Issue 03/2019
Highlights: Toys Injection Moulding Basics: Microplastics Mind the right terms Captured CO2
Highlights:
Toys
Injection Moulding
Basics:
Microplastics
Mind the right terms
Captured CO2
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May / June<br />
<strong>03</strong> | <strong>2019</strong><br />
bioplastics MAGAZINE Vol. 14 ISSN 1862-5258<br />
Basics<br />
Microplastics | 56<br />
Mind the right terms | 54<br />
Captured CO 2<br />
vs. biobased | 48<br />
Highlights<br />
Toys | 10<br />
Injection Moulding | 30<br />
Cover Story<br />
bio-PE truck ride-on<br />
... is read in 92 countries
PLAY WITH PLASTICS!<br />
Sustainable – Safe – Sophisticated<br />
The world we live in is unique, exciting and full of surprises. Children discover<br />
their world in a fun way by playing with toys, which generate curiosity and<br />
stimulate the imagination while having to withstand countless adventures.<br />
Our bioplastics combine sustainability with trend-setting material<br />
properties that help to reduce CO2 emissions.<br />
With FKuR bioplastics you will get high-quality toys that meet<br />
your needs exactly and that children will enjoy for a long time.
Editorial<br />
dear<br />
readers<br />
The hottest bioplastics news to break these past two months was surely the publication<br />
in April of a study from the University of Plymouth. Taken up and amplified by numerous<br />
journalists - including the yellow press – in addition to receiving TV coverage and drawing<br />
the attention of many serious publications, it has certainly roiled the bioplastics debate. The<br />
study appeared under the title “Environmental Degradation of Biodegradable, Degradable<br />
and Conventional Plastic Carrier Bags in the Sea, Soil and Open-Air Over a Three-Year<br />
Period“, and sparked blaring headlines, including “‘Biodegradable plastic bags survive<br />
three years in soil and sea”.<br />
Five bags were examined: oxo-degradable bags, one fossil-based non-biodegradable<br />
polyethylene bag, one bag marketed as – but not proven to be - biodegradable, and only<br />
one product certified compostable according to the European Norm 13432.<br />
While only the certified compostable bag sample had completely disappeared<br />
after three months in the marine environment, the utterly crucial point to emphasize<br />
here is that even certified compostable bio-waste bags have not been developed to<br />
degrade in the soil or in a marine environment. These certified bags are designed<br />
to degrade under industrial composting conditions. Whenever ‘biodegradability’ or<br />
‘compostability’ is claimed, the conditions (environment, temperature etc) must be<br />
given. And – neither biodegradability nor compostability is meant to be a solution<br />
to littering. Littering, and subsequently also marine pollution can only be solved by<br />
changing people’s behaviour, not by any kind of material. As this topic could easily fill<br />
many pages, we are planning to give it the necessary space in one of the upcoming<br />
issues of bioplastics MAGAZINE. Until then, links to a number of salient comments can<br />
be found at www.bioplasticsmagazine.de/<strong>2019</strong><strong>03</strong>.<br />
Other highlight topics in this issue are Injection moulding and Toys. Following the very<br />
successful 1st bio!TOY conference in Nuremberg in March with about 90 delegates, we are<br />
happy to share the articles the event generated in this issue.<br />
In the Basics section 3 topics are covered. We first take a closer look at Microplastics, then<br />
discuss the question:Can products made from captured/recycled CO 2<br />
be called Biobased?<br />
Finally, we explain once and for all the difference between Biodegradable - compostable -<br />
oxo-degradable plastics.<br />
Just days before this issue went to print, we hosted the third edition of our bio!PAC<br />
conference on biobased packaging in Düsseldorf, which was a very successful event in every<br />
respect. And we are already focussing on the next big event this year: The K-Show in October<br />
in Düsseldorf, Germany with our 4th Bioplastics Business Breakfast. The call for papers is<br />
open. We are looking forward to your contributions.<br />
We hope to see you at the K-Show this autumn, or perhaps elsewhere even earlier, and<br />
until then, enjoy the summer - and of course, have a great time reading bioplastics MAGAZINE.<br />
Sincerely yours<br />
EcoComunicazione.it<br />
WWW.MATERBI.COM<br />
r1_05.2017<br />
05/05/17 11:39<br />
bioplastics MAGAZINE Vol. 14 ISSN 1862-5258<br />
Basics<br />
Microplastics | 56<br />
Mind the right terms | 54<br />
Captured CO 2 vs. biobased | 48<br />
Highlights<br />
Toys | 10<br />
Injection Moulding | 30<br />
May / June<br />
Cover Story<br />
<strong>03</strong> | <strong>2019</strong><br />
bio-PE truck ride-on<br />
... is read in 92 countries<br />
Follow us on twitter!<br />
www.twitter.com/bioplasticsmag<br />
Like us on Facebook!<br />
www.facebook.com/bioplasticsmagazine<br />
Michael Thielen<br />
bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 3
Content<br />
Imprint<br />
May / June <strong>03</strong>|<strong>2019</strong><br />
3 Editorial<br />
5 News<br />
8 Events<br />
42 Application News<br />
50 Patents<br />
52 Brand Owner<br />
53 10 years ago<br />
54 Basics<br />
58 Suppliers Guide<br />
62 Companies in this issue<br />
Publisher / Editorial<br />
Dr. Michael Thielen (MT)<br />
Samuel Brangenberg (SB)<br />
Head Office<br />
Polymedia Publisher GmbH<br />
Dammer Str. 112<br />
41066 Mönchengladbach, Germany<br />
phone: +49 (0)2161 6884469<br />
fax: +49 (0)2161 6884468<br />
info@bioplasticsmagazine.com<br />
www.bioplasticsmagazine.com<br />
Media Adviser<br />
Samsales (German language)<br />
phone: +49(0)2161-6884467<br />
fax: +49(0)2161 6884468<br />
sb@bioplasticsmagazine.com<br />
Michael Thielen (English Language)<br />
(see head office)<br />
Layout/Production<br />
Kerstin Neumeister<br />
Print<br />
Poligrāfijas grupa Mūkusala Ltd.<br />
1004 Riga, Latvia<br />
bioplastics MAGAZINE is printed on<br />
chlorine-free FSC certified paper.<br />
Print run: 3.500 copies<br />
Toys<br />
10 Biobased toys a perfect win-win<br />
13 Binabo and other sustainable toys<br />
14 Relaunch of coean safe beach toys<br />
16 Baby Toys - safe and sustainable<br />
18 Danish bio toys - a success story<br />
20 Bioplastic items for kids<br />
22 Consumer Attitudes<br />
25 Toymakers find many paths to sustainability<br />
26 Cooler than wood. Better than plastic.<br />
Cover Story<br />
28 You never forget your first car<br />
Injection Moulding<br />
30 Optimize PLA for injection moulding<br />
32 Single use cutlery & food containers<br />
34 Injection Moulding Handbook<br />
36 Injection Molding PLA<br />
Applications<br />
40 Cosmetic tubes from bio-PE<br />
44 This spoon dies the rext !<br />
Materials<br />
46 Pack it in feathers<br />
47 Novel biobased barrier film<br />
bioplastics magazine<br />
ISSN 1862-5258<br />
bM is published 6 times a year.<br />
This publication is sent to qualified subscribers<br />
(169 Euro for 6 issues).<br />
bioplastics MAGAZINE is read in<br />
92 countries.<br />
Every effort is made to verify all Information<br />
published, but Polymedia Publisher<br />
cannot accept responsibility for any errors<br />
or omissions or for any losses that may<br />
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All articles appearing in<br />
bioplastics MAGAZINE, or on the website<br />
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covered by copyright. No part of this<br />
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in any form, including electronic format,<br />
without the prior consent of the publisher.<br />
Opinions expressed in articles do not necessarily<br />
reflect those of Polymedia Publisher.<br />
bioplastics MAGAZINE welcomes contributions<br />
for publication. Submissions are<br />
accepted on the basis of full assignment<br />
of copyright to Polymedia Publisher GmbH<br />
unless otherwise agreed in advance and in<br />
writing. We reserve the right to edit items<br />
for reasons of space, clarity or legality.<br />
Please contact the editorial office via<br />
mt@bioplasticsmagazine.com.<br />
The fact that product names may not be<br />
identified in our editorial as trade marks<br />
is not an indication that such names are<br />
not registered trade marks.<br />
bioplastics MAGAZINE tries to use British<br />
spelling. However, in articles based on<br />
information from the USA, American<br />
spelling may also be used.<br />
Envelopes<br />
A part of this print run is mailed to the<br />
readers wrapped bioplastic envelopes<br />
sponsored by Taghleef Industries, Italy<br />
Cover<br />
Ferbedo<br />
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daily upated news at<br />
www.bioplasticsmagazine.com<br />
News<br />
DIN CERTCO<br />
cooperates with Scion<br />
from New Zealand<br />
Kaneka Americas<br />
Holding, to create new<br />
biopolymers division<br />
DIN CERTCO (Berlin, Germany) is now starting a<br />
new cooperation with Scion (Rotorua, New Zealand)<br />
for the testing of compostable products.<br />
Oliver Ehlert (product manager, compostable<br />
products, DIN CERTCO) said: “With the acknowledgment<br />
of our new testing partner Scion we strengthen our<br />
position in Australia and New Zealand. We can offer<br />
our customers a faster service for laboratory testing<br />
with local partners around the globe.”<br />
Florian Graichen (science leader biopolymers and<br />
chemicals, Scion) said: “DIN CERTCO is a key partner<br />
for Scion in our role to lead the transition of New<br />
Zealand to a circular bioeconomy. Scion is helping<br />
to solve the new challenges that arise through the<br />
transition into a new economy focused on sustainable<br />
design and renewable resources. The ability to design,<br />
manufacture, test and certify compostable products<br />
and materials are crucial for the success and future<br />
growth of New Zealand’s packaging and plastics<br />
related businesses.”<br />
For certifications, according to the AS 4736 and<br />
AS 5810 standards in the Australia and New Zealand<br />
(Australasia) markets, DIN CERTCO already cooperates<br />
with the Australasian Bioplastics Association (ABA)<br />
and the certification system there.<br />
Scion covers the full scope of laboratory tests for<br />
industrial compostable products and home compostable<br />
products and can perform the laboratory testing for<br />
the certification of compostable products according<br />
to all relevant national and international standards:<br />
ASTM D 6400, EN 13432, EN 14995, ISO 17088, ISO 18606,<br />
AS 4736, AS 5810, NF T 51-800. MT<br />
www.dincertco.de/en | www.scionresearch.com<br />
Kaneka Americas Holding, Inc. headquartered in<br />
Houston, Texas, recently announced the creation of a new<br />
biopolymers division, for the sale of Kaneka’s plant-based<br />
degradable plastic PHBH compounds in the United States.<br />
The new division will also be located in Houston.<br />
Kaneka's PHBH is a plant-based product that offers both<br />
flexibility and heat resistance. It is produced via a novel biofermentation<br />
process which uses renewable plant oils as<br />
feedstock. Kaneka's products are not only biobased and<br />
compostable in aerobic, anaerobic or marine environments,<br />
they are also strongly resistant to heat and can act as a<br />
barrier to water vapour.<br />
Stable under everyday conditions of use, given the right<br />
conditions, under either anaerobic, aerobic or marine<br />
conditions in the natural environment, the products will<br />
begin to biodegrade.<br />
PHBH has been granted Food Contact Approval by the<br />
FDA and is suitable for all food packaging products. PHBH<br />
can be formed into many products such as cups, cutlery,<br />
food trays, plates etc.<br />
Kaneka has been producing PHBH since 2011 and<br />
is currently expanding its facilities in Takasago, Japan.<br />
Kaneka hopes to find an alternative solution to the current<br />
single-use plastic products as the company recognizes the<br />
need to bring to market a plant-based product that will<br />
help reduce the ocean and<br />
landfill pollution. Currently,<br />
it is estimated that about 8<br />
Million tonnes of plastic end<br />
up in the marine environment<br />
every year, which has created<br />
a massive environmental issue<br />
in the oceans of the world. MT<br />
www.kaneka.com/kaneka-americas<br />
Picks & clicks<br />
Most frequently clicked news<br />
Here’s a look at our most popular online content of the past two months.<br />
The story that got the most clicks from the visitors to bioplasticsmagazine.com was:<br />
tinyurl.com/news<strong>2019</strong><strong>03</strong>20<br />
PHA water bottle coming soon (20 March <strong>2019</strong>)<br />
It may sound like California Dreamin' but a new bottle, manufactured and<br />
marketed in California under the brand name Cove, is the first bottle of water<br />
made entirely of biodegradable material, say its makers.<br />
The material the bottle is made of is PHA, which will break down into CO 2<br />
,<br />
water, and organic waste. This will happen in compost or a landfill, and even<br />
in the ocean.<br />
PHA, or polyhydroxyalkanoate, is an FDA-approved, naturally occurring<br />
biopolymer. It’s biodegradable, compostable, produces zero toxic waste, and<br />
breaks down into CO 2<br />
, water, and organic waste.<br />
bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 5
News<br />
daily upated news at<br />
www.bioplasticsmagazine.com<br />
Arkema selects Singapore as new<br />
Rilsan production site<br />
In early May, Arkema, headquartered in Colombes,<br />
France, announced the location of its planned new worldscale<br />
plant for the production of the monomer of PA11 -<br />
11-Aminoundecanoic acid, derived<br />
from castor oil - and its Rilsan ®<br />
polyamide 11 resins.<br />
The company has chosen Jurong<br />
Island in Singapore to set up its new<br />
bio-sourced polyamide production<br />
site, because of the advantages<br />
the location offers in terms of<br />
infrastructure, logistics, industrial<br />
integration and operational<br />
excellence, as well as optimization<br />
of the carbon footprint of the<br />
planned business.<br />
Plans for the new plant, which will double global production<br />
capacities, were announced in July 2017, in response to<br />
strong demand from Asia for high-performance bio-sourced<br />
lightweighting solutions. Rilsan polyamide 11 is derived from<br />
castor oil and so is the 100% bio-sourced polyamide approved<br />
for many of the most demanding applications, in particular<br />
in the electronics, 3D printing, oil and gas extraction, and<br />
automotive markets, as a substitute to metal.<br />
“This major investment bolsters<br />
our global presence in biosourced<br />
materials while bringing<br />
us significantly closer to our<br />
customers in Asia Singapore’s<br />
industrial and innovation-friendly<br />
environment is, we believe, a key<br />
asset for our project, " commented<br />
Erwoan Pezron, global group<br />
President for Arkema’s technical<br />
polymers business line.<br />
This project is part of the Group’s<br />
exceptional investments of in total<br />
some 500 million Euros earmarked for the 2018-2021 period.<br />
Construction is scheduled to be completed by late 2021 MT<br />
www.arkema.com<br />
From cigars to PLA-films ERRATUM (<strong>Issue</strong> 02/<strong>2019</strong>)<br />
Founded at the end of the 19th century as cigar<br />
manufactory the company shifted from cigars to plastics<br />
film packaging in the 1970s and became arbo Plastic, a<br />
Swiss pioneer company to offer first-class quality films.<br />
2016, after many years of successfully producing<br />
specialty Barex barrier plastic films, Barex resin was no<br />
longer manufactured by the supplier. These circumstances<br />
forced arbo Plastic to carefully evaluate and rethink<br />
their future business orientation. The aim is to convert<br />
to modern, environmentally friendly, sustainable and<br />
compostable materials.<br />
2018 arbo Plastic took up the challenge by stepping into<br />
the future. The right moment to recognise the signs of the<br />
times. An enormous amount of new materials needed to be<br />
tested, the best qualities had to be found and the market<br />
has to be conquered anew. An inspiring task for a visionary<br />
like the owner and CEO Ursula Friederich and her team.<br />
The company recognized that PLA is the material of choice<br />
which meets the needs of a rapidly growing market.<br />
With their comprehensive experience in the field of film<br />
extrusion, mainly in the 80 µm and higher range, arbo<br />
Plastic are best prepared for an intensive exchange of<br />
knowledge and the repositioning of the company. With<br />
uncomplicated flexibility, speed, precision and reliability<br />
the Swiss offer personal support and development of<br />
individual solutions for specific customer requirements,<br />
even for small quantities: arbo Plastic stands for Swiss<br />
quality. MT www.arboplastic.ch<br />
Heat Resistant and<br />
home compostable<br />
PLA resins<br />
In the last issue bioplastics MAGAZINE published an<br />
article about Kompuestos' "Heat Resistant and home<br />
compostable PLA resins". We sincerely apologize for<br />
an error that occured in this article. The production<br />
capacity is 170,000 tonnes, not 17,000 tonnes.<br />
The paragraph should red correctly:<br />
Kompuestos is a Spanish company founded in 1986 in<br />
Palau Solità i Plegamans near Barcelona. Over the past<br />
three decades, Kompuestos has acquired an in-depth<br />
knowledge of the market and has positioned itself as<br />
oneof the main international suppliers of a large variety<br />
of masterbatches, all of which are intended to meet the<br />
needs of very diverse markets in the plastics industry,<br />
among which the packaging sector. With a production<br />
capacity of over 170,000 tonnes per year and growing,<br />
Kompuestos has established itself as one of the leading<br />
companies in the sector, while still seeking to expand its<br />
business MT<br />
www.kompuestos.com<br />
6 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
News<br />
DowDuPont Inc. selling out on sustainability?<br />
During a May 2 conference call, DowDuPont said it is moving six units into a new non-core segment as it considers options,<br />
including divestment.<br />
Incoming company CEO Marc Doyle who will take over from ED Breen as DuPont’s CEO said the non-core units are photovoltaic<br />
and advanced materials, biomaterials – including corn-derived Sorona textiles - clean technologies, sustainable solutions, the<br />
Hemlock Semiconductor Group joint venture and the DuPont Teijin Films joint venture.<br />
Questions were raised, as four of the six operations be considered for divestment involve environmentally-oriented products.<br />
DowDuPont CEO Ed Breen, who will be chairman of DuPont, responding by explaining that “they are more volatile assets than<br />
I would want in my portfolio.”<br />
The businesses totalled $2B in revenues and generated about $500 million of operating earnings last year, said Doyle.<br />
Previously, in November 2018, Breen had sold off DowDuPont’s cellulosic ethanol business, which converts the inedible parts<br />
of the corn plant into motor fuel, including a $200 million Iowa biorefinery that opened in 2015. The DuPont cellulosic ethanol<br />
plant in the town of Nevada, in Iowa, USA was sold to the US subsidiary of German biofuels company's Verbio.<br />
Verbio plans to start construction to transition the plant from ethanol to renewable natural gas in the spring, with commercial<br />
production of renewable transportation fuel ready to go by summer 2020.<br />
DowDuPont, the company that resulted following the merger of equals in August 2017, is currently in the process of breaking<br />
up into three independent publicly traded companies, with Dow being dedicated to commodity chemical production, DuPont to<br />
specialty chemical production, and Corteva to agricultural chemicals. Dow, the Materials Science division, was successfully<br />
spun off on April; the Agriculture and Speciality divisions will be split up in June <strong>2019</strong>. MT<br />
www.dow-dupont.com<br />
BASF and Lactips partner to market<br />
water-soluble, biodegradable film<br />
BASF and Lactips announced in mid-May that<br />
both companies have signed an exclusive contract to<br />
market Lactips’ water-soluble, 100% biobased and fully<br />
biodegradable material prepared from natural ingredients.<br />
This long-term partnership supports BASF’s strategy to<br />
leverage sustainable solutions to drive business growth.<br />
BASF and Lactips will bring<br />
in their respective expertise<br />
to offer this innovative<br />
technology to the home care<br />
as well as industrial and<br />
institutional (I&I) market.<br />
While Lactips focuses on<br />
the development of the film<br />
material technology based<br />
on technical casein obtained<br />
from excess of milk protein<br />
production, BASF will bring<br />
in its expertise in network and supply chain to market the<br />
product. The solution of Lactips aims on the replacement<br />
of polyvinyl alcohol films in home care and I&I applications,<br />
such as dishwasher tabs.<br />
“Sustainability plays a major role in all of BASF’s business<br />
processes,” said Robert Parker, Director, New Business<br />
Development at Care Chemicals, BASF. “Lactips’ solution<br />
for films for dishwasher tabs supplements our existing<br />
portfolio of sustainable offerings. It allows us to provide our<br />
customers with a broad portfolio of bio-degradable products<br />
for the home care industry.”<br />
“Lactips is proud to have its technology marketed by a<br />
leading global partner with a strong network,” said Marie-<br />
Hélène Gramatikoff, CEO Lactips. “We will benefit from<br />
BASF’s experience and latest<br />
developments in the home<br />
care industry.”<br />
Lactips offers the<br />
first water-soluble, fully<br />
biodegradable plasticfree<br />
plastic. Created in<br />
2014 by Marie-Hélène<br />
Gramatikoff, plastics and<br />
business strategy specialist,<br />
and Frédéric Prochazka,<br />
researcher at Saint-Etienne<br />
University, Lactips designs, develops and markets a watersoluble,<br />
biodegradable plastic-free plastic material based<br />
on milk protein. This new material is also food contact<br />
approved, edible and aligned with the sustainable ambitions<br />
of the food processing sector. In the middle term, Lactips<br />
plans to build a 2,500 m² plant to expand production to 3,000<br />
tonnes a year and up. MT<br />
www.lactips.com | www.basf.com<br />
bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 7
Events<br />
Anandi Eco+ Compostable sanitary<br />
pads from India win again<br />
Sustainable fibres from Finland and home compostable coffee capsules<br />
from Germany are the runner-up winners of the innovation award<br />
F<br />
or the 12 th year in a row, the innovation award “Biobased<br />
Material of the Year” has been granted to the<br />
young, innovative biobased chemicals and materials<br />
industry by nova-Institute (Hürth, Germany).<br />
As usual for this award the three winners were chosen<br />
by the expert audience at the “12 th International Conference<br />
on Bio-based Materials” (Cologne, Germany 15/16 May)<br />
from six previously selected nominees. With more than 270<br />
participants and 30 exhibitors, the conference established<br />
itself further as one of the world’s most important meeting<br />
places for the leaders of the bioeconomy.<br />
Organizer Michael Carus, nova-Institute, was enthusiastic<br />
about the overwhelming response: “The most important<br />
pioneers of the global bioeconomy met in Cologne and<br />
exchanged views on the strong dynamics of the industry.<br />
