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ioplastics MAGAZINE Vol. 12<br />

ISSN 1862-5258<br />

Nov/Dec<br />

<strong>06</strong> | <strong>2017</strong><br />

Highlights<br />

Films / Flexibles / Bags | 12<br />

Polyurethanes / Elastomers | 14<br />

Basics<br />

Blown Film Extrusion | 48<br />

ITALY / FRANCE-<br />

Special<br />

... is read in 92 countries


BIO-FLEX<br />

NEXT GENERATION<br />

✓ 40 % bio-based<br />

✓ Home compostable<br />

✓ Outstanding contact transparency<br />

✓ Meets the requirements of the<br />

French Energy Transmission Law


Editorial<br />

dear<br />

readers<br />

Films, Flexibles, Bags is traditionally the first highlight topic of every December issue of<br />

bioplastics MAGAZINE. While it is one that, in the past, has always proven to be among the<br />

most popular, this year apparently there was surprisingly little news to report. Fortunately,<br />

this was more than made up for by the unexpected outpour of<br />

contributions we received on the topic Polyurethanes/Elastomers<br />

and related building blocks, which will bring our readers up to date<br />

on the latest developments in this area.<br />

Then, for those of you, who missed it… On page 10 we present this<br />

year’s winner of the Global Bioplastics Award.<br />

As always, we’ve rounded up some of the most recent news<br />

items on materials and applications to keep you abreast of the<br />

latest innovations and ongoing advances in the world of bioplastics.<br />

Lastly, I’d like to remind you of the 5th PLA World Congress in<br />

Munich/Germany next May – the call for papers is still open. If<br />

you have an interesting topic to report on, please let us know. The<br />

same goes for the first PHA platform World Congress in Cologne/<br />

Germany next September.<br />

Let me take this opportunity to wish you all a relaxing time<br />

over the holidays as this year comes to an end. Together with<br />

you, our readers, we look forward with confidence to a new year<br />

of challenges, innovations - and events. On our calendar, we’ve already marked<br />

down Chinaplas, taking place next year at a new location in Shanghai, NPE in Orlando,<br />

NatureWorks’ ITR in September and a host of other conferences. We’ll be covering these<br />

events, and more - and we hope to see you there, too.<br />

EcoComunicazione.it<br />

WWW.MATERBI.COM COME TO VISIT US AT<br />

28 • 29 november <strong>2017</strong><br />

MARITIM PROARTE HOTEL • BERLIN<br />

adv mela se tore_bioplasticmagazine_11.12.<strong>2017</strong>_210x297_flagEBC_ese.indd 1 03/11/17 15:22<br />

r2_11.<strong>2017</strong><br />

bioplastics MAGAZINE Vol. 12<br />

ISSN 1862-5258<br />

... is read in 92 countries<br />

Nov/Dec<br />

<strong>06</strong> | <strong>2017</strong><br />

Highlights<br />

Films / Flexibles / Bags | 12<br />

Polyurethanes / Elastomers | 14<br />

Basics<br />

Blown Film Extrusion | 48<br />

ITALY / FRANCE-<br />

Special<br />

Until then, please enjoy reading this latest issue of bioplastics MAGAZINE.<br />

Sincerely yours<br />

Michael Thielen<br />

In this issue we have a closer<br />

look to France and Italy. .<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 3


Content<br />

Imprint<br />

Nov / Dec <strong>06</strong>|<strong>2017</strong><br />

Bioplastic Award<br />

10 And the winner is ...<br />

Films/Flexibles/Bags<br />

12 Compostable film resins from Malaysia<br />

13 Mulch films and more<br />

Polyurethanes/Elastomers<br />

14 Biobased EP(D)M<br />

16 Renewable Polyols<br />

17 Congratulations - 10 years soy foam in Ford cars<br />

18 Biobased thermoplastic elastomer compounds<br />

20 Bio-succinic acid<br />

23 New biobased lactide polyol polyesters<br />

24 Injection molders who have made bioplastics work<br />

26 Sugar for extra grip<br />

Processing<br />

27 Optimize Processability<br />

Materials<br />

30 Biobased adhesives<br />

From Science & Research<br />

34 PEF: an alternative with a future<br />

36 Aconitic acid as a building block for bioplastics<br />

36 Flexible barrier film<br />

37 From municipal waste to bioplastics<br />

Applications<br />

44 Hot compost bin<br />

45 Race Tesla with bio-composites<br />

Report<br />

46 Product communication<br />

50 Situation in France<br />

3 Editorial<br />

5 News<br />

28 Material News<br />

37 Application News<br />

48 Basics<br />

52 Opinion<br />

55 Brand Owner<br />

56 10 years ago<br />

57 Survey<br />

58 Suppliers Guide<br />

61 Event Calendar<br />

52 Companies in this issue<br />

Publisher / Editorial<br />

Dr. Michael Thielen (MT)<br />

Samuel Brangenberg (SB)<br />

Head Office<br />

Polymedia Publisher GmbH<br />

Dammer Str. 112<br />

41<strong>06</strong>6 Mönchengladbach, Germany<br />

phone: +49 (0)2161 6884469<br />

fax: +49 (0)2161 6884468<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Media Adviser<br />

Samsales (German language)<br />

phone: +49(0)2161-6884467<br />

fax: +49(0)2161 6884468<br />

s.brangenberg@samsales.de<br />

Chris Shaw (English language)<br />

Chris Shaw Media Ltd<br />

Media Sales Representative<br />

phone: +44 (0) 1270 522130<br />

mobile: +44 (0) 7983 967471<br />

and Michael Thielen (see head office)<br />

Layout/Production<br />

Kerstin Neumeister<br />

Print<br />

Poligrāfijas grupa Mūkusala Ltd.<br />

1004 Riga, Latvia<br />

bioplastics MAGAZINE is printed on<br />

chlorine-free FSC certified paper.<br />

Print run: 3.500 copies<br />

bioplastics magazine<br />

ISSN 1862-5258<br />

bM is published 6 times a year.<br />

This publication is sent to qualified subscribers<br />

(149 Euro for 6 issues).<br />

From Jan 2018 on: EUR 169 for 6 issues<br />

bioplastics MAGAZINE is read in<br />

92 countries.<br />

Every effort is made to verify all Information<br />

published, but Polymedia Publisher<br />

cannot accept responsibility for any errors<br />

or omissions or for any losses that may<br />

arise as a result.<br />

All articles appearing in<br />

bioplastics MAGAZINE, or on the website<br />

www.bioplasticsmagazine.com are strictly<br />

covered by copyright. No part of this<br />

publication may be reproduced, copied,<br />

scanned, photographed and/or stored<br />

in any form, including electronic format,<br />

without the prior consent of the publisher.<br />

Opinions expressed in articles do not<br />

necessarily reflect those of Polymedia<br />

Publisher.<br />

bioplastics MAGAZINE welcomes contributions<br />

for publication. Submissions are<br />

accepted on the basis of full assignment<br />

of copyright to Polymedia Publisher GmbH<br />

unless otherwise agreed in advance and in<br />

writing. We reserve the right to edit items<br />

for reasons of space, clarity or legality.<br />

Please contact the editorial office via mt@<br />

bioplasticsmagazine.com.<br />

The fact that product names may not be<br />

identified in our editorial as trade marks<br />

is not an indication that such names are<br />

not registered trade marks.<br />

bioplastics MAGAZINE tries to use British<br />

spelling. However, in articles based on<br />

information from the USA, American<br />

spelling may also be used.<br />

Envelopes<br />

A part of this print run is mailed to the<br />

readers wrapped in bioplastic envelopes<br />

sponsored by Taghleef Industries, S.p.A.,<br />

Maropack GmbH & Co. KG, and SFV-<br />

Verpackungen<br />

Cover<br />

shutterstock / Michaelpuche<br />

Follow us on twitter:<br />

http://twitter.com/bioplasticsmag<br />

Like us on Facebook:<br />

https://www.facebook.com/bioplasticsmagazine


daily upated news at<br />

www.bioplasticsmagazine.com<br />

News<br />

Ellen MacArthur Foundation issues call to ban<br />

oxo-degradable plastic packaging<br />

A new statement from the Ellen MacArthur foundation<br />

that proposes banning oxo-degradable plastic packaging<br />

worldwide was endorsed by over 150 organisations around<br />

the globe. Signatories include leading businesses, industry<br />

associations, NGOs, scientists, and elected officials.<br />

Oxo-degradable plastic packaging, including carrier<br />

bags, is often marketed as a solution to plastic pollution,<br />

with claims that such plastics degrade into harmless<br />

residues within a period ranging from a few months to<br />

several years. However, as outlined in a new statement<br />

by the Ellen MacArthur Foundation’s New Plastics<br />

Economy initiative, significant evidence indicates that<br />

oxo-degradable plastics do not degrade into harmless<br />

residues, but instead fragment into tiny pieces of plastic<br />

and contribute to microplastic pollution, posing a risk to<br />

the ocean and other ecosystems, potentially for decades<br />

to come.<br />

“The available evidence overwhelmingly suggests oxodegradable<br />

plastics do not achieve what their producers<br />

claim and instead contribute to microplastic pollution. In<br />

addition, these materials are not suited for effective longterm<br />

reuse, recycling at scale or composting, meaning they<br />

cannot be part of a circular economy,” said Rob Opsomer,<br />

Lead for Systemic Initiatives at the Ellen MacArthur<br />

Foundation. In other words: “Oxo-degradable plastic<br />

packaging is not a solution to plastic pollution, and does<br />

not fit in a circular economy.”<br />

Signatories of the Foundation’s statement include M&S,<br />

PepsiCo, Unilever, Veolia, British Plastics Federation, Gulf<br />

Petrochemicals and Chemicals Association, Packaging<br />

South Africa, World Wildlife Fund (WWF), Plymouth Marine<br />

Laboratory, and ten Members of the European Parliament.<br />

In total, over 150 organisations, including leading<br />

businesses representing every step of the plastics supply<br />

chain, industry associations, NGOs, scientists, and elected<br />

officials have endorsed the statement calling for global<br />

action to avoid widescale environmental risk.<br />

“Using oxo-degradable additives is not a solution<br />

for litter. Their use in waste management systems will<br />

likely cause negative outcomes for the environment and<br />

communities,” said Erin Simon, Director of Sustainability<br />

Research and Development, World Wildlife Fund. “When<br />

public policy supports the cascading use of materials –<br />

systems where materials get reused over and over, this<br />

strengthens economies and drives the development of<br />

smarter materials management systems. This leads to<br />

wins for both the environment and society.”<br />

However, oxo-degradable plastics are still produced in<br />

many European countries, including the UK, and marketed<br />

across the world as safely biodegradable. Several countries<br />

in the Middle-East and Africa, including the United Arab<br />

Emirates, Saudi Arabia, areas of Pakistan, Yemen, Ivory<br />

Coast, South Africa, Ghana and Togo, are still promoting<br />

the use of oxo-degradable plastics or have even made their<br />

use mandatory.<br />

To create a plastics system that works, the Ellen<br />

MacArthur Foundation’s New Plastics Economy initiative,<br />

together with the signing organisations, supports<br />

innovation that designs out waste and pollution, and keeps<br />

products and materials in high-value use in line with the<br />

principles of a circular economy MT<br />

The complete statement can be downloaded from<br />

tinyurl.com/ban-oxodegr<br />

Bio-on completes construction of the world's<br />

largest PHA fermenters<br />

Bio-on (Bologna, Italy), one of the main players in the new eco-sustainable chemical industry, recently announced the<br />

completion of the fermenters that are at the heart of the production technology for 100% biodegradable and natural bioplastic<br />

at the Bio-on plant set to open next year. This big technological challenge has enabled the world's largest fermenters to be<br />

built with a capacity of over 100 thousand litres and a height of over 13 metres. These large silos will house the fermentation<br />

process in which bacteria produce PHA bioplastics.<br />

The new fermenters have been designed by Bio-on's technical staff (ENG Business Unit) in collaboration with RAF, the inhouse<br />

team of scientists that developed the various stages of aerobic fermentation over the last 4 years. The two fermenters,<br />

which have just been delivered, will be transported and installed at the Bio-on Plants site in Castel San Pietro Terme, Bologna<br />

and will contribute towards the upcoming production of biopolymers for cosmetic use. MT<br />

www.bio-on.it<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 5


News<br />

daily upated news at<br />

www.bioplasticsmagazine.com<br />

European Parliament supports use of<br />

biodegradable mulch films<br />

On October 24, <strong>2017</strong>, the Plenary of the European Parliament<br />

voted in favour of supporting biodegradable mulch films in the<br />

revision of the EU Fertilizers Regulation. European Bioplastics<br />

(EUBP), the association for the bioplastics industry in Europe,<br />

welcomes the outcome. “The inclusion of biodegradable<br />

mulches in the EU Fertilizers Regulation will help to harmonise<br />

regulations across the EU Member States and to create a<br />

single market for bio-based and biodegradable materials used<br />

in agriculture”, says François de Bie, Chairman of EUBP.<br />

The amendments, which have already been approved by the<br />

Parliament’s Committees on Internal Market and Consumer<br />

Protection (IMCO), on Agriculture and Rural Development<br />

(AGRI), and on the Environment, Public Health and Food<br />

Safety (ENVI) in July earlier this year, acknowledge the innovative potential of biodegradable mulch films to provide positive<br />

agronomical effects and to help avoid the accumulation of microplastics on fields. Biodegradable mulch films have been<br />

available on the EU market for many years, meeting a high level of acceptance among European farmers. They play an essential<br />

role in modern agriculture as help to increase yield, improve the quality of crops, enhance weed control, and reduce water<br />

irrigation and pesticides. Additionally, they offer distinctive advantages at the end of the crop cycle as they can be left on the<br />

field and ploughed under.<br />

The approved amendments on biodegradable mulch films are linked to the criteria of the upcoming European standard CEN<br />

FprEN 17033 on biodegradation of plastic mulch films in soil developed by CEN-Technical Committee 249 on Plastics. The<br />

standard is expected to be published at the beginning of 2018. MT<br />

www.european-bioplastics.org<br />

BPI taps DIN CERTCO<br />

for third-party compostability verification<br />

The Biodegradable Products Institute (BPI)’s Board of Directors recently announced that DIN CERTCO has been hired for the<br />

administration of technical reviews under the BPI certification program, effective December 1, <strong>2017</strong>.<br />

BPI (New York, USA) operates North America’s leading certification for compostable products, with over 6,500 products<br />

currently approved based on ASTM’s scientific standards. DIN CERTCO (Berlin, Germany) has more than 2 decades of<br />

experience administering compostability certification for groups such as European Bioplastics Association and Australasia<br />

Bioplastics, as well as its own certifications.<br />

Certification for compostable products is critical for ensuring that items have been properly tested, meet international<br />

standards, and can be identified as such by composters, municipalities, restaurants, consumers, and others engaged in the<br />

diversion of organic waste. US-states like California and Maryland have laws requiring any product marketed as compostable<br />

to meet these standards, and BPI certification is widely acknowledged as the best means of doing so.<br />

“We are excited to partner with DIN CERTCO for this next phase of our certification program, as they<br />

are a recognized leader in the compostability field,” says Rhodes Yepsen, Executive Director of BPI. “This<br />

will not change the appearance of the BPI certification to those who trust and rely on it. However, offices<br />

in China and Taiwan will assist with the growing number of companies located overseas, and technical<br />

expertise will ensure continued strength in compostability claims for products and packaging that are<br />

increasingly complex in nature.”<br />

“This is an excellent opportunity for BPI and DIN CERTCO to provide our<br />

customers the best service possible. We are convinced that we are able to<br />

provide a value added service with our experts, since we have been active in the<br />

field of industrial compostable products for more than 20 years.” adds Robert<br />

Zorn, Managing Director of DIN CERTCO. “Together with BPI we will be able to<br />

provide customers a one-stop solution to access several markets in one go.” MT<br />

www.bpiworld.org | www.dincertco.de/en<br />

6 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


News<br />

Braskem and Haldor Topsoe partner to develop<br />

biobased MEG<br />

Braskem (São Paulo, Brazil) and Haldor Topsoe (Lyngby,<br />

Denmark) have signed a technological cooperation agreement<br />

to develop a pioneering route to produce monoethylene glycol<br />

(MEG) from sugar. The agreement calls for the construction<br />

of a demonstration plant in Denmark, with operation slated<br />

to begin in 2019.<br />

MEG is a key component of e.g. PET resin. The project is<br />

based on a two-step process developed at Topsoe’s labs along<br />

with own catalysts, and focuses on the conversion of sugar<br />

into MEG at a single industrial unit, which will reduce initial<br />

investment in the production and boost the competitiveness<br />

of the process.<br />

“This novel biobased initiative allies a cutting-edge<br />

technology with deep expertise in process design, scaleup<br />

and industrial operation, which will allow us to push the<br />

renewable chemistry to a whole new level. After the Green<br />

Polyethylene, this is another major step forward in our<br />

vision of using renewable polymers as a carbon capture tool<br />

and keep contributing to a more sustainable future.” said<br />

Mateus Lopes, head of Innovation in Renewable Chemicals at<br />

Braskem.<br />

With the agreement, Braskem wants to expand its<br />

portfolio of renewable products to offer new solutions that<br />

complement its biobased polyethylene marketed with the<br />

I’m green TM seal. “With this new partnership, we strengthen<br />

our position as protagonists in the development of innovative<br />

solutions that will leverage the competitiveness of different<br />

biomasses and complement the traditional solutions offered<br />

by the petrochemical industry,” said Gustavo Sergi, director of<br />

Renewable Chemicals at Braskem.<br />

“Catalysis will play an extremely important role in the<br />

development of sustainable solutions that produce important<br />

chemicals from renewable sources such as sugars. We are<br />

proud to deliver the ground-breaking technology for the<br />

project with Braskem, and we look forward to applying our<br />

world-leading competencies within catalysis and process<br />

engineering in the further commercialization of this important<br />

technology,” said Kim Knudsen, Executive Vice President at<br />

Haldor Topsoe.<br />

The demonstration plant will conduct tests to validate the<br />

technology and confirm its technical and economic feasibility,<br />

which is a critical step before launching production on an<br />

industrial scale and commercial operations. The unit will be<br />

flexible to validate the technology in different raw materials<br />

such as sucrose, dextrose and second-generation sugars. MT<br />

www.braskem.com.br | www.topsoe.com<br />

biocompositescc.com<br />

Sustainable eyeware solutions<br />

API (Mussolente, Italy) an Italian company that specializes<br />

in the production of thermoplastic elastomeric compounds<br />

and bioplastics that was acquired by global materials<br />

company Trinseo (headquartered in Berwyn, Pennsylvania,<br />

USA) in July <strong>2017</strong>, has announced a green partnership<br />

with EMS-GRIVORY (Domat/Ems, Switzerland), a leading<br />

Swiss manufacturer of high performance polymers and<br />

supplier of structural materials in the eyewear industry.<br />

The partnership aims at developing a series of sustainable<br />

eyewear solutions with a lower environmental impact,<br />

providing customers with cutting-edge materials.<br />

The demand to combine soft elastomeric compounds with<br />

hard substrates has been constantly increasing. Engineers<br />

from both companies will collaborate on combining<br />

the adhesion modified soft-touch TPE (Thermoplastic<br />

Elastomers) with the harder Ems Grilamid TR ® or Grilamid ®<br />

BTR materials, thereby fully complying with the VDI 2019<br />

standard. API and Ems-Grivory will work on the development<br />

of specific bio-solutions, both on a fossil and renewable basis.<br />

“We are excited to partner with Ems-Grivory as we focus<br />

our combined expertise serving a broader and greener<br />

product range,” says Giancarlo Busa, Business Unit Manager,<br />

Footwear & Sporting Goods, API. “Our materials will satisfy<br />

social, economic and environmental benefits, without<br />

imposing performance limitations. We strongly believe in the<br />

future of innovative and sustainable solutions for eyewear.”<br />

Ems-Grivory showcased<br />

their eyewear products<br />

at the 25 th HKTDC<br />

Hong Kong Optical Fair<br />

(8‐10 November <strong>2017</strong>).<br />

www.APIplastic.com<br />

www.trinseo.com/API-plastic<br />

www.emsgrivory.com<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 7


News<br />

daily upated news at<br />

www.bioplasticsmagazine.com<br />

Erratum<br />

In our last issue we published an article about Cathay<br />

Biotech: "Advances in textile applications for biobased<br />

polyamide". However we made a mistake in the title of<br />

Fig 3.<br />

We sincerely apologize. Please find the correct picture<br />

below. MT<br />

25 —<br />

20 —<br />

15 —<br />

10 —<br />

5 —<br />

0 —<br />

0 2 3 4 8<br />

Terryl<br />

www.cathaybiotech.com/en<br />

K/S<br />

PA6<br />

PA66<br />

Figure 3: Terryl uses less dye to achieve<br />

the same dyeing performance<br />

New PHA plant<br />

Hydal Corporation (headquartered in Singapore) will<br />

start the production of a PHA biopolymer (PHB) in Slovakia<br />

on the site of its Slovak partner. It is the first industrial plant<br />

for production of this biopolymer. Hydal biotechnology<br />

enables the production from used cooking oil.<br />

The production capacity of the factory in the first phase<br />

will be 1.000 tonnes with up-scaling up to 10.000 tonnes<br />

of PHB per year. Production will begin at the end of 2018.<br />

PHB will be used to develop and manufacture their own<br />

nonoilen bioplastic solution and for cosmetic applications.<br />

The Hydal Corporation was founded by two EU partners:<br />

NAFIGATE Corporation – owner of biopolymer PHA<br />

production technology know-how and Panara Ltd. – owner<br />

of biopolymer blends process technology know-how.<br />

Contribution of both companies in the form of patented,<br />

unique industrial know-how gives Hydal Corporation<br />

very big potential to succeed in the worldwide market<br />

expansion.<br />

Besides technology know-how, both partners are<br />

experts in the area of bio-technologies and bio-plastics<br />

processing. Both founders have strong R&D base and<br />

technical support which increases the potential of<br />

successful investments into project in each phase of its<br />

realization.<br />

www.hydalbiotech.com<br />

Picks & clicks<br />

Most frequently clicked news<br />

Here’s a look at our most popular online content of<br />

the past two months. The story that got the most clicks<br />

from the visitors to bioplasticsmagazine.com was:<br />

New Studies Confirm: Biodegradable<br />

Plastics Boost Organic Recycling and<br />

Improve Mechanical Recycling (17 Oct <strong>2017</strong>)<br />

Biodegradable plastics offer innovative solutions to<br />

improve recycling quality by facilitating the means for<br />

more efficient separate waste collection.<br />

more at tinyurl.com/news-<strong>2017</strong>1017<br />

This has been<br />

confirmed by a new<br />

study concerning<br />

the effects of<br />

biodegradable plastics<br />

on plastics recycling<br />

streams in Italy,<br />

where all single-use<br />

carrier bags have to<br />

be compostable since<br />

2011....<br />

Online toolbox for easier<br />

biobased procurement<br />

The European project InnProBio has launched an online<br />

toolbox for biobased procurement in the public sector.<br />

The toolbox includes an online database of biobased<br />

products and suppliers, good practice examples,<br />

procurement instruments and standard tender text blocks.<br />

The toolbox is available in English, German, Dutch and Polish.<br />

The toolbox is a starting point for public buyers to get<br />

informed about the various biobased products available on<br />

the market. It includes a database of products and suppliers<br />

of biobased products. Information about the biobased<br />

content, sustainability, functionality and end-of-life aspects<br />

such as biodegradability are also included. Claims are<br />

supported by references to standards, technical sheets,<br />

labels and certificates. Producers and suppliers of biobased<br />

products are invited to add their products to the database.<br />

In addition, the toolbox provides instruments that can<br />

support the procurement of biobased products: good<br />

practice examples showing how biobased procurement<br />

is successfully implemented in practice, information<br />

on procurement instruments most relevant in biobased<br />

procurement, and sample tender text blocks that can be<br />

used when putting together tender documents.<br />

http://tools.innprobio.eu<br />

8 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


organized by<br />

5 th PLA World Congress<br />

29-30 MAY* 2018 MUNICH › GERMANY<br />

is a versatile bioplastics raw<br />

PLA material from renewable resources.<br />

It is being used for films and rigid packaging,<br />

for fibres in woven and non-woven applications.<br />

Automotive industry and consumer electronics<br />

are thoroughly investigating and even already<br />

applying PLA. New methods of polymerizing,<br />

compounding or blending of PLA have broadened<br />

the range of properties and thus the range<br />

of possible applications.<br />

That‘s why bioplastics MAGAZINE is now<br />

organizing the 5 th PLA World Congress on:<br />

29-30 May* 2018 in Munich / Germany<br />

Experts from all involved fields will share their<br />

knowledge and contribute to a comprehensive<br />

overview of today‘s opportunities and challenges<br />

and discuss the possibilities, limitations<br />

and future prospects of PLA for all kind of<br />

applications. Like the four previous congresses<br />

the 5 th PLA World Congress will also offer<br />

excellent networking opportunities for all<br />

delegates and speakers as well as exhibitors<br />

of the table-top exhibition.<br />

The team of bioplastics MAGAZINE is looking<br />

forward to seeing you in Munich.<br />

The conference will comprise high class presentations on<br />

› Latest developments<br />

› Market overview<br />

call for papers still open<br />

› High temperature behaviour<br />

› Blends and comounds<br />

› Additives / Colorants<br />

› Applications (film and rigid packaging, textile,<br />

automotive,electronics, toys, and many more)<br />

Sponsor:<br />

Contact us at: mt@bioplasticsmagazine.com<br />

for exhibition and sponsoring opportunities<br />

www.pla-world-congress.com<br />

* date subject to changes<br />

› Fibers, fabrics, textiles, nonwovens<br />

› Reinforcements<br />

› End of life options<br />

(recycling,composting, incineration etc)<br />

Supported by:<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 9


Award<br />

And the winner is ...<br />

The 12 th Global Bioplastics Award <strong>2017</strong> goes<br />

to MAIP Srl for a newly developed PHBH-<br />

Compound for ABB Light switch covers<br />

I<br />

am NATURE is a special PHBH based compound, available<br />

in tailor made grades and suitable for high temperature<br />

applications. It offers a sustainable solution preserving the<br />

technical properties of a traditional thermoplastic material.<br />

Maip has developed different bioplastics that are sold under<br />

the name of I am NATURE for several years. These PHBH<br />

based grades are compounded with mineral fillers, with<br />

water-repellent properties, natural fillers, natural based<br />

colours and additives of vegetal origin as well as functional<br />

components for specific requirements. The PHBH can also<br />

be blended with other biobased products such as PLA or<br />

with other biodegradable materials such as PBS, PBSA,<br />

PBAT, and others.<br />

For a new series of switch cover frames that should<br />

have an advanced design and a remarkable environment<br />

sustainability connotation, ABB was looking for a bioplastic<br />

material that could replace technopolymers such as ABS or<br />

PC/ ABS. In a joint development ABB and Maip succeeded<br />

in creating a special I am NATURE grade that is suitable to<br />

satisfy all the multiple requirements of the component. The<br />

new compound exhibits particular properties such as high<br />

dimensional stability, thermal resistance (about 130 °C),<br />

superior UV and light resistance, easy colourability and easy<br />

mouldability in multi cavity moulds. Easy processability and<br />

specific electric features such as for example a glow wire of<br />

650 °C at 2 mm.<br />

The most severe test of all, the scratch resistance, led to<br />

the development of special grades that show surprising mar<br />

/ scratch resistance values also in case of matte textures.<br />

The main properties that were achieved, allow the definition<br />

of the new I am NATURE as an actual Bio-Technopolymer<br />

that also allows to eliminate the painting (because of its<br />

good mass colourability) dramatically reducing the carbon<br />

footprint of the component. The switch covers were officially<br />

introduced to the market in Europe in September <strong>2017</strong>.<br />

The judges were convinced of the concept. The<br />

application of the ABB light switch covers shows that the<br />

right combination of Polyhydroxyalkanoate polymers with<br />

other naturally based ingredients can lead to sophisticated<br />

applications.<br />

The prize was awarded to the winning company on<br />

November 28 th , <strong>2017</strong> during the 12 th European Bioplastics<br />

