaging of<br />

liquid dairy products<br />

Environmental, economic, safety and regulatory<br />

Definition of requirements and selection of materials<br />

Development of bottle packages<br />

for liquid dairy products<br />

Figure 1: BIOBOTTLE work scheme<br />

Reactive extrusion<br />

Validation at pilot plant scale<br />

Industrial scale up<br />

and product validation<br />

Figure 2: Negative search for pathogenic bacteria<br />

Development of pouches,<br />

lids and caps<br />

The aim of the BIOBOTTLE project is to develop new<br />

biodegradable materials suitable to obtain plastic bottles<br />

and pouches for dairy products; probiotics, fresh<br />

milk and shakes. These packages do not need to be separated<br />

of the rest of the organic waste at the end of their<br />

short shelf-life.<br />

The new packages keep the shelf-life of selected dairy<br />

products in comparison with traditional packages as well<br />

as fulfill different characteristics based on functional,<br />

microbiological, legal requirements for food contact<br />

applications in each case study.<br />

In addition, the new materials are suitable to be<br />

processed by traditional plastic processing methods, such<br />

as blown film coextrusion, extrusion blow moulding and<br />

injection moulding to obtain pouches, bottles and caps,<br />

respectively. The materials are completely biodegradable<br />

under controlled composting conditions (ISO 14885-1:2005)<br />

and are harmless after biodegradation according to the<br />

Compostability Standard, EN 13432.<br />

Market Data<br />

The worldwide output of plastics increases each year,<br />

but the management of plastic disposal has no satisfactory<br />

environmentally friendly solution at the moment because<br />

landfilling is still the first option in many countries [1].<br />

As a consequence of this problem, there has been an<br />

increased interest in using alternative materials such as<br />

biodegradable bioplastics.<br />

Nowadays, the European countries are the biggest<br />

consumer of milk products in the world, with an average<br />

of 219 kg per year (FAO, 2011). Therefore, the use of biomaterials<br />

to package dairy products is especially interesting<br />

for both dairy and plastic industries as well as for the endusers<br />

since the packages can be managed in composting<br />

conditions with the rest of the organic wastes.<br />

Requirements of bio-packages<br />

The requirements that the packages for dairy products<br />

must fulfil are shown in table 1.<br />

According to these requirements, one of the main<br />

difficulties overcame by the researches of the project, was<br />

the thermal limitations of the commercial biodegradable<br />

materials, which showed thermal resistances around<br />

65 ºC. The compounding process has been carried out using<br />

reactive extrusion technology, which lead to the development<br />

of different bio-compounds suitable to obtain the packages<br />

used in thermal treatments such as the sterilization or<br />

pasteurization processes that reach temperatures up to<br />

90 – 95 ºC. The bio-compounds are different PLA based biopolyesters<br />

with renewable content between 20 and 45 %.<br />

Figure 1 shows the development work in the BIOBOTTLE<br />

project.<br />

12 bioplastics MAGAZINE [<strong>04</strong>/16] Vol. 11

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