Previous hopefuls of the biobased chemistry are weakening<br />
and others are making amazing breakthroughs!”<br />
The winners in detail:<br />
First place: Aakar Innovations Pvt. Ltd. (India):<br />
Anandi Eco+ – 100% Compostable Sanitary Pads<br />
Anandi Eco+ is the first and only Govt. of India Lab certified<br />
compostable sanitary pad. (cf. comprehensive reports<br />
in bioplastics MAGAZINE issues <strong>03</strong>/2018 and 06/2018). In a<br />
compost environment, at least 90% of the pad are biodegraded<br />
within 180 days. Under other conditions in nature it takes<br />
longer respectively. The pads can be disposed easily in the<br />
backyard mud pit of any rural household to avoid polluting the<br />
environment and create bio-manure for agriculture. Aakar<br />
also uses local resources like starch, jute, bagasse, banana<br />
fibre and water hyacinth to produce their sanitary pads to<br />
reduce cost and utilizes agricultural plant waste materials.<br />
Anandi Eco+ pads do not use any harmful chemicals like<br />
superabsorbent polymers (SAP) and convert into manure<br />
post disposal, which can be further utilised. This way, the<br />
pads contribute to environmental protection and increased<br />
resource reuse. It also follows the American Standard ASTM<br />
D6400 & European Standard EN 13432. Aakar contributes to<br />
12 out of the 17 Sustainable Development Goals of the UN<br />
through their work. Decentralised production is carried out by<br />
women in India and soon also in various African countries on<br />
the basis of regional raw materials.<br />
Second place: Spinnova Oy (Finland):<br />
Spinnova – Sustainable Textile Fibre<br />
Spinnova is a sustainable fibre company from Finland that<br />
develops ecological breakthrough technology for manufacturing<br />
cellulose-based textile fibre. Spinnova’s patented technology<br />
does without harmful chemicals and creates no waste or side<br />
streams, making the fibre and the production method probably<br />
the most sustainable in the world. The biggest difference to<br />
other man-made cellulosic fibres is that no chemical dissolution<br />
takes place throughout the whole process. Spinnova’s raw<br />
material commitment is to only use FSC certified wood or waste<br />
stream-based cellulose. Spinnova’s objective is to globally<br />
commercialize the fibre products in collaboration with major<br />
textile brands. The properties and prices of the new cellulose<br />
fibres are based on cotton.<br />
Third place: Golden Compound GmbH (DE):<br />
HOMEcap – Home Compostable Coffee Capsules<br />
HOMEcap is the world’s first and only home compostable<br />
coffee capsule successfully introduced in the market that is<br />
‘OK compost HOME’ certified and made with natural fibres<br />
of the sunflower seed hull. The biodegradation in home<br />
compost avoids considerable waste streams. The capsule<br />
was successfully launched on the market in the spring of<br />
this year. It is made from a unique compound comprising<br />
PTTMCCs PBS and PBSA mixed with sunflower seed shells<br />
and inorganic fillers<br />
The nova-Institute would like to acknowledge InfraServ<br />
GmbH & Co. Knapsack KG (DE) for sponsoring the renowned<br />
innovation award “Bio-based Material of the Year <strong>2019</strong>”. MT<br />
Jaydeep Mandal (Aakar Innovations)<br />
with Anandi Eco + and the award<br />
www.bio-based-conference.com<br />
www.aakarinnovations.com<br />
www.spinnova.com<br />
www.golden-compound.com<br />
8 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
Call for papers now open!<br />
organized by<br />
16. - 19.10.<strong>2019</strong><br />
Messe Düsseldorf, Germany<br />
BIOPLASTICS<br />
BUSINESS<br />
BREAKFAST<br />
B 3<br />
Bioplastics in<br />
Packaging<br />
PLA, an Innovative<br />
Bioplastic<br />
Bioplastics in<br />
Durable Applications<br />
PHA, Opportunities<br />
& Challenges<br />
www.bioplastics-breakfast.com<br />
At the World‘s biggest trade show on plastics and rubber:<br />
K‘<strong>2019</strong> in Düsseldorf bioplastics will certainly play an important role again.<br />
On four days during the show bioplastics MAGAZINE will host a<br />
Bioplastics Business Breakfast: From 8am to 12pm the delegates will<br />
enjoy highclass presentations and unique networking opportunity.<br />
The trade fair opens at 10 am.<br />
Media Partner:<br />
bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 9
Toys<br />
By:<br />
Biobased toys -<br />
Harald Kaeb<br />
narocon<br />
Berlin, Germany<br />
The intense debate on plastics, their deficiencies and<br />
drawbacks when it comes to sustainability and circularity,<br />
is centred around packaging. However, the discussion<br />
is not limited to this biggest sector of consumption. In<br />
this article, Harald Kaeb, inventor and co-organiser of the first<br />
bio!TOY conference examines the options for a wider use of<br />
renewable raw materials and biobased plastics in the toy sector.<br />
He also analyses the supply chain practices in the sector,<br />
exploring how it could become an emerging market and outlet<br />
for biobased polymers. The ideas and findings discussed in<br />
this article were the basis for the bio!TOY conference concept.<br />
Looking back at the event - the first encounter between the toy<br />
sector and the biobased plastics industry – the feedback from<br />
participants confirms that, as a concept, this was a success.<br />
Moreover, it offered scope for opening the door for collaborative<br />
development, hopefully based on strategic considerations.<br />
The toy sector - a user analysis<br />
Five years ago, a UNEP report was published examining the<br />
role and use of plastics in different sectors, including the toy<br />
industry [1]. The report revealed that “toy manufacturers have<br />
the highest plastic intensity in the consumer goods sector, at<br />
48 tonnes of CO 2<br />
equivalents per USD1 million revenue, due to<br />
their use of plastic in products (incl. packaging). As a result,<br />
they have the highest value at risk at 3.9% of annual revenue.<br />
This would wipe out the profits of several companies if they had<br />
to pay the full cost of environmental damage caused by plastic.<br />
That is a finding that should make the chief financial officer sit<br />
up and take note”. In other words: The toy industry ranks #1<br />
due to its heavy use of plastics, with famous toy brands shown<br />
to be indifferent to environmental issues, and, more so than<br />
any other consumer sector, to have no thought for the financial<br />
consequences of this irresponsible behaviour. Any awareness<br />
of the fact that, if these external costs were internalised, their<br />
economic model and financial stability would be at risk, seems<br />
lacking. Such disregard for environmental responsibility can<br />
be fatal to an industry’s image.<br />
This obliviousness to environmental concerns, while at the<br />
same time continuing to be a heavy (ab)user, will become even<br />
more risky with the increasing visibility of climate change and<br />
the public outrage this has awakened. Children and young<br />
people have taken to the streets to call for strict and powerful<br />
action, as they see climate change as the biggest threat to their<br />
future. In a survey conducted among almost 11,000 people aged<br />
15-30, climate change ranked as the number one concern [2].<br />
Toy makers who respond to issues by reviewing the materials<br />
they use in the light of sustainability performance criteria,<br />
Figure 1 Total natural capital cost and<br />
intensity of selected sectors Source [1]<br />
18,000<br />
23%<br />
4%<br />
TOTAL NATURAL CAPITAL COST ( $m)<br />
16,000<br />
14,000<br />
12,000<br />
10,000<br />
8,000<br />
6,000<br />
4,000<br />
2,000<br />
12%<br />
10%<br />
9% 9%<br />
8%<br />
6% 6% 5%<br />
4% 3% 2%<br />
1% 1% 1%<br />
1%<br />
3%<br />
2%<br />
1%<br />
PERCENTAGE OF REVENUE AT RISK<br />
0<br />
FOOD<br />
SOFT DRINKS<br />
NON-DURABLE HOUSEHOLD GOODS<br />
AUTOMOBILES<br />
FURNITURE<br />
RETAIL<br />
DURABLE HOUSEHOLD GOODS<br />
FOOTWEAR<br />
CLOTHING AND ACCESSORIES<br />
TOYS<br />
PERSONAL PRODUCTS<br />
CONSUMER ELECTRONICS<br />
ATHLETIC GOODS<br />
RESTAURANTS<br />
TOBACCO<br />
MEDICAL AND PHARMACEUTICAL PRODUCTS<br />
0%<br />
TOTAL NATURAL CAPITAL COST<br />
PERCENTAGE OF REVENUE AT RISK<br />
10 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14<br />
Corresponds approximately to over 80 million tonnes of plastic. Trucost calculations derived from, but not limited to, World Bank [7];<br />
PlasticsEurope [8]; Eurostat [9], and the US EPA [10] datasets (full set of references and methodologies available in appendices 3<br />
and 4 of this report).
Toys<br />
A perfect win win? An analysis of the supply side<br />
and user sector<br />
i.e. longevity, circularity and greenhouse gas emissions, will<br />
benefit from a growing green consumerism. Failure to find<br />
an adequate response may put the whole business at risk -<br />
as climate change will surely trigger measures to internalise<br />
such costs, e.g. through CO 2<br />
tariffs. Pioneers like the famous<br />
toy brand LEGO, with its clear commitment to making the<br />
transition to sustainable materials, will push others to take<br />
action. The bio!TOY conference showed how many brands<br />
and players from the toy industry are already searching for<br />
solutions. The sector is ready for development partnerships.<br />
The biobased industry - supply side analysis<br />
For a long time, the plastics market remained almost<br />
untouched by issues such as pollution and over-consumption.<br />
Single-use food service packaging and many other shortlife<br />
plastic products abounded. As public and legal concerns<br />
mounted, the food service packaging sector increasingly turned<br />
to biodegradable and compostable plastics and is by far the<br />
biggest application segment for this type of plastic today. The<br />
study “Consumption of biodegradable plastics in Europe 2015 /<br />
2020” [3] revealed that around 80% of the sales were bags and<br />
serviceware like drinking cups or cutlery. Now, however, service<br />
packaging is being hit by new regulations: products made from<br />
biodegradable plastics are currently not exempt from recently<br />
PRIORITIES FOR THE EU<br />
Priorities for the EU Source: [2]<br />
1<br />
2<br />
3<br />
4<br />
For young people, the main priorities for EU action<br />
in the 10 years to come are:<br />
PROTECTING THE<br />
ENVIRONMENT &<br />
CLIMATE CHANGE<br />
67% 1<br />
Women<br />
71%<br />
15-19 yo<br />
70%<br />
IMPROVING<br />
EDUCATION & TRAINING,<br />
including the free movement<br />
of students, apprentices or pupils<br />
56% 2<br />
Men<br />
63%<br />
25-30 yo<br />
64%<br />
… who stayed abroad<br />
61%<br />
…those<br />
still studying<br />
72%<br />
FIGHTING POVERTY ,<br />
… involved in volunteering<br />
ECONOMIC &<br />
60%<br />
SOCIAL INEQUALITIES<br />
56% 3<br />
BOOSTING EMPLOYMENT<br />
AND TACKLING<br />
UNEMPLOYMENT<br />
49% 4<br />
adopted EU legislation on the reduction of certain single use<br />
plastics items in the environment, which is a threat to the<br />
bioplastics industry as a whole. With bans and reduction targets<br />
almost everywhere around the globe, the biggest market for<br />
biodegradable plastics is up for discussion. Future growth<br />
perspectives now rely on how biodegradability will be treated<br />
under the new legislation – and whether such products will be<br />
exempt from reduction measures [4].<br />
Biobased plastics are facing other challenges as well. The<br />
EU Circular Economy policy and its related plastic strategy rank<br />
recyclability and the uptake of recycled materials as priority<br />
number #1 amongst the envisaged measures. The perspectives<br />
of biobased and biodegradable polymers in its #1 market -<br />
packaging - will strongly depend on whether full compatibility<br />
with existing (!) recycling schemes is achieved or not. Products<br />
which are hard to recycle, and where recycled content is hard<br />
to realise will be also reviewed, and changes in design or<br />
materials are likely to occur. As a consequence, the biobased<br />
plastics industry needs to review and re-position itself according<br />
to these heavy-weighing, global drivers (#NewPlasticEconomy).<br />
One element which biodegradable or non-biodegradable<br />
plastic products have in common is the renewable or biobased<br />
content, which usually results in a low carbon polymer profile.<br />
Young people most likely to<br />
see this as a priority are…<br />
Young people most likely to see<br />
this as a priority are those…<br />
… living in small towns<br />
52%<br />
… who have a negative<br />
opinion about the EU<br />
56%<br />
1 In 11 countries more than two thirds of young people believe environment and climate change should be a priority: Denmark, France, Germany, Luxembourg, Austria, Portugal, Sweden,<br />
Belgium, Czechia, Ireland and Spain<br />
2 In 17 countries more than half young people believe that education and training should be a priority at EU level. Netherlands, Hungary, Portugal, Germany, Bulgaria, France, UK, Ireland,<br />
Luxembourg, Austria, Spain, Romania, Latvia, Greece, Denmark, Czechia, Belgium<br />
3 In 20 countries half of young people or more believe that fighting poverty economic and social inequalities should be a priority at EU level. Portugal, Germany, Luxembourg, Greece,<br />
Belgium, Austria, Cyprus, France, Denmark, Spain, Latvia, Hungary, Estonia, Ireland, Bulgaria, Netherlands, UK, Croatia, Malta, Slovenia<br />
4 In 15 countries, half or more of young people believe that boosting employment and tackling unemployment should be a priority at EU level. Belgium, Bulgaria, Greece, Spain, Croatia,<br />
Italy, Cyprus, Latvia, Luxembourg, Hungary, Netherlands, Austria, Portugal, Slovenia, Finland<br />
bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 11
Toys<br />
Greenhouse gas emissions<br />
KgCO 2<br />
e per kg of product<br />
10<br />
Greenhouse 8<br />
gas emissions<br />
KgCO 2<br />
e per kg of product<br />
10<br />
6<br />
4<br />
8<br />
2<br />
6<br />
0<br />
4<br />
Bio-based polymers<br />
Fossil-based polymers<br />
Fossil-based polymers<br />
-2<br />
2<br />
-4<br />
Bio-based polymers<br />
0<br />
0 20 40 60 80 100 120<br />
-2<br />
Depletion of fossil resources<br />
-4<br />
megajoules (10 6 joules) per kg of product<br />
0 20 40 60 80 100 120<br />
Fossil-based polymers include:<br />
polypropylene (PP),<br />
high-density polyethylene (HDPE),<br />
low-density polyethylene (LDPE),<br />
polyethylene terapthalate (PET),<br />
polystyrene Fossil-based (PS), polymers include:<br />
polycarbonate polypropylene (PC). (PP),<br />
high-density polyethylene (HDPE),<br />
low-density polyethylene (LDPE),<br />
Source: polyethylene JRC, 2017 (upper terapthalate panel); (PET), WEF et al., 2016 (lower panel).<br />
polystyrene (PS),<br />
Selling “bioplastics”<br />
polycarbonate<br />
on climate<br />
(PC).<br />
change contributions rather<br />
than biodegradability is not a complete novelty in this industry,<br />
but has hardly Source: been JRC, a 2017 game (upper changer panel); WEF in sales et al., 2016 discussions (lower panel). in<br />
the past. Now, as climate change becomes a number one topic<br />
everywhere from politics to the nursery, new opportunities are<br />
opening up for biobased plastics.<br />
The biobased plastics industry cannot just deliver on CO 2<br />
reduction targets. Looking at toys, and how these are made, it<br />
is becoming evident that a combination of functionalities and<br />
design characteristics are needed to make a fun and functional<br />
toy. The wide spectrum of biobased polymers - polyolefins, PET,<br />
polyesters, PAs, (T)PUs or TPEs, and compounds made thereof<br />
- allow for a wide use of applications, ranging from fiberbased<br />
toys and fillers, soft or hard surfaces, puppets, figures,<br />
games or building blocks and many, many more. Biobased<br />
CO 2<br />
-saving polymers can partly or completely replace the<br />
conventional plastics used for toys in many applications. The<br />
bio!TOY conference has shown that even the initial portfolio<br />
is spectacular, and that there are almost no limits to the<br />
opportunities for to explore partners.<br />
Fusion & Conclusion<br />
For the biobased industry, the development of the toy<br />
application sector holds many opportunities and overall, good<br />
perspectives. Development will be widespread, driven by the<br />
need for so many different toy functionalities, as toy makers<br />
embrace the low carbon and GHG emission profile of biobased<br />
plastics. The toy sector offers a perfect place for storytelling<br />
and for winning over future consumers who are now still in the<br />
nursery - in all segments of plastic use. A partnership between<br />
the biobased industry and the world’s toy makers presents the<br />
opportunity needed to develop sustainable and safe products<br />
and solutions against future threats. And to win parents and<br />
grandparents today and tomorrow.<br />
All in all, this was the basic idea behind the bio!TOY conference.<br />
All those who attended and participated in the conference<br />
agreed that it had successfully distilled this vision into a practical<br />
platform for knowledge exchange and partnering. This first<br />
meeting between the biobased industry and the toy industry was<br />
an important initial step to support and promote transitions in<br />
Bio-based polymers include:<br />
bio-based polylactic acid (PLA),<br />
bio-based polyhydroxyalkanoate (PHA),<br />
bio-based polyethylene (PE).<br />
Bio-based polymers include:<br />
bio-based polylactic acid (PLA),<br />
bio-based polyhydroxyalkanoate (PHA),<br />
bio-based polyethylene (PE).<br />
Depletion of fossil resources<br />
megajoules (10 6 joules) per kg of product<br />
Source: JRC, 2017 [upper panel]; WEF et<br />
al., 2016 [lower panel]. (in: EU ENV Agency<br />
27 Aug 2018 [5])<br />
both industries. Participants were calling for more and we are<br />
ready to serve them.<br />
[1]: Valuing Plastics: The Business Case for Measuring, Managing and<br />
Disclosing Plastic Use in the Consumer Goods Industry, (pdf at tinyurl.com/<br />
valuingplastics)<br />
[2]: http://ec.europa.eu/commfrontoffice/publicopinion/index.cfm/survey/<br />
getsurveydetail/instruments/flash/surveyky/2224 or tinyurl.com/surveyyoung-people<br />
[3]: Kaeb, H.: Market study on the consumption of biodegradable and<br />
compostable plastic products in Europe 2015 and 2020, (editor nova institute,<br />
April 2016), tinyurl.com/study-consumption<br />
[4]: N.N.: Single-use plastics directive fails to acknowledge potential of<br />
biodegradable plastics; (European Bioplastics) tinyurl.com/single-usedirective<br />
[5]: N.N.: The circular economy and the bioeconomy, Partners in sustainability,<br />
https://www.eea.europa.eu/publications/circular-economy-andbioeconomy?mc_cid=d946509efd&mc_eid=5bc8123860<br />
or tinyurl.com/eea-circular<br />
www.narocon.de | www.bio-toy.info<br />
The first bio!TOY conference organized by bioplastics MAGAZINE<br />
together with Harald Kaeb (narocon) took place on 27 and<br />
28 March <strong>2019</strong> in Nuremberg, Germany. The event, which<br />
covered topics ranging from technical and ecological issues<br />
to practical examples in the market attracted 90 delegates<br />
from major players from the entire value chain around the<br />
world, including brands such as Lego, Mattel, Playmobil,<br />
Habermaaß, Ravensburger and Zapf Creation. Companies that<br />
already offer toys made of bioplastics, such as Zoë B, eKoala,<br />
Lego, Bioserie, BioBlo, and TicToys shared their experience.<br />
Speakers and exhibitors from the bioplastics industry included<br />
DuPont, Braskem, Hexpol, Neste, and Total-Corbion, as well as<br />
compounders such as Greendot Bioplastics, Tecnaro and FKuR.<br />
The participants agreed that there is great development potential.<br />
The conference with exhibition was also much welcomed as a<br />
platform for dialogue and cooperation.<br />
Read also the post-bio!TOY press release at tinyurl.com/biotoy-press<br />
Harald Kaeb, Michael Thielen<br />
12 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
Toys<br />
Binabo and other sustainable toys<br />
A success-story<br />
www.tictoys.de<br />
TicToys is a toy manufacturer based in Leipzig, Germany.<br />
Founded in 2011 by Matthias Meister and Tony Ramenda,<br />
the company has since grown from what was simply<br />
a fun idea into a serious player in the international toy market<br />
- and a pioneer in the use of bioplastics to produce toys.<br />
From the very start, TicToys has adhered to its founding principles:<br />
1. Create toys that foster movement and active play<br />
2. Promote creative and open-ended play by simple design<br />
3. Use high quality materials and processing<br />
technologies<br />
4. Only use all natural and renewable materials<br />
5. Produce gender-neutral toys<br />
6. All toys are to be locally „Made in Germany“<br />
The result is a brand with a promises to deliver “Die neue<br />
Spielzeugkultur“ (“The new way to play“).<br />
Holding to these core tenets has meant that is has not<br />
always been easy to participate in today’s fast-changing and<br />
highly competitive toy market. In particular, the fourth on<br />
the list – the company’s determination to use “all natural<br />
and renewable materials“ - presented a major challenge,<br />
when it came to broadening the product range.<br />
Although the company originally produced only wooden<br />
toys, TicToys first came into the contact with bioplastics<br />
during the development of its Tualoop” outdoor game. The<br />
ame is played with two sticks that are used to catch and<br />
throw a ring – the Tualoop – in various ways.<br />
During the product development, the rings were initially<br />
made from wood. However, this soon proved to be the wrong<br />
choice, both due to the rigidity of the material and its high<br />
cost. In search of an alternative, TicToys stumbled across<br />
the possibility of using a bioplastic material and, after<br />
researching the subject, decided in favour of Arboblend ®<br />
compounds. This advanced biomaterial from Tecnaro<br />
(Ilsfeld, Germany) consists of a blend of different biobased<br />
plastics and wood fibres and is therefore one hundred<br />
percent natural.<br />
Many trials and tests with different compounds followed,<br />
with as result a fantastic game – Tualoop was released<br />
in 2013 – that pioneered the use of bioplastics in the toy<br />
industry.<br />
From the very beginning, Tony and Matthias believed in<br />
manufacturing their toys from renewable raw materials -<br />
from the product to the packaging. “Our intention has always<br />
been to encourage sustainable consumer behaviour in this<br />
area as well,” the two explained, who have since brought their<br />
sixth toy creation to market, named Binabo.<br />
“This was by far our most difficult project. We spent five<br />
years working on a single perfect toy construction element<br />
made from bioplastic. The flexible components, which<br />
differ only in colour, can be assembled as desired and allow<br />
unlimited combination options.”<br />
Binabo is also manufactured from a special Arboblend<br />
grade. The material is flexible, extremely stable, free of toxins<br />
and suitable for indoor and outdoor use.<br />
The idea for the Binabo originated from the project to<br />
create a ball that can be juggled barefoot - just as has been<br />
a tradition in Myanmar for 1500 years. The local pastime -<br />
called Chinlone, - is a combination of sport and dance and<br />
is played with a ball traditionally woven from rattan. However,<br />
the bioplastic “Made in Germany” can be used for more than<br />
just for making the Chinlone ball.<br />
“The elements can be simply clicked together to create an<br />
infinite number of movement games: Throwing discs, catching<br />