Conference in Berlin, Germany. MT<br />

www.maipsrl.com<br />

10 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


call for papers now open!<br />

Save the Date<br />

04-05 Sep 2018<br />

Cologne, Germany<br />

www.pha-world-congress.com<br />

PHA (Poly-Hydroxy-Alkanoates or polyhydroxy fatty acids) is a family of biobased polyesters. As in many<br />

mammals, including humans, that hold energy reserves in the form of body fat there are also bacteria that<br />

hold intracellular reserves of polyhydroxy alkanoates. Here the micro-organisms store a particularly high level<br />

of energy reserves (up to 80% of their own body weight) for when their sources of nutrition become scarce.<br />

Examples for such Polyhydroxyalkanoates are PHB, PHV, PHBV, PHBH and many more. That’s why we speak<br />

about the PHA platform.<br />

This PHA-platform is made up of a large variety of bioplastics raw materials made from many different renewable<br />

resources. Depending on the type of PHA, they can be used for applications in films and rigid packaging,<br />

biomedical applications, automotive, consumer electronics, appliances, toys, glues, adhesives, paints, coatings,<br />

fibers for woven and non-woven and inks. So PHAs cover a broad range of properties and applications.<br />

That’s why bioplastics MAGAZINE and Jan Ravenstijn are now organizing the 1 st PHA-platform World Congress<br />

on 4-5 September 2018 in Cologne / Germany.<br />

This congress will address the progress, challenges and market opportunities for the formation of this new polymer<br />

platform in the world. Every step in the value chain will be addressed. Raw materials, polymer manufacturing,<br />

compounding, polymer processing, applications, opportunities and end-of-life options will be discussed by parties<br />

active in each of these areas. Progress in underlying technology challenges will also be addressed.<br />

Platinum Sponsor:<br />

Gold Sponsor:<br />

organized by<br />

Co-organized by Jan Ravenstijn


Films/Flexibles/Bags<br />

Mulch films<br />

and more<br />

Barbier Group Bioplastic films<br />

Barbier Group is a French family-owned company founded<br />

in 1955 and headquartered in Sainte-Sigolène near Lyon,<br />

Barbier extrudes, prints and recycles polyethylene films.<br />

Its activity focuses on three complementary markets: agriculture<br />

films, industrial packaging films and retailing (mainly garbage<br />

and carrier bags).<br />

National leader and in the top 10 producers of flexible<br />

polyethylene film in Europe, Barbier Group has always been<br />

committed to environmental issues. Indeed, in the 1980s, Barbier<br />

Group invested in a recycling plant in order to stop throwing<br />

away plastic waste. Initially focusing on post-production waste,<br />

this plant then began recycling post use plastic film as well. This<br />

marked the end of a linear model (manufacture, sell, discard)<br />

and the beginning of a circular economy (manufacture, sell,<br />

collect, recycle, manufacture …). This commitment to recycling<br />

activities carried on with the construction of a second recycling<br />

plant in 2015.<br />

In the 1990s, when the first biodegradable raw materials<br />

for flexible film applications became available on the market,<br />

Barbier Group decided to launch R&D projects aiming to develop<br />

biodegradable film. From the beginning, Barbier’s approach was<br />

the following: to use biodegradable raw materials only when they<br />

offered real benefits both for end-users and for the environment.<br />

Indeed biodegradability is only an additional function for a<br />

product and has to be promoted only when it represents the best<br />

option for product end of life. Too often biodegradability has been<br />

used primarily for marketing reasons. That is why Barbier Group<br />

works closely with its clients to understand their needs and how<br />

the product is used:<br />

• When plastic film is easy to collect and not too soiled, a<br />

recyclable product is advised<br />

• When plastic film is hard to collect and very soiled, a<br />

biodegradable product is advised<br />

The product life cycle is therefore thought of since its<br />

conception.<br />

In 2000, Barbier Group introduced its first biodegradable<br />

product into the market: a biodegradable mulching film (Bionov ® ).<br />

Standard mulching films (films made with polyethylene resins)<br />

are laid every year by farmers and should be removed after use<br />

because they are not biodegradable. This is very time consuming<br />

for them and it is difficult to recycle these soiled films. Thus<br />

bioplastic is really the right solution: there is no need to remove<br />

the plastic film and no ground pollution.<br />

To meet the requirements of the new Energy Transition for<br />

Green Growth Act (France) and also to meet the growing demand<br />

for eco-friendly bags, Barbier Group in collaboration with<br />

Novamont (a leading European producer of compostable and<br />

biosourced resins) developed a wholly compostable bag for home<br />

composting: Ma-ter-bio ® . This bag is an alternative to traditional<br />

non-biodegradable and non-compostable plastics packaging:<br />

Ma-ter-bio’s percentage of renewable content (obtained from<br />

locally sourced starch and sunflower oil), is at least 40 %, but<br />

can already be increased to over 50 %. This product reflects the<br />

commitment of Barbier to the circular economy and to a clean<br />

and environmentally friendly industry.<br />

In response to the same requirement, Barbier Group also<br />

developed a biodegradable home compostable mailing film.<br />

In <strong>2017</strong>, and for the first time in Barbier Group’s history,<br />

biodegradable products will represent around 5 % of the<br />

company’s total production volume and the target is 8 % in<br />

the near future. www.babiergroup.com<br />

Magnetic<br />

for Plastics<br />

www.plasticker.com<br />

• International Trade<br />

in Raw Materials, Machinery & Products Free of Charge.<br />

• Daily News<br />

from the Industrial Sector and the Plastics Markets.<br />

• Current Market Prices<br />

for Plastics.<br />

• Buyer’s Guide<br />

for Plastics & Additives, Machinery & Equipment, Subcontractors<br />

and Services.<br />

• Job Market<br />

for Specialists and Executive Staff in the Plastics Industry.<br />

Up-to-date • Fast • Professional<br />

12 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


Films/Flexibles/Bags<br />

Sustainable and eco-friendly bioplastics developer<br />

SECOS Group Limited (headquartered in Mt<br />

Waverley Victoria, Australia) recently announced<br />

its successful Malaysian operations will expand to<br />

commence manufacturing compostable resin in the<br />

first quarter of 2018.<br />

This supports Secos’ international growth strategy<br />

and follows ongoing business development at the<br />

Company’s production facility at Port Klang near Kuala<br />

Lumpur. Secos’ new strategic business unit will be<br />

named Cardia Bioplastics (Malaysia) Sdn Bhd and will<br />

operate under the Stellar Films (Malaysia) Sdn Bhd<br />

business the Company acquired in April 2015.<br />

The company’s establishment of a resin manufacturing<br />

facility furthers the strong green initiatives set by the<br />

Malaysian Government and encourages sustainable<br />

manufacturing. This move represents the outcome of<br />

18 months of government negotiations, dialogue with<br />

the Malaysian Plastics Association, and discussions<br />

with key players in the local film and bag industry.<br />

These green initiatives have culminated in the<br />

Malaysian Government awarding the new strategic<br />

business unit with Bionexus status. This recognition<br />

bestows fiscal incentives, grants and other guarantees<br />

to assist growth. Only certain qualified companies<br />

undertaking value-added biotechnology and/or life<br />

sciences activities qualify for Bionexus status.<br />

The business unit will commence operations having<br />

made strong sales of compostable resin (in excess of 35<br />

tonnes) to large-scale bag manufacturers in Malaysia.<br />

These initial sales have followed successful production<br />

trials, using resin Secos manufactured at its Nanjing,<br />

China plant.<br />

Secos Managing Director, Stephen Walters, said:<br />

“With single-use plastic bags having become a<br />

global ecological issue, we applaud the Malaysian<br />

Government for showing leadership and making a<br />

strong commitment to bioplastics. Establishing a<br />

new compostable resin plant in Malaysia will set the<br />

Company as a leader in the Malaysian bioplastics<br />

industry and provide Secos with a significant growth<br />

opportunity.<br />

The new plant will work closely with local film and<br />

bag producers to produce and market bioplastic resins<br />

that suit the needs of the large Malaysian bag market.<br />

The Malaysian plastics industry is estimated to be worth<br />

more than 5 billion EURO (A$8 bn) and is growing at 5 %<br />

to 8 % per annum, with a large percentage of this growth<br />

coming in the bioplastics sector. The Company expects<br />

to reap the benefit of additional synergies through its<br />

Stellar Films Malaysia business accelerating its use<br />

of bioplastics in products for the hygiene market. The<br />

Company is increasingly offering products with higher<br />

blends of biohybrid resin that decrease the use of oilbased<br />

plastics in baby diapers and feminine hygiene<br />

products.<br />

This initiative will strengthen Secos’ relationship with<br />

its customers as it opens the potential for innovative<br />

new products and guarantees continuity of supply.” MT<br />

www.secosgroup.com.au<br />

Compostable<br />

film resins<br />

from Malaysia<br />

Malaysian plant upgrade to meet<br />

demand for compostable resin<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 13


Polyurethanes / Elastomers<br />

Biobased EP(D)M<br />

Focus on sustainability<br />

ARLANXEO Netherlands has made a pioneering move<br />

towards exploring a future based on renewable resources,<br />

by developing the world’s first biobased<br />

EP(D)M elastomers commercialized under the tradename<br />

Keltan ® Eco.<br />

Keltan Eco is produced from biobased ethylene supplied<br />

by Braskem which originates from sugar cane (Figure 1).<br />

The sugar from sugar cane is converted to ethanol, which is<br />

then dehydrated to ethylene by Braskem in their Brazilian<br />

Triunfo plant. This biobased ethylene is transported via a<br />

pipeline to the neighboring Arlanxeo EP(D)M polymerization<br />

plant. Depending on the ethylene content of the particular<br />

grade, the bio-carbon content of Keltan Eco elastomer<br />

ranges between 48 and 70 wt-%.<br />

Translating this to final rubber articles produced from<br />

EP(D)M compounds, a bio-carbon content of 15-20 wt-%<br />

can be achieved, if Keltan Eco is the only biobased ingredient<br />

of the compound (Figure 1).<br />

Keltan Eco gives the following benefits:<br />

• reduced dependence on fossil resources;<br />

• reduced carbon footprint due to use of sugar cane;<br />

• truly sustainable as validated by a Life Cycle Assessment<br />

performed by Thinkstep;<br />

• biobased content up to 70% measured and traced back<br />

by ASTM D6866 carbon-14 test performed by Beta<br />

Analytic.<br />

Figure 2 shows the Global Warming Potential of Keltan<br />

Eco. Depending on ethylene content the EP(D)M carbon<br />

footprint is reduced up to 82 % for Keltan Eco 5470 (70<br />

wt-% biobased ethylene) and up to 54 % for Keltan Eco 8550<br />

(55 wt‐% biobased ethylene).<br />

Figure 2 - Global Warming Potential of Keltan Eco 5470<br />

and 8850 compared to crude oil-based Keltan 5470 and<br />

8550, all produced in Triunfo plant (kg CO2-equiv. per ton<br />

polymer) (Data by Thinkstep).<br />

In essence Keltan Eco elastomers look, feel and behave<br />

like conventional crude oil-based EP(D)M, which show<br />

exceptional elasticity, flexibility, weather ability and durability.<br />

It can be mixed, moulded, extruded and calendared to<br />

produce rubber articles with excellent aesthetics. Arlanxeo<br />

has six Keltan Eco elastomers commercially available in its<br />

portfolio (Table 1).<br />

Typically, rubber articles not only consist of elastomer(s),<br />

but also of (reinforcing) filler(s), plasticizer(s), crosslinking<br />

agents and other additives. EP(D)M products may<br />

contain higher than 400 phr of compounding ingredients<br />

incorporated into 100 phr of EP(D)M elastomer.<br />

Carbon black is produced via incomplete combustion of<br />

a hydrocarbon feed with natural gas. Silica is produced via<br />

precipitation from a silicate salt solution. Inert white fillers,<br />

such as clay, talc and chalk are extracted from the ground<br />

in open mines and milled to fine powders.<br />

Traditional extender oils for EP(D)M are refinery fractions<br />

of crude oil. All of these ingredients, lack sustainability.<br />

In further efforts to increase the sustainability of EP(D)M<br />

rubber products based on Keltan Eco, the potential of using<br />

sustainable alternatives for traditional plasticizer oils and<br />

(reinforcing) fillers have been explored.<br />

Typical issues encountered when exploring relatively<br />

polar and unsaturated natural oils and fats in EP(D)M<br />

compounds are:<br />

• a lack of compatibility (mixing issues and oil bleeding);<br />

• competition for sulfur vulcanization (reduced crosslink<br />

density, inferior vulcanization properties).<br />

Modified natural oils, such as hydrogenated coconut oil or<br />

trans-esterified mono-esters have improved compatibility<br />

and/or vulcanization performance.<br />

Squalane (EPM hexamer) provides the best biobased<br />

alternative for mineral oil plasticizer, since it is as apolar as<br />

EP(D)M and is fully saturated.<br />

As far as sustainable fillers are concerned, pyrolysis black<br />

was shown to have a reinforcing efficiency 90 % of that of<br />

furnace N550 black. Rice husk ash and micro-cellulose do<br />

not show reinforcing properties, but can still be used as<br />

inert, white fillers, substituting certain traditional, mineral<br />

white fillers.<br />

Combining these sustainable plasticizer oils and<br />

(reinforcing) fillers has resulted in automotive solid seal<br />

EP(D)M compounds based on Keltan Eco with more than<br />

85 % sustainable content and properties comparable to<br />

the reference EP(D)M compounds, including heat ageing<br />

resistance up to 125 ºC.<br />

The final step towards a fully sustainable EP(D)M<br />

rubber compound would require the development of<br />

biobased rubber additives and curatives, which considering<br />

their chemical structure will be a long and challenging<br />

development.<br />

Aside improving sustainability of EP(D)M rubber products<br />

by compounding sustainable plasticizer oils, (reinforcing)<br />

fillers, another approach would be to develop a second<br />

generation Keltan Eco EP(D)M based on bio-ethylene<br />

ánd bio-propylene, which would bring the total biocarbon<br />

content of the EP(D)M elastomer, and sustainable<br />

compounds directly, to ~95 %.<br />

14 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


Polyurethanes / Elastomers<br />

By:<br />

Joyce Kersjes<br />

Technical Manager<br />

Global M&S/TSAD Keltan EPDM<br />

Arlanxeo High Performance Elastomers<br />

Geleen, The Netherlands<br />

Table 1 - Keltan Eco EP(D)M portfolio and key properties<br />

For the future Arlanxeo and its raw material<br />

suppliers are assessing routes to increase the biocarbon<br />

content of the EP(D)M elastomer to a maximum<br />

attainable, amongst others via:<br />

• production of methanol from wood, followed by<br />

conversion of methanol to propylene;<br />

• sugar-based routes either via ethanol to ethylene<br />

and then via metathesis to propylene or via<br />

isopropanol to propylene;<br />

• direct fermentation of glucose using genetically<br />

engineered micro-organisms to a mixture of<br />

olefins, including propylene.<br />

The finishing touch to 100 % bio-carbon EP(D)M<br />

elastomer would be a biobased diene.<br />

As an example to stimulate interest, it can be<br />

mentioned that first experiments with an amorphous<br />

EP(D)M with 6 wt% 2,4-dimethyl-2,7-octadiene<br />

(natural terpene) as the diene, showed reasonable<br />

sulfur vulcanization characteristics and corresponding<br />

vulcanization properties, similar to a medium ENB-<br />

EP(D)M.<br />

Up till now Keltan Eco has received a positive<br />

response in the market and commercialization<br />

at customers is on-going in different application<br />

segments, like automotive and construction window<br />

and door sealing systems, as well as in hoses, innertubes,<br />

(bio-)plastics impact modification, TPE-V<br />

production, sport surfaces and sports goods. Some<br />

examples are displayed below.<br />

In conclusion: The broad portfolio of Keltan Eco<br />

EP(D)M elastomers offers the unique opportunity<br />

to industries to develop sustainable and bio-carbon<br />

based compounds and TPE-Vs for many applications.<br />

www.keltan.com | www.ARLANXEO.com<br />

[kg CO 2<br />

-Equiv]<br />

Sugar<br />

cane<br />

Crude oil<br />

Figure 2: Global Warming Potential of Keltan Eco 5470 and 8850<br />

compared to crude oil-based Keltan 5470 and 8550, all produced in<br />

Triunfo plant (kg CO 2<br />

-equiv. per ton polymer) (Data by Thinkstep)<br />

3,500<br />

3,000<br />

2,500<br />

2,000<br />

1,500<br />

1,000<br />

500<br />

0<br />

Grades<br />

Raw materials<br />

Ethanol<br />

Viscosity ML(1+4)<br />

(@ shown °C) [MU]<br />

Figure 1 - Route to biobased EP(D)M<br />

100%<br />

bio-based<br />

Ethylene<br />

0%<br />

bio-based<br />

C2<br />

[wt%]<br />

50-70%<br />

bio-based<br />

Keltan-Eco®<br />

EPDM<br />

ENB<br />

[wt%]<br />

Keltan Eco 0500R 11 g/10 min. (MFI) 49 -<br />

Keltan Eco 3050 51 (@ 100°C) 49 -<br />

Keltan Eco 5470 55 (@ 125°C) 70 4.6<br />

Keltan Eco 8550 80 (@ 125°C) 55 5.5<br />

Keltan Eco 6950 65 (@ 125°C) 48 9.0<br />

Keltan Eco 9950 60 (@ 150°C) 48 9.0<br />

15-20% biobased<br />

0%<br />

bio-based<br />

End products<br />

K5470 Triunfo K5470 Eco K8550 Triunfo K8550 Eco<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 15


Polyurethanes / Elastomers<br />

Renwable polyols<br />

Perstorp launches world’s first portfolio of renewable polyols<br />

Perstorp (Malmö, Sweden) recently announced the world’s<br />

first portfolio of renewable alternatives to the essential<br />

polyols Pentaerythritol (Penta), Trimethylolpropane (TMP),<br />

and Neopentyl glycol (Neo). The product portfolio was<br />

globally launched at China Coat (15-17 November <strong>2017</strong>,<br />

Shanghai). The launch is a response to the fast growing<br />

global need for more sustainable Coatings, Resins and<br />

Synthetic Lubricants to mention a few. This means that<br />

Perstorp is the only chemical company in the world to offer<br />

all three essential polyols Penta, TMP and Neo in both<br />

traditional and renewable forms.<br />

World’s first renewable Penta, known as Voxtar, was<br />

launched in 2010. It can reduce carbon footprint by up to<br />

80 % compared to fossil alternatives. The addition of two<br />

new innovative products; Evyron (partly renewable TMP)<br />

and Neeture (partly renewable Neo) will give Perstorp’s<br />

customers a clear market advantage in creating proenvironmental<br />

low carbon footprint products.<br />

Anna Berggren, Global Market Segment Manager for<br />

Resins at Perstorp commented: “The time is right to add two<br />

new renewable polyols. The market demand for biobased<br />

material is rapidly increasing due to a strong focus on<br />

sustainable chemistry and renewable raw materials. We are<br />

committed to our environmental responsibility as well as<br />

to helping our customers in their sustainable development.<br />

We are dedicated to our pro-environment products, giving<br />

prioritized supply for pro-environmental partners at all<br />

times.”<br />

Committed to the pro-environmental walk<br />

Perstorp’s commitment to sustainability runs deep in the<br />

company led by CEO, Jan Secher. “This launch is a great<br />

achievement and I’m very proud of the engagement from<br />

our employees. It’s clear that we are looking to make a<br />

difference. Sustainability is in the core of everything we do<br />

which also makes it a perfect strategic fit.”<br />

Perstorp’s new pro-environment portfolio is a great<br />

example of how they intend to work towards their 2030<br />

ambition to become Finite Material Neutral. “It is a tough<br />

ambition but we have to do it. There is no plan B, because<br />

we only have one planet,” Jan continues.<br />

Currently Perstorp is devoting 80 % of its R&D resources<br />

to finding new sustainable solutions and in addition, all<br />

Perstorp Swedish plants will switch to using only renewable<br />

electricity in 2018. “With the new pro-environment products<br />

we are launching at China Coat, we are reaffirming that we<br />

believe our molecules can change things for the better”,<br />

Jan concludes.<br />

Good for business and good for the environment<br />

The two new Pro-Environment Polyols – Evyron and<br />

Neeture - complete the portfolio of the three essential<br />

polyols in renewable options. The new portfolio is based on<br />

a certified mass balance concept. Mass balance is about<br />

mixing fossil and renewable in the same existing systems<br />

but keeping track of their quantities and allocating them<br />

to specific products. This ensures that the quality and<br />

performance of the molecules are exactly the same giving<br />

customers a real go-pro-environmental choice.<br />

Perstorp’s Pro-Environment Polyols are all ISCC<br />

certified which among other things ensures a traceability<br />

of the biobased raw material back to its country of origin.<br />

Anna Berggren highlights: “The biobased material in our<br />

products is sustainably sourced and I am proud to say that<br />

Perstorp launches world´s first portfolio of renewable<br />

polyols. And even better, they will also be the first to become<br />

ISCC certified.” MT<br />

www.perstorp.com<br />

16 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


Polyurethanes / Elastomers<br />

Congratulations!<br />

Ford Motor Company celebrates 10-year<br />

anniversary of soybean-based foam<br />

Ten years ago, the 2008 Ford Mustang launched with<br />

seats made of soybean-based foam. Today, soy foam<br />

has saved over 100,000 tonnes (228 million pounds) of<br />

CO 2<br />

from entering the atmosphere; the same as would be<br />

consumed by four million trees per year, according to a consumer<br />

horticulturist at North Carolina State University.<br />

Ford has used soy foam since the Mustang went into<br />

production in late 2007, replacing traditional petroleumbased<br />

foam that most industries use. Researching and<br />

testing renewable, plant-based alternatives to petroleumbased<br />

plastics is something Ford has been committed to<br />

since 2000.<br />

“From our labs to our suppliers, incorporating renewable<br />

materials into auto parts takes a lot of work, but it’s the right<br />

thing to do,” said Executive Chairman Bill Ford. “At Ford, we<br />

want to do our part to reduce our impact on the environment,<br />

and using more sustainable materials in the vehicle is one of<br />

the ways we are doing this.”<br />

Since 2011, every Ford vehicle built in North America uses<br />

the soy foam in seat cushions, backs and headrests. It meets<br />

the company’s strict requirements as a renewable solution<br />

and doesn’t compromise durability and performance. Over<br />

the past decade, approximately 18.5 million vehicles have<br />

been produced with soy foam in them - that’s over 578 billion<br />

soybeans.<br />

Debbie Mielewski, Ford senior technical leader, has been<br />

leading the sustainable materials effort from the beginning,<br />

and said it wasn’t easy convincing suppliers to do molding<br />

trials; especially when petroleum oil prices were available at<br />

a low cost. The United Soybean Board (USB) - a group located<br />

in Chesterfield, Missouri, USA, that oversees investments in<br />

soybean innovations nationwide - played an integral role in<br />

funding the initial trials, and Bill Ford kept the project moving<br />

through all obstacles.<br />

“We may not have ever gone to<br />

market with soy foam if Bill Ford had not been at the helm,”<br />

Mielewski said. “It was a project that would only move forward<br />

with both a visionary and an environmentalist in the driver’s<br />

seat, so to speak, and we were lucky to have him there.”<br />

In 2008, when oil prices skyrocketed, the value of soy foam<br />

became widely apparent - not only was replacing petroleumbased<br />

polyol with soy beneficial to the environment, it could<br />

also save the company money.<br />

Ford worked tirelessly with other industries to help them<br />

formulate foams that met their specific requirements, like<br />

agriculture, furniture and home goods, allowing them the<br />

chance to also incorporate it into their products - stretching<br />

the environmental benefits even further.<br />

“We knew that putting farm materials into a performance<br />

car like the Mustang could be met with a lot of skepticism,”<br />

said Mielewski. “But we also knew that if we succeeded, the<br />

foam we created could, over time, make a positive impact.”<br />

After the success of soy foam, Ford began the development<br />

of other renewable materials to reinforce plastics in vehicles,<br />

including wheat straw, rice hulls and cellulose fibers from<br />

sustainably grown trees, coconut fibers and kenaf. The<br />

sustainable materials research team is currently working on<br />

approximately 20 other unlikely sustainable candidates for<br />

auto parts - tomato peels, agave fiber (tequila), recycled U.S.<br />

currency, dandelions and algae to name a few. They continue<br />

to work with the USB to develop soy-based materials for<br />

rubber components like tires and gaskets.<br />

“Soy foam was an important first step, but we still have<br />

a lot of work to do,” said Mielewski. “There are many more<br />

opportunities arising to reduce our environmental impact,<br />

and with resources becoming more constrained, it becomes<br />

more important that we explore them.” MT<br />

www.ford.com | unitedsoybean.org<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 17


