Issue 3/2018
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ISSN 1862-5258<br />
May / June<br />
03 | <strong>2018</strong><br />
bioplastics MAGAZINE Vol. 13<br />
Basics<br />
Castor Oil | 52<br />
Highlights<br />
Injection Moulding | 14<br />
Additives/Masterbatches | 18<br />
Cover Story:<br />
Netherlands to prohibit<br />
Oxo-degradables | 9<br />
... is read in 92 countries
Resins<br />
THE BIOPLASTIC<br />
SPECIALIST OFFERS:<br />
Elaborated product portfolio<br />
Technical support<br />
Marketing advice<br />
Tailor-made formulations<br />
PLA Blends<br />
Green PE Compounds<br />
Cellulose Compounds<br />
Bio-PA Compounds<br />
Bio-TPE Compounds<br />
Natural Fibre Compounds
Editorial<br />
dear<br />
readers<br />
Towards the end of May, most of us were absolutely swamped with e-mails asking<br />
us to re-subscribe or to confirm some subscription or the other - but mostly<br />
newsletters. And we apologize for being part of this annoying hassle. The reason<br />
is the European General Data Protection Regulation (GDPR) that came into force<br />
on May 25. So we’d like to take the opportunity here again to ask all who haven’t<br />
done so already to (re-) register for our free bi-weekly e-mail-newsletter and<br />
info-mailings about our events or other related products or services. We will use<br />
nothing but your e-mail address. And only for the aforementioned purposes. No<br />
third party will ever have access to your data.<br />
Here is the link tinyurl.com/bio-newsletter<br />
The soccer referee on our cover photo is Patrick Gerritsen, founder and CEO<br />
of Bio4pack (www.bio4pack.com). From 2003-2009, he was an official FIFA<br />
referee, presiding over 60 international matches, next to acting as match official<br />
in the “Koninklijke Nederlandse Voetbal Bond” (Dutch professional soccer<br />
league) from 1997 to 2015. The cover relates to the news on page 9, which, it<br />
should be noted, was also was the most clicked-on item in our daily online<br />
news on our website, namely ”The Netherlands looking to ban oxo-degradable<br />
plastics”.<br />
Other highlight topics of this issue are Injection moulding and Additives /<br />
Masterbatches. In the Basics section we have a closer look at Castor oil.<br />
The next event we’d like to bring to your attention is the new 1 st PHA platform World<br />
Congress in Cologne, Germany on the 4 th and 5 th of September.<br />
Plus: the call for proposals for the <strong>2018</strong> edition of the Global Bioplastics Award is also<br />
open (cf. p. 41). So if you think your product or service from the world of biobased plastics<br />
deserves the award, or you’d like to nominate somebody else’s, just let us know.<br />
And please don’t forget: for current news, be sure to check the latest reports, breaking<br />
news and daily news updates at www.bioplasticsmagazine.com.<br />
EcoComunicazione.it<br />
WWW.MATERBI.COM<br />
adv mela se tore_bioplasticmagazine_05.06.2017_210x297_ese.indd 1 05/05/17 11:39<br />
r1_05.2017<br />
bioplastics MAGAZINE Vol. 13<br />
ISSN 1862-5258<br />
Basics<br />
Castor Oil | 49<br />
Highlights<br />
Injection Moulding | 14<br />
Additives/Masterbatches | 18<br />
May / June<br />
Cover Story:<br />
Netherlands to prohibit<br />
Oxo-degradables | 9<br />
03 | <strong>2018</strong><br />
... is read in 92 countries<br />
We hope you enjoy reading bioplastics MAGAZINE.<br />
Sincerely yours<br />
Michael Thielen<br />
In this issue we have a closer look to India. India, also called the Republic of<br />
India. is a country in South Asia. It is the seventh-largest country by area, the<br />
second-most populous country (with over 1.2 billion people), and the most<br />
populous democracy in the world. It is bounded by the Indian Ocean on the<br />
south, the Arabian Sea on the southwest, and the Bay of Bengal on the southeast<br />
(Wikipedia).<br />
bioplastics MAGAZINE [03/18] Vol. 13 3
Content<br />
Imprint<br />
May / June 03|<strong>2018</strong><br />
3 Editorial<br />
5 News<br />
9 Cover Story<br />
10 Events<br />
26 Application News<br />
45 Material News<br />
48 Brand Owner<br />
49 Basics<br />
51 10 years ago<br />
58 Suppliers Guide<br />
61 Event Calendar<br />
62 Companies in this issue<br />
Publisher / Editorial<br />
Dr. Michael Thielen (MT)<br />
Samuel Brangenberg (SB)<br />
Head Office<br />
Polymedia Publisher GmbH<br />
Dammer Str. 112<br />
41066 Mönchengladbach, Germany<br />
phone: +49 (0)2161 6884469<br />
fax: +49 (0)2161 6884468<br />
info@bioplasticsmagazine.com<br />
www.bioplasticsmagazine.com<br />
Media Adviser<br />
Samsales (German language)<br />
phone: +49(0)2161-6884467<br />
fax: +49(0)2161 6884468<br />
s.brangenberg@samsales.de<br />
Michael Thielen (English Language)<br />
(see head office)<br />
Layout/Production<br />
Kerstin Neumeister<br />
Print<br />
Poligrāfijas grupa Mūkusala Ltd.<br />
1004 Riga, Latvia<br />
bioplastics MAGAZINE is printed on<br />
chlorine-free FSC certified paper.<br />
Print run: 3.300 copies<br />
Injection Moulding<br />
14 Dimensional stability of injection<br />
moulded bioplastics<br />
16 Injection moulded NFC<br />
Additives / Masterbatches<br />
18 Biobased masterbatches for PLA,<br />
PBS and biobased blends<br />
20 Biobased additives<br />
21 Renewable, sustainable mineral<br />
22 Bio-Masterbatches with ecofriendly,<br />
mineral pigments<br />
23 Biobased wax additives<br />
From Science & Research<br />
28 PHBV from waste water<br />
30 Breaking barrier for clean &<br />
green BioPolyols<br />
34 Biobased filler for SMC<br />
38 Astroplastic<br />
Report<br />
28 Spanish project will develop customized<br />
materials<br />
46 The journey of bioplastics in the Indian<br />
subcontinent<br />
INDIA<br />
32 Compostable sanitary napkins for<br />
India’s girls and women<br />
Materials<br />
37 Sun protection cosmetics<br />
40 Thermoplastic Starch<br />
Trade shows<br />
24 Chinaplas-Review<br />
42 NPE-Review<br />
bioplastics magazine<br />
ISSN 1862-5258<br />
bM is published 6 times a year.<br />
This publication is sent to qualified subscribers<br />
(169 Euro for 6 issues).<br />
bioplastics MAGAZINE is read in<br />
92 countries.<br />
Every effort is made to verify all Information<br />
published, but Polymedia Publisher<br />
cannot accept responsibility for any errors<br />
or omissions or for any losses that may<br />
arise as a result.<br />
All articles appearing in<br />
bioplastics MAGAZINE, or on the website<br />
www.bioplasticsmagazine.com are strictly<br />
covered by copyright. No part of this<br />
publication may be reproduced, copied,<br />
scanned, photographed and/or stored<br />
in any form, including electronic format,<br />
without the prior consent of the publisher.<br />
Opinions expressed in articles do not<br />
necessarily reflect those of Polymedia<br />
Publisher.<br />
bioplastics MAGAZINE welcomes contributions<br />
for publication. Submissions are<br />
accepted on the basis of full assignment<br />
of copyright to Polymedia Publisher GmbH<br />
unless otherwise agreed in advance and in<br />
writing. We reserve the right to edit items<br />
for reasons of space, clarity or legality.<br />
Please contact the editorial office via<br />
mt@bioplasticsmagazine.com.<br />
The fact that product names may not be<br />
identified in our editorial as trade marks<br />
is not an indication that such names are<br />
not registered trade marks.<br />
bioplastics MAGAZINE tries to use British<br />
spelling. However, in articles based on<br />
information from the USA, American<br />
spelling may also be used.<br />
Envelopes<br />
A part of this print run is mailed to the<br />
readers wrapped in bioplastic envelopes<br />
sponsored by Plastiroll Oy, Finland.<br />
Cover<br />
Photo: Jan Ligtenberg<br />
Follow us on twitter:<br />
http://twitter.com/bioplasticsmag<br />
Like us on Facebook:<br />
https://www.facebook.com/bioplasticsmagazine
daily upated news at<br />
www.bioplasticsmagazine.com<br />
News<br />
Packaging related properties of biopolymers<br />
Because of the multitude of biopolymers on the market it<br />
is often difficult to gain an overview about their packaging<br />
related properties. For this reason, Verena Jost from<br />
the Fraunhofer Institute for Process Engineering and<br />
Packaging IVV (Freising, Germany) extruded and analysed<br />
various commercially available biopolymers. The oxygen<br />
and water vapour barrier, crystallinity, tensile strength,<br />
elongation at break and Young’s modulus of PLA, PHAs,<br />
PHB, PHBHB, PHBV, TPS, PBAT, PBS, PCL and BioPE<br />
were analysed. The results show the broad range of<br />
mechanical and barrier properties of biopolymer films<br />
that can be achieved by currently available grades. From<br />
the functional point of view, the commodity polymers<br />
PE and PP can be well complemented by the analysed<br />
biopolymers. MT<br />
Young‘s modulus YM [GPa]<br />
5 —<br />
—<br />
4<br />
—<br />
3 —<br />
—<br />
2 —<br />
—<br />
1 —<br />
BioPE PP-HD<br />
PBAT+PLA+filler<br />
—<br />
PLC<br />
PBAT+PLA<br />
PP-LD PBAT<br />
PBS TPS<br />
TPU<br />
0 —<br />
0 20 40 60 200 250<br />
Tensile strength σ [MPa]<br />
—<br />
—<br />
PHB<br />
—<br />
PHBV11<br />
PHBV7<br />
—<br />
PHBV3<br />
—<br />
PHBHB18<br />
PP<br />
PHBHB10+PLA+filler<br />
PHBHB13<br />
—<br />
—<br />
PLA<br />
—<br />
PET-BO<br />
—<br />
—<br />
Info:<br />
1: The complete report can be downloaded from<br />
tinyurl.com/bm<strong>2018</strong>03<br />
www.ivv.fraunhofer.de<br />
Picks & clicks<br />
Most frequently clicked news<br />
Magnetic<br />
for Plastics<br />
www.plasticker.com<br />
Here’s a look at our most popular online content of the past two<br />
months. The story that got the most clicks from the visitors to<br />
bioplasticsmagazine.com was:<br />
The Netherlands looking to ban oxo-degradable plastics<br />
(29 Mar <strong>2018</strong>)<br />
After France and Spain implemented actions in 2017 to limit the production,<br />
distribution, sale, provision and utilization of packaging or bags made<br />
from oxo-degradable plastics – conventional plastics that falsely claim<br />
to biodegrade – the Netherlands now, too, has announced plans for a<br />
complete ban of oxo-degradable plastics.<br />
See also our Cover-Story on page 9<br />
• International Trade<br />
in Raw Materials, Machinery & Products Free of Charge.<br />
• Daily News<br />
from the Industrial Sector and the Plastics Markets.<br />
• Current Market Prices<br />
for Plastics.<br />
• Buyer’s Guide<br />
for Plastics & Additives, Machinery & Equipment, Subcontractors<br />
and Services.<br />
• Job Market<br />
for Specialists and Executive Staff in the Plastics Industry.<br />
Up-to-date • Fast • Professional<br />
bioplastics MAGAZINE [03/18] Vol. 13 5
News<br />
daily upated news at<br />
www.bioplasticsmagazine.com<br />
Camphor as viable alternative to castor oil for<br />
production bio-PA?<br />
Within the scope of the Camphor-based polymers<br />
international research project, the Fraunhofer Institute IGB<br />
will, in the coming year, research sustainable production<br />
processes for biobased monomers.<br />
The Camphor-based polymers<br />
project, a collaborative effort between<br />
the IGB branch Bio, Electro and<br />
Chemocatalysis BioCat in Straubing,<br />
Germany and research and industry<br />
partners, aims to develop technology<br />
that will make it possible to use residual<br />
materials from pulp production for the<br />
manufacture of plastics.<br />
Castor (ricinus) oil is one biobased<br />
alternative to crude oil as a starting material for the production<br />
of polyamides; however, it has some disadvantages: processing<br />
is complex and several synthesis steps are required to convert<br />
castor oil into monomers.<br />
BioCat and its project partners are investigating the use of<br />
terpene camphor for the production of biobased monomers<br />
for polyamides and polyesters. Moreover, in contrast to castor<br />
oil production, both the extraction and processing of camphor<br />
is unproblematic. The terpene is produced in large quantities<br />
in China from by-products of the pulp industry and is therefore<br />
not only a sustainable raw material, but also readily available.<br />
In addition, only a single synthesis step is required to produce<br />
the targeted biomonomers.<br />
As part of the Camphor-based polymers project, BioCat and<br />
its partners are working on an efficient biocatalytic process for<br />
the selective functionalization of the camphor into biobased<br />
monomers.<br />
“The ultimate goal of our project is<br />
the sustainable production of biobased<br />
polymers, which ranges from the use of<br />
natural terpenes from the Chinese pulp<br />
industry to the production of polymeric<br />
materials in Germany,” said IGB scientist<br />
Dr. Michael Hofer, who heads the project<br />
at BioCat.<br />
In order to achieve this goal and to<br />
map out the entire value-added chain,<br />
Hofer and his team are working together<br />
with scientific and industrial project partners from China and<br />
Germany. Worldwide, pulp-based camphor production currently<br />
amounts to 17 000 tonnes per year, mainly produced by just five<br />
Chinese pulp manufacturers. One of these was enlisted as an<br />
industrial partner for the project “Camphor-based polymers”.<br />
The potential for global camphor production based on pulp is<br />
estimated by the project partners to be 100 000 tonnes.<br />
The project, which was launched in January <strong>2018</strong>, is<br />
scheduled to run until December 2020 and is coordinated by the<br />
Chair of Chemistry of Biogenic Raw Materials at the Technical<br />
University of Munich. The Federal Ministry of Education and<br />
Research is funding the project as part of the “Bioeconomy<br />
international” program. MT<br />
https://is.gd/PDuoR7 (Fraunhofer IGB)<br />
DuPont & Archer Daniels Midland open<br />
biobased pilot facility<br />
End of April <strong>2018</strong>, DuPont Industrial Biosciences (DuPont) and Archer Daniels Midland Company (ADM) announced the<br />
opening of the world’s first biobased furan dicarboxylic methyl ester (FDME) pilot production facility in Decatur, Illinois. The<br />
plant is the centerpiece of a long-standing collaboration that will help bring a greater variety of sustainably sourced biomaterials<br />
into the lives of consumers.<br />
FDME is a molecule derived from fructose that can be used to create a variety of biobased chemicals and materials, including<br />
plastics, that are ultimately more cost-effective, efficient and sustainable than their<br />
fossil fuel-based counterparts.<br />
One of the first FDME-based polymers under development by DuPont is<br />
polytrimethylene furandicarboxyate (PTF), a novel polyester also made from DuPont’s<br />
proprietary Bio-PDO (1,3-propanediol). PTF is a 100 % renewable polymer that, in<br />
bottling applications, can be used to create plastic bottles that are lighter-weight,<br />
more sustainable and better performing.<br />
Research shows that PTF has up to 10-15 times the CO2 barrier performance of<br />
traditional PET plastic, which results in a longer shelf life. With that better barrier,<br />
companies will be able to design significantly lighter-weight packages, lowering the<br />
carbon emissions and significant costs related with shipping carbonated beverages. MT<br />
www.biosciences.dupont.com<br />
6 bioplastics MAGAZINE [03/18] Vol. 13
News<br />
BioAmber announces<br />
filing for stay of proceedings<br />
on creditors<br />
BioAmber Inc. announced on May 4th, that it filed a<br />
voluntary petition for relief under chapter 11 of the United<br />
States Bankruptcy Code<br />
Its two Canadian subsidiaries, BioAmber Sarnia Inc. and<br />
BioAmber Canada Inc., filed a Notice of Intention (the "NOI")<br />
to make a proposal under the Bankruptcy and Insolvency Act<br />
(Canada), with a view to strengthening the company’s financial<br />
health and solidifying its long-term business prospects.<br />
BioAmber believes filing these procedures is the best way<br />
to protect all stakeholders and will best facilitate its efforts to<br />
renegotiate its debt and raise the funds needed to continue<br />
its operations. The filing of these procedures has the effect of<br />
imposing an automatic stay of proceedings that will protect<br />
the company, its Canadian subsidiaries and their assets<br />
from the claims of creditors while the company pursues its<br />
restructuring efforts.<br />
There can be no guarantee that the company will be<br />
successful in securing further financing or achieving its<br />
restructuring objectives. Failure by the company to achieve<br />
its financing and restructuring goals will likely result in<br />
the company and/or its subsidiaries being forced to cease<br />
operations and liquidate its assets<br />
Pursuant to the NOI filing, PricewaterhouseCoopers Inc. has<br />
been appointed as the trustee in the proposal proceedings. MT<br />
www.bio-amber.com<br />
Symphony<br />
Environmental moves<br />
into the bioplastic<br />
sector<br />
Symphony Environmental Technologies has signed<br />
a collaboration agreement and commitment to a<br />
strategic investment with French biotechnology start<br />
up, Eranova.<br />
bEranova has developed a technology which extracts<br />
starch from algae which can be used to produce a range<br />
of compostable and biodegradable bioplastics. Other<br />
applications include biofuel, biopolymers, proteins for<br />
food and animal feed stock, and by-products for the<br />
pharmaceutical and cosmetic industries.<br />
The key benefits of the technology, said Symphony,<br />
are, among other things, the fact that a natural,<br />
renewable waste product which pollutes beaches can<br />
now be put to good use; also, algae are a non-foodbased<br />
resource, which do not impact the food industry,<br />
in addition to providing higher yields per hectare due to<br />
the fast growing rate of algae.<br />
The agreement marks Symphony’s first move into<br />
the bioplastics sector. The UK-based company is a<br />
producer of a wide range of polymer masterbatches and<br />
additives, including oxo-degradable and anti-microbial<br />
technologies.MT<br />
www.symphonyenvironmental.com<br />
Full stereocomplex PLA technology now<br />
commercially available from Total Corbion PLA<br />
Total Corbion PLA, Gorinchem,The Netherlands, recently<br />
announces the launch of a novel technology that can create full<br />
stereocomplex PLA in a broad range of industrial applications.<br />
The proprietary technology will enable PLA applications able<br />
to withstand temperatures close to 200°C (HDT-A).<br />
The new technology enables stereocomplex PLA – a<br />
material with long, regularly interlocking polymer chains that<br />
enable an even higher heat resistance than standard PLA.<br />
This breakthrough in PLA temperature resistance unlocks<br />
a range of new application possibilities, and provides a<br />
biobased replacement for PBT and PA glass fiber reinforced<br />
products. For example, injection molded applications for<br />
under-the-hood automotive components can now be made<br />
from glass fiber reinforced stereocomplex PLA, offering both<br />
a higher biobased content and a reduced carbon footprint.<br />
The technology can offer these same sustainability benefits to<br />
the wider automotive, aerospace, electronics,home appliance,<br />
marine and construction industries.<br />
“Over the past decades, the benefits of full stereocomplex<br />
PLA have been studied by universities and R&D departments<br />
on a laboratory scale”, says Stefan Barot, Senior Business<br />
Director Asia Pacific. “Now, Total Corbion PLA is the first<br />
company to scale up this technology and make it available<br />
for a broad range of industrial applications. The technology<br />
enables full stereocomplex morphology not only in the lab<br />
environment but also in commercial production facilities”.<br />
Commercial samples of full stereocomplex PLA will soon<br />
be made available for customer evaluation. Total Corbion PLA<br />
is looking for brand owners, converters and compounders<br />
that wish to validate and capitalize on this new technology. MT<br />
www.total-corbion.com<br />
bioplastics MAGAZINE [03/18] Vol. 13 7
Richard Altice named<br />
new president and CEO of NatureWorks<br />
NatureWorks’ board of directors has named Richard<br />
Altice as the company’s new President and Chief Executive<br />
Officer, replacing Marc Verbruggen, who led the company<br />
from 2008 to his retirement in 2017.<br />
Altice comes to NatureWorks from PolyOne Corporation<br />
where he was Senior Vice President and President –<br />
Designed Structures and Solutions. At PolyOne, he had<br />
global responsibility for the sheet, roll stock, and<br />
formed packaging business. Prior to PolyOne,<br />
Altice also served as Vice President of Hexion’s<br />
global specialty epoxy business focused on<br />
coatings and composites. Altice holds a Bachelor<br />
of Science degree in Chemical Engineering from<br />
Missouri University of Science and Technology.<br />
“We are pleased to welcome Rich as<br />
NatureWorks’ CEO. Rich is an exemplary leader.<br />
He brings broad experience and demonstrated<br />
success in international business, strategic<br />
marketing, and building highly effective teams<br />
to serve customers in the polymer and chemical<br />
industry,” said Peter Hawthorne, Chairman of the Board. “We<br />
believe Rich’s leadership will advance market development<br />
and the adoption of NatureWorks’ performance materials in<br />
new applications.”<br />
“Through my prior work experience, I became familiar<br />
with NatureWorks and thought very highly of the company<br />
and its products,” said Altice. In a personal meeting with<br />
bioplastics MAGAZINE Rich added: ”I’m excited about the time<br />
in which I have joined NatureWorks, seeing an enormous<br />
amount of efforts by very dedicated, long-term employees in<br />
this company. I think they have really created NatureWorks<br />
culture, the company’s leadership, and the market interest<br />
in renewably sourced advanced polymers and chemicals.<br />
This all presents an exciting opportunity”.<br />
NatureWorks was the first company to offer commercially<br />
available low-carbon-footprint bioplastics derived<br />
from 100 % annually renewable resources. Recently,<br />
NatureWorks reached the milestone of 900,000 tonnes<br />
(2 bn pounds) of Ingeo biopolymer sold globally via its<br />
comprehensive portfolio of 33 grades, which<br />
are converted into thousands of consumer<br />
and industrial products. In 2017, the company<br />
launched a performance chemicals business<br />
with the new Vercet platform for adhesives<br />
and coatings. Along with its customers<br />
and supply chain partners, NatureWorks<br />
continues to introduce new, innovative Ingeobased<br />
applications across a spectrum of<br />
industries, including expanded offerings<br />
for 3D printing filaments, a first-of-itskind<br />
liner to increase the energy efficiency<br />
of refrigerators (cf. p. 45), and hydrophilic<br />
nonwovens for absorbent hygiene products. With leading<br />
coffee companies, NatureWorks is developing a new<br />
generation of high performance compostable capsules for<br />
single-serve coffee makers.<br />
These applications and more will be discussed at<br />
Innovation Takes Root, the international forum on advanced<br />
biomaterials, this September in San Diego, California.<br />
bioplastics MAGAZINE will then do a more comprehensive<br />
interview with Richard Altice, who is married, father of two<br />
daughters and who, when not working for NatureWorks,<br />
loves outdoor activities like hiking, running and golf. MT<br />
www.natureworksllc.com<br />
Bioplastics will outpace the economy as a whole<br />
In a Plastics Market Watch report released 10 May, entitled Watching: Bioplastics – the Plastics Industry Association<br />
(PLASTICS) reports bioplastics are in a growth cycle stage and will outpace the economy as a whole.<br />
New investments and entrants in the sector and new products and manufacturing technologies are projected to make<br />
bioplastics more competitive and dynamic.<br />
The report finds growing interest in bioplastics, but also a continued need for education. According to a survey PLASTICS<br />
conducted of U.S. consumers in January <strong>2018</strong>, more consumers are “familiar” or “somewhat familiar” with bioplastics<br />
compared to a survey conducted just two years ago; 32 % of consumers are familiar with bioplastics in <strong>2018</strong> compared to only<br />
27 % in 2016. The PLASTICS survey also indicated 64 % of consumers would prefer to buy a product made with bioplastics – and<br />
expect to see bioplastics in disposable plastic tableware, plastic bags, food and cosmetic packaging, and toys.<br />
As bioplastics product applications continue to expand, the growth dynamics of the industry will continue to shift. Looking at<br />
industry studies on market segmentation, packaging is the largest segment of the market at 37 % followed by bottles at 32 %.<br />
Growth opportunities in bioplastics manufacturing are expected to continue from the demand and supply side. While in the past<br />
growth in bioplastics was primarily driven by higher petrol-based polymers, changes in consumer behavior will be a significant<br />
factor for higher demand of bioplastics.<br />
The report is available for download to members and non-members.<br />
www.plasticsindustry.org<br />
8 bioplastics MAGAZINE [03/18] Vol. 13
Cover-Story<br />
The Netherlands looking to ban<br />
oxo-degradable plastics<br />
After France and Spain implemented actions in 2017 to limit the production, distribution, sale, provision and utilization of<br />
packaging or bags made from oxo-degradable plastics – conventional plastics that falsely claim to biodegrade – the Netherlands<br />
now, too, has announced plans for a complete ban of oxo-degradable plastics.<br />
“A ban on oxo-plastics that fall apart into microplastics is an important step in the fight against pollution,” said Suzanne Kröger,<br />
Member of the Dutch Parliament and GroenLinks, the party that submitted the proposal in the Lower House. "Microplastics are<br />
an increasing problem. They end up in nature, in the food chain and in our bodies. It is important for a total ban to be imposed<br />
on these plastics that fall apart as soon as possible. If it can no longer be produced, then this rubbish will no longer end up in<br />
our nature" [1]<br />
The announcement followed a report by the European Commission earlier in January this year announcing plans to restrict<br />
the use of these materials in Europe. The New Plastics Economy initiative of the Ellen MacArthur Foundation called for a ban<br />
on oxo-degradable plastics as early as November last year. "Although there is a perception that these materials are safely<br />
biodegradable, there is scientific evidence that they can be harmful to the food chain," said The New Plastics Economy [2].<br />
The use of oxo-degradable plastics for bags, bottles and labels is on the rise in different areas of the world. Made from<br />
conventional, fossil-based polymers to which chemical additives are added to promote degradation, these plastics disintegrate<br />
at an accelerated rate following exposure to UV-light, oxygen or heat.<br />
The key word in this context is ‘disintegrate’: rather than undergoing biodegradation, the plastic breaks down into tiny<br />
particles, which contributes to the formation of microplastics. The microparticles can be found in plankton and algae, among<br />
other things, and therefore spread easily into other organisms, according to GroenLinks [2].<br />
The Netherlands supports a full ban, rather than the restricted use proposed by the Commission. “If it is no longer allowed<br />
to be produced, it will no longer be able to find its way into our environment,” said Kröger. MT<br />
[1] www.pakkracht.biz<br />
[2] www.duurzaambedrijfsleven.nl<br />
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1804012ERE_Bioplastics Magazine.indd 1 bioplastics MAGAZINE 25.04.18 [03/18] Vol. 15:4413<br />
9
Events<br />
organized by<br />
Co-organized by Jan Ravenstijn<br />
www.pha-world-congress.com<br />
4 th PHA platform World Congress, preliminary programme<br />
Tuesday, Sep 04, <strong>2018</strong><br />
08:45-09:15 Jan Ravenstijn The PHA Platform - Virtues and Challenges<br />
09:15-09:40 Mats Linder, Ellen MacArthur Foundation The role of PHA in a circular economy for plastics<br />
09:40-10:05 Michael Carus, nova Institute<br />
Production capacities of bio-based polymers –<br />
status and outlook & political and social framework for further growth<br />
10:05-10:30 Erwin LePoudre, Kaneka Marketing of Biodegradable Polymer PHBHTM as a Solution to Plastic Waste <strong>Issue</strong>s<br />
11:10-11:35 Harald Kaeb, narocon Pitfalls and opportunities for marketing PHA products<br />
11:35-12:00 Fred Bollen, LifetecVision Exploiting competitive advantage and creating market attractiveness for PHA-polymers<br />
12:00-12:25 Jos Labée, Modified Materials Use of PHBH in fishing gear<br />
12:25-12:50 Sam Deconinck, OWS Biodegradation of PHAs: not simply a fixed feature<br />
Phil van Trump, Danimer<br />
14:00-14:30<br />
& Garry Kohl, PepsiCo<br />
PHA for packaging applications (t.b.c.)<br />
14:30-14:55 Eligio Martini, MAIP PHBH compounds for electrical switches (ABB)<br />
14:55-15:20 Pieter Samyn, Hasselt University<br />
Formulation and processing of PHB with fibrillated<br />
cellulose for nanocomposite films and paper coatings<br />
15:20-15:45 Urs Hänggi, Biomer Virgin PHB has thermoplastic properties, but is not a thermoplast<br />
16:00-16:20 Coffee<br />
16:20-16:55 Eike Langenberg & Carsten Niermann, FKuR Meet the needs for future legislations: Innovative PHA compounds<br />
16:55-17:20 Remy Jongboom, Biotec PHBH compounds for bags?<br />
Wednesday, Sep. 05, <strong>2018</strong><br />
09:00-09:25 Karel Wilsens, AMIBM Nucleating agents for PHAs and other biopolymers<br />
09:25-09:50 Christophe Collet, Scion Research From pine to PHA products<br />
09:50-10:15 Leon Korving, Phario High quality PHBV from wastewater<br />
10:15-10:40 Lenka Mynářová, Hydal/Nafigate Hydal PHA – Circular Economy Concept<br />
11:20-11:45 Li Teng, Bluepha<br />
11:45-12:10 Molly Morse, Mango Materials t.b.d.<br />
12:10-12:35 Andrew Falcon, FullCycle Bioplastics PHB/PHBV from waste streams<br />
Bluepha: Industrial-scale Low-cost P(3HB-co-4HB)<br />
Production using Halomonas bluephagenesis TD via an Open Fermentation Process<br />
14:00-14.25 Christian Bonten, IKT, Univ. Stuttgart Impact modification of PHB by building of a blockcopolymer<br />
14:25-14:50 Harold van der Zande, Stamicarbon PHA coating for slow release fertilization<br />
14:50-15:15 Ruud Rouleaux, Helian (on behalf of Tianan) PHBV from Tianan / 3D printing applications<br />
16:05-16:30 Kenichiro Nishi, Kaneka PHBH applications presentation<br />
16:30-16:55 Alessandro Carfagnini, Sabio Kartell (design furniture)<br />
16:55-17:20 Stefan Jockenhövel, AMIBM Role of Biodegradable Polymers for (Regenerative) Medicine<br />
Subject to changes, please visit the conference website<br />
10 bioplastics MAGAZINE [03/18] Vol. 13
Automotive<br />
Save the Date<br />
04-05 Sep <strong>2018</strong><br />
Cologne, Germany<br />
Register now, and benefit from our<br />
Early Bird discount until June 30/<strong>2018</strong><br />
www.pha-world-congress.com<br />
organized by<br />
Co-organized by Jan Ravenstijn<br />
PHA (Poly-Hydroxy-Alkanoates or polyhydroxy fatty acids) is a family of biobased polyesters. As in many<br />