cups, cones or even a basketball basket are possible. The<br />
colorful chips invite you to construct the most daring figures<br />
and shapes,” explained Tony.<br />
In the end, it almost doesn’t matter what comes out of it.<br />
“It’s about being creative. This is something that nowadays,<br />
children are all too often denied. That’s why we hadn’t originally<br />
planned to include any building instructions.” Children<br />
are more creative than many adults suspect and therefore<br />
do not ask for instructions. However, many parents ask for<br />
instructions, because they do not have enough confidence in<br />
their children’s creativity.<br />
Today, the two entrepreneurs export their toys from the<br />
plant in Leipzig to all over the world. However, they still buy<br />
cardboard boxes for the packaging from ”nearby” Chemnitz.<br />
“Regionality has always been part of our philosophy,” said<br />
Mattias. “Production steps that cannot be implemented<br />
regionally at least remain in Germany,” he concluded. MT<br />
Tualoop (Photo: TicToys)<br />
Levi playing with Binabo during bio!TOY <strong>2019</strong><br />
(Photo: Oliver Reinhardt)<br />
bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 13
Toys<br />
Relaunch of<br />
ocean-safe<br />
beach toys<br />
About 350 million tonnes of plastic is produced<br />
globally every year with approximately 25 % of it<br />
used in packaging, most of which is designed for single<br />
use. (The average North American throws away about 100<br />
kg of plastic each year.) An estimated 32 % of all packaging<br />
leaks out of the system, leading to both land and ocean pollution.<br />
As a result, more than 8 million tonnes of plastic trash<br />
winds up in the oceans annually, adding to the estimated 150<br />
million tonnes that’s currently in the marine environments.<br />
Of even greater consequence is that fact that much of this<br />
debris breaks down over time into tiny particles smaller than<br />
5 mm. These microplastics are found in marine habitats<br />
everywhere on earth, and they don’t biodegrade. According to<br />
5 Gyres, a non-profit fighting global plastic pollution, the 2017<br />
United Nations Clean Seas Campaign estimated that there are<br />
51 trillion microplastic particles in the ocean today—500 times<br />
more than the number of stars in our galaxy. Unfortunately<br />
for the ocean’s ecosystem, marine animals, and even humans<br />
who consume seafood, these marine plastics persist and have<br />
the potential to cause real harm.<br />
So how do we start turning the corner toward products<br />
that are useful without continuing to destroy our oceans?<br />
In 2011, Valerie Lecoeur, founder of Zoë b Organic (Winston<br />
Salem, North Carolina, USA), decided to tackle the problem<br />
right where she found it every summer–on the beach, in the<br />
hands of her kids (cf. bM 02/2011). As a mother of three young<br />
children, it sickened her to see the number of stray shovels<br />
and orphaned, plastic beach-bucket handles washed up on<br />
the shore. So, she decided to use the technology available at<br />
the time to make smarter beach toys that are safer for both<br />
kids and the environment.<br />
compounds<br />
are designed to meet established<br />
certification standards for biodegradation<br />
into carbon dioxide, water, and biomass–thus avoiding the<br />
generation of microplastics and providing the ideal material<br />
for beach toys that accidentally get washed out to sea.<br />
Today Valerie and Zoë b<br />
Organic are grateful to be<br />
partnering with DuPont to<br />
relaunch her Ocean-Safe<br />
Beach Toys in the U.S. this<br />
summer. While technology<br />
continues to evolve, Valerie<br />
remains steadfast in her<br />
mission: “Bioplastics may<br />
not be the solution for<br />
replacing all plastics, but<br />
those that biodegrade in<br />
marine environments are<br />
the perfect replacement<br />
for every beach toy on the<br />
planet.” MT<br />
http://www.zoeborganic.com<br />
ISSN 1862-5258<br />
bioplastics MAGAZINE Vol. 9<br />
Highlights<br />
Fibers & Textiles | 12<br />
Toys | 36<br />
September / October 05 | 2014<br />
... is read in 91 countries<br />
Beach toys by Zoë b<br />
made from PHA, p. 44<br />
Cover-Story<br />
bioplastics MAGAZINE<br />
05/2014<br />
In 2011, Zoë b Organic launched the world’s first<br />
biodegradable beach toys using Mirel, a polyhydroxyalkanoate<br />
(PHA) bioplastic made from corn sugars which meets<br />
established standards for biodegradation in marine<br />
environments. Manufactured in the USA, the toys were sold<br />
online and also picked up by Pottery Barn Kids, among other<br />
retailers. However, disruptions and unfavorable economics in<br />
the product’s supply caused Zoë b Organic to ultimately stop<br />
selling its beach toys.<br />
In 2017, Alterra Plastics, a compounding company operating<br />
out of Seymour, Indiana (USA), focused on the emerging need<br />
for plant-based and biodegradable materials and re-initiated<br />
the development of PHA-based thermoplastic compounds.<br />
In collaboration with DuPont BioMaterials, a new family of<br />
compounds was developed. TerraBio ® is a PHA-based resin<br />
that incorporates Nuvolve Engineered PolySaccharides to<br />
enhance mechanical properties and the overall aesthetics of<br />
derived injection-molded products. With building blocks that<br />
are all plant-based and inherently biodegradable, these new<br />
14 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
Automotive<br />
ORDER<br />
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bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 15
Toys<br />
Baby toys –<br />
safe and<br />
sustainable<br />
Simple, down to earth designs<br />
made from the safest of<br />
biomaterials may be the classic<br />
playthings of tomorrow<br />
The Bioserie brand was created at the end of 2009 as an<br />
initiative of bioplastic enthusiasts eager to use these<br />
exciting new materials to make durable consumer<br />
products. While the first products were phone accessories,<br />
the self-funded Hong-Kong-based venture soon turned to<br />
developing and selling toys. The founders, who are also<br />
parents, wanted to use their know-how to bring to families<br />
useful basics made entirely of biomaterials, that were<br />
smart, fun to play with, and convenient for day-to-day use.<br />
The company decided first to focus on baby toys: logically<br />
speaking, babies are the ones at greater risk when<br />
exposed to traditional plastics. Concern is mounting, both<br />
among medical experts in the pediatrics field and the general<br />
public, about the lack of (sufficient) screening for the<br />
use of harmful chemicals in the toy industry. Since Bioserie<br />
has been committed from the start to using only non-petrochemical<br />
components, they are firmly convinced that they<br />
can answer the needs of the most worried and demanding<br />
clients of the sector: parents of babies and infants.<br />
From idea to product<br />
Building a new product line that works, with only limited<br />
means at their disposal, the brand’s founders have had to<br />
be resourceful.<br />
First, that meant taking into account the limitations of the<br />
material they are working with, which is mostly PLA based.<br />
The costs of the PLA compound are significantly higher<br />
than that of conventional commodity plastics. Injection<br />
moulding cycle times are longer, and it is necessary<br />
to use moulds of very high quality. The material is<br />
fairly rigid and prone to breaking if not managed<br />
properly.<br />
16 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
Toys<br />
Therefore, design ideas had to be screened with all these<br />
factors in mind to determine the shapes that could be used;<br />
and the team had to anticipate potential pain points during<br />
assembly or fitting to minimize later trial and error testing<br />
processes.<br />
Of course, they also had to take into account the price<br />
limit that would be acceptable for consumers. They have<br />
therefore positioned their offering at prices comparable to<br />
toys made from natural materials, such as wood, natural<br />
rubber or eco-fabrics.<br />
They knew from the start that they would not be able to<br />
compete with regular plastics: their objective was to make<br />
no compromises on their value proposition and refuse to<br />
use any petrochemical additives.<br />
Both by necessity, but also because they believe that<br />
quality is better than quantity, Bioserie’s owners decided to<br />
build a line focused on the basic needs of babies, with six<br />
different types of products:<br />
• Stage 1 (babies aged 0-3 months): Two simple toys for<br />
babies to teethe on and to help them grasp (Star Teether<br />
and Interlocking Disks, both available in two colors);<br />
• Stage 2 (babies aged 3-6 months): Two rattles which<br />
encourage observation skills and the discovery of the<br />
cause and effect relationship (one round shaped rattle<br />
and one dumbbell shaped rattle),<br />
• Stage 3 (babies aged 6-12 months): Two types of<br />
stackers which are about matching and learning shapes,<br />
sizes, and improving gross motor skills. Bioserie has<br />
obtained a patent for the design of its Shape Sorting and<br />
Stacking Cube, and their 2-in-1 Stacker has proved to be<br />
one of their most popular items over the past year.<br />
The progressive concept of the product line is<br />
communicated by different colors on the packaging sides<br />
for each developmental stage.<br />
The importance of teamwork<br />
To get to this point, the brand has been fortunate in being<br />
able to gather together a team of motivated and talented<br />
people to support them. The brand owners have worked<br />
with Batug Koprulu, an industrial designer, to formalize<br />
their design ideas and transform sketches into a 3D<br />
reality. They have had the support of Dominic Mak, who is<br />
a renowned biomaterials scientist, as well as endorsement<br />
from leading figures in the toy and nursery industry, such as<br />
Pamela Marcus, who created the now famous Lifefactory<br />
brand, and Jeff Cornelison, who worked for a long time for<br />
Kids II.<br />
Making 100 % biobased toys is no easy game, as<br />
Bioserie discovered, and far more is needed than scientific<br />
knowledge alone. Dedication and enthusiasm is required<br />
from everyone involved in the chain to make it work: the<br />
people with the idea and the people who actually help turn<br />
these ideas into real and effective products.<br />
And the process is one of constant fine-tuning. The first<br />
toy test run was in 2015, a patent process in 2016 was<br />
initiated and since 2017, the company has been creating<br />
its own compound, as a means to increase supply chain<br />
reliability and facilitate scaling up scenarios. Compounding<br />
now takes place at the injection moulding facilities.<br />
By:<br />
Stephanie Triau<br />
Bioserie<br />
The Bioserie team now feels that they have a<br />
CPLA compound that delivers what they wanted: no<br />
petrochemicals, high temperature resistance, a better melt<br />
flow vs. other compounds they have used, consistency of<br />
results across all the different geometries used, good<br />
quality touch and feel results.<br />
That said, they’re always on the lookout for potential new<br />
additives that could enhance the product or make the job<br />
easier or better and are frequently in conversations with<br />
players in the field.<br />
From the product to the consumer<br />
Yes, we’re at a time when the biobased materials trend<br />
is going mainstream. 85% of consumers have stated they<br />
are committed to buying more sustainable products; policy<br />
makers and big brands have also implemented strong<br />
initiatives in this direction.<br />
However, from Bioserie’s perspective, the key selling point<br />
for what they do is chemical safety: over 70% of consumers<br />
actually prioritize health and safety over environmental<br />
concerns.<br />
To communicate their difference vs. other materials<br />
clearly to customers, Bioserie is proud to have received two<br />
exclusive certifications. Their toys are the first and only to be<br />
100 % biobased certified by the USDA (ASTM D6866: no fossil<br />
carbon), and to have obtained MADESAFE’s certification<br />
(MADESAFE is a growing third party certification in the US<br />
which focuses on non-food products and thoroughly screens<br />
each and every chemical used to ensure that they are not<br />
dangerous for human health nor for our environment).<br />
According to Bioserie, biobased products like theirs<br />
should be considered to be “new luxury products”. In<br />
other words, products customers can trade up for in their<br />
particular category, i.e spend more on them and waive the<br />
price concern). Bioserie focusses and delivers on the three<br />
key points that influence the decision process: they have<br />
technical differences (good design), they deliver health and<br />
environmental benefits (a functional performance), and they<br />
allow their buyers them to do their bit for the environment<br />
(we all like to support a good cause, and these toys don’t<br />
use anything that can’t grow again).<br />
www.bioserie.com<br />
bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 17
Toys<br />
By:<br />
Johnny Koch Hansen<br />
Sales Manager<br />
Dantoy<br />
Hobro, Denmark<br />
dantoy (Hobro, Denmark)<br />
has been developing and<br />
manufacturing quality toys in<br />
Denmark for more than 50 years. In<br />
that time, the company has grown into one of the<br />
biggest manufacturers of plastic toys in the Nordic countries.<br />
In February 2018, dantoy launched its new line of BIO<br />
products, which has gained much more attention than<br />
initially anticipated. Today, more than 15% of all dantoy’s<br />
products are made from bio materials, a development<br />
clearly contributing to this toy company’s healthy<br />
sales figures. Located in the middle of Jutland<br />
in Denmark and employing some 50 employees,<br />
most of whom have been with the company<br />
for more than 10 years, dantoy’s production<br />
facilities span an area of 15,000 m 2 . In addition,<br />
dantoy employs a number of affiliated colleagues<br />
who assemble the products at home or at sheltered<br />
workshops. All this says something about dantoy’s<br />
DNA, and the company culture dantoy is known<br />
for.<br />
There is nothing strange about dantoy’s<br />
decision to introduce its new bio line last year.<br />
It is simply a part of the company’s DNA. Ten<br />
years ago, the company’s first products certified<br />
with the Nordic Swan, the official ecolabel of the<br />
Nordic Countries, appeared on the market.<br />
Dantoy’s much-loved scooter, a<br />
product familiar to almost every<br />
child in Denmark, was<br />
the first to bear the<br />
label. Today, more<br />
than 98 % of all<br />
dantoy’s core products<br />
have earned certification and carry<br />
the Nordic Swan Ecolabel and more are on<br />
the way. Dantoy chose to have its products certified<br />
because it was the best way to show the customers that<br />
children can use all these products without any concerns.<br />
Plastic toys licensed for the Nordic Swan Ecolabel must<br />
Danish bio-toys<br />
a success story<br />
Products made from sugarcane are a<br />
natural development for the Danish<br />
toy manufacturer dantoy<br />
comply with the<br />
world’s strictest<br />
requirements for<br />
plastic contents, going far<br />
beyond the Danish law. For instance, products<br />
bearing the Nordic Swan Ecolabel may not contain harmful<br />
substances such as phthalates, perfume, BPA or endocrinedisruptive<br />
substances. All this says much about the high<br />
standard to which dantoy’s products are manufactured. The<br />
world’s first toys to be licensed for the Nordic Swan Ecolabel<br />
were from dantoy. The company received their first licence<br />
for the Nordic Swan Ecolabel as early as in 2010.<br />
The bio product line started with an idea. Like<br />
any other dantoy product, the new line needed<br />
to comply with the company’s strategy and<br />
goals to develop high-quality toys with an<br />
environmental focus. There was<br />
no doubt that dantoy wanted to<br />
create a bio line but achieving the<br />
quality required to meet dantoy’s<br />
high standards proved to be a challenge.<br />
After a few years of struggle and cooperation with<br />
the different raw material suppliers, dantoy found<br />
a raw material good enough for their new bio line:<br />
Braskem’s Green PE, supplied by FKuR. For now, dantoy<br />
is happy to produce its high-quality products in the new bio<br />
18 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
Toys<br />
material, but the company continues to further develop and<br />
improve its bio products on an ongoing basis. At the moment,<br />
dantoy has only one raw material at its disposal to make the<br />
bio products, while it uses more than twenty different raw<br />
materials for its other products. For example, it is currently<br />
not possible to produce the scooter from bio material,<br />
although this remains a long-term goal for the future.<br />
The newest member to join the dantoy family of products<br />
is its Tiny line: bio products especially developed for babies.<br />
Dantoy is the first in the world to make baby products in bio<br />
material, certified with the Nordic Swan. All dantoy products<br />
stand for both high quality and care for the environmental,<br />
so customers can choose between bio or conventional. One<br />
of the company’s goals is to broaden the knowledge of its<br />
products in all its 50 different markets.<br />
In addition to using biobased plastic raw materials for<br />
the bio and Tiny lines, dantoy tries to minimise the impact<br />
of its operations on the environment. The company has<br />
therefore implemented eco-friendly processes to manage<br />
the consumption of energy, water and raw materials and to<br />
prevent the possibility of accidental releases or emissions via<br />
the manufacturing process.<br />
It is important for dantoy to be the best, and to produce<br />
the best toys possible, so that children around the world can<br />
play safely every day, while they develop their motor skills,<br />
learning skills, social skills etc. This is what drives dantoy<br />
forward and also the main reason the company chose to<br />
certify its products with the Nordic Ecolabel 10 years ago.<br />
It’s also why it has now chosen to produce the new Tiny line.<br />
www.dantoy.dk<br />
14 –15 NOVEMBER <strong>2019</strong>, MATERNUSHAUS, COLOGNE, GERMANY<br />
The BIOCOMPOSITES CONFERENCE COLOGNE is the world‘s largest conference<br />
and exhibition on the topic. This conference offers you the unique opportunity to gain a<br />
comprehensive overview of the world of biocomposites in Cologne.<br />
The conference at a glance:<br />
• More than 250 participants and 30 exhibitors expected<br />
• Innovative raw materials for biocomposites – Wood, natural fibres and polymers<br />
• Market opportunities for biocomposites in consumer goods (such as music instruments,<br />
casing and cases, furniture, tables, toys, combs and trays) as well as rigid packaging<br />
• Latest development in technology and strategic market positioning<br />
• Trends in biocomposite granulates for injection moulding, extrusion and 3D printing<br />
• Latest developments in construction and automotive<br />
Conference Manager<br />
Dominik Vogt<br />
Phone: +49(0)2233-48-1449<br />
dominik.vogt@nova-institut.de<br />
Organiser:<br />
Sponsor Innovation<br />
Award:<br />
VOTE FOR<br />
the Innovation Award<br />
“Bio-based Material<br />
of the Year <strong>2019</strong>”!<br />
www.nova-institute.eu<br />
www.coperion.com<br />
www.biocompositescc.com<br />
bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 19
Toys<br />
Bioplastic<br />
items for kids…<br />
a real bet<br />
Speaking at the inaugural bio!TOY Conference was a<br />
major event for eKoala, said Beatrice Radaelli, cofounder<br />
of the company. bioplastics MAGAZINE talked<br />
to her about what it took to start a bioplastics toy company.<br />
bM: Why was the bio!TOY such a special event for you?<br />
Beatrice: Speaking at bio!TOY was a great opportunity for<br />
us to think and finally to talk about what we have done and<br />
the results we have achieved so far.<br />
bM: How did it all start?<br />
Beatrice: After we started our<br />
project, and officially founded the<br />
company in 2014, we spent more<br />
than two years doing research<br />
and development work. As a first<br />
result, we could officially launch<br />
the first eKoala line of products<br />
at the end of 2016.<br />
bM: What challenges did you<br />
face and how did you master<br />
them?<br />
Beatrice: One of the most<br />
difficult issues was finding<br />
the right material to obtain<br />
a good and stable product.<br />
We were looking for a material<br />
that was suitable for injection moulding made using<br />
the highest possible percentage of raw materials from<br />
renewable resources. In addition, the material had to be<br />
biodegradable as we felt that to gain the full advantages of<br />
using a bioplastic, this should be both renewably sourced<br />
and biodegradable.<br />
bM: Who were your partners?<br />
Beatrice: After contacting quite a few bioplastic<br />
manufacturers around the world, we finally discovered<br />
Mater-bi. The fact that the material is made by an Italian<br />
company also allowed us to label our products ‘100 % Made<br />
in Italy.’<br />
bM: And then you could “hit the road” and start production?<br />
Beatrice: After finally deciding in favour of MaterBi, it<br />
still took a while to produce our item number 1. It was a<br />
mixture of happiness, pride and relief when we held it in<br />
our hands for the first time. Item number 1 is still on our<br />
desk, reminding us every day of all the hard work we did<br />
to get to it.<br />
eKaboom<br />
20 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
Toys<br />
Beatrice Radaelli and her brother Daniele Radaelli<br />
Interview with Beatrice Radaelli (Interview: Caroli Buitenhuis,<br />
Green Serendipity)<br />
bM: How was the market entry?<br />
Beatrice: The following two years (2017-2018) were<br />
needed to test the products with the customers. It was a<br />
hard start. People are not always aware of what bioplastic<br />
really is and the commonly used term “bioplastic” does<br />
not really help to identify a material that is different from<br />
traditional plastic. That’s one of the reasons why accurate<br />
and clear communication is really important when dealing<br />
with bioplastic products.<br />
bM: How are sales today?<br />
Beatrice: In the years since, we have built up and<br />
strengthened the distribution in Italy. Our products are<br />
available in more than 300 shops all around Italy today. But<br />
we also worked to spread our distribution internationally.<br />
We now have customers in Germany, Scandinavia and<br />
the Baltics, Poland and other Eastern countries. We are<br />
discussing possible collaborations with distributors in the<br />
USA and in China.<br />
bM: Your first line consisted of baby food and teething<br />
products, What came then?<br />
Beatrice: Each year, we invest in the development of<br />
new products to broaden the portfolio. After introducing<br />
our basic line, last year we launched the first eKoala toy.<br />
eKaboom is a multifunctional stacking toy, that can also<br />
serve as a percussion instrument. Currently we are working<br />
on two new toys for <strong>2019</strong>.<br />
bM: Are you satisfied?<br />
Beatrice: The numbers are not very high yet, but we<br />
keep on working to increase our areas of distribution. It’s<br />
really hard work, especially for a tiny company like ours.<br />