Polyurethanes / Elastomers<br />

Biobased<br />

thermoplastic<br />

elastomer<br />

compounds<br />

In response to increasing demands for sustainable alternatives<br />

to fossil based flexible polymer compounds, international<br />

compounding group, HEXPOL ® TPE, launched<br />

the Dryflex ® Green family of biobased Thermoplastic Elastomers<br />

(TPE) in 2015. Since then they have continued to develop<br />

the range, adding new possibilities to the biobased<br />

thermoplastic market by covering a wider range of hardnesses<br />

while incorporating high levels of renewable content.<br />

TPEs are often described as the bridge between rubber<br />

and plastics, they combine elasticity, flexibility and softness<br />

similar to rubber with the recyclability and processing<br />

advantages of plastics. Hexpol TPE were among the first<br />

companies to develop TPE compounds in Europe and they<br />

built on their 50 years heritage in the flexible polymers<br />

market in developing their biobased materials. Dryflex<br />

Green TPE compounds are available from 15 Shore A<br />

through to 55 Shore D. The range includes grades with<br />

biobased content over 90 % (ASTM D 6866), achieved by<br />

use of sustainable raw materials and feedstocks such as<br />

sugarcane, with recognised certifications such as ISCC+<br />

and can derive from raw materials such as polymers, fillers,<br />

plasticizers or additives.<br />

For applications wanting a look even closer to nature,<br />

Hexpol TPE has developed compounds using organic fillers<br />

and natural fibres from plants, crops or trees, including<br />

cork, these give an additional ‘organic’ appearance. Cork<br />

is a natural product which comes from the bark of the cork<br />

oak tree. The removal of the bark does not harm the trees<br />

and the bark is only harvested after the first 20 years of<br />

growth. The removal stimulates a steady regeneration of<br />

the bark.<br />

Dryflex Green TPE compounds display mechanical<br />

and physical properties close to and comparable to TPE<br />

compounds from fossil based raw materials. In general<br />

the Dryflex Green compounds show very good bonding<br />

behaviour to PE and PP, special grades with good bonding<br />

to ABS, PET and PLA are also available. Like conventional<br />

TPE compounds, Dryflex Green TPEs can easily be coloured<br />

to give vibrant and appealing visual impact. Grades suitable<br />

for food contact are also available.<br />

Dryflex Green TPE compounds can be used in many<br />

applications that currently use conventional TPE and<br />

flexible polymers, such as soft-touch grips and handles,<br />

sealings, mats and closures, Klas Dannäs, Global R&D<br />

manager at Hexpol TPE commented “We’re seeing some<br />

very interesting development projects for the Dryflex Green<br />

materials; for applications ranging from household goods,<br />

sports equipment and toys to automotive interiors, packaging<br />

and infant care. Our R&D teams are constantly evaluating new<br />

polymer combinations and we have been working closely with<br />

suppliers to develop sustainable and ethical alternatives to<br />

fossil-based polymer compounds.” MT<br />

www.hexpolTPE.com<br />

HEXPOL TPE<br />

worked with Wildo<br />

Sweden AB on the<br />

development of<br />

a biobased TPE<br />

for their iconic<br />

Fold-A-Cup.<br />

Typical Percentage of Bio-Content vs Hardness in Biobased TPEs<br />

Table 1: Typical Properties of Representative Dryflex Green Grades<br />

HARDNESS (1)<br />

ISO 868<br />

BIOBASED<br />

CARBON<br />

CONTENT<br />

% on TOC<br />

ASTM<br />

D6866-12<br />

DENSITY<br />

g/cm³<br />

TENSILE<br />

STRENGTH (2)<br />

MPa<br />

ISO 2781 ISO 37 (Type 1)<br />

ELONGATION<br />

AT BREAK (2)<br />

%<br />

ISO 37<br />

(Type 1)<br />

25 Shore A >40 0.89 1.3 500<br />

40 Shore A >40 0.91 2 410<br />

50 Shore A >80 0.89 5 500<br />

60 Shore A >75 0.91 5 360<br />

70 Shore A >50 0.93 8 700<br />

80 Shore A >80 0.91 6 500<br />

55 Shore D >70 0.94 20 900<br />

(1)<br />

After 15 seconds, (2) Across the flow direction<br />

18 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


©<br />

3,5<br />

actual data<br />

3<br />

2,5<br />

2<br />

1,5<br />

1<br />

0,5<br />

2011 2012 2013<br />

L-LA<br />

Epichlorohydrin<br />

Succinic<br />

1,4-BDO<br />

acid<br />

-Institut.eu | <strong>2017</strong><br />

forecast<br />

2014 2015 2016 <strong>2017</strong> 2018 2019 2020 2021<br />

Sebacic<br />

MEG<br />

Ethylene<br />

1,3-PDO<br />

MPG<br />

Lactide<br />

acid<br />

2,5-FDCA D-LA<br />

11-Aminoundecanoic acid<br />

Adipic<br />

DDDA<br />

acid<br />

Full study available at www.bio-based.eu/reports<br />

©<br />

100%<br />

80%<br />

60%<br />

40%<br />

20%<br />

0%<br />

-Institut.eu | <strong>2017</strong><br />

PBS(X)<br />

APC –<br />

cyclic<br />

PA<br />

PET<br />

PTT<br />

PBAT<br />

Starch<br />

Blends<br />

PHA<br />

PLA<br />

PE<br />

Full study available at www.bio-based.eu/markets<br />

©<br />

10<br />

5<br />

0<br />

2011 2012<br />

PUR<br />

PA<br />

-Institut.eu | 2016<br />

actual data<br />

2% of total<br />

polymer capacity,<br />

€13 billion turnover<br />

2013 2014 2015 2016<br />

Epoxies PET<br />

CA<br />

PBS<br />

PBAT PHA<br />

<strong>2017</strong><br />

Starch<br />

Blends<br />

EPDM<br />

2018<br />

PLA<br />

APC<br />

2019 2020<br />

PE<br />

PEF<br />

2021<br />

PTT<br />

Full study available at www.bio-based.eu/markets<br />

Bio-based Polymers & Building Blocks<br />

The best market reports available<br />

Data for<br />

2016<br />

Commercialisation updates on<br />

bio-based building blocks<br />

Standards and labels for<br />

bio-based products<br />

Bio-based polymers, a revolutionary change<br />

Bio-based Building Blocks<br />

and Polymers<br />

Selected bio-based building blocks: Evolution of worldwide<br />

production capacities from 2011 to 2021<br />

Comprehensive trend report on PHA, PLA, PUR/TPU, PA<br />

and polymers based on FDCA and SA: Latest developments,<br />

producers, drivers and lessons learnt<br />

Global Capacities and Trends 2016 – 2021<br />

million t/a<br />

Bio-based polymers, a<br />

revolutionary change<br />

million t/a<br />

Bio-based polymers: Evolution of worldwide<br />

production capacities from 2011 to 2021<br />

Jan Ravenstijn <strong>2017</strong><br />

E-mail: j.ravenstijn@kpnmail.nl<br />

Mobile: +31.6.2247.8593<br />

Picture: Gehr Kunststoffwerk<br />

Author: Doris de Guzman, Tecnon OrbiChem, United Kingdom<br />

July <strong>2017</strong><br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Authors: Lara Dammer, Michael Carus and Dr. Asta Partanen<br />

nova-Institut GmbH, Germany<br />

May <strong>2017</strong><br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Author: Jan Ravenstijn, Jan Ravenstijn Consulting, the Netherlands<br />

April <strong>2017</strong><br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Authors: Florence Aeschelmann (nova-Institute),<br />

Michael Carus (nova-institute) and ten renowned international experts<br />

February <strong>2017</strong><br />

This is the short version of the market study (249 pages, € 2,000).<br />

Both are available at www.bio-based.eu/reports.<br />

Policies impacting bio-based<br />

plastics market development<br />

and plastic bags legislation in Europe<br />

Asian markets for bio-based chemical<br />

building blocks and polymers<br />

Brand Views and Adoption of<br />

Bio-based Polymers<br />

Market study on the consumption<br />

of biodegradable and compostable<br />

plastic products in Europe<br />

2015 and 2020<br />

Share of Asian production capacity on global production by polymer in 2016<br />

A comprehensive market research report including<br />

consumption figures by polymer and application types<br />

as well as by geography, plus analyses of key players,<br />

relevant policies and legislation and a special feature on<br />

biodegradation and composting standards and labels<br />

Bestsellers<br />

Disposable<br />

tableware<br />

Biowaste<br />

bags<br />

Carrier<br />

bags<br />

Rigid<br />

packaging<br />

Flexible<br />

packaging<br />

Authors: Dirk Carrez, Clever Consult, Belgium<br />

Jim Philp, OECD, France<br />

Dr. Harald Kaeb, narocon Innovation Consulting, Germany<br />

Lara Dammer & Michael Carus, nova-Institute, Germany<br />

March <strong>2017</strong><br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Author: Wolfgang Baltus, Wobalt Expedition Consultancy, Thailand<br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Author: Dr. Harald Kaeb, narocon Innovation Consulting, Germany<br />

January 2016<br />

This and other reports on the bio-based economy are available at<br />

www.bio-based.eu/reports<br />

Authors: Harald Kaeb (narocon, lead), Florence Aeschelmann,<br />

Lara Dammer, Michael Carus (nova-Institute)<br />

April 2016<br />

The full market study (more than 300 slides, 3,500€) is available at<br />

bio-based.eu/top-downloads.<br />

www.bio-based.eu/reports<br />

www.co2-chemistry.eu<br />

Leading Event on<br />

Carbon Capture and Utilisation<br />

15 – 16 March 2018, Cologne (Germany)<br />

Conference Team<br />

Jutta Millich<br />

Partners, Media Partners<br />

+49 (0)0561 503580-44<br />

jutta.millich@nova-institut.de<br />

Dr. Asta Partanen<br />

Sponsoring<br />

+49 (0)2233 4814-59<br />

asta.partanen@nova-institut.de<br />

Achim Raschka<br />

Programme<br />

+49 (0)2233 4814-51<br />

achim.raschka@nova-institut.de<br />

Conference highlights and main topics<br />

• CO 2<br />

for feed – proteins made from carbon dioxide<br />

• CO 2<br />

for platform chemicals and polymers<br />

• CO 2<br />

for future fuels<br />

• CO 2<br />

for aviation kerosene<br />

• Sustainability & climate change<br />

mitigation potential<br />

• Key drivers: renewable energy<br />

& hydrogen production<br />

• Artificial photosynthesis as future technology<br />

• Political framework & visions<br />

Newsticker on<br />

Carbon Capture and Utilisation!<br />

Free access:<br />

www.co2-chemistry.eu/news<br />

www.co2-chemistry.eu<br />

Dominik Vogt<br />

Conference Manager<br />

+49 (0)2233 4814-49<br />

dominik.vogt@nova-institut.de<br />

Venue<br />

Maternushaus<br />

Kardinal-Frings-Str. 1<br />

5<strong>06</strong>68 Cologne<br />

www.maternushaus.de<br />

Organiser<br />

nova-Institut GmbH<br />

Chemiepark Knapsack<br />

Industriestraße 300<br />

50354 Hürth, Germany<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 19


Polyurethanes / Elastomers<br />

Bio-succinic acid:<br />

A frontrunner for high-performance biobased polyurethanes and beyond<br />

Biobased polyurethanes (PU) and packaging are<br />

increasingly being used for consumer goods and becoming<br />

more common in stores and supermarkets. Following this<br />

trend, the platform chemicals required to manufacture<br />

sustainable biomaterials are also becoming more readily<br />

available. Biosuccinium ® , the renewable bio-succinic<br />

acid produced by Dutch biotech company Reverdia<br />

(Geleen), continues to demonstrate strong opportunities<br />

for polyurethanes and bioplastic products. These modern<br />

materials offer enhanced performance for footwear, the<br />

automotive industry and other market sectors.<br />

VAUDE (Tettnang, Germany), a manufacturer of innovative<br />

outdoor products, is already benefiting from the winning<br />

footprint of bio-succinic acid. The company recently<br />

announced that it will reduce its dependency on oil by replacing<br />

conventional materials with those derived from Biosuccinium.<br />

Sustainable footwear with benefits<br />

As a near drop-in for adipic acid, bio-succinic acid can<br />

be used to produce biobased polyester polyols, which have<br />

been well received in the footwear industry. Vaude’s new<br />

Skarvan range of trekking shoes will use Biosucciniumbased<br />

thermoplastic polyurethane (TPU) in its shoe toe<br />

caps and heel counters. It is the first time the brand will use<br />

a biobased TPU in its shoes and the range will be available<br />

to consumers in spring 2018.<br />

This is a clear example of how biobased chemicals can<br />

help producers meet growing customer demands for more<br />

sustainable products. Vaude is committed to minimising<br />

the environmental footprint of its products while not<br />

compromising on high-end design and sturdy quality.<br />

The brand has previously demonstrated this by being the<br />

first outdoor company to be certified under the EU’s Ecomanagement<br />

and Audit Scheme (EMAS).<br />

Reverdia views the growing trend of biobased consumer<br />

goods as a positive sign of things to come. High-performance<br />

biobased footwear on store shelves is just one example. In<br />

<strong>2017</strong>, it showcased a range of cutting-edge<br />

Biosuccinium-based polyurethanes at<br />

PSE Europe in Munich, Germany.<br />

These PU prototypes could be used across markets. They<br />

have a significantly reduced environmental footprint due<br />

to the renewable raw materials used and the sustainable<br />

technology which produces the biobased chemicals.<br />

Biobased content reached 60 % in some samples. The<br />

biomaterials can be used for applications such as industrial<br />

components (cast PU), artificial leather (PU dispersion),<br />

footwear products including sole plates (TPU) for soccer<br />

boots and trainers for other field sports, as well as casual<br />

shoe soles (microcellular PU).<br />

In China, Reverdia and Dezhou Xinhuarun Technology<br />

(Xinhuarun) have signed an agreement to jointly develop<br />

and promote microcellular PU foams. Xinhuarun’s products<br />

are exported across Asia, America, Europe and the Middle<br />

East. The manufacturer will work exclusively with Reverdia,<br />

using Biosuccinium in its shoe soles and will expand the<br />

partnership towards development and commercialisation<br />

of other sustainable polymers with excellent functionality<br />

and best-in-class eco-footprint.<br />

One step beyond!<br />

It is not only footwear products which can benefit from<br />

switching to bio-succinic acid. Biosuccinium-based<br />

materials could also offer enhanced performance for the<br />

automotive and aircraft industries. Flexible PU foams<br />

with various densities have been synthesised by partially<br />

replacing traditional polyols with Biosuccinium-based<br />

polyols.<br />

Recently in Italy, the Institute for Polymers, Composites<br />

and Biomaterials (Naples), the Institute for Macromolecular<br />

Studies (Milan) and Adler Plastic (Ottaviano) published<br />

studies showing bio-succinic acid-based flex foam with<br />

improved mechanical and acoustic performance. Amongst<br />

those benefits are a positive effect on the foams’ compressive<br />

performance and their increased sound absorption level.<br />

With these benefits, the foams made with bio-succinic<br />

acid could be considered as potential substitutes to reduce<br />

vibrations and noise pollution and consequently increase<br />

comfort.<br />

Bio-succinic<br />

acid-running<br />

shoes pair<br />

grey green<br />

20 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


Polyurethanes / Elastomers<br />

By:<br />

Bio-succinic<br />

acid-Microcellular<br />

PU collage<br />

Lawrence Theunissen<br />

Global Director Application Development<br />

Reverdia, Geleen, The Netherlands<br />

An unrelated<br />

agreement between<br />

Reverdia and Covestro<br />

was announced in 2015 to<br />

jointly develop and promote<br />

TPU based on renewable<br />

raw materials. Covestro<br />

will use Biosuccinium<br />

in the production of its<br />

Desmopan ® -brand TPU<br />

for a variety of applications<br />

beyond footwear, such as apparel and<br />

consumer electronics. Beyond biobased PU,<br />

bio-succinic acid is also enabling leading developments in<br />

plastic packaging and resins.<br />

Developments in sustainable packaging<br />

Polybutylene succinate (PBS) is one of the newest<br />

biopolymers under development for numerous applications<br />

worldwide. Biosuccinium can be used to create PBS for<br />

plastics and packaging. Traditionally, PBS is based on<br />

petrochemical succinic acid and 1,4 butanediol (1,4 BDO).<br />

Petro-based PBS is already biodegradable. However,<br />

Biosuccinium can boost PBS’s biobased content, making it<br />

even more sustainable.<br />

PBS has a range of interesting properties including<br />

flexibility and heat resistance. The material can be used<br />

as a matrix polymer or as a modifier to be combined with<br />

another chemical such as polylactic acid (PLA). PBS offers<br />

opportunities for a wide range of applications like food<br />

packaging, coffee cups, paper lamination, agricultural<br />

mulch films, non woven, electrics and electronics, and<br />

automotive interiors.<br />

In order to further broaden the application scope for PBS,<br />

Reverdia operates a joint development programme with<br />

Wageningen UR Food & Biobased Research on biobased<br />

PBS compounds for injection moulding. The research pays<br />

close attention to the longevity, appearance and processing<br />

characteristics. Plastic<br />

product manufacturers<br />

will also play a key role<br />

in the testing process<br />

in order to validate these<br />

new compounds for reusable<br />

horticultural crates and rigid<br />

food packaging with hinges. The<br />

final biomaterials are predicted to<br />

demonstrate an improved carbon footprint<br />

in comparison to the polypropylene typically<br />

used for these applications.<br />

Bio-succinic acid for resins<br />

Paint and coating manufacturers can increase the<br />

biobased content of their resins by using Biosuccinium.<br />

Solvents and coalescing agents based on bio-succinic acid<br />

also allow for reduced levels of volatile organic compounds<br />

(VOCs) in their formulations, addressing continuously<br />

stricter government and industry regulations.<br />

Investment in superior biobased resins is growing, as is<br />

the demand for more sustainable products across the value<br />

chain. Biosuccinium is a near drop-in for adipic and phthalic<br />

acids and has applications in a wide range of products.<br />

Product finishes, special purpose coatings and structural<br />

materials are just a few examples.<br />

Alkyd paints which use bio-succinic acid are already on<br />

the market. Mäder (Lille, France), the leading producer of<br />

paints and coatings, recently launched a range of biobased<br />

paints using Biosuccinium under the CAMI brand. The<br />

CADÉLI range includes two EU Ecolabel-certified products<br />

with extra functionalities: anti-microbial interior paint and<br />

depolluting (anti-formaldehyde) interior paint.<br />

Both of the paints are 98 % biobased and use a combination<br />

of Biosuccinium and Roquette’s POLYSORB isosorbide. The<br />

formulation allows for specific physical properties, such as<br />

hardness and scratch resistance.<br />

Bio-succinic<br />

acid-Reverdia &<br />

Wageningen UR<br />

have developed<br />

durable PBS based<br />

on Biosuccinium.<br />

Picture courtesy of<br />

RPC Promens<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 21


www.pu-magazine.com<br />

Polyurethanes / Elastomers<br />

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Plus, it’s nonflammable and U.S. EPA SNAP-listed.<br />

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© <strong>2017</strong> Honeywell International Inc. All rights reserved.<br />

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Volume 8, May <strong>2017</strong><br />

Going the distance<br />

Whether for footwear, furnishings, packaging or<br />

paint, industry leadership is crucial for biobased<br />

plastic to compete with traditional petro-based<br />

products. New materials must be competitive and<br />

provide enhanced product specifications while also<br />

delivering sustainability advantages. Many modern<br />

materials derived from bio-succinic acid can<br />

outperform petro-based equivalents. With further<br />

incentives and industry buy-in, they can provide a<br />

significant impact.<br />

This is why Reverdia works with brand owners<br />

and manufacturers towards truly sustainable<br />

products. It will keep building on its partnerships to<br />

co-develop innovative high-performance solutions<br />

throughout the value chain. Brand owners, original<br />

equipment manufacturers and chemical companies<br />

are becoming increasingly aware of Biosuccinium’s<br />

potential to unlock and mainstream sustainable<br />

products.<br />

Innovative biomaterials<br />

Reverdia has been enabling innovative biobased materials<br />

since 2010. A joint venture between Royal DSM, the Dutch<br />

global Life Sciences and Materials Sciences company and<br />

Roquette Frères, the French global starch and starchderivatives<br />

company, Reverdia was created to produce and<br />

commercialise bio-succinic acid, marketed under the brand<br />

name Biosuccinium.<br />

Having opened the world’s first dedicated, commercialscale<br />

biorefinery for the production of renewable succinic acid<br />

in 2012, Reverdia supplies worldwide. Its production plant in<br />

Italy continues to use a patented fermentation technology<br />

with a best-in-class environmental footprint.<br />

Biosuccinium is a biobased alternative to traditional diacids<br />

used in the production of plastics and other materials.<br />

Thanks to its biobased content and Reverdia’s game-changing<br />

technology, bio-succinic acid has a carbon footprint which is<br />

half that of petro-based succinic acid and up to 90% lower<br />

than adipic acid.<br />

www.reverdia.com<br />

SEEING POLYMERS<br />

WITH DIFFERENT EYES...<br />

Biokraftstoffkompatibilität von FKM<br />

Silica/silane reaction mechanism<br />

self-healing tpu<br />

POLYURETHANES MAGAZINE INTERNATIONAL<br />

Trim The Weight,<br />

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Interviews: ISL-Chemie, Dow, Magna, Vencorex<br />

PSE Europe <strong>2017</strong> preview<br />

High temperature foam<br />

PIR insulation<br />

CNSL-based polyols<br />

Blowing Agents<br />

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Strukture le Faserverbundbauteile<br />

PU-basierte Bedachungsmaterialien<br />

Polyole auf CNSL-Basis<br />

Polyesterpolyole<br />

Interview mit G. Burrow, Magna<br />

Führende Köpfe für führende Lösungen<br />

Pultrusion neu gedacht<br />

Relaxed Extrusion<br />

PEEK-PTFE-cg-Materialien<br />

Fachmagazin für die Polymerindustrie<br />

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Volume 12, July <strong>2017</strong><br />

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Our technical magazines and books create your expertise<br />

22 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12<br />

Tel. +49 2102 9345-0 · Fax +49 2102 9345-20<br />

www.gupta-verlag.com


New biobased lactide<br />

polyester polyols<br />

By:<br />

Bill Coggio<br />

Application and Technology<br />

Development Manager<br />

Performance Chemicals Division<br />

NatureWorks, Minnetonka, USA<br />

NatureWorks Introduces new Vercet biobased lactide polyester<br />

polyols as reactive intermediates for urethane adhesives and coatings<br />

NatureWorks (Minnetonka, Minnesota, USA), known for its<br />

broad portfolio of renewably-sourced PLA polymers under<br />

the Ingeo brand, recently formed a Performance Chemicals<br />

Division to supply lactides, polyols, binder resins, and chemical<br />

intermediates to companies that manufacture coatings, adhesives,<br />

sealants, elastomers, toners, and fine chemicals products.<br />

Vercet is the brand name of the company’s new tunable<br />

platform of lactide-based chemistries. Vercet polyols are<br />

customizable and provide excellent hardness, solvent<br />

resistance, and low color in polyurethanes. Alkyd resins for<br />

coatings made using Vercet lactides can significantly reduce<br />

resin viscosity enabling low volatile organic compound (VOC)<br />

formulations for solvent-borne alkyd coatings for wood and<br />

metal. Furthermore, these alkyd coatings exhibit excellent<br />

adhesion and show improved abrasion and impact resistance.<br />

Solvent-borne coatings and hot melt adhesives utilizing Vercet<br />

intermediate resins have a tunable work life and viscosity<br />

range with excellent adhesion to metal and plastics.<br />

High bio-content reactive intermediates for<br />

polyurethane adhesives and coatings<br />

Vercet polyols are easily customized to control key properties<br />

that impact performance in polyurethanes. Controlled Vercet<br />

product properties include hydroxyl functionality, viscosity, glass<br />

transition temperature (Tg), compatibility, and solubility. Vercet<br />

polyols are easily converted into urethane thermoplastics via a<br />

direct reaction with an isocyanate and chain extender, which means<br />

Fig 2: Film coated with Vercet-based urethane coating shows high<br />

transparency and low haze<br />

these new chemistries will be easily substituted for non-biobased<br />

intermediates. They can also be made into isocyanate prepolymers<br />

to facilitate formulation flexibility for use in 1K and 2K reactive<br />

thermoset urethane systems. In reactive hot melt adhesives, Vercet<br />

polyols offer excellent adhesion and are tuned to improve green<br />

strength shortening component assembly in applications involving<br />

wood or plastic products.<br />

Vercet polyurethane systems for both coatings and adhesives<br />

exhibit superior oil resistance, modulus, adhesion, and gloss<br />

compared to a non-biobased control polyester.<br />

Vercet polyurethane coatings on metal and plastic demonstrated<br />

excellent adhesion even when used with no adhesion promoter and<br />

thus offer formulators the potential to simplify formulations and<br />

reduce system costs.<br />

Since NatureWorks uses biobased feedstocks to produce the<br />

Vercet lactides, polyols, and resins the company does not have the<br />

price volatility and supply chain pinch points of traditional coating<br />

and adhesive components.<br />

www.vercet.natureworksllc.com<br />

Fig 1: Vercet lactide-based polyurethanes show notable<br />

resistance to hydrocarbon oil, vegetable oil, and hexane,<br />

a common non-polar organic solvent.<br />

10%<br />

8%<br />

6%<br />

4%<br />

2%<br />

10 DAY WT%<br />

SOLVENT<br />

PICK-UP<br />

0%<br />

-2%<br />

IRM 903 OIL CANOLA OIL N-HEXANE WATER<br />

CONTROL 10.00% 4.50% 1.50% 0.60%<br />

P2040X -0.20% 0.20% 0.60% 0.90%<br />

P2140X 0.10% 0.00% 0.10% 1.00%<br />

Wt% data collected 68˚C<br />

Table 1: Urethane coatings made with Vercet lactide polyols show excellent hardness and adhesion. They are made with a high level of bio-content.<br />

Sample<br />

60° Gloss<br />

85°<br />

Gloss<br />

X-Adhesion<br />

König<br />

Hardness<br />

Pencil Hardness<br />

Biobased Carbon Content<br />

Uncoated Metal 83 22 NA 220 sec NA -<br />

PU Control 40 71<br />

PU w/ Vercet Polyol 95 88<br />

• Solvent borne TPU coated on metal Q panels<br />

• Ethyl acetate ~20% solids, bar coated DFT ~ 30<br />

um thick<br />

1B<br />

(35-65% loss)<br />

5B<br />

(no loss)<br />

• RT dried, no crosslinking reagent<br />

• Biobased carbon content is calculated<br />

45 sec


Polyurethanes/Elastomers<br />

Injection molders who have<br />

made bioplastics work<br />

Summary<br />

Bioplastics have a problematic reputation among injection<br />

molders because running them in the past has been - in<br />

some cases - both cumbersome and expensive. However,<br />

many modern bioplastics do not exhibit the troubling<br />

qualities of their predecessors and can now run through<br />

the injection molding process similarly to traditional<br />

petroleum-based plastics. The author spoke with four<br />

injection molders in North America who have successfully<br />

worked with bioplastics to gauge their thoughts on the<br />

material’s performance.<br />

How has the relationship between injection<br />

molders and bioplastics changed?<br />

Injection molders have had issues with bioplastics in the<br />

past because certain materials were expensive and not<br />

compatible with existing equipment. These issues forced<br />

injection molders at times to purchase new equipment and<br />

even make fundamental and expensive changes to their<br />

processes. As a result, bioplastics now have a problematic<br />

reputation among injection molders, who are wary of using<br />

them in their facilities.<br />

However, bioplastics have since evolved and most of them<br />

can now seamlessly replace certain traditional petroleumbased<br />

plastics. The four interviewed injection molders<br />

provided valuable and promising insights on what working<br />

with bioplastics entails. Although each had technical issues<br />

at the initial stages, they were eventually able to run the<br />

materials successfully in their respective facilities.<br />

Matt Poischbeg, an injection molder at Sea-Lect Design<br />

(Everett, Washington, USA), was enthusiastic about<br />

experimenting with different bioplastics due to the possible<br />

competitive advantages they could offer to customers. He<br />

found out about Green Dot Bioplastics five years ago at an<br />

outdoor retailer expo in Salt Lake City, Utah, USA. Poischbeg<br />

said the company caught his attention because he “…was<br />

amazed that they had a flexible compostable plastic.” He<br />

had heard of compostable biodegradable plastics but had<br />

never seen elastomeric materials. Poischbeg experimented<br />

with the flexible compostable plastic material for kayak<br />

manufacturers but had to forgo the project due to a lack of<br />

demand.<br />

However, he successfully developed a compostable<br />

luggage tags for Pearl Jam with Green Dot Bioplastic’s<br />

Terratek Flex (a biodegradable elastomer) and Terratek BD<br />

(a biodegradable bioplastic) and is eager to continue<br />

experimenting with different materials. Poischbeg’s<br />

enthusiasm parallels the prediction made by the European<br />

Bioplastics Association (source: Plastics Today) that<br />

biobased and biodegradable plastics will see an increase<br />

in global demand.<br />

Should injection molders experiment with<br />

bioplastics?<br />

While it is understandable why companies want to stick<br />

with established plastic materials, experimenting with new<br />

ones can be rewarding. Hal Alameddine, the President<br />

of Pike’s Peak Plastics (Colorado Springs,Colorado,<br />

USA), successfully worked with a Terratek Biocomposite<br />

composed of bio-based polyethylene derived from<br />

sugarcane and corncob fibers to develop Eco-Rigs for Begin<br />

Again Toys, which was licensed by John Deere. Alameddine<br />

said, “It’s a good material to run. We didn’t feel that we<br />

needed to make major adjustments to our current process<br />

with respect to running standard polyethylene. This one was<br />

a little trickier because of the addition of the corncob into<br />

it. But in general, I would say it ran as well as any other<br />

material.”<br />

Initial challenges are not uncommon. Reed Hardgrave,<br />

an injection molder at Ferguson Production (McPherson,<br />

Kansas, USA), initially experienced some difficulty with<br />

bioplastic resins expressing desirable end properties.<br />

However, he eventually found success with a wood plastic<br />

composite used to mold toys, replicating the aesthetics of<br />

wood.<br />

Technical considerations<br />

Injection molders who are apprehensive about the<br />

compatibility of bioplastics with existing equipment can be<br />

confident that most modern materials don’t require any<br />

inconvenient specifications.<br />

Kevin Godsey, an injection molder at Mid-Continent<br />

Tool and Molding, Inc. (North Kansas City, Missouri,<br />

USA), made compostable dog-waste dispensers with a<br />

starch-based elastomer. He emphasized that although<br />

a lower temperature profile was required for the heatsensitive<br />

elastomers, the adjustments weren’t beyond<br />

standard protocol. In fact, cycle times fell within the norm<br />

and even the drying times, which have been a pain point<br />

for injection molders, weren’t an inconvenience since he<br />

only had to account for surface moisture. Despite having<br />

initial challenges, Godsey stated that the material was still<br />

“moldable and very user friendly.”<br />

What are some of the benefits of working with<br />

bioplastics?<br />

Based off of the experiences of the injection molders the<br />

author spoke with, it is clear that the right bioplastic can<br />

be molded with minimal technical issues. Hence, it could<br />

be productive for injection molders to at least experiment<br />

with different bioplastic resins so they can determine for<br />

themselves if the materials are in fact user friendly.<br />

24 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


Polyurethanes/Elastomers<br />

By:<br />

Kevin Ireland<br />

Communications Manager<br />

Green Dot Bioplastics<br />

Cottonwood Falls, Kansas, USA<br />

Injection molders should think about<br />

experimenting and potentially working with<br />

bioplastics because:<br />

• Most modern bioplastics can be seamlessly incorporated<br />

into the injection molding process and no additional<br />

equipment is needed to accommodate the materials.<br />

• They could diversify options for their customers,<br />

especially since Grand View Research (San Francisco,<br />

California, USA) found that bioplastics are projected<br />

to control 5 % market share of the plastics industry by<br />

2020.<br />

• Bioplastics provide customers with unique advertising<br />

opportunities since many materials offer unique<br />

performance properties and – in addition – sustainability<br />

advantages.<br />

Small learning curve<br />

Although most bioplastics are compatible with existing<br />

molding equipment and processes, injection molders still<br />

need to experiment with different materials to figure out<br />

technical details such as cycle and drying times. Of course,<br />

this means the initial stages won’t be perfect.<br />

However, each of the interviewed injection molders<br />

emphasized that the learning curve was not steep and that<br />

they were ultimately able to run the materials with minimal<br />

hitches. For example, Godsey noted that scrap rates were<br />

somewhat high at the initial stages but quickly got them<br />

back within a standard ratio. When we asked Hardgrave<br />

if he had issues integrating bioplastics into his current<br />

operation, he noted that “venting is a big one. If [bioplastics]<br />

don’t vent, plating can become blackened.” Ultimately,<br />

Hardgrave was able to overcome his venting challenge and<br />

made accommodations for it whenever he was working with<br />

bioplastics.<br />

Injection molders can now confidently experiment and<br />

eventually work with many different bioplastics and many<br />

are optimistic about the demand of the materials in the<br />

coming years.<br />

www.greendotbioplastics.com<br />

Photo: Courtesy BeginAgain<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 25