mammals, including humans, that hold energy reserves in the form of body fat there are also bacteria that<br />
hold intracellular reserves of polyhydroxy alkanoates. Here the micro-organisms store a particularly high level<br />
of energy reserves (up to 80% of their own body weight) for when their sources of nutrition become scarce.<br />
Examples for such Polyhydroxyalkanoates are PHB, PHV, PHBV, PHBH and many more. That’s why we speak<br />
about the PHA platform.<br />
This PHA-platform is made up of a large variety of bioplastics raw materials made from many different renewable<br />
resources. Depending on the type of PHA, they can be used for applications in films and rigid packaging,<br />
biomedical applications, automotive, consumer electronics, appliances, toys, glues, adhesives, paints, coatings,<br />
fi bers for woven and non-woven and inks. So PHAs cover a broad range of properties and applications.<br />
That’s why bioplastics MAGAZINE and Jan Ravenstijn are now organizing the 1 st PHA-platform World Congress<br />
on 4-5 September <strong>2018</strong> in Cologne / Germany.<br />
This congress will address the progress, challenges and market opportunities for the formation of this new polymer<br />
platform in the world. Every step in the value chain will be addressed. Raw materials, polymer manufacturing,<br />
compounding, polymer processing, applications, opportunities and end-of-life options will be discussed.<br />
When there is sufficient interest there will be a workshop on the basics of the PHA-platform in the afternoon of<br />
September 3 rd , preceding the conference.See website for details.<br />
Platinum Sponsor:<br />
Gold Sponsor:<br />
Silver Sponsor:<br />
Media Partner:<br />
Supported by:<br />
Bronze Sponsor:<br />
1 st Media Partner<br />
Institut<br />
für Ökologie und Innovation<br />
bioplastics MAGAZINE [03/18] Vol. 13 11
Events<br />
Glass fibre reinforced<br />
PLA wins award<br />
Innovation Award Bio-based Material of the Year <strong>2018</strong><br />
for Arctic Biomaterials<br />
The Innovation Award Bio-based Material of the Year<br />
<strong>2018</strong> was awarded to three innovative bio-based materials.<br />
The competition focused on new developments in the biobased<br />
economy, which have a market launch in <strong>2018</strong>. The<br />
winners were elected on 15 May by the participants of the<br />
11th International Conference on Bio-based Materials in<br />
Cologne, Germany. As in the previous year, the award was<br />
sponsored by InfraServ GmbH & Co. Knapsack KG, a service<br />
provider for the planning, construction and operation of<br />
plants and sites.<br />
The “International Conference on Bio-based Materials”<br />
is organised by nova-Institute (Germany) and a wellestablished<br />
global meeting point for companies working<br />
in the field of bio-based chemicals and materials. 205<br />
participants, mainly from the industry and representing 22<br />
countries, met in Cologne on 15 and 16 May <strong>2018</strong> to discuss<br />
the latest developments in the sector. 21 companies<br />
presented their products and services at the exhibition.<br />
The winners in detail:<br />
No 1: Arctic Biomaterials Oy (Finland):<br />
Degradable PLA reinforced with glass fibre that erodes<br />
back to harmless minerals in composting environment<br />
ArcBioxTM BGF30-B1 is a Polylactic Acid (PLA) that<br />
is reinforced using LFT (long fibre) technology with a<br />
special degradable glass fibres. This innovation makes it<br />
possible that bio-based plastics can be used in technically<br />
demanding durable applications and still have the option<br />
of biodegradation at the end of life. The<br />
reinforcement is a glass fibre<br />
developed by Arctic<br />
Biomaterials Oy (ABM) and can also be used for<br />
several other bio-based polymers. This composite material<br />
reduces the carbon footprint and use of non-renewable<br />
energy of a composite product drastically compared to<br />
fossil-based reinforced plastics. This reinforced PLA is<br />
compostable and certified by the seedling mark from DIN<br />
CERTCO. More information: www.abmcomposite.com<br />
No 2: Cardolite Corporation (US/Belgium):<br />
Cashew nutshell residual-based blocking agent<br />
NX-2026 is an ultra-high purity 3-pentadeca-dienylphenol<br />
recently developed by Cardolite through advanced<br />
proprietary process technology. 3-pentadeca-dienyl-phenol<br />
is the main component distilled from cashew nutshell<br />
liquid, a renewable and non-edible resin extracted from<br />
the honeycomb structure of the cashew nut. NX-2026 has<br />
been successfully introduced to the coating and adhesive<br />
market as a non-toxic isocyanate (NCO) blocking agent that<br />
is a suitable replacement for petrochemical phenols. NCO<br />
systems blocked with NX-2026 provide lower viscosity and<br />
deblocking temperature than equivalent systems blocked<br />
with phenols. Moreover, NX-2026 blocked NCO prepolymers<br />
can be used in 2K epoxy systems to improve bond and T-peel<br />
strengths while maintaining good cure properties. More<br />
information: www.cardolite.com<br />
No 3: AIMPLAS Instituto Tecnológico del Plástico<br />
(Spain):<br />
Bio-based and biodegradable nets for green beans<br />
A packaging<br />
material which is more<br />
than 80% bio-based<br />
and more sustainable<br />
than conventional<br />
polyethylene nets but<br />
has similar linear<br />
weight and mechanical<br />
properties. The<br />
innovative product is<br />
a biodegradable net<br />
suitable for green beans packaging. A compound has been<br />
developed through reactive extrusion and the combination<br />
of different biodegradable materials and additives. Chemical<br />
modification was made by grafting low molecular weight<br />
units, such as oleic alcohol, obtained by the fermentation of<br />
sugars extracted from vegetable waste (watermelon). More<br />
information: www.aimplas.es<br />
www.bio-based-conference.com<br />
www.nova-institute.eu<br />
The nova-Institute would like to thank:<br />
The nova-Institute would like to thank InfraServ GmbH<br />
& Co. Knapsack KG (Germany) for sponsoring the<br />
renowned Innovation Award “Bio-based Material of the<br />
Year <strong>2018</strong>”.<br />
BASF SE (Germany) and UPM Biochemicals (Finland/<br />
Germany) are supporting the conference as Silver<br />
Sponsors and Neste SA (Finland/Suisse), FKUR<br />
Kunststoff GmbH (Germany) and Synvina C. V.<br />
(Netherlands) as a Bronze Sponsor.<br />
12 bioplastics MAGAZINE [03/18] Vol. 13
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nova-Institute Events in <strong>2018</strong><br />
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18 September <strong>2018</strong><br />
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All conferences at www.bio-based.eu<br />
bioplastics MAGAZINE [03/18] Vol. 13 13
Injection Moulding<br />
Dimensional stability of<br />
injection moulded bioplastics<br />
During processing plastics, there are different fundamental<br />
factors that influence the quality of a component.<br />
A key factor for the injection moulding process<br />
is the dimensional stability. This describes how much the<br />
dimensions of the processed part deviate from the specified<br />
dimension after processing. In particular, problems<br />
often quickly arise here due to different shrinkage and warpage<br />
properties, once a new material, such as a bioplastic,<br />
should be used for an existing injection moulded component.<br />
At the Institute for Bioplastics and Biocomposites –<br />
IfBB, University of Applied Sciences and Arts, Hanover, various<br />
bioplastics were therefore investigated in more detail.<br />
The following marketable and commercially available materials<br />
were examined:<br />
material to be substituted, differs strongly in its shrinkage<br />
properties, this usually leads to processing problems and<br />
requires a corresponding adjustment of the cavity. It is<br />
therefore not possible to make the general statement that<br />
a slight shrinkage is good and a large shrinkage is bad. As<br />
a general rule, if the cavity should not be reconstructed<br />
to suit the material, the bioplastic should exhibit similar<br />
shrinkage behaviour as the petrochemical material to be<br />
substituted. In addition, when processing bioplastics – as<br />
well as conventional plastics – widely differing shrinkage<br />
properties in and across the direction of flow lead to<br />
component distortion.<br />
Table 1: Overview of the examined bioplastics for injection moulding applications<br />
Material Tmelt [°C] Tmold [°C] Holding pressure [bar] Flow Direction [%] Cross Direction [%] FD/CD<br />
Nature Works Ingeo 3052D 200 °C 30 °C 500 bar 0,247 0,315 0,784126984<br />
Nature Works Ingeo 3251D 200 °C 30 °C 500 bar 0,242 0,28 0,864285714<br />
Nature Works Ingeo 6202D 200 °C 30 °C 500 bar 0,258 0,294 0,87755102<br />
Zhejiang Hisun Revode 190 200 °C 30 °C 500 bar 0,265 0,304 0,871710526<br />
Jelu WPC Bio PLA H60-500-14 200 °C 30 °C 500 bar 0,154 0,171 0,900584795<br />
Jelu WPC Bio PE H50-500-20<br />
#DIV/0!<br />
FKuR Terralene HD 3505 230 °C 30 °C 500 bar 1,906 1,45 1,314482759<br />
Evonik Vestamid Terra HS16 250 °C 80 °C 500 bar 1,558 1,631 0,955242183<br />
Showa Denko Bionolle 1020MD 200 °C 30 °C 500 bar 0,814 0,839 0,970202622<br />
Metabolix Mirel P1004 180 °C 30 °C 500 bar 0,404 0,64 0,63125<br />
During processing, the bioplastic is melted in the injection<br />
moulding machine and injected under high pressure into an<br />
injection mold cavity. Once the cooling time is completed,<br />
the cooled part is ejected from the cavity. At this point,<br />
important aspects that must be observed when changing<br />
from a conventional plastic to a bioplastic – this also applies<br />
when changing to a different petroleum-based plastic –<br />
are the different shrinkage and warpage characteristics<br />
of the substituting material. The material shrinkage<br />
allows significant statements to be made concerning the<br />
compatibility of the selected material with the existing cavity<br />
and whether component distortion must be expected. If the<br />
The results of this investigations show that most of the<br />
investigated bioplastics show an almost isotropic shrinkage<br />
and warpage (FD/CD) behavior with a little more shrinkage<br />
in CD than in FD and a ranking lower than 1. This is similar<br />
to most of the petroleum-based plastics and therefore an<br />
important aspect of substitutability. Furthermore, it can be<br />
seen that the PLA-based bioplastics show a low shrinkage.<br />
This corresponds to a typical behavior of unreinforced<br />
amorphous thermoplastics. The other bioplastics have<br />
significantly higher processing shrinkages. In the case of<br />
Vestamid Terra HS16, the shrinkage is very high but in a<br />
magnitude typical for PA. The bioplastic Bionolle 1020MD<br />
14 bioplastics MAGAZINE [03/18] Vol. 13
Injection Moulding<br />
By:<br />
Marco Neudecker, Nuse Lack, Hans-Josef Endres<br />
Institute for Bioplastics and Biocomposites – IfBB<br />
University of Applied Sciences and Arts<br />
Hanover, Germany<br />
Figure 1: Shrinkage and warpage of bioplastics<br />
FD/CD Ranking 0 0,2 0,4 0,6 0,8 1 1,2 1,4 1,6 1,8 2<br />
Nature Works Ingeo 3052D<br />
Nature Works Ingeo 3251D<br />
Nature Works Ingeo 6202D<br />
Zhejiang Hisun Revode 190<br />
Jelu WPC Bio PLA H60-500-14<br />
—<br />
—<br />
—<br />
—<br />
—<br />
—<br />
Jelu WPC Bio PE H50-500-20<br />
not measurable due to bad surface<br />
—<br />
FKUR Terralene HD 3505<br />
—<br />
Evonik Vestamid Terra HS16<br />
—<br />
Showa Denko Bionolle 1020MD<br />
—<br />
Metabolix Mirel P1004<br />
—<br />
FD/CD<br />
Flow Direction (%) Cross Direction (%)<br />
also shows increased shrinkage values which are still in<br />
the lower usual range of semi-crystalline thermoplastics.<br />
Significant anisotropy is exhibited by the Mirel P1004 and<br />
the Terralene HD 3505. The shrinkage of Mirel P1004<br />
is characteristic of largely amorphous thermoplastics,<br />
which also have a relatively high viscosity. Striking is<br />
the high anisotropy, which makes this material prone to<br />
distortion. Terralene HD 3505 belongs to semi-crystalline<br />
thermoplastics but shows a very high shrinkage value,<br />
especially in FD.<br />
We STARCH<br />
your bioplastics.<br />
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The results listed here and many other conclusions<br />
relevant to processors could be identified in the processing<br />
project funded by the German Federal Ministry of Food and<br />
Agriculture. All results are freely accessible and available to<br />
anyone interested in two databases:<br />
• Material Data Center (www.materialdatacenter.com/bo/)<br />
• Project Results Database (http://www.biokunststoffeverarbeiten.de).<br />
The project outcome closes important gaps in the<br />
knowledge of the processing of bio-synthetic materials.<br />
For further questions the competence network of project<br />
partners can be contacted (http://verarbeitungsprojekt.<br />
ifbb-hannover.de/de/projektkontakte.html).<br />
www.ifbb-hannover.de<br />
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THE NATURAL UPGRADE<br />
bioplastics MAGAZINE [03/18] Vol. 13 15
Injection Moulding<br />
Injection moulded NFC<br />
Simulation vs. Experiment<br />
Figure 1: SEM pictures of sisal fibre<br />
bundles before (left) und after compounding<br />
(right). A: Fibre bundle breakage. B: Start of<br />
fibre bundle splitting. C: Peeling behaviour<br />
of sisal. [2]<br />
Figure 2: Distribution of the length (left)<br />
and width (right) for sisal before processing<br />
(Original), after compounding (Granules)<br />
and after injection moulding (Plate). The<br />
results are shown as box-and-whisker plots<br />
(whiskers with a maximum of 1.5 x IQR,<br />
outliers shown as circles). Boxplots with *<br />
represent not normally distributed samples<br />
and different capitals represent significant<br />
differences. [2]<br />
Due to growing environmental concerns, the interest<br />
for renewable resources increases drastically nowadays.<br />
Natural fibre-reinforced composites (NFC) are<br />
an interesting prospect to combine light weight constructions<br />
with renewable resources. Natural fibre-reinforced<br />
form-pressed composites have been used for interior panels<br />
since 1954 [1]. A new interest increases using natural<br />
fibre-reinforced, injection moulded components for largescale<br />
production in the automotive industry. As engineers<br />
only consider predictable compounds in component development<br />
processes, models to simulate natural fibre-reinforced<br />
compounds need to be developed. Common software<br />
programs for injection moulding simulation already include<br />
models to simulate glass fibre-reinforced polymers, but<br />
not yet NFC. To close this gap the project “Material and<br />
Flow Models for Natural Fibre-Reinforced Injection Moulding<br />
Materials for Practical Use in the Automotive Industry”<br />
(NFC-Simulation) was created.<br />
Besides others, two main aspects of the simulation are<br />
the prediction of the fibre orientation and the final fibre<br />
morphology (fibre length and width) in the component<br />
part. The fibre orientation and fibre morphology influence<br />
the mechanical properties of the component. For the<br />
analyses of the fibre orientation and fibre morphology in a<br />
component, plates were injection moulded with 30 mass%<br />
sisal/PP. Sisal fibres are leaf fibres from the plant Agave<br />
sisalana P.. The fibre morphology was determined before<br />
compounding, after compounding and after injection<br />
moulding via scanning electron microscopy (SEM) and via<br />
FibreShape 5.1.1 (IST AG, Vilters, Switzerland), an image<br />
analysis software. The SEM pictures show that the sisal<br />
fibre bundles split and break during compounding (figure 1).<br />
In figure 2, it is shown that the length is significantly reduced<br />
during compounding, while no further reduction could<br />
be observed during injection moulding. The simulation<br />
also showed correlating results: no fibre breakage during<br />
injection moulding [2].<br />
For the fibre orientation measurements, the µ-CT analysis<br />
was found to be the most promising experimental method<br />
to validate the fibre orientation results of the injection<br />
moulding simulation [3]. The fibre orientation results of the<br />
µ-CT analysis showed good correlation with the injection<br />
moulding simulation via Cadmould at different measuring<br />
points on the injection moulded plate (see figure 3).<br />
Finally, glove boxes of the Ford B-Max (figure 4)<br />
were injection moulded by IAC Group and crash tests<br />
were performed experimentally and simulatively. The<br />
experiments and crash simulation correlated well [4,5].<br />
A first closed development cycle for a sisal-reinforced<br />
component could be realised from the process simulation,<br />
over the component manufacturing and component test to<br />
the crash-simulation in the project NFC-Simulation.<br />
16 bioplastics MAGAZINE [03/18] Vol. 13
Injection Moulding<br />
By:<br />
Katharina Albrecht, HSB – City University of Applied Sciences Bremen, Germany<br />
Tim Osswald, University of Wisconsin - Madison, USA<br />
Erwin Baur, M-Base Engineering + Software GmbH, Aachen, Germany<br />
Maira Magnani, Ford Forschungszentrum Aachen, Aachen, Germany<br />
Jörg Müssig, HSB – City University of Applied Sciences Bremen, Germany<br />
Natural fibres used to reinforce polymers in the automotive<br />
industry instead of glass fibres can provide the advantage<br />
of reduced carbon footprints [6]. The implementation of<br />
material models of NF-reinforced polymers in software<br />
programs opens the market for sustainable, bio-based<br />
compounds in various automotive components.<br />
References<br />
[1] Prömper E. (2010): Natural Fibre-Reinforced Polymers in Automotive<br />
Interior Applications. In: Müssig J., (editor): Industrial application of<br />
natural fibres: Structures, properties and technical applications. Ed.<br />
John Wiley & Sons, Ltd, 2010, 423-437.<br />
[2] Albrecht, K., Osswald, T., Baur, E., Meier, T., Wartzack, S. & Müssig,<br />
J. (<strong>2018</strong>): Fibre length reduction in natural fibre-reinforced polymers<br />
during compounding and injection moulding - Experiments versus<br />
numerical prediction of fibre breakage. Journal of Composites Science<br />
2, 20.<br />
[3] Albrecht, K., Baur, E., Endres, H.-J., Gente, R., Graupner, N., Koch, M.,<br />
Neudecker, M., Osswald, T., Schmidtke, P., Wartzack, S., Webelhaus, K.<br />
& Müssig, J. (2017): Measuring fibre orientation in sisal fibre-reinforced,<br />
injection moulded polypropylene - Pros and cons of the experimental<br />
methods to validate injection moulding simulation. Composites Part A:<br />
Applied Science and Manufacturing 95, 54–64.<br />
[4] Ford Forschungszentrum Aachen GmbH, IAC Group GmbH,<br />
LyondellBasell, Kunststoffwerk Voerde, Simcon Kunststofftechnische<br />
Software GmbH, M-Base Engineering und Software GmbH,<br />
Hochschule Hannover, Hochschule Bremen, TU Clausthal, Fraunhofer<br />
LBF, University of Wisconsin-Madison (2014): Werkstoff- und<br />
Fließmodelle für naturfaserverstärkte Spritzgießmaterialien für den<br />
praktischen Einsatz in der Automobilindustrie. Final report of the<br />
project “NFC-Simulation”, 2014. < http://www.fnr-server.de/ftp/pdf/<br />
berichte/22005511.pdf > (<strong>2018</strong>-04-27). – in German<br />
[5] Franzen, M., Magnani, M. & T. Baranowski (2014): Advanced Crash<br />
Simulation of Natural Fiber Reinforced Thermoplastics with MF-<br />
GenYld+CrachFEM. 3rd MATFEM Conference, 21st October 2014 Schloss<br />
Hohenkammer, Hohenkammer, DE.<br />
[6] Markarian J. (2015): Renewable reinforcements hit the road.<br />
Compounding World 2015, Vol. March 2015, 57-64.<br />
www.bionik-bremen.de<br />
Figure 3: Comparison of results of the µ-CT<br />
measurements and the IM simulation determing<br />
the fibre orientation at six measuring points in<br />
the IM plate. Left: Main fibre orientation angles<br />
in the shell layer. Right: Main fibre orientation<br />
angles in the core layer. Positions without any bar<br />
refer to an angle of 0°. Results are shown in a<br />
mathematical positive sense. [3]<br />
The project NFC-Simulation was funded by the German<br />
Federal Ministry of Food, Agriculture and Consumer<br />
Protection (BMELV) through the Fachagentur<br />
Nachwachsende Rohstoffe e.V. (FNR, Gülzow, Germany).<br />
Project partners were: Ford Forschungszentrum<br />
Aachen GmbH, Aachen, DE; IAC (International Automotive<br />
Components), Ebersberg, DE; LyondellBasell,<br />
Frankfurt, Germany; Kunststoffwerk Voerde Hueck &<br />
Schade GmbH & Co. KG, Ennepetal, DE; Simcon Kunststofftechnische<br />
Software GmbH, Würselen, DE; M-Base<br />
Engineering + Software GmbH, Aachen, DE; University<br />
of Wisconsin-Madison, Madison, USA; University of<br />
Applied Sciences and Arts Hannover, IfBB (Institute for<br />
Bioplastics and Biocomposites), Hannover, DE; HSB -<br />
City University of Applied Sciences Bremen, Bremen,<br />
De; Clausthal University of Technology, Institute of Polymer<br />
Materials and Plastic Engineering, Clausthal,<br />
DE, and Fraunhofer LBF, Darmstadt, DE.<br />
Figure 4: Injection moulded glove box with 30 %<br />
sisal/PP. [4] (Foto: Frank Schumann, IAC)<br />
bioplastics MAGAZINE [03/18] Vol. 13 17
Additives / Masterbatches<br />
Biobased masterbatches for<br />
PLA, PBS and biobased blends<br />
Sukano AG (Schindellegi, Switzerland) is proud to<br />
have embarked on the bioplastics journey over a<br />
decade ago (cf. p. 51). By leveraging their expertise,<br />
focus and dedication in conventional polyester plastics to<br />
bioplastics, their biobased masterbatches portfolio has<br />
grown significantly with a product range for any kind of<br />
PLA, as well as PBS and bio PET.<br />
Today the spotlight is on what PBS based masterbatches<br />
can do to strengthen this revolutionary resin and its<br />
blends, mainly with PLA, with its two-fold bio properties.<br />
Being essentially biobased, bio-PBS resin and<br />
masterbatches are also biodegradable and compostable.<br />
Sukano tailor-made bio-PBS masterbatches are easily<br />
compounded with another bioplastic material. They<br />
provide a drop-in type of masterbatch to be added to<br />
the resin, and require no process changes, nor new<br />
machinery machinery to achieve great results according to<br />
customer’s manufacturing needs at the same throughput<br />
as comparable conventional plastics.<br />
Bio-PBS is a resin that needs bio-PBS based<br />
masterbatches, highly compatible to this polymer,<br />
to support its material environmental friendly, food<br />
compliant, printability and heat resistance properties.<br />
To achieve the best benefits from this choice, the<br />
masterbatches are also formulated for biobased content<br />
with cradle-to-cradle biopolymer and ingredients.<br />
Knowing that Bio- PBS is naturally compostable at 30 °C<br />
into H 2<br />
O, CO 2<br />
and biomass either in a composting facility<br />
or at home, Sukano developed three main product grades<br />
to enhance the final product even further. This enables it to<br />
finally replace several flexible packaging structures out in<br />
the market while still complying with the biodegradability<br />
regulations. Sukano’s masterbatches are designed to<br />
maintain the main resin characteristics, and therefore to<br />
be disposed of along with organic waste.<br />
The array of applications and assessments made<br />
by their experts indicate that Sukano’s masterbatches<br />
support applications that can be used for food contact at<br />
up to 100 °C. This high service temperature performance<br />
means it is suitability for hot beverages, boxes and utensils<br />
for freshly cooked food and food containers.<br />
The modified resin with Sukano’s masterbatches<br />
achieves its heat seal performance at the same level of<br />
sealability properties as fossil-based polymers.<br />
These characteristics, in addition to potential blends,<br />
means that bio-PBS can be also targeted for key end<br />
applications such as paper coatings, single use food<br />
service and flexible packaging.<br />
Paper cups are among the main target of PBS and PLA<br />
resins or blends as replacements for PE coatings. This<br />
18 bioplastics MAGAZINE [03/18] Vol. 13
By:<br />
Alessandra Funcia<br />
Head of Sales and Marketing<br />
Sukano AG<br />
Schindellegi, Switzerland<br />
application is certainly one of the most commonly misunderstood when it<br />
comes to its compostability claim.<br />
Today, many paper cups are still laminated with conventional plastics to<br />
prevent liquid from leaking out or soaking the paper, ultimately causing the<br />
cup to collapse. This thin fossil-based plastic coating negatively impacts<br />
the biodegradation process of the paper, making it almost impossible to<br />
biodegrade, especially when both sides of the cup are coated.<br />
However, using Bio-PBS or PLA coated paper cups makes them indeed<br />
compostable. Additionally, the bio-PBS masterbatches added to the bio-<br />
PBS paper cups or heat stable PLA means the cups can still be filled with<br />
hot and cold beverages, and consumers can safely enjoy their drinks in an<br />
environmentally improved product type.<br />
Other applications where the use of highly compatible masterbatches<br />
enable bio-PBS and its blends to outperform conventional plastics is in the<br />
injection molding process for food service applications.<br />
The blended products achieve improved mechanical properties, such<br />
as impact strength, in addition to higher service temperatures, keeping<br />
dimensional stability at desired levels, allowing the material to flow smoothly,<br />
the parts to be molded properly and at industrial yields needed, while still<br />
being compostable.<br />
What’s more, the greatest breakthrough where Sukano biobased<br />
masterbatches in PBS and PLA are present is in flexible packaging.<br />
A typical flexible packaging is based on dry lamination of many layers,<br />
where each layer has a predefined role of its own. Sukano masterbatches<br />
based in PBS and PLA are used in combination with bio-PBS and special<br />
grades of neat PLA, creating a combination of resins that have a compostable<br />
sealing performance compared to other bioplastics, yet still provide a higher<br />
gas barrier than low density PE, and retain the aroma of the packaged<br />
product longer. Sukano masterbatches do not interfere in the packaging<br />
transparency, thus allowing the product to be seen so it can display its<br />
appetite appeal on the shelves naturally.<br />
The flexible packaging structures can be used for dry, baked and frozen<br />
food, fruits and vegetables. Sukano masterbatches enable flexible packaging<br />
structures to remain recyclable, compostable and be produced using less<br />
conventional plastic.<br />
The circular economy concept indicates the design phase for new<br />
packaging as the key disruptive point for higher environmental credentials<br />
of packaging. Flexible package is in the top of the list of targeted packaging<br />
where urgent improvements are required.<br />
Sukano masterbatches enable creative and functional changes for the<br />
flexible packaging market, protecting food from wastage, being compostable,<br />
transparent and using less plastic – and all able to be processed on existing<br />
industrial manufacturing lines.<br />
www.sukano.com<br />
EMERY<br />
OLEOCHEMICALS –<br />
THE FIRST CHOICE<br />
IN SUSTAINABLE<br />
POLYMER ADDITIVES.<br />
LUBRICANTS<br />
RELEASE AGENTS<br />
SPECIAL PLASTICIZERS<br />
SURFACE FINISH AGENTS<br />
VISCOSITY REGULATORS<br />
CREATING VALUE<br />
www.emeryoleo.com<br />
bioplastics MAGAZINE [03/18] Vol. 13 19
Additives / Masterbatches<br />
Biobased additives<br />
that enhance polymer processing and improve end product quality<br />
With more than 60 years of experience delivering<br />
high-performance, natural-based products to the<br />
plastics industry, Emery Oleochemicals GmbH<br />
(Düsseldorf, Germany; headquartered in Telok Panglima<br />
Garang, Malaysia) is well-positioned to offer natural-based<br />
polymer additives, especially lubricants, plasticizers and<br />
surface finish agents to companies in the plastics industry<br />
that are seeking more sustainable products.<br />
Why Green Polymer Additives?<br />
Due to the plastics industry’s heightened interest in<br />
sustainability, Emery Oleochemicals is also constantly<br />
refining its Green Polymer Additives product portfolio to<br />
exceed the increasingly stringent standards and regulations.<br />
From the very beginning, when the LOXIOL ® brand was<br />
first introduced in 1957, Emery’s experienced product<br />
development teams around the globe have concentrated on<br />
creating specialized additives through the use of renewable<br />
biobased raw materials from natural fats and oils.<br />
Lubricants for Optimal Processability<br />
Loxiol lubricants from Emery Oleochemicals are<br />
compatible with various stabilizers and are mainly based on<br />
renewable raw materials. Loxiol G 59 improves the material<br />
flow during extrusion and reduces the melt viscosity. It<br />
has food contact approval and is suitable for transparent<br />
applications. It is compatible with several polymers and it<br />
reduces the formation of deposits (blooming) on the final<br />
article as well as on the machines (plate out), and thereby, it<br />
increases the productivity.<br />
Loxiol G 24 is an external lubricant and release agent<br />
that is based on 100 % renewable resources. It can replace<br />
paraffin and Fischer-Tropsch waxes.<br />
Sustainable Additives for C-PVC<br />
It is well known in the plastics industry that the processing<br />
behavior of C-PVC is significantly different from that of PVC.<br />
To meet these unique application requirements, Emery<br />
Oleochemicals’ latest technical developments include<br />
tailored ester lubricants for processing of chlorinated PVC<br />
(C-PVC). Advantages of Emery’s new lubricants are, among<br />
others, a biobased-feedstock, a minor influence on the Vicat<br />
softening point and a defined chemical structure similar to<br />
the often used paraffin waxes. These lubricants also enable<br />
an exact adjustment of the processing window. In addition,<br />
Emery’s most recent product developments include food<br />
contact compliant additives that adhere to the respective<br />
regulations in all major regions worldwide.<br />
Customized Solutions to Meet Today’s<br />
Challenging Applications<br />
In addition to a broad portfolio of established products,<br />
Emery Oleochemicals offers customized products that<br />
are not only eco-friendly, but also tailored to the desired<br />
performance specifications. as well as economically<br />
viable,” emphasizes Dr. Harald Klein, Global Platform Head<br />
of Emery Oleochemicals’ Green Polymer Additives business<br />
unit.<br />
In addition to a broad portfolio of established products,<br />
Emery Oleochemicals offers customized solutions tailored<br />
to special requirements. “Today, it is not enough to provide<br />
standardized products. Plastics manufacturers require<br />
additives that are not only eco-friendly, but also customized<br />
to their performance specifications as well as economically<br />
viable,” emphasizes Dr. Harald Klein, Global Platform Head<br />
of Emery Oleochemicals’ Green Polymer Additives business<br />
unit.<br />
