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From Science & Research<br />

By:<br />

Jasmin Bauer,Carola Westphalen<br />

KNOTEN WEIMAR<br />

Internationale Transferstelle Umwelttechnologien GmbH<br />

Weimar, Germany<br />

Tobias Hartmann, Roman Rinberg,,Lothar Kroll<br />

Technische Universität Chemnitz<br />

Chemnitz, Germany<br />

material first underwent the automated sorting process<br />

and was then manually separated from the fractions.<br />

The following results were achieved:<br />

• Detecting and, in particular, separation of PLA materials<br />

as individual material fraction in a state-of-the-art plant<br />

is possible.<br />

• Sorting under normal conditions for lightweight<br />

packaging (PLA detection not active) approx. 9 % of the<br />

PLA input goes into the PVC fraction. Hence, PLA is<br />

classified as PVC if no PLA spectrum is active.<br />

• Small scale adaption was made by adjusting the plant<br />

technology by scanning the PLA spectra.<br />

• Positive sorting on PLA results in a sorting rate of 55%.<br />

• Positive sorting on PLA+PE/PP extracted 46% of PLA<br />

input.<br />

The generated test material (PLA fraction) was grinded,<br />

washed and the grist was purified to 90 % PLA with the help<br />

of Hamos GmbH (Penzberg, Germany) in the company’s<br />

own pilot plant. The purification took place in three stages:<br />

air separation, metal separation and plastic-plastic<br />

separation. The main contamination after the cleaning<br />

process was adhesive label residues from the yoghurt cup.<br />

As not enough input material was available for the final<br />

regranulation on an industrial plant, a test material (~ 0.8 t)<br />

Fig. 2 Input material (left), automated sorting process (right)<br />

was mixed analogous to the purified fraction. This grist<br />

was regranulated at Sysplast GmbH&Co. KG in Nürnberg,<br />

Germany on a Coperion ZSK 50MC with an Ettlingen rotary<br />

filter ERF (sieve width 250 µm) with throughputs of up to 400 kg<br />

per hour. The impurities were separated effectively and a<br />

green regranulate was obtained (see Fig. 3).<br />

The mechanical testing revealed the following losses<br />

with regard to the virgin material (Ingeo 2003D from<br />

NatureWorks):<br />

Young’s modulus -1 %<br />

tensile strength -24 %<br />

Charpy unnotched -31 %<br />

Charpy notched -17.4 %<br />

All the tests and results mentioned, as well as further<br />

experiments on the recycling of PLA, including a life cycle<br />

assessment, are detailed in the final report of the research<br />

alliance “Nachhaltige Verwertungsstrategien für Produkte<br />

und Abfälle aus biobasierten Kunststoffen” funded by<br />

BMEL in which eight partners from science and industry<br />

participated [3]. A quick overview of the most important<br />

results, as well as further links to the joint project and the<br />

partners, are summarised in the results paper “PLA in the<br />

waste stream” (download link see [4]).<br />

References:<br />

[1] European Bioplastics, nova-Institut (2017). www.biobased.eu/markets<br />

[2] https://www.fnr.de/index.php?id=11150&fkz=22019212<br />

[3] https://www.european-bioplastics.org/pla-in-the-waste-stream/<br />

[4] https://www.umsicht.fraunhofer.de/content/dam/umsicht/en/<br />

documents/press-releases/2017/pla-in-the-waste-stream.pdf<br />

www.bionet.net | www.leichtbau.tu-chemnitz.de<br />

Fig. 3: seperates impurities (left) and green PLA regranulate (right)<br />

bioplastics MAGAZINE [<strong>06</strong>/18] Vol. 13 19

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