Polyurethanes / Elastomers<br />

Sugar for extra grip<br />

Kuraray unveils biobased elastomer Septon Bio<br />

Fig. 1: Getting a grip: The new<br />

copolymer Septon Bio from<br />

Kuraray displays high grip and<br />

non-slip properties on wet and dry<br />

surfaces.<br />

Kuraray Europe (Hattersheim, Germany) is unveiling<br />

Septon TM Bio, its new bio-based thermoplastic elastomer.<br />

The hydrogenated styrene farnesene block copolymer<br />

(HSFC) is the outcome of collaboration between specialty<br />

chemicals producer Kuraray and bio-science company<br />

Amyris (Emeryville, California, USA). Septon Bio can be used<br />

in a multitude of applications, needs only small quantities of<br />

plasticizer, and is particularly easy to process thanks to its<br />

special properties.<br />

Cycle handlebar grips have to provide a firm handhold,<br />

nonwoven fabrics have to be elastic, and sports shoes have to be<br />

effective in absorbing impact. Special thermoplastic elastomers<br />

(TPEs) make these properties possible. They are put to use in<br />

a variety of applications such as fibers, composite materials<br />

and coatings and have to be highly elastic, and tear- and heatresistant.<br />

International specialty chemicals manufacturer<br />

Kuraray has developed its Septon TPE series for this purpose. The<br />

hydrogenated styrene di- and triblock copolymers with their high<br />

flowability are easy to process and highly elastic and are used as<br />

the basic polymers for a broad variety of products and for polymer<br />

modification. Kuraray is now presenting Septon Bio, a TPE that is<br />

bio-based while exhibiting the wide-ranging benefits of the Septon<br />

series.<br />

Kuraray has developed the new Septon Bio TPE in cooperation<br />

with US bio-science company Amyris. The copolymer is based on<br />

beta-farnesene, a renewable monomer from Amyris derived from<br />

biological raw materials. “During fermentation, special strains<br />

of yeast convert sources of sugar such as sugarcane into betafarnesene,”<br />

explains Jan-Sebastian Weber, Marketing and Sales<br />

Manager at Kuraray. “The hydrogenated styrene farnesene block<br />

copolymer (HSFC) is then produced from the beta-farnesene.”<br />

After polymerization, the farnesene has a special chemical<br />

structure.<br />

More Flexible, More Elastic and Easier to Process<br />

than HSBC<br />

Thanks to its characteristic structure, HSFC has unique<br />

properties and hence distinct advantages over conventional<br />

hydrogenated styrene block copolymers (HSBC). HSFC Septon Bio<br />

has a lower viscosity than conventional styrene block copolymers<br />

and at the same time a high loss factor (tan delta) over a large<br />

temperature range. Septon Bio therefore shows much better flow<br />

behavior than comparable copolymers. In addition, Septon Bio has<br />

very good adhesive properties, again over a broad temperature<br />

range. The new copolymer is thus easy to process and suitable for<br />

numerous applications in a wide-range of sectors.<br />

• Septon Bio facilitates outstanding grip in wet and dry<br />

conditions. This makes the copolymer an excellent choice<br />

for sports and household articles, footwear and industrial<br />

applications.<br />

• Septon Bio is extra-elastic and features low tensile strength.<br />

In addition, it has an extremely low compression set and<br />

thus deforms very little even after long-term exposure to<br />

compression. This makes the copolymer highly compatible<br />

with such processes as melt-spinning for nonwoven fabrics<br />

and extrusion for elastic films.<br />

• Septon Bio can be released easily and without residues – ideal<br />

for use in protective films.<br />

• Its particularly high damping effect is<br />

exhibited over a broad temperature<br />

range. This makes Septon Bio the ideal<br />

raw material for products in which sound<br />

or vibration absorption is important, such<br />

as in sports shoes.<br />

• At the same time, HSFC Septon Bio is<br />

much less rigid than HSBC polymers.<br />

Consequently, less plasticizer is necessary in<br />

the processing of Septon Bio. This prevents<br />

oil migrating to the product surface (oil<br />

bleeding). The original rigidity and non-slip<br />

properties of products containing Septon Bio<br />

are retained in the long term.<br />

Thanks to its extensive positive characteristics, Septon Bio<br />

can be used in a large variety of areas, such as in adhesives and<br />

composites, sealants, gels, foams, films, fibers and nonwoven<br />

fabrics as well as in applications calling for high grip. MT<br />

www.kuraray.eu<br />

Fig. 3:<br />

Renewable<br />

raw materials:<br />

The biological<br />

component<br />

of the new<br />

copolymer<br />

Septon Bio –<br />

beta-farnesene<br />

from Amyris<br />

– is produced<br />

from sugar<br />

sources such<br />

as sugarcane.<br />

400%<br />

350%<br />

300%<br />

250%<br />

200%<br />

150%<br />

100%<br />

50%<br />

0%<br />

Hardness<br />

MFR<br />

Active site<br />

PSt<br />

SEPTON Bio-series (HSFC)<br />

Elongation<br />

Permanent Set<br />

Sugarcane<br />

ϐ - Farnesene<br />

Poly (ϐ - Farnesene)<br />

Compression Set @ RT<br />

Rebound resilience<br />

Fig. 2: Sticking tight:<br />

Septon Bio, the new<br />

bio-based copolymer<br />

from Kuraray, has<br />

very good adhesive<br />

properties and is<br />

therefore ideal<br />

for adhesives and<br />

composites.<br />

Fig. 4: Versatile: Septon Bio, the new bio-based styrene farnesene<br />

block copolymer (HSFC) from Kuraray, has numerous advantages<br />

over conventional styrene block copolymers (HSBC), such as very low<br />

compression set and low rigidity.<br />

SEPTON Bio-series (HSFC)<br />

Coefficient of static friction (Dry)<br />

Coefficient of static friction (Wet)<br />

PSt<br />

26 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


Processing<br />

Optimize processability<br />

of bioplastics<br />

Working closely with sustainability partner, Dynisco,<br />

(Franklin, Massachusetts, USA,) Glycon Corp. (Tecumseh,<br />

Michigan, USA,) has incorporated Dynisco’s<br />

breakthrough technology in analytical instrumentation<br />

known as the Dynisco ViscoIndicator Online Rheometer into<br />

their screw design protocol. The ViscoIndicator provides<br />

continuous measurements of melt flow rates, apparent<br />

viscosity or intrinsic viscosity directly on the Glycon lab extruder.<br />

Dynisco aims to provide a window into the process<br />

for processors of all sizes in order to simplify rheology and<br />

improve quality and profitability. Glycon is maximizing this<br />

information by utilizing it in their screw design protocol to<br />

determine the best type of screw to run any bioplastic, composite,<br />

or blend of materials, as well as to determine the<br />

specific geometry and flight configuration of the feedscrew.<br />

Glycon has been designing feedscrews for the plastics<br />

processing industry for over 40 years. Whether the process is<br />

extrusion, injection molding or blow molding, the feedscrew<br />

design has a major effect on the quality and quantity of the<br />

end product being produced.<br />

As more bioplastics that have a favorable impact on the<br />

environment are introduced, key factors in their acceptability<br />

by manufacturers will be cost and processability. With<br />

accurate rheological data on the material, whether it be<br />

virgin material in pellet form, a blend of virgin or re-grind,<br />

a composite of plant based and recycled or even recovered<br />

ocean plastics, accurate rheological data, combined with<br />

Glycon’s experience and state-of-the-art instrumentation in<br />

their Innovation Lab, will provide the critical link to maximize<br />

output rates, provide a homogeneous mix and deliver a high<br />

quality melt on the new polymers being introduced.<br />

Protocol for developing Bio-Screw ® designs<br />

1. Obtain and review material data sheets.<br />

2. Analyze and determine material form and bulk density.<br />

3. Establish processing goals and objectives.<br />

- desired output rate<br />

- discharge pressure<br />

- discharge melt temperature<br />

4. Select processing conditions based on processing<br />

goals.<br />

- screw speeds<br />

- feeding rate- barrel temperatures<br />

5. Select screw type and geometry.<br />

- conventionally flighted metering screw<br />

- barrier screw<br />

- distributive mix/melt screw<br />

- grooved or smooth feed<br />

- mixers required<br />

6. Run material(s) monitoring:<br />

- temperature<br />

- pressure<br />

- apparent/intrinsic viscosity<br />

- melt flow rate<br />

- shear rate<br />

- viscosity at different shear rates<br />

- shear sensitivity<br />

7. If more than one material is tested, run a comparative<br />

analysis.<br />

8. Optimize performance:<br />

- adjust temperature profile<br />

- adjust head pressure<br />

- adjust screw speed<br />

- change/modify feedscrew<br />

9. Prepare a detailed report on the test including:<br />

- number of trials<br />

- temperatures and screw speeds<br />

- horsepower<br />

- lb or kg/hr/rpm<br />

- torque<br />

- energy consumption<br />

- melt quality<br />

10. Generate a screw design recommendation.<br />

The Innovation Lab, equipped with Dynisco’s ViscoIndicator,<br />

gives Glycon state-of-the-art capability specifically targeted<br />

at sustainable materials and the circular economy. With live<br />

streaming available, material tests can be viewed around<br />

the globe in real time. MT<br />

www.glycon.com<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 27


Material News<br />

New water soluble film<br />

As a result of its customer focused research and development,<br />

Mondi’s technical films business has<br />

created and introduced a water soluble film for the<br />

smart and convenient packing and dosing of powders, tabs<br />

and granulates. Dissolving completely in water, the film is<br />

ideal for single doses of dry materials, such as dishwasher<br />

and laundry tabs or bath salts. The water soluble film is an<br />

example how customers benefit from Mondi’s synergized<br />

research and development strategies having its core competencies<br />

in areas such as plastic films, packaging, paper<br />

and coating brought together under one roof.<br />

The film offers excellent sealing and deep drawing<br />

properties, provides an effective barrier to oxygen and is<br />

completely soluble even in cold water. Consumers are also<br />

protected from direct contact with the contents, which<br />

adds an extra layer of safety. Customers can bolster their<br />

sustainable credentials too, through the environmental<br />

benefits water soluble films provide compared to standard<br />

plastic films. In addition to reducing overall packaging<br />

waste, the films are also considered to be biodegradable,<br />

non-toxic and non-inhibitory.<br />

Oliver Sperber, Chief Innovation Officer at Mondi<br />

Consumer Packaging (Gronau, Germany), comments:<br />

“Mondi’s water soluble film provides several layers of<br />

benefits for both brands and their customers alike. Our<br />

committed application engineers are able to customise the<br />

film according to customers’ specific needs, in addition to<br />

providing all of the necessary on-site support required to<br />

successfully launch a product using this material. Mondi’s<br />

pedigree as a packaging provider, with a broad portfolio<br />

across many industries, means new product possibilities<br />

are being presented on an ongoing basis. Interplay between<br />

central and local R&D and Innovation teams, in partnership<br />

with our customers even on-site if required, is key to this.”<br />

One such collaboration relates to flow pack film tabs for<br />

dishwashing applications. Through a collaborative effort<br />

between the customer and Mondi’s R&D and Innovation<br />

teams, packaging innovation is brought to the next level.<br />

This is made possible through specialist teams combining<br />

market-specific knowledge and their ability to develop<br />

the ideas that result from this process, coupled with the<br />

fact that on-site support can be provided from conception<br />

through to completion of a project.<br />

While Mondi’s water soluble films are particularly<br />

suited to the home and personal care market, a number<br />

of applications in other sectors are continuing to emerge.<br />

Agrochemical packaging, for fertilizer, sowing and<br />

disinfectants, for example, is a major area of interest, as is<br />

the building and construction sector – where the films can<br />

be used as liner for bags in the cement industry. MT<br />

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28 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


Tel: (852) 2811 8897 (Hong Kong) Email: chinaplas.PR@adsale.com.hk Adsale Plastics Website: www.AdsaleCPRJ.com Adsale Group: www.adsale.com.hk<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 29


Materials<br />

Biobased adhesives:<br />

Requirements and perspective<br />

By:<br />

Horst Beck and Andreas Taden<br />

Henkel - Adhesive Research / Bio-Renewables Platform<br />

Düsseldorf, Germany<br />

Biobased adhesives literally constitute an ancient material<br />

class. Already 200.000 years ago Neanderthals<br />

identified birch pitch as valuable adhesive material,<br />

which can be obtained from the bark via pyrolysis under the<br />

absence of oxygen – a non-obvious and quite sophisticated<br />

technological process [1]. Being liquid at higher temperatures<br />

it solidifies under ambient conditions and was eventually<br />

used throughout the ages (stone and metal ages)<br />

as hotmelt glue to fasten arrowheads or metal tools onto<br />

wooden shafts (Figure 1).<br />

In the more recent Sumerian and Egyptian history<br />

animal-based proteins – especially animal skin, blood<br />

(Albumin), fish glues from air bladders and casein from<br />

milk – and starch-based binders appeared as the first<br />

truly industrial adhesives produced on larger scale.<br />

However, during the 20 th century biobased adhesives lost<br />

their predominant importance, which is closely related to<br />

the scientific progress in synthetic polymer chemistry and<br />

the development of phenolic resins, epoxides, acrylics,<br />

polyurethanes, silicones, etc. Numerous fossil-based<br />

high performance adhesives, typically designed and<br />

optimized for one specific application with an individual<br />

set of requirements, eventually replaced most biobased<br />

systems. Apart from pure performance considerations the<br />

steadier and hence more calculable raw material quality<br />

and cost of supply of synthetic fossil-based compounds<br />

did foster this development over the last decades. On the<br />

contrary, recent progress in biotechnology enables the<br />

green production of bio-renewable platform chemicals and<br />

specific design of functional proteins & peptides, which is<br />

expected to significantly impact adhesive development and<br />

create numerous new possibilities and applications. In this<br />

context this contribution aims to discuss the requirements<br />

and perspective of biobased adhesives in our modern world.<br />

Hurdles and drivers<br />

Recently biobased adhesives regained a lot of attention.<br />

As most obvious driver increased sustainability might<br />

appear, i.e. the content of renewable carbon. However, this<br />

one-dimensional perspective has too many shortcomings<br />

and cannot substitute a comprehensive life cycle analysis<br />

survey. Renewable carbon content is not interchangeable<br />

with reduced carbon dioxide footprint, and neither are<br />

biobased components necessarily biodegradable materials<br />

or less dangerous in terms of safety & health. With respect<br />

to the above mentioned advantages of synthetic adhesives,<br />

the regained focus on biobased adhesives can only be put<br />

into perspective and justified considering a larger context<br />

of requirements in our modern world. Furthermore the<br />

current regulations and trends in chemistry, like costintensive<br />

registration of new chemicals (REACH, TSCA, etc.)<br />

or the anticipated long-term price stability of crude oil, are<br />

opposing to ongoing biobased research efforts. Additional<br />

issues are insecure availability and potential food to fuel<br />

dilemma of biorenewables.<br />

Initially the drop-in approach, which simply involves the<br />

one-to-one replacement of petro-based molecules with<br />

otherwise chemically identical biobased substances, was<br />

seen as fast track methodology towards a more sustainable<br />

value chain. Unfortunately significant market shares were<br />

never achieved, mainly due to higher cost levels [2]. Two<br />

further aspects have to be considered in this context: 1.) In<br />

order to make a meaningful market claim, the composition<br />

of the complete formulation should be close to 100 %<br />

biobased content. 2.) The customer awareness for biobased<br />

adhesives is relatively low, especially when the adhesive<br />

remains a rather invisible part of the finished product,<br />

like in cars, handheld devices, etc. An additional hurdle<br />

for biobased adhesives is the relatively small market size<br />

and the different technological requirements compared<br />

to plastics, which leads many bio-related companies to<br />

focus on high molecular weight polymers as thermoplastic<br />

materials for construction, transportation or packaging. In<br />

contrast to that adhesive formulations are typically based<br />

on low molecular weight (reactive) precursors which are<br />

liquid or enable a low melt viscosity as starting point for<br />

the consecutive setting process (curing reaction). As a<br />

consequence the availability of biobased raw materials<br />

which are suited or even especially designed for adhesives<br />

so far remains limited.<br />

Performance as key contribution<br />

In some niche areas bio-polymer adhesives escaped their<br />

replacement by petro-based materials because of a very<br />

good fit to the requirements, selected examples include<br />

starches as adhesive in the manufacturing of corrugated<br />

paper boards, cellulose- and starch ethers for wallpaper<br />

glues or rheology modifiers in cement-based formulations<br />

and casein as bottle-labelling adhesive with fast setting<br />

behavior even on wet and cold bottles. It seems that within<br />

this complex framework of requirements and constraints<br />

(see “hurdles and drivers”) the terms for the development<br />

30 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


Materials<br />

Figure 1: Arrowhead mounted onto a wooden shaft supported<br />

by birch pitch as “Neanderthal hotmelt adhesive”. This biobased<br />

glue was used throughout the ages for ca. 200.000 years. The<br />

picture shows is a replica made by Henkel Adhesive Research<br />

of new biobased adhesives are surprisingly clear – simple<br />

drop-in alternatives cannot prevail, and the key to success<br />

can only be significantly increased performance benefits<br />

originating from novel low to medium molecular weight<br />

species.<br />

Unfortunately, as stressed out above and closing the<br />

loop to the introduction, most biobased adhesives became<br />

substituted due to a lack of performance compared to<br />

synthetic polymer systems. However, the amazing ability<br />

of Mother Nature to undergo strong and sometimes<br />

highly specific bonding under ambient conditions was not<br />

recognized and valued adequately, mainly due to the absence<br />

of modern analytical capabilities. Furthermore, industrial<br />

or so-called white biotechnology was basically unknown<br />

for the synthesis of biobased platform chemicals. Today<br />

more attention is paid to safety, health and environment<br />

(SHE), e.g. reduction or elimination of undesired volatile<br />

organic compounds (VOC) like organic solvents or residual<br />

monomers, and adhesive performance becomes evaluated<br />

in a more comprehensive manner, including sustainability<br />

and life circle analysis supplementing the well-established<br />

purely application dependent technical specifications.<br />

In order to achieve new performance levels in the various<br />

dimensions interdisciplinary thinking is required, which lead<br />

to the employment of biotechnological synthesis methods<br />

for novel raw materials, the development of hybrid systems<br />

and biomimetic binders. As will be explained the unique<br />

synthesis and interaction capabilities found in nature<br />

enable new-to-the-word systems with unprecedented<br />

property combinations. In the following selected examples<br />

will be briefly introduced.<br />

Novel platform chemicals via biotechnology<br />

Biotechnology is known to humankind for thousands of<br />

years, but only in the late 20 th and early 21 st centuries it<br />

developed in a thriving discipline with previously unmatched<br />

synthetic possibilities supported by genomics and<br />

recombinant gene design. White biotechnology works by<br />

engineering living cells into micro-factories that — by using<br />

sugars, starches or even lignocellulosic-based biomass<br />

as a feedstock rather than traditional petrochemicals —<br />

produce valuable products via fermentation that can<br />

function as stand-alone products (e.g. enzymes, fuels)<br />

or serve as platform chemicals for further downstream<br />

processing.<br />

In 2004 the DOE (US Department of Energy) [3] published<br />

an overview about so-called platform chemicals based<br />

on the vision of an expert panel. This vision identified<br />

already a detailed view how those platform chemicals<br />

could be transferred via a complete value chain to end<br />

(consumer) products. Recently the European Commission<br />

published a report which provides an assessment of the<br />

technology development status and market size for the<br />

most important platform chemicals, which consists mainly<br />

– but not exclusively – out of hydroxyl- or carboxylicfunctionalized<br />

molecules [4]. Typical examples are bioderived<br />

1,4-butanediol (BDO), succinic acid, adipic acid or<br />

2,5-Furandicarboxylic acid (FDCA). The progress in this<br />

new area of biotechnological derived raw materials is very<br />

dynamic and especially the development and upscaling<br />

of further downstream derivatives is an ongoing process.<br />

Consequently certain biobased platform chemicals with<br />

high potential for adhesive applications and/or polymer<br />

chemistry in general are not yet available on a commercial<br />

scale. Furthermore the value proposition for each of<br />

these components can be quite different, ranging from<br />

predominately cost-driven considerations (e.g. for BDO or<br />

succinic adid, which are at least cost-competitive compared<br />

to their petrol-based analogues) to unique chemical and/<br />

or physical characteristics. Following the scope of this<br />

contribution, trans-β-farnesene belongs to the latter<br />

category and is particularly interesting for adhesive<br />

applications [5]. It´s a branched chain alkene which shall<br />

be exemplary discussed as modem biotechnological<br />

platform chemical with no identical fossil based substitute<br />

and hence new-to-the-world performance characteristics.<br />

Farnesene can be used as fragrance, cosmetic emollient<br />

or fuel, and with respect to polymers and adhesives it´s<br />

particularly valuable due to its similar reactivity compared<br />

to (gaseous) butadiene, which constitutes the main<br />

raw material for synthetic rubber. However, due to its<br />

higher molecular weight Farnesene is a liquid monomer,<br />

which substantially simplifies the rubber polymerization<br />

process and the related reactor design. Farnesene can be<br />

polymerized via free racial, cationic or anionic pathways —<br />

the latter process enables highly defined bottle-brush<br />

Poly(trans-β-farnesene) polyols. This particular backbone<br />

structure provides low tendency for entanglements and<br />

hence drastically altered viscoelastic properties, i.e. greatly<br />

reduced viscosity compared to polybutadiene systems of<br />

similar molecular weight [7]. Polyfarnesene<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 31


Materials<br />

polyols therefore offer novel opportunities in<br />

polyurethane chemistry, e.g. high performing liquid applied<br />

optical clear adhesives (LOCA) as important technology<br />

enabler for handheld devices, optical displays, lightning<br />

applications, etc.<br />

Biconjugates/ biomimetic systems<br />

Apart from the synthesis of novel platform chemicals<br />

modern biotechnology is well known for the production of<br />

proteins and peptides with tailored amino acid sequence.<br />

Astonishing properties, like extreme selectivity (chemical<br />

site-recognition), stimuli-responsiveness or catalytic<br />

reactivity, can be obtained and explained by their complex<br />

hierarchical structure. The industrially most proliferated<br />

examples are enzymes, e.g. certain proteases that serve<br />

as key performance ingredients for detergents and<br />

cleaners, which are produced on large industrial scale.<br />

Furthermore so-called “adhesive peptides”, characterized<br />

either by almost universally strong interaction or — quite<br />

contrary — highly substrate-specific binding interaction,<br />

have been recently identified [7]. Consequently, our<br />

current research aims to utilize adhesive peptides as<br />

advanced adhesion promoters for the development of<br />

1.) high-performing universal glues for a large variety of<br />

substrates, ranging from metals, ceramics to low-energy<br />

plastic surfaces and 2.) highly substrate selective, selfdifferentiating<br />

adhesives, that for example will only interact<br />

with one special metal alloy while neglecting other metal<br />

compositions. Despite of significant research efforts<br />

over the last decades such adhesion characteristics are<br />

so far unknown and can be seen as an emerging area of<br />

materials science. Over the last few years, bioconjugates<br />

(apart from other biomimetic systems) gained increased<br />

interest as novel class of macromolecules and advanced<br />

approach of joining specific and outstanding biological<br />

interaction capabilities with well-established polymeric<br />

advantages (processability, high strength, flexibility,<br />

chemical resistance, hydrolytic stability, scale-up, costs,<br />

etc.). Certain bioconjugation techniques are already wellknown,<br />

like PEGylating peptide or protein drugs to improve<br />

stability, solubility and immunogenicity. However, apart<br />

from life science the concept of bioconjugation has not<br />

yet developed into a mature technology with significant<br />

commercial success. Despite the prospects of innovative<br />

materials with disruptive performance characteristics<br />

and hence tremendous market differentiation intense<br />

research efforts are still required to understand and adjust<br />

the complex interactions of the individual segments. Last<br />

but not least highly efficient, selective, facile and scalable<br />

synthesis procedures are required to reduce the associated<br />

costs of bioconjugation for industrial applications like<br />

coatings, adhesives and sealants.<br />

In summary, novel advanced biobased adhesives with<br />

unique property combinations are an emerging technology<br />

with tremendous potential for future applications.<br />

Although technologically visionary they their development<br />

follows scientifically sound and clear targets. The overall<br />

requirements and perspective is likely to accompany<br />

numerous researchers over many years to follow, maybe<br />

even for generations, but shows in an impressive manner<br />

the way forward and technological possibilities of biobased<br />

adhesives in our modern world.<br />

www.henkel.com<br />

References<br />

[1] P. Kozowyk, M. Soressi, D. Pomstra, G. Langejans. „Experimental<br />

methods for the Palaeolithic dry distillation of birch bark:<br />

implications for the origin and development of Neandertal adhesive<br />

technology.“ Scientific Reports, <strong>2017</strong>: 8033.<br />

[2]M. Carus, Nova-Institut. „Biobased Building Blocks and Polymers.“<br />

Biobased Materials Cologne. Cologne, <strong>2017</strong>.<br />

[3] T. Werpy, G. Petersen. Top value added Chemicals from Biomass.<br />

2004. http://www.pnl.gov/main/publications/external/technical_<br />

reports/PNNL-14808.pdf.<br />

[4] E4Tech, RE-CORD, WUR. „From the sugar platform to biofuels and<br />

biochemicals .“ Final report for the European Commission, 2015.<br />

[5] C. Halfmann, L. Gu, W. Gibbons, R. Zhou. „Genetically engineering<br />

cyanobacteria to convert CO2, water, and light into the long-chain<br />

hydrocarbon farnesene.“ Applied Microbiology and Biotechnology,<br />

Volume 98, <strong>Issue</strong> 23, 2014: 9869.<br />

[6] T. Yoo, S. K. Henning. „SYNTHESIS AND CHARACTERIZATION<br />

OF FARNESENE-BASED POLYMERS.“ Rubber Chemistry and<br />

Technology, Volume 90, No. 2, <strong>2017</strong>: 308.<br />

[7] A. Taden, B. Veith, R. Breves, I. Schmidt, T. Weber. „Peptide that can<br />

be used in coating agents, adhesion promoters or adhesives for<br />

oxidic surfaces.“ EP2917740 B1, 4. Jan <strong>2017</strong>.<br />

32 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


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bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 33