Emery Oleochemicals’ global operations are supported<br />
by a diverse workforce and an extensive global distribution<br />
network covering over 50 countries worldwide. MT<br />
http://greenpolymeradditives.emeryoleo.com/additives/<br />
20 bioplastics MAGAZINE [03/18] Vol. 13
Additives / Masterbatches<br />
Renewable,<br />
sustainable<br />
mineral<br />
By:<br />
Jeff Apisdorf<br />
President<br />
MultiPlast Systems, Inc.<br />
Solon, Ohio, USA<br />
Multiplast Systems, Inc. (Solon, Ohio) recently introduced<br />
a range of masterbatches made with RenewCal, a<br />
renewable biogenic, highly purified oolitic aragonite<br />
(calcium carbonate). This unique mineral has physical and<br />
environmental characteristics unlike all other mined alternatives.<br />
Compatible with a wide range of resins, including biobased<br />
resins, RenewCal masterbatches offer a wide range of<br />
benefits including performance, economics, environmental<br />
and degrading in both flexible and rigid products.<br />
Sourced in their 500 square mile lease on the Bahama<br />
Banks, this unique crystalline formed mineral is replenished<br />
by approximately 900,000 tonnes per year. Current supply of<br />
this accumulated material is over 2 billion tonnes. The natural<br />
biogenic process is based on a confluence of factors, including<br />
ocean currents, sea-floor topography, and the natural<br />
presence of picoplankton stimulated by photosynthesis, which<br />
cause these microscopic organic organisms to combine<br />
atmospheric carbon dioxide with pure calcium in the water, to<br />
form oolitic aragonite. These oolites then precipitate as very<br />
pure grains of calcium carbonate, which settle on the ocean<br />
floor. This continuing natural mineralization process is also,<br />
at the same time, sequestering 5,680 tonnes of CO 2<br />
from<br />
the atmosphere. Unlike mined minerals which vary based<br />
on the range of sources, RenewCal is very consistent. as it is<br />
produced from the same source under the same conditions.<br />
Harvested with minimal environmental impact, RenewCal<br />
is proven to be carbon minimal to negative, renewable and<br />
sustainable. Environmental benefits include replacing fossil<br />
fuel-based resins, lowering carbon footprint compared to<br />
mined minerals, and producing finished products with a<br />
higher degree of renewable content.<br />
Benefits of improved degradability/compostability are due to<br />
RenewCal’s ability of high Ph buffer against acids, for higher<br />
loadings and for greater mineral surface area, which all speed<br />
up the degradation process.<br />
Benefits in production, performance, and economics are<br />
due to its unique crystalline needle like particle shape, high<br />
zeta potential (improved dispersion), ability to load high<br />
percentages depending on the application and cost reduction<br />
by replacing more expensive resins. Improved barrier<br />
characteristics and heat deflection are achieved by its high<br />
aspect ratio, crystalline particle shape and high loading thus<br />
producing a greater tortuous path.<br />
RenewCal masterbatches are FDA compliant for food<br />
packaging, come in a range of carriers and can have mineral<br />
content up to 80 %.<br />
Typical applications are flexible film, thermoformed<br />
sheeting, blown and injection molding, synthetic paper and<br />
extrusion coatings.<br />
www.multiplastsystems.com<br />
COMPEO<br />
Uniquely efficient. Incredibly versatile. Amazingly flexible.<br />
With its new COMPEO Kneader series, BUSS continues<br />
to offer continuous compounding solutions that set the<br />
standard for heat- and shear-sensitive applications, in all<br />
industries, including for biopolymers.<br />
• Moderate, uniform shear rates<br />
• Extremely low temperature profile<br />
• Efficient injection of liquid components<br />
• Precise temperature control<br />
• High filler loadings<br />
www.busscorp.com<br />
Leading compounding technology<br />
for heat- and shear-sensitive plastics<br />
bioplastics MAGAZINE [03/18] Vol. 13 21
Additives / Masterbatches<br />
Biobased wax<br />
additives<br />
Clariant adds high-performing<br />
solutions based on non-food<br />
competing biomass to its broad<br />
portfolio of waxes for bio- and<br />
conventional plastics applications.<br />
External Lubrication: Polyamide 6 (PA 6)<br />
Clariant, a world leader in specialty chemicals and<br />
recognized as one of the most sustainable chemical<br />
companies in the Dow Jones Sustainability Index,<br />
is introducing a family of high-performance waxes<br />
based on renewable feedstock: Licocare ® RBW. These<br />
multi-purpose additives are based on crude rice bran<br />
wax. This is a non-food-competing by-product from the<br />
production of rice bran oil. Clariant chemically and physically<br />
upgrades this non-edible component of the oil and<br />
thus contributes to using the rice bran’s full value. The<br />
main target applications for Licocare RBW are engineering<br />
thermoplastics such as polyamides, polyesters or<br />
TPU, biopolymers like PLA, and epoxy resins. They offer<br />
benefits to resin manufacturers, Masterbatch producers,<br />
compounders or plastics convertors. Clariant’s innovative<br />
solutions can also be used for other applications,<br />
such as agriculture, coatings, home and personal care.<br />
By:<br />
Manuel Bröhmer<br />
Product Manager<br />
Clariant Plastics & Coatings (D) GmbH<br />
Gersthofen, Germany<br />
Release force [N]<br />
Spiral length [cm]<br />
520 —<br />
500 —<br />
480 —<br />
460 —<br />
440 —<br />
420 —<br />
46 —<br />
45 —<br />
44 —<br />
43 —<br />
42 —<br />
41 —<br />
40 —<br />
Without<br />
Lubricant<br />
Without<br />
Lubricant<br />
Licocare<br />
RBW 300<br />
Licocare<br />
RBW 102<br />
Standard<br />
Montan wax<br />
Polymer: Durethan B 29, Dosage: 0,3%<br />
Flow Improvement: Polyamide 6 (PA 6)<br />
Licocare<br />
RBW 300<br />
Licocare<br />
RBW 102<br />
Standard<br />
Montan wax<br />
Standard<br />
PETS<br />
Standard<br />
PETS<br />
Formulation for the test; Polymer: Durethan B 29, Dosage of test product: 0,3%<br />
Application tests by Clariant show that Licocare RBW<br />
solutions achieve higher performance levels compared<br />
to alternative solutions on the market. The major two<br />
grades for plastics applications, Licocare RBW 300 TP and<br />
Licocare RBW 102 TP, fulfil numerous highly demanding<br />
requirements set for example by the transportation and<br />
electrical and electronic industries. Licocare RBW 300<br />
TP is a highly thermostable, partially saponified wax,<br />
Licocare RBW 102 TP is a medium-polarity wax type.<br />
Clariant’s new solutions improve melt flow, lower the<br />
amount of force required to release parts from molds,<br />
ensure a more homogeneous distribution of pigments<br />
or fillers, and lead to less yellowing of final products.<br />
Furthermore, they offer outstanding processing stability,<br />
even at elevated temperatures, due to their superior<br />
thermal stability, very low volatility and low metal<br />
content. Ultimately, Licocare RBW benefits its customers<br />
by significant claims: improved shaping flexibility, better<br />
mechanical properties and improved surface finish.<br />
Reduced rejection rates and more effective dosage can<br />
positively impact the financial bottom line of Clariant’s<br />
and its customers’ customers.<br />
Clariant has launched its EcoTain ® -certified Licocare<br />
RBW solutions in Japan, China and the United States this<br />
year and is gradually introducing its sustainable product<br />
line for plastics in other markets. Clariant awards its<br />
EcoTain sustainable excellence label to products in its<br />
portfolio that provide sustainable benefits above market<br />
standard and therefore represent best-in-class solutions.<br />
“Sustainability has become a major focus in the plastics<br />
industry, driven by society’s growing environmental<br />
awareness and consumers’ demand for more sustainable<br />
plastics”, says Manuel Mueller, Global Head of Market<br />
Segment Plastics in Business Line Advanced Surface<br />
Solutions at Clariant. “To improve the eco-friendliness and<br />
to boost their product performance, plastics companies<br />
are increasingly making use of renewable raw materials<br />
such as bio-polymers and bio-additives. Our Licocare RBW<br />
solutions support this development at the forefront.” MT<br />
www.clariant.com<br />
22 bioplastics MAGAZINE [03/18] Vol. 13
Additives / Masterbatches<br />
Bio-Masterbatches with<br />
ecofriendly, mineral pigments<br />
Bio-masterbatches from Albrecht Dinkelaker, Polymer-<br />
und Produktentwicklung (Zell im Wiesental,<br />
Germany) are made with the compostable, waterproof<br />
carrier material Caprowax P. They are suitable for use as<br />
universal colourants of bioplastics, blends and biocomposites,<br />
such as<br />
• PLA, PBS, PHA, PCL, Caprowax P-blends<br />
• Polysaccharides and derivates, PVAc/bioplastic-blends,<br />
• bio-NFC, bio-WPC, PVOH, bio-UPR, bio-TPE and NIPU<br />
(Non-isocyanate polyurethane)<br />
The pigments added to the Caprowax P base carrier<br />
are non-toxic minerals comparable to naturally occurring<br />
inorganic pigments, such as oxides, ultramarines, silicates,<br />
pyrophosphates, natural carbonates and vegetable carbon.<br />
These bio-masterbatches enable bioplastics to be dyed<br />
according to the specifications of DIN EN 13432. They are<br />
water insoluble, already mineralised and yield colours<br />
ranging from light pastel shades to strong, natural hues.<br />
The carrier material - Caprowax P - is a mixture of a<br />
compostable polyester and modified, GMO-free plant oils,<br />
tested and approved by MFPA (Materialforschungs- und<br />
-prüfanstalt, University Weimar, Germany). It is compliant<br />
with the criteria of DIN EN 13432. The material has<br />
been comprehensively tested by MFPA, to evaluate its<br />
disintegration at bench scale and the quality of the compost,<br />
including its ecotoxicological harmless state (MFPA - Test<br />
certificate: P31029-05).<br />
Albrecht Dinkelaker’s bio-masterbatches are compatible<br />
with many different bioplastics in a wide range of<br />
thermoplastic processing technologies:<br />
• Injection moulding, thermoforming, blow moulding,<br />
compression moulding<br />
• fibres, mono- and multifilaments, sheets, foils, films,<br />
foams,<br />
• hotmelt, NF-biocomposites<br />
• and much more …<br />
These masterbatches can be supplied in opaque or<br />
translucent colours, while achromatic and pearlescent<br />
effects are also possible. Step by step, the palette of<br />
Caprowax P - bio-masterbatches will be expanded. This<br />
includes ecofriendly, calcined Kaolin as white pigment.<br />
Interested customers can ask for up to 4 free 50 g<br />
samples. Commercial quantities are available in 80 – 500 kg<br />
batches. Samples of laboratory prototypes with brightening<br />
Kaolin or pearlescent pigments are also available.<br />
The mineral color pigments used in Caprowax P are<br />
harmless, lightfast, non-migratory, thermally stable, water<br />
insoluble and comparable with natural, mineral pigments.<br />
They are - in a range of 15 – 40% - low-dusty incorporated in<br />
the compostable carrier material and already mineralised.<br />
Pigments and carrier material are free of aromatics and<br />
toxic heavy metals.<br />
For the most part, they are free of nitrogenous substances.<br />
The renewable, modified plant oil is GMO-free and presents<br />
no competition to food and feed.<br />
Bio-masterbatches can be processed at temperatures<br />
from 90 to 200 °C, and for a short time up 220 °C. Different<br />
bioplastics can be coloured with masterbatches in a range<br />
of 0,5 – 6 %. In colored final products separate, mineralic<br />
components are ≤1% . MT<br />
www.caprowax-p.eu<br />
bioplastics MAGAZINE [03/18] Vol. 13 23
Chinaplas-Review<br />
Chinaplas <strong>2018</strong><br />
The rainy weather in Shanghai seemed not to have affected<br />
the number of visits to Chinaplas <strong>2018</strong> which was<br />
moved to the National Exhibition and Convention Centre,<br />
Hongqiao, Shanghai for the first time.<br />
The National Exhibition and Convention Centre is located<br />
about 1.5 km from Hongqiao Airport and 60 km from Pudong<br />
Airport. It is close to the Hongqiao highspeed train HUB, just a<br />
10 minutes walk away. Metro lines 2, 17 and 23 stop there, and<br />
were highly suggested as they are the most convenient way<br />
to get to Chinaplas <strong>2018</strong> because of the heavy street traffic in<br />
Shanghai.<br />
The design of National Exhibition and Convention Centre<br />
is like a Shamrock grass leaf with three office buildings and<br />
a 5 star hotel at the four leaf tips. The complex offers over<br />
400,000 m² indoor exhibition space including 13 halls with<br />
28,800 m² each and 3 halls with 10,00 m² each. An additional<br />
100,000 m² outdoor exhibition space completes the centre.<br />
From 24 th April to 27 th April <strong>2018</strong>, Chinaplas saw a record<br />
breaking attendance of 180,701 visitors which shows a 21.6 %<br />
increase compared to 2016 and 16.4 % compared to 2017. On<br />
the second day alone Chinaplas had 64,385 visitors, which is as<br />
many as NPE (Orlando/USA) two weeks later saw over 5 days.<br />
At Chinaplas <strong>2018</strong>, two new special zones, 3D technology<br />
zone and TPE rubber zone were introduced in addition to the<br />
existing 16 zones.<br />
In the Bioplastics zone a total of 38 exhibitors, consisting of<br />
resins manufacturers, compounders and products converters<br />
showed their products and services.<br />
bioplastics MAGAZINE talked with most of the Chinese<br />
exhibitors and found that the local market accounts only for<br />
less than 10 % of their total sales volume. Insider pointed<br />
out that a lack of an efficient waste classification system and<br />
missing anaerobic organic waste biodegradation systems<br />
result in a lack of value for biodegradable products in a circular<br />
economic system.<br />
According to China Bioplastics Alliance, a first breakthrough<br />
for biodegradable plastics applications would be agricultural<br />
mulch films. Although according to the latest legalization<br />
the use of any plastic mulch film less than 12 µm thickness<br />
is forbidden, so that farmers can re-collect PE mulch film<br />
after harvest. However, according to local experts, the Chinese<br />
government is well aware about the comparative advantages<br />
of biodegradable mulch films. Every province has accumulated<br />
biodegradable mulch film trial data over the last 10 years. There<br />
seem to be no functional issues. The biggest obstacle seems<br />
to be the cost factor. China Bioplastics Alliance are studying<br />
different ways to reduce cost to an acceptable level including<br />
building a large scale factory in Northwest China where natural<br />
gas is available to produce BDO and subsequently PBAT.<br />
One of the most interesting visitors at the booth of bioplastics<br />
MAGAZINE was a company from Tibet. They have been involved<br />
in water treatment in Tibet and are now looking for a partner<br />
to introduce anaerobic organic waste digestion systems to<br />
Tibet. They claimed that Tibet may be the most suitable place<br />
to adopt anaerobic digestion of organic waste because of the<br />
following reasons:<br />
Tibet’s regional spirit is back to nature. According to the<br />
Tibetan faith, celestial burial is performed by letting animals<br />
eat dead bodies.<br />
Tibetan people incinerate combustible waste for heating<br />
purposes in winter. Therefore their concept of waste<br />
classification is much better than in most parts of the People’s<br />
Republic of China.<br />
Tibet is a minority area. It is therefore expected that<br />
government will spend much more resources in environmental<br />
protection.<br />
www.chinaplasonline.com<br />
By:<br />
John Leung, Biosolutions<br />
24 bioplastics MAGAZINE [03/18] Vol. 13
Automotive<br />
Back in 1989, we had a big, crazy idea.<br />
What if we could turn greenhouse gases like carbon dioxide into<br />
products? It took a lot of research and some real innovation, but<br />
today Ingeo is valued for its unique properties and found in<br />
products from coffee capsules to nonwovens to appliances.<br />
natureworksllc.com |<br />
@natureworks<br />
Join us at Innovation Takes Root to learn more.<br />
The NatureWorks Advanced Biomaterials Forum | September 10 -12<br />
Rancho Bernardo Inn | San Diego, California USA<br />
innovationtakesroot.com | #ITR<strong>2018</strong><br />
bioplastics MAGAZINE [03/18] Vol. 13 25
Application AutomotiveNews<br />
Chocomel to opt for innovative packaging of<br />
more than 80 % plant-based materials<br />
Sustainable production<br />
is high on the agenda<br />
at FrieslandCampina<br />
(Amersfoort. The Netherlands)<br />
as sustainable<br />
leader in the dairy sector.<br />
For the long-keeping<br />
variety of their brand<br />
Chocomel, the company<br />
is now the first food<br />
producer in the world to<br />
opt for a new, innovative<br />
cardboard liter pack. One<br />
that is for more than 80<br />
% made of raw materials<br />
that come from plants,<br />
with wood and sugar cane<br />
as parent materials. The<br />
new packaging has been<br />
available in stores in the<br />
Netherlands since end of<br />
May <strong>2018</strong>.<br />
The new packaging of the sustainable varieties of Chocomel<br />
is from more than 80 % made of plant-based materials. In<br />
addition to the cardboard, which is produced from wood that<br />
is 100 % sourced from FSC-certified forests, the plastic cap<br />
and the outer plastic layer of the iconic yellow-colored suit<br />
are now made from plants. It concerns the part of the plant<br />
that remains after the part that is suitable for food has been<br />
taken out. The exact plastic material was not disclosed, but<br />
presumably it is Braskem’s bio-PE. The processing of this<br />
material for the packaging of Chocomel is therefore not at<br />
the expense of food. On an annual basis, about 40 million<br />
packages are involved.<br />
By crossing the 80 % limit FrieslandCampina reaches<br />
the threshold for the highest possible, 4-star certificate,<br />
‘Ok Biobased’. This is issued by the worldwide accredited<br />
inspection and certification organisation TÜV Austria<br />
(formerly Vinçotte). Compared with the previous packaging,<br />
the new Chocomel pack yields a CO 2<br />
saving of 17 %,<br />
according to the independent Swedish environmental<br />
research institute IVL.<br />
The choice for this innovative packaging is completely<br />
in line with FrieslandCampina’s strategy, route2020, and<br />
purpose, Nourishing by nature, which stands for better<br />
nutrition for consumers in the world, good income for the<br />
farmers, now and in the future. To achieve climate-neutral<br />
growth, FrieslandCampina is working on an efficient and<br />
sustainable production chain. In line with Sustainable<br />
Development Goal 12 of the United Nations, Sustainable<br />
consumption and production (SDG 12), the company aims to<br />
use only agricultural raw materials and paper packaging in<br />
2020, from fully sustainably managed sources.” MT<br />
www.frieslandcampina.com<br />
WPC posts for electric fences<br />
Green Dot Bioplastics (Emporia, Kansas, USA) developed<br />
a wood-plastic composite for Kencove’s PasturePro Posts<br />
for electric fences that is stronger, lasts longer and is easier<br />
to use compared to conventional solutions.<br />
It’s organic certifed and ready for long-term use.<br />
Kencove Farm Fence Supplies is a US-nationwide<br />
manufacturer and distributor of electric fence supplies<br />
for animal containment and exclusion. They manufacture<br />
electric fencing materials such as posts, wire and energizers<br />
and serve large farming operations as well as personal<br />
backyard farms — anyone who needs animal containment<br />
and protection solutions. The<br />
company carries electric fencing<br />
supplies for chickens, horses,<br />
cattle, sheep, goats, pigs and<br />
more.<br />
The material for the PasturePro<br />
Posts had to balance:<br />
Dielectric properties, tensile<br />
strength, memory capability,<br />
durability, aesthetics, flexibility,<br />
UV properties, and recyclability.<br />
Determining a formulation that met all these requirements<br />
as well as the cost target was challenging. As such, Green<br />
Forest Composites, the original manufacturer of PasturePro<br />
Posts, reached out to Green Dot Bioplastics.<br />
Green Dot Bioplastics worked to run multiple trial<br />
productions with various combinations of polypropylene (PP)<br />
grades and wood, as well as various processing conditions.<br />
Wood fiber was used to add strength and lighten the<br />
weight of the posts. There was a wide range of wood species<br />
to pick from, including oak, pine and maple that came in<br />
various particle sizes. Choosing the correct one was critical<br />
since its properties would affect the manufacturing process.<br />
There were several manufacturing challenges associated<br />
with the PasturePro Posts. In the early 2000s, the orientation<br />
of wood-plastic composites was a newly patented process<br />
and everything from speed, length of the line, heating,<br />
cooling and die sizes were constantly being adjusted. After<br />
carefully consulting with Green Forest Composites, Green<br />
Dot Bioplastics was able to pinpoint a consistent wood pellet<br />
that could function within the formulation. MT<br />
www.greendotbioplastics.com<br />
www.kencove.com<br />
26 bioplastics MAGAZINE [03/18] Vol. 13
Application Automotive News<br />
New generation of coffee capsules<br />
Flo, a major European food packaging producer from Parma, Italy, recently<br />
introduced Gea, the first coffee capsule in the world that combines compostability,<br />
oxygen barrier, and an improved taste and aroma experience for the consumer. The<br />
capsule was created in partnership with NatureWorks and is the result of a two-year<br />
joint development process that created a compostable capsule aimed to deliver on<br />
the high-performance requirements of the most demanding roasters.<br />
“Gea represents a new generation of capsules, designed to meet the needs of<br />
coffee roasters and coffee lovers, but also to address environmental issues related<br />
to the management of waste,” says Erika Simonazzi, marketing director of Flo. “As<br />
food packaging producers, we are very careful to study the right materials for their<br />
use, based on environmental requirements and the dictates of the new rules of the<br />
circular economy.”<br />
Gea is entirely composed of Ingeo PLA, which is certified for industrial composting systems according to global standards<br />
such as EN-13432 (EU) and ASTM D6400-04 (USA). The new capsule technology platform is fully approved for food contact and<br />
is now in final testing by TÜV Austria and the Italian Composting and Biogas Association (CIC) for compostability certification.<br />
“A fully compostable capsule provides an elegant and simple system for delivering the valuable used coffee grounds to<br />
industrial compost,” said Steve Davies, commercial director, NatureWorks Performance Packaging. “Thanks to the collaboration<br />
with Flo and their unique capability and dedication to developing improved packaging technologies, we are proud to support the<br />
commercialization of the first compostable coffee capsule made from 100 % Ingeo. The results demonstrate that delivering a<br />
superior taste and brewing experience to the consumer does not have to sacrifice sustainability.”<br />
Compared to compostable capsules currently on the market, the new Gea capsules address market requests for material<br />
ageing stability in an industrially compostable format. “Being able to count on a capsule that does not show signs of ageing in<br />
a few months, but is shelf stable for years, is a huge value for coffee roasters,” explains Erika Simonazzi. “Roasters should be<br />
focused on their coffee, not the packaging it is packed in. NatureWorks’ unique analytical and engineering capabilities together<br />
with Flo’s know-how in thermoforming technology, were critical to developing this solution.”<br />
Gea capsules also are an excellent barrier to oxygen, which protects the organoleptic qualities of the packaged coffee. The<br />
taste and aroma of the coffee are preserved, satisfying the needs of coffee roasters while ensuring an enhanced brewing<br />
experience for consumers.<br />
Initially targeting the demanding requirements of high pressure, single serve coffee systems, the Gea capsules have<br />
successfully passed the industrialization and filling tests at Flo’s major partner coffee roasters and will be available on the<br />
market starting in October <strong>2018</strong>.” MT<br />
www.flo.eu | www.natureworksllc.com<br />
(Photo: The Guardian / Shutterstock)<br />
Arla introduce mass-balance based bio-packaging<br />
Arla Foods Germany (Düsseldorf) is the first company to opt for the innovative SIGNATURE PACK from SIG Combibloc<br />
(Neuhausen, Switzerland) – the world’s first aseptic carton pack that is 100% linked to plant-based renewable material.<br />
Signature pack cartons are made from 77% paper board from wood and 23% plant-based polymers through mass balancing. This<br />
means that for the polymers used in the packaging, an equivalent amount of biobased feedstock went into the manufacturing of<br />
(other) polymers ofthe supplier. To ensure the integrity of this process, the mass balancing is certified through recognised and<br />
audited certification schemes (ISCC PLUS and TÜV SÜD CMS71). Arla now offers its 1 litre 1.5% and 3.8% organic milk (Arla ®<br />
BIO Weidemilch) in the Signature pack.<br />
By choosing the innovative Signature pack, Arla is demonstrating its commitment to sustainability as it strives to increase<br />
the market share of its organic dairy products. Arla’s organic milk cartons now carry a clear message to consumers: buying<br />
this pack promotes the use of renewable raw materials to protect fossil resources while making a positive impact in reducing<br />
the CO 2<br />
level compared with a standard carton pack.<br />
Elise Bijkerk, Marketing Director at Arla Foods Germany said: “The Signature pack<br />
is a great match for our BIO Weidemilch. Consumers that choose for our pure Arla BIO<br />
Weidemilch also have an increasingly strong interest in sustainable packaging. With<br />
the value-added pack from SIG, we can demonstrate our commitment to transparency<br />
and our holistic approach to sustainability across the value chain. We are happy to be<br />
the first company to use Signature pack and to be able to offer consumers in Germany<br />
this solution.”<br />
www.signature-pack.com<br />
bioplastics MAGAZINE [03/18] Vol. 13 27
Report<br />
PHBV from waste water<br />
Phario: an opportunity for the polymer market<br />
Save the date<br />
see page 10-11 for details<br />
Polyhydroxyalkanoate (PHA) is a well-known family of biodegradable<br />
bioplastics. One in particular is PHBV, a less<br />
crystalline and amorphous rubbery material with unique<br />
properties. A Dutch consortium with -surprisingly- regional<br />
water authorities has committed to investing in a PHBV demonstration<br />
project called PHARIO in 2019. It is an open invitation<br />
to the polymer industry to co-invest in the development of<br />
this promising, biodegradable value chain.<br />
PHARIO<br />
A group of five Dutch water authorities, responsible for<br />
processing wastewater into clean water and protection of<br />
shores against rising water levels, form a core development<br />
group called Phario. This group assisted with its sectoral<br />
innovation institute, technology providers and two sludge<br />
incinerators. During a 10-month pilot, they achieved an<br />
excellent PHBV quality and business case, producing PHBV<br />
(up to 40% HV) from municipal sludge and waste fatty acids<br />
and successfully testing applications.<br />
Etteke Wypkema, innovation manager of Phario explains<br />
the concept: ‘The processes required for purifying sewage<br />
water already appear to breed the right bacteria for making<br />
PHA bioplastic. For the bacteria, this plastic is a form of<br />
energy reserve; if you offer them enough food under the right<br />
conditions (fatty acids), they produce this plastic, up to 50 %<br />
of their own weight. This plastic has very beneficial thermal<br />
and mechanical properties that make it usable for all kinds of<br />
applications. It is also biodegradable, and, most importantly:<br />
globally scalable, as the approach fits most conventional<br />
wastewater treatment plants (WWTP).’<br />
Promising results from the pilot stage<br />
Mid 2016 the project concluded in a public report [1] that<br />
the harvested activated sludge can consistently produce a<br />
high quality PHA/PHBV polymer that has interesting and<br />
meaningful application potentials and a sound business case.<br />
The polymer produced showed a 70% lower environmental<br />
impact compared to currently available PHA bioplastic and<br />
other benefits (non-GMO and no competition with food and<br />
feed nor land use).<br />
“The project showed that a high quality<br />
PHBV can be produced for less than EUR<br />
3.50 per kg on a 5,000 ton/year scale.<br />
Further cost reductions are possible, we<br />
need industrial participation”, says Mr.<br />
Martijn Bovee, business developer.<br />
Road to demonstration phase in 2019: open to<br />
partners<br />
Within the Phario project a large set of material data<br />
(thermal, mechanical) was generated, that made it possible<br />
for investors and end-users to evaluate the potential of<br />
the material. Now, higher volumes are needed. Pilot scale<br />
application tests are the key to commercialization.<br />
Various European compounders and end-users have shown<br />
their interest in Phario. Especially the content of up to 40%<br />
HV (amorphous, high polymer weight) and its ability to steer<br />
mechanical and thermal properties are key benefits. For this<br />
reason, Phario consortium will scale up to demonstration<br />
phase in 2019 with a larger role for the private sector. The<br />
project will cost approx. 5.5 million euro. Private sector<br />
involvement and EU-subsidies are expected to reduce net<br />
costs. During the project a few thousands of kilogrammes<br />
PHA/PHBV will be produced and evaluated to verify more<br />
extensively with application partners. The results of these<br />
tests will form the guarantees for the next development<br />
stage: a commercial reference facility with approx. 5,000 ton/<br />
year capacity [1].<br />
“Phario really combines ‘doing good’ with<br />
‘doing well’: it is beneficial to the water<br />
authorities, the industry and the environment”,<br />
says Mr. Berenst, executive of one of the Phario<br />
consortia members.<br />
Mr. Egbert Berenst, executive of Wetterskip Fryslân:<br />
“Our commitment is high. We believe we enable and boost<br />
biodegradable applications. It is one of the solutions to reduce<br />
the severe effects of micro plastics and plastic soup, and it<br />
is supportive to good governance and recycling as major<br />
solutions too. We also play another role in this market:<br />
we encourage all suppliers of biopolymers to supply biodegradable<br />
applications and solutions we can use in our<br />
water system. Phario really combines ‘doing good’ with ‘doing<br />