Somebody at the bioToy! conference said the bioplastics<br />
have not made him rich…nor us, either.<br />
bM: Some final words?<br />
Beatrice: But we truly believe in what we are doing and<br />
we are still enthusiastic about that. We will keep on working<br />
and studying because we strongly believe it’s high time to<br />
make a change and we know we are on the right path. MT<br />
www.ekoala.eu<br />
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THE NATURAL UPGRADE<br />
bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 21
Toys<br />
Consumer<br />
attitudes<br />
and bioplastics for Eco-babies &<br />
Bio-parenting<br />
By:<br />
Clara Blasco, Design & Trend Researcher at Consumer Insights<br />
Ana Ibáñez, Bioplastic Researcher at Innovative Materials & Manufacturing<br />
Paco Varela, European Project Manager at R&D Department<br />
María Costa, R&D Director<br />
AIJU, Technological Institute for children’s products and leisure<br />
Ibi, Spain.<br />
Environmental protection is a challenge that cannot be<br />
faced by political and economic means alone. As society<br />
at large awakens to this task, the children’s products<br />
sector must have the commitment to contribute by incorporating<br />
environmental values in toy production and consumption.<br />
Companies have the responsibility to create innovative strategies<br />
to enhance sustainability. In this respect, the owners of<br />
companies in the children’s products industry are key stakeholders<br />
in implementing and accelerating the biobased economy.<br />
Understanding parents’ requirements and attitudes and<br />
implementing research into biobased plastics are two ways to<br />
face this new reality.<br />
AIJU, the Technological Institute for Children’s Products<br />
and Leisure — a European research institution which aims to<br />
boost research, development and technological innovation in<br />
children’s products — have a long history of work on issues of<br />
sustainability. Among other competences, AIJU has expertise<br />
in studies with children and families as users and consumers<br />
as well as research into new plastic materials to be applied in<br />
the children’s sector.<br />
New parents, new values<br />
The term sustainability means protecting the environment<br />
and its natural resources in order to maintain an ecological<br />
balance. In this respect, society is acquiring greater awareness<br />
of issues related to the environment that are, now more than<br />
ever before, influencing the purchasing decisions of today’s<br />
new parents — the millennials.<br />
Millennials are the generation of people who reached young<br />
adulthood in the early twenty-first century, and as parents they<br />
have new values and preferences. Families are aware of social<br />
challenges: society has undergone the so-called fourth wave of<br />
feminism, parents are demanding effective work-life balance<br />
policies, and they are also promoting equality and denouncing<br />
gender stereotypes. Beyond these issues, society has been<br />
becoming more activist. On the other hand, new parents are<br />
aware of environmental challenges such as climate change<br />
and plastic pollution. There is also an increasing concern<br />
about air pollution. Parents want to keep their children safe<br />
by using products that help create a healthier environment for<br />
their babies. It is also relevant that many new parents want to<br />
protect children from consumerism. They have a new concept<br />
of consumption which is defined by welcoming practices that<br />
reduce consumerism and the rise of use of second-hand<br />
articles and renting activities.<br />
Although each new parenting style understands<br />
sustainability differently, a sensitivity towards this concept<br />
is common to all of them. Whereas some parents only look<br />
for essential products that are respectful to people and the<br />
planet — products they can justify purchasing — other profiles<br />
understand that a product is sustainable when is adaptable for<br />
different ages and the product has a long life. There are other<br />
kinds of parents who seek products with an eco concept that<br />
is linked with quality, exclusivity, and luxury, whereas others<br />
will buy eco products if they offer the healthiest option in the<br />
market.<br />
The understanding of social changes, together with an<br />
awareness of governmental policies and the campaigns being<br />
initiated by large companies across several sectors, highlights<br />
the need for an in-depth reflexion in the children’s sector.<br />
Sustainability approaches for the toy industry<br />
Sustainability can be approached in several ways — not<br />
only by introducing eco-friendly materials, but by employing<br />
manufacturing processes, carrying out campaigns, or<br />
designing play proposals that are in harmony with improving<br />
people’s lives and the health of our planet. The text below<br />
lays out a series of measures and practices that companies<br />
targeting the children’s market can apply to their strategic<br />
definition, product development, and marketing strategies in<br />
order to achieve a meaningful and respectful impact.<br />
New and old materials that make the difference<br />
Toy companies have at their disposal a range of materials<br />
that are environmentally friendly, and are perceived as such<br />
by consumers. If a single material can be named as iconic,<br />
22 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
Toys<br />
Figure 1. From left to right: BIOROT, FLEXIROT, ROTELEC and<br />
NATURBIOFITOPLAG demonstrators of the mentioned biobased projects.<br />
it is most certainly that of wood. Nevertheless, not just any<br />
wood will be accepted. Nowadays, society is highly informed,<br />
so parents will look for toys made with wood from forests<br />
with an FSC (Forest Stewardship Council) certification — the<br />
well-known seal that guarantees the correct management<br />
of forest resources. There are other interesting options, such<br />
as cardboard. Toys made of recycled cardboard are readily<br />
perceived as being eco, as society is generally aware of this<br />
material and understands how it can be given a second use.<br />
Regarding cork, the use of this material is seen in several<br />
toy categories — not just in building blocks to stack, but in<br />
more technically complex proposals, such as building bricks,<br />
construction games, board games, vehicles, ride-ons and<br />
sensory toys for toddlers. For years now, bamboo has been<br />
used to manufacture sustainable toys. Companies such as<br />
Hape or Janod introduced it to offer a distinctive solution for<br />
new products.<br />
Organic fabric, especially organic cotton, is the most widely<br />
known eco-friendly fabric. At present, its use has extended<br />
beyond children’s clothes and textiles and it is now used in<br />
childcare products — one example is the Kikadu play gym.<br />
It is even possible to find it in products that are not in actual<br />
contact with children, such as children’s mobiles. This shows<br />
that organic fabrics are not only valued for being good for<br />
humans, but for being good for the planet too. Furthermore,<br />
toys made from natural rubber have been well received by<br />
parents — those with children aged up to 3 years have the<br />
greatest number of products available, a wide range of articles<br />
— including bath toys, rattles, teethers, and sensory toys —<br />
have been designed for this target. The reason behind it being<br />
well received by parents is partly motivated by the unified<br />
communication strategy (conducted by the companies that<br />
use it) of its origin and its environmental benefits.<br />
Among all these possibilities, there are also interesting<br />
opportunities for the plastic toy industry. Nowadays, the<br />
bioplastics industry is becoming more present in the children’s<br />
sector, from toys to childcare products. Making products with<br />
recycled plastic is one of the options which prove the potential<br />
of a new era of plastics. One example is the Ocean Bound<br />
Plastic Tide Pool Set by Green toys, which is made with recycled<br />
plastic that has been collected from global communities that<br />
lack waste-collection infrastructure. Another is the Bugaboo<br />
stroller brand, which uses recycled PET plastic to manufacture<br />
the fabrics of the Bugaboo Fox.<br />
Another alternative is biocomposite plastics, and it is<br />
possible to find toys made from a combination of natural fibres,<br />
or wood flour mixed with recycled, biodegradable, or biobased<br />
plastics, such as the Dump truck by Luke’s toy factory, which<br />
is made from recycled organic fibres (sawdust from furniture<br />
factories) and recycled plastic.<br />
Among these alternatives, the toy industry is beginning to<br />
opt for biobased plastics — plastics made from plant-based<br />
materials — which may be non-biodegradable, biodegradable,<br />
or compostable. Both well-established and new companies<br />
are introducing toys with these materials in their product<br />
portfolio — such as Dantoy, who have launched a brand-new<br />
“I’m green” line of bioplastic products made from at least<br />
90% sugarcane. We also encounter brands such as eKoala or<br />
BiOBUDDi, who are building their entire brands — and their<br />
value proposition — on sustainable values.<br />
Research projects about bioplastics in the toy<br />
industry<br />
In this context, the Technological Institute for Children’s<br />
Products and Leisure (AIJU) in Spain has, over the past<br />
ten years, been studying the possibility of incorporating<br />
biodegradable materials in the manufacture of toys and other<br />
consumer products by means of injection (BIOTOYS Project,<br />
2008), rotational moulding (BIOROT project, 2011, ROTELEC<br />
2013 or FLEXIROT, 2018) or blowing (NATURBIOFITOPLAG)<br />
(Figure 1). In these projects, the traditional material is replaced<br />
by biobased material.<br />
Another noteworthy example was the LIFE MASTALMOND<br />
project (2011–2014) (Figure 2), in which the objective was the<br />
development of new masterbatches, or colour concentrates,<br />
based on biodegradable thermoplastics (PLA, PHB, starchbased<br />
polymer), containing a natural waste product — almond<br />
shells. This filler provides lightness while maintaining adequate<br />
hardness and rigidity levels according to industrial standards<br />
and is easily processed, which makes it especially interesting<br />
in the field of non-structural compound materials from an<br />
economic point of view, in addition to its low environmental<br />
impact.<br />
bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 23
Toys<br />
According to the latest market data compiled by European<br />
Bioplastics in cooperation with the research consultancy nova-<br />
Institute, global bioplastics production capacity is set to increase<br />
from around 2.11 million tonnes in 2018 to approximately 2.62<br />
million tonnes in 2023. Furthermore, it is a fact that bioplastics<br />
are being used in an increasing number of markets, from<br />
packaging, catering products, consumer electronics, toys, the<br />
automotive industry, agriculture/horticulture, to textiles and a<br />
number of other industries. Despite these positive prospects,<br />
the high cost and difficulty of achieving certain mechanical or<br />
thermal properties with currently existing biobased materials<br />
are some drawbacks that have arisen.<br />
Currently, AIJU is working on two projects related to<br />
biodegradable materials. The first, the B-PLAS project, whose<br />
objective is to achieve an automated treatment plant that<br />
enables food waste, WWT (Waste Water Treatment) sludge,<br />
and other organic waste to be cheaply and efficiently converted<br />
into polyhydroxyalkanoates (PHA), a biodegradable plastic of<br />
biological origin, useful for packaging, one-use articles, toys,<br />
among other uses. The second, Becoming Green, aims to<br />
develop and improve some properties (thermal or mechanical)<br />
of biobased plastics to adapt them to the quality and safety<br />
requirements of consumer products, toys, and the household<br />
sector.<br />
The power of the play proposal: sustainable topics<br />
The TrendGallery at the Spielwarenmesse Toy Fair is a<br />
platform which presents the latest toy trends with new toys<br />
and know-how for the industry. In 2018, it announced the new<br />
trend Explore Nature, which continues to be important. This<br />
trend is about encouraging children to discover nature and its<br />
inhabitants for themselves and experience and investigate the<br />
world with all their senses.<br />
Children learn about the adult world through play. Themes<br />
such as fruits, vegetables, gardening, and the observation<br />
and exploration of the environment are great for this. Parents<br />
really perceive them as perfect ways to instil good values<br />
related to sustainability. It is also possible to raise awareness<br />
by introducing topics related to recycling. Toy recycling trucks<br />
have been seen before, but now the theme is being used in<br />
board games, dolls, ride-ons and other toy categories as well.<br />
Gentle manufacturing processes: do it and<br />
communicate it<br />
Beyond positively valuing sustainable products, new parents<br />
seek companies which are consistent in all their actions — not<br />
only by introducing eco-friendly materials and themes, but<br />
also the manufacturing process involved, which is obviously<br />
a relevant aspect when analysing whether a toy company is<br />
offering sustainable alternatives for the children’s sector.<br />
One possibility is to employ eco-friendly processes. This<br />
means using manufacturing processes that are sustainable<br />
or respectful to the environment, renewable energy sources,<br />
meeting safety standards, having environmental certifications,<br />
or creating healthy work environments.<br />
Moreover, it is possible to reinforce the concept of<br />
sustainability by communicating the social value which the toy<br />
brings to the market. This means taking into consideration not<br />
only the “made in”, but also the “made by”, which is crucial.<br />
Some companies are deciding to manufacture in countries<br />
and areas where they can actually have a positive impact on<br />
the community, helping specific people in need. These actions<br />
are also perceived as sustainable.<br />
Children’s companies should communicate these good<br />
practices to the final consumer. Those which are most<br />
conscious of this aspect are involved in designing specific<br />
self-explanatory icons and graphics to be included in their<br />
packaging, introducing sustainable values in their claims, and<br />
creating sustainable manifestos or environmental campaigns<br />
supporting reforestation or endangered species by donations<br />
to NGOs and non-profit organisations.<br />
Conclusion<br />
There are several ways to implement changes and strategies<br />
into children’s products and marketing campaigns in order<br />
to be able to achieve improvements in the sustainability of<br />
businesses in the children’s sector. In this sense, toys are a<br />
powerful tool to educate the society of the future by opting for<br />
materials and processes that are more respectful of people<br />
and the environment, and, moreover, by generating play<br />
proposals related to helping children acquire an ecological<br />
vision of the world.<br />
Today’s new parents — millennials that are becoming<br />
mums and dads — are more aware of their contradictions as<br />
consumers and feel the need to act. They seek to bring up their<br />
children with sustainable products in multiple areas — such<br />
as fashion, food, and toys — more so now than ever before. The<br />
eco concept in toys will grow in importance for many years!<br />
www.aiju.info<br />
Figure 2. Ride-on toy<br />
(top) and furniture<br />
(bottom) performed with<br />
MASTALMOND biobased<br />
masterbatches.<br />
24 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
Toys<br />
Toymakers find many paths to<br />
sustainability<br />
Toys are one of the most<br />
competitive consumer<br />
markets. Parents have a<br />
myriad of choices from hundreds<br />
of manufacturers. In the past decade<br />
several toy companies have distinguished themselves in<br />
a crowded marketplace by offering toys made with materials<br />
created to lighten their environmental impact.<br />
Successful companies convey specific value propositions<br />
for their products that allow consumers to understand<br />
how these products can help contribute to a more<br />
sustainable world.<br />
Green Dot Bioplastics (Emporia, Kansas, USA) is proud to<br />
have worked with award winning toymakers, creating 100%<br />
plant-based biocomposites for plastic toys. And, they have<br />
helped to make toys designed to biodegrade when their<br />
useful life has ended. “We’re also excited to be working with<br />
companies seeking to make toys that consumers already<br />
know and love more sustainable by reducing non-renewable<br />
resources used in its production,” says Kevin Ireland,<br />
Communications Manager at Green Dot Bioplastics. “We<br />
think that all of these strategies are beneficial, and believe<br />
that consumers will respond positively when presented with<br />
a clear and accurate value proposition. It’s not enough to<br />
simply say a product is ‘greener,’ brand owners must tell<br />
consumers how toys are more sustainable and why this<br />
matters.”<br />
Understanding material properties and the environmental<br />
advantages of bioplastic materials is a crucial first step<br />
for both product development and marketing.<br />
Bioplastics made from plant-based materials<br />
decrease dependence on fossil resources, and<br />
can lower GHG emissions. Biodegradable<br />
bioplastics can serve as an integral role in<br />
a closed loop system, where<br />
feedstocks are returned<br />
to nature after their<br />
useful life has ended. In<br />
addition, bioplastics are free<br />
from toxic plasticizers<br />
that parents seek to<br />
avoid, like petroleumbased<br />
phthalates and<br />
bisphenol A.<br />
Not all of these features may be beneficial<br />
to all consumers. For instance, a biodegradable toy<br />
may not be compelling if industrial composting is not<br />
available or if the composting facilities are not willing to<br />
take biodegradable plastics. Environmental claims do not<br />
equate to environmental benefits if consumers are not able<br />
parts.<br />
to take advantage of them.<br />
While some companies have focused on<br />
creating toys that are made completely<br />
from renewable plant-based materials,<br />
or are completely biodegradable, others<br />
focus on making their products more<br />
sustainable incrementally – adding<br />
renewable materials like plant-based<br />
fibers and starches to petroleum-based<br />
plastics. These fillers and fibers can<br />
decrease non-renewable petroleumbased<br />
feedstocks by more than half, and<br />
can imbue a more natural aesthetic to plastic<br />
This incremental approach can also make a compelling<br />
value proposition for consumers. Substituting fibers,<br />
starches, or plant-based polymers for fossil-based<br />
feedstocks can have significant environmental advantages.<br />
For instance, according to the United States Environmental<br />
Protection Agency, reducing petroleum-based feedstocks<br />
by just 10 % can save 280 million barrels of oil a year,<br />
reducing CO 2<br />
emissions equivalent to the sequestration of<br />
100 hectares (250 acres) of forest.<br />
Toymakers continue to be on the vanguard of creating safer,<br />
more sustainable plastics. “At Green Dot we are committed<br />
to serving their needs with plastics that are designed to<br />
decrease the use of petroleum-based feedstocks, increase<br />
the use of plant-based feedstocks, encourage the use<br />
of reclaimed and recycled feedstocks, and enhance the<br />
performance of biodegradable feedstocks,” Kevin adds.MT<br />
www.greendotbioplastics.com<br />
bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 25
Toys<br />
Cooler than wood.<br />
Better than plastic.<br />
How an inconspicuous building brick from<br />
Austria has set out to conquer the world.<br />
The story of Bioblo started in summer 2014 when plastics<br />
expert Hannes Frech had a random encounter with<br />
marketing man Stefan Friedrich in the small town of Tulln,<br />
Lower Austria. Stefan, who was really looking for a suitable<br />
material to bring his idea of a brick-based furniture system<br />
to life, was immediately fascinated by the 12 by 2.4 by 0.8 cm<br />
building brick that Hannes pulled from a drawer during their<br />
very first meeting.<br />
Hannes Frech, who was – and still is to this day – heading<br />
the technical laboratory of the Institute of Natural Materials<br />
Technology within the Department of Agrobiotechnology at IFA<br />
Tulln, had constructed the then-unnamed brick for his daughter<br />
a couple of years prior to the encounter. Little did he know that<br />
the very same brick would embark on such a successful and<br />
far-reaching journey.<br />
In September 2014, Bioblo was born – not yet as a company,<br />
but as a brand. The two men added a third one to the core team:<br />
Dietmar Kreil, who Stefan Friedrich had come to know as one of<br />
Austria’s finest art directors during their common employment<br />
at Viennese advertising agencies DDB Tribal and Jung von Matt.<br />
Stefan came up with the Bioblo name, Dietmar designed the<br />
logo, and the very first boxes were sold for Christmas via the<br />
company’s webshop.<br />
Broadening the horizon<br />
The early customers’ feedback being<br />
overwhelmingly positive, Bioblo soon extended<br />
their reach into kindergartens and schools,<br />
a channel that is not only interesting in itself<br />
but also as a multiplier for B2C sales. The<br />
rationale behind this is that kids<br />
tend to recommend the toys<br />
they like in kindergarten to<br />
their parents at home. Early<br />
distribution partners in this<br />
field included the Austrian<br />
companies Schmiderer &<br />
Schendl, Höller Spiel and<br />
Lipura. Shortly after the<br />
official foundation of the company<br />
“Bioblo Spielwaren GmbH” in May 2015<br />
another important partnership was formed<br />
when European distribution rights were<br />
signed over to “Wiener<br />
Spielkartenfabrik<br />
Ferdinand Piatnik &<br />
Söhne”, a traditional Viennese<br />
manufacturer of playing cards, board games and puzzles, and a<br />
long-standing player in the toy market. Together, an expansion<br />
plan was developed that consequently brought Bioblo to France,<br />
Germany, Canada, the UK, Poland, Hungary and many other<br />
markets.<br />
Form follows function. Material follows Form.<br />
So what is special about Bioblo? The company’s unofficial<br />
slogan “Cooler than wood. Better than plastic.” actually<br />
describes it quite well: The unique honeycomb structure that<br />
seems to appeal to children more than the usual wooden blocks<br />
can only be accomplished by means of injection moulding,<br />
which in turn requires a mouldable material. This is where Bio-<br />
Fasal, the highly sophisticated wood and plastics composite<br />
behind Bioblo, enters the stage. The composite, which has<br />
been developed by the above-named institution over a period<br />
of almost 20 years, combines the best characteristics of “both<br />
worlds”: On the one hand, the sustainability, look and feel of<br />
wood; on the other hand, the durability and processability of<br />
plastics. Add to that the ecological benefits of bioplastics over<br />
fossil-based plastics, and you have already gathered more<br />
than enough selling points in a world that is increasingly<br />
environment-minded.<br />