From Science & Research<br />

PEF: an alternative<br />

with a future<br />

Within the European project EnzOx2 (New enzymatic<br />

oxidation/oxyfunctionalization technologies for<br />

added value bio-based products. BBI JU, European<br />

Union’s Horizon 2020 programme), research is being conducted<br />

on the development of new biochemical technologies<br />

based on the use of oxidative enzymes with the aim<br />

of providing innovative solutions in the production of some<br />

high added-value compounds from biomass compounds.<br />

This project has a huge interest, since the use of this kind<br />

of enzymes is practically unexplored at industrial level. The<br />

obtaining of these products entails different oxidation and<br />

oxyfunctionalization reactions catalysed by different types<br />

of fungal oxidoreductases (such as oxidases and peroxygenases).<br />

In this context, EnzOx2 plans to develop a 100 %<br />

enzymatic conversion of 5-hydroxymethylfurfural (HMF)<br />

or 5-methoxymethylfurfural (MMF) into diformylfuran and<br />

2,5-furandicarboxylic acid (FDCA), a plastic building-block<br />

to be used in substitution of terephthalic acid. Moreover, another<br />

research line of this project will focus on optimizing<br />

the selective hydroxylation of plant lipids (such as fatty acids,<br />

terpenes and steroids) with the aim of producing flavour<br />

and fragrance ingredients, as well as active pharmaceutical<br />

ingredients (API).<br />

Therefore, one of the working lines which AIMPLAS<br />

is working in is related to the synthesis of derivates of<br />

polyethylene furanoate (PEF). In order to carry out the<br />

polymerization of this family of compounds, one of the<br />

monomers derived from the biomass, in particular FDCA<br />

will be employed. These new bioplastics, derived from PEF,<br />

have many advantages and they could be good candidates<br />

for the replacement of fossil-based polymers, such as<br />

polyethylene terephthalate (PET) (figure 1). Some of the<br />

advantages of this type of biopolymer in comparison with<br />

PET are:<br />

• PEF has a 50 % lower carbon footprint compared to PET.<br />

• PEF has oxygen permeability values, carbon dioxide and<br />

water better than the values of PET.<br />

• When compared to the properties of PET, its polymer<br />

has a lower melting temperature, while the glass<br />

transition temperature is higher.<br />

• PEF can be processed in the same way and with the<br />

same equipment as PET.<br />

• Its recycling process is the same as for PET.<br />

Figure 2:<br />

Technology used<br />

by Avantium [1]<br />

34 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


By:<br />

Alba Ortiz<br />

Researcher, Chemical Laboratory<br />

AIMPLAS, Valencia, Spain<br />

From Science & Research<br />

Since 2005, the company Avantium has developed a<br />

patented technology (YXY technology) to produce bio-based<br />

polymers: PEF from different sources, such as plants,<br />

grain, lignocellulose (wood) and even wastes like paper or<br />

agricultural residues.<br />

The main advantages of the EnzOx2 biochemical<br />

technology (which uses oxidases and/or peroxygenases) for<br />

producing PEF are the following:<br />

• The reaction conditions for obtaining this compound<br />

are softer, which entails an important decrease in the<br />

manufacturing costs.<br />

• Due to the high selectivity of the biochemical<br />

technology used, the number of byproducts, such as<br />

monofunctional monomers, is diminished.<br />

• AIMPLAS will develop the synthesis of compounds<br />

derived from PEF, so the influence of these<br />

modifications in the final properties could be assessed<br />

(figure 3).<br />

For that reason, during the three years duration of the<br />

EnzOx2 project, twelve participants from five European<br />

countries will work on the production of high added-value<br />

products from plant biomass using enzymatic technologies.<br />

References:<br />

[1] www.avantium.com/yxy/yxy-technology/<br />

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Figure 1: PEF vs PET<br />

O<br />

O<br />

O<br />

O<br />

O<br />

n<br />

O<br />

O<br />

O<br />

O<br />

n<br />

polyethylene furanoate (PEF)<br />

polyethylene terephthalate (PET)<br />

Figure 3:<br />

PEF derivatives obtained by<br />

AIMPLAS within the<br />

European project EnzOx2<br />

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O<br />

O<br />

m<br />

O<br />

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bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 35


News From Science & Research<br />

Aconitic acid as a building block<br />

Scientists at the Austrian Centre of Industrial Biotechnology<br />

(acib) from Graz, Austria, succeeded in using the mold<br />

Aspergillus niger to produce aconitic acid – a new raw material<br />

and important building block (with three carboxylic acid<br />

groups) for the production of non-toxic bioplastics. Thereby,<br />

acib sets a further, important step in the manufacturing<br />

process of chemical compounds from renewable resources to<br />

end our dependence on fossil resources for the well-being of<br />

our planet.<br />

The most amazing innovations are still coming from mother<br />

nature: For example, molds are chemical specialists who can<br />

produce a number of products by fermentation from renewable<br />

raw materials, e.g. antibiotics, additives for detergents or<br />

acidulants for the food industry. They are very important for<br />

the industry, since - for more than 50 years - molds have been<br />

the main production vehicle of citric acid, which in its quantity<br />

is a prominent product for all kinds of applications. Therefore,<br />

acib scientists questioned if the black fungi can do even more<br />

than they would have expected.<br />

Old fungus, new tricks<br />

In cooperation with the Dutch University of Leiden, scientists<br />

at acib found a way to modify this fungus to produce another<br />

organic acid, namely aconitic acid. “We discovered a protein<br />

of another fungus, which is able to transport aconitic acid out<br />

from the mitochondria, the power house of the cell”, explains<br />

acib researcher and project manager Matthias Steiger. After<br />

insertion of this protein, Aspergillus niger produces the<br />

biochemical for the first time in a controlled bioprocess.<br />

The research results have been published in the prestigious<br />

scientific journal “Metabolic Engineering”.<br />

A further step for bio-based products<br />

So far, aconitic acid – which got its name by the eponymous<br />

plant Aconitum napellus – was isolated as a by-product of<br />

sugar-beet. In very small quantities it also occurs as part of<br />

the metabolism in the cells of every living organism, including<br />

humans. There, it allows the conversion of sugars and fats<br />

into energy. Thanks to this new production method, aconitic<br />

acid will be of particular interest and entails great potential<br />

for the chemical industry. “Esters of aconitic acid can e.g.<br />

serve as building blocks for the production of biopolymers<br />

and therefore have the ability to replace mineral oil based<br />

polymers. Furthermore, they are suitable as a non-toxic<br />

alternative for plasticizers, for the use as a wetting agent<br />

or as precursor for other chemicals”, explains Diethard<br />

Mattanovich, BOKU-professor and acib-key-researcher. It will<br />

take a few more years until the process will be ready for an<br />

industrial implementation. Nevertheless, the acid is attributed<br />

with great potential. Mattanovich: “This is an important<br />

milestone for the renewable production of chemical products<br />

in tomorrow’s bioeconomy in order to end the dependence on<br />

fossil fuels. MT www.acib.at<br />

Flexible barrier film<br />

Biodegradable flexible multilayer structures for<br />

medium-barrier food packaging<br />

The RECUBIO project, led by Plásticos Romero, Molina de<br />

Segura, Spain, has enabled the development medium-barrier<br />

biodegradable PLA-based packages for the food sector from<br />

complex structures.<br />

The manufacturer of blown film collaborated with AIMPLAS,<br />

a Plastics Technology Centre located in Valencia, Spain, on<br />

a project aimed at the production of sustainable packaging<br />

from complex structures. This project, called Recubio, ran for<br />

a period of 18 months and was funded by Spanish National<br />

Program for R&D Activities, CDTI (Centro para el Desarrollo<br />

Tecnológico Industrial).<br />

Multilayer packaging offers a host of advantages in terms<br />

of mechanical properties, sealability, gas barrier properties,<br />

as well as the packaging process, from which the packaged<br />

products benefit. In 2015, more than 440,000 tonnes of flexible<br />

plastic packages were used in Spain, according to the Spanish<br />

Statistical Office, the equivalent of a turnover of about one<br />

million euros.<br />

The problem is that this complex film is obtained by<br />

means of lamination processes with adhesives of different<br />

plastic films, so it is a mixture of materials with different<br />

origin, which is virtually impossible<br />

to recycle. Fortunately, over the<br />

past several years, interest in<br />

biodegradable materials in the<br />

packaging sector has grown. These<br />

materials can provide an alternative<br />

and sustainable end of life. Within<br />

the scope of the Recubio project,<br />

Plásticos Romero, worked to<br />

develop a sustainable alternative which is technically feasible<br />

and to find a solution for the current main limitation of<br />

biodegradable materials: the oxygen and water vapour barrier<br />

properties.<br />

In the Recubio project, a coating technology was applied to<br />

address this issue. A coating was applied to a biodegradable<br />

film to give it the required barrier properties. The final complex<br />

structure formed by this coated film that, was subsequently<br />

laminated with a three-layer structure providing rigidity and<br />

sealability to the final packaging, as well as protection to the<br />

barrier coating.<br />

The result is a complex final structure suitable for food<br />

packaging requiring medium barrier properties, such as<br />

bakery, fresh or frozen products. MT<br />

www.aimplas.es | www.plasticosromero.com<br />

36 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


News From Science & Research<br />

Application News<br />

From municipal waste<br />

to bioplastics<br />

Electric scooter from<br />

biobased materials<br />

The recently launched European URBIOFIN BBI-project<br />

will focus on converting the organic fraction of municipal<br />

solid waste on a semi-industrial scale. The project, that looks<br />

into the techno-economic and environmental feasibility will<br />

create chemical building blocks, biopolymers and/or additives<br />

using the biorefinery concept urban biorefinery. Ultimately,<br />

URBIOFIN offers a new feasible and more sustainable scenario<br />

alternative to the current treatment of the organic fraction of<br />

municipal solid waste. Wageningen Food & Biobased Research<br />

focuses on two specific topics in this project: the production<br />

of medium-chain length fatty acids and derived PHAs via<br />

microbial fermentation, and the scale-up, efficient extraction<br />

and novel commercial applications of these bioplastics.<br />

As a building block for high quality products, sustainable<br />

fatty acids have interesting market applications says Hans<br />

Mooibroek, project manager at Wageningen Food & Biobased<br />

Research. “‘In this project we are focusing on the conversion<br />

of fatty acids to PHAs. A key advantage of these microbial<br />

plastics is that they are produced from renewable resources<br />

and are completely bio-degradable. Our specific objective<br />

is to produce so-called medium chain length PHAs (mcl-<br />

PHAs), which are suitable for high value applications such<br />

as biodegradable agricultural plastics or biomaterials for the<br />

cosmetics industry.”<br />

Two-step fermentation process<br />

The production of PHAs occurs in stages, Mooibroek<br />

explains: “In the first step, we use short chain fatty acids<br />

from solid biomass and employ our intricate knowledge on<br />

fermentation technology. We put a yeast to work that converts<br />

the carbohydrates into longer chain fatty acids. We have a<br />

considerable track record on mcl-fatty acid production and<br />

mcl PHA-production using the yeast Cryptococcus curvatus<br />

and the soil bacterium Pseudomonas putida respectively. Both<br />

organisms grow well on a variety of agricultural side streams.<br />

In the URBIOFIN project both fermentation processes will be<br />

combined to produce mcl-PHAs efficiently.”<br />

Transferring knowledge to commercial partners<br />

URBIOFIN is a typical BBI demonstration project, Mooibroek<br />

explains: “We carry the technology that we develop in our lab<br />

on to partners who want to apply the process on an industrial<br />

scale. Together with our research partner AINIA from Valencia,<br />

which produces short chain fatty acids and PHAs from waste,<br />

we have recently visited another Spanish partner IRIAF/<br />

Clamber (providing upscaling services especially for research<br />

demo projects) to make sure that they have the knowledge<br />

and facilities for scaling up the fermentation and downstream<br />

processes.” Bringing the various PHAs to market is the task<br />

of commercial partners Stéfany Emballages Services (SES,<br />

France, packaging materials) and NaturePlast (France,<br />

supporting bioplastics applications development).<br />

The 16 project partners in URBIOFIN are located in eight<br />

European countries, with Spanish engineering company<br />

IMECAL coordinating the project. MT<br />

Sustainable mobility has been given a shot in the<br />

arm with the introduction of the Be.e. The Be.e is the<br />

first electric scooter that was designed, developed<br />

and manufactured, with structural parts made from<br />

biocomposites.<br />

The scooter was introduced in Amsterdam on<br />

September 12. And it has more going for it than<br />

its sustainability credentials alone: developed in<br />

collaboration with design studio Waarmakers, much<br />

time and creativity also went into its look& feel. The<br />

result is an alluring two-wheeler with distinctive lines<br />

and character, with attention for details such as handstitched<br />

saddles, available in vinyl or leather; or the<br />

integrated generously-sized windscreen, impregnated<br />

with a nano coating for outstanding wet-weather vision.<br />

The wide tires provide good grip and stability on uneven<br />

ground; LED lights, indicators and side running lights<br />

make sure you can see and be seen at all times.<br />

The Be.e has a body made of biocomposite, in this<br />

case, hemp fibres from Groningen in the norther part of<br />

the Netherlands in a matrix of partly biobased structure<br />

that at the same time is designed to perform. The drive<br />

train is top of the bill. The scooter features a 4kW motor<br />

(highest in its class) and a 2.5kWh Li-ion battery that<br />

comes with a 4 year or 1000 cycle guarantee, ensuring<br />

long range with more power and torque. The on-board<br />

charger completely recharges the battery in just 4<br />

hours; topping up in between is no problem.<br />

Range anxiety is a thing of the past: the display<br />

accurately shows the distance that can be travelled on<br />

the current battery charge.<br />

The Be.e also has a reverse gear, making it easy to<br />

manoeuvre under difficult conditions.<br />

The development of the Be.e was made possible by<br />

a successful crowdfunding campaign in 2015. Angel<br />

investors and the first launching customers provided an<br />

extra boost in realizing the first 8 Be.e scooters. These<br />

will be delivered and on the road in just a few weeks. MT<br />

ww.vaneko.com<br />

www.wur.eu/fermentationtechnology<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 37


Application AutomotiveNews<br />

Brazilian sugar now packaged in sugar-based<br />

Bio-PE<br />

Braskem’s Green Plastic will be used for the first time in<br />

packages of refined sugar in Brazil. Pioneering this use is<br />

Caravelas Sugar, one of the country’s most important companies<br />

in this segment.<br />

The Caravelas brand consumes 140 tonnes of packaging<br />

per month and is the first and, so far. the only one in the<br />

segment to have sugarcane in its production cycle from start<br />

to finish. Consumers will be able to identify the new packaging<br />

through the I’m green seal, visible on the product front,<br />

which is Braskem’s identifying mark for packaging made<br />

with Green Plastic.<br />

“Sustainability is an essential pillar in our company, especially<br />

due to the production process of our product, whereas<br />

innovation and pioneering are directly linked to the positioning<br />

of our brand: In Favor of Tasting What Is New. In this<br />

sense, Green Plastic is an important initiative that can effectively<br />

respond to all these demands, bringing important innovation<br />

to the entire segment”, says Javel Colombo, commercial<br />

director for the Colombo Plant, Caravelas Sugar’s<br />

producer.<br />

The new packaging is produced by Zaraplast, the leader in<br />

flexible packaging solutions, longtime partner of Caravelas.<br />

“As suppliers of flexible packaging 50 years ago, we have noticed<br />

that every day consumers are looking for products that<br />

offer more sustainable solutions; and managing to combine<br />

Braskem’s renewable raw material, our transformation expertise<br />

and Caravelas product was rewarding”, said Eli Kattan,<br />

director of Zaraplast.<br />

For Braskem, which constantly monitors the market, the<br />

launch is aligned with the company’s goal of finding solutions<br />

for its customers and improving people’s lives through<br />

chemistry and plastic. “There is a growing concern of companies<br />

in the adoption of innovative solutions with a lower<br />

environmental impact. Green Plastic is the material that fits<br />

the attributes that Caravelas seeks for its products: innovation<br />

and respect for the environment”, says Gustavo Sergi,<br />

Director of Renewable Chemicals at Braskem.<br />

Braskem’s Green Plastic is 100 % recyclable, captures<br />

and fixes 3.09 tonnes of CO 2<br />

from the atmosphere for each<br />

ton of resin of renewable origin produced, collaborating to<br />

reduce the emissions of greenhouse gases. The product<br />

also has the same characteristics of traditional polyethylene<br />

and can be recycled in the already existing chain. MT<br />

www.braskem.com<br />

Hot beverage cups<br />

Synbra Technology, Etten-Leur, The Netherlands, recently introduced a high heat biobased and biodegradable alternative<br />

for hot beverage cups and hot food packaging. In Asia for example hot noodle dishes are often served in foamed plastic bowls,<br />

even from vending machines.<br />

Synbra Technology has developed and patented a process to make such beverage cups and bowls using BioFoam ® , their PLA<br />

particle foam that can be processed on modified existing EPS moulding equipment. Thus this new cup and bowl application is<br />

an addition to the already established market of ice cream packaging and white goods production. The coffee and hot beverage<br />

and noodle cups that are heat resistant, yet biodegradable and can now be produced CO 2<br />

neutral.<br />

“Even after 48 hours the cups don’t not leak any coffee, which is surpassing the industry standard,” as Jan Noordegraaf,<br />

Managing Director of Synbra Technology points out.<br />

A myriad of bans loom for not using polystyrene for using beverages packaging. Polystyrene particle<br />

foam is the most used material to make drinking cups, and despite its good recyclability it is getting<br />

under pressure. In Malaysia all EPS and plastic foam packs are banned and there is a demand for<br />

biodegradable alternatives. In the state of California, a new bill aims to ban Styrofoam throughout<br />

the state for applications such as disposable foodservice cups, plates, and containers. This new<br />

development opens up a market for alternatives for compostable disposables. MT<br />

www.synbra-technology.nl<br />

38 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


Application Automotive News<br />

Barrier lidding<br />

Italian flexible packaging converter, Corapack (Brenna,<br />

Italy), has used Futamura’s renewable and compostable<br />

NatureFlex cellulose films for compostable lidding for<br />

trays. The lidding material is a proven compostable structure<br />

that is an ideal alternative to conventional plastics that often<br />

end up in landfill.<br />

To supply the best technical solution and functionality<br />

the high barrier NatureFlex film is laminated to an internal<br />

sealing bio-polymer so that the final structure, certified<br />

compostable, can be heat sealed to compostable base trays<br />

made from bio-polymers or wood pulp.<br />

NatureFlex films are produced from sustainable wood pulp<br />

harvested from managed plantations and are certified to both<br />

EU (EN13432) and US (ASTM D6400) composting standards.<br />

In addition to industrial composting, the product has reached<br />

the standard required for home composting. NatureFlex<br />

provides high barrier to moisture, aroma and gasses, has<br />

excellent transparency and high gloss; making it an ideal<br />

solution for a compostable lidding structure.<br />

Giorgio Berton, Futamura’s Italian regional sales manager,<br />

said: “This application is another great example of a successful collaboration where renewable and compostable NatureFlex<br />

films have been selected as a real alternative to conventional plastics; this means the brand owner can be happy that they are<br />

providing an environmen environmentally responsible solution without compromising on functionality”. MT<br />

www.futamuragroup.com<br />

Men’s skincare in<br />

Green PE tubes<br />

RPC M&H Plastics and Bulldog Skincare for Men have<br />

joined forces once again for Bulldog’s new line of skincare<br />

packaging, with a sustainable twist.<br />

The first men’s skincare brand in the world to use<br />

Braskem’s sugarcane based Green PE as a raw material,<br />

Bulldog have chosen to go green with their updated flexible<br />

tube line up, which features Moisturisers, Face Washes<br />

and Face Scrubs, with multiple variations of each product<br />

focusing on different skin types which includes sensitive<br />

skin, mature skin and oily skin.<br />

Simon Duffy, founder of Bulldog Skincare For Men says:<br />

“Bulldog is proud to be the first men’s skincare brand in the<br />

world to use plastic from sugarcane in our packaging. We<br />

have always tried to make the most ethical and sustainable<br />

decisions we can, from never testing on animals, to never<br />

using microbeads to making all our products suitable for<br />

vegetarians and vegans. Plastic from Sugar Cane is the<br />

latest step in this approach and we are delighted to have<br />

worked with M&H Plastics to<br />

turn Green PE into something we<br />

can use in the tubes and caps of<br />

our packaging.”MT<br />

www.rpc-group.com<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 39


Application News<br />

Bioplastic housing for<br />

grain mill<br />

Until recently, the housings<br />

of the high-quality corundumceramic<br />

stone grinders of<br />

Wolfgang Mock (Darmstadt,<br />

Germany) were made of wood.<br />

Mock grinders make up about<br />

70 % of all household mills sold and place the company<br />

prominently among European market leaders.<br />

The newest Mockmills come dressed in a Tecnaro<br />

housing, as announced in a recent press release<br />

dressed up in flowery words. Two models are encased<br />

in a stylish housing made of Tecnaro’s ARBOBLEND ® .<br />

Wolfgang Mock points out: “We have never used<br />

housing made of petroleum-based plastics for our<br />

mills.” It would not have suited the company philosophy.<br />

Now, the use of Tecnaro’s moulded wood also makes<br />

it easier to produce larger quantities of mills. The<br />

injection molding process allows for more streamlined,<br />

hence economical and faster production. This is how the<br />

Darmstadt-based family-run company is approaching<br />

the market, and the high-quality mills have received a<br />

warm welcome in markets across Europe and in the<br />

USA.<br />

The new Wolfgang Mock GmbH has the ambition to far<br />

exceed the 15,000 mills sold in one of the best years by<br />

his earlier company KoMo GmbH. And Wolfgang Mock<br />

is confident when he considers his decision to base his<br />

latest mills on the cooperation with Tecnaro. MT<br />

www.tecnaro.de | www.wolfgangmock.com<br />

Horticultural pots<br />

Using biopolymers for<br />

horticultural applications is<br />

something that makes eminent<br />

sense. At least, Growfun thinks<br />

so.<br />

Netherlands-based Growfun<br />

produces biodegradable<br />

horticultural pots from starchbased<br />

bio-based resin produced<br />

by Rodenburg Biopolymers in Oosterhout. Offering a<br />

sustainable alternative for fossil fuels, the company uses<br />

starch obtained from waste from the potato industry.<br />

According to Jan Blankestijn, managing director of Grofun,<br />

the company chose to collaborate with Rodenburg Biopolymers<br />

because of their expertise in that specific development area.<br />

“Based on their know-how, and in close collaboration with<br />

them we can develop a specific and high-quality product,” he<br />

said.<br />

Growfun is a flexible and innovative company that cooperates<br />

with customers and partners working with high-quality plastic<br />

products. The company invests considerable time and money<br />

in R & D, and, together with the University of Wageningen<br />

explores new technologies that they can apply to themes such<br />

as the circular economy.<br />

“Innovation plays a major role in both technology and design<br />

at Growfun, but only by investing continuously therein can we<br />

serve our customers quickly, expertly and professionally.”<br />

Growfun’s customers are national and international<br />

growers, exporters and retailers who demand a flexible,<br />

responsive supplier, for whom quality is an absolute given. MT<br />

www.growfun.nl<br />

Soybean oil enhances tire performance<br />

The Goodyear Tire & Rubber Company (Acron, Ohio, USA) is harvesting some unique seeds of innovation as it introduces a<br />

new tire technology with support from the United Soybean Board (USB).<br />

The first commercial use of a new soybean oil-based rubber compound is helping Goodyear enhance tire performance in<br />

dry, wet and winter conditions. A Goodyear team of scientists and engineers created a tread compound, or formulation, using<br />

soybean oil, which is naturally derived, cost-effective, carbon-neutral and renewable.<br />

“Goodyear’s legacy of innovation drives us to continue to apply new technology solutions,<br />

developing superior performing tires that meet consumer demands,” said Eric Mizner, Goodyear’s<br />

director of global materials science.<br />

By employing soybean oil in tires, Goodyear found a new way to help keep the rubber compound<br />

pliable in changing temperatures, a key performance achievement in maintaining and enhancing<br />

the vehicle’s grip on the road surface.<br />

Goodyear’s tests have shown rubber made with soybean oil mixes more easily in the silicareinforced<br />

compounds used in manufacturing certain tires. This also improves manufacturing<br />

efficiency and reduces energy consumption.<br />

Goodyear cooperated on the project with the USB, a group of farmer-directors who oversee the<br />

investments of a checkoff program on behalf of all U.S. soybean farmers. The USB provided some<br />

funding support for the development of Goodyear’s soybean oil application in tires.<br />

The commercialization of soybean oil in tires as the latest technology breakthrough by Goodyear<br />

builds on the company’s other recent innovations, such as the use of silica derived from rice husk<br />

ash. MT<br />

www.goodyear.com<br />

40 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


Application News<br />

Compostable meat tray for organic meat<br />

In collaboration with Promessa (Deventer, The<br />

Netherlands) several members of the supermarket<br />

chain SuperUnie (including Coop and Poiesz) as well<br />

as EkoPlaza will switch to completely compostable and<br />

renewable meat trays by Bio4Pack to package organic<br />

meat. The tray, transparent film, label and absorption pad<br />

will all be biobased and compostable according to<br />

EN 134342, as well as indistinguishable from traditional<br />

meat packaging.<br />

“This is the first meat tray in the entire world which is<br />

completely compostable in accordance with the strict<br />

EN-13432 norm,” says Patrick Gerritsen from Bio4Pack.<br />

“Therefore, the tray may be labelled with the Seedling<br />

logo and can be thrown in the bin for organic waste<br />

after use. The tray and film are made of PLA, which is<br />

made from sugar cane. The impact of these trays on the<br />

environment is considerably less than traditional trays, as<br />

the resources are renewable. This means that no fossil<br />

resources are used at all. The absorption pad is made of<br />

cellulose and the Bio4Life label, including glue and ink, is<br />

completely compostable as well.”<br />

Bio4Pack started development of this organic tray back<br />

in 20<strong>06</strong>, and managed to keep its costs only a fraction<br />

higher than those of a traditional plastic tray. “It was<br />

quite a challenge. PLA is more fragile than other types<br />

of plastic, which means you have to add approved impact<br />

additives to the mix. In addition, the material must have<br />

good barrier properties and the packaging should be able<br />

to be mechanically processed with ease. However, the<br />

green colour was the biggest hurdle,” according to Patrick<br />

Gerritsen.<br />

An added benefit for retailers is that they will have to pay<br />

virtually no packaging tax for them. MT<br />

www.bio4pack.com<br />

Organic soil<br />

conditioner bags<br />

The Montgomery County Department of Environmental<br />

Protection (DEP) has taken another step to protect the<br />

environment in Montgomery County (Maryland, USA) .<br />

DEP will partner with Braskem’s I’m Green polyethylene<br />

(PE) and ProAmpac’s Trinity Packaging Division to provide<br />

packaging for Leafgro ® , which is the County’s composted<br />

soil enrichment product. The new wrapping is a sustainable<br />

resource made from sugarcane.<br />

“I have made the commitment to improving the County’s<br />

environment a priority for my administration,” said County<br />

Executive Ike Leggett. “Adopting this more environmentallyresponsible<br />

packaging product reflects this commitment,<br />

as well demonstrating the County’s embrace of the<br />

Governor’s Sustainable Materials Management Policy,<br />

which seeks ‘an updated and more holistic materials<br />

management approach… to ensure continuous<br />

environmental improvement. I<br />

commend the Department of<br />

Environmental Protection and the<br />

Division of Solid Waste Services for<br />

their leadership in achieving this<br />

important accomplishment.”MT<br />

www2.montgomerycountymd.gov<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 41