well’: we focus on both strong business and value cases.”<br />
www.phario.eu<br />
[1] Public report: https://tinyurl.com/phario<br />
Partners of PHARIO:<br />
Waterschap Brabantse Delta, Waterschap de Dommel, Wetterskip<br />
Fryslân, Waterschap Hollandse Delta, Waterschap Scheldestromen,<br />
HVC, SNB, STOWA, TUDelft, Wetsus, Paques, EFGF<br />
28 bioplastics MAGAZINE [03/18] Vol. 13
Report<br />
By:<br />
Martijn Bovée<br />
Business Developer<br />
Energie- & Grondstoffenfabriek<br />
Tiel, The Netherlands<br />
rethinking<br />
plastic<br />
PHARIO claims the following value proposition for<br />
applications:<br />
• High purity due to green solvent extraction<br />
• Design polymer: consistent quality and composition control options<br />
• Up to 40% HV content and high molecular weight (>1.000 kDA)<br />
• Lower melting points, amorphous<br />
• No use of raw materials and land; only waste/residues, non GMO<br />
• Cost competitive and 70% better LCA than classic PHA from monoculture<br />
Produced<br />
exclusively from<br />
pure plant-based,<br />
renewable<br />
resources!<br />
Figure 2: 1 kg of PHBV biopolymer from<br />
waste water<br />
Figure 3: Alternative to fishing lead<br />
Our premium range from<br />
renewable raw materials<br />
Figure 4: Festival tokens<br />
With Joma Nature® we offer a select<br />
range of our Spice Grinders and our<br />
Securibox® as an environmentally<br />
conscious alternative to conventional<br />
products – sustainable and CO 2-<br />
neutral.<br />
For our environment, we aim to<br />
protect our natural surroundings<br />
and secure a livable world for our<br />
children.<br />
www.joma.at<br />
bioplastics MAGAZINE [03/18] Vol. 13 29
From Science & Research<br />
The French project PolyOil2Industry aimed at the development<br />
of a new biobased polymer based on renewable<br />
polyol intermediates. This 4 year research project<br />
has recently been completed. It was an inspiring collaboration<br />
between several French industrial partners which finally<br />
resulted in new renewable building blocks.<br />
These green polyols needed to answer the current<br />
demand of the different markets with new technical<br />
performance. Three main areas of applications were<br />
targeted in the project: building, packaging and cosmetics<br />
with the respective companies Soprema, Vegeplast and<br />
Polymerexpert. The project partner ITERG as well as LCPO<br />
(the joint research unit of the University of Bordeaux,<br />
CNRS and Bordeaux National Polytechnic Institute) have<br />
first developed the building blocks and prepolymers on<br />
laboratory scale, answering the specifications for each of<br />
the targeted applications. Of the most promising building<br />
blocks, ITERG scaled up the different protocols. The biobased<br />
1,3-propanediol developed by Metabolic Explorer made it<br />
possible to synthesize 100% renewably sourced polyols.<br />
Oleon, also project leader, was in charge of the further<br />
upscaling to the final production on an industrial scale of<br />
the selected molecules after the technical screening in the<br />
different applications.<br />
Along with the project, the different partners have<br />
been supplied with several building blocks obtained from<br />
vegetable triglycerides (from high oleic sunflower oil to<br />
castor oil) for an extensive evaluation of the performance<br />
in the applications. One molecule per applications has been<br />
selected, namely, a polyester polyol derived from ricinoleic<br />
acid for use in insulating foam (building), a diol prepolymer<br />
as a precursor for gelling of an oil phase for cosmetic<br />
application and a polymer additive as impact modifier for<br />
poly-L-lactide (PLA) for packaging.<br />
At this stage, tests in real production conditions are still<br />
necessary in the case of insulating foams for construction,<br />
but the results so far are promissing. For the other<br />
applications, commercial development perspectives are<br />
quite achievable. The invention of the gelling agent has<br />
been secured by a patent and commercialisation is started.<br />
With respect to the polymer additive for packaging, a<br />
wide range of polyricinoleates have been tested in PLAblends.<br />
Toughness of the blends has been significantly<br />
improved, elongation at break reached values of 100%, with<br />
no decrease of the tensile maximum strength as shown in<br />
Fig. 1. The PLA impact resistance has been doubled thanks<br />
to the addition of 3 %wt of the polyricinoleate additive. This<br />
mayor improvement of the properties offers the possibility<br />
to inject new flexible and impact-resistant bioinspired<br />
packagings (tray, tops) based on PLA.<br />
The results of the project is therefore very satisfactory.<br />
Molecules from vegetable lipid resources can be just as<br />
powerful as petrochemical molecules. They give access<br />
to new performances and this thanks to environmentally<br />
friendly processes.<br />
Breaking<br />
barrier for<br />
clean<br />
&<br />
green<br />
BioPolyols<br />
Fig. 1: PLA-polymer dumbbell-shaped specimen after tensile<br />
testing, v = 5mm/min (top specimen: before testing, middle: PLA<br />
without polyricinoleate, bottom: PLA with 3% polyricinoleate)<br />
Fig.: 2: Examples of PLA packaging materials with polyricinoleate<br />
additive as impact modifier:<br />
www.oleon.com | www.iterg.com | www.lcpo.fr | www.soprema.fr |<br />
www.vegeplast.com | www.polymerexpert.fr | www.metabolic-explorer.com<br />
30 bioplastics MAGAZINE [03/18] Vol. 13
Automotive<br />
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bioplastics MAGAZINE [03/18] Vol. 13 31
Report<br />
Compostable sanitary napkins<br />
for India’s girls and women<br />
Menstruation, the most natural bio-physiological phenomenon<br />
in a woman’s life cycle, is considered dirty<br />
and impure throughout India. This is reflected in the<br />
way the entire concept of Menstrual Hygiene gets handled.<br />
The shame, the secrecy, lack of access to clean pads or<br />
toilet facilities further adds to the challenges. The implications<br />
are deeper and more pervasive than any statistic can<br />
attempt to portray.<br />
<strong>Issue</strong>s such as lack of awareness, lack of access, and<br />
un-affordability force approximately 300 million women<br />
to rely on old rags, plastic, sand, and ash to address their<br />
sanitation needs during their menstrual cycle.<br />
The 12 % that do have access will throw away approximately<br />
433 million napkins every month (which equates to nearly<br />
150 kg of waste per woman/girl over her lifetime). Studies<br />
show that each sanitary pad could take 500-800 years to<br />
decompose.<br />
According to a report, it is estimated that these 433<br />
million pads annually generate a potential of 9,000 tonnes<br />
of sanitary waste in India. Furthermore, more than 80 %<br />
of this waste is either flushed down the toilet or ending up<br />
dumped in a landfill. Sanitary waste disposal is not merely<br />
a waste management issue, it’s a health and human rights<br />
issue that affects the entire country. As there is currently<br />
no standardized method of sustainable sanitary waste<br />
disposal, every menstrual product disposed contributes to<br />
either soil, air or water contamination. Any soiled sanitary<br />
products is a breeding ground for infections and diseases.<br />
Stagnant menstrual blood accumulates bacteria such as<br />
Escherichia coli, or E coli, which multiplies at an alarming<br />
rate.<br />
Through the Aakar Model, Aakar Innovations endeavour<br />
to break the silence around the issue of menstrual hygiene<br />
and provide knowledge and guidance to all stakeholders,<br />
especially adolescent girls. The idea is that something as<br />
natural as menstruation does not become a thing of shame,<br />
adolescent girls have access to pads, know how to use<br />
and dispose them, while the community and institutional<br />
systems are sensitised and support them in this process.<br />
Aakar is a hybrid social enterprise that enables women<br />
to produce and distribute affordable, high-quality, 100 %<br />
compostable sanitary napkins within their communities<br />
while simultaneously raising awareness and sensitization<br />
of menstrual hygiene management. In 2013, Aakar became<br />
India’s first company to launch a 100 % compostable<br />
sanitary pad under the brand name Anandi.<br />
To increase the efficiency of fluid (menstrual blood)<br />
absorption and make the pad thin, most of the sanitary<br />
napkins as produced by the MNCs (Multi National<br />
Companies) utilize gel-sheet of super absorbent polymer<br />
(SAP), dioxane, and other hazardous chemicals. SAP can<br />
sometimes suck the useful fluid which may cause serious<br />
infections and can lead to various diseases like cancer, skin<br />
diseases, etc. In fact, India is one of the countries with the<br />
highest rates of cervical cancer (it accounts for almost 23 %<br />
of all cancer in Indian women), and the studies shows a<br />
direct link between HPV (Human papillomavirus infection)<br />
infections (cause of cervical cancer) and poor menstrual<br />
hygiene.<br />
This situation necessitates the development of user and<br />
environmental friendly menstrual health products. ‘Anandi’<br />
Fig 1 +2: Women produce compostable sanitary napkins<br />
32 bioplastics MAGAZINE [03/18] Vol. 13
www.pu-magazine.com<br />
SPM-FLP-639 Flex Foam Ad_145x165mm.indd 1<br />
03/2017 JUNE/JULY<br />
Molded flexible foam with Honeywell Solstice® Liquid Blowing Agent<br />
cuts weight up to 20% in seats, carpet underlayment, other acoustic<br />
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and acoustics. You’ll have the flexibility to meet desired designs while<br />
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By:<br />
Jaydeep Mandal<br />
Aakar Innovations Pvt. Ltd.<br />
CBD Belapur, Navi Mumbai, India<br />
(patent no.3129/MUM/2015) is 100 % compostable sanitary<br />
napkin using biobased compostable polymer film. It uses<br />
virgin soft pine wood pulp containing more than 97 % of<br />
cellulose and hemi-cellulose. The wood pulp as used has<br />
pure cellulose materials with complete uniformity of fibers<br />
allowing it to decompose easily. Activated by only ecofriendly<br />
Ozone treatment process and using compostable<br />
bioplastic. The root sources of the material used is from<br />
naturally available Corn starch.<br />
www.aakarinnovations.com<br />
Sanitary napkins made from biobased and compostable materials<br />
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bioplastics MAGAZINE [03/18] Vol. 13 33
From Science & Research<br />
Biobased filler for SMC<br />
Introduction and motivation: In the market of glass-fiberreinforced<br />
polymer composites (GFRPC), Sheet Molding<br />
Compound (SMC) has high market relevance, as 20 % of<br />
all the glass fibers produced in Europe are handled in SMC<br />
processes [1]. Normally, SMC consists of a highly filled thermoset<br />
resins system, mostly based on unsaturated polyester<br />
resin, glass fi-bers, application specific additives and<br />
filler materials, see Figure 1. SMC is, based on its me-chanical<br />
properties, predestinated for the use in semi-structural<br />
parts or hang-on parts – e.g. for automotive applications.<br />
By a variation of the specific additives and the directly linked<br />
change of the composition of the semi-finished product, the<br />
scope of application can be diversified. The properties of the<br />
material itself can be changed from e.g. electrical applications<br />
for cabi-nets to parts with an equal thermal expansion<br />
coefficient as steel. Further advantages of the material are<br />
the advantageous price for the semi-finished product and<br />
the possibility for cost-efficient large-scale processing of<br />
the material in a parallel regulated compression molding<br />
pro-cess.<br />
Project approach: In a standard SMC, based on UP resin<br />
systems, approximately 40 % of the total weight of the SMC<br />
semi-finished product consists of mineral filler materials<br />
(Figure 1). These fillers can be divided into functional filler<br />
materials, e.g. aluminum hydroxide (Al(OH)3 as flame<br />
retardant with a density of 2.4 g/cm³) and non-functional<br />
filler materials, e.g. calcium carbonate ((CaCO3) with a<br />
density of 2.71 g/cm³). Within the scope of this research<br />
work, which was carried out at the Institute for Composite<br />
Materials (IVW) and the Institute for Bio-technology and<br />
Drug Research (IBWF) (both Kaiserslautern, Germany), the<br />
use of renewable and biobased filler materials replacing<br />
conventional filler materials was examined. Here, attention<br />
was paid to the fact that the biobased materials are a<br />
by-product of food industry and for-estry and should not be<br />
in direct contradiction. As biobased filler materials, wood<br />
flour out of regional soft- and hardwood, rapeseed meal,<br />
rice hulls and sunflower hull meal were used. The different<br />
fillers were subjected to different test series regarding their<br />
density, particle size distri-bution, dispensability, wettability,<br />
influence to resin paste viscosity and their tendency to<br />
fungus growth. This work will show an extract of the<br />
results which were achieved using grinded sun-flower<br />
hulls as a filler material for a standard SMC. In different<br />
test series, the non-functional filler material was replaced<br />
by an increasing proportion of biobased filler materials.<br />
Hereby, the focus was on the processability of the semifinished<br />
products. The semi-finished products should be<br />
processable with a conventional SMC production line and<br />
pressed with a conven-tional press cycle, see Table 1.<br />
Liquid<br />
components<br />
Figure 1:<br />
Composition of<br />
a typical SMC<br />
formulation (data<br />
in weight percent)<br />
Production and processing of SMC with biobased filler<br />
materials: The production of the SMC resin paste was<br />
carried out on a laboratory scale circular disc dissolver. The<br />
amount of biobased filler materials, replacing conventional<br />
filler materials, was raised in different test se-ries by steps<br />
of 25 %. The resin paste was processed to a SMC semi-<br />
Thermoplastic<br />
additiv 8 %<br />
UP-resin<br />
15 %<br />
Glass<br />
fibers<br />
30 %<br />
Application<br />
specific<br />
additives 7 %<br />
Filler<br />
materials<br />
40 %<br />
Powedery<br />
compomets<br />
34 bioplastics MAGAZINE [03/18] Vol. 13
From Science & Research<br />
By:<br />
Florian Gortner 1 ; Anja Schüffler 2 ,<br />
Jochen Fischer 2 , Peter Mitschang 1<br />
1: Institut für Verbundwerkstoffe GmbH (IVW)<br />
2: Institut für Biotechnologie und Wirkstoff-Forschung gGmbH (IBWF)<br />
(both) Kaiserslautern, Germany<br />
finished material on the institutes’ own SMC production<br />
line under industry-oriented processing parameters. After<br />
a maturing time of 4 to 6 days, the semi-finished material<br />
was processed to specimen plates with conventional SMC<br />
processing parameters, see Table 1.<br />
Fungus/microorganism growth testing: All material<br />
samples with differing biobased filler concentrations<br />
were cut into square pieces (15 x 15 mm). The samples<br />
were photographed using a reflected-light microscope<br />
and afterwards incubated in microbiological growth<br />
medium inoculated with a Trichoderma species (Figure 2<br />
A1), a mixture of airborne organisms (Figure 2 A2) and a<br />
standardized humus soil (Figure 2 A3), respectively. All<br />
samples were incubated at 27°C in a laboratory incubator<br />
at 40 rpm to ensure oxygen supply. The samples were<br />
surface-analyzed for possible degradation after 6 weeks.<br />
Additionally the square pieces were incubated based on<br />
the “Mildew Resistance Test Procedure GMW3259” but<br />
incubation temperature was 37 °C, 45 ml PS tubes with<br />
lamella stopper as containers and supports made of plastic<br />
were used.<br />
Results of mechanical properties and density reduction:<br />
By the replacement of the con-ventional non-functional<br />
fillers with biobased fillers, a reduction of the density of the<br />
semi-finished products up till 9,4 % could be realized. The<br />
mechanical properties given in this work were determined<br />
on tensile test according to DIN EN ISO 527-4 specimen<br />
type 2 (250x15x4 mm³) and decrease slightly with increasing<br />
share of the biobased filler materials. With a content of<br />
biobased filler materials of 75 %, Young’s modulus was<br />
decreased by 18 %, tensile strength was decreased by 20 %<br />
(Figure 2). Taking the specific mechanical properties into<br />
account, the new materials are very well comparable to<br />
standard SMC.<br />
Results of fungus/microorganism growth testing:<br />
Although the cut edges of all material samples were covered<br />
with a biofilm (Figure 2 C) in the cultures inoculated with<br />
Trichoderma, airborne microorganisms and humus soil<br />
sample, no degradation was observed even when 100 % biofiller<br />
were used (exemplarily a sample with 75 % bio-filler is<br />
shown before (Figure 2 B) and after incubation with airborne<br />
organisms for six weeks (Figure 2 D)). Furthermore, the<br />
mate-rial samples incubated based on “GMW3259” did not<br />
possess any fungal growth nor moldy odor after two weeks.<br />
Conclusion: The good mechanical results and the<br />
biological durability show that the use of biobased materials<br />
as filler materials for SMC is a realistic option. By using<br />
a former by-product of food industry or forestry as a raw<br />
material in a composite material an ecological useful upcycling<br />
is enabled.<br />
www.ivw.uni-kl.de | www.ibwf.de<br />
Table 1: Processing parameter<br />
for the production and processing of SMC<br />
Figure 2: Influence of the biobased filler materials to the<br />
mechanical properties according to DIN EN ISO 527<br />
Manufacturing:<br />
14.000 —<br />
Tensile strength<br />
Young‘s Modulus<br />
— 100<br />
Resin paste viscosity for the<br />
processing on a SMC-line<br />
Processing:<br />
15 – 45 Pa∙s<br />
Tool temperature 135 – 145 °C<br />
Cycle time<br />
approx. 1 min per mm<br />
thickness of the part<br />
Pressure inside the mold 100 – 120 bar<br />
Young‘s Modulus [MPa]<br />
12.000 —<br />
10.000 —<br />
8.000 —<br />
6.000 —<br />
4.000 —<br />
2.000 —<br />
0 —<br />
100 % CaCO 3<br />
0 % bio-filler<br />
75 % CaCO 3<br />
25 % bio-filler<br />
50 % CaCO 3<br />
50 % bio-filler<br />
Variation of filler materials<br />
— 100<br />
— 80<br />
— 60<br />
— 40<br />
— 20<br />
— 0<br />
25 % CaCO 3<br />
75 % bio-filler<br />
Tensile strength [MPa]<br />
A B C D<br />
1 2 3<br />
Figure 3: Material samples incubated with Trichoderma sp. (A1), airborne organisms (A2) and humus soil (A3); magnification of a sample<br />
with 75 % bio-filler before (B), with biofilm after (C) and washed after incuba-tion with airborne organisms for 6 weeks<br />
bioplastics MAGAZINE [03/18] Vol. 13 35
Report<br />
Spanish project will develop<br />
customized materials<br />
New customized compostable materials for the manufacture<br />
of tableware, packages and single-use bags<br />
In recent years, the legislation regulating waste management<br />
has focused on reducing the environmental impact<br />
of packaging and its waste with specific provisions that<br />
foster the use of compostable bags, such as the French directive<br />
that, since the beginning of 2020, will ban the use of<br />
disposable tableware if not a minimum amount of 50 % of<br />
the material used for its man- ufacture is derived<br />
from renewable<br />
sources<br />
and the<br />
materials are<br />
not compostable<br />
in home<br />
composting. In<br />
Spain, a Royal<br />
Decree project will<br />
force to spread the<br />
concept of biodegradable<br />
to<br />
compostable.<br />
In this<br />
legislative<br />
context and<br />
a lack of a<br />
sufficiently<br />
w i d e<br />
range of<br />
materials<br />
covering<br />
the needs<br />
required by the<br />
(Generic picture)<br />
market and being<br />
an adequate alternative to conventional<br />
plastic materials, the Spanish project BIO+ will<br />
develop customized materials responding to these needs.<br />
The project Bio+ companies manufacturing singleuse<br />
products, led by the bag manufacturer PICDA and<br />
coordinated by AIMPLAS (both from Valencia, Spain)<br />
collaborate with other centres and universities.<br />
The main objective of the project is to develop customized<br />
compostable materials for mass-market single-use<br />
products complying with the current legislation and with<br />
the same functional requirements as products made<br />
from traditional plastic materials and at competitive cost.<br />
For that purpose, tasks are being carried out to realize<br />
the biodegradation of different products with view to their<br />
end of life. Thus, for single-use packages and disposable<br />
tableware, which are normally contaminated with food<br />
scraps, a compostability in ‘home compost’ conditions is<br />
to be achieved. For single-use bags that wrongly managed<br />
may end in the environment, rivers and subsequently the<br />
oceans, a biodegradability in marine environment is to be<br />
sought.<br />
The consortium of the project is led by PICDA specialized<br />
in extrusion of plastic bags of different formats, and<br />
Granzplast (Corbera, Valencia, Spain), engaged in the<br />
manufacture of customized plastic compounds for injection<br />
and extrusion technologies. In order to tackle<br />
the developments in disposable household<br />
items developed, the companies<br />
Nupik (Polinyà, Barcelona, Spain),<br />
leader in the manufacture of<br />
disposable household items and<br />
Perez Cerdá Plastics<br />
(Castalla, Alicante,<br />
Spain), specialized<br />
in tasks of plastics<br />
injection applied their<br />
knowledges in singleuse<br />
injected household<br />
items (cutlery and<br />
cups). The consortium<br />
is completed with<br />
companies addressing<br />
the developments in<br />
single-use packaging,<br />
such as Indesla (Biar,<br />
Alacant, Spain),<br />
manufacturer<br />
of packages<br />
for the fruit and<br />
vegetable and food<br />
sectors and Thermolympic<br />
(Utebo, Zaragoza, Spain), a company dedicated<br />
to the injection of thermoplastics that, in this project, will<br />
tackle the development of packages for catering. Moreover,<br />
the consortium has the support of three technology centres<br />
such as Aimplas, AITIIP and CETIM and the University of<br />
Santiago de Compostela (USC), which will provide scientific<br />
and technical support to the companies taking part in R&D<br />
tasks.<br />
The project BIO+ has been funded by the Spanish Ministry<br />
of Economy, Industry and Competitiveness through the<br />
Centre for the Development of Industrial Technology (CDTI)<br />
through the call aimed at funding the strategic programme<br />
for national business research consortia (CIEN 2017<br />
programme) and with grant number SOL-00103164. MT<br />
www.aimplas.net<br />
36 bioplastics MAGAZINE [03/18] Vol. 13
Materials<br />
Sun protection<br />
cosmetics made with<br />
PHB bioplastic<br />
Save the date<br />
see page 10-11 for details<br />
Bio-on (Bologna, Italy), recently presented a brand-new<br />
line of cosmetic ingredients for sun protection made<br />
from its 100% natural and biodegradable PHB bioplastic.<br />
The new products are part of the minerv bio cosmetics<br />
family of bioplastic micro powders presented in spring<br />
2017 and designed for cosmetics that respect the environment<br />
and human health. This latest innovation is a series<br />
of high-performing SPF (Sun Protection Factor) Boosters<br />
designed to improve sun protection products.<br />
Increased awareness of the harm caused by exposure<br />
to sunlight is accelerating the number of products with UV<br />
filters released on the market. Their purpose is to screen<br />
against UV radiation: UV-B rays, the most common cause<br />
of sun erythema and sunburn, and UV-A rays, which are<br />
responsible for more serious long-term effects: blood<br />
vessel damage, photoaging, photocarcinogenesis.<br />
What people ignore is that, unfortunately, organic<br />
UV filters can be phototoxic and photounstable. The<br />
main goal of the scientific community is to find a way to<br />
limit their concentration in cosmetics formulas without<br />
compromising performance. This is where the new SPF<br />
Booster line developed for the minerv bio cosmetics brand<br />
comes in. These ingredients (micro powders made from<br />
biodegradable PHB microscopic spheres or capsules) are<br />
designed to significantly reduce the percentage<br />
of UV filters used in the sun protection product<br />
and boost waterresistance.<br />
The minerv bio cosmetics portfolio, which<br />
already includes texturizing powders for skin<br />
care and make-up, mattifiers, scrubs, and<br />
micro capsules for the controlled release<br />
of active substances, ideal for anti-ageing<br />
treatments, is now extended to include:<br />
• minervPHB Riviera an SPF Booster<br />
suitable for all solar formulations<br />
• minervPHB Riviera Plus an innovative<br />
SPF Booster, enriched with antioxidants,<br />
ideal for total care products (skin care,<br />
make-up, hair care).<br />
“Riviera represents another building<br />
block in our green cosmetics revolution,”<br />
says Marco Astorri, Bio-on Chairman and<br />
CEO, “to make the personal care market<br />
truly sustainable and fully respect the<br />
ocean and the land. By continuing to find<br />
new solutions for the cosmetics sector, our<br />
company is setting a new standard thanks<br />
to our PHBs bioplastic.”<br />
“The Riviera line is a success story from our Powder<br />
Boutique,” explains Paolo Saettone, Managing Director<br />
of the Bio-on CNS Business Unit, “a site dedicated to<br />
advanced research, where our scientists play with our<br />
versatile biopolymer like tailors play with fabrics, seeking<br />
out the perfect morphology and technology to maximise<br />
performance. This fine work has created the Riviera micro<br />
particles, which are the perfect scattering centre element<br />
for UV rays.”<br />
All the PHAs (polyhydroxyalkanoates) developed by Bio-on<br />
are made from renewable plant sources with no competition<br />
with food supply chains. They can replace a number of<br />
conventional polymers currently made with petrochemical<br />
processes using hydrocarbons; they guarantee the same<br />
thermo-mechanical properties as conventional plastics<br />
with the advantage of being completely eco-sustainable and<br />
100% naturally biodegradable.<br />
Starting in summer <strong>2018</strong>, all minerv bio cosmetics<br />
products will be made by Bio-on Plants, Bio-on’s first<br />
industrial plant dedicated to the production of cosmetic<br />
ingredients. Located in Castel San Pietro Terme (Bologna),<br />
it will produce 1000 tons/year of PHB micro powders over<br />
an area of 3,000 m2 with an overall investment of 20 million<br />
Euro. MT<br />
www.minerv-biocosmetics.com | www.bio-on.it<br />
bioplastics MAGAZINE [03/18] Vol. 13 37
From Science & Research<br />
Astroplastic – 3D-printable PHB<br />
from human waste for<br />
use in space<br />
Governments and private enterprises alike are gearing<br />
up for travel across our Solar System. Plans to<br />
colonize nearby planets are underway, with Elon<br />
Musk spearheading the initiative to put a human colony on<br />
Mars by 2030. In a parallel vein, NASA is planning a manned<br />
exploratory mission to Mars as early as the 2030s. Several<br />
other space agencies have similar plans and timelines for<br />
their own Mars explorations. This exciting time in our history<br />
nonetheless comes with the challenges of long-term space<br />
travel. Two ecological and economic challenges arise: the<br />
sustainable management of waste produced on a spaceship<br />
and the high cost of shipping materials to space [1].<br />
A current University of Calgary’s project involves using<br />
genetically engineered E. coli to turn human waste into<br />
bioplastics. The project is envisioned as a start-to-finish<br />
integrated system that can be used in space to generate<br />
items useful to astronauts during early Mars missions. This<br />
will solve the problem of waste management by upcycling<br />
solid human waste into a usable product. It will also reduce<br />
astronautical costs, as expensive fuel routinely used to ship<br />
materials to space can be saved.<br />
For the team of students testing a breakthrough<br />
biological plastic for 3D printing in space, the formula was<br />
the difference between using fake feculence or finding a<br />
volunteer to provide the real deal [2].<br />
“We actually tried to pursue the route of using the real<br />
thing, but no one wanted to have it inside the lab,” laughs<br />
Alina Kunitskaya, a fourth-year chemical engineering<br />
student at the Schulich School of Engineering.<br />
UCalgary’s project, entitled Astroplastic: From Colon<br />
to Colony, tests the theory of using human waste as the<br />
foundation for a bioplastic that can then be used in 3D<br />
printers to build tools — a process that would be especially<br />
useful to astronauts on deep-space missions.<br />
The bioplastic material meant here is Poly(3-<br />
hydroxybutyrate) (PHB), a linear polyester and is a product<br />
of bacterial fermentation of some sugars or lipids. PHB is<br />
used by certain bacteria as carbon and energy storage.<br />
“With space travel, such as a three-year mission to<br />
Mars, there are major challenges to overcome,” explains<br />
Kunitskaya, who specializes in biomedical engineering.<br />
“Transporting material is difficult and expensive, and<br />
how do you anticipate every challenge and everything you<br />
need over three years on a trip to Mars? Recycling waste is<br />
another major challenge.”<br />
Making plastic out of poop could be the answer, and<br />
the Calgary team — composed of 14 undergraduate<br />
students from the Faculty of Science, the Cumming School<br />
of Medicine, and the Schulich School of Engineering,<br />
with mentoring from six faculty advisers from the three<br />
disciplines — decided to find out.<br />
“We got the team together at the beginning of the winter<br />
semester (2016) and started brainstorming ideas, and each<br />
person came up with their own idea,” says Kunitskaya.<br />
“The only criteria is having synthetic biology which is<br />
engineering bacteria to do something useful. And at first,<br />
our idea was to make plastic out of wastewater.”<br />
A visit to Calgary’s wastewater treatment plant and<br />
further brainstorming refined that idea into a solution for<br />
deep-space astronauts. And, armed with the advice of<br />
38 bioplastics MAGAZINE [03/18] Vol. 13
From Science & Research<br />
Save the date<br />
see page 10-11 for details<br />
real space travellers like Chris Hadfield and University of<br />
Calgary Chancellor Robert Thirsk, the team had its mission.<br />
“This year, the University of Calgary’s project involves<br />
using genetically engineered E. coli to turn human waste<br />
into PHB,” reads the team summary of the project.<br />
“We envision our project as a start-to-finish integrated<br />
system that can be used in space to generate items useful<br />
to astronauts during early Mars missions. This will solve the<br />
problem of waste management by upcycling solid human<br />
waste into a usable product.”<br />