Success comes with awards – and<br />
vice versa<br />
Bioblo soon discovered the relevance<br />
of certificates and awards to the<br />
quality-minded parents. This is why<br />
the bricks were tested extensively<br />
to document the absolute absence<br />
of heavy metals, bisphenol A, BPA,<br />
plasticisers and other potentially harmful<br />
substances. As a result of these efforts,<br />
Bioblo was the very first toy brand to be<br />
awarded the Austrian “Umweltzeichen” as well as<br />
the German “Blauer Engel” certificate, which last<br />
year celebrated its 40 th anniversary making it THE<br />
oldest and one of the World’s most trusted ecolabels.<br />
26 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
Toys<br />
Toys<br />
Process PLA<br />
with Improved<br />
Molecular Weight<br />
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In case you ever asked yourself how we can prevent our<br />
children from spending their entire days pinching, zooming<br />
and swiping on their smartphones, Bioblos might be just the<br />
answer. Building with their own two hands not only drives<br />
away our kids’ boredom but actively promotes their handeye<br />
and hand-hand coordination. It enhances their physical<br />
and mechanical understanding, trains their concentration<br />
and improves their patience, stamina and ability to deal with<br />
frustration (for example when the cat knocks everything over).<br />
Not surprisingly, building with friends, classmates, parents<br />
or siblings is even more fun – and it promotes team spirit<br />
and communication skills beyond the scope of WhatsApp and<br />
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bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 27
Cover Story<br />
You never<br />
forget your<br />
first car<br />
Especially not your first<br />
eco-friendly car!<br />
By:<br />
Erik Petraschek<br />
Owner<br />
Ferbedo Kinderfahrzeuge<br />
Fürth, Germany<br />
The bioplastic ride-on truck made by Fürth, Germanybased<br />
FERBEDO was one of the product innovations<br />
introduced at the Spielwarenmesse <strong>2019</strong>, the<br />
International Toy Fair in Nuremberg, Germany. In this<br />
article bioplastics MAGAZINE presents the company behind<br />
this product and the challenges of using bioplastics to<br />
produce it.<br />
Ferbedo Kinderfahrzeuge was founded in 1898 and is one<br />
of many German medium-sized champions who, having<br />
carved out a niche for themselves, have been able to hold<br />
their own against the big players in the market through<br />
innovative thinking and hard work. For many years now, the<br />
company has produced ride-on toys for toddlers aged 12<br />
months and older, and go-karts. The realistic design and<br />
high-quality workmanship of the company’s range of blow<br />
moulded ride-on vehicles have made these particularly<br />
popular choices for children. The ride-ons, featuring such<br />
details as LED lighting, whisper tires with individual wheel<br />
rims and textile or leather seating, are manufactured<br />
in particular for automobile OEMs (such as Audi, MAN,<br />
Jaguar, Volvo) and sold via their dealer networks. Ferbedo<br />
has also been producing beautifully made pedal go-karts<br />
for many years. These - and Ferbedo’s own ride-on toys -<br />
are available directly from the manufacturer.<br />
The company is keenly aware of its responsibility for<br />
the environment and listens to what its customers say. A<br />
few years ago, Ferbedo started exploring how it could best<br />
continue making its much loved, highly popular plastic toy<br />
products while at the same time reducing their impact on<br />
the environment to an ecologically compatible level.<br />
The first step is to manufacture products that are as<br />
appealing as possible. Ferbedo succeeds in this almost too<br />
well, as very often, customers pass the ride-on which they<br />
purchased for one child down to others in the family. It’s one<br />
of the best approaches to sustainability: crafting products<br />
with lasting quality and appeal. Nevertheless, Alexander<br />
Bacsics, Managing Director of Ferbedo, was eager to think<br />
about an alternative to the plastic materials currently used.<br />
Bacsics: “Demand from the market was still low two years<br />
ago, when the topic first came up for us, but we noticed that<br />
the connection between plastics and the environment was<br />
increasingly being addressed in the media. We also wanted<br />
to distinguish ourselves clearly from the flood of cheap<br />
products from China and offer retailers and consumers an<br />
additional selling point.”<br />
After researching the topic, Ferbedo discovered the<br />
existence of Green PE, which is derived from sugar<br />
cane. Use of this material not only cut back on the<br />
consumption of petroleum-based plastic; one tonne<br />
of the biobased plastic could store up to 3 tonnes of<br />
CO 2<br />
. It was also important that the new material,<br />
like the one already in use, met all the existing<br />
standards. Bacsics: “Our products are used by<br />
children from about one year of age onward.<br />
Inevitably, there will be mouth contact - a<br />
toddler may lick on the ride-on, for example -<br />
or some other unusual kind of close contact<br />
will occur. We can reassure the parents: The<br />
new biomaterial fulfils all relevant standards<br />
and is therefore safe for our youngest<br />
customers”.<br />
In FKuR (Willich, Germany), a producer<br />
and distributor of biobased materials,<br />
Ferbedo has found a partner able to<br />
provide outstanding support, especially<br />
in the initial phase, with the expertise<br />
to offer the right answers to questions.<br />
Ferbedo found it extremely easy to use the<br />
material. No special preparation and, above all,<br />
no modifications to the existing machines were<br />
necessary. It was decided to start with the<br />
Ferbedo ride-on truck - the only children’s<br />
ride-on truck worldwide. Children are<br />
thrilled and fall in love with it immediately<br />
because of its size and design. The truck is also<br />
available as a fire engine, complete with a functioning siren<br />
and flashing blue light.<br />
Ferbedo started producing with the environmentally<br />
friendly material right away. After heating up the machine<br />
and running a few cycles, the production operators had<br />
28 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
Cover Story<br />
found the perfect setting for the machine. The parameters<br />
had to be adjusted only slightly after which the new<br />
material could be used without any problem. Bacsics: “We<br />
were happily surprised by the result. The surface of the<br />
articles with bioplastic corresponds to that of petroleumbased<br />
products. Sometimes we could even observe a slight<br />
improvement in the surface structure!”<br />
Even though Ferbedo’s ride-on toys regularly get passed<br />
down in families, their robustness notwithstanding, there<br />
comes a time when even these toys reach the end-of-life.<br />
The bio ride-on truck can then be recycled together with<br />
conventional PE. If the car ends up in a waste-to-energy<br />
incineration plant, the bio-PE becomes a renewable energy<br />
source. The solar energy stored in the biobased plastic can<br />
then be exploited without releasing additional CO 2<br />
into the<br />
atmosphere.<br />
The interest shown by customers at the International Toy<br />
Fair in Nuremberg earlier this year was enormous. Ferbedo<br />
has definitely tapped into the mood of the times! The higher<br />
price of the material compared to conventional PE remains<br />
something of an obstacle, as this has not yet been fully<br />
accepted by customers. However, Ferbedo assumes that,<br />
as their use becomes increasingly widespread, the cost of<br />
bioplastics will eventually fall to a level comparable with oilbased<br />
plastics.<br />
Then, at last, there will be nothing<br />
to hinder the breakthrough of this<br />
material. Today’s youngsters<br />
will be able to remember their<br />
first sustainable car for the rest<br />
of their lives!<br />
6 th PLA World Congress<br />
19-20 MAY 2020 MUNICH › GERMANY<br />
organized by<br />
www.pla-world-congress.com<br />
www.ferbedo.de<br />
organized by<br />
Co-organized by Jan Ravenstijn<br />
Save the Date<br />
02-<strong>03</strong> Sep 2020<br />
Cologne, Germany<br />
www.pha-world-congress.com<br />
bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 29
Injection Moulding<br />
Optimizing PLA for<br />
injection moulding<br />
Founded in 2014, Arctic Biomaterials Oy (ABM) from<br />
Tampere, Finland is now divided into two segments:<br />
Medical materials and Technical materials.<br />
On the medical side of the business, ABM offers innovative<br />
raw materials for bioresorbable implant applications such as<br />
anchors, pins and screws. This market has never before seen<br />
materials with loadbearing properties as high as those in these<br />
new materials developed by ABM. This is due to the resorbable<br />
glass fiber that ABM has developed.<br />
This article, however, will introduce three of the company’s<br />
new Technical materials. The background and motivation for<br />
these innovations is the willingness to contribute to efforts to<br />
decrease global warming and to enable the use of sustainable<br />
solutions in an increasing number of applications. These<br />
materials allow brand owners to design products with a lower<br />
carbon footprint, and hence to contribute to the sustainable<br />
targets that countries have globally committed to. ABM<br />
previously introduced a degradable glass fiber for use<br />
as reinforcement for biopolymers, for which the<br />
company received the 2018 “Bioplastic material<br />
of the year” award (from nova Institute). In this<br />
article, the focus will be on new materials without the<br />
degradable glass reinforcement. ABM has adopted a<br />
global approach to the market.<br />
The three different materials that are introduced here are<br />
all PLA-based materials. The end-of-life options for these<br />
materials are basically the same as for fossil-based plastics,<br />
i.e., incineration or recycling, albeit with the addition of industrial<br />
composting, depending on the applications. Through industrial<br />
composting, the materials will be transformed into biomass<br />
and CO 2<br />
. This CO 2<br />
will eventually be absorbed back by the plants<br />
via photosynthesis, thus closing the carbon cycle.<br />
ABM also works with other biomaterials such as PBS,<br />
PHB, starch and more, always depending on the customer’s<br />
requirements regarding mechanical properties and endof-life<br />
solutions. However, ABM is not a polymer producer.<br />
As a specialty compounder, their strategy is to enhance the<br />
properties and reinforce the current bioplastics that are<br />
available in the market.<br />
ArcBiox MFA30-B2000, improved temperature<br />
resistance with fast cycle and cold mould<br />
This novel PLA-based mineral filled material has been<br />
developed with a view to improving processability. Temperature<br />
resistance has always been one of the challenges for PLAbased<br />
materials, as high mould temperatures (110 °C) are<br />
required and long cycle times (60 s) needed in order for the<br />
material to withstand temperatures above 50-60 °C (HDT B).<br />
ArcBiox MFA30-B2000 offers a HDTB of 96 °C and faster cycle<br />
times, while the mould temperature can be as low as 30-50 °C.<br />
Potential applications for ArcBiox MFA30-B200 range from<br />
houseware products to cosmetics; the material truly opens a<br />
new window for applications where processing has been the<br />
barrier.<br />
ArcBiox B1005, improved impact properties<br />
ArcBiox B1005 was developed as an alternative to fossilbased<br />
plastics similar to ABS. The focus has been on improving<br />
the impact properties of PLA-based materials. The applications<br />
mainly comprise different kinds of housings and covers. The<br />
material can be processed in a hot or cold mould. The hot<br />
mould will result in extra temperature resistance due to the<br />
crystallization of the PLA. In a hot mould, impact properties of 40<br />
kJ/m² (IZOD notched) and NB (no breakage - IZOD unnotched)<br />
can be achieved. In a cold mould, these values are 20 kJ/m²<br />
(IZOD notched) and 140 kJ/m² (IZOD unnotched). The general<br />
impact values for ABS would be 20 kJ/m² (IZOD notched) and<br />
NB (no breakage - IZOD unnotched)<br />
ArcBiox B2004, excellent hinge properties<br />
ABM’s new ArcBiox B2004 has been specifically designed to<br />
offer excellent hinge properties. This grade provides a viable<br />
solution for e.g. caps and closure applications. While some<br />
development is still ongoing as regards elongation at break,<br />
hinge properties of this quality have not been achieved before in<br />
a PLA-based material.<br />
The experts at ABM aim to fully satisfy the needs of their<br />
market. To that end, they always listen to their customers’<br />
requirements in terms of mechanical properties and assess<br />
the end-of-life solution offering the best value proposition. The<br />
polymer matrix and compound or reinforcement can then be<br />
chosen which best meets these requirements.<br />
The product photos are generic pictures to show possible<br />
applications. These are not commercial products. MT<br />
www.abmcomposite.com<br />
30 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
Automotive<br />
The World’s No. 1 Trade Fair<br />
for Plastics and Rubber<br />
Home of<br />
Innovation. K <strong>2019</strong><br />
No matter what your focus is – circular<br />
economy, digitalisation, Industry 4.0, lightweight<br />
construction, additive manufacturing, advanced<br />
materials or other forward-looking topics in the<br />
global plastics and rubber industry – K <strong>2019</strong> is<br />
the place to be to scout for new solutions. The<br />
fascinating forum for innovation and investment.<br />
The industry’s most important business platform.<br />
Around 3,200 international exhibitors offer you<br />
the latest in research and development. Welcome<br />
to the show!<br />
www.k-online.com/ticketing<br />
Messe Düsseldorf GmbH<br />
P.O. Box 10 10 06 _ 40001 Düsseldorf _ Germany<br />
Tel. +49 211 4560 01 _ Fax +49 211 4560 668<br />
www.messe-duesseldorf.de<br />
bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 31
Injection Moulding<br />
Single-use<br />
cutlery & food<br />
containers<br />
Compostable, high-heat stable,<br />
food-contact safe, easy to process<br />
nature2need, located in Heidelberg, Germany with its<br />
manufacturing units in Zhejiang, PR China, is a global<br />
supplier of biopolymers and natural fiber reinforced<br />
compounds and sheets; preferred natural fiber<br />
reinforcements are mechanically extracted bamboo fibers.<br />
Different grades are available for applications in various<br />
industries, like automotive, personal care, houseware,<br />
kitchenware, toys, outdoor, agriculture and gardening<br />
industry.<br />
During April <strong>2019</strong>, nature2need launched its new biocompound<br />
Bioblend LT25B, a biopolymer that is compostable<br />
in industrial compost conditions according to EN 14995<br />
(for Europe) and ASTM D 6400 (for North-America). The<br />
Bioblend grade is a blend of different biopolymers, modified<br />
with mineral fillers. Main base polymer of the compound is<br />
PLA. The compound is very easy to process with industryrelevant<br />
cycle times on standard equipment and injection<br />
moulds. A quick, in-line annealing process, right after<br />
demoulding, is suitable to get all parts heat-stable up to<br />
110 °C (HDT-B). nature2need´s right choice of different<br />
biopolymers, natural additives that work as nucleating<br />
agents and natural, highly-effective compatibilizers<br />
guarantuee a quick and efficient material crystallization to<br />
meet high-heat requirements. The material is food-contact<br />
safe.<br />
Bioblend LT25B targets to replace traditional, fossilbased<br />
plastics that are used in single-use items, like<br />
cutlery, food-containers, drinking cups, etc. Single-use<br />
applications made with non biodegradable materials are<br />
already or will be banned in a lot of countries very soon.<br />
There are a few alternatives to traditional, single-use<br />
plastics parts on the market, most of them are either very<br />
expensive or are not performing well. Especially thermal<br />
stability at temperatures around 70 – 100 °C is a problem<br />
with most of the eco-friendly alternatives. Products made<br />
with Bioblend LT25B compounds can even be re-used a<br />
couple of times, a camping holiday or a few dish-washer<br />
cycles are no problem, even for thin-walled parts.<br />
“The spoons, knives and forks we molded with our<br />
material are sturdy, high-temperature resistant, they come<br />
with a surprisingly high perceived quality; bright-white with<br />
a very glossy surface. A much better product than the ones<br />
we all know made with traditional, oil-based plastics like<br />
PS. The material is completely compostable and - on top of<br />
this - offers significant reduction in carbon footprint.” says<br />
Dr. Karsten Brast, CEO of the nature2need Group. “Low<br />
cost and high-quality levels will make it easier to convince<br />
everybody out there to finally change to sustainable<br />
products!”<br />
A biodegradable/compostable solution is good, but not<br />
perfect. nature2need is currently developing a new material,<br />
biodegradable in soil, with very similar properties that will<br />
be commercially available soon. MT<br />
http://nature2need.com<br />
32 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
Automotive<br />
PRESENTS<br />
The Bioplastics Award will be presented<br />
during the 14 th European Bioplastics Conference<br />
December <strong>03</strong>-04, <strong>2019</strong>, Berlin, Germany<br />
<strong>2019</strong><br />
THE FOURTEENTH ANNUAL GLOBAL AWARD FOR<br />
DEVELOPERS, MANUFACTURERS AND USERS OF<br />
BIOBASED AND/OR BIODEGRADABLE PLASTICS.<br />
Call for proposals<br />
Enter your own product, service or development,<br />
or nominate your favourite example from<br />
another organisation<br />
Please let us know until August 31 st<br />
1. What the product, service or<br />
development is and does<br />
2. Why you think this product,<br />
service or development should win an award<br />
3. What your (or the proposed) company<br />
or organisation does<br />
Your entry should not exceed 500 words (approx. 1 page) and<br />
may also be supported with photographs, samples, marketing<br />
brochures and/or technical documentation (cannot be sent<br />
back). The 5 nominees must be prepared to provide a 30 second<br />
videoclip and come to Berlin on December 3 rd , <strong>2019</strong>.<br />
An entry form can be found at<br />
www.bioplasticsmagazine.com/en/events/award/bio-award19.pdf<br />
supported by<br />
bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 33
Injection Moulding<br />
The bioplastics handbook<br />
for injection molders<br />
T<br />
his article is an excerpt of “The bioplastics handbook<br />
for injection molders”, created and published<br />
by Green Dot Bioplastics (Emporia, Kansas, USA),<br />
edited by Michael Thielen. Download the full handbook via<br />
the link given at the end [1].<br />
Processing bioplastics<br />
Bioplastics can be processed with the same equipment<br />
and, in many cases, similar cycle times as traditional<br />
plastics. As with switching from one traditional plastic<br />
to another traditional plastic (e.g., polyethylene to a<br />
polystyrene), though, it’s important to understand the<br />
processing parameters of the new material. And if you plan<br />
to use the same mold, it’s important to choose a bioplastic<br />
with similar processing characteristics to the material<br />
you’re currently using.<br />
Because of the custom nature of many materials, materialspecific<br />
processing considerations vary formulation by<br />
formulation. Still, there are category-specific processing<br />
considerations injection molders would find helpful to know<br />
before using a bioplastic.<br />
In this guide, Green Dot Bioplastics offers general<br />
considerations for these two overarching bioplastic<br />
categories: Biocomposites (plastics made with a matrix<br />
resin — either petroleum-based or renewable and a<br />
reinforcement of natural fibers or fillers) and biodegradables<br />
(plastics which are metabolized into organic bio-mass after<br />
use). See info-box for details about Green Dot Bioplastics’<br />
materials.<br />
Injection molding with biocomposites<br />
Biocomposites can replace as much as 65 % (in cases<br />
even up to 70 %) of petroleum-based content with renewable<br />
materials such as wood-, flax-, hemp-, bamboo- etc. fibers<br />
or starch — a compelling bio story in a time when plastics<br />
bans and restrictions are heightening.<br />
Most biocomposites do not deviate significantly from<br />
traditional plastics and can be processed on the same<br />
equipment without major modifications to the injection<br />
molding process. As long as injection molders are aware of<br />
the small ways in which biocomposites differ from traditional<br />
plastics —and the small ways that difference affects the<br />
injection molding process— processing problems are easy<br />
to avoid. And as with any material change, it’s paramount<br />
to follow the processing characteristics laid out by the<br />
material manufacturer.<br />
Lower temperatures, slower injection speeds<br />
Biocomposites are filled with organic fillers and fibers,<br />
which are especially sensitive to high temperatures and<br />
shear buildup. If the material gets above about 205°C<br />
(400°F), there’s potential for degradation of the cellulose<br />
and burn streaks in the finished part. Changes in the<br />
process (e.g., lower temperatures, slower injection speeds)<br />
and tooling (e.g., opening a cooling line, enlarging gates)<br />
may be needed to alleviate shear stress and prevent the<br />
material from overheating.<br />
Although injection speeds might need to be lower for<br />
biocomposites, cycle times should remain within an<br />
acceptable range because they are being processed at<br />
lower temperatures meaning less cooling time is required.<br />
And the organic filler adds a degree of dimensional stability<br />
to the material, allowing it to be removed from the mold at<br />
higher temperatures than conventional plastics and further<br />
reducing cycle times.<br />
Follow drying recommendations<br />
The organic fillers (e.g., natural fibers, wood, starch,<br />
etc.) in a biocomposite readily absorb moisture from the<br />
environment and must be dried in a desiccant dryer prior<br />
to processing. Processing biocomposites at moisture<br />
levels above about 0.5% can result in a host of processing<br />
problems such as drooling from the nozzle or runner and<br />
the formation of voids within the part.<br />
Account for differing shrinkage characteristics<br />
The higher the ratio of organic fiber and fillers in a<br />
biocomposite, the lower the shrink rate. Injection molders<br />
who currently make a part out of a traditional plastic (e.g.,<br />
polyethylene) and want to switch to a biocomposite (e.g., a<br />
wood fiber polyethylene composite) need to be conscious<br />
of the differing shrinkage characteristics between the two<br />
materials. A higher shrink rate isn’t necessarily good, and<br />
a lower shrink rate isn’t necessarily bad. But molds are<br />
designed with draft angles to accommodate the shrinkage<br />
of one plastic material — and if the same mold shall be<br />
used for the new material, a material with a similar shrink<br />
rate needs to be chosen.<br />
Injection molding with biodegradables<br />
Experience shows that the vast majority of processing<br />