Application News<br />

New TAPP water filter to be made from<br />

biodegradable PLA<br />

water in the shower. Following the success of both products,<br />

TAPP Water launched TAPP 2, a new version of its flagship<br />

product with a more elegant design and new features – a<br />

Bluetooth sensor - in October <strong>2017</strong>.<br />

“Integrated in the TAPP 2 is the first 100 % biodegradable<br />

filter on the market – globally,” said Magnus. Why a Bluetooth<br />

sensor? “Because, if people can follow the status of the filter<br />

on their phones, they become more engaged, and the impact<br />

is bigger,” Magnus pointed out. The sensor provides realtime<br />

data to a mobile device to track water consumption<br />

and battery life. The filter can calculate the consumption<br />

of water in real time and send an alert when the cartridge<br />

needs changing. “After the shelf life, about 3 months in an<br />

average household, the cartridge can be deposited in the<br />

recycling container of organic matter, without contaminating<br />

the environment with any kind of plastic waste,” he said.<br />

Complaints about the taste of tap water have fuelled the<br />

trend for consuming bottled water instead, leading in<br />

turn to the massive accumulation of waste plastic bottles.<br />

Now, a Barcelona company is combatting the problem at<br />

the source: the water tap at home.<br />

“I come from Sweden, and was used to drinking water<br />

from the tap that tasted good,” said Magnus Jern, founding<br />

partner of TAPP Water. “When I moved to Barcelona, I found<br />

that the water had an odour and tasted like chlorine. Instead<br />

of switching to bottled water, I decided it was time to do<br />

something about it.”<br />

Together with four other partners, he first extensively<br />

researched and analysed the situation, and found that only<br />

60 % of the population consume tap water in the Mediterranean<br />

corridor of Spain, especially in Barcelona. For two years, they<br />

also studied filtration technologies, consulting with experts<br />

in the field of water, from private companies, universities and<br />

water quality institutes.<br />

They also discovered that a good filter could eliminate the<br />

unpleasant taste and remove microplastics and the heavy<br />

metals leaching from old pipes – and TAPP Water was born.<br />

After testing more than 50 different filters and technologies,<br />

and conducting blind tests with hundreds of people, as<br />

well as installation tests and analysis of water institutes to<br />

ensure that filters have the highest quality standards, a new<br />

filtering system was developed that that is being touted as<br />

“revolutionary technology.”<br />

“What we discovered was that not much technological<br />

progress had been made over the last 30 years or so,” said<br />

Magnus. Mostly, activated carbon and carbon blocks were still<br />

being used.<br />

In June 2016, the company launched its first filtration<br />

product, TAPP 1, designed in Barcelona and manufactured in<br />

Taiwan. Six months later, the company went one step further<br />

and released TAPP 1s, the perfect solution for filtering the<br />

The organic coconut fibre filter integrated into TAPP 2<br />

eliminates the bad taste and odour of water, as well as<br />

chlorine, microplastics, agricultural chemicals, pesticides<br />

and other compounds that can remain in public water after<br />

sanitation, respecting those components that are beneficial<br />

to the body, such as magnesium or iron.<br />

Magnus said that TAPP Water managed to help consumers<br />

avoid purchasing 75,000 bottles of plastic waste in 2016.<br />

“Our aim is to raise this figure to 10 million plastic bottles by<br />

the end of <strong>2017</strong>, the equivalent of 50 football fields filled with<br />

1.5-liter bottles.”<br />

In addition to a thinner design,<br />

TAPP 2 is an improvement on its<br />

predecessor TAPP 1 as itadds a<br />

Bluetooth sensor BLE 4.0, which<br />

provides real-time data to a mobile<br />

device to track water consumption<br />

and battery life. The filter can<br />

calculate the consumption of water<br />

in real time and send a warning when it is necessary to<br />

change the cartridge. After the shelf life, about 3 months in<br />

an average household, the cartridge can be deposited in the<br />

recycling container of organic matter, without contaminating<br />

the environment with any kind of plastic waste.<br />

And the system saves money: “In Spain, the average price<br />

of bottled water per litre is around € 0.30, compared to<br />

the € 0.0023 that costs one litre of tap water in a city like<br />

London. Thus, filtered tap water is up to 130 times cheaper<br />

than bottled water.”<br />

And the latest news? “We are raising money via a<br />

crowdfunding campaign to launch a TAPP Water filter<br />

made of a specially formulated biodegradable, home<br />

compostable PLA, replacing the ABS it is now made of. So,<br />

we are an environmentally responsible product made of<br />

environmentally responsible material.” MT<br />

www.tappwater.co<br />

www.tappwater.co/crowdfunding<br />

42 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


Application News<br />

New milestone in biodegradability of coffee capsules<br />

Italy-based API, specialized in the production of<br />

thermoplastic elastomeric compounds and bioplastics and<br />

acquired by global materials company Trinseo in July <strong>2017</strong>,<br />

has announced it has broadened its portfolio of Apinat<br />

bioplastic materials for single-serve coffee capsules.<br />

In response to a growing consumer demand for<br />

compostable coffee capsules, API has now launched<br />

various new grades of biodegradable and compostable<br />

bioplastics, including thermoplastic elastomers TPE-E<br />

and TPC.<br />

Apinat bioplastics offer excellent mechanical and<br />

thermal characteristics during the brewing process and<br />

can easily substitute conventional plastics. The new grades<br />

are suitable both for injection moulding and continuous<br />

compression moulding.<br />

The new Apinat grades boast a renewable content of<br />

60 % up to over 90 % and comply with U.S. Food and Drug<br />

Administration and EU food contact regulations.<br />

The products are also in conformity with the<br />

biodegradability standards of the European Bioplastics<br />

Association and the scientifically recognized standards for<br />

the biodegradability and compostability of plastic products<br />

(EU 13432/EN 14995 and US ASTM D6400 standards).<br />

“Consumers are increasingly looking for eco-friendly<br />

solutions for their coffee machines,” said Aldo Zanetti,<br />

Business Unit Manager, API. “This innovation around<br />

APINAT Bioplastics reinforces API’s commitment to<br />

sustainability and environmental responsibility, offering<br />

coffee in compostable coffee capsules.”<br />

In 2016 alone, the industry still produced more than 35<br />

billion non-recyclable plastic coffee capsules worldwide.<br />

Experts expect an increase of 17 billion plastic capsules by<br />

the end of 2020. MT<br />

www.APIplastic.com<br />

| www.trinseo.com/API-Plastic.<br />

Introducing Sprig<br />

farm trucks<br />

Lightweight yet durable these chunky outdoor trucks<br />

are ready to roll for miles of adventures. These rugged<br />

preschool trucks are perfect for the backyard, beach, or<br />

living room and are made from plants instead of oil based<br />

plastic. The toys feature a new bio-plastic derived from<br />

sugar cane and upcycled corn cobs.<br />

These trucks are made from plants grown on farms.<br />

They even smell like toasted corn, yep toasted corn.<br />

The toys are made in Fort Collins, Colorado (USA) in<br />

collaboration with farmers, scientists, engineers, and US<br />

factories.<br />

However, the trucks and other toys are not available yet,<br />

as it is still a kickstarter project. If you want to support<br />

the idea, you can do<br />

so until December 16.<br />

Visit the kickstarter<br />

page via the link<br />

below. MT<br />

tinyurl.com/sprigbioplastic<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 43


Applications<br />

Automotive<br />

Hot<br />

compost bin<br />

Figure 1:<br />

Current hot bin and new stackable design for the hot bin.<br />

Figure 2:<br />

Foam cup (with paperclip) in a PE net, after 3 weeks was found<br />

to be totally composted.<br />

The hot compost bin was originally pioneered by DS<br />

Smith in the UK. It is made of EPP, a sturdy and insulating<br />

material that works much better than the<br />

poorly insulating PE used for conventional, rotomoulded<br />

bins.<br />

In cooperation with DS Smith, the Netherlands-based<br />

Synprodo, a subsidiary of Synbra Group has now introduced<br />

this hot bin concept to the continental European market.<br />

The aim is to realise the production of the hot bin in Europe,<br />

the USA, Japan and China, working with selected partners,<br />

who sign a franchise contract.<br />

The initial tests showed that the hot bin is ideal for<br />

disposing of cups and packaging made of BioFoam ® (cups<br />

cf. Application News p 38). BioFoam is certified according<br />

to the industrial composting standard EN 13432 and does<br />

not break down at room temperature. Yet in a hot bin, it was<br />

found to compost extremely fast. Cups were put in a PE<br />

net, to enable these to be identified, and added to an active<br />

and fully functioning hot bin, in which the temperature<br />

reached 60-70 °C due to the excellent insulating properties<br />

of the bin. Within three weeks, all the BioFoam cups were<br />

composted (see fig. 2). A Greeny ice cream container made<br />

of BioFoam was shown to have degraded in the same time,<br />

as well.<br />

BioFoam was not the only material that was found to<br />

compost. Thermoformed PLA parts made of NatureWorks’<br />

Ingeo 2003, as well as of Luminy ® LX175 from Total-<br />

Corbion and BioFlex ® 1130 from FKUR, all composted<br />

within three weeks. This shows that the composting<br />

as an end of life option can be accelerated for many<br />

bioplastics and that industrially compostable bioplastics<br />

have the potential to become home compostable with a<br />

simple device. As a result, bioplastics packaging waste<br />

does not have to leave the premises and will not mix with<br />

conventional plastics.<br />

An internet shippable stackable bin has been produced<br />

by Synprodo since the end of <strong>2017</strong> and can be tailor made<br />

in larger dimensions to suit the needs of sport clubs,<br />

canteens or schools, mixing food waste with bioplastics.<br />

Sport clubs or schools can convert their entire canteen<br />

waste stream to only using bioplastics. MT<br />

www.synbra-technology.nl<br />

44 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


Applications<br />

Race Tesla with bio-composites<br />

Electric GT and Bcomp reveal lightweight renewable natural fibre<br />

composite body panels and tease “secret weapon” LED display<br />

Electric GT (headquartered at Circuit Pau-Arnos, France),<br />

has announced its unique partnership with Swiss company<br />

Bcomp - manufacturers of high-performance<br />

lightweight composite materials to replace some traditional<br />

carbon fibre panels in the Electric GT racing car. Bcomp (Fribourg,<br />

Switzerland) has developed a proprietary high-performance<br />

lightweight material for the automotive industry, producing<br />

high-performance, cost-efficient materials that can<br />

replace or reinforce carbon fibre and other engineering materials,<br />

and cut up to 40 % weight with maintained performance.<br />

Its powerRibs ® - and ampliTex ® reinforcement fabrics<br />

have first been used within Bcomp’s initial Sports & Leisure<br />

markets, and can typically be found in products such as skis,<br />

snowboards, surfboards, canoes and guitars. In addition, the<br />

company has collaborated with the European Space Agency<br />

ESA on the development of lightweight space applications for<br />

several years.<br />

Working with Electric GT, Bcomp has also teased a<br />

revolutionary LED system within the natural fibres which can<br />

create a display for live data and telemetry on the outer body<br />

of the racing car.<br />

Bcomp revealed the new technology at the Electric GT<br />

headquarters at Circuit Pau-Arnos, where EGT’s sustainable<br />

credentials are put into action from the ground up, creating an<br />

incubator for technology and clean energy.<br />

Electric GT CEO Mark Gemmell said: “Not only do<br />

Bcomp’s revolutionary natural fibre panels give us increased<br />

performance in terms of damping and stiffness, Bcomp have<br />

also assisted us in achieving a 20 % weight saving compared<br />

to the road-going production version of this car. That is quite<br />

staggering.<br />

“In addition to the performance characteristics these<br />

materials offer, we are also working with Bcomp to develop<br />

our secret weapon - bespoke LED arrays within the fibre<br />

composite panels, so that the cars will have the capability to<br />

display key information to the watching crowd and viewers at<br />

home.<br />

“From race numbers to race telemetry, energy levels and<br />

even biometric feedback from the drivers, the possibilities are<br />

endless and this is just the start of how we bring fans to the<br />

heart of the racing action.”<br />

Christian Fischer, CEO at Bcomp said: “At Bcomp, we’re<br />

really excited about the global shift towards clean, sustainable<br />

mobility. Our goal is to contribute with our lightweight, highperformance<br />

renewable materials, and EGT offers the perfect<br />

platform to show to the world how the future mobility will look.<br />

“When you meet like-minded people, things can go really<br />

fast. Just like us, Electric GT wants to explore the new<br />

opportunities of technology and push boundaries, which is<br />

how the idea of integrating LED arrays into our translucent<br />

body panels was born.”<br />

“From our first contact with Mark and his colleagues at<br />

Electric GT, it was clear that both teams wanted to create<br />

something entirely new and different, that would completely<br />

change the game plan for racing. We cannot wait to see where<br />

this partnership takes us.” MT<br />

www.electricgt.co | www.bcomp.ch<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 45


Report<br />

Product communication<br />

for bioplastics<br />

Uncharted territory and an adventure for the companies involved.<br />

Results of a study<br />

“And the companies that bring<br />

the products to market are in for an<br />

adventure...” [1].<br />

After making the decision to use bioplastics, companies<br />

are often faced with the question if and how this new material<br />

can be implemented in product communication, and yet there<br />

are presently almost no established methods of doing this.<br />

The feeling of adventure in the quote above expresses the<br />

uncertainty experienced by many companies, and interviews<br />

conducted in the Product Communication research project –<br />

being a part of the Junior Research Group at IfBB (Institute<br />

of Bioplastics and Biocomposites, Hanover, Germany)<br />

– confirm this. The underlying conditions for marketing<br />

products containing bioplastics were analyzed with the goal of<br />

developing effective communication strategies.<br />

24 interviews were conducted in 2016 with 35 communication<br />

executives. The focus was placed on questions concerning<br />

the existing knowledge, requirements and reservations<br />

with respect to the use of bioplastics. The survey addressed<br />

companies that either produce or sell bioplastic products,<br />

as well as representatives from politics, non-governmental<br />

organizations (NGOs), the scientific community and relevant<br />

associations.<br />

The reasons for the interest in bioplastics are manifold and<br />

range from a desire for the use of sustainable materials to<br />

perceived pressure from business or the customer:<br />

“But we also see it as a marketing tool,<br />

we can’t do without it. That’s an issue.<br />

If we are asked about it, we have to have<br />

something to show.” [2].<br />

The fear of resource scarcity is also a common reason for<br />

choosing bioplastics.<br />

Bioplastics offer real advantages that can be conveyed in<br />

product communications. On the one hand, the interviewees<br />

acknowledged the positive aspects for the environment such<br />

as the reduction of both CO 2<br />

output and oil consumption:<br />

“Yes, petroleum-free, 100 % from<br />

renewable resources and odorless, these<br />

are the three main arguments” [3].<br />

On the other hand, the higher costs, difficult cultivation<br />

conditions, technical limitations and public criticism of<br />

competition with food production were often mentioned as<br />

disadvantages:<br />

“In our view, it is quite true that those<br />

materials should be preferred, which do<br />

not compete with land use. Thus, material<br />

out of waste would be our first choice” [4].<br />

Nevertheless, biodegradability is an advantage if it<br />

fits the product properties and the application; however,<br />

disadvantages are presented by the fact that the disposal<br />

options are unclear; and that many technical difficulties still<br />

exist.<br />

Those interviewees indicated that the features and<br />

appearance of the products need to be emphasized:<br />

“It really does make sense to find new<br />

materials with new qualities such as better<br />

barrier properties or, in the simplest case,<br />

an improved ability to be printed upon<br />

or molded. Add the aspect of their being<br />

biobased, and you have created a real<br />

business opportunity...” [5].<br />

When businesses gather information on this subject,<br />

they primarily use internal sources such as their suppliers,<br />

trade associations, their own departments, and scientific<br />

publications, while the communication goals vary according to<br />

the target group. These goals can be anything from informing<br />

and clarifying up to the generation of pull effects. The biggest<br />

challenge for communication is that this topic generally<br />

requires much explanation, especially regarding the disposal<br />

options. Communication activities should start in-house and<br />

must include both informing and training.<br />

Furthermore, the topic of bioplastics often meets with false<br />

expectations and prejudices and is sometimes perceived to<br />

lack in relevance [6]. A fear of criticism and association with<br />

greenwashing was noticeable:<br />

“You’re more aware of defensive issues,<br />

because you definitely want to avoid being<br />

accused of greenwashing“ [7].<br />

46 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


Report<br />

This inhibits communication, but it also creates the<br />

incentive for companies to communicate more clearly.<br />

The results of the interviews show that green marketing is<br />

not necessarily advantageous for various reasons. The topic<br />

of bioplastics is too complex; and the potential pitfalls and<br />

challenges to communication efforts are too great. When<br />

bioplastics are mentioned at all, product communication<br />

should instead inform and explain the issue by being<br />

transparent. It should also address prejudices.<br />

In effective product communication, focus should be<br />

placed on the product: its quality, its properties, and its<br />

design. The material itself should be secondary, and for this<br />

reason, the properties of bioplastics should be represented<br />

as pleasant side-effects, not as a main feature. Potentially,<br />

this could lead to an increase in the perceived value of the<br />

product, but in order for this to come into effect, customers<br />

(end users, business customers, public authorities) will<br />

need some sort of confidence-building evidence in the form<br />

of certification or product labeling.<br />

The study results also indicate that there are still many<br />

challenges that communication cannot solve alone: For<br />

example, there is still a lack of uniform standards both<br />

on a national and on an EU level; the purchase prices are<br />

still high; production processes must be changed; and<br />

disposal infrastructures (composting, recycling) have<br />

to be expanded. In the case of small and medium-sized<br />

Enterprises, it makes sense to think about alliances to<br />

generate more market power and to carry out concerted<br />

marketing campaigns. With good products to build upon,<br />

communication will be able to effectively support the<br />

establishment process.<br />

The research group FNG of the Institute of Bioplastics and<br />

Biocomposites (IfBB) at University of Applied Sciences and<br />

Arts in Hanover plans to introduce bioplastics products to<br />

the German market in cooperation with the business sector.<br />

Ecological and economic assessments and clarification of<br />

technical feasibility will also be carried out. The project<br />

is funded by the German Federal Ministry for Food and<br />

Agriculture (BMEL) under the sponsorship of the Agency<br />

for Renewable Resources (FNR).<br />

More information about the Junior Research Group at<br />

IfBB can be found here: http://fng.ifbb-hannover.de All<br />

results of the research project will be available on the IfBB<br />

website starting middle of January 2018.<br />

www.ifbb-hannover.de<br />

References<br />

[1] „Und das Abenteuer bestreiten halt die Firmen, die die<br />

Produkte auf den Markt bringen…” (interview partner 14,<br />

Applying company).<br />

[2] „Aber wir sehen das halt auch als Marketinginstrument, wir<br />

können nicht darauf verzichten, das ist ein Thema. Wenn wir<br />

darauf angesprochen werden, müssen wir so was haben“<br />

(interview partner 14, applying company).<br />

[3]„Ja, erdölfrei, 100 % aus nachwachsenden Rohstoffen und<br />

geruchsneutral, das sind so die drei Hauptargumente“<br />

(interview partner 18, applying company)<br />

[4] „Aus unserer Sicht ist es natürlich schon so, dass natürlich<br />

Ausgangsmaterialien, die jetzt vielleicht nicht so sehr auch in<br />

Konkurrenz zum Land-Use stehen, bevorzugt werden sollten.<br />

Also eben Material aus Abfällen wären für uns ... erste Wahl“<br />

(interview partner 22, trade company).<br />

[5]„Sinn macht es wirklich, neue Materialien zu finden, die<br />

irgendwelche neuen Eigenschaften haben, zum Beispiel<br />

einfach bessere Barriereeigenschaften oder im einfachsten<br />

Fall lassen sie sich besser bedrucken oder verformen. Wenn<br />

dann noch die Biobasiertheit dazukommt, dann hat man<br />

einen wirklichen Mehrwert geschaffen für die Industrie...“<br />

(interview partner 25, association).<br />

[6] Pls. see also results of the focus groups: a survey with a total<br />

of 48 consumers in the context of the FNG research project<br />

(2016): here: Webinar 3 (German language only, registration<br />

via e-mail is required)<br />

https://www.ifbb-hannover.de/de/webinare.html<br />

[7] „Man geht da mit dem Thema eher bewusst defensiv um,<br />

weil man halt definitiv vermeiden möchte, in diese Ecke<br />

geschmissen zu werden, dass man halt Greenwashing<br />

betrieben hat“ (interview partner 14, applying company).<br />

By:<br />

Miriam Jaspersen<br />

FNG II-Projekt<br />

Hochschule Hannover, Germany<br />

Wiebke Möhring<br />

FNG II-Projekt<br />

Technical University Dortmund, Germany<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 47


Basics<br />

Blown Film<br />

Extrusion<br />

By Michael Thielen<br />

Blown Film Extrusion is an established process which<br />

is used to manufacture a wide range of thin commodity<br />

and specialized plastic films mainly for the packaging<br />

industry, but also for other sectors, such as for example<br />

mulch films for agricultural applications. Also known<br />

as Film Blowing Process, this extrusion process generally<br />

comprises the extrusion of a molten thermoplastic tube<br />

and its constant inflation to several times its initial diameter.<br />

This forms a thin, tubular product which may be used<br />

directly, or indirectly by slitting it to create a flat film.<br />

Materials used<br />

In the process of Blown Film Extrusion, the common<br />

resins that are used are polyethylenes (LDPE, HDPE and<br />

LLDPE). However, various other materials, including many<br />

biobased and biodegradable plastics, can also be used in<br />

this process, as a blend with other resins or even as single<br />

layers or in multi-layer film structures. In few instances<br />

of multilayer production, when the individual materials<br />

are not able to gel together, a multi-layer film might delaminate.<br />

This can happen if polyethylene or polypropylene<br />

is combined with other thermoplastics. Hence, to overcome<br />

this issue, various tiny layers of special adhesive resins are<br />

used purposefully in between. These tiny layers are called<br />

tie layers.<br />

Process of blown film extrusion<br />

The extrusion and subsequent tube-forming of the plastic<br />

melt is done via an annular slit die, generally vertically in<br />

the upward direction, for the formation of a thin walled melt<br />

tube. The introduction of air takes place through a hole in<br />

the die’s center for blowing up the tube just like a balloon.<br />

The cooling of the hot film is done by a high-speed air ring<br />

that blows onto it. This air ring is mounted above the die.<br />

Then the following procedures take place:<br />

The tube of the film continues its movement upwards<br />

(constantly cooling) until it is squeezed by two opposing flat<br />

surfaces (collapsing frame) to collapse the tube before it<br />

enters the primary nip rolls at the top of the tower structure.<br />

The now collapsed tube is transported on idler rolls down<br />

the tower by the secondary tension-controlled nip.<br />

On higher output lines, an exchange of air inside the<br />

bubble is necessary. This is called IBC (Internal Bubble<br />

Cooling).<br />

Finally, the collapsed tube is kept as it is or is slit into<br />

two individual sheets or webs. Then the film is wound onto<br />

cores to make film roll stock. The film can also be sent to<br />

an in-line sealing machine to make bags. This process can<br />

also be carried out off-line at a later stage.<br />

Depending on where the inflated melt-film starts to<br />

solidify (so-called frost line) a short neck process or – if the<br />

frost line lies rather high – a long neck process are being<br />

distinguished. As an example, PE-LD is usually run on in a<br />

short neck process, whereas PE-HD is preferably run on<br />

long neck equipment.<br />

Advantages of blown film extrusion<br />

• In a single operation, flat as well as gusseted tubing can<br />

be formed.<br />

• Regulation of film thickness and width with the control<br />

of air volume in the bubble<br />

• Capability of biaxial orientation, which allows uniformity<br />

in all the mechanical properties<br />

• Very high productivity<br />

• Allows combination of different materials as well as<br />

properties<br />

Applications of blown film extrusion<br />

In this extrusion process, the blown film is used either<br />

in tube form (for plastic sacks and bags) or a sheet can be<br />

used by slitting the tube. Typical applications of the Blown<br />

Film Extrusion or Film Blowing includes following:<br />

industry packaging<br />

• shrink film<br />

• stretch film<br />

• bag film<br />

• container liners<br />

consumer packaging<br />

• packaging film for frozen products<br />

• shrink film for transport packaging<br />

• food wrap film<br />

• packaging bags<br />

• form, fill and seal packaging film<br />

laminating film<br />

• laminating of aluminium or paper used for packaging<br />

milk, coffee, and similar products<br />

agricultural film<br />

• Mulch film<br />

• greenhouse film<br />

• crop forcing film<br />

• silage film<br />

• silage stretch film<br />

films for packaging medical products<br />

[1, 2]<br />

Blown film extrusion of bioplastics<br />

Most bioplastics can be run on conventional blown<br />

film extrusion equipment. However, due to their different<br />

flow behavior – just like changing any other polymer –<br />

most bioplastics need a new and exact adjustment of the<br />

extrusion dies, output speeds, temperatures etc. for the<br />

respective operating points.<br />

48 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


Basics<br />

As an example, some particularities of BASF’s ecovio ®<br />

blown film types (F and FS - grades) shall be mentioned<br />

here:<br />

The ecovio blown film grades can be run on conventional<br />

blown film extrusion lines in thicknesses ranging from<br />

usually 8 up to 250 μm (depending in the product type).<br />

All existing downstream equipment (winding-, printing-,<br />

cutting- and welding/sealing, bag-making equipment etc)<br />

can be used.<br />

Conventional spiral mandrel die heads of the latest<br />

generation can be used to process ecovio F and FS. The range<br />

of usable die gaps is rather wide. Existing metallocene‐ dies<br />

with gap widths of 1.2-1.8 mm can be used as well as die<br />

gaps as narrow as 0.8 mm.<br />

Ususally ecovio is being processed in a normal- (or<br />

short)-neck process (PE-LD). To a limited extent, it can<br />

also be run on existing PE-HD long neck equipment. The<br />

neck-length however, should be significantly shorter as for<br />

running PE-HD.<br />

Usual blow up ratios for ecovio are in the range of 1:2.5 up<br />

to 1:4 (e.g. mulch films).<br />

The ecovio F and FS grades are pre-compounded with a<br />

certain amount (1~2 %) of slip- and antiblock masterbatches<br />

to adapt sliding properties, avoid fold formation and reduce<br />

blocking of the film. However, additional adding of such<br />

additives may be advised. [3]<br />

Sources:<br />

[1] www.industrialextrusionmachinery.com<br />

[2] www.kpfilms.com<br />

[3] BASF brochure “ecovio® Biologically degradable solutions for extrusion<br />

applications”<br />

The 3-layer plant of the machine manufacturer<br />

Hosokawa Alpine. The picture shows the plant in the<br />

Augsburg test centre (Photo courtes Hosokawa-Alpine)<br />

Nip Rolls<br />

Collapsing<br />

Frame<br />

Stabilizing Cage<br />

Air Ring<br />

Winder<br />

Extruder<br />

Die<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 49


Report<br />

Situation<br />

in France<br />

By:<br />

Marie Plancke<br />

Secrétaire Générale<br />

Club Bio-plastique<br />

Paris, France<br />

Two years ago, France’s Energy Transition for Green<br />

Growth bill was voted into law by the National Assembly.<br />

This wide-reaching Act aims to provide effective<br />

tools to boost green growth, to reduce environmental<br />

impacts and is strongly committed to a circular economy<br />

transition. A key aspect of the law is to tackle unemployment<br />

through green growth by relocating industrial plants<br />

in territories.<br />

As biobased and biodegradable plastics are predicated<br />

on a systemic approach that starts from the soil and ends<br />

in the soil, they illustrate a concrete model of the French<br />

perspective on a circular economy focused on territories.<br />

The starch from which French bioplastics are made, indeed,<br />

comes from, potatoes and maize cultivated in French soil.<br />

Biorefineries and plastics converting companies can be<br />

integrated into local areas where bioplastics are produced.<br />

Club Bio-plastiques, the French representative of the<br />

bioplastics industry (from agro-resources to their final<br />

conversion) has been invited to work on the French Circular<br />

Economy roadmap which is scheduled for publication in<br />

March 2018.<br />

Bioplastics in France: now & tomorrow<br />

Since January 1 st <strong>2017</strong>, thin-walled single-use plastics<br />

bags have been banned. The bags must be made from<br />

plastic with a minimum biobased content of 30 %, and<br />

be home compostable, compliant to the French home<br />

composting standard NFT 51 800. The minimally required<br />

biobased percentage will increase progressively to 60 % in<br />

2025.<br />

Checkout carrier bags must now be reusable, which<br />

means they must be have a thickness > 50µm to be in<br />

compliance with the law. Nevertheless, many PE single-use<br />

bags can still be found at small city markets, although most<br />

supermarkets are now in conformity. Club Bio-plastiques<br />

continues to work on this issue with the Environment<br />

Ministry in order to meet the single-use plastic bags ban.<br />

The Ministry for Economic Affairs has commissioned a<br />

report about the environmental & economic benefits of this<br />

regulation that will be published in 2018.<br />

Under the Energy Transition Act, a ban on disposable<br />

cups, glasses and plates not made of bioplastic will go<br />

into effect on January 1 st 2020 . Although members of<br />

Club Bio-plastiques are very pleased and welcome this<br />

latest weapon in the fight against plastic pollution, they<br />

warned the Ministry and its representatives about the<br />

home composting obligation. Under the law, “cups, glasses<br />

and plates” must be made of bioplastic with a minimum<br />

biocontent of 50 % and home compostable (in compliance<br />

with the French standard), which leads to a technical issue<br />

for companies. Although industrial composting would not<br />

have been a problem, the industry has not yet been able to<br />

produce disposable plates, cups and glasses that are home<br />

compostable - in spite of massive R&D investments. The<br />

problem is the thickness. Manufacturers of these products<br />

do not expect to successfully produce home compostable<br />

serviceware before the year 2020.<br />

Another deadline will occur in 2025 with the<br />

generalization of source separation, the first step for the<br />

separate collection of biowaste, which could help towards<br />

achieving the targets of the Circular Economy Package<br />

(decrease of landfilling and so on). Indeed, by requiring<br />

source separation and organic waste valorization, the Act<br />

aims to enhance compost quality. The French Agency for<br />

the Environment (ADEME) published a best practices guide<br />

for biowaste collection last spring, highlighting the use of<br />

biodegradable bags in the process.<br />

The importance of organic waste collection, and role of<br />

biobased and biodegradable plastics in the model were<br />

emphasized in discussions during the Food & Farming<br />

General State led by the government. Invited to participate<br />

and to discuss on the bioeconomy and the Circular<br />

Economy, Club Bio-plastiques also called for a ban on<br />

oxofragmentable mulch films. These products are still used<br />

in France despite their environmental impact, and in spite<br />

of existing biodegradable mulch films solutions.<br />

www.bioplastiques.org<br />

50 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


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bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 51