And yes, it works. More than just an exercise on paper,<br />
the team actually produced PHB in the Bachelor of Health<br />
Sciences laboratory, where the team worked all spring<br />
and summer, carefully documenting every detail of their<br />
collaborative work on a wiki website [1].<br />
The detailed research and stringent attention to the<br />
iGEM requirements earned the team a gold medal at the<br />
International Genetically Engineered Machine (iGEM)<br />
Foundation’s Giant Jamboree in Boston, where nearly 5,000<br />
students representing 330 universities presented their<br />
best ideas on synthetic biology. In addition the Astroplastic<br />
project was nominated for Best Manufacturing Project at<br />
the Boston event — the world’s premiere student team<br />
competition in synthetic biology.<br />
“The jamboree was their time to shine, and shine they<br />
did — for the University of Calgary,” says Mayi Arcellana-<br />
Panlilio, senior instructor in biochemistry and molecular<br />
biology at Cumming School of Medicine, and lead faculty<br />
adviser of the iGEM team. MT<br />
Sources:<br />
[1] Astroplastic-wiki: http://2017.igem.org/Team:Calgary<br />
[2] https://tinyurl.com/astroplastic<br />
www.ucalgary.ca<br />
bioplastics MAGAZINE [03/18] Vol. 13 39
Materials<br />
Thermoplastic<br />
starch from the<br />
heart of Europe<br />
By:<br />
Gottfried Krapfenbauer (Sales Director Technical Specialities) and<br />
Barbara Fahrngruber (Teamlead R&D)<br />
AGRANA STÄRKE<br />
Vienna, Austria<br />
The need for green ingredients in bioplastics is becoming<br />
an important topic. Efficient resource management<br />
that addresses renewable materials and waste<br />
recovery is a crucial future step towards a circular economy.<br />
Thermoplastic starch (TPS) produced by AGRANA can help<br />
to fulfill these requirements.<br />
AMITROPLAST ®<br />
Starch, itself consisting of the two polymers amylose and<br />
amylopectin, is an amazing and very versatile material,<br />
making it an important base for modern bioplastics. In the<br />
production of bioplastics, Agrana uses its many years of<br />
expertise in the production and processing of starch and<br />
supplements this with the knowledge of the needs of the<br />
plastics industry.<br />
With the Amitroplast product family, Agrana provides<br />
user-friendly TPS (Thermoplastic Starch) for extrusion, film<br />
blowing, injection moulding and 3D printing.<br />
Amitroplast is bio-based, biodegradable and can be<br />
disposed of in a home or industrial composting environment.<br />
All Amitroplast products allow users to incorporate<br />
significant amounts of TPS and thus, to create tailor-made<br />
Starch TPS Blend Final Product<br />
• Nongenetically<br />
modified<br />
• Renewable<br />
raw material<br />
• Biodegradable<br />
• Compostable<br />
• Biobased<br />
• Made in<br />
Austria<br />
Material<br />
adaptation<br />
specifically to<br />
requirements<br />
by<br />
combination<br />
with other<br />
bio-polymers<br />
and additives<br />
Products with<br />
the previously<br />
customdetermined<br />
properties<br />
polymer compounds that are processable by using standard<br />
polymer equipment and capable of adding extra value to<br />
innovative products.<br />
The material properties of a 25 µm film, based on a<br />
compound that consists of 50 % Amitroplast and 50 % PBAT<br />
(polybutylene adipate-co-terephthalate), results typically<br />
in an extensibility of approximately 350 % and a tensile<br />
strength of 20-25 MPa.<br />
Furthermore, the new technology of Amitroplast<br />
significantly reduces the development of fumes during film<br />
blowing.<br />
Amitroplast is produced from renewable and regional raw<br />
material. All ingredients are derived from non-geneticallymodified<br />
sources.<br />
R&D at Agrana<br />
The journey of implementing sustainable solutions to<br />
ensure the fulfillment of today´s and future demands is not<br />
yet over. Agrana employs a significant number of scientists<br />
and technicians who conduct applied research and<br />
customer-oriented product development. Strengthening<br />
sustainable partnerships is their motivation, whereby<br />
confidentiality and technical support are guaranteed.<br />
Agrana worldwide<br />
Agrana is an international company headquartered in<br />
Vienna, Austria. Founded in 1988, Agrana today achieves<br />
a turnover of 2.6 billion EUR with 8900 employees. The<br />
main areas are starch, fruit and sugar with more than 1000<br />
products across the divisions. Agrana is the leading sugar<br />
company in Central and Eastern Europe, as well as the<br />
global leader in fruit preparations and a major producer of<br />
fruit juice concentrates in Europe.<br />
Agrana Starch specialises in processing and adding value<br />
to high quality agricultural commodities such as corn,<br />
potato and wheat to make a wide range of starch product.<br />
Tailored to different industrial uses from top quality<br />
foodstuffs to numerous industrial upstream products<br />
as well as bioethanol, AGRANA STARCH has a long and<br />
exceptionally successful track record in the development<br />
and marketing of starch products. More details at<br />
www.agrana.com/en/products/starch-portfolio/productsfor-technical-applications/<br />
www.agrana.com<br />
40 bioplastics MAGAZINE [03/18] Vol. 13
Automotive<br />
PRESENTS<br />
The Bioplastics Award will be presented<br />
during the 13 th European Bioplastics Conference<br />
December 04-05, <strong>2018</strong>, Berlin, Germany<br />
THE THIRTEENTH ANNUAL GLOBAL AWARD FOR<br />
DEVELOPERS, MANUFACTURERS AND USERS OF<br />
BIOBASED AND/OR BIODEGRADABLE PLASTICS.<br />
Call for proposals<br />
Enter your own product, service or development,<br />
or nominate your favourite example from<br />
another organisation<br />
Please let us know until August 31 st<br />
1. What the product, service or<br />
development is and does<br />
2. Why you think this product,<br />
service or development should win an award<br />
3. What your (or the proposed) company<br />
or organisation does<br />
<strong>2018</strong><br />
Your entry should not exceed 500 words (approx. 1 page)<br />
and may also be supported with photographs, samples,<br />
marketing brochures and/or technical documentation<br />
(cannot be sent back). The 5 nominees must be prepared<br />
to provide a 30 second videoclip and come to Berlin on<br />
December 4 th , <strong>2018</strong>.<br />
More details and an entry form can be downloaded from<br />
www.bioplasticsmagazine.de/award<br />
supported by<br />
bioplastics MAGAZINE [03/18] Vol. 13 41
NPE <strong>2018</strong><br />
The Plastics Show, May 7-11, Orlando, Florida, USA, was again the largest plastics show in North America that<br />
attracted plastics producers converters, scientists and otherwise involved visitors from around the world. This<br />
show was the largest in history, with more than 2,180 exhibiting companies showcasing innovations in plastics<br />
in more than 111,000 m² of exhibit space on the tradeshow floor. PLASTICS, the US Plastics Industry Association<br />
estimated a total of about 65,000 attendees.<br />
And bioplastics were again well represented. Of course, a handful of the good 50 exhibitors that we announced<br />
in the last issue didn’t have anything about bioplastics in their portfolio, although listed in the official catalogue… .<br />
But those that did show bioplastics related products and services were well known protagonists as well as<br />
newcomers in this industry. In the following paragraphs we will introduce just a few highlights.<br />
<strong>2018</strong><br />
NPE Review<br />
Danimer Scientific<br />
Danimer Scientific, Bainbridge, Georgia,<br />
USA, is a pioneer in creating more sustainable,<br />
more natural ways to make plastic products.<br />
For more than a decade, their renewable and<br />
sustainable biopolymers have helped create<br />
plastic products that are biodegradable and<br />
compostable.<br />
One product Danimer presented at NPE<br />
that, among many others, caught the attention<br />
of bioplastics MAGAZINE, was a flexible snack<br />
packaging for PepsiCo. It is the 2nd generation<br />
made of a proprietary formulation<br />
from Danimer which contains PLA and<br />
other biopolymers and it is industrially<br />
compostable.<br />
Brad Rodgers, Global R&D Director<br />
– Food Packaging Discovery of PepsiCo<br />
however mentioned that it’s working<br />
with Danimer Scientific to create a biobased<br />
film from polyhydroxyalkanoate<br />
(PHA) – the 3 rd generation – so to say.<br />
Brad stated that PepsiCo has been researching<br />
and developing biobased flexible packaging<br />
for more than 10 years. And the results of<br />
their research made them believe that PHA<br />
will have some significant performance and<br />
environmental advantages once it’s at scale.<br />
“We are pleased and honored that PepsiCo<br />
has chosen to work with Danimer Scientific for<br />
their packaging applications,” said Scott Tuten,<br />
Chief Marketing Officer at Danimer Scientific,<br />
“the future for biopolymers continues to grow<br />
tremendously with forward thinking companies<br />
like PepsiCo leading the way.<br />
Save the date<br />
c2renew<br />
c2renew Corporation (Colfax, North Dakota, USA) develops<br />
proprietary biocomposite formulations that satisfy demanding<br />
engineering specifications. With their technology customers can<br />
take advantage of lower-cost, renewable resources while meeting,<br />
maintaining, and even improving upon the mechanical properties<br />
required. With biocomposite materials made of recycled plastics and<br />
locally sourced agricultural byproducts, c2renew materials support<br />
both the environment and the community.<br />
On top of designing the material, the company also provides a range<br />
of engineering services. Their team of experienced engineers will<br />
guide businesses through every step of the design, manufacturing,<br />
and testing process, ensuring the plastic or composites components<br />
are developed effectively and to the customer’s specifications.<br />
At NPE c3renew showed, among others, a few unique formulations<br />
demonstrated with equally unique samples.<br />
c2PLA – Coffee is a PLA compound with coffee residuals (coffee<br />
chaff, the dried skin of coffee beans, the husk, which comes off during<br />
the roasting process). The compound is up to 40 % filled and provides<br />
an aromatic hint of coffee that emanates from the compound. The<br />
coffee mug on the picture is made of this material.<br />
The beer stein is made of a similar compound filled with residues<br />
from the beer brewing process. Dried Destillers Grains? “Something<br />
similar,” as CEO Corey Kratcha told bioplastics MAGAZINE at their<br />
booth.<br />
Other compounds include c2PLA-Blue (PLA/flax shive, coloured)<br />
and c2PLA-Natural (PLA/flax shive), and c2HIPS (HIPS / heat<br />
stabilized biomass), that can be used up<br />
to the degradation temperature of HIPS<br />
(high impact polystyrene) without any<br />
off-degassing.<br />
www.c2renew.com<br />
www.danimerscientific.com<br />
see page 10-11 for details<br />
42 bioplastics MAGAZINE [03/18] Vol. 13
NPE Review<br />
NatureWorks<br />
From coffee capsules to food serviceware, home<br />
appliances, and innovative 3D printing solutions,<br />
NatureWorks (Minnetonka, Minneapolis, USA) has been<br />
leading application innovations from biomaterials since<br />
1989.<br />
The products NatureWorks displayed at NPE<br />
demonstrated how Ingeo PLA can be tailored to<br />
enhance performance attributes critical to performance.<br />
These attributes include barrier properties, heat and<br />
impact resistance, and thermoformability, all while<br />
embracing the concepts of a low-carbon circular<br />
economy. Recently, NatureWorks reached the milestone<br />
of 900,000 tonnes (2 bn pounds) of Ingeo biopolymer sold<br />
globally via its comprehensive portfolio of 33 grades.<br />
These grades are converted into thousands of consumer<br />
and industrial products across dozens of industries.<br />
A project, that NatureWorks (Minnetonka, Minneapolis,<br />
USA) have worked on for a couple of years was presented<br />
at NPE: Thermoformed refrigerator liners made of from<br />
Ingeo PLA. While keeping the insulation polyurethane<br />
foam the same, Oak Ridge National Laboratories found<br />
that by replacing the HIPS-liner with a new Ingeo<br />
PLA liner, the energy consumption is reduced by 7 to<br />
13%. Over the lifetime of a refrigerator this will save a<br />
significant amount of energy. “If all refrigerators sold in<br />
the USA in <strong>2018</strong> used INGEO liners, the lifetime energy<br />
savings are equal to running an average power plant for<br />
3.2 years”, says Frank Diodato of NatureWorks.<br />
Fostag, Viappiani<br />
Viappiani Printing presented<br />
an innovative application for<br />
the production of IML labeled<br />
compostable coffee capsules.<br />
The exhibit was run on a<br />
Netstal injection machine with a mould from Fostag, a<br />
robot from Beck Automation and IML labels from Viappiani<br />
Printing.<br />
The coffee capsule is injection moulded with PLA. To close<br />
the green circle of sustainability, the capsule is decorated<br />
with an in-mould label which is printed by Viappiani on a<br />
special PLA film. This way a mono component PLA capsule<br />
is obtained, which is fully conform to the EN 13432 norm<br />
regarding industrial composting.<br />
The exhibit combines the need for a green alternative<br />
for capsules, with an improved packaging performance<br />
compared to commonly used plastic materials in terms of<br />
both mechanical and barrier properties. The combination<br />
with high-end decoration given by the IML technology fully<br />
integrates the PLA label into the frame of compostability<br />
needs, and provides 360 degree labelling with highest<br />
offset quality.<br />
Viappiani Printing is specialized in the production of IML<br />
labels which are successfully sold all over the world since<br />
more than 35 years.<br />
www.fostag.com | www.biomebioplastics.com | www.viappiani.it<br />
780<br />
[kWh/yr]<br />
Total Energy Use<br />
740<br />
700<br />
660<br />
620<br />
0 3 6 9 12 15<br />
Energy consumption was modeled under two assumptions:<br />
Unchanged (UC):The Ingeo liner unless punctured will retain a<br />
flat, low level of conductivity through the life of the refrigerator.<br />
Exponential (Exp): The Ingeo liner will eventually reach the<br />
higher level of conductivity performance associated with HIPS.<br />
In addition, there is no sacrificing of the inner capacity<br />
of the refrigerators. The PLA liner is ten times glossier<br />
than the HIPS version and it offers improved resistance to<br />
food oils and fats. The inherent stiffness of PLA provides<br />
additional structural integrity to the liners. Ingeo PLA<br />
systems do not contain styrene or any chemicals of<br />
concern.<br />
www.natureworksllc.com<br />
Years<br />
HIPS<br />
Ingeo EXP.<br />
Ingeo UC<br />
Croda<br />
Croda Polymer Additives, headquartered in Snaith, UK,<br />
presented additives for biopolymers.<br />
Depending on the polymer type and grade, biopolymers<br />
can exhibit a number of problems including high friction<br />
(adhesion), limited impact properties and heat resistance,<br />
and they can require enhancements in melt strength and<br />
other properties.<br />
Croda offer a range of additives that are suitable for<br />
use in biobased polymers that can help overcome most of<br />
these issues, including slip and anti-block, mould release,<br />
torque release, anti-static, anti-fog and UV-absorption.<br />
Croda’s slip additives for polyester based biopolymers for<br />
example can improve overall processability in PLA film<br />
and sheet manufacturing and during injection moulding<br />
by decreasing friction up to 50%, improving mould release<br />
and packaging density of moulded parts. The scratch and<br />
scuff resistance can be improved as well as the surface<br />
quality. And final also the pigment dispersion and melt<br />
flow during processing can be improved.<br />
All these additives have minimal impact on colour,<br />
clarity and physical properties of the biopolymers.<br />
www.crodapolymeradditives.com<br />
bioplastics MAGAZINE [03/18] Vol. 13 43
NPE Review<br />
Mitsubishi Chemical<br />
Mitsubishi Chemical Corporation (headquartered<br />
in Chiyoda-ku, Tokyo) presented two applications for<br />
their a new grade of biobased engineering plastic<br />
DURABIO that can be applied to large automotive<br />
exterior components. One is a front grill of a Mazda<br />
vehicle and the other an interior door panel cover part.<br />
The biobased engineering plastic Durabio is made<br />
from isosorbide deriving from renewable plants. The<br />
material features superior properties compared to<br />
general biobased engineering plastics in terms of<br />
impact resistance, heat resistance and weathering,<br />
among other aspects. It also has good color-capability<br />
and, simply by adding pigments, creates a mirror-like<br />
smooth surface and deep color tone surpassing painted<br />
products with similar properties.<br />
China XD<br />
China XD Plastics Company Limited (Harbin, China), is<br />
a specialty chemical company. The Company is engaged<br />
in the research, development, manufacture and sale<br />
of modified plastics for automotive applications in<br />
China and to a lesser extent, in Dubai, the United Arab<br />
Emirates (UAE). On their big booth they also displayed<br />
different PLA grades and biocomposites.<br />
One example was an automotive dome light cover,<br />
made of PLA filled with talc.<br />
www.mcpp-global.com<br />
Automotive dome light<br />
cover (PLA/talc)<br />
44 bioplastics MAGAZINE [03/18] Vol. 13
New<br />
wood-based<br />
biocomposite<br />
Stora Enso (Stockholm & Helsinki) is launching its<br />
wood-based biocomposites, DuraSense. This is another<br />
major step on the group’s journey to replacing fossilbased<br />
materials with renewable solutions.<br />
DuraSense enables the use of renewable fibres, such<br />
as wood, to substitute for a large portion of fossil-based<br />
plastic. The production of biocomposites began in <strong>2018</strong> at<br />
Stora Enso’s Hylte Mill in Sweden, following the EUR 12<br />
million investment announced in 2017. At full production,<br />
the mill’s annual production capacity is 15,000 tonnes,<br />
which is the largest capacity in Europe dedicated to wood<br />
fibre composites.<br />
“Reducing the amount of plastic and replacing it<br />
with renewable and traceable materials is a gradual<br />
process. With DuraSense, we can offer customers a wood<br />
fibre-based alternative which improves sustainability<br />
performance and, depending on the product, significantly<br />
reduces the carbon footprint – all the way up to 80%,” says<br />
Jari Suominen, Head of Wood Products at Stora Enso.<br />
The DuraSense product family is suitable for a wide<br />
range of applications from consumer goods to industrial<br />
applications. Typical applications include, for example,<br />
furniture, pallets, hand tools, automotive parts, beauty<br />
and lifestyle products, toys and items, such as kitchen<br />
utensils and bottle caps, among other uses.<br />
The DuraSense granules are a combination of<br />
natural wood fibres, polymers and additives offering<br />
the mouldability of plastic with the sustainability and<br />
workability of wood. With DuraSense, it is also possible<br />
to combine fibres with recycled or bio-based polymers<br />
to further enhance environmental values. For example,<br />
DuraSense Eco100, which is one of the product grades<br />
and based on wood fibres and biopolymers, is a costcompetitive<br />
way to fully replace fossil-based plastics.<br />
“Affordable sustainability and the environment are<br />
climbing upwards on consumer agendas,” says Patricia<br />
Oddshammar, Head of Biocomposites at Stora Enso.<br />
“DuraSense can reduce the consumption of plastic<br />
materials by up to 60%, ensuring less microplastics end<br />
up in the environment. Stora Enso’s biocomposites can<br />
be reused as a material up to seven times or or recycled<br />
along with other plastic materials or, alternatively, used for<br />
energy recovery at their end of life.” MT<br />
www.storaenso.com<br />
Join us at the<br />
13th European Bioplastics<br />
Conference<br />
– the leading business forum for the<br />
bioplastics industry.<br />
4/5 December <strong>2018</strong><br />
Titanic Chaussee Hotel<br />
Berlin, Germany<br />
REGISTER<br />
NOW!<br />
EARLY BIRD DISCOUNT<br />
UNTIL 30 JUNE <strong>2018</strong><br />
@EUBioplastics #eubpconf<br />
www.european-bioplastics.org/events<br />
For more information email:<br />
conference@european-bioplastics.org<br />
bioplastics MAGAZINE [03/18] Vol. 13 45
Report<br />
The journey of bioplastics<br />
in the Indian subcontinent<br />
Bioplastics or biopolymers was a word never heard of<br />
on the Indian subcontinent, till a serial entrepreneur<br />
and environmentalist, Perses Bilimoria, founded<br />
Earthsoul India, in the year 2002. bioplastics MAGAZINE spoke<br />
to Perses, when he visited the editorial office in Mönchengladbach<br />
in April <strong>2018</strong>.<br />
“My task was not only challenging, but almost born to die,<br />
as Indians did not have a care in the world, in those days, for<br />
waste disposal systems and had a passionate ongoing love<br />
affair, with synthetic polymers, or plastic.”<br />
In the early days of Earthsoul India, Perses visited one of<br />
the world’s pioneering bioplastic manufacturing companies,<br />
Novamont SRL (Mater-Bi) in Italy and at his first meet with<br />
the CEO, Catia Bastioli, was told that this venture was not<br />
a model for the Indian sub-continent at all, on account of<br />
raw material costing tenfold more than comparable fossilbased<br />
plastic.<br />
However Perses’ commitment, his passion for the<br />
environment and his persistent attitude, encouraged him<br />
over the next sixteen years to educate, tutor and plant<br />
the seed of biopolymers to the members of the Ministry<br />
of Environment and Forests, Central / State Pollution<br />
Control Boards, Central Institute of Plastic Engineering &<br />
Technology (CIPET), Bureau of Indian Standards, various<br />
agricultural institutes, etc., on the merits and sustainability<br />
of this next generation material, an alternative to synthetic<br />
plastics made from fossil fuels resources and hence not<br />
renewable.<br />
“During the past sixteen years, India has witnessed a few<br />
start-ups in the bioplastic products arena,” Perses said,<br />
“and sadly a lot of fake” bioplastic and oxo-degradable<br />
product manufacturers, most of whom have tremendous<br />
political and financial clout in India to misrepresent and fool<br />
uneducated consumers.”<br />
Perses Bilimoria also mentioned that Professor Ramani<br />
Narayan of Michigan State University is one of the pioneering<br />
scientist of bioplastics globally and a company he is involved<br />
with, has its roots in India, but not yet a manufacturing<br />
facility.<br />
In the past years many states in India, today nearly 18<br />
states, have actually banned fossil-based plastics, but<br />
sadly no implementation or policing laws in place, have<br />
made the ban a tool to fight widespread corruption and<br />
misinformation.<br />
“I must however mention that Maharashtra state have<br />
taken a lead in providing a focused vision of implementing<br />
the plastic ban,” Perses said. “Furthermore, the government<br />
of India has an extremely high rate of import duties on the<br />
raw materials imported which makes the products further<br />
unviable in a developing economy.”<br />
Unlike India’s neighbours China and Thailand which<br />
have set up a bioplastics association and research and<br />
development cells, along with various raw material<br />
manufacturing facilities, India is still a laggard, “although<br />
we have all the natural resources to produce the raw<br />
46 bioplastics MAGAZINE [03/18] Vol. 13
Report<br />
By:<br />
Michael Thielen<br />
Jaydeep Mandal (cf. pp.32), Perses Bilomoria, and Michael Thielen<br />
materials for biopolymers. This is extremely unfortunate<br />
and will hopefully change very soon under our current<br />
government’s make in India initiative,” he added<br />
In the year 2010 India adopted the ISO 17088 standard for<br />
compostable biopolymers through its local Bureau of Indian<br />
Standards and this has encouraged a few compostable<br />
product manufacturers to enter the market in 2012.<br />
However, the market was still uneducated and resistant to<br />
the high pricing and availability of local raw materials.<br />
Fast forward to the year 2016 and the Ministry of<br />
Environment and Forests structured a plastic waste<br />
management law, which promoted the use of compostable<br />
bags below 50 µm thickness in all Indian states.<br />
As India is a federal structure this law was viewed with<br />
suspicion and 18 states have implemented it as of yet, a few<br />
with changes in the structure.<br />
Dr. Mohanty of CIPET (Central Institute of Plastics<br />
Engineering & Technology) the only test certification agency<br />
in India for products with ISO 17088, has mentioned that<br />
there is an urgent need for test protocols to be streamlined<br />
with regards to IS/ISO 17088. “It is unbelievable that still<br />
several raw materials with 60 % starch are blended with<br />
polyethylene and sold as compostable products currently,”<br />
Perses said angrily.<br />
Large multinationals like BASF, Cargill, sought entry into<br />
the Indian market with a fair amount of spends on education<br />
and awareness on certified compostable products, but the<br />
price factor still remained a very big problem.<br />
In the year 2017 the Indian Government reduced the<br />
import duties to 15 %, from prevailing 23 % and this saw a<br />
window of opportunity for new entrepreneurs, to query the<br />
pitch.<br />
“As the pioneer of bioplastics in India, my wish would be<br />
to have multiple international raw material manufacturers<br />
set up facilities in India and invest in the infrastructure, to<br />
create a model of self-local sustainability for the long term.”<br />
However, before this is embarked upon the market must<br />
mature and be ready to embrace bioplastics in the fields of<br />
retail, agriculture, medical amongst other industry.<br />
It is also critical to have an implementation and policing<br />
policy for genuine certified compostable products, which<br />
will be key to the success of all the new entrepreneurs in<br />
this industry.<br />
It will be interesting to see one of the fastest growing<br />
economies of the world embrace bioplastics and hopefully<br />
will soon become the fastest growing bioplastics market of<br />
the world.<br />
It is noteworthy to mention the fact that June 5th, <strong>2018</strong> –<br />
World Environment Day will be celebrated in India and the<br />
focus will be Reduction and Elimination of Plastic Waste.<br />
“My dream will then be fulfilled as India’s Bioplastic man,<br />
Perses concluded, still optimistic. www.earthsoulindia.com<br />
(Photo: MichaelThielen)<br />
bioplastics MAGAZINE [03/18] Vol. 13 47
Brand Owner<br />
Save the date<br />
see page 10-11 for details<br />
Brand-Owner’s perspective<br />
on bioplastics and how to<br />
unleash its full potential<br />
PepsiCo continues to invest in research to help drive the development of<br />
bioplastics for use in food packaging. Last year we announced our partnership<br />
with Danimer Scientific. The companies’ agreement builds on a long-standing<br />
relationship including the development of biobased compostable packaging<br />
for PepsiCo’s snack brands and will facilitate the expansion of Danimer<br />
Scientifics’ Nodax PHA plant. Danimer Scientifics’ PHA received the first<br />
ever OK Marine Biodegradable certification from Vinçotte International,<br />
validating that the biopolymer safely biodegrades in salt water environments,<br />
leaving no toxins behind.<br />
Brad Rodgers<br />
R&D Director for Discovery & Sustainability,<br />
PepsiCo Global Foods Packaging<br />
PepsiCo’s packaging goals are to reduce our greenhouse gas<br />
footprint and to design our packaging to be recyclable, compostable or<br />
biodegradable. Snack food packaging represents an opportunity to design a film<br />
for composting along with other organic waste. Utilizing biobased feedstocks<br />
to produce the packaging material can also help us lower our GHG footprint.<br />
Use of the bioplastics under development with Danimer will help us meet both goals.<br />
www.pepsico.com<br />
How about going bio?<br />
For almost every conventional plastic, there is a bioplastic alternative.<br />
Our PLA masterbatches can help introduce PLA into your portfolio.<br />
Make the switch today.<br />
www.sukano.com<br />
48 bioplastics MAGAZINE [03/18] Vol. 13
©<br />
©<br />
-Institut.eu | <strong>2018</strong><br />
-Institut.eu | 2017<br />
Full study available at www.bio-based.eu/reports<br />
Full study available at www.bio-based.eu/reports<br />
©<br />
-Institut.eu | 2017<br />
Full study available at www.bio-based.eu/markets<br />
Bio-based Polymers & Building Blocks<br />
The best market reports available<br />
Automotive<br />
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July 2017<br />
This and other reports on the bio-based economy are available at<br />
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Authors: Lara Dammer, Michael Carus and Dr. Asta Partanen<br />
nova-Institut GmbH, Germany<br />
May 2017<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Author: Jan Ravenstijn, Jan Ravenstijn Consulting, the Netherlands<br />
April 2017<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Policies impacting bio-based<br />
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Asian markets for bio-based chemical<br />
building blocks and polymers<br />
Market study on the consumption<br />
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Share of Asian production capacity on global production by polymer in 2016<br />
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80%<br />
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40%<br />
20%<br />
0%<br />
PBS(X)<br />
APC –<br />
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PA<br />
PET<br />
PTT<br />
PBAT<br />
Starch<br />
Blends<br />
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PE<br />
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bags<br />
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bags<br />
Rigid<br />
packaging<br />
Flexible<br />
packaging<br />
Authors: Dirk Carrez, Clever Consult, Belgium<br />
Jim Philp, OECD, France<br />
Dr. Harald Kaeb, narocon Innovation Consulting, Germany<br />
Lara Dammer & Michael Carus, nova-Institute, Germany<br />
March 2017<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Author: Wolfgang Baltus, Wobalt Expedition Consultancy, Thailand<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Authors: Harald Kaeb (narocon, lead), Florence Aeschelmann,<br />
Lara Dammer, Michael Carus (nova-Institute)<br />
April 2016<br />
The full market study (more than 300 slides, 3,500€) is available at<br />
bio-based.eu/top-downloads.<br />
www.bio-based.eu/reports<br />
bioplastics MAGAZINE [03/18] Vol. 13 49
Automotive<br />
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50 bioplastics MAGAZINE [03/18] Vol. 13<br />
Visit our bookstore for prices and many more books!