problems with biodegradable plastics stem back to<br />
moisture and temperature. Processing biodegradable<br />
plastics at above the recommended temperature will cause<br />
the material to degrade. And if excess moisture is present,<br />
the resulting parts will be brittle, weak and have a reduced<br />
shelf life.<br />
If all processing recommendations of the raw material<br />
suppliers (e.g. Green Dot Bioplastics) are followed, though,<br />
the biodegradable plastic will remain strong and functional<br />
until subjected to the specific conditions in which it is<br />
designed to biodegrade. Most often, this is in industrial<br />
composting facilities or, in special cases, backyard<br />
composting settings — not while a product is on a store<br />
shelf or in use.<br />
34 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
Injection Moulding<br />
Drying time and moisture levels<br />
It’s essential to follow the drying instructions<br />
specified by the material manufacturer to ensure the<br />
material is at or below the recommended moisture<br />
level prior to processing. Moisture levels above 0.1%<br />
will not only cause problems during the injection<br />
molding process (e.g., foaming, drooling, voids) but<br />
also product performance problems. The presence<br />
of excess moisture can cause the plastic to<br />
hydrolyze during the product lifecycle, resulting<br />
in a loss of molecular weight and mechanical<br />
performance. This can cause parts to be brittle<br />
and weak and, ultimately, fail.<br />
Lower processing temperatures<br />
Many biodegradable plastics tend to be more<br />
shear-sensitive and have lower melting points than<br />
most biocomposites and traditional plastics. Because of<br />
this, most biodegradable materials have to be dried and<br />
processed at much lower temperatures, often well below<br />
175°C (350°F). Processing biodegradable plastics above<br />
the manufacturer recommended temperature can result<br />
in material degradation. Slower injection speeds and<br />
larger gates / runners may be required to further reduce<br />
the temperature and shear stress depending on the mold<br />
and material you are using.<br />
Meet injection molders who have made<br />
bioplastics work<br />
In a separate publication by Green Dot Bioplastics, four<br />
injection molders provide valuable and promising insights<br />
on working with bioplastics. Although each had technical<br />
issues at the initial stages, they were eventually able to run<br />
the materials successfully in their respective facilities [2].<br />
A research-driven guidebook to processing<br />
bioplastics<br />
A special guide published by IfBB – Institute for Bioplastics<br />
and Biocomposites (Hanover University of Applied Sciences<br />
and Arts) and supported by FNR (specialist agency<br />
renewable resources) to the processing of bioplastics gives<br />
a straightforward explanation of processing considerations<br />
for a variety of materials and processing procedures based<br />
on years of research [3]. The texts were contributed by IAP<br />
– Fraunhofer Institute for Applied Polymer Research, IfBB,<br />
SKZ, SLK, Chair of Lightweight Structures and Polymer<br />
Technology, Technical University Chemnitz.<br />
[1] The bioplastics handbook for injection molders (complete pdf) The<br />
Bioplastics handbook for injection molders<br />
tinyurl.com/bioplastics-handbook<br />
[2] N.N.: Injection molders who have made bioplastics work;<br />
tinyurl.com/injection-moulders<br />
[3] Offers, J.; Lack, N. (Edts): Processing of Bioplastics – a guideline –<br />
tinyurl.com/bioplasticsprocessingguideline<br />
Green Dot Bioplastics materials at a glance<br />
Each of Green Dot’s Terratek® material lines don’t describe a<br />
discrete material, but rather a class of materials.<br />
• Terratek BD, is a class of materials that are both bio-based<br />
and biodegradable. Within the Terratek BD category, there are<br />
near-infinite possibilities to customize a formulation by alloying<br />
different polymers and additives to meet customer-specific<br />
performance requirements. These grades are more rigid and<br />
similar to traditional polyolefin resins.<br />
• Terratek Flex is a class of biodegradable elastomers that is<br />
rubber-like and soft to the touch,<br />
Terratek BD and Terratek Flex, are certified compostable according<br />
to ASTM D6400 and EN 13432, meaning they will disintegrate<br />
within 12 weeks and biodegrade within 180 days in an industrial<br />
composting facility.<br />
• Terratek WC is a class of wood-plastic composites. WC contains<br />
up to 60% wood particles<br />
• Terratek SC is a class of starchplastic composites with starch-toplastic<br />
ratios ranging from 30 to 65%.<br />
Terratek WC and SC replace a significant portion of traditional<br />
plastic with renewable, reclaimed organic fillers. The organic<br />
material adds dimensional stability, stiffness and a natural<br />
appearance to plastic products without sacrificing performance or<br />
processability.<br />
The value of Green Dot Bioplastics lies in the material science<br />
expertise which gives the supplier the flexibility to customize their<br />
material lines to match the unique requirements of each client.<br />
Green Dot Bioplastics offers custom formulations for each category,<br />
alloying different polymers, additives and fillers to achieve a broad<br />
range of performance and processing parameters.<br />
www.greendotbioplastics.com<br />
bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 35
Injection Moulding<br />
By:<br />
Daniel Ganz,<br />
Global Product Manager Bioplastics<br />
Sukano<br />
Schindeleggi, Switzerland<br />
Injection Molding PLA<br />
Make the switch today<br />
S<br />
ukano, a global Masterbatch specialist for polyester<br />
and specialty resins, has leveraged its expertise<br />
to enable a broader design variety to be injection<br />
molded with PLA without major financial investments.<br />
One of the key bioplastics, PLA, is currently the second<br />
highest consumed bioplastic worldwide by volume, and<br />
it offers a broad range of functionalities optimized for<br />
each type of application. It can be processed into a vast<br />
array of products using conventional plastics processing<br />
technologies – in most cases, the process parameters of<br />
the processing equipment simply needs to be adjusted to<br />
the individual specification of each polymer.<br />
Overcoming the barriers in injection molding<br />
Currently, polyolefins and polystyrenes resin are the most<br />
commonly used materials for injection molding. However,<br />
a bigger shift toward PLA in injection molding has been<br />
slowed by serious issues. There are several challenges that<br />
convertors have faced when processing injection molded<br />
PLA parts, especially when using existing equipment and<br />
tools, including:<br />
• Difficulties to fill cavities due to higher melt viscosity of<br />
the carrier, especially for thin wall applications<br />
• Additional force required to fill the form, which may lead<br />
to shorter lifespan of the tool<br />
• Material sticking to the mold surface, making demolding<br />
more difficult and increasing the risk of surface defects<br />
in the end application<br />
Due to these issues, processing PLA was not even<br />
possible in many cases – until now.<br />
Enabling a broader design variety<br />
Formulated to enable a broader design variety to be<br />
injection molded with PLA Sukano has developed a mold<br />
release additive masterbatch that enables convertors<br />
to injection mold PLA – even for thin wall applications –<br />
without needing to change the machine or the equipment.<br />
Customer cases have demonstrated that the switch from<br />
fossil-based plastics to PLA for injection molding is very<br />
much possible, all without major financial investments.<br />
SUKANO ® Mold Release Masterbatch achieves this by<br />
providing the critical barrier between a molding surface<br />
and the substrate, facilitating the separation of the cured<br />
part from the mold. It acts by migrating to the surface of<br />
the final product, which helps to demold the injection<br />
molded part from the metal surface of the cavity, therefore<br />
reducing the demolding force required. This unique feature<br />
can help ensure reduced cycle times, continuous running<br />
of production lines, fewer rejects and waste, as well as<br />
reduced machine wear out and cleaning.<br />
Melt flow increase as an additional effect<br />
Sukano Mold Release Masterbatch also has an<br />
interesting and very beneficial side effect, as demonstrated<br />
in sophisticated spiral flow length trials conducted in an<br />
external lab. By reducing the friction between the polymer<br />
chains, it creates a lower melt viscosity – and therefore<br />
a higher melt flow – without increasing the temperature.<br />
This helps to fill the cavities, which can be especially<br />
challenging in thin wall applications, and enables a broader<br />
design variety to be injection molded with PLA. It essentially<br />
eliminates the critical issue of decreased melt flow, often<br />
a major barrier to the switch from conventional plastics to<br />
bio-based materials in this type of process.<br />
Sukano Mold Release Masterbatch helps producers<br />
make the switch to PLA while still achieve a consistent<br />
high-quality standard of their PLA-based end products,<br />
with high clarity, scratch and scuff resistance, improved<br />
surface finish, improved material homogenization, and it is<br />
food compliant.<br />
1600 —<br />
1500 —<br />
1422<br />
1400 —<br />
PLA: Peak demolding force / N<br />
Hold pressure: 400 bar,<br />
melt temperature: 200°C,<br />
mold temperature: 25°C<br />
1300 —<br />
1200 —<br />
1100 —<br />
1000 —<br />
900 —<br />
1213<br />
1075<br />
800 —<br />
PLA reference PLA + 1% PLA mr S533 PLA + 3% PLA mr S533<br />
36 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
Injection Moulding<br />
REGISTER<br />
NOW & SAVE<br />
€300<br />
Sukano – your guide in the move to bioplastics<br />
In our highly interconnected world, the general public<br />
has become more and more concerned – and engaged –<br />
about the planet’s future in the face of increasingly serious<br />
environmental challenges. The debate has reached its<br />
tipping point, with the European Commission itself stating<br />
that “European consumers are more and more prepared to<br />
buy goods and services which have a reduced environmental<br />
impact.” People are now prepared to participate via their<br />
purchase habits and preferences to ensure their impact on<br />
the environment are minimized or at least well reduced.<br />
To support its customers in making the switch to<br />
bioplastics, Sukano has invested in a powerful R&D<br />
analytical laboratory and pilot plant. This allows the<br />
company to provide industry-leading capabilities to quickly<br />
respond to customer’s most urgent demands and flexibility<br />
requirements. Together with over 30 years of experience in<br />
the field, Sukano is ready and, willing and able to support<br />
you to make the switch today.<br />
www.sukano.com<br />
Specific injection pressure in bar<br />
1100%<br />
1050%<br />
1000%<br />
950%<br />
900%<br />
850%<br />
Performance of Injection Pressure<br />
(MB + Ingeo-PLA 3251D)<br />
800%<br />
0% 1%<br />
3% 5%<br />
Dosage of mold release SUKANO mr S533<br />
27/28 June <strong>2019</strong>, FrankFurt Messe<br />
EXAMINING HOW BIOPLASTICS CAN HELP<br />
CREATE A WORLD FREE FROM PLASTIC WASTE<br />
applications in Packaging, automotive, textiles & transportation<br />
PLUS: Increasing use of recycled Materials & end-of-Life solutions<br />
sponsors<br />
www.plasticfree-world.com<br />
bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 37
Chinaplas-Review<br />
Chinaplas <strong>2019</strong> Review<br />
By:<br />
John Leung<br />
Biosolutions<br />
Hong Kong<br />
A<br />
companying the growth of China’s plastics and<br />
rubber industries for over 30 years, CHINAPLAS<br />
has become a distinguished meeting and business<br />
platform for these industries and has also largely contributed<br />
to their prosperous development. At present, CHINA-<br />
PLAS is the world’s leading plastics and rubber trade fair,<br />
and also widely recognized by the industry as one of the<br />
most influential exhibitions in the world. Its significance is<br />
surpassed only by K Fair in Germany, the world’s premier<br />
plastics and rubber trade fair.<br />
Chinaplas <strong>2019</strong> (21-24 May), the 33rd International<br />
Exhibition on Plastics and Rubber Industries, attracted over<br />
180,000 professional visitors from 150 countries and regions<br />
to the China Import and Export Fair Complex, Pazhou,<br />
Guangzhou. The exhibition space compriswd more than<br />
250,000 square-meters. The show gathered together more<br />
than 3,600 leading exhibitors from all over the world, in<br />
which more than 1,800 of them are related to the packaging<br />
industry.<br />
Among the 20 Theme Zones, including for the first time<br />
a Recycled Plastics Zone, Chinaplas <strong>2019</strong> again featured a<br />
Bioplastics Zone to address the industry’s need for green<br />
and circular solutions.<br />
The biobased plastics and bio-composites shown in the<br />
Bioplastics Zone not only can be used in a wide range of<br />
applications such as packaging, electronic appliances,<br />
toys, children products, automobiles, and 3D printing but<br />
also are degradable, compostable, environmentally friendly,<br />
non-toxic and as affordable as petroleum-based plastics.<br />
Some examples are:<br />
NatureWorks LLC’s Ingeo ® biobased plastics come from<br />
100% renewable plant resources. According to ISO 14040<br />
and 14044 standards, Ingeo® reduces greenhouse gas<br />
emissions and consumes less non-renewable energy than<br />
conventional plastic PS/PET/ABS.<br />
Today, Ingeo is favored for its unique features! It has been<br />
used in products such as food utensils, coffee capsules,<br />
nonwovens and home appliances. As part of its commitment<br />
to the recycling bioeconomy and away from petrochemical<br />
feedstocks, NatureWorks announced that 100% of all<br />
agricultural raw materials used in Ingeo biopolymers will<br />
be certified by the International Sustainable Development<br />
and Carbon Certification System in 2020, in line with ISCC<br />
PLUS agricultural production. Best practice standards.<br />
According to Johannes Becker, BASF’s Global Biopolymer<br />
Marketing Director, “Rapid industrialization, economic growth<br />
and environmental awareness have driven the development<br />
of sustainable living in China. BASF is committed to helping<br />
China meet these challenges through innovative, sustainable<br />
plastic solutions. ”<br />
The biobased and compostable material of Suzhou Hanfeng<br />
New Material Co., Ltd. has changed the situation of traditional<br />
plastics being difficult to degrade and combustion producing<br />
harmful gases. With the technology for blending PLA and PBAT,<br />
customers’ various requirements for the physical properties<br />
of products and cost control can be satisfied, and the softness<br />
and environmental friendliness of products will be enhanced.<br />
Users can opt for such degradable and non-toxic packaging<br />
with higher quality when purchasing products in the future.<br />
The material can be used to manufacture green courier bags,<br />
disposable lunch boxes, bowls, cups, supermarket shopping<br />
bags, bags on a roll, flat-top bags and so on.<br />
Biocosafe ® developed by Xinfu Technology uses binary acid<br />
and binary alcohol as raw materials, and uses high-efficiency<br />
non-toxic catalyst to directly synthesize according to the onestep<br />
polycondensation method. Under the ISO14855 detection<br />
method, the relative biodegradation rate of the material<br />
exceeds 90%. The glass transition temperature of the resin is<br />
-35 ° C. It can meet the requirements of cold, hot drinks and<br />
lunch boxes, and is a biodegradable material with excellent<br />
temperature resistance. It could be applied to stationery, toys,<br />
entertainment products, etc.<br />
Ecoworld ® developed by Jinhui Zhaolong can be decomposed<br />
into carbon dioxide and water by microorganisms within<br />
180 days under composting conditions. Under composting<br />
conditions, organic fertilizer can be produced, and the<br />
degradation process does not produce toxic gases. The main<br />
raw material of plastic film is biodegradable and compostable,<br />
which can effectively deal with white pollution.<br />
www.chinaplasonline.com<br />
BASF showcased the new biodegradable polymer ecovio ®<br />
courier bags, indicating that BASF is helping to cope with the<br />
white pollution challenge caused by the surge in domestic<br />
courier bags. This ecovio degradable courier bag delivers<br />
outstanding performance and not only meets customer<br />
needs, but also provides an environmentally friendly<br />
solution. BASF is working with key downstream partners to<br />
explore cutting-edge technologies for biodegradable bags.<br />
38 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
Natural Rubber © -Institut.eu | 2018<br />
Starch-based Polymers<br />
Lignin-based Polymers<br />
Cellulose-based Polymers<br />
©<br />
PBAT<br />
PET-like<br />
PU<br />
APC<br />
PTT<br />
PLA<br />
PU<br />
PA<br />
PTF<br />
PHA<br />
-Institut.eu | 2017<br />
PMMA<br />
HDMA<br />
DN5<br />
PVC<br />
Isosorbide<br />
1,3 Propanediol<br />
Caprolactam<br />
UPR<br />
PP<br />
Propylene<br />
Vinyl Chloride<br />
Ethylene<br />
Sorbitol<br />
Lysine<br />
MPG<br />
Epoxy resins<br />
Epichlorohydrin<br />
EPDM<br />
Ethanol<br />
Glucose<br />
PE<br />
MEG<br />
Terephthalic<br />
acid<br />
Isobutanol<br />
PET<br />
p-Xylene<br />
Starch Saccharose<br />
Fructose<br />
Lignocellulose<br />
Natural Rubber<br />
Plant oils<br />
Hemicellulose<br />
Glycerol<br />
PU<br />
Fatty acids<br />
NOPs<br />
Polyols<br />
PU<br />
PU<br />
LCDA<br />
THF<br />
PBT<br />
1,4-Butanediol<br />
Succinic acid<br />
3-HP<br />
5-HMF/<br />
5-CMF<br />
Aniline<br />
Furfural<br />
PA<br />
SBR<br />
Acrylic acid<br />
2,5-FDCA/<br />
FDME<br />
PU<br />
PFA<br />
PU<br />
PTF<br />
ABS<br />
PHA<br />
Full study available at www.bio-based.eu/reports<br />
Full study available at www.bio-based.eu/reports<br />
PEF<br />
PBS(X)<br />
©<br />
-Institut.eu | 2017<br />
Full study available at www.bio-based.eu/markets<br />
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7 th<br />
Bio-based Polymers & Building Blocks<br />
The best market reports available<br />
Automotive<br />
Commercialisation updates on<br />
bio-based building blocks<br />
7 th 1<br />
Data Data for for<br />
2018 2018<br />
UPDATE<br />
<strong>2019</strong><br />
UPDATE<br />
<strong>2019</strong><br />
Bio-based Building Blocks<br />
Bio-based Building Blocks<br />
and Polymers – Global Capacities<br />
and Polymers – Global Capacities<br />
and Trends 2018-2023<br />
and Trends 2017-2022<br />
Carbon dioxide (CO 2 ) as chemical<br />
feedstock for polymers – technologies,<br />
polymers, developers and producers<br />
Succinic acid: New bio-based<br />
building block with a huge market<br />
and environmental potential?<br />
Million Tonnes<br />
6<br />
5<br />
4<br />
3<br />
2<br />
1<br />
2011<br />
Bio-based polymers:<br />
Evolution of worldwide production capacities from 2011 to 2022<br />
Lactic<br />
acid<br />
Adipic<br />
acid<br />
Methyl<br />
Metacrylate<br />
Itaconic<br />
acid<br />
Furfuryl<br />
alcohol<br />
Levulinic<br />
acid<br />
2012 2013 2014 2015 2016 2017 2018 <strong>2019</strong> 2020 2021 2022<br />
Dedicated<br />
Drop-in<br />
Smart Drop-in<br />
Superabsorbent<br />
Polymers<br />
Pharmaceutical/Cosmetic<br />
Acidic ingredient for denture cleaner/toothpaste<br />
Antidote<br />
Calcium-succinate is anticarcinogenic<br />
Efferescent tablets<br />
Intermediate for perfumes<br />
Pharmaceutical intermediates (sedatives,<br />
antiphlegm/-phogistics, antibacterial, disinfectant)<br />
Preservative for toiletries<br />
Removes fish odour<br />
Used in the preparation of vitamin A<br />
Food<br />
Bread-softening agent<br />
Flavour-enhancer<br />
Flavouring agent and acidic seasoning<br />
in beverages/food<br />
Microencapsulation of flavouring oils<br />
Preservative (chicken, dog food)<br />
Protein gelatinisation and in dry gelatine<br />
desserts/cake flavourings<br />
Used in synthesis of modified starch<br />
Succinic<br />
Acid<br />
Industrial<br />
De-icer<br />
Engineering plastics and epoxy curing<br />
agents/hardeners<br />
Herbicides, fungicides, regulators of plantgrowth<br />
Intermediate for lacquers + photographic chemicals<br />
Plasticizer (replaces phtalates, adipic acid)<br />
Polymers<br />
Solvents, lubricants<br />
Surface cleaning agent<br />
(metal-/electronic-/semiconductor-industry)<br />
Other<br />
Anodizing Aluminium<br />
Chemical metal plating, electroplating baths<br />
Coatings, inks, pigments (powder/radiation-curable<br />
coating, resins for water-based paint,<br />
dye intermediate, photocurable ink, toners)<br />
Fabric finish, dyeing aid for fibres<br />
Part of antismut-treatment for barley seeds<br />
Preservative for cut flowers<br />
Soil-chelating agent<br />
Authors:<br />
Raj Authors: Chinthapalli, Raj Chinthapalli, Dr. Pia Skoczinski, Michael Carus, Michael Wolfgang Carus, Wolfgang Baltus, Baltus,<br />
Doris Doris de de Guzman, Harald Harald Käb, Käb, Achim Achim Raschka, Jan Jan Ravenstijn,<br />
April 2018<br />
<strong>2019</strong><br />
This and other reports on the bio-based economy are available at<br />
This www.bio-based.eu/reports<br />
and other on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Authors: Achim Raschka, Dr. Pia Skoczinski, Jan Ravenstijn and<br />
Michael Carus<br />
nova-Institut GmbH, Germany<br />
February <strong>2019</strong><br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Authors: Raj Chinthapalli, Dr. Pia Skoczinski, Achim Raschka,<br />
Michael Carus, nova-Institut GmbH, Germany<br />
Update March <strong>2019</strong><br />
This and other reports on the bio-based economy are available<br />
at www.bio-based.eu/reports<br />
Standards and labels for<br />
bio-based products<br />
Bio-based polymers, a revolutionary change<br />
Comprehensive trend report on PHA, PLA, PUR/TPU, PA<br />
and polymers based on FDCA and SA: Latest developments,<br />
producers, drivers and lessons learnt<br />
million t/a<br />
Selected bio-based building blocks: Evolution of worldwide<br />
production capacities from 2011 to 2021<br />
3,5<br />
actual data<br />
forecast<br />
3<br />
2,5<br />
Bio-based polymers, a<br />
revolutionary change<br />
2<br />
1,5<br />
Jan Ravenstijn 2017<br />
1<br />
0,5<br />
Picture: Gehr Kunststoffwerk<br />
2011<br />
2012<br />
2013<br />
2014<br />
2015 2016 2017 2018 <strong>2019</strong> 2020<br />
2021<br />
L-LA<br />
Epichlorohydrin<br />
MEG<br />
Ethylene<br />
Sebacic<br />
acid<br />
1,3-PDO<br />
MPG<br />
Lactide<br />
E-mail:<br />
j.ravenstijn@kpnmail.nl<br />
Succinic<br />
acid<br />
1,4-BDO<br />
2,5-FDCA<br />
D-LA<br />
11-Aminoundecanoic acid<br />
DDDA<br />
Adipic<br />
acid<br />
Mobile: +31.6.2247.8593<br />
Author: Doris de Guzman, Tecnon OrbiChem, United Kingdom<br />
July 2017<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Authors: Lara Dammer, Michael Carus and Dr. Asta Partanen<br />
nova-Institut GmbH, Germany<br />
May 2017<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Author: Jan Ravenstijn, Jan Ravenstijn Consulting, the Netherlands<br />
April 2017<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Policies impacting bio-based<br />
plastics market development<br />
and plastic bags legislation in Europe<br />
Asian markets for bio-based chemical<br />
building blocks and polymers<br />
Market study on the consumption<br />
of biodegradable and compostable<br />
plastic products in Europe<br />
