Issue 04/2016
bioplasticsMAGAZINE_1604
bioplasticsMAGAZINE_1604
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Blow Moulding<br />
Bio-packaging of<br />
liquid dairy products<br />
Environmental, economic, safety and regulatory<br />
Definition of requirements and selection of materials<br />
Development of bottle packages<br />
for liquid dairy products<br />
Figure 1: BIOBOTTLE work scheme<br />
Reactive extrusion<br />
Validation at pilot plant scale<br />
Industrial scale up<br />
and product validation<br />
Figure 2: Negative search for pathogenic bacteria<br />
Development of pouches,<br />
lids and caps<br />
The aim of the BIOBOTTLE project is to develop new<br />
biodegradable materials suitable to obtain plastic bottles<br />
and pouches for dairy products; probiotics, fresh<br />
milk and shakes. These packages do not need to be separated<br />
of the rest of the organic waste at the end of their<br />
short shelf-life.<br />
The new packages keep the shelf-life of selected dairy<br />
products in comparison with traditional packages as well<br />
as fulfill different characteristics based on functional,<br />
microbiological, legal requirements for food contact<br />
applications in each case study.<br />
In addition, the new materials are suitable to be<br />
processed by traditional plastic processing methods, such<br />
as blown film coextrusion, extrusion blow moulding and<br />
injection moulding to obtain pouches, bottles and caps,<br />
respectively. The materials are completely biodegradable<br />
under controlled composting conditions (ISO 14885-1:2005)<br />
and are harmless after biodegradation according to the<br />
Compostability Standard, EN 13432.<br />
Market Data<br />
The worldwide output of plastics increases each year,<br />
but the management of plastic disposal has no satisfactory<br />
environmentally friendly solution at the moment because<br />
landfilling is still the first option in many countries [1].<br />
As a consequence of this problem, there has been an<br />
increased interest in using alternative materials such as<br />
biodegradable bioplastics.<br />
Nowadays, the European countries are the biggest<br />
consumer of milk products in the world, with an average<br />
of 219 kg per year (FAO, 2011). Therefore, the use of biomaterials<br />
to package dairy products is especially interesting<br />
for both dairy and plastic industries as well as for the endusers<br />
since the packages can be managed in composting<br />
conditions with the rest of the organic wastes.<br />
Requirements of bio-packages<br />
The requirements that the packages for dairy products<br />
must fulfil are shown in table 1.<br />
According to these requirements, one of the main<br />
difficulties overcame by the researches of the project, was<br />
the thermal limitations of the commercial biodegradable<br />
materials, which showed thermal resistances around<br />
65 ºC. The compounding process has been carried out using<br />
reactive extrusion technology, which lead to the development<br />
of different bio-compounds suitable to obtain the packages<br />
used in thermal treatments such as the sterilization or<br />
pasteurization processes that reach temperatures up to<br />
90 – 95 ºC. The bio-compounds are different PLA based biopolyesters<br />
with renewable content between 20 and 45 %.<br />
Figure 1 shows the development work in the BIOBOTTLE<br />
project.<br />
12 bioplastics MAGAZINE [<strong>04</strong>/16] Vol. 11