Automotive<br />
rials<br />
10<br />
Years ago<br />
tinyurl.com/bm-add-0308<br />
„Green“<br />
packaging for electronic<br />
components<br />
Article contributed by<br />
Thomas Weigl, Managing Director,<br />
Sukano Products Ltd., Schindellegi,<br />
Switzerland<br />
E<br />
www.sukano.com<br />
Transparent antistatic masterbatch for PLA<br />
ven electronic components can be attractively packaged in<br />
compostable plastic - at least they can if Sukano‘s transparent<br />
antistatic PLA (polylactic acid) masterbatch is used.<br />
The highly transparent materials compare well, both technically<br />
and economically, with conventional alternatives, and have the added<br />
advantage of being biodegradable. And to be sure that the product<br />
in the pack is not only presented in an environmentally friendly and<br />
attractive way, but also securely protected, Sukano calls once again<br />
on its experienced research team: SUKANO ® PLA as S546 transparent<br />
antstatic masterbatch significantly reduces the surface electrical<br />
resistance and so prevents the build-up of a static charge on film,<br />
sheet and injection-moulded parts. The packaging attracts less dust<br />
and the risk of damage to any sensitive components by electrical discharge<br />
is extremely small.<br />
On PLA film extruded in the Sukano test laboratory using 4 to<br />
6% (monofilm) and also 5 to 7% (outer layer of laminated film) of<br />
SUKANO ® PLA as S546 and 2% SUKANO ® PLA dc S511 slip/antiblock<br />
masterbatch, a surface resistance of █1011 ohms was measured and<br />
any electrostatic charge was dissipated after a few seconds.<br />
In order that plastics processors can achieve optimum performance<br />
for each application Sukano offers, in addition to the antistatic<br />
masterbatch, a wide range of functional and visually enhancing<br />
masterbatches and compounds. These include the recently launched<br />
and highly successful SUKANO ® PLA im S550 impact modifier, plus<br />
slip/antiblock, UV and color masterbatches, to mention just a few. All<br />
SUKANO ® PLA masterbatches are biodegradable and the majority<br />
of them are approved for food contact. They can also be supplied by<br />
the manufacturer in combination, i.e. as special tailor-made masterbatches<br />
to provide processors with an ideal performance profile.<br />
Published in<br />
bioplastics MAGAZINE<br />
In May <strong>2018</strong>, Daniel Ganz, Global R&D product<br />
leader for Bioplastics masterbatches at<br />
Sukano says:<br />
Sukano is proud to have embarked in the<br />
bioplastic challenging journey already since<br />
2005, and witness the progress over the years<br />
of our bioplastics portfolio. Back 10 years<br />
ago, Sukano was promoting its PLA transparent<br />
impact modifier, and its antistatic masterbatches<br />
for PLA electronics packaging,<br />
launched around the same period, which now<br />
became a reference in the market. Since then,<br />
Sukano´s portfolio has grown significantly<br />
with the market and its demand, from a product range for<br />
any kind of polylactic acid (PLA), as well as polybutene<br />
succinate (PBS) and bio PET.<br />
From these days till today, the company has defined<br />
its bioplastics platform of masterbatches as core and<br />
strategic, established presence and proactive engagement<br />
and collaboration with leading companies in the<br />
bioplastics supply chain for the full PLA and PBS bioplastics<br />
market (cf. p. 18).<br />
This decision has proven to be successful both in<br />
generating industry-leading technical know-how<br />
about bioplastics processing for our technical experts<br />
and dedicated R&D team, resulting in new products<br />
brought to the market.<br />
Companies can now use our masterbatches certain<br />
that the integrity of their claims, certifications<br />
on compostability and biodegradability will be supported<br />
by our products. Just as well as mechanical<br />
and visual properties will be very close to conventional<br />
oil-based plastics allowing manufacturers<br />
to use bio-materials that meet all their processing<br />
requirements and which can be adapted to each<br />
packaging and production practices.<br />
Such as for BOPLA, creating lighter weight<br />
packages with a greater proportion of biobased<br />
content.<br />
Or the launch of new PBS-based masterbatches<br />
for flexible packaging manufacturers<br />
to design new multi-layer packaging structures<br />
– addressing the consumer demand for lower<br />
environmental impact through smart product<br />
design and packaging.<br />
And we are extremely active in this field,<br />
aiming to continue to bring the bioplastics applications<br />
to more diverse markets and processing<br />
conditions.<br />
30 bioplastics MAGAZINE [03/08] Vol. 3<br />
bioplastics MAGAZINE [03/18] Vol. 13 51
Basics<br />
Castor oil<br />
By:<br />
Michael Thielen<br />
Castor oil is the raw material of choice for the production<br />
of biobased sebacic acid. A number of biobased<br />
plastics, for example several partly or fully biobased<br />
polyamides are manufactured using sebacic acid as a monomer<br />
or as a chemical building block. Another monomer<br />
based on castor oil is 11-aminoundecanoic acid.<br />
About the castor plant<br />
The Castor plant (Ricinus communis) is from the family<br />
Euphorbiaceae and grows wild in varied climatic conditions.<br />
It produces seeds that contain up to 50 % wt castor oil.<br />
The oil can easily be extracted from castor seeds and find<br />
its use in a multitude of sectors such as a building block<br />
for bioplastics (mainly biobased polyamides), medicine,<br />
chemicals industry and in other technologies [4].<br />
India is the largest producer of Castor oil in the world.<br />
The expected harvest for <strong>2018</strong> is 1.4 to 1.5 million tonnes<br />
of castor seeds,” as K.S. Najappa, CEO of Planters<br />
International (Indiranagar Bengaluru, Karnataka, India) told<br />
bioplastics MAGAZINE, “which will yield to approximately<br />
700,000 tonnes of Castor oil” [5].<br />
Approximately 86% of the castor seed production in India<br />
is concentrated in Gujarat, followed by Andhra Pradesh<br />
and Rajasthan. Specifically, the regions of Mehsana,<br />
Banaskantha, and Saurashtra/Kutch in Gujarat and the<br />
districts of Nalgonda and Mahboobnagar of Andhra Pradesh<br />
are the major areas of castor oil production in India. The<br />
economic success of castor crops in Gujarat in the 1980s<br />
and thereafter can be attributed to a combination of a<br />
good breeding program, a good extension model, coupled<br />
with access to well-developed national and international<br />
markets [12].<br />
Other countries that produce castor oil include Brazil and<br />
China. China, however, “does not produce enough castor<br />
oil for their own needs,” says Najappa, “so that they import<br />
from India.”<br />
With view to bioplastics, the main derivative product<br />
of castor oil is sebacic acid. The main countries to<br />
produce sebacic acid are again India and China. Najappa:<br />
“Unfortunately India cannot seriously compete with China,<br />
because the Chinese Government gives their manufacturers<br />
a lot of incentives” [5].<br />
The world castor seed production has increased from<br />
1.055 million tons in 2003 to 1.440 million tons in 2013 with<br />
India being the leading producer and accounts for over 75<br />
% of the total production followed by China and Brazil each<br />
accounting for 12.5 and 5.5 % respectively [13]<br />
Throughout the growth season, the castor plant<br />
responds well to temperatures between 20 – 26°C with a<br />
low humidity and grows best in loamy soils with medium<br />
texture. Nonetheless, castor plants are renowned as a low<br />
maintenance crop with the ability to be cultivated especially<br />
on marginal lands and can tolerate various weather<br />
conditions.<br />
Biochemicals from castor oil do not affect food production<br />
or cause any land use change. Castor oil is toxic and thus<br />
not part of food chain, a characteristic that is drawing more<br />
and more attention lately. The castor plants grow on arid to<br />
marginal lands with little or no agrochemicals needed [7].<br />
From castor oil to bioplastic<br />
Castor oil is a vegetable oil extracted from the castor<br />
bean (or better from the castor seed as the castor plant,<br />
Ricinus communis, is not a member of the bean family<br />
Fabaceae; it is a member of the Euphorbiaceae). Castor oil<br />
ranges from colorless to very pale yellow liquid with mild or<br />
no odor or taste. Its boiling point is 313°C and its density is<br />
0.961 kg/cm3 [1].<br />
After the oil extraction, the Castor meal (also known<br />
as Castor cake) is separated and the oil is subsequently<br />
hydrolyzed to a mixture of glycerine and ricinoleic acid in<br />
the refining process.<br />
Ricinoleic acid, a monounsaturated, 18-carbon fatty acid,<br />
is unusual compared to other fatty acids due to its hydroxyl<br />
functional group on the 12th carbon. This functional group<br />
renders ricinoleic acid unusually polar, and also increases<br />
its chemical reactivity, a property that is unique when<br />
compared with most of the others vegetable oils. It is the<br />
hydroxyl group which makes castor oil and ricinoleic acid<br />
susceptible of an easy chemical derivatization, thus a<br />
valuable chemical feedstocks [2].<br />
In a next step the ricinoleic acid is converted into either<br />
undecenoic acid (monomer for PA11) or sebacic acid (one of<br />
the monomers for PA6.10 and PA10.10).<br />
This sebacic acid (or decanedioic acid (the IUPAC<br />
name), or 1,8-octanedicarboxylic acid or C10H18O4<br />
or [HOOC(CH2)8COOH]) is a dicarboxylic acid that can<br />
for example be used as monomer for different types of<br />
polyamides [3]. In the commercially available polyamides<br />
PA 4.10, 5.10 and PA 6.10, the ‘10’-component is based on<br />
this dicarboxylic acid with 10 carbon atoms.<br />
Since the other component (the diamine) in these resins<br />
usually is not made from renewable resources, these partly<br />
biobased polyamides have 63% (PA 6.10) biobased content.<br />
Polyamides 4.10, 5.10, PA 10.10 and PA 10.12 can be<br />
100% biobased as here the diamine can be derived from<br />
renewable resources as well. In the case of PA 10.10 both<br />
monomers (1,10-decamethylene diamine and sebacic acid)<br />
are derived from castor oil [8].<br />
A third example is PA 11. Here a single monomer is being<br />
used. First the ricinoleic acid from the castor oil is converted<br />
into undecanoic acid [H2C=CH-(CH2)-COOH] via a catalytic<br />
reaction (methanolysis). This is then further converted into<br />
11-aminoundecanoic acid in a subsequent catalytically<br />
supported reaction with ammonia [9]. This 100% biobased<br />
polyamide has been discovered and marketed since as far<br />
back as 1947 [3].<br />
Sebacic acid is also found as ingredient in the cosmetic<br />
industry, as thickeners for coatings and lubricants, as<br />
antifreeze for lubricants, as plastizers, stabilizers, anticorrosion<br />
chemicals or other polymers such as polyols and<br />
polyesters and many other uses.<br />
52 bioplastics MAGAZINE [03/18] Vol. 13
Basics<br />
References<br />
[1] Aldrich Handbook of Fine Chemicals and Laboratory Equipment, Sigma-<br />
Aldrich, 2003 (found in Wikipedia)<br />
[2] Wikipedia: http://en.wikipedia.org/wiki/Castor_oil<br />
[3] Basics of Bio-polyamides, bioplastics MAGAZINE, vol 5, issue 03/2010<br />
[4] Ogunniyi DS (2006) Castor oil: a vital industrial raw material. Bioresour<br />
Technol 97:1086–1089<br />
[5] Najappa K.S: personal information May <strong>2018</strong>, Planters International<br />
(Indiranagar Bengaluru, Karnataka, India)<br />
[6] FAOSTAT, 2006-2009, FAO data based on imputation methodology<br />
[7] Wang, M.S., Huang, J.C., 1994, Nylon 1010 properties and applications,<br />
J. Pol. Eng., 13 (2), pp155-174 & New Crop Resource Online Program,<br />
Purdue University, www.hort.purdue.edu/newcrop/default.html<br />
[8] VESTAMID® Terra - Because we care (brochure of Evonik, Marl<br />
Germany), 2012<br />
[9] Endres, H.-J., Siebert-Raths, Engineering Biopolymers, Carl Hanser<br />
Verlag, 2011<br />
[10] www.usitc.gov/publications/701_731/pub3775.pdf<br />
[11] Thielen, M. Castor oil, an important source for bioplastics, bioplastics<br />
MAGAZINE 03/2012 (with the help of Evonik and nova-Institute)<br />
[12] Patel, V.R. et. al.: Castor Oil: Properties, Uses, and Optimization of<br />
Processing Parameters in Commercial Production, Lipid Insights. 2016;<br />
9: 1–12.<br />
[13] Severino L.S. et.al.: Review on the challenges for increased production<br />
of castor. Agron J 104:853–880, (2012)<br />
Castor bean<br />
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The bioplastics industry has been experiencing an<br />
increase in the use of Castor oil for the last few years.<br />
Castor plant<br />
The annual conference of the International Castor oil Association brings<br />
together major participants in the industry to exchange views and discuss<br />
latest news and trends about castor oil.<br />
The next conference will be held June 6-8, <strong>2018</strong> in<br />
Stockholm, Sweden.<br />
Visit the ICOA website for conference details.<br />
www.icoa.org<br />
bioplastics MAGAZINE [03/18] Vol. 13 53
Basics<br />
Glossary 4.2 last update issue 02/2016<br />
In bioplastics MAGAZINE again and again<br />
the same expressions appear that some of our readers<br />
might not (yet) be familiar with. This glossary shall help<br />
with these terms and shall help avoid repeated explanations<br />
such as PLA (Polylactide) in various articles.<br />
Bioplastics (as defined by European Bioplastics<br />
e.V.) is a term used to define two different<br />
kinds of plastics:<br />
a. Plastics based on → renewable resources<br />
(the focus is the origin of the raw material<br />
used). These can be biodegradable or not.<br />
b. → Biodegradable and → compostable<br />
plastics according to EN13432 or similar<br />
standards (the focus is the compostability of<br />
the final product; biodegradable and compostable<br />
plastics can be based on renewable<br />
(biobased) and/or non-renewable (fossil) resources).<br />
Bioplastics may be<br />
- based on renewable resources and biodegradable;<br />
- based on renewable resources but not be<br />
biodegradable; and<br />
- based on fossil resources and biodegradable.<br />
1 st Generation feedstock | Carbohydrate rich<br />
plants such as corn or sugar cane that can<br />
also be used as food or animal feed are called<br />
food crops or 1 st generation feedstock. Bred<br />
my mankind over centuries for highest energy<br />
efficiency, currently, 1 st generation feedstock<br />
is the most efficient feedstock for the production<br />
of bioplastics as it requires the least<br />
amount of land to grow and produce the highest<br />
yields. [bM 04/09]<br />
2 nd Generation feedstock | refers to feedstock<br />
not suitable for food or feed. It can be either<br />
non-food crops (e.g. cellulose) or waste materials<br />
from 1 st generation feedstock (e.g.<br />
waste vegetable oil). [bM 06/11]<br />
3 rd Generation feedstock | This term currently<br />
relates to biomass from algae, which – having<br />
a higher growth yield than 1 st and 2 nd generation<br />
feedstock – were given their own category.<br />
It also relates to bioplastics from waste<br />
streams such as CO 2<br />
or methane [bM 02/16]<br />
Aerobic digestion | Aerobic means in the<br />
presence of oxygen. In →composting, which is<br />
an aerobic process, →microorganisms access<br />
the present oxygen from the surrounding atmosphere.<br />
They metabolize the organic material<br />
to energy, CO 2<br />
, water and cell biomass,<br />
whereby part of the energy of the organic material<br />
is released as heat. [bM 03/07, bM 02/09]<br />
Since this Glossary will not be printed<br />
in each issue you can download a pdf version<br />
from our website (bit.ly/OunBB0)<br />
bioplastics MAGAZINE is grateful to European Bioplastics for the permission to use parts of their Glossary.<br />
Version 4.0 was revised using EuBP’s latest version (Jan 2015).<br />
[*: bM ... refers to more comprehensive article previously published in bioplastics MAGAZINE)<br />
Anaerobic digestion | In anaerobic digestion,<br />
organic matter is degraded by a microbial<br />
population in the absence of oxygen<br />
and producing methane and carbon dioxide<br />
(= →biogas) and a solid residue that can be<br />
composted in a subsequent step without<br />
practically releasing any heat. The biogas can<br />
be treated in a Combined Heat and Power<br />
Plant (CHP), producing electricity and heat, or<br />
can be upgraded to bio-methane [14] [bM 06/09]<br />
Amorphous | non-crystalline, glassy with unordered<br />
lattice<br />
Amylopectin | Polymeric branched starch<br />
molecule with very high molecular weight<br />
(biopolymer, monomer is →Glucose) [bM 05/09]<br />
Amylose | Polymeric non-branched starch<br />
molecule with high molecular weight (biopolymer,<br />
monomer is →Glucose) [bM 05/09]<br />
Biobased | The term biobased describes the<br />
part of a material or product that is stemming<br />
from →biomass. When making a biobasedclaim,<br />
the unit (→biobased carbon content,<br />
→biobased mass content), a percentage and<br />
the measuring method should be clearly stated [1]<br />
Biobased carbon | carbon contained in or<br />
stemming from →biomass. A material or<br />
product made of fossil and →renewable resources<br />
contains fossil and →biobased carbon.<br />
The biobased carbon content is measured via<br />
the 14 C method (radio carbon dating method)<br />
that adheres to the technical specifications as<br />
described in [1,4,5,6].<br />
Biobased labels | The fact that (and to<br />
what percentage) a product or a material is<br />
→biobased can be indicated by respective<br />
labels. Ideally, meaningful labels should be<br />
based on harmonised standards and a corresponding<br />
certification process by independent<br />
third party institutions. For the property<br />
biobased such labels are in place by certifiers<br />
→DIN CERTCO and →Vinçotte who both base<br />
their certifications on the technical specification<br />
as described in [4,5]<br />
A certification and corresponding label depicting<br />
the biobased mass content was developed<br />
by the French Association Chimie du Végétal<br />
[ACDV].<br />
Biobased mass content | describes the<br />
amount of biobased mass contained in a material<br />
or product. This method is complementary<br />
to the 14 C method, and furthermore, takes<br />
other chemical elements besides the biobased<br />
carbon into account, such as oxygen, nitrogen<br />
and hydrogen. A measuring method has<br />
been developed and tested by the Association<br />
Chimie du Végétal (ACDV) [1]<br />
Biobased plastic | A plastic in which constitutional<br />
units are totally or partly from →<br />
biomass [3]. If this claim is used, a percentage<br />
should always be given to which extent<br />
the product/material is → biobased [1]<br />
[bM 01/07, bM 03/10]<br />
Biodegradable Plastics | Biodegradable Plastics<br />
are plastics that are completely assimilated<br />
by the → microorganisms present a defined<br />
environment as food for their energy. The<br />
carbon of the plastic must completely be converted<br />
into CO 2<br />
during the microbial process.<br />
The process of biodegradation depends on<br />
the environmental conditions, which influence<br />
it (e.g. location, temperature, humidity) and<br />
on the material or application itself. Consequently,<br />
the process and its outcome can vary<br />
considerably. Biodegradability is linked to the<br />
structure of the polymer chain; it does not depend<br />
on the origin of the raw materials.<br />
There is currently no single, overarching standard<br />
to back up claims about biodegradability.<br />
One standard for example is ISO or in Europe:<br />
EN 14995 Plastics- Evaluation of compostability<br />
- Test scheme and specifications<br />
[bM 02/06, bM 01/07]<br />
Biogas | → Anaerobic digestion<br />
Biomass | Material of biological origin excluding<br />
material embedded in geological formations<br />
and material transformed to fossilised<br />
material. This includes organic material, e.g.<br />
trees, crops, grasses, tree litter, algae and<br />
waste of biological origin, e.g. manure [1, 2]<br />
Biorefinery | the co-production of a spectrum<br />
of bio-based products (food, feed, materials,<br />
chemicals including monomers or building<br />
blocks for bioplastics) and energy (fuels, power,<br />
heat) from biomass.[bM 02/13]<br />
Blend | Mixture of plastics, polymer alloy of at<br />
least two microscopically dispersed and molecularly<br />
distributed base polymers<br />
Bisphenol-A (BPA) | Monomer used to produce<br />
different polymers. BPA is said to cause<br />
health problems, due to the fact that is behaves<br />
like a hormone. Therefore it is banned<br />
for use in children’s products in many countries.<br />
BPI | Biodegradable Products Institute, a notfor-profit<br />
association. Through their innovative<br />
compostable label program, BPI educates<br />
manufacturers, legislators and consumers<br />
about the importance of scientifically based<br />
standards for compostable materials which<br />
biodegrade in large composting facilities.<br />
Carbon footprint | (CFPs resp. PCFs – Product<br />
Carbon Footprint): Sum of →greenhouse<br />
gas emissions and removals in a product system,<br />
expressed as CO 2<br />
equivalent, and based<br />
on a →life cycle assessment. The CO 2<br />
equivalent<br />
of a specific amount of a greenhouse gas<br />
is calculated as the mass of a given greenhouse<br />
gas multiplied by its →global warmingpotential<br />
[1,2,15]<br />
54 bioplastics MAGAZINE [03/18] Vol. 13
Basics<br />
Carbon neutral, CO 2<br />
neutral | describes a<br />
product or process that has a negligible impact<br />
on total atmospheric CO 2<br />
levels. For<br />
example, carbon neutrality means that any<br />
CO 2<br />
released when a plant decomposes or<br />
is burnt is offset by an equal amount of CO 2<br />
absorbed by the plant through photosynthesis<br />
when it is growing.<br />
Carbon neutrality can also be achieved<br />
through buying sufficient carbon credits to<br />
make up the difference. The latter option is<br />
not allowed when communicating → LCAs<br />
or carbon footprints regarding a material or<br />
product [1, 2].<br />
Carbon-neutral claims are tricky as products<br />
will not in most cases reach carbon neutrality<br />
if their complete life cycle is taken into consideration<br />
(including the end-of life).<br />
If an assessment of a material, however, is<br />
conducted (cradle to gate), carbon neutrality<br />
might be a valid claim in a B2B context. In this<br />
case, the unit assessed in the complete life<br />
cycle has to be clarified [1]<br />
Cascade use | of →renewable resources means<br />
to first use the →biomass to produce biobased<br />
industrial products and afterwards – due to<br />
their favourable energy balance – use them<br />
for energy generation (e.g. from a biobased<br />
plastic product to →biogas production). The<br />
feedstock is used efficiently and value generation<br />
increases decisively.<br />
Catalyst | substance that enables and accelerates<br />
a chemical reaction<br />
Cellophane | Clear film on the basis of →cellulose<br />
[bM 01/10]<br />
Cellulose | Cellulose is the principal component<br />
of cell walls in all higher forms of plant<br />
life, at varying percentages. It is therefore the<br />
most common organic compound and also<br />
the most common polysaccharide (multisugar)<br />
[11]. Cellulose is a polymeric molecule<br />
with very high molecular weight (monomer is<br />
→Glucose), industrial production from wood<br />
or cotton, to manufacture paper, plastics and<br />
fibres [bM 01/10]<br />
Cellulose ester | Cellulose esters occur by<br />
the esterification of cellulose with organic<br />
acids. The most important cellulose esters<br />
from a technical point of view are cellulose<br />
acetate (CA with acetic acid), cellulose propionate<br />
(CP with propionic acid) and cellulose<br />