2015 and 2020<br />
Share of Asian production capacity on global production by polymer in 2016<br />
100%<br />
A comprehensive market research report including<br />
consumption figures by polymer and application types<br />
as well as by geography, plus analyses of key players,<br />
relevant policies and legislation and a special feature on<br />
biodegradation and composting standards and labels<br />
80%<br />
60%<br />
Bestsellers<br />
40%<br />
20%<br />
0%<br />
PBS(X)<br />
APC –<br />
cyclic<br />
PA<br />
PET<br />
PTT<br />
PBAT<br />
Starch<br />
PHA<br />
PLA<br />
PE<br />
Blends<br />
Disposable<br />
tableware<br />
Biowaste<br />
bags<br />
Carrier<br />
bags<br />
Rigid<br />
packaging<br />
Flexible<br />
packaging<br />
Authors: Dirk Carrez, Clever Consult, Belgium<br />
Jim Philp, OECD, France<br />
Dr. Harald Kaeb, narocon Innovation Consulting, Germany<br />
Lara Dammer & Michael Carus, nova-Institute, Germany<br />
March 2017<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Author: Wolfgang Baltus, Wobalt Expedition Consultancy, Thailand<br />
This and other reports on the bio-based economy are available at<br />
www.bio-based.eu/reports<br />
Authors: Harald Kaeb (narocon, lead), Florence Aeschelmann,<br />
Lara Dammer, Michael Carus (nova-Institute)<br />
April 2016<br />
The full market study (more than 300 slides, 3,500€) is available at<br />
bio-based.eu/top-downloads.<br />
www.bio-based.eu/reports<br />
1<br />
bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 39
Applications<br />
Cosmetic<br />
tubes from<br />
bio-PE<br />
Saving resources,<br />
recyclable and<br />
promoting sales<br />
With Braskem’s<br />
Green PE, FKuR has<br />
a family of biobased<br />
plastics in its<br />
portfolio, which has<br />
proved to be a great<br />
success with tube<br />
producers.<br />
It is a sustainable,<br />
environmentally<br />
compatible and<br />
easily printable<br />
alternative to fossil<br />
based counterparts.<br />
(Picture: FKuR)<br />
Cosmetic tubes made from Braskem‘s biobased Green<br />
PE combine sustainability and recyclability along<br />
with attractiveness at the point of sale so meeting<br />
the demands of brand owners and end consumers. FKuR<br />
(Willich, Germany), presents successful applications at<br />
CosmeticBusiness <strong>2019</strong> in Munich on 5th and 6th June, in<br />
hall 3 booth E02.<br />
Application specific biopolymers<br />
FKuR’s portfolio covers a wide range of biobased plastics<br />
for the production of cosmetic packaging. Having good<br />
barrier properties and durability, all grades provide the<br />
required resistance to the ingredients. This is combined<br />
with excellent printability giving an attractive product<br />
without having to use secondary packaging. The biobased<br />
polyethylene Green PE produced by Braskem from renewably<br />
sourced sugar cane, is ideally suited for the extrusion blow<br />
molding of tubes. Depending on the application, HDPE<br />
grades with more than 90 % of biobased content, or LDPE<br />
grades with more than 95 % of biobased content, as well<br />
as LLDPE grades with more than 80 % of biobased content<br />
(according to ASTM D 6866) are available. Furthermore,<br />
with its Terralene LL 1712 FKuR offers a ready-to-use<br />
compound for tube production based on Green PE.<br />
The mechanical characteristics and the recyclability<br />
of these materials are the same as those of conventional<br />
fossil based PE. Hence, they can be used for identical<br />
applications and are also 100 % recyclable in the same PE<br />
waste stream. As a sales support measure, brand owners<br />
can use Braskem’s license-free I’m green logo on the tubes.<br />
The use of this logo requires the communication of the<br />
renewable portion of the product, which should be verified<br />
by C14 analysis according to ASTM D6866. Also certificates<br />
from independent certification bodies can be used, such as<br />
the OK Biobased from TÜV Austria or DIN tested by DIN<br />
Certco with its corresponding points rating system.<br />
First applications – attractive and successful<br />
As a result of customers desires and the end users’<br />
trend of increasingly considering sustainability and<br />
environmental compatibility when making purchasing<br />
decisions, Emballator Tectubes, a Swedish producer of<br />
injection molded and extruded plastics and aluminum<br />
tubes, made the transition to biobased Green PE several<br />
years ago. Supported by Polymerfront, the Swedish<br />
distributor for FKuR, the company had previously conducted<br />
intensive tests with Green PE and with the alternative PLA.<br />
The biobased PE was chosen as a result of its better water<br />
barrier and ease of processing.<br />
Jan-Erik Svensson, Strategic Purchasing, at Emballator<br />
Tectubes comments: “As the first producer who used Green<br />
PE for our tubes, we faced a considerable challenge. Special<br />
compounds were developed, all processing parameters and<br />
the molds were optimized, and after several production<br />
trials and result analysis the optimum solution was reached.<br />
Again, the help of Polymerfront was extremely valuable.”<br />
Today, the company uses Green PE for tubes in a variety<br />
of sizes from 5 to 275 ml, and also uses this bioplastic to<br />
make caps.<br />
Another pioneer in the use of biobased polyethylene<br />
is LageenTubes, a leading manufacturer of tubes for the<br />
cosmetics, body, hair and oral care, pharmaceutical &<br />
food industries, headquartered in Kibbutz Yagur, Israel.<br />
They have been active worldwide and for more than 50<br />
years. The company uses Green PE for its sugarcane<br />
tubes, citing unrestricted recyclability as an important<br />
argument for Green PE. Timor Benari-Shuster, Marketing<br />
Communications Manager, says: “At the beginning, more<br />
than six years ago until recently, we had to do a lot of<br />
convincing work and had to demonstrate the suitability of<br />
biobased plastic with supporting facts about the durability<br />
and quality. Today, the industry has recognized that<br />
tubes made from Green PE have the same performance<br />
characteristics as conventional PE and are therefore<br />
suitable for cosmetic primary packaging. Lageentubes<br />
offers the sugarcane tube in both formats mono layer and<br />
co-ex 5 layers. A good argument was also that the change<br />
to Green PE does not require any changes in the production<br />
or investment in tooling.”<br />
At LageenTubes the opportunity to directly digitally print<br />
cosmetic tubes made from Green PE is also new. Benari-<br />
Shuster continues: “With this possibility, we now offer<br />
a revolutionary direct digital printing that allows design<br />
freedom such as end-to-end-printing including the cap,<br />
360° decoration without a gap or overlaps with realistic<br />
40 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
Applications<br />
images, shades, gradients, and halftones, customized and<br />
also personalized on-demand.” LageenTubes will present<br />
their sugarcane tube at CosmeticBusiness Hall 2 Stand<br />
B19.<br />
At its Wasungen (Germany) site, packaging specialist<br />
Tubex produces tubes made by co-extruding Green PE<br />
with a barrier plastic. Among other things, the company<br />
supplies Swox, a Munich-based manufacturer of special<br />
sun protection products for outdoor athletes.<br />
Katharina Kestler, Public Relations, at Swox affirms:<br />
“Our customers have a natural interest in protecting the<br />
environment and are fully aware of their responsibilities.<br />
That is why Swox also took a closer look at packaging and<br />
finally chose Green PE in close cooperation with Tubex.”<br />
Sandra Storandt, Account Manager Plastic Tubes at Tubex<br />
adds: “We see a steadily increasing customer<br />
demand for sustainable packaging solutions,<br />
which we can usually fulfill thanks to our<br />
close cooperation with the bioplastics expert<br />
FKuR, because Green PE is environmentally<br />
friendly, compatible with the product and easy<br />
to recycle.”<br />
A future-oriented user of such tubes is also the<br />
Austrian bio-cosmetic label Hands on Veggies.<br />
Its biocosmetic products, marketed under the<br />
same name, contain valuable ingredients from<br />
garden vegetables such as pumpkins, carrots,<br />
kale & co. Multitubes, a Dutch expert in the field<br />
of plastic tubes for cosmetic, food, pharmaceutical<br />
and industrial applications manufactures the tubes<br />
from Green PE and prints them with bright fresh<br />
colors. The use of biobased plastic also creates<br />
a real added value, as the company is showing the<br />
consumer that it is taking its environmental thinking<br />
to the very end and is adopting a logical conclusion.<br />
The beginning of a promising development<br />
Patrick Zimmermann, Director Sales & Marketing at<br />
FKuR summarizes: “Green PE offers ideal properties for<br />
this purpose. That’s why our cooperation with cosmetic<br />
tube manufacturers is already very successful. But in fact,<br />
we see the examples given here only as the beginning of a<br />
promising development. They show how biobased plastics<br />
can be used to particular advantage in this area of<br />
application, because they also clearly point out the<br />
environmental awareness of brand owners on the<br />
point of sales.<br />
Based on this, we are involved in the development<br />
of further tube applications in the cosmetics and<br />
healthcare sectors, where we advise on application<br />
technology and if necessary also develop customerspecific<br />
modifications of our bioplastics. A good example<br />
of this is our Terralene PP as a partially biobased<br />
plastic with the properties of polypropylene, used for the<br />
production of e. g. the caps with and without film hinges.”<br />
www.fkur.com |<br />
www.fkur-polymers.com |<br />
http://plasticoverde.braskem.com.br/site.aspx/plastic-green |<br />
http://tectubes.com/en/green-pe-tubes/ |<br />
www.lageentubes.com/2016/10/02/1111/ |<br />
www.tubex.de/kunststofftuben.html |<br />
www.swox.com/de/produkte/ |<br />
www.handsonveggies.de/ |<br />
https://multitubes.nl/bio-based/|<br />
By:<br />
Patrick Zimmermann<br />
Director Marketing & Sales<br />
FKuR Kunststoff<br />
Willich, Germany<br />
Multitubes<br />
Lageen<br />
Tubes<br />
Tubex / Swox<br />
Emballator<br />
Tectubes<br />
bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 41
Application News<br />
Automotive<br />
Plant-based performance shoes<br />
Leading global barefoot shoe company Vivobarefoot<br />
(London, UK) recently announced the launch of Primus<br />
Lite II Bio, the company’s most innovative sustainable<br />
shoe to-date and one of the world’s first plant-based<br />
performance shoes. The mission-driven brand unveiled<br />
the highly anticipated unisex shoe on the heels of<br />
independent sustainability research, which highlighted<br />
eco materials as a key<br />
factor in consumer<br />
purchasing decisions.<br />
The Primus Lite II Bio<br />
has been available in a<br />
limited run online since<br />
May 20 th , <strong>2019</strong>.<br />
The new vegan shoe is<br />
designed with over 30 %<br />
renewable plant-based<br />
materials, including Bio<br />
TPU made from yellow<br />
dent field corn, natural<br />
rubber and harvested algae called Bloom, instead of<br />
single-use petroleum materials. The design is the<br />
company’s lightest and most efficient performance shoe<br />
yet and weighs on average an estimated 10 % less than<br />
today’s standard performance shoes.<br />
The new generation of Vivobarefoot’s legacy Primus<br />
Lite style is a game-changer for the footwear industry<br />
and represents a major stride for the company towards<br />
its goal of using 100 % biobased materials in a future<br />
iteration of this product.<br />
Vivobarefoot’s sustainability ethos is uniquely different from<br />
other footwear brands in the industry, as it is rooted in design,<br />
wellness and social impact, along with utilizing eco-friendly<br />
materials. The company believes product design encompasses<br />
doing more with less and creating durable products. Its focus<br />
on wellness enables people to move in a natural, healthy,<br />
connected way, while maintaining performance and durability.<br />
“The launch of the<br />
Primus Lite Bio represents<br />
an exciting step away from<br />
the industry’s reliance<br />
on single use petroleumbased<br />
materials and<br />
towards a promising<br />
future of plant-based<br />
alternatives,” said Asher<br />
Clark, Design Director at<br />
Vivobarefoot. “We want<br />
to challenge the world’s<br />
relationship with shoes, the<br />
materials they are made from and the impact they are having<br />
on us and our environment. Our ultimate goal is complete<br />
circularity.”<br />
More than 20 billion pairs of shoes are made annually, most<br />
from petrochemicals, which have a harmful impact on the<br />
environment, contributing to the already serious effects of<br />
climate change. The plant-based materials in the Primus Lite<br />
II Bio shoe are sourced and managed responsibly, reducing<br />
water, energy and CO 2<br />
emissions, improving waste water and<br />
ultimately reducing their ecological footprint. MT<br />
www.vivobarefoot.com<br />
Swedish outdoor brand switches to bioplastic<br />
As of this year Swedish Light my Fire (Malmö) transitioned<br />
its entire product line to biobased plastics, featuring a new<br />
palette of warm and soft colors inspired by nature. “We’re<br />
always looking to use the most sustainable raw materials,”<br />
says CEO Calill Odqvist Jagusch. “By experimenting with<br />
various biobased plastics, we’ve found a solution that meets<br />
our sustainability objectives while not compromising on our<br />
product’s functionality and durability.”<br />
Biobased plastics are still in their infancy, and as they<br />
continue to blaze trail LMF wants to share its knowledge<br />
and be as transparent as possible. To this end, LMF has<br />
prepared a “Little School of Plastic” mini-tutorial and a<br />
fully transparent overview of all their product materials<br />
and suppliers in “Let’s Talk Materials,” both found on their<br />
website.<br />
Plastic pollution in nature is a tragedy – and with proper<br />
recycling and behavioral changes, it’s completely avoidable.<br />
Much of plastic pollution currently consists of single-use<br />
items like plastic straws, forks and packaging, and until<br />
recycling becomes widespread single-use items really have<br />
no place in a sustainable world.<br />
“Products like our ReStraw, Pack-up-Cup and Spork are in<br />
fact durable, reusable replacements of many of these singleuse<br />
items,” explains Calill Odqvist Jagusch. “However, like<br />
most other brands, we’ve used single-use plastics in our<br />
packaging. Moving forward, this year we plan to remove singleuse<br />
plastics in all our packaging using RE-PET storage bags as<br />
well as recycled and<br />
recyclable cardboard<br />
where needed.”<br />
Light My Fire has<br />
cooperated with SK<br />
Chemicals, of South<br />
Korea, Hexpol and<br />
FKuR to arrive at the<br />
selection of bioplastic<br />
materials appropriate<br />
for their products,<br />
taking issues such as<br />
durability and foodcontact<br />
approvals into<br />
account. MT<br />
www.lightmyfire.com<br />
42 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
Application News<br />
Spectacles from coffee and flax<br />
www.ochis.coffee<br />
The first Kickstarter campaign with a collection of sunglasses, made from organic coffee residues and flax resulting in durable<br />
eyewear that smells of coffee, was a full success in 2018. Now Ochis Coffee (Washington DC, USA) launched a new collection<br />
of Ochis Coffee eyewear. Founder Max Gavrilenko wanted to avoid the use of petroleum based plastic: “We use recyclables for<br />
the glasses production: coffee grounds and flax. They’re glued together by a biopolymer based on vegetable oil,” Max said. the<br />
frame smells slightly of freshly roasted coffee and has a matte<br />
texture that is pleasant to the touch. The polarized lenses with<br />
UV-filter are made of cellulose triacetate and feature an antiscratch<br />
coating.<br />
According to Ochis, the frames decompose 100 times faster<br />
than ordinary plastic glasses. In fact, the frame completely<br />
degrades after 10 years in soil or water, and turns into a<br />
natural fertilizer should the wearer lose it. There are four<br />
colours of Carl Zeiss lenses available and the frames are Rxable.<br />
The new spring <strong>2019</strong> collection was again introduced in<br />
a new Kickstarter campaign. MT<br />
First modular storage system<br />
from Bio-on’s bioplastic<br />
Only a few short months following the announcement of<br />
the alliance between Kartell (Noviglio, Italy), a leading design<br />
company, and biotechnology company Bio-on (Bologna, Italy),<br />
the first fruits of the partnership are being exhibited at the<br />
Salone del Mobile, Milan (Italy).<br />
Kartell has chosen to produce a new eco-friendly and<br />
sustainable edition of one of its best sellers - a modular<br />
storage unit designed in 1967 by Anna Castelli Ferrieri - in<br />
Bio-on’s 100% natural bioplastic material. The 50-year old<br />
design is available in four colours: green, pink, cream and<br />
yellow in the three-module version.<br />
For Kartell, research is a mission, said company president<br />
Claudio Luti. “We will continue to experiment to combine<br />
innovation and design.”<br />
Kartell celebrates its 70 th anniversary this year, thus ‘we are<br />
happy to be able to reach another milestone’, he added.<br />
“We have worked with Bio-on to be able to offer our public a<br />
very high-quality bioplastic product and we have chosen to do<br />
it on one of our historic products, one of the most recognized<br />
in the world. Research on bioplastics fits with our quest for<br />
innovation and is part of the “Kartell loves the planet” project<br />
aimed at enhancing good sustainability practices.”<br />
For Bio-on, it is ‘an honour’, said founder and CEO Marco<br />
Astorri. The company is proud to see its bioplastic showcased<br />
with one of the most famous Italian design brands in the<br />
world. To reciprocate and in gratitude for the trust placed in<br />
the material, Bio-on has given the biopolymer used for this<br />
specific application the name CL, the initials of Claudio Luti.<br />
In just a few days, Bio-on first saw the launch of the first<br />
line of solar cosmetics based on its technology, and now<br />
the first piece of furniture. “It is a clear confirmation of the<br />
extreme versatility that our biopolymer can offer, bringing its<br />
extraordinary advantages to all sectors,” Astorri concluded... MT<br />
www.bio-on.it<br />
bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 43
Applications<br />
This spoon does the rest!<br />
Whether yoghurt cups or jam jars, peanut butter,<br />
chocolate cream, bottled baby food or other packaged<br />
pasty food: significant residual quantities<br />
remain in all the containers of these products even after<br />
they have been emptied. In some cases, we lose up to 10%<br />
of the contents of food packaging, because their special<br />
shapes make it impossible to remove the products completely.<br />
When having almost completely emptied a jar, some<br />
of us will ambitiously try to take out even this last remnant.<br />
A normal tablespoon or teaspoon is not an ideal means<br />
for emptying a recipient completely, to avoid cleaning before<br />
waste disposal. The water which is consumed for this<br />
purpose needs to be cleaned at high costs, too. Additional<br />
resource consumption is the consequence.<br />
Thomas Griebl, a designer from Oberschneiding,<br />
Germany, who has been working for many years as movie<br />
and stage designer now developed the Balaenos ® - spoon.<br />
The whale<br />
For Thomas<br />
b i o n i c s<br />
should be<br />
an important<br />
aspect of design.<br />
This is very well<br />
illustrated by whales, whose bodies<br />
are excellently shaped for their<br />
natural habitat. For long periods they<br />
have been able to adapt themselves<br />
to their environment. With the aim of<br />
optimizing, evolution has thereby formed back a l l<br />
features which are not required any longer. The eponym<br />
of the Balaenos- spoon, the bowhead whale (Balaena<br />
mysticetus), even gets along without a dorsal fin. It is the<br />
only whale species who doesn’t have one.<br />
The idea for designing the Balaenos- spoon came up<br />
when “plunging” into the yoghurt jar or when “fishing”<br />
for remnants of its contents. Both the spoon’s design and<br />
function were inspired by this animal.<br />
The spoon<br />
Balaenos - spoons are made in one work-step from<br />
thermoplastic resin in an injection moulding process. Its<br />
special shape distinguishes this spoon from conventional<br />
spoons and it simplifies the uncomfortable gathering or<br />
scraping of remaining residual quantities. The spoondesign<br />
is copyrighted at the German Patent Office and<br />
internationally protected by WIPO.<br />
Inspired by an international major debate on how to avoid<br />
plastic waste and in view of the long-term environmental<br />
pollution by conventional plastics, Thomas and his team<br />
decided to manufacture the spoon from a biobased and<br />
biodegradable PLA compound. “By using biopolymers, both,<br />
we and the users, try to achieve the aim of a sustainable and<br />
ecologically safe use of plastic materials in the household<br />
and to reduce environmental pollution,” Thomas says.<br />
The PLA material used for Balaenos consists to approx.<br />
70% of renewable raw materials and works therefore as a<br />
carbon-dioxide buffer storage. It can be completely recycled,<br />
used for energy production, or led back into the ecological<br />
cycle, after use. Of course, the material is FDA compliant and<br />
approved for use with food.<br />
The special compound makes the spoon resistant<br />
to temperatures of approx. 75°C. It is therefore not<br />
recommended to clean the spoon in the dishwasher, but<br />
better wash it by hand like other natural materials (such as<br />
wooden knife handles and kitchen utensils).<br />
The spoon is home compostable, if such a possibility exists.<br />
Mechanical comminution like grinding or rasping accelerates<br />
this biological degradation.<br />
The Balaenos - spoon is available in two different sizes. The<br />
two versions of the spoon are based on the usual dimensions<br />
for cutlery.<br />
The idea behind<br />
Balaenos is to design<br />
a complete range<br />
of everyday utensils<br />
which are produced as sustainably as<br />
possible. Their materials are derived from nature in a<br />
resource-saving way, in order to return them to their natural<br />
cycle at the end of their lifetime.<br />
The uniform design language<br />
evokes their<br />
models from<br />
nature and<br />
our contact<br />
with nature<br />
as an integral<br />
part of it.<br />
“Simple and widely used products, at best produced<br />
locally at low cost, sold via different distribution channels,<br />
will enrich our everyday life with new, renewable materials,<br />
and can substantially influence our attitude and our general<br />
behaviour towards existing resources,“ Thomas Griebl<br />
says.“ Much could be achieved when the special spoon on<br />
the breakfast table, the hygiene product in the bathroom or<br />
small office accessories create awareness that we are not<br />
consumers, but users, who think in terms of closed circuits!”<br />
Balaenos will be manufactured completely in southern<br />
Germany and customized and despatched in-line with<br />
customers’ requirements. Sustainability is also kept in mind<br />
for packaging materials, by using cardboard from grass<br />