Opinion<br />

Position Paper: Plastic bags<br />

Background<br />

What do lettuce from the weekly market, a pack of<br />

headache pills, a DVD, a teddy bear and jeans have in<br />

common? At first glance, you would think: nothing. But a<br />

second look reveals: often when you buy them, all these<br />

items are put in a disposable polymer bag, better known as<br />

plastic bag.<br />

Statistically, 45 plastic bags per capita were used in<br />

Germany in 2016 [1]. In a city like Oberhausen with 210,000<br />

citizens this amounts to a total of almost 10 million bags<br />

per year. While some of the plastic bags are reused several<br />

times after their initial use, for example as a means of<br />

transport or as a garbage bag, most of them directly<br />

end up in the mixed waste bin or, as it should be, are fed<br />

into recycling via the yellow bin, the German lightweight<br />

packaging collecting system. Especially so called hygiene<br />

bags with a wall thickness of less than 15 μm (0.015 mm),<br />

often used for fruit and vegetables bought at markets and<br />

grocery stores, are just used once.<br />

The amount of plastic litter in the oceans is still increasing<br />

– in total it is estimated to be 27-66,7 million tonnes [2] –<br />

and more and more pictures of starved birds and beached<br />

whales with their stomachs full of plastics fragments and<br />

bags instead of food are going around the world [3]. That<br />

is why plastics, especially in the form of plastic bags and<br />

packaging, are increasingly becoming a subject of harsh<br />

criticism. For many years, plastic bags have been one of<br />

the top 10 litter items found during beach clean-ups [4].<br />

Several initiatives, like plastic-free shops [5] or plastic-free<br />

cities [6], aim at completely abandoning these products.<br />

In April 2016 the Federal Ministry for the Environment,<br />

Nature conservation, Construction and Nuclear Safety<br />

(BMUB) and the Trade Association of Germany (HDE)<br />

signed a voluntary agreement to reduce the use of plastic<br />

bags by half in the next ten years. Therein, the participating<br />

companies commit themselves to charge their customers<br />

a reasonable fee for plastic bags from 1 July 2016 at the<br />

latest. Exceptions are only made for very light carrier bags<br />

with a wall thickness below 15 μm (i. e. hygiene bags) and<br />

freezer and long-life carrier bags with a wall thickness of<br />

more than 50 μm. The latter types had already mostly been<br />

charged for anyway.<br />

Many retailers have reacted and do not offer free bags<br />

anymore but charge a fee for plastic bags instead. Some<br />

even go a step further. The German food retailer REWE, for<br />

example, has completely stopped the sale of plastic bags<br />

since 1 June 2016 and nowadays offers alternatives made<br />

from cotton, jute or paper as well as reusable bags from<br />

recycled materials or cardboard boxes [7]. In September<br />

2016 the German discounter Lidl also announced not to<br />

offer standard plastic bags any more starting in <strong>2017</strong> [8].<br />

Today, one can find long-life carrier bags, cotton and paper<br />

bags as eco-friendly alternatives in their stores [9].<br />

52 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


Opinion<br />

By:<br />

Jürgen Bertling, Stephan Kabasci<br />

Markus Hiebel, Leandra Harmann<br />

Fraunhofer UMSICHT<br />

Oberhausen, Germany<br />

But how should the subject be evaluated from a scientific<br />

perspective? Experts from Fraunhofer UMSICHT have<br />

compiled the following facts and assessments.<br />

Position of Fraunhofer UMSICHT<br />

1. Similar to the criticized material polyvinyl chloride<br />

(PVC) the plastic bag has become a highly symbolic icon in<br />

environmental debates. It has been singled out from a variety<br />

of plastic products which have quite a similar relevance from<br />

an environmental perspective. Its importance regarding the<br />

quantitative environmental impact is frequently overrated<br />

and the complexity of the overall problem with polymers in<br />

the environment tends to be oversimplified. This makes an<br />

unbiased discussion based on facts difficult.<br />

2. The mass fraction of plastic bags accounts for less<br />

than one percent of the total consumption of plastics. With<br />

45 per capita and year the consumption of plastic bags<br />

in Germany is well below the EU average of 198 bags per<br />

capita and year. Nevertheless, there are countries such as<br />

Luxembourg and Ireland which show a significantly lower<br />

consumption [1, 10].<br />

3. Life cycle assessments (LCA) do not show specific<br />

advantages of paper and cotton bags over bags made from<br />

conventional plastics or bio-plastics. A multiple use of bags<br />

has positive effects on LCA results [11]. However, LCAs are<br />

quite limited in their informative value. For example, long<br />

term necessary paradigm shifts (from fossil to renewable<br />

sources), the technical level of development of materials or<br />

products (learning curve of efficiency) or the impact of litter<br />

– including microplastics – in the environment are not or<br />

not sufficiently considered yet.<br />

4. The utilization of biodegradable materials as alternative<br />

sources for plastic bags needs further investigation. It is<br />

known that not all biodegradable plastics degrade as quickly<br />

in different environmental compartments (e.g. on and in<br />

the soil, in fresh and sea water) as it is proven in standard<br />

laboratory tests. However, even a slower degradation –<br />

albeit lasting several years – would already improve the<br />

situation compared to the extremely long lasting standard<br />

plastics bags (mostly made out of the polyolefines PE or<br />

PP). Closer examinations of degradation mechanisms and<br />

kinetics in the environment as well as sociological studies<br />

dealing with the suspected rebound effect of increased<br />

littering of biodegradable bags into the environment are yet<br />

to be carried out.<br />

5. Plastic bags made of polyethylene (PE) with catalytic<br />

additives which enhance oxidative fragmentation (so<br />

called oxo-degradables) are to be strictly rejected. They<br />

purposefully produce microplastics which can have severe<br />

consequences in the low trophic levels (plankton, bivalves,<br />

worms etc.) of the food chain (please see our position paper<br />

on microplastics for further information) [12].<br />

450-<br />

400-<br />

350-<br />

300-<br />

250-<br />

200-<br />

150-<br />

100-<br />

50-<br />

Number of plastic bags used per capita in 2010 in the EU [13]<br />

0-<br />

Bulgaria - 421<br />

Czech Rep. -297<br />

Greece - 269<br />

Romania - 252<br />

Italy - 204<br />

EU 27 - 198<br />

Cyprus - 140<br />

UK - 137<br />

Spain - 133<br />

Malta - 119<br />

Sweden - 111<br />

Belgium - 98<br />

Netherlands - 81<br />

France - 79<br />

Denmark - 79<br />

Finland - 77<br />

Germany - 71<br />

Austria - 51<br />

Luxembourg - 20<br />

Ireland - 18<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 53


Opinion<br />

6. Biobased polymers are an important strategic route<br />

since a path change away from fossil raw materials to<br />

renewable sources will be unavoidable in the long term.<br />

Regardless of biodegradation this route should be followed<br />

in any case. Another long-term option could be the material<br />

use of carbon dioxide using regenerative energies for its<br />

extraction.<br />

7. Multiple uses and improved end-of-life management<br />

are necessary for all types of shop-ping bags.<br />

8. A general ban on plastic bags is rather to be rejected.<br />

Instead, strategies should be pursued promoting careful and<br />

responsible use. These include, for example, measures of<br />

environmental education, deposit systems or fees for plastic<br />

bags in shops. The latter has al-ready been implemented<br />

successfully in Germany following the voluntary agreement<br />

of the Federal Ministry for the Environment and the Trade<br />

Association of Germany (HDE).<br />

9. Furthermore, any means that facilitate plastic recycling,<br />

such as collecting systems, which facilitates an efficient<br />

separate collection, or an abandoning of multi-material<br />

systems, should be reasonably accompanied by political and<br />

regulatory measures.<br />

These facts and recommendations form the basis for<br />

technical and social innovations which are developed by<br />

Fraunhofer UMSICHT.<br />

Plastic bag consumption – examples from<br />

around the world<br />

The per capita consumption of plastic bags varies<br />

from country to country. In 2010 Bulgaria led the EU<br />

member states with 421 bags, followed by the Czech<br />

Republic (297), Greece (269), Ro-mania (252) and Italy<br />

(204). Germany already was at the lower end of the<br />

range with 71 bags per capita in 2010. According to<br />

most recent figures, it has reduced its consumption<br />

further down to 45 bags per capita per year [1]. Less<br />

plastic bags were only used in Luxemburg (20) and<br />

Ireland (18) – see the following figure. The low value for<br />

Ireland can be explained by a former introduction of a<br />

fee for plastic bags.<br />

Some non-European countries have already imposed<br />

complete bans. In Bangladesh plastic bags were<br />

first banned in the capital city of Dhaka in 2001 and<br />

subsequently prohibited throughout the country. The<br />

reason was that they were partly made responsible<br />

for blocking wastewater sys-tems leading to floodings<br />

in 1988 and 1998. In Morocco, plastic bags have been<br />

banned com-pletely since 1 July 2016. The country<br />

previously ranked second behind the USA with an<br />

annual consumption of 900 bags per capita and 26<br />

billion in total.<br />

Ultrathin plastic bags are prohibited in China, Kenia,<br />

Rwanda and South Africa. In the city of San Francisco<br />

plastic bags also got banned. Furthermore, in China<br />

plastic bags are charged for, as well as in Washington<br />

D. C. and Los Angeles. Some further countries also<br />

consider implementing laws because farm animals<br />

have increasingly started to feed on plastic bags and as<br />

a consequence have suffered from health problems.<br />

Sources: [1, 14, 15, 16, 17, 18].<br />

References:<br />

[1] GVM (<strong>2017</strong>): Ein Drittel weniger Kunststofftüten in Deutschland -<br />

Presseinformation des Handelsverband Deutschland: Datengrundlage<br />

(GVM - Gesellschaft für Verpackungs-marktforschung). Last time<br />

checked: <strong>2017</strong>, June 28. https://www.einzelhandel.de/index.php/<br />

presse/aktuellemeldungen/item/127648-ein-drittel-wenigerkunststofft%C3%BCten-in-deutschland<br />

[2] Eunomia (2016): Plastics in the Marine Environment. Bristol, United<br />

Kingdom<br />

[3] Spiegel Online (<strong>2017</strong>): Müll im Meer: Wal hatte 30 Plastiktüten im Magen.<br />

Last time checked: <strong>2017</strong>, April 28. http://www.spiegel.de/wissenschaft/<br />

natur/muell-im-meer-wal-hatte-30-plastiktueten-im-magen-a-1132942.<br />

html<br />

[4] Ocean Conservancy (2016): 30th Anniversary International Coastal<br />

Cleanup: Annual Re-port. Washington DC<br />

[5] Utopia (2016): Verpackungsfreier Supermarkt: einkaufen ohne<br />

Verpackung. Last time checked: <strong>2017</strong>, April 28. http://www.utopia.de/<br />

magazin/plastikfreie-laeden<br />

[6] IBP - Interkulturelle Begegnungsprojekte e.V. (2015): Unplastic<br />

Billerback. Last time checked: <strong>2017</strong>, April 28. http://www.unplasticbillerbeck.de/<br />

[7] Süddeutsche Zeitung (2016): Rewe stoppt Verkauf von Plastiktüten. Last<br />

time checked: <strong>2017</strong>, April 28. http://www.sueddeutsche.de/wirtschaft/<br />

plastikmuell-rewe-stoppt-verkauf-von-plastiktueten-1.3014599<br />

[8] Presseportal (2016): Lidl Deutschland spart ab <strong>2017</strong> jährlich 3500<br />

Tonnen Plastik: Lidl nimmt bundesweit Standard-Plastiktüte aus dem<br />

Sortiment und setzt auf Mehrfachver-wendung seines erweiterten<br />

Tragetaschensortiments. Last time checked: <strong>2017</strong>, April 28. http://www.<br />

presseportal.de/pm/58227/3434594<br />

[9] LIDL Deutschland (<strong>2017</strong>): Tragetaschensortiment - Lidl Deutschland<br />

- lidl.de. Last time checked: <strong>2017</strong>, April 28. https://www.lidl.de/de/<br />

tragetaschensortiment/s3219<br />

[10] Zeit Online (2013): Umweltverschmutzung: EU will Plastiktüten-<br />

Verbrauch begrenzen. Last time checked: <strong>2017</strong>, April 28. http://www.zeit.<br />

de/wissen/umwelt/2013-11/plastik-eu-kommission<br />

[11] Environment Agency (2011): Evidence. Life cycle assessment of<br />

supermarket carrierbags: a review of the bags available in 20<strong>06</strong>. Report:<br />

SC030148. Bristol: Environment Agency (En-vironment Agency science<br />

report)<br />

[12] Fraunhofer-Institut für Umwelt-, Sicherheits- und Energietechnik<br />

UMSICHT (2015): Fraun-hofer UMSICHT nimmt Stellung: Thema<br />

Mikroplastik. https://www.umsicht.fraunhofer.de/de/nachhaltigkeit/agnachhaltigkeit/umsicht-nimmt-stellung/mikroplastik.html<br />

[13] European Commission - DG Environment (2011): Assessment of impacts<br />

of options to reduce the use of single-use plastic carrier bags: Final<br />

report<br />

[14] Umweltbundesamt (2013): Plastiktüten. UBA: Dessau-Roßlau<br />

[15] Doyle, T.; O’Hagen, A. M. (2013): The Irish ‘Plastic Bag Levy’: A<br />

mechanism to reduce marine litter? (Marine Litter in Eurpean Seas)<br />

[16] Süddeutsche Zeitung (2016): Marokko: Kommt nicht in die Tüte. Last<br />

time checked: <strong>2017</strong>, April 28. http://www.sueddeutsche.de/panorama/<br />

marokko-kommt-nicht-in-die-tuete- 1.3104571<br />

[17] Deutschlandfunk (2016): Energiewende-Gesetz: Frankreich will<br />

Plastiktüten teilweise ver-bieten. Last time checked: <strong>2017</strong>, April 28.<br />

http://www.deutschlandfunk.de/energiewende-gesetz-frankreich-willplastiktueten-teilweise.697.de.html?dram:article_id=358804<br />

[18] Earth Policy Institute (2014): Plastic Bags Fact Sheet<br />

tinyurl.com/postion-bags<br />

54 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


Brand Owner<br />

Brand owner’s<br />

perspectives<br />

What is driving investment in biobased<br />

materials.<br />

Respondents said growth factors for biobased materials<br />

include consumer demand for environmentally-friendly<br />

products (65 %) and packaging (46 %), as well as brands<br />

wanting to improve public image (48 %).<br />

On this page our readers usually find a statement from<br />

a brand owner. This issue, however, we give ourselves<br />

a break. Not because we are lazy, but simply because<br />

our friends at Sustainability Consult did such a good job<br />

with their survey on #WhatBrandsWant. In this issue we<br />

publish an excerpt from their report.<br />

Sustainability Consult, the leading bioeconomy<br />

communications and PR consultancy (Brussels, Belgium)<br />

realised that they (just like we) often hear the same<br />

questions:<br />

• How can biomaterials manufacturers make it easier for<br />

brands to engage?<br />

• What can the biobased industry do to encourage brands<br />

to invest in biobased materials?<br />

• How do biobased solutions fit in with brand sustainability<br />

goals?<br />

• How can brands help the biobased industry to grow?<br />

So they decided to ask over 40 brands across different<br />

sectors ranging from apparel, footwear & textiles, to food<br />

& beverages and personal care. The results offer an insight<br />

on the drivers and barriers affecting market growth in the<br />

biobased materials sector.<br />

Here are some of their findings:<br />

Level of knowledge<br />

Respondents from brands were informed about biobased<br />

materials, with 59 % claiming they were informed, 39 %<br />

well-informed and only 2 % not informed about biobased<br />

materials. This trend was also reflected by those brands not<br />

currently using biobased solutions.<br />

not informed<br />

well informed<br />

informed<br />

What information are brands exactly looking<br />

for?<br />

To evaluate whether to adopt biobased materials, 63 %<br />

said they need more information from suppliers on pricing,<br />

61 % on availability and 57 % on performance.<br />

peformance<br />

availability<br />

pricing<br />

0%<br />

0%<br />

10%<br />

20% 40% 60% 80%<br />

20%<br />

30% 40% 50% 60% 70% 80%<br />

improve their public image<br />

Consumer demand for<br />

environmentally-friendly packaging<br />

Consumer demand for<br />

environmentally-friendly products<br />

What are the biggest barriers?<br />

0% 10% 20% 30% 40% 50% 60% 70%<br />

Among the brands, 87 % indicated cost as the biggest<br />

barrier to widespread uptake of biobased materials.<br />

Performance (42 %) and security of supply (37 %) were<br />

identified as the next biggest barriers.<br />

security of supply<br />

performance<br />

cost<br />

0%<br />

20% 40% 60% 80% 100%<br />

Do brands owners communicate externally on<br />

their use of biobased materials?<br />

Communicating openly on their use of biobased<br />

materials demonstrates confidence in biobased technology<br />

and products. 71 % of the respondents do communicate<br />

externally, whereas 27 % said they don’t.<br />

do not commuexternaly<br />

nicate externaly<br />

communicate<br />

0%<br />

20% 40% 60% 80%<br />

What growth rates are expected for biobased<br />

materials?<br />

Most respondents expect the market to experience<br />

moderate growth (61 %), although brands already using biobased<br />

materials are more optimistic, with 43 % suggesting<br />

there will be strong market growth. In their comments,<br />

respondents highlighted the price of oil, lengthy product<br />

planning cycles, end-of-life options and legislative changes<br />

as having a strong impact on the evolution of the market.<br />

Perhaps more surprisingly, brands not using biobased<br />

materials also expect moderate growth. This is a positive<br />

sign of market development for biomaterials producers. MT<br />

The complete report can be downloaded for free at:<br />

www.bioplasticsmagazine.de/<strong>2017</strong><strong>06</strong>/whatbrandswant.pdf<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 55


Automotive<br />

10<br />

Years ago<br />

Special<br />

Published in<br />

bioplastics MAGAZINE<br />

Article contributed by Christian Garaffa,<br />

Marketing Department, Project Manager<br />

Waste Management Area.<br />

A<br />

fter Ireland, San Francisco and Oakland in California,<br />

Modbury in Britain, the debate on disposable<br />

carrier bags has recently moved to London. Many<br />

other countries and cities are looking to introduce or already<br />

have some form of ban, tax, levy or some voluntary<br />

agreement on throwaway shopping bags (e.g. France or<br />

Italy).<br />

The question is always the same: how to manage the<br />

environmental issue posed by non biodegradable carrier<br />

bags? The common logic permeating the different choices<br />

is always the one dictated by the waste hierarchy: prevent,<br />

reuse, recover, dispose of.<br />

Factors like an intensive communication to the consumers<br />

and the introduction of reusable bags “for life”<br />

which can be used for several times before they are finally<br />

thrown away or given back to the store, are an essential<br />

part of this schemes.<br />

Compostable shopping<br />

carrier bags: what is the<br />

logic for their contribution<br />

to the environment?<br />

www.novamont.com<br />

How do compostable carrier bags place themselves into<br />

this picture?<br />

Compostable carriers can actually be a powerful aid to<br />

waste minimization and recovery policies especially there<br />

were organic waste collection schemes are to be set up<br />

or are already in place. In order for such schemes to be<br />

successful they must be hygienic for both consumer and<br />

collection crews and be as convenient as possible. The<br />

best way to ensure both these criteria is for consumers<br />

to line their kitchen caddy with a compostable liner which<br />

can then be tied and placed in the larger container. Using<br />

liners in this fashion not only keeps the system clean and<br />

hygienic from kitchen to collection to treatment facility,<br />

but by being simple to use, they also lead to higher levels<br />

of participation and subsequently greater amounts of food<br />

waste are recovered and less material is landfilled.<br />

A proper communication and the possibility for the<br />

householder to easily identify the compostable bags are<br />

completing the picture for this kind of schemes which are<br />

able to recover as much as 90% of the kitchen organics<br />

present in the household waste.<br />

In November <strong>2017</strong>,<br />

Christian Garaffa, Novamont<br />

says:<br />

Since 10 years ago, Europe is<br />

now talking about circular economy<br />

and making efforts to make it really happen. Italy was the<br />

first Member State to adopt a single use plastic bag ban in 2011<br />

promoting reusable bags but also allowing shopping bags certified<br />

to EN13432 for reuse in the organic waste collection. At EU<br />

level in 2015 a new Directive set targets to reduce the current<br />

level of consumption of lightweight plastic carrier bags (Directive<br />

(EU) 2015/720). It also addresses biodegradable and compostable<br />

plastic carrier bags, recognizing as a matter of fact<br />

the value of such bags for re-use in organic waste collection.<br />

The directive was also a door opener for further legislation at<br />

Member State level such as France imposing fresh produce<br />

bags to be compostable in <strong>2017</strong> and Italy to follow suit in 2018.<br />

From 1 January 2020 also Spain will allow only compostable<br />

carrier bags and fresh produce bags.<br />

The city of Milan is the perfect example of the role played<br />

by compostable shopping bags as a key tool for high participation<br />

and capture rates of biowaste: 70 kilograms per<br />

person per year of just residential food scraps are being<br />

collected. At the beginning of this year the EU Commission<br />

issued a Communication on the role of waste-to-energy<br />

in the circular economy, COM(<strong>2017</strong>) 34, stating that “since<br />