butyrate (CB with butanoic acid). Mixed polymerisates,<br />
such as cellulose acetate propionate<br />
(CAP) can also be formed. One of the most<br />
well-known applications of cellulose aceto<br />
butyrate (CAB) is the moulded handle on the<br />
Swiss army knife [11]<br />
Cellulose acetate CA | → Cellulose ester<br />
CEN | Comité Européen de Normalisation<br />
(European organisation for standardization)<br />
Certification | is a process in which materials/products<br />
undergo a string of (laboratory)<br />
tests in order to verify that the fulfil certain<br />
requirements. Sound certification systems<br />
should be based on (ideally harmonised) European<br />
standards or technical specifications<br />
(e.g. by →CEN, USDA, ASTM, etc.) and be<br />
performed by independent third party laboratories.<br />
Successful certification guarantees<br />
a high product safety - also on this basis interconnected<br />
labels can be awarded that help<br />
the consumer to make an informed decision.<br />
Compost | A soil conditioning material of decomposing<br />
organic matter which provides nutrients<br />
and enhances soil structure.<br />
[bM 06/08, 02/09]<br />
Compostable Plastics | Plastics that are<br />
→ biodegradable under →composting conditions:<br />
specified humidity, temperature,<br />
→ microorganisms and timeframe. In order<br />
to make accurate and specific claims about<br />
compostability, the location (home, → industrial)<br />
and timeframe need to be specified [1].<br />
Several national and international standards<br />
exist for clearer definitions, for example EN<br />
14995 Plastics - Evaluation of compostability -<br />
Test scheme and specifications. [bM 02/06, bM 01/07]<br />
Composting | is the controlled →aerobic, or<br />
oxygen-requiring, decomposition of organic<br />
materials by →microorganisms, under controlled<br />
conditions. It reduces the volume and<br />
mass of the raw materials while transforming<br />
them into CO 2<br />
, water and a valuable soil conditioner<br />
– compost.<br />
When talking about composting of bioplastics,<br />
foremost →industrial composting in a<br />
managed composting facility is meant (criteria<br />
defined in EN 13432).<br />
The main difference between industrial and<br />
home composting is, that in industrial composting<br />
facilities temperatures are much<br />
higher and kept stable, whereas in the composting<br />
pile temperatures are usually lower,<br />
and less constant as depending on factors<br />
such as weather conditions. Home composting<br />
is a way slower-paced process than<br />
industrial composting. Also a comparatively<br />
smaller volume of waste is involved. [bM 03/07]<br />
Compound | plastic mixture from different<br />
raw materials (polymer and additives) [bM 04/10)<br />
Copolymer | Plastic composed of different<br />
monomers.<br />
Cradle-to-Gate | Describes the system<br />
boundaries of an environmental →Life Cycle<br />
Assessment (LCA) which covers all activities<br />
from the cradle (i.e., the extraction of raw materials,<br />
agricultural activities and forestry) up<br />
to the factory gate<br />
Cradle-to-Cradle | (sometimes abbreviated<br />
as C2C): Is an expression which communicates<br />
the concept of a closed-cycle economy,<br />
in which waste is used as raw material<br />
(‘waste equals food’). Cradle-to-Cradle is not<br />
a term that is typically used in →LCA studies.<br />
Cradle-to-Grave | Describes the system<br />
boundaries of a full →Life Cycle Assessment<br />
from manufacture (cradle) to use phase and<br />
disposal phase (grave).<br />
Crystalline | Plastic with regularly arranged<br />
molecules in a lattice structure<br />
Density | Quotient from mass and volume of<br />
a material, also referred to as specific weight<br />
DIN | Deutsches Institut für Normung (German<br />
organisation for standardization)<br />
DIN-CERTCO | independant certifying organisation<br />
for the assessment on the conformity<br />
of bioplastics<br />
Dispersing | fine distribution of non-miscible<br />
liquids into a homogeneous, stable mixture<br />
Drop-In bioplastics | chemically indentical<br />
to conventional petroleum based plastics,<br />
but made from renewable resources. Examples<br />
are bio-PE made from bio-ethanol (from<br />
e.g. sugar cane) or partly biobased PET; the<br />
monoethylene glykol made from bio-ethanol<br />
(from e.g. sugar cane). Developments to<br />
make terephthalic acid from renewable resources<br />
are under way. Other examples are<br />
polyamides (partly biobased e.g. PA 4.10 or PA<br />
6.10 or fully biobased like PA 5.10 or PA10.10)<br />
EN 13432 | European standard for the assessment<br />
of the → compostability of plastic<br />
packaging products<br />
Energy recovery | recovery and exploitation<br />
of the energy potential in (plastic) waste for<br />
the production of electricity or heat in waste<br />
incineration pants (waste-to-energy)<br />
Environmental claim | A statement, symbol<br />
or graphic that indicates one or more environmental<br />
aspect(s) of a product, a component,<br />
packaging or a service. [16]<br />
Enzymes | proteins that catalyze chemical<br />
reactions<br />
Enzyme-mediated plastics | are no →bioplastics.<br />
Instead, a conventional non-biodegradable<br />
plastic (e.g. fossil-based PE) is enriched<br />
with small amounts of an organic additive.<br />
Microorganisms are supposed to consume<br />
these additives and the degradation process<br />
should then expand to the non-biodegradable<br />
PE and thus make the material degrade. After<br />
some time the plastic is supposed to visually<br />
disappear and to be completely converted to<br />
carbon dioxide and water. This is a theoretical<br />
concept which has not been backed up by<br />
any verifiable proof so far. Producers promote<br />
enzyme-mediated plastics as a solution to littering.<br />
As no proof for the degradation process<br />
has been provided, environmental beneficial<br />
effects are highly questionable.<br />
Ethylene | colour- and odourless gas, made<br />
e.g. from, Naphtha (petroleum) by cracking or<br />
from bio-ethanol by dehydration, monomer of<br />
the polymer polyethylene (PE)<br />
European Bioplastics e.V. | The industry association<br />
representing the interests of Europe’s<br />
thriving bioplastics’ industry. Founded<br />
in Germany in 1993 as IBAW, European<br />
Bioplastics today represents the interests<br />
of about 50 member companies throughout<br />
the European Union and worldwide. With<br />
members from the agricultural feedstock,<br />
chemical and plastics industries, as well as<br />
industrial users and recycling companies, European<br />
Bioplastics serves as both a contact<br />
platform and catalyst for advancing the aims<br />
of the growing bioplastics industry.<br />
Extrusion | process used to create plastic<br />
profiles (or sheet) of a fixed cross-section<br />
consisting of mixing, melting, homogenising<br />
and shaping of the plastic.<br />
FDCA | 2,5-furandicarboxylic acid, an intermediate<br />
chemical produced from 5-HMF.<br />
The dicarboxylic acid can be used to make →<br />
PEF = polyethylene furanoate, a polyester that<br />
could be a 100% biobased alternative to PET.<br />
Fermentation | Biochemical reactions controlled<br />
by → microorganisms or → enyzmes (e.g.<br />
the transformation of sugar into lactic acid).<br />
FSC | Forest Stewardship Council. FSC is an<br />
independent, non-governmental, not-forprofit<br />
organization established to promote the<br />
responsible and sustainable management of<br />
the world’s forests.<br />
bioplastics MAGAZINE [03/18] Vol. 13 55
Basics<br />
Gelatine | Translucent brittle solid substance,<br />
colorless or slightly yellow, nearly tasteless<br />
and odorless, extracted from the collagen inside<br />
animals‘ connective tissue.<br />
Genetically modified organism (GMO) | Organisms,<br />
such as plants and animals, whose<br />
genetic material (DNA) has been altered<br />
are called genetically modified organisms<br />
(GMOs). Food and feed which contain or<br />
consist of such GMOs, or are produced from<br />
GMOs, are called genetically modified (GM)<br />
food or feed [1]. If GM crops are used in bioplastics<br />
production, the multiple-stage processing<br />
and the high heat used to create the<br />
polymer removes all traces of genetic material.<br />
This means that the final bioplastics product<br />
contains no genetic traces. The resulting<br />
bioplastics is therefore well suited to use in<br />
food packaging as it contains no genetically<br />
modified material and cannot interact with<br />
the contents.<br />
Global Warming | Global warming is the rise<br />
in the average temperature of Earth’s atmosphere<br />
and oceans since the late 19th century<br />
and its projected continuation [8]. Global<br />
warming is said to be accelerated by → green<br />
house gases.<br />
Glucose | Monosaccharide (or simple sugar).<br />
G. is the most important carbohydrate (sugar)<br />
in biology. G. is formed by photosynthesis or<br />
hydrolyse of many carbohydrates e. g. starch.<br />
Greenhouse gas GHG | Gaseous constituent<br />
of the atmosphere, both natural and anthropogenic,<br />
that absorbs and emits radiation at<br />
specific wavelengths within the spectrum of<br />
infrared radiation emitted by the earth’s surface,<br />
the atmosphere, and clouds [1, 9]<br />
Greenwashing | The act of misleading consumers<br />
regarding the environmental practices<br />
of a company, or the environmental benefits<br />
of a product or service [1, 10]<br />
Granulate, granules | small plastic particles<br />
(3-4 millimetres), a form in which plastic is<br />
sold and fed into machines, easy to handle<br />
and dose.<br />
HMF (5-HMF) | 5-hydroxymethylfurfural is an<br />
organic compound derived from sugar dehydration.<br />
It is a platform chemical, a building<br />
block for 20 performance polymers and over<br />
175 different chemical substances. The molecule<br />
consists of a furan ring which contains<br />
both aldehyde and alcohol functional groups.<br />
5-HMF has applications in many different<br />
industries such as bioplastics, packaging,<br />
pharmaceuticals, adhesives and chemicals.<br />
One of the most promising routes is 2,5<br />
furandicarboxylic acid (FDCA), produced as an<br />
intermediate when 5-HMF is oxidised. FDCA<br />
is used to produce PEF, which can substitute<br />
terephthalic acid in polyester, especially polyethylene<br />
terephthalate (PET). [bM 03/14, 02/16]<br />
Home composting | →composting [bM 06/08]<br />
Humus | In agriculture, humus is often used<br />
simply to mean mature →compost, or natural<br />
compost extracted from a forest or other<br />
spontaneous source for use to amend soil.<br />
Hydrophilic | Property: water-friendly, soluble<br />
in water or other polar solvents (e.g. used<br />
in conjunction with a plastic which is not water<br />
resistant and weather proof or that absorbs<br />
water such as Polyamide (PA).<br />
Hydrophobic | Property: water-resistant, not<br />
soluble in water (e.g. a plastic which is water<br />
resistant and weather proof, or that does not<br />
absorb any water such as Polyethylene (PE)<br />
or Polypropylene (PP).<br />
Industrial composting | is an established<br />
process with commonly agreed upon requirements<br />
(e.g. temperature, timeframe) for transforming<br />
biodegradable waste into stable, sanitised<br />
products to be used in agriculture. The<br />
criteria for industrial compostability of packaging<br />
have been defined in the EN 13432. Materials<br />
and products complying with this standard<br />
can be certified and subsequently labelled<br />
accordingly [1,7] [bM 06/08, 02/09]<br />
ISO | International Organization for Standardization<br />
JBPA | Japan Bioplastics Association<br />
Land use | The surface required to grow sufficient<br />
feedstock (land use) for today’s bioplastic<br />
production is less than 0.01 percent of the<br />
global agricultural area of 5 billion hectares.<br />
It is not yet foreseeable to what extent an increased<br />
use of food residues, non-food crops<br />
or cellulosic biomass (see also →1 st /2 nd /3 rd<br />
generation feedstock) in bioplastics production<br />
might lead to an even further reduced<br />
land use in the future [bM 04/09, 01/14]<br />
LCA | is the compilation and evaluation of the<br />
input, output and the potential environmental<br />
impact of a product system throughout its life<br />
cycle [17]. It is sometimes also referred to as<br />
life cycle analysis, ecobalance or cradle-tograve<br />
analysis. [bM 01/09]<br />
Littering | is the (illegal) act of leaving waste<br />
such as cigarette butts, paper, tins, bottles,<br />
cups, plates, cutlery or bags lying in an open<br />
or public place.<br />
Marine litter | Following the European Commission’s<br />
definition, “marine litter consists of<br />
items that have been deliberately discarded,<br />
unintentionally lost, or transported by winds<br />
and rivers, into the sea and on beaches. It<br />
mainly consists of plastics, wood, metals,<br />
glass, rubber, clothing and paper”. Marine<br />
debris originates from a variety of sources.<br />
Shipping and fishing activities are the predominant<br />
sea-based, ineffectively managed<br />
landfills as well as public littering the main<br />
land-based sources. Marine litter can pose a<br />
threat to living organisms, especially due to<br />
ingestion or entanglement.<br />
Currently, there is no international standard<br />
available, which appropriately describes the<br />
biodegradation of plastics in the marine environment.<br />
However, a number of standardisation<br />
projects are in progress at ISO and ASTM<br />
level. Furthermore, the European project<br />
OPEN BIO addresses the marine biodegradation<br />
of biobased products.[bM 02/16]<br />
Mass balance | describes the relationship between<br />
input and output of a specific substance<br />
within a system in which the output from the<br />
system cannot exceed the input into the system.<br />
First attempts were made by plastic raw material<br />
producers to claim their products renewable<br />
(plastics) based on a certain input<br />
of biomass in a huge and complex chemical<br />
plant, then mathematically allocating this<br />
biomass input to the produced plastic.<br />
These approaches are at least controversially<br />
disputed [bM 04/14, 05/14, 01/15]<br />
Microorganism | Living organisms of microscopic<br />
size, such as bacteria, funghi or yeast.<br />
Molecule | group of at least two atoms held<br />
together by covalent chemical bonds.<br />
Monomer | molecules that are linked by polymerization<br />
to form chains of molecules and<br />
then plastics<br />
Mulch film | Foil to cover bottom of farmland<br />
Organic recycling | means the treatment of<br />
separately collected organic waste by anaerobic<br />
digestion and/or composting.<br />
Oxo-degradable / Oxo-fragmentable | materials<br />
and products that do not biodegrade!<br />
The underlying technology of oxo-degradability<br />
or oxo-fragmentation is based on special additives,<br />
which, if incorporated into standard<br />
resins, are purported to accelerate the fragmentation<br />
of products made thereof. Oxodegradable<br />
or oxo-fragmentable materials do<br />
not meet accepted industry standards on compostability<br />
such as EN 13432. [bM 01/09, 05/09]<br />
PBAT | Polybutylene adipate terephthalate, is<br />
an aliphatic-aromatic copolyester that has the<br />
properties of conventional polyethylene but is<br />
fully biodegradable under industrial composting.<br />
PBAT is made from fossil petroleum with<br />
first attempts being made to produce it partly<br />
from renewable resources [bM 06/09]<br />
PBS | Polybutylene succinate, a 100% biodegradable<br />
polymer, made from (e.g. bio-BDO)<br />
and succinic acid, which can also be produced<br />
biobased [bM 03/12].<br />
PC | Polycarbonate, thermoplastic polyester,<br />
petroleum based and not degradable, used<br />
for e.g. baby bottles or CDs. Criticized for its<br />
BPA (→ Bisphenol-A) content.<br />
PCL | Polycaprolactone, a synthetic (fossil<br />
based), biodegradable bioplastic, e.g. used as<br />
a blend component.<br />
PE | Polyethylene, thermoplastic polymerised<br />
from ethylene. Can be made from renewable<br />
resources (sugar cane via bio-ethanol) [bM 05/10]<br />
PEF | polyethylene furanoate, a polyester<br />
made from monoethylene glycol (MEG) and<br />
→FDCA (2,5-furandicarboxylic acid , an intermediate<br />
chemical produced from 5-HMF). It<br />
can be a 100% biobased alternative for PET.<br />
PEF also has improved product characteristics,<br />
such as better structural strength and<br />
improved barrier behaviour, which will allow<br />
for the use of PEF bottles in additional applications.<br />
[bM 03/11, 04/12]<br />
PET | Polyethylenterephthalate, transparent<br />
polyester used for bottles and film. The<br />
polyester is made from monoethylene glycol<br />
(MEG), that can be renewably sourced from<br />
bio-ethanol (sugar cane) and (until now fossil)<br />
terephthalic acid [bM 04/14]<br />
PGA | Polyglycolic acid or Polyglycolide is a biodegradable,<br />
thermoplastic polymer and the<br />
simplest linear, aliphatic polyester. Besides<br />
ist use in the biomedical field, PGA has been<br />
introduced as a barrier resin [bM 03/09]<br />
PHA | Polyhydroxyalkanoates (PHA) or the<br />
polyhydroxy fatty acids, are a family of biodegradable<br />
polyesters. As in many mammals,<br />
including humans, that hold energy reserves<br />
in the form of body fat there are also bacteria<br />
that hold intracellular reserves in for of<br />
of polyhydroxy alkanoates. Here the microorganisms<br />
store a particularly high level of<br />
56 bioplastics MAGAZINE [03/18] Vol. 13
Basics<br />
energy reserves (up to 80% of their own body<br />
weight) for when their sources of nutrition become<br />
scarce. By farming this type of bacteria,<br />
and feeding them on sugar or starch (mostly<br />
from maize), or at times on plant oils or other<br />
nutrients rich in carbonates, it is possible to<br />
obtain PHA‘s on an industrial scale [11]. The<br />
most common types of PHA are PHB (Polyhydroxybutyrate,<br />
PHBV and PHBH. Depending<br />
on the bacteria and their food, PHAs with<br />
different mechanical properties, from rubbery<br />
soft trough stiff and hard as ABS, can be produced.<br />
Some PHSs are even biodegradable in<br />
soil or in a marine environment<br />
PLA | Polylactide or Polylactic Acid (PLA), a<br />
biodegradable, thermoplastic, linear aliphatic<br />
polyester based on lactic acid, a natural acid,<br />
is mainly produced by fermentation of sugar<br />
or starch with the help of micro-organisms.<br />
Lactic acid comes in two isomer forms, i.e. as<br />
laevorotatory D(-)lactic acid and as dextrorotary<br />
L(+)lactic acid.<br />
Modified PLA types can be produced by the<br />
use of the right additives or by certain combinations<br />
of L- and D- lactides (stereocomplexing),<br />
which then have the required rigidity for<br />
use at higher temperatures [13] [bM 01/09, 01/12]<br />
Plastics | Materials with large molecular<br />
chains of natural or fossil raw materials, produced<br />
by chemical or biochemical reactions.<br />
PPC | Polypropylene Carbonate, a bioplastic<br />
made by copolymerizing CO 2<br />
with propylene<br />
oxide (PO) [bM 04/12]<br />
PTT | Polytrimethylterephthalate (PTT), partially<br />
biobased polyester, is similarly to PET<br />
produced using terephthalic acid or dimethyl<br />
terephthalate and a diol. In this case it is a<br />
biobased 1,3 propanediol, also known as bio-<br />
PDO [bM 01/13]<br />
Renewable Resources | agricultural raw materials,<br />
which are not used as food or feed,<br />
but as raw material for industrial products<br />
or to generate energy. The use of renewable<br />
resources by industry saves fossil resources<br />
and reduces the amount of → greenhouse gas<br />
emissions. Biobased plastics are predominantly<br />
made of annual crops such as corn,<br />
cereals and sugar beets or perennial cultures<br />
such as cassava and sugar cane.<br />
Resource efficiency | Use of limited natural<br />
resources in a sustainable way while minimising<br />
impacts on the environment. A resource<br />
efficient economy creates more output<br />
or value with lesser input.<br />
Seedling Logo | The compostability label or<br />
logo Seedling is connected to the standard<br />
EN 13432/EN 14995 and a certification process<br />
managed by the independent institutions<br />
→DIN CERTCO and → Vinçotte. Bioplastics<br />
products carrying the Seedling fulfil the<br />
criteria laid down in the EN 13432 regarding<br />
industrial compostability. [bM 01/06, 02/10]<br />
Saccharins or carbohydrates | Saccharins or<br />
carbohydrates are name for the sugar-family.<br />
Saccharins are monomer or polymer sugar<br />
units. For example, there are known mono-,<br />
di- and polysaccharose. → glucose is a monosaccarin.<br />
They are important for the diet and<br />
produced biology in plants.<br />
Semi-finished products | plastic in form of<br />
sheet, film, rods or the like to be further processed<br />
into finshed products<br />
Sorbitol | Sugar alcohol, obtained by reduction<br />
of glucose changing the aldehyde group<br />
to an additional hydroxyl group. S. is used as<br />
a plasticiser for bioplastics based on starch.<br />
Starch | Natural polymer (carbohydrate)<br />
consisting of → amylose and → amylopectin,<br />
gained from maize, potatoes, wheat, tapioca<br />
etc. When glucose is connected to polymerchains<br />
in definite way the result (product) is<br />
called starch. Each molecule is based on 300<br />
-12000-glucose units. Depending on the connection,<br />
there are two types → amylose and →<br />
amylopectin known. [bM 05/09]<br />
Starch derivatives | Starch derivatives are<br />
based on the chemical structure of → starch.<br />
The chemical structure can be changed by<br />
introducing new functional groups without<br />
changing the → starch polymer. The product<br />
has different chemical qualities. Mostly the<br />
hydrophilic character is not the same.<br />
Starch-ester | One characteristic of every<br />
starch-chain is a free hydroxyl group. When<br />
every hydroxyl group is connected with an<br />
acid one product is starch-ester with different<br />
chemical properties.<br />
Starch propionate and starch butyrate |<br />
Starch propionate and starch butyrate can be<br />
synthesised by treating the → starch with propane<br />
or butanic acid. The product structure<br />
is still based on → starch. Every based → glucose<br />
fragment is connected with a propionate<br />
or butyrate ester group. The product is more<br />
hydrophobic than → starch.<br />
Sustainable | An attempt to provide the best<br />
outcomes for the human and natural environments<br />
both now and into the indefinite future.<br />
One famous definition of sustainability is the<br />
one created by the Brundtland Commission,<br />
led by the former Norwegian Prime Minister<br />
G. H. Brundtland. The Brundtland Commission<br />
defined sustainable development as<br />
development that ‘meets the needs of the<br />
present without compromising the ability of<br />
future generations to meet their own needs.’<br />
Sustainability relates to the continuity of economic,<br />
social, institutional and environmental<br />
aspects of human society, as well as the nonhuman<br />
environment).<br />
Sustainable sourcing | of renewable feedstock<br />
for biobased plastics is a prerequisite<br />
for more sustainable products. Impacts such<br />
as the deforestation of protected habitats<br />
or social and environmental damage arising<br />
from poor agricultural practices must<br />
be avoided. Corresponding certification<br />
schemes, such as ISCC PLUS, WLC or Bon-<br />
Sucro, are an appropriate tool to ensure the<br />
sustainable sourcing of biomass for all applications<br />
around the globe.<br />
Sustainability | as defined by European Bioplastics,<br />
has three dimensions: economic, social<br />
and environmental. This has been known<br />
as “the triple bottom line of sustainability”.<br />
This means that sustainable development involves<br />
the simultaneous pursuit of economic<br />
prosperity, environmental protection and social<br />