paper and films from biodegradable PLA.<br />
Domestic production for the German and the adjacent<br />
European markets avoids long transport routes from overseas<br />
and multiple transport itineraries to the end users. MT<br />
www.balaenos.de<br />
44 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
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bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 45
Materials<br />
Pack it in feathers<br />
pluumo – The world’s first feather-based,<br />
sustainable packaging material<br />
Thousands of tonnes of waste feathers are generated<br />
every day by the global poultry industry. The average<br />
amount of meat consumed per person globally has<br />
more than doubled in the past 50 years, e.g. from 23 kg<br />
in the 1960s to 69 kg in 2016 in the European Union [1].<br />
This has a massive impact not only on anthropogenic GHG<br />
emissions, but also continues to create a huge amount of<br />
waste. In the EU alone, over 20 million tonnes of animal-byproducts<br />
(ABP) are produced annually and over 3.1 million<br />
tonnes of this material are feathers from poultry production.<br />
Feathers protect birds from adverse weather conditions<br />
and are inherently biodegradable in their nature. Honing<br />
in on these two properties; the team of AEROPOWDER<br />
(London, UK) has conducted comprehensive manufacturing<br />
testing in order to harness the beneficial assets of feathers<br />
and create a high-performance feather-based material.<br />
Other early-stage product ideas included water-proof<br />
coatings and composite materials. After several years of<br />
development, the team just launched a sustainable textile<br />
named pluumo, designed to be a highly effective insulation<br />
material. The material comes in the form of sheets and<br />
batts and is applicable in a variety of sectors, such as<br />
building, automotive and furniture. However, the initial<br />
focus is on packaging, using the novel textile as a featherbased<br />
thermal insulator for chilled shipments. pluumo is<br />
composed of feathers making it lightweight. Additionally, its<br />
packaging film is fully compostable, and it also adheres to<br />
strict environmental standards. The film is supplied by biofilm<br />
expert Nuova Erreplast in Italy, which conventionally<br />
produce flexible packaging. A pivotal role in the company<br />
policy is played by the search for new technologies and<br />
sustainable packaging solutions, aiming at having a low<br />
impact on the environment: one of the reasons why Nuova<br />
Erreplast embraced the pluumo project.<br />
Elena Dieckmann (CTO, Aeropowder) states: “The current<br />
discourse about the environmental impact of packaging is<br />
huge, and rightly so. We thought we could create a circular<br />
packaging product that is eco-friendly, waste-derived<br />
and high performance. Feathers can replace synthetic<br />
insulators, such as polyethylene foams or polystyrene (EPS)<br />
without loss of performance. In the booming industry that<br />
is online food delivery, this means that for every standard<br />
sized packaged being sent to a customer, around 400g of<br />
EPS packaging are avoided.”<br />
In order to create a fully compostable product, Aeropowder<br />
connected with Trevira (Bobingen, Germany), an innovative<br />
European manufacturer of high-value branded fibres<br />
and filament yarns. Trevira provided a solution in form of<br />
innovative, fully biodegradable binding fibres used to fuse<br />
the feather fibres together. These recyclable binding fibres<br />
are bicomponent fibres consisting of the biopolymers<br />
polylactic acid (PLA) and polybutylene succinate (PBS).<br />
“Fibres made from biopolymers are a sustainable alternative<br />
to petroleum-based fibres and provide a basis for intelligent<br />
materials with added functions, for new applications and for<br />
niche products,” says Joerg Dahringer of Trevira. “They are<br />
as economical as they are efficient.” And Elena Dieckmann<br />
adds: “ For us, Trevira was the ideal partner – they are real<br />
pioneers of sustainability and have the technical expertise to<br />
create customized products.”<br />
Compostability test for the whole pluumo product are<br />
currently performed with accredited laboratories in Europe.<br />
In addition to biodegradability, pluumo must observe certain<br />
cold chain delivery requirements with regards to its insulative<br />
performance. Therefore, pluumo was tested extensively<br />
in collaboration with several research facilities in the UK.<br />
The product has been designed to outperform conventional<br />
EPS packaging (30 mm) by several hours. The secret to this<br />
impressive performance is down to the structure of feathers<br />
themselves.<br />
Feathers are made of keratin, an integral building block in<br />
nature. A unique feature of feather composition is their hollow<br />
microstructure traps air. Preventing movement of air is critical<br />
to preventing conductive heat transfer and thus tied directly to<br />
insulative performance. The team at Aeropowder have found<br />
a way to optimise the arrangement of feather fibres within<br />
the structure of pluumo, resulting in the material having a<br />
thermal conductivity 0.<strong>03</strong>2 W/mk. Additionally, the strength<br />
of keratin means that pluumo retains its structural integrity<br />
after impact, providing additional cushioning protection for<br />
fragile items. pluumo’s specifications are also customisable<br />
in terms of height and density to meet a variety of demanding<br />
applications.<br />
Currently, Aeropowder is supplying pluumo Europe-wide,<br />
but its potential is wide-reaching. Wherever poultry found,<br />
pluumo and other innovative sustainable materials can be can<br />
be manufactured. MT<br />
[1]: OECD-FAO Agricultural Outlook 2017-2026;<br />
http://www.fao.org/3/a-i7465e.pdf<br />
www.pluumo.com<br />
46 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
Materials<br />
Novel biobased barrier films<br />
According to recent forecasts by European Bioplastics<br />
and nova Institute, global production of biopolymers<br />
will increase from about 2.05 million tonnes in 2017<br />
to 2.44 million tonnes in 2022. The trend towards biobased<br />
and biodegradable plastics was induced mainly by the global<br />
waste problem and increasing environmental regulations<br />
for the industry. Consumers’ growing environmental awareness<br />
also has a beneficial effect for the bioplastics sector.<br />
Furthermore, certain bioplastics offer technical advantages.<br />
Due to its unique barrier properties towards oxygen,<br />
nitrogen and carbon dioxide, polylactide (PLA), for example,<br />
is already being successfully applied in the packaging industry<br />
- the largest field of application for biopolymers.<br />
This is where the Bio-Barrier Films (BioBaFol) project ties<br />
in, which was launched as part of the support programme<br />
for Renewable Resources by the German Federal Ministry<br />
of Food and Agriculture (BMEL). The project partners,<br />
SKZ, Fraunhofer Institute for Silicate Research, Tecnaro,<br />
JenCAPS Technology and Südpack Packaging (all from<br />
Germany) are jointly developing PLA-based films with<br />
special barrier properties for the food, pharmaceutical<br />
and cosmetics industries. An inorganic-organic functional<br />
layer integrated in these films is intended to improve<br />
the films’ barrier effect in comparison to conventional<br />
multilayer films. Such hybrid polymers are already being<br />
used in numerous fields of application, such as photoand<br />
electrochromic, scratch- and abrasion-resistant or<br />
antistatic coatings. These excellent barrier properties are<br />
now being evaluated for use in food packaging and flexible<br />
encapsulation of optoelectronic applications.<br />
Conventional barrier films are mainly covered by<br />
laminated composites. These usually consist of duplex<br />
sheets wherein two different films are bonded together<br />
by coextrusion. Application-specific polyolefins are added<br />
In the framework of the Bio-Barrier Films (BioBaFol) project, the<br />
SKZ and several project partners are jointly developing PLA-based<br />
films with special barrier properties for food, pharmaceutical and<br />
cosmetics industries.<br />
as sealing media. These laminated composites currently<br />
cannot be broken down into their individual components,<br />
and thus cannot be recycled. “The use of a hybrid polymer<br />
layer on a PLA carrier material is now intended to facilitate<br />
the recycling process,” explained SKZ scientist Alexander<br />
Rusam. “During renewed film extrusion, this layer can be<br />
incorporated in the polymer matrix and can thus serve both<br />
as a nucleating agent for crystallization and as an additional<br />
barrier filler material. It is therefore not necessary to<br />
separate the barrier layer from the PLA carrier material,<br />
and recycling will thus be possible in the future. “<br />
Besides feasibility, by the end of the project period, in mid<br />
2021, a scale-up at pilot-scale is also aimed at. MT<br />
www.skz.de<br />
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bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 47
Basics<br />
Captured carbon vs. biobased<br />
Can products made from captured/recycled CO 2<br />
be called biobased?<br />
B<br />
iobased carbon content and captured or recycled<br />
carbon content are two separate metrics, though not<br />
always exclusive of each other. Biobased content is<br />
based upon the source of the raw material and is thus a ‘beginning<br />
of life’ concept. On the other hand, recycled or captured<br />
carbon content is based upon an ‘end of life’ action of<br />
e.g. incineration. As such, it is important to understand the<br />
differences between the two carbon content types and why<br />
each needs to be treated differently when developing standards<br />
for measurement or determination.<br />
Defining biobased<br />
The term biobased is used to describe materials (products<br />
and/or chemicals) derived in whole or in part from biomass<br />
resources; organic materials available on a continuous basis<br />
(i.e. renewable) from terrestrial and marine agricultural, plant,<br />
animal, and fungal sources living in a natural environment in<br />
equilibrium with the atmosphere (ref D6866, USDA, Farm Bill,<br />
EU). The phrase “living in a natural environment in equilibrium<br />
with the atmosphere” in the definition is critical because it<br />
provides for the absolute measurement of the biobased<br />
carbon content of a product using radiocarbon (carbon-14)<br />
analysis, and validates the amount of carbons originating<br />
from plant-biomass resources.<br />
There are three naturally occurring isotopes of carbon: 12 C,<br />
13<br />
C, 14 C and all are present in living organisms. Carbon-14<br />
( 14 C), however, is radioactive. The living systems maintain their<br />
C-14 content in equilibrium with atmospheric C-14. In other<br />
words, all plant-biomass feedstocks will contain the same<br />
level of C-14 as the atmosphere does. When a living plant or<br />
animal dies, it ceases to take up C-14, and thus no longer<br />
maintains an equilibrium level of C-14 with atmospheric C-14.<br />
The amount of C-14 in the carbon from this material will then<br />
decay exponentially from the equilibrium level with a half-life<br />
of 5730 years. Products made from biomass feedstocks like<br />
agricultural, plant, animal, marine, and forestry materials will<br />
still retain 100% of C-14 radioactivity for a long period of time<br />
(only 1% of radioactivity is lost after 100 years). Fossil carbons<br />
in products will have zero radioactivity as they are formed<br />
over millions of years. The ASTM & ISO test methods use the<br />
above radiocarbon concept to quantify the biobased carbons<br />
originating from the biomass feedstocks. The amount of<br />
biobased carbon in a given sample can be determined using<br />
radiocarbon dating, which measures the amount of carbon-14<br />
present.<br />
Because carbon present in biobased materials is recently<br />
captured from the atmosphere, the combustion and release<br />
of carbon dioxide (CO 2<br />
) from biobased material results in a<br />
net zero carbon footprint: if this carbon dioxide is captured<br />
or recycled, then this is also biobased captured or recycled<br />
carbon dioxide. In contrast, fossil fuel-derived material is<br />
formed over millions of years (devoid of carbon-14) and thus<br />
combustion of fossil fuels adds to the atmospheric levels<br />
of carbon dioxide. But, as will be discussed later, the use of<br />
captured or recycled CO 2<br />
partially mitigates this addition of<br />
greenhouse gases into the atmosphere.<br />
Test standards for biobased testing<br />
Carbon-14 testing is performed according to widely<br />
accepted test standards such as ASTM D6866 and ISO<br />
16620-2. ASTM D6866 is a standard test method used<br />
for determining the biobased content of solid, liquid and<br />
gaseous samples using radiocarbon dating [3]. Likewise,<br />
ISO 16620-2 is an international standard test method<br />
for determining the biobased content of solid, liquid and<br />
gaseous samples using carbon-14 analysis [4].<br />
After analyzing a sample, the result is cited as percent<br />
modern carbon (pMC) and reported as percent biobased<br />
carbon content (or simply percent biobased content). A<br />
result of zero pMC indicates a sample is wholly derived<br />
from fossil carbon and does not contain any measurable<br />
carbon-14. In contrast, one hundred pMC represents a<br />
sample comprised entirely of biobased carbons from plantbiomass<br />
resources. If the pMC value is between 0 and<br />
100, the content is a mixture of fossil carbon and biobased<br />
carbon. Under ASTM D6866, this percentage is a measure<br />
of the amount of biomass-derived carbon in a product<br />
compared to its total organic carbon (TOC) content. ISO<br />
16620-2 uses this terminology as well [3, 4].<br />
Certifying biobased products<br />
Carbon-14 testing has been used for over a decade<br />
to validate biobased claims and often to receive product<br />
eligibility for third-party certifications and eco-labels. ISO-<br />
17025 accredited laboratory Beta Analytic has tested the<br />
percent biobased content of over a thousand samples within<br />
a wide range of product types. The biobased approach has<br />
qualified over 2,500 biobased products in the marketplace<br />
today [5].<br />
Globally, there are several biobased certification<br />
programs. The United States Department of Agriculture<br />
(USDA) BioPreferred ® Program requires the measurement<br />
of the biobased content of products according to the<br />
ASTM D6866 standard. This program includes two parts: a<br />
mandatory federal purchasing requirement and a voluntary<br />
labeling program for biobased products. The USDA has<br />
identified over 100 product categories with a minimum<br />
biobased content established per category for which federal<br />
agencies have purchasing requirements. Furthermore, the<br />
voluntary labeling initiative allows companies to receive<br />
the USDA Certified Biobased Product certification label on<br />
products that exceed the minimum threshold of biobased<br />
content required for the specific product category. This has<br />
certified over 2,500 products [6]. Several of these products<br />
may also be certified by other programs such as TÜV<br />
AUSTRIA’s OK biobased (using a a star system: one-star<br />
is for products with biobased content between 20% and<br />
40% while a four-star certified product contains over 80%<br />
48 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
Basics<br />
By:<br />
Kelvin Okamoto, Green Bottom Line, Chair of ASTM D20.96<br />
Ramani Narayan, Michigan State University, Former Chair of ASTM D20.96<br />
Stephany Mason, Beta Analytic<br />
Haley Gershon, Beta Analytic<br />
biobased content [7] and DIN CERTCO’s DIN-Geprüft (with<br />
three quality divisions: Biobased 20-50%, Biobased 50-85%,<br />
and Biobased >85%) [8] in Europe.<br />
Beyond those mentioned above, biobased testing has been<br />
incorporated into many other eco-labeling programs and<br />
biobased product initiatives. These include but are not limited<br />
to Japan BioPlastics Association’s BiomassPla certification,<br />
Canada’s EcoLogo Program, French Decree 2016-379 on<br />
Single-Use Plastic Bags, and Italy’s EU Directive 2015/720 on<br />
Biobased Plastic Bags.<br />
Products manufactured from captured/recycled CO 2<br />
To reiterate, in order to be called ‘biobased’ a product or<br />
chemical needs to be manufactured from renewable, plantbiomass<br />
living systems that exist in a natural environment in<br />
equilibrium with atmospheric CO 2<br />
. Products obtained from<br />
converting smokestack CO 2<br />
from coal, natural gas or other<br />
fossil fuel burning systems do not fall under the ‘biobased’<br />
definition and do not lend themselves to quantitative analysis<br />
by radiocarbon measurement (ASTM D6866) since these<br />
products do not contain any carbon-14 content.<br />
Therefore, PHAs and algae-based products, polymers, or<br />
chemicals produced from only petroleum-based smokestack<br />
CO 2<br />
are not “biobased.”<br />
However, these products are beneficial to<br />
the environment by removing CO 2<br />
during<br />
production that would otherwise be emitted<br />
back into the atmosphere.<br />
By using recycled CO 2<br />
the product manufacturing process<br />
also does not require the burning of additional fossil fuels.<br />
Again, this reduces the emissions of carbon dioxide into the<br />
atmosphere.<br />
There are, however, fuel combustion sources that burn<br />
municipal solid waste (MSW) or mixed fuels (biomass-derived<br />
and fossil fuel). Any captured or recycled CO 2<br />
from these sources<br />
will have a radiocarbon signal. The US EPA Greenhouse Gas<br />
(GHG) reporting rule requires the determination of the biogenic<br />
(biomass-derived) CO 2<br />
contribution from these sources using<br />
the ASTM D6866 standard. Thus, products made from these<br />
sources of captured CO 2<br />
may have biobased content.<br />
Conclusion<br />
While products derived from recycled CO 2<br />
may provide<br />
environmental benefits, they do not always meet the<br />
requirements to be considered as biobased products. There<br />
are over 2,500 products certified under the USDA BioPreferred<br />
Program based on testing per ASTM D6866 and countless<br />
products in Europe and Asia that qualify as biobased and<br />
whose biobased carbon content can be accurately validated.<br />
Modifying the existing D6866 (and ISO) standards to<br />
accommodate products made with recycled carbon dioxide<br />
devoid of carbon-14 content could negatively impact the<br />
credibility and market acceptance of biobased products and<br />
open the door to non-verifiable products. Separate verifiable<br />
standards and validation criteria for environmental benefit<br />
should be developed for these products. Approaches using<br />
carbon tagging or an audit approach would be useful to<br />
develop. Future standards for products captured from<br />
recycled CO 2<br />
containing only petroleum-based carbon are<br />
critical in order to develop this new class of chemicals and<br />
polymers.<br />
References<br />
1. Narayan, Ramani, The Promise of Bioplastics - Bio-Based and<br />
Biodegradable-Compostable Plastics, Editor: Kabasci, Stephan Bio-<br />
Based Plastics, Chapter 14, 347-357, 2014, DOI:10.1002/9781118676646<br />
2. Ramani Narayan, Biobased & Biodegradable Polymer Materials:<br />
Rationale, Drivers, and Technology Exemplars; ACS (an American<br />
Chemical Society publication) Symposium Ser. 1114, Chapter 2, pg 13-31,<br />
2012<br />
3. ASTM International. ASTM D6866 - 18, Standard Test Methods for<br />
Determining the Biobased Content of Solid, Liquid, and Gaseous Samples<br />
Using Radiocarbon Analysis. 2018.<br />
4. International Organization for Standardization. ISO 16620-2:2015,<br />
Plastics -- Biobased content -- Part 2: Determination of biobased carbon<br />
content. 2015.<br />
5. United States Department of Agriculture. Fact Sheet: Overview of<br />
USDA’s BioPreferred Program. (https://www.usda.gov/media/pressreleases/2016/02/18/fact-sheet-overview-usdas-biopreferred-program).<br />
6. United States Department of Agriculture. What is BioPreferred? (https://<br />
www.biopreferred.gov/BioPreferred/faces/pages/AboutBioPreferred.<br />
xhtml).<br />
7. TUV Austria. OK biobased. Belgium. (http://www.tuv-at.be/certifications/<br />
ok-biobased/).<br />
8. TUV Rheinland Din CERTCO. Certification Scheme Biobased Products in<br />
accordance with ASTM D 6866 and/or ISO 16620, Parts 1-3 and/ or DIN<br />
SPEC 91236 (DIN CEN/TS 16137). Berlin, Germany, 2015. (https://www.<br />
dincertco.de/media/dincertco/dokumente_1/certification_schemes/<br />
Biobasierte_Produkte_biobased_products_certification_scheme.pdf).<br />
Want to help ASTM D20.96 ?<br />
ASTM D20.96 Environmentally Degradable Plastics and<br />
Biobased Products subcommittee is moving forward with<br />
developing a recycled/capture carbon content standard and is<br />
actively seeking individuals interested in helping. If you have<br />
interest in this, please email Kelvin Okamoto<br />
(kelvin@greenbottomline.com).<br />
Biobased vs. recycled CO 2<br />
bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 49
new<br />
series<br />
Bioplastic Patents<br />
By:<br />
Barry Dean,<br />
Naperville, Illinois, USA<br />
U.S. Patent 10,087,305 (October 2, 2018): “Nucleated<br />
Crystallization of Poly(Trimethylene-2,5-Furandicarboxylate)<br />
(PTF) and Articles Made Therefrom”, Gordon Mark Cohen,<br />
Frederik Nederberg, Bhuma Rajagopalan, (E. I. DuPont De<br />
Nemours and Company. (Wilmington, DE USA)<br />
Ref: PCT WO2015/095466 EP<br />
The composition taught is a block copolymer consisting of<br />
a hard segment, poly(trimethylene-2,5-furandicarboxylate)<br />
and a soft segment, 2,5-furan dicarboxylate based<br />
poly(alkylene ether glycol). A critical teaching is the use<br />
of a nucleating agent, a neutralized carboxylic acid salt or<br />
trisodium phosphate, for promoting crystallization of the<br />
hard segment from the melt which is key for the injection<br />
molding process cycle time. The level of nucleating agent is<br />
1 – 2.5 weight %<br />
The ratio of hard segment to soft segment will influence<br />
bulk mechanical properties such as modulus, impact<br />
strength and compressive strength.<br />
This section highlights recently granted patents<br />
that are relevant to the specific theme/focus of<br />
the Bioplastics Magazine issue. The information<br />
offered is intended to acquaint the reader with<br />
a sampling of know-how being developed to<br />
enable growth of the bioplastics markets.<br />
The five patents cited demonstrate<br />
compositions and process for renewable/<br />
biodegradable injection moldable compositions.<br />
Key for injection molding are compositions that<br />
deliver bulk properties in the final article but also<br />
must offer fast cycle times for the production of<br />
the molded article.<br />
U.S. Patent 9,914,831 (March 13, 2018): ”Injection Molded<br />
Article”, Maximillian Lehenmeier, Gabriel Skupin, Martin<br />
Bussmann , (BASF SE, Ludwigshafen DE)<br />
Ref: PCT WO2015/169660<br />
This patent teaches an injection molding composition<br />
exhibiting an HDT of 80 – 105 C with balance of Charpy impact<br />
strength and modulus to allow for thin wall structures. The<br />
multi-component composition consists of 47 – 59 weight<br />
% of polyester derived from succinic acid and a C6 – C20<br />
aliphatic acid with 1,3-propanediol and 1,4-butanediol; 3-<br />
14 weight % of polyester derived from C6 – C20 aliphatic<br />
acid and terephthalic acid with 1,3-propanediol and<br />