2014, the city has almost reached 100 % collection of food<br />

and organic waste, providing an average of 120.000 tonnes<br />

of biodegradable waste per year. At full capacity (12.8<br />

MW), the city biogas plant should produce some 35.880<br />

MWh of electricity a year, enough to supply 24.000 people,<br />

and yield 14.400 tonnes of fertiliser.” These figures are<br />

unmatched by far by any other large European city and<br />

compostable plastic bags are the standard tool to collect<br />

these food scraps and every second compostable<br />

bag found in the waste analyses is a shopping bag. In<br />

conclusion, after then years the compostable bioplastic<br />

shopping bag model has scaled up and supports the<br />

best performing organic waste collection systems in<br />

Europe. A perfect example of real circular economy.<br />

20 bioplastics MAGAZINE [07/04] Vol. 2<br />

tinyurl.com/bags200704<br />

56 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


Report<br />

Bioplastics Survey<br />

By:<br />

Michael Thielen<br />

In this edition of our “Special focus on certain geographical<br />

areas” series, we take a closer look at France and Italy.<br />

To that end, we once again conducted the short, non-representative<br />

survey we used in previous editions to attempt to<br />

gain an idea of people’s notions and perception of bioplastics<br />

in these countries.<br />

In this sixth edition of the series, we visited an attractive<br />

plaza in a pedestrian area in the centre of Strasbourg in<br />

France. We approached a (non-representative) number of<br />

passers-by and asked whether they would be willing to<br />

answer a few brief questions.<br />

Of those we interviewed, 47.8 % were male and 52.2 % were<br />

female. About 60.9 % were aged between 20 and 40, while<br />

39.1 % were between the ages of 40 and 60. This represents<br />

the average distribution of people browsing this plaza on a<br />

sunny, but chilly Thursday morning in October.<br />

When asked whether they knew what bioplastics were,<br />

almost 40 % responded that yes, they did (and had no<br />

difficulties in proving this, as they went on to mention aspects<br />

such as biobased origin and/or biodegradable features).<br />

Like all previous surveys in this series, the other 60 % was<br />

interested in learning about what bioplastics were. And after<br />

a brief explanation about the features and benefits, most<br />

seemed convinced that bioplastics were beneficial for the<br />

environment and for the climate.<br />

Strikingly, however, we found the French people we spoke<br />

to that morning were rather more differentiated than we had<br />

hitherto experienced in the other countries, and this yielded<br />

a number of very intense discussions. Two young female<br />

students, in particular, were highly reluctant to agree to the<br />

fact that there might be benefits to opting for bioplastics. The<br />

first argued about fertilizers and solvents, and the energy<br />

needed to produce bioplastics, while the second merely said:<br />

“We recycle and that’s good enough”.<br />

Happily, in other conversations we found that some of the<br />

people were really interested: they asked questions about<br />

availability, the processes that take place during composting<br />

and much more. They seemed to have time, the sun was<br />

shining and it was a nice area …<br />

Finally, we also asked all our interviewees whether they<br />

would buy products made of bioplastics, if they should happen<br />

to see them on display at the store. 91.3 % confirmed that<br />

they would. And – no surprise after the abovementioned<br />

discussions – 13 % said that they would not be willing to<br />

pay more for such products, with most of the other 87 %<br />

responding: “a little more, yes” or “it depends on the product”.<br />

What is paradoxical is that even in a country where, today,<br />

the use of biodegradable shopping bags is mandatory, some<br />

60 % of our non-representative choice of people knew little<br />

to nothing about or were unaware of bioplastics and their<br />

potential. And again, the results of this survey reveal that,<br />

given the knowledge and the chance, many consumers<br />

would opt for products using bioplastics and even be willing<br />

to pay a small premium. This indicates an obvious need for<br />

comprehensive end consumer education. Consumer behaviour<br />

can have a significant impact on the ways products affect the<br />

environment. Educating consumers about bioplastics offers<br />

a huge opportunity to promote these materials and to effect<br />

positive changes in the shopping choices people make.<br />

female<br />

20-40<br />

years<br />

40-60<br />

years<br />

Do you know what<br />

bioplastics are?<br />

Would you buy?<br />

Would you pay more?<br />

male<br />

YES<br />

39,1%<br />

NO<br />

60,9%<br />

YES<br />

91,3%<br />

NO<br />

8,7%<br />

YES<br />

87%<br />

NO<br />

13%<br />

47,6%<br />

55%<br />

50%<br />

55,6%<br />

52,4%<br />

45%<br />

50%<br />

44,4%<br />

44,4% 55,6% 71,4% 28,6% 54% 46%<br />

100%<br />

100%<br />

60% 40%<br />

66,7%<br />

33,3%<br />

33,3% 66,7%<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 57


Suppliers Guide<br />

1. Raw Materials<br />

Simply contact:<br />

Tel.: +49 2161 6884467<br />

suppguide@bioplasticsmagazine.com<br />

Stay permanently listed in the<br />

Suppliers Guide with your company<br />

logo and contact information.<br />

For only 6,– EUR per mm, per issue you<br />

can be present among top suppliers in<br />

the field of bioplastics.<br />

For Example:<br />

AGRANA Starch<br />

Bioplastics<br />

Conrathstraße 7<br />

A-3950 Gmuend, Austria<br />

technical.starch@agrana.com<br />

www.agrana.com<br />

BASF SE<br />

Ludwigshafen, Germany<br />

Tel: +49 621 60-9995<br />

martin.bussmann@basf.com<br />

www.ecovio.com<br />

PTT MCC Biochem Co., Ltd.<br />

info@pttmcc.com / www.pttmcc.com<br />

Tel: +66(0) 2 140-3563<br />

MCPP Germany GmbH<br />

+49 (0) 152-018 920 51<br />

frank.steinbrecher@mcpp-europe.com<br />

MCPP France SAS<br />

+33 (0) 6 07 22 25 32<br />

fabien.resweber@mcpp-europe.com<br />

Jincheng, Lin‘an, Hangzhou,<br />

Zhejiang 311300, P.R. China<br />

China contact: Grace Jin<br />

mobile: 0086 135 7578 9843<br />

Grace@xinfupharm.comEurope<br />

contact(Belgium): Susan Zhang<br />

mobile: 0032 478 991619<br />

zxh<strong>06</strong>12@hotmail.com<br />

www.xinfupharm.com<br />

1.1 bio based monomers<br />

Total Corbion PLA bv<br />

Arkelsedijk 46, P.O. Box 21<br />

4200 AA Gorinchem<br />

The Netherlands<br />

Tel.: +31 183 695 695<br />

Fax.: +31 183 695 604<br />

www.total-corbion.com<br />

pla@total-corbion.com<br />

62 136 Lestrem, France<br />

Tel.: + 33 (0) 3 21 63 36 00<br />

www.roquette-performance-plastics.com<br />

1.2 compounds<br />

Global Biopolymers Co.,Ltd.<br />

Bioplastics compounds<br />

(PLA+starch;PLA+rubber)<br />

194 Lardproa80 yak 14<br />

Wangthonglang, Bangkok<br />

Thailand 10310<br />

info@globalbiopolymers.com<br />

www.globalbiopolymers.com<br />

Tel +66 81 9150446<br />

Kingfa Sci. & Tech. Co., Ltd.<br />

No.33 Kefeng Rd, Sc. City, Guangzhou<br />

Hi-Tech Ind. Development Zone,<br />

Guangdong, P.R. China. 51<strong>06</strong>63<br />

Tel: +86 (0)20 6622 1696<br />

info@ecopond.com.cn<br />

www.ecopond.com.cn<br />

FLEX-162 Biodeg. Blown Film Resin!<br />

Bio-873 4-Star Inj. Bio-Based Resin!<br />

FKuR Kunststoff GmbH<br />

Siemensring 79<br />

D - 47 877 Willich<br />

Tel. +49 2154 9251-0<br />

Tel.: +49 2154 9251-51<br />

sales@fkur.com<br />

www.fkur.com<br />

39 mm<br />

Polymedia Publisher GmbH<br />

Dammer Str. 112<br />

41<strong>06</strong>6 Mönchengladbach<br />

Germany<br />

Tel. +49 2161 664864<br />

Fax +49 2161 631045<br />

info@bioplasticsmagazine.com<br />

www.bioplasticsmagazine.com<br />

Microtec Srl<br />

Via Po’, 53/55<br />

30030, Mellaredo di Pianiga (VE),<br />

Italy<br />

Tel.: +39 041 519<strong>06</strong>21<br />

Fax.: +39 041 5194765<br />

info@microtecsrl.com<br />

www.biocomp.it<br />

Cardia Bioplastics<br />

Suite 6, 205-211 Forster Rd<br />

Mt. Waverley, VIC, 3149 Australia<br />

Tel. +61 3 85666800<br />

info@cardiabioplastics.com<br />

www.cardiabioplastics.com<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

Sample Charge:<br />

39mm x 6,00 €<br />

= 234,00 € per entry/per issue<br />

Sample Charge for one year:<br />

6 issues x 234,00 EUR = 1,404.00 €<br />

The entry in our Suppliers Guide is<br />

bookable for one year (6 issues) and<br />

extends automatically if it’s not canceled<br />

three month before expiry.<br />

Tel: +86 351-8689356<br />

Fax: +86 351-8689718<br />

www.jinhuizhaolong.com<br />

ecoworldsales@jinhuigroup.com<br />

API S.p.A.<br />

Via Dante Alighieri, 27<br />

36<strong>06</strong>5 Mussolente (VI), Italy<br />

Telephone +39 0424 579711<br />

www.apiplastic.com<br />

www.apinatbio.com<br />

Green Dot Bioplastics<br />

226 Broadway | PO Box #142<br />

Cottonwood Falls, KS 66845, USA<br />

Tel.: +1 620-273-8919<br />

info@greendotholdings.com<br />

www.greendotpure.com<br />

www.facebook.com<br />

www.issuu.com<br />

www.twitter.com<br />

www.youtube.com<br />

Xinjiang Blue Ridge Tunhe<br />

Polyester Co., Ltd.<br />

No. 316, South Beijing Rd. Changji,<br />

Xinjiang, 831100, P.R.China<br />

Tel.: +86 994 2713175<br />

Mob: +86 13905253382<br />

lilong_tunhe@163.com<br />

www.lanshantunhe.com<br />

PBAT & PBS resin supplier<br />

BIO-FED<br />

Branch of AKRO-PLASTIC GmbH<br />

BioCampus Cologne<br />

Nattermannallee 1<br />

50829 Cologne, Germany<br />

Tel.: +49 221 88 88 94-00<br />

info@bio-fed.com<br />

www.bio-fed.com<br />

NUREL Engineering Polymers<br />

Ctra. Barcelona, km 329<br />

50016 Zaragoza, Spain<br />

Tel: +34 976 465 579<br />

inzea@samca.com<br />

www.inzea-biopolymers.com<br />

58 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


Suppliers Guide<br />

Sukano AG<br />

Chaltenbodenstraße 23<br />

CH-8834 Schindellegi<br />

Tel. +41 44 787 57 77<br />

Fax +41 44 787 57 78<br />

www.sukano.com<br />

Kaneka Belgium N.V.<br />

Nijverheidsstraat 16<br />

2260 Westerlo-Oevel, Belgium<br />

Tel: +32 (0)14 25 78 36<br />

Fax: +32 (0)14 25 78 81<br />

info.biopolymer@kaneka.be<br />

TIPA-Corp. Ltd<br />

Hanagar 3 Hod<br />

Hasharon 45013<strong>06</strong>, ISRAEL<br />

P.O BOX 7132<br />

Tel: +972-9-779-6000<br />

Fax: +972 -9-7715828<br />

www.tipa-corp.com<br />

Natur-Tec ® - Northern Technologies<br />

4201 Woodland Road<br />

Circle Pines, MN 55014 USA<br />

Tel. +1 763.404.8700<br />

Fax +1 763.225.6645<br />

info@natur-tec.com<br />

www.natur-tec.com<br />

4. Bioplastics products<br />

TECNARO GmbH<br />

Bustadt 40<br />

D-74360 Ilsfeld. Germany<br />

Tel: +49 (0)7<strong>06</strong>2/97687-0<br />

www.tecnaro.de<br />

1.3 PLA<br />

TianAn Biopolymer<br />

No. 68 Dagang 6th Rd,<br />

Beilun, Ningbo, China, 315800<br />

Tel. +86-57 48 68 62 50 2<br />

Fax +86-57 48 68 77 98 0<br />

enquiry@tianan-enmat.com<br />

www.tianan-enmat.com<br />

1.6 masterbatches<br />

Bio-on S.p.A.<br />

Via Santa Margherita al Colle 10/3<br />

40136 Bologna - ITALY<br />

Tel.: +39 051 392336<br />

info@bio-on.it<br />

www.bio-on.it<br />

NOVAMONT S.p.A.<br />

Via Fauser , 8<br />

28100 Novara - ITALIA<br />

Fax +39.0321.699.601<br />

Tel. +39.0321.699.611<br />

www.novamont.com<br />

Zhejiang Hisun Biomaterials Co.,Ltd.<br />

No.97 Waisha Rd, Jiaojiang District,<br />

Taizhou City, Zhejiang Province, China<br />

Tel: +86-576-88827723<br />

pla@hisunpharm.com<br />

www.hisunplas.com<br />

weforyou PLA & Applications<br />

office@weforyou.pro<br />

www.weforyou.pro<br />

1.4 starch-based bioplastics<br />

BIOTEC<br />

Biologische Naturverpackungen<br />

Werner-Heisenberg-Strasse 32<br />

46446 Emmerich/Germany<br />

Tel.: +49 (0) 2822 – 92510<br />

info@biotec.de<br />

www.biotec.de<br />

Grabio Greentech Corporation<br />

Tel: +886-3-598-6496<br />

No. 91, Guangfu N. Rd., Hsinchu<br />

Industrial Park,Hukou Township,<br />

Hsinchu County 30351, Taiwan<br />

sales@grabio.com.tw<br />

www.grabio.com.tw<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

Albrecht Dinkelaker<br />

Polymer and Product Development<br />

Blumenweg 2<br />

79669 Zell im Wiesental, Germany<br />

Tel.:+49 (0) 7625 91 84 58<br />

info@polyfea2.de<br />

www.caprowax-p.eu<br />

2. Additives/Secondary raw materials<br />

GRAFE-Group<br />

Waldecker Straße 21,<br />

99444 Blankenhain, Germany<br />

Tel. +49 36459 45 0<br />

www.grafe.com<br />

3. Semi finished products<br />

3.1 films<br />

Bio4Pack GmbH<br />

D-48419 Rheine, Germany<br />

Tel.: +49 (0) 5975 955 94 57<br />

info@bio4pack.com<br />

www.bio4pack.com<br />

BeoPlast Besgen GmbH<br />

Bioplastics injection moulding<br />

Industriestraße 64<br />

D-40764 Langenfeld, Germany<br />

Tel. +49 2173 84840-0<br />

info@beoplast.de<br />

www.beoplast.de<br />

INDOCHINE C, M, Y , K BIO C , M, Y, K PLASTIQUES<br />

45, 0,90, 0<br />

10, 0, 80,0<br />

(ICBP) C, M, Y, KSDN BHD<br />

C, M, Y, K<br />

50, 0 ,0, 0<br />

0, 0, 0, 0<br />

D-09, Jalan Tanjung A/4,<br />

Free Trade Zone<br />

Port of Tanjung Pelepas<br />

81560 Johor, Malaysia<br />

T. +607-507 1585<br />

icbp.bioplastic@gmail.com<br />

www.icbp.com.my<br />

President Packaging Ind., Corp.<br />

PLA Paper Hot Cup manufacture<br />

In Taiwan, www.ppi.com.tw<br />

Tel.: +886-6-570-4<strong>06</strong>6 ext.5531<br />

Fax: +886-6-570-4077<br />

sales@ppi.com.tw<br />

6. Equipment<br />

6.1 Machinery & Molds<br />

Buss AG<br />

Hohenrainstrasse 10<br />

4133 Pratteln / Switzerland<br />

Tel.: +41 61 825 66 00<br />

Fax: +41 61 825 68 58<br />

info@busscorp.com<br />

www.busscorp.com<br />

Molds, Change Parts and Turnkey<br />

Solutions for the PET/Bioplastic<br />

Container Industry<br />

284 Pinebush Road<br />

Cambridge Ontario<br />

Canada N1T 1Z6<br />

Tel. +1 519 624 9720<br />

Fax +1 519 624 9721<br />

info@hallink.com<br />

www.hallink.com<br />

6.2 Laboratory Equipment<br />

1.5 PHA<br />

Bio-on S.p.A.<br />

Via Santa Margherita al Colle 10/3<br />

40136 Bologna - ITALY<br />

Tel.: +39 051 392336<br />

info@bio-on.it<br />

www.bio-on.it<br />

Infiana Germany GmbH & Co. KG<br />

Zweibrückenstraße 15-25<br />

91301 Forchheim<br />

Tel. +49-9191 81-0<br />

Fax +49-9191 81-212<br />

www.infiana.com<br />

Minima Technology Co., Ltd.<br />

Esmy Huang, COO<br />

No.33. Yichang E. Rd., Taipin City,<br />

Taichung County<br />

411, Taiwan (R.O.C.)<br />

Tel. +886(4)2277 6888<br />

Fax +883(4)2277 6989<br />

Mobil +886(0)982-829988<br />

esmy@minima-tech.com<br />

Skype esmy325<br />

www.minima.com<br />

MODA: Biodegradability Analyzer<br />

SAIDA FDS INC.<br />

143-10 Isshiki, Yaizu,<br />

Shizuoka,Japan<br />

Tel:+81-54-624-6260<br />

Info2@moda.vg<br />

www.saidagroup.jp<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 59


Suppliers Guide<br />

7. Plant engineering<br />

‘Basics‘ book<br />

on bioplastics<br />

110 pages full<br />

color, paperback<br />

ISBN 978-3-<br />

9814981-1-0:<br />

Bioplastics<br />

ISBN 978-3-<br />

9814981-2-7:<br />

Biokunststoffe<br />

2. überarbeitete<br />

Auflage<br />

This book, created and published by Polymedia<br />

Publisher, maker of bioplastics MAGAZINE<br />

is available in English and German language<br />

(German now in the second, revised edition).<br />

EREMA Engineering Recycling<br />

Maschinen und Anlagen GmbH<br />

Unterfeldstrasse 3<br />

4052 Ansfelden, AUSTRIA<br />

Phone: +43 (0) 732 / 3190-0<br />

Fax: +43 (0) 732 / 3190-23<br />

erema@erema.at<br />

www.erema.at<br />

Uhde Inventa-Fischer GmbH<br />

Holzhauser Strasse 157–159<br />

D-13509 Berlin<br />

Tel. +49 30 43 567 5<br />

Fax +49 30 43 567 699<br />

sales.de@uhde-inventa-fischer.com<br />

Uhde Inventa-Fischer AG<br />

Via Innovativa 31, CH-7013 Domat/Ems<br />

Tel. +41 81 632 63 11<br />

Fax +41 81 632 74 03<br />

sales.ch@uhde-inventa-fischer.com<br />

www.uhde-inventa-fischer.com<br />

9. Services<br />

European Bioplastics e.V.<br />

Marienstr. 19/20<br />

10117 Berlin, Germany<br />

Tel. +49 30 284 82 350<br />

Fax +49 30 284 84 359<br />

info@european-bioplastics.org<br />

www.european-bioplastics.org<br />

10.2 Universities<br />

Institut für Kunststofftechnik<br />

Universität Stuttgart<br />

Böblinger Straße 70<br />

70199 Stuttgart<br />

Tel +49 711/685-62814<br />

silvia.kliem@ikt.uni-stuttgart.de<br />

www.ikt.uni-stuttgart.de<br />

Michigan State University<br />

Dept. of Chem. Eng & Mat. Sc.<br />

Professor Ramani Narayan<br />

East Lansing MI 48824, USA<br />

Tel. +1 517 719 7163<br />

narayan@msu.edu<br />

The book is intended to offer a rapid and uncomplicated<br />

introduction into the subject of bioplastics, and is aimed at all<br />

interested readers, in particular those who have not yet had<br />

the opportunity to dig deeply into the subject, such as students<br />

or those just joining this industry, and lay readers. It gives<br />

an introduction to plastics and bioplastics, explains which<br />

renewable resources can be used to produce bioplastics,<br />

what types of bioplastic exist, and which ones are already on<br />

the market. Further aspects, such as market development,<br />

the agricultural land required, and waste disposal, are also<br />

examined.<br />

An extensive index allows the reader to find specific aspects<br />

quickly, and is complemented by a comprehensive literature<br />

list and a guide to sources of additional information on the<br />

Internet.<br />

The author Michael Thielen is editor and publisher<br />

bioplastics MAGAZINE. He is a qualified machinery design<br />

engineer with a degree in plastics technology from the RWTH<br />

University in Aachen. He has written several books on the<br />

subject of blow-moulding technology and disseminated his<br />

knowledge of plastics in numerous presentations, seminars,<br />

guest lectures and teaching assignments.<br />

Order now for € 18.65 or US-$ 25.00 (+<br />

VAT where applicable, plus shipping and handling, ask<br />

for details) order at www.bioplasticsmagazine.de/books,<br />

by phone +49 2161 6884463 or by e-mail<br />

books@bioplasticsmagazine.com<br />

Or subscribe and get it as a free gift<br />

(see page 61 for details, outside German y only)<br />

Osterfelder Str. 3<br />

46047 Oberhausen<br />

Tel.: +49 (0)208 8598 1227<br />

thomas.wodke@umsicht.fhg.de<br />

www.umsicht.fraunhofer.de<br />

narocon<br />

Dr. Harald Kaeb<br />

Tel.: +49 30-28096930<br />

kaeb@narocon.de<br />

www.narocon.de<br />

9. Services (continued)<br />

nova-Institut GmbH<br />

Chemiepark Knapsack<br />

Industriestrasse 300<br />

50354 Huerth, Germany<br />

Tel.: +49(0)2233-48-14 40<br />

E-Mail: contact@nova-institut.de<br />

www.biobased.eu<br />

10. Institutions<br />

10.1 Associations<br />

BPI - The Biodegradable<br />

Products Institute<br />

331 West 57th Street, Suite 415<br />

New York, NY 10019, USA<br />

Tel. +1-888-274-5646<br />

info@bpiworld.org<br />

IfBB – Institute for Bioplastics<br />

and Biocomposites<br />

University of Applied Sciences<br />

and Arts Hanover<br />

Faculty II – Mechanical and<br />

Bioprocess Engineering<br />

Heisterbergallee 12<br />

30453 Hannover, Germany<br />

Tel.: +49 5 11 / 92 96 - 22 69<br />

Fax: +49 5 11 / 92 96 - 99 - 22 69<br />

lisa.mundzeck@hs-hannover.de<br />

www.ifbb-hannover.de/<br />

10.3 Other Institutions<br />

Green Serendipity<br />

Caroli Buitenhuis<br />

IJburglaan 836<br />

1087 EM Amsterdam<br />

The Netherlands<br />

Tel.: +31 6-24216733<br />

www.greenseredipity.nl<br />

60 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


Events<br />

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the next six issues for €169.– 1)<br />

Special offer<br />

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young professionals<br />

1,2) € 99.-<br />

2) aged 35 and below.<br />

end a scan of your<br />

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or similar proof ...<br />

European Biopolymer Summit<br />

14.02.2018 - 15.02.2018 - Duesseldorf, Germany<br />

www.wplgroup.com/aci/event/biopolymer-conference-europe/<br />

You can meet us<br />

World Bio Markets<br />

20.03.2018 - 22.03.2018 - Amsterdam, The Netherlands<br />

https://www.biobasedworldnews.com/events/world-bio-markets<br />

International Seminar PLASTICS ARE FUTURE<br />

24.04.2018 - 25.04.2018 - Valencia, Spain<br />

http://www.plasticsarefuture.com/home.php<br />

CHINAPLAS 2018<br />

The 32nd International Exhibition on Plastics &<br />

Rubber Industries<br />

24.04.2018 - 27.04.2018 - Shanghai, China<br />

adsale.hk/t.aspx?unt=2545-CPS18_Bioplastics_EN_calender<br />

ISSN 1862-5258<br />

WWW.MATERBI.COM COME TO VISIT US AT<br />

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05 | <strong>2017</strong><br />

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MARITIM PROARTE HOTEL • BERLIN<br />

Highlights<br />

Fibres & Textiles | 14<br />

Beauty & Healthcare | 34<br />

Basics<br />

Land use | 43<br />

ISSN 1862-5258<br />

Nov/Dec<br />

<strong>06</strong> | <strong>2017</strong><br />

Highlights<br />

Films / Flexibles / Bags | 12<br />

Polyurethanes / Elastomers | 14<br />

Basics<br />

Blown Film Extrusion | 48<br />

Polymer/Bioplastic Failure & Defects Problem Solving<br />

25.04.2018 – 26.04.2018 - Amsterdam<br />

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5 th PLA World Congress<br />

by bioplastics MAGAZINE<br />

29.-30. 05.2018 - Munich, Germany<br />

www.pla-world-congress.com<br />

bioplastics MAGAZINE Vol. 12<br />

e tore_bioplasticmagazine_11.12.<strong>2017</strong>_210x297_flagEBC_ese.indd 1 03/11/17 15:22<br />

... is read in 92 countries<br />

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bioplastics MAGAZINE Vol. 12<br />

C, M, Y , K<br />

45, 0,90, 0<br />

C, M, Y, K<br />

50, 0 ,0, 0<br />

C , M, Y, K<br />

10, 0, 80,0<br />

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Cover Story:<br />

Meet ICBP<br />

Malaysia‘s Bioplastics<br />

Industry Anchor |10<br />

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Special<br />

Plastics Tomorrow via Biobased Chemicals &<br />

Recycling<br />

25.<strong>06</strong>.2018 - 28.<strong>06</strong>.2018 - New York City Area, USA<br />

http://innoplastsolutions.com/bio.html<br />

BIO World Congress<br />

16.07.2018 - 19.07.2018 - Philadelphia PA, USA<br />

www.bio.org/worldcongress<br />

25th Anniversary meeting of the Bio-Environmental<br />

Polymer Society (BEPS)<br />

15.08.2018 - 17.08.2018 - Rensselaer Polytechnic University<br />

(RPI) (Troy, New York)<br />

http://homepages.rpi.edu/~grossr/index.htm<br />

or<br />

Mention the promotion code ‘watch‘ or ‘book‘<br />

and you will get our watch or the book 3)<br />

Bioplastics Basics. Applications. Markets. for free<br />

1) Offer valid until 28 February 2018<br />

3) Gratis-Buch in Deutschland nicht möglich, no free book in Germany<br />

bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12 61


Companies in this issue<br />

Company Editorial Advert Company Editorial Advert Company Editorial Advert<br />

ABB 10<br />

ACIB 36<br />

Adler Plastics 20<br />

Adsale (Chinaplas) 29<br />

Agrana Starch Bioplastics 58<br />

AIMPLAS 34, 36<br />

Amyris 26<br />

API Applicazioni Plastiche Industriali 7, 43 58<br />

Arlanxeao 14<br />

Avantium 34<br />

Barbier Group 13<br />

BASF 49 58<br />

Bcomp 45<br />

BeginAgain 24<br />

Beoplast 59<br />

Beta Analytic 14<br />

Bio4pack 41 59<br />

Bio-Fed Branch of Akro-Plastic 35, 58<br />

Bio-on 5 59<br />

Biotec 59<br />

BPI 6 60<br />

Braskem 7, 14, 38, 39, 41<br />

British Plastics Federation 5<br />

Bulldog Skin Care 39<br />

Buss 59<br />

Caprowachs, Albrecht Dinkelaker 59<br />

Caravelas 38<br />

Cardia Bioplastics 13 58<br />

Cathay Industrial Biotech 8<br />

Coop 41<br />

Corapack 39<br />

Covestro 21<br />

Dezhou Xinhuarun Techn. 20<br />

DIN-Certco 6<br />

Dr. Heinz Gupta Verlag 22<br />

DS Smith 44<br />

DSM 22<br />

Dynisco 27<br />

EcoPlaza 41<br />

Electric GT 45<br />

Ellen MacArthur Foundation 5<br />

EMS-Grivory 7<br />

Erema 25, 60<br />

European Bioplastics 6, 10, 43 60<br />

European Parliament 5, 6<br />

Ferguson Production 25<br />

FKuR 44 2, 58<br />

Ford Motor Company 17<br />

Fraunhofer UMSICHT 52 60<br />

Futamura 39<br />

Global Biopolymers 58<br />

Glycon 27<br />

Goodyear Tire & Rubber 40<br />

GRABIO Greentech Corporation 59<br />

Grafe 58, 59<br />

Green Dot Bioplastics 24 58<br />

Green Serendipity 60<br />

Growfun 40<br />

Gulf Petrochem. & Chem. Ass. 5<br />

Halder Topsoe 7<br />

Hallink 59<br />

Henkel 30<br />

Hexpol TPE 18 14<br />

Hydal 8, 11<br />

Indochine Bio Plastiques 59<br />

Infiana Germany 59<br />

InnProBio 8<br />

Inst. f. Bioplastics & Biocomp. 60<br />

Inst. F. Macromol. Studies 20<br />

Inst. Polym. Comp. & Biomat. 20<br />

IRIAF 37<br />

ISCC 16, 17<br />

Jinhui Zhaolong 58<br />

Kaneka 11 59<br />

Kingfa 58<br />

Kuraray 26<br />

Mädler 21<br />

Maip 10<br />

Malaysian Plastics Association 13<br />

Marks & Spencer 5<br />

Michigan State University 60<br />

Microtec 58<br />

Mid-Continent Tool & Molding 25<br />

Minima Technology 59<br />

Mondi 28<br />

Montgomery County Dept. 41<br />

Nafigate 8<br />

narocon 60<br />

Natureplast 37<br />

NatureWorks 23, 44<br />

Natur-Tec 59<br />

nova Institute 19, 60<br />

Novamont 59, 64<br />

NPE 33<br />

Nurel 58<br />

Packaging South Africa 5<br />

Parana 8<br />

PepsiCo 5<br />

Perstorp 16<br />

Pike's Peak Plastics 24<br />

plasticker 13<br />

Plásticos Romeros 36<br />

Plastiroll 39, 41, 43<br />

Plymouth Marine Laboratory 5<br />

Poiesz 41<br />

polymediaconsult 60<br />

President Packaging 59<br />

ProAmpac 41<br />

Promessa 41<br />

PTT/MCC 58<br />

Reverdia 20<br />

Rodenburg Biopolymers 40<br />

Roquette 58<br />

Roquette 21<br />

RPC 39<br />

Saida 59<br />

Sea-Lect Design 24<br />

Secos Group 13<br />

Sprig 43<br />

Stéfany Emballages Services 37<br />

Stellar Films 13<br />

Sukano 59<br />

SuperUnie 41<br />

Synbra 38, 44<br />

Synprodo 44<br />

Tapp Water 42<br />

Tecnaro 40 59<br />

Tesla 45<br />

TianAn Biopolymer 59<br />

Tipa 55<br />

Total-Corbion 9, 44 58<br />

Trinseo 7, 43<br />

Uhde Inventa-Fischer 60<br />

Unilever 5<br />

United Soybean Board 17, 40<br />

Univ. App. Sc. Hannover 46<br />

Univ. Leiden 36<br />

Univ. Stuttgart (IKT) 60<br />

Univ. Wageningen 40<br />

Univ Dortmund 474<br />

Vaude 20<br />

Veolia 5<br />

Waarmakers 37<br />

Wageningen Food & Biobased Res. 37<br />

Wageningen UR 21<br />

Weforyou 36 59<br />

Wildo Sweden 18<br />

Wolfgang Mock 40<br />

WWF 5<br />

Xinjiang Blue Ridge Tunhe Polyester 58<br />

Zaraplast 38<br />

Zhejiang Hangzhou Xinfu Pharm. 58<br />

Zhejiang Hisun Biomaterials 59<br />

<strong>Issue</strong><br />

Editorial Planner<br />

Month<br />

Publ.<br />

Date<br />

edit/ad/<br />

Deadline<br />

<strong>2017</strong>/18<br />

Edit. Focus 1 Edit. Focus 2 Edit. Focus 3 Basics<br />

01/2018 Jan/Feb 08 Jan 18 22 Dec 17 Automotive Foam Thailand (t.b.c) t.b.d.<br />

Trade-Fair<br />

Specials<br />

Subject to changes<br />

62 bioplastics MAGAZINE [<strong>06</strong>/17] Vol. 12


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