equity. In other words, businesses have<br />
to expand their responsibility to include these<br />
environmental and social dimensions. Sustainability<br />
is about making products useful to<br />
markets and, at the same time, having societal<br />
benefits and lower environmental impact<br />
than the alternatives currently available. It also<br />
implies a commitment to continuous improvement<br />
that should result in a further reduction<br />
of the environmental footprint of today’s products,<br />
processes and raw materials used.<br />
Thermoplastics | Plastics which soften or<br />
melt when heated and solidify when cooled<br />
(solid at room temperature).<br />
Thermoplastic Starch | (TPS) → starch that<br />
was modified (cooked, complexed) to make it<br />
a plastic resin<br />
Thermoset | Plastics (resins) which do not<br />
soften or melt when heated. Examples are<br />
epoxy resins or unsaturated polyester resins.<br />
Vinçotte | independant certifying organisation<br />
for the assessment on the conformity of bioplastics<br />
WPC | Wood Plastic Composite. Composite<br />
materials made of wood fiber/flour and plastics<br />
(mostly polypropylene).<br />
Yard Waste | Grass clippings, leaves, trimmings,<br />
garden residue.<br />
References:<br />
[1] Environmental Communication Guide,<br />
European Bioplastics, Berlin, Germany,<br />
2012<br />
[2] ISO 14067. Carbon footprint of products -<br />
Requirements and guidelines for quantification<br />
and communication<br />
[3] CEN TR 15932, Plastics - Recommendation<br />
for terminology and characterisation<br />
of biopolymers and bioplastics, 2010<br />
[4] CEN/TS 16137, Plastics - Determination<br />
of bio-based carbon content, 2011<br />
[5] ASTM D6866, Standard Test Methods for<br />
Determining the Biobased Content of<br />
Solid, Liquid, and Gaseous Samples Using<br />
Radiocarbon Analysis<br />
[6] SPI: Understanding Biobased Carbon<br />
Content, 2012<br />
[7] EN 13432, Requirements for packaging<br />
recoverable through composting and biodegradation.<br />
Test scheme and evaluation<br />
criteria for the final acceptance of packaging,<br />
2000<br />
[8] Wikipedia<br />
[9] ISO 14064 Greenhouse gases -- Part 1:<br />
Specification with guidance..., 2006<br />
[10] Terrachoice, 2010, www.terrachoice.com<br />
[11] Thielen, M.: Bioplastics: Basics. Applications.<br />
Markets, Polymedia Publisher,<br />
2012<br />
[12] Lörcks, J.: Biokunststoffe, Broschüre der<br />
FNR, 2005<br />
[13] de Vos, S.: Improving heat-resistance of<br />
PLA using poly(D-lactide),<br />
bioplastics MAGAZINE, Vol. 3, <strong>Issue</strong> 02/2008<br />
[14] de Wilde, B.: Anaerobic Digestion, bioplastics<br />
MAGAZINE, Vol 4., <strong>Issue</strong> 06/2009<br />
[15] ISO 14067 onb Corbon Footprint of<br />
Products<br />
[16] ISO 14021 on Self-declared Environmental<br />
claims<br />
[17] ISO 14044 on Life Cycle Assessment<br />
bioplastics MAGAZINE [03/18] Vol. 13 57
Suppliers Guide<br />
1. Raw Materials<br />
Simply contact:<br />
Tel.: +49 2161 6884467<br />
suppguide@bioplasticsmagazine.com<br />
Stay permanently listed in the<br />
Suppliers Guide with your company<br />
logo and contact information.<br />
For only 6,– EUR per mm, per issue you<br />
can be present among top suppliers in<br />
the field of bioplastics.<br />
For Example:<br />
AGRANA Starch<br />
Bioplastics<br />
Conrathstraße 7<br />
A-3950 Gmuend, Austria<br />
bioplastics.starch@agrana.com<br />
www.agrana.com<br />
BASF SE<br />
Ludwigshafen, Germany<br />
Tel: +49 621 60-9995<br />
martin.bussmann@basf.com<br />
www.ecovio.com<br />
PTT MCC Biochem Co., Ltd.<br />
info@pttmcc.com / www.pttmcc.com<br />
Tel: +66(0) 2 140-3563<br />
MCPP Germany GmbH<br />
+49 (0) 152-018 920 51<br />
frank.steinbrecher@mcpp-europe.com<br />
MCPP France SAS<br />
+33 (0) 6 07 22 25 32<br />
fabien.resweber@mcpp-europe.com<br />
Jincheng, Lin‘an, Hangzhou,<br />
Zhejiang 311300, P.R. China<br />
China contact: Grace Jin<br />
mobile: 0086 135 7578 9843<br />
Grace@xinfupharm.comEurope<br />
contact(Belgium): Susan Zhang<br />
mobile: 0032 478 991619<br />
zxh0612@hotmail.com<br />
www.xinfupharm.com<br />
1.1 bio based monomers<br />
1.2 compounds<br />
Cardia Bioplastics<br />
Suite 6, 205-211 Forster Rd<br />
Mt. Waverley, VIC, 3149 Australia<br />
Tel. +61 3 85666800<br />
info@cardiabioplastics.com<br />
www.cardiabioplastics.com<br />
API S.p.A.<br />
Via Dante Alighieri, 27<br />
36065 Mussolente (VI), Italy<br />
Telephone +39 0424 579711<br />
www.apiplastic.com<br />
www.apinatbio.com<br />
FKuR Kunststoff GmbH<br />
Siemensring 79<br />
D - 47 877 Willich<br />
Tel. +49 2154 9251-0<br />
Tel.: +49 2154 9251-51<br />
sales@fkur.com<br />
www.fkur.com<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
Green Dot Bioplastics<br />
226 Broadway | PO Box #142<br />
Cottonwood Falls, KS 66845, USA<br />
Tel.: +1 620-273-8919<br />
info@greendotholdings.com<br />
www.greendotpure.com<br />
39 mm<br />
Polymedia Publisher GmbH<br />
Dammer Str. 112<br />
41066 Mönchengladbach<br />
Germany<br />
Tel. +49 2161 664864<br />
Fax +49 2161 631045<br />
info@bioplasticsmagazine.com<br />
www.bioplasticsmagazine.com<br />
Sample Charge:<br />
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Sample Charge for one year:<br />
6 issues x 234,00 EUR = 1,404.00 €<br />
The entry in our Suppliers Guide is<br />
bookable for one year (6 issues) and<br />
extends automatically if it’s not canceled<br />
three month before expiry.<br />
www.facebook.com<br />
www.issuu.com<br />
www.twitter.com<br />
www.youtube.com<br />
Microtec Srl<br />
Via Po’, 53/55<br />
30030, Mellaredo di Pianiga (VE),<br />
Italy<br />
Tel.: +39 041 5190621<br />
Fax.: +39 041 5194765<br />
info@microtecsrl.com<br />
www.biocomp.it<br />
Tel: +86 351-8689356<br />
Fax: +86 351-8689718<br />
www.jinhuizhaolong.com<br />
ecoworldsales@jinhuigroup.com<br />
Xinjiang Blue Ridge Tunhe<br />
Polyester Co., Ltd.<br />
No. 316, South Beijing Rd. Changji,<br />
Xinjiang, 831100, P.R.China<br />
Tel.: +86 994 2716865<br />
Mob: +86 18699400676<br />
maxirong@lanshantunhe.com<br />
http://www.lanshantunhe.com<br />
PBAT & PBS resin supplier<br />
BIO-FED<br />
Branch of AKRO-PLASTIC GmbH<br />
BioCampus Cologne<br />
Nattermannallee 1<br />
50829 Cologne, Germany<br />
Tel.: +49 221 88 88 94-00<br />
info@bio-fed.com<br />
www.bio-fed.com<br />
Global Biopolymers Co.,Ltd.<br />
Bioplastics compounds<br />
(PLA+starch;PLA+rubber)<br />
194 Lardproa80 yak 14<br />
Wangthonglang, Bangkok<br />
Thailand 10310<br />
info@globalbiopolymers.com<br />
www.globalbiopolymers.com<br />
Tel +66 81 9150446<br />
Kingfa Sci. & Tech. Co., Ltd.<br />
No.33 Kefeng Rd, Sc. City, Guangzhou<br />
Hi-Tech Ind. Development Zone,<br />
Guangdong, P.R. China. 510663<br />
Tel: +86 (0)20 6622 1696<br />
info@ecopond.com.cn<br />
www.kingfa.com<br />
NUREL Engineering Polymers<br />
Ctra. Barcelona, km 329<br />
50016 Zaragoza, Spain<br />
Tel: +34 976 465 579<br />
inzea@samca.com<br />
www.inzea-biopolymers.com<br />
Sukano AG<br />
Chaltenbodenstraße 23<br />
CH-8834 Schindellegi<br />
Tel. +41 44 787 57 77<br />
Fax +41 44 787 57 78<br />
www.sukano.com<br />
Natureplast – Biopolynov<br />
11 rue François Arago<br />
14123 IFS<br />
Tel: +33 (0)2 31 83 50 87<br />
www.natureplast.eu<br />
58 bioplastics MAGAZINE [03/18] Vol. 13
Suppliers Guide<br />
TECNARO GmbH<br />
Bustadt 40<br />
D-74360 Ilsfeld. Germany<br />
Tel: +49 (0)7062/97687-0<br />
www.tecnaro.de<br />
1.3 PLA<br />
Kaneka Belgium N.V.<br />
Nijverheidsstraat 16<br />
2260 Westerlo-Oevel, Belgium<br />
Tel: +32 (0)14 25 78 36<br />
Fax: +32 (0)14 25 78 81<br />
info.biopolymer@kaneka.be<br />
TIPA-Corp. Ltd<br />
Hanagar 3 Hod<br />
Hasharon 4501306, ISRAEL<br />
P.O BOX 7132<br />
Tel: +972-9-779-6000<br />
Fax: +972 -9-7715828<br />
www.tipa-corp.com<br />
Natur-Tec ® - Northern Technologies<br />
4201 Woodland Road<br />
Circle Pines, MN 55014 USA<br />
Tel. +1 763.404.8700<br />
Fax +1 763.225.6645<br />
info@natur-tec.com<br />
www.natur-tec.com<br />
Total Corbion PLA bv<br />
Arkelsedijk 46, P.O. Box 21<br />
4200 AA Gorinchem<br />
The Netherlands<br />
Tel.: +31 183 695 695<br />
Fax.: +31 183 695 604<br />
www.total-corbion.com<br />
pla@total-corbion.com<br />
TianAn Biopolymer<br />
No. 68 Dagang 6th Rd,<br />
Beilun, Ningbo, China, 315800<br />
Tel. +86-57 48 68 62 50 2<br />
Fax +86-57 48 68 77 98 0<br />
enquiry@tianan-enmat.com<br />
www.tianan-enmat.com<br />
1.6 masterbatches<br />
4. Bioplastics products<br />
Bio-on S.p.A.<br />
Via Santa Margherita al Colle 10/3<br />
40136 Bologna - ITALY<br />
Tel.: +39 051 392336<br />
info@bio-on.it<br />
www.bio-on.it<br />
NOVAMONT S.p.A.<br />
Via Fauser , 8<br />
28100 Novara - ITALIA<br />
Fax +39.0321.699.601<br />
Tel. +39.0321.699.611<br />
www.novamont.com<br />
6. Equipment<br />
6.1 Machinery & Molds<br />
Zhejiang Hisun Biomaterials Co.,Ltd.<br />
No.97 Waisha Rd, Jiaojiang District,<br />
Taizhou City, Zhejiang Province, China<br />
Tel: +86-576-88827723<br />
pla@hisunpharm.com<br />
www.hisunplas.com<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
Bio4Pack GmbH<br />
D-48419 Rheine, Germany<br />
Tel.: +49 (0) 5975 955 94 57<br />
info@bio4pack.com<br />
www.bio4pack.com<br />
Buss AG<br />
Hohenrainstrasse 10<br />
4133 Pratteln / Switzerland<br />
Tel.: +41 61 825 66 00<br />
Fax: +41 61 825 68 58<br />
info@busscorp.com<br />
www.busscorp.com<br />
weforyou PLA & Applications<br />
office@weforyou.pro<br />
www.weforyou.pro<br />
1.4 starch-based bioplastics<br />
BIOTEC<br />
Biologische Naturverpackungen<br />
Werner-Heisenberg-Strasse 32<br />
46446 Emmerich/Germany<br />
Tel.: +49 (0) 2822 – 92510<br />
info@biotec.de<br />
www.biotec.de<br />
Grabio Greentech Corporation<br />
Tel: +886-3-598-6496<br />
No. 91, Guangfu N. Rd., Hsinchu<br />
Industrial Park,Hukou Township,<br />
Hsinchu County 30351, Taiwan<br />
sales@grabio.com.tw<br />
www.grabio.com.tw<br />
Albrecht Dinkelaker<br />
Polymer and Product Development<br />
Blumenweg 2<br />
79669 Zell im Wiesental, Germany<br />
Tel.:+49 (0) 7625 91 84 58<br />
info@polyfea2.de<br />
www.caprowax-p.eu<br />
2. Additives/Secondary raw materials<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
3. Semi finished products<br />
3.1 films<br />
BeoPlast Besgen GmbH<br />
Bioplastics injection moulding<br />
Industriestraße 64<br />
D-40764 Langenfeld, Germany<br />
Tel. +49 2173 84840-0<br />
info@beoplast.de<br />
www.beoplast.de<br />
INDOCHINE C, M, Y , K BIO C , M, Y, K PLASTIQUES<br />
45, 0,90, 0<br />
10, 0, 80,0<br />
(ICBP) C, M, Y, KSDN BHD<br />
C, M, Y, K<br />
50, 0 ,0, 0<br />
0, 0, 0, 0<br />
D-09, Jalan Tanjung A/4,<br />
Free Trade Zone<br />
Port of Tanjung Pelepas<br />
81560 Johor, Malaysia<br />
T. +607-507 1585<br />
marketing@icbp.com.my<br />
www.icbp.com.my<br />
Molds, Change Parts and Turnkey<br />
Solutions for the PET/Bioplastic<br />
Container Industry<br />
284 Pinebush Road<br />
Cambridge Ontario<br />
Canada N1T 1Z6<br />
Tel. +1 519 624 9720<br />
Fax +1 519 624 9721<br />
info@hallink.com<br />
www.hallink.com<br />
6.2 Laboratory Equipment<br />
MODA: Biodegradability Analyzer<br />
SAIDA FDS INC.<br />
143-10 Isshiki, Yaizu,<br />
Shizuoka,Japan<br />
Tel:+81-54-624-6155<br />
Fax: +81-54-623-8623<br />
info_fds@saidagroup.jp<br />
www.saidagroup.jp/fds_en/<br />
7. Plant engineering<br />
1.5 PHA<br />
Bio-on S.p.A.<br />
Via Santa Margherita al Colle 10/3<br />
40136 Bologna - ITALY<br />
Tel.: +39 051 392336<br />
info@bio-on.it<br />
www.bio-on.it<br />
Infiana Germany GmbH & Co. KG<br />
Zweibrückenstraße 15-25<br />
91301 Forchheim<br />
Tel. +49-9191 81-0<br />
Fax +49-9191 81-212<br />
www.infiana.com<br />
Minima Technology Co., Ltd.<br />
Esmy Huang, COO<br />
No.33. Yichang E. Rd., Taipin City,<br />
Taichung County<br />
411, Taiwan (R.O.C.)<br />
Tel. +886(4)2277 6888<br />
Fax +883(4)2277 6989<br />
Mobil +886(0)982-829988<br />
esmy@minima-tech.com<br />
Skype esmy325<br />
www.minima.com<br />
EREMA Engineering Recycling<br />
Maschinen und Anlagen GmbH<br />
Unterfeldstrasse 3<br />
4052 Ansfelden, AUSTRIA<br />
Phone: +43 (0) 732 / 3190-0<br />
Fax: +43 (0) 732 / 3190-23<br />
erema@erema.at<br />
www.erema.at<br />
bioplastics MAGAZINE [03/18] Vol. 13 59
Suppliers Guide<br />
‘Basics‘ book<br />
on bioplastics<br />
110 pages full<br />
color, paperback<br />
ISBN 978-3-<br />
9814981-1-0:<br />
Bioplastics<br />
ISBN 978-3-<br />
9814981-2-7:<br />
Biokunststoffe<br />
2. überarbeitete<br />
Auflage<br />
This book, created and published by Polymedia<br />
Publisher, maker of bioplastics MAGAZINE<br />
is available in English and German language<br />
(German now in the second, revised edition).<br />
The book is intended to offer a rapid and uncomplicated<br />
introduction into the subject of bioplastics, and is aimed at all<br />
interested readers, in particular those who have not yet had<br />
the opportunity to dig deeply into the subject, such as students<br />
or those just joining this industry, and lay readers. It gives<br />
an introduction to plastics and bioplastics, explains which<br />
renewable resources can be used to produce bioplastics,<br />
what types of bioplastic exist, and which ones are already on<br />
the market. Further aspects, such as market development,<br />
the agricultural land required, and waste disposal, are also<br />
examined.<br />
An extensive index allows the reader to find specific aspects<br />
quickly, and is complemented by a comprehensive literature<br />
list and a guide to sources of additional information on the<br />
Internet.<br />
Uhde Inventa-Fischer GmbH<br />
Holzhauser Strasse 157–159<br />
D-13509 Berlin<br />
Tel. +49 30 43 567 5<br />
Fax +49 30 43 567 699<br />
sales.de@uhde-inventa-fischer.com<br />
Uhde Inventa-Fischer AG<br />
Via Innovativa 31, CH-7013 Domat/Ems<br />
Tel. +41 81 632 63 11<br />
Fax +41 81 632 74 03<br />
sales.ch@uhde-inventa-fischer.com<br />
www.uhde-inventa-fischer.com<br />
9. Services<br />
Osterfelder Str. 3<br />
46047 Oberhausen<br />
Tel.: +49 (0)208 8598 1227<br />
thomas.wodke@umsicht.fhg.de<br />
www.umsicht.fraunhofer.de<br />
narocon<br />
Dr. Harald Kaeb<br />
Tel.: +49 30-28096930<br />
kaeb@narocon.de<br />
www.narocon.de<br />
9. Services (continued)<br />
nova-Institut GmbH<br />
Chemiepark Knapsack<br />
Industriestrasse 300<br />
50354 Huerth, Germany<br />
Tel.: +49(0)2233-48-14 40<br />
E-Mail: contact@nova-institut.de<br />
www.biobased.eu<br />
European Bioplastics e.V.<br />
Marienstr. 19/20<br />
10117 Berlin, Germany<br />
Tel. +49 30 284 82 350<br />
Fax +49 30 284 84 359<br />
info@european-bioplastics.org<br />
www.european-bioplastics.org<br />
10.2 Universities<br />
Institut für Kunststofftechnik<br />
Universität Stuttgart<br />
Böblinger Straße 70<br />
70199 Stuttgart<br />
Tel +49 711/685-62831<br />
silvia.kliem@ikt.uni-stuttgart.de<br />
www.ikt.uni-stuttgart.de<br />
Michigan State University<br />
Dept. of Chem. Eng & Mat. Sc.<br />
Professor Ramani Narayan<br />
East Lansing MI 48824, USA<br />
Tel. +1 517 719 7163<br />
narayan@msu.edu<br />
IfBB – Institute for Bioplastics<br />
and Biocomposites<br />
University of Applied Sciences<br />
and Arts Hanover<br />
Faculty II – Mechanical and<br />
Bioprocess Engineering<br />
Heisterbergallee 12<br />
30453 Hannover, Germany<br />
Tel.: +49 5 11 / 92 96 - 22 69<br />
Fax: +49 5 11 / 92 96 - 99 - 22 69<br />
lisa.mundzeck@hs-hannover.de<br />
www.ifbb-hannover.de/<br />
10.3 Other Institutions<br />
The author Michael Thielen is editor and publisher<br />
bioplastics MAGAZINE. He is a qualified machinery design<br />
engineer with a degree in plastics technology from the RWTH<br />
University in Aachen. He has written several books on the<br />
subject of blow-moulding technology and disseminated his<br />
knowledge of plastics in numerous presentations, seminars,<br />
guest lectures and teaching assignments.<br />
Bioplastics Consulting<br />
Tel. +49 2161 664864<br />
info@polymediaconsult.com<br />
10. Institutions<br />
10.1 Associations<br />
Green Serendipity<br />
Caroli Buitenhuis<br />
IJburglaan 836<br />
1087 EM Amsterdam<br />
The Netherlands<br />
Tel.: +31 6-24216733<br />
www.greenseredipity.nl<br />
Order now for € 18.65 or US-$ 25.00<br />
(+ VAT where applicable, plus shipping and handling,<br />
ask for details) order at www.bioplasticsmagazine.de/<br />
books, by phone +49 2161 6884463 or by e-mail<br />
books@bioplasticsmagazine.com<br />
Or subscribe and get it as a free gift<br />
(see page 61 for details, outside Germany only)<br />
BPI - The Biodegradable<br />
Products Institute<br />
331 West 57th Street, Suite 415<br />
New York, NY 10019, USA<br />
Tel. +1-888-274-5646<br />
info@bpiworld.org<br />
60 bioplastics MAGAZINE [03/18] Vol. 13
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7 th Biobased Chemicals and Plastics<br />
05.06.<strong>2018</strong> - 08.06.<strong>2018</strong> - Bangkok, Thailand<br />
www.cmtevents.com/main.aspx?ev=180617&pu=274110<br />
You can meet us<br />
7 th Biobased performance materials in the circular<br />
economy<br />
14.06.<strong>2018</strong> - Wageningen, Netherlands<br />
22.04.<strong>2018</strong> - Geleen, Niederlande<br />
biobasedperformancematerials.nl/en/bpm.htm<br />
Plastics Tomorrow via Biobased Chemicals & Recycling<br />
25.06.<strong>2018</strong> - 28.06.<strong>2018</strong> - New York City Area, USA<br />
http://innoplastsolutions.com/bio.html<br />
BIO World Congress<br />
16.07.<strong>2018</strong> - 19.07.<strong>2018</strong> - Philadelphia PA, USA<br />
www.bio.org/worldcongress<br />
The 15 th ISBBB<br />
24.07.<strong>2018</strong> - 27.07.<strong>2018</strong> - Guelph, Canada<br />
http://isbbb.org<br />
Mar / Apr<br />
02 | <strong>2018</strong><br />
ISSN 1862-5258<br />
May/June<br />
01 | <strong>2018</strong><br />
25 th Anniversary meeting of the Bio-Environmental<br />
Polymer Society (BEPS)<br />
15.08.<strong>2018</strong> - 17.08.<strong>2018</strong> - (Troy, New York)<br />
ME TO VISIT US AT<br />
https://tinyurl.com/beps<strong>2018</strong><br />
ISSN 1862-5258<br />
14-18 MAY <strong>2018</strong><br />
messe mÜnchen<br />
HALL 5 • stand 323<br />
1st PHA platform World Congress<br />
by bioplastics MAGAZINE<br />
04.09.<strong>2018</strong> - 05.09.<strong>2018</strong> - Cologne, Germany<br />
www.pha-world-congress.com<br />
Innovation Takes Root <strong>2018</strong><br />
10.09.<strong>2018</strong> - 12.09.<strong>2018</strong> - San Diego (CA), USA<br />
https://www.innovationtakesroot.com/<br />
bioplastics MAGAZINE Vol. 13<br />
bioplastics MAGAZINE<br />
Highlights<br />
Thermoforming | 10<br />
Toys | 18<br />
Basics<br />
Mechanical Recycling | 52<br />
Cover Story:<br />
Toy bricks from bio-PE<br />
| 22<br />
Preview:<br />
bioplastics MAGAZINE Vol. 13<br />
Basics<br />
Castor Oil | 48<br />
Highlights<br />
Injection Moulding | 10<br />
Additives/Masterbatches | 42<br />
... is read in 92 countries<br />
... is read in 92 countries<br />
Cover Story:<br />
Netherlands to prohibit<br />
Oxo-degradables | 42<br />
16 th International Symposium on Biopolymers <strong>2018</strong><br />
(ISBP <strong>2018</strong>)<br />
21.10.<strong>2018</strong> - 24.10.<strong>2018</strong> - Beijing, China<br />
http://www.isbp<strong>2018</strong>.com/<br />
r3_03.<strong>2018</strong><br />
07/03/18 12:53<br />
+<br />
or<br />
Mention the promotion code ‘watch‘ or ‘book‘<br />
and you will get our watch or the book 3)<br />
Bioplastics Basics. Applications. Markets. for free<br />
1) Offer valid until 30 July <strong>2018</strong><br />
3) Gratis-Buch in Deutschland nicht möglich, no free book in Germany<br />
bioplastics MAGAZINE [03/18] Vol. Vol. 13 13 61
Companies in this issue<br />
Company Editorial Advert Company Editorial Advert Company Editorial Advert<br />
Aakar Innovations 32<br />
Agrana Starch Bioplastics 40 15, 58<br />
AIMPLAS 12, 13<br />
AITIIP 36<br />
AMIBM 10<br />
API 58<br />
Archer Daniels Midland 6<br />
Arctic Biomaterials 12<br />
BASF 12, 47 58<br />
Bio4Pack 1, 3 59<br />
BioAmber 7<br />
Biomer 10, 43<br />
Bio-on 37 59<br />
BioSolutions 24<br />
Biotec 10 59, 63<br />
Bluepha 10<br />
Bordeaux National Polytechnic Inst. 30<br />
Buss 21, 59<br />
c2renew 42<br />
Cardia Bioplastics 58<br />
Caprowachs, Albrecht Dinkelaker 23 59<br />
Cardiolite Corporation 12<br />
CIPET 46<br />
CETIM 36<br />
China VX 44<br />
Clariant 22<br />
Croda Polymer Additives 43<br />
Danimer Scientific 10, 42<br />
Dr. Heinz Gupta Verlag 33<br />
DuPont 6<br />
Earthsoul India 46<br />
Ellen MacArthur Foundation 10<br />
Emery Oleochemicals 20 19<br />
Eranova 7<br />
Erema 9, 59<br />
European Bioplastics 45, 60<br />
FKuR 10, 13 2, 58<br />
Ford Motor Company 17<br />
Fostag 43<br />
Fraunhofer IGB 6<br />
Fraunhofer IVV 5<br />
Fraunhofer UMSICHT 60<br />
Friesland Campina 27<br />
FullCycle Bioplastics 10<br />
Global Biopolymers 58<br />
Grafe 58, 59<br />
Green Serendipity 60<br />
Grieve 53<br />
Hallink 59<br />
Hasselt University 10<br />
Helian 10<br />
Hydal/Nafigate 10<br />
ICOA 53<br />
IKT, Univ. Stuttgart 10 60<br />
Indesla 36<br />
Indochine Bio Plastiques 59<br />
Infiana Germany 59<br />
InfraServ Knapsack 12<br />
Ins. Verbundwerkstoffe IVW 34<br />
Inst Biotechn. & Wirkstoffforschung 34<br />
Inst. F. Bioplastics & Biocomp. IfBB 14 60<br />
Iterg 30<br />
Jan Ravenstijn 10<br />
Jinhui Zhaolong 58<br />
Joma 29<br />
Kaneka 10 59<br />
LCPO 30<br />
LifetecVision 10<br />
M+Base Engineering 17<br />
MAIP 10<br />
Mango Materials 10<br />
Michigan State University 46 60<br />
Microtec 58<br />
Minima Technology 59<br />
Mitsubishi Chemical 44<br />
Modified Materials 10<br />
MulsiPlast Systems 21<br />
narocon InnovationConsulting 10 60<br />
Natureplast-Biopolynov 58<br />
NatureWorks 8, 43 25<br />
Natur-Tec 59<br />
Neste (Suisse) 12<br />
Netstal 43<br />
Northern Technologies 59<br />
nova Institute 10, 12 13, 49, 60<br />
Novamont 46 59, 64<br />
Nupik 36<br />
Nurel 58<br />
Oak Ridge National Laboratories 43<br />
Organic Waste Systems 10<br />
PepsiCo 10, 42, 48<br />
Perez Cerdá Plastics 36<br />
Phario 10, 28<br />
plasticker 5<br />
Plastics (SPI) 8<br />
polymediaconsult 60<br />
PolyOne 8<br />
PTT/MCC 58<br />
Sabio 10<br />
Saida 59<br />
Scion Research 10<br />
Stamicarbon 10<br />
StoraEnso 45<br />
Sukano 18, 51 48, 58<br />
Symphony Environmental 7<br />
Synvina 12<br />
Tecnaro 59<br />
Thermolympic 36<br />
TianAn Biopolymer 59<br />
TIPA 59<br />
Total-Corbion PLA 7 59<br />
Univ Bordeaux 3<br />
Univ. App. Sc. Bremen 17<br />
Univ. Calgary 38<br />
Univ. Munich 6<br />
Univ. Santiago de Compostela 36<br />
Univ. Stuttgart (IKT) 60<br />
Univ. Wisconsin Madison 17<br />
UPM Biomaterials 12<br />
Viappiani 43<br />
Weforyou 59<br />
Xinjiang Blue Ridge Tunhe Polyester 58<br />
Zhejiang Hangzhou Xinfu Pharmaceutical 58<br />
Zhejiang Hisun Biomaterials 44, 59<br />
<strong>Issue</strong><br />
Editorial Planner<br />
Month<br />
04/<strong>2018</strong> Jul<br />
Aug<br />
Publ.<br />
Date<br />
edit/ad/<br />
Deadline<br />
<strong>2018</strong><br />
Edit. Focus 1 Edit. Focus 2 Edit. Focus 3 Basics<br />
06 Aug 18 06 Jul 18 Blow Moulding Coffee Pods &<br />
Capsules<br />
UK Special<br />
PEF<br />
Trade-Fair<br />
Specials<br />
05/<strong>2018</strong> Sep<br />
Oct<br />
06/<strong>2018</strong> Nov<br />
Dec<br />
01 Oct 18 28 Sep 18 Fiber / Textile /<br />
Nonwoven<br />
03 Dec 18 02 Nov 18 Films/Flexibles/<br />
Bags<br />
Polyurethanes/<br />
Elastomers/<br />
Rubber<br />
Bioplastics<br />
from Waste<br />
Streams<br />
Poland & Baltic<br />
States Special<br />
t.b.d.<br />
Industrial Composting,<br />
Challenges / Hurdles<br />
Shelf Life of Bioplastics<br />
Subject to changes<br />
62 bioplastics MAGAZINE [03/18] Vol. 13
A COMPLETE RANGE<br />
OF SOLUTIONS.<br />
BIOPLAST®,<br />
INNOVATIVE<br />
SOLUTIONS FOR<br />
EVERYDAY PRODUCTS.<br />
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film, flat film, cast<br />
film, injection molded<br />
and thermoformed<br />
components.<br />
100 % biodegradable,<br />
BIOPLAST® is particularly<br />
suitable for ultra-light<br />
films with a thickness of<br />
approx. 10-15 μm.<br />
S002<br />
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HOME<br />
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GMO FREE<br />
www.biotec.de<br />
member of the SPHERE<br />
group of companies<br />
LJ Corporate – © JB Mariou – BIOTEC HRA 1183
WWW.MATERBI.COM<br />
EcoComunicazione.it<br />
r1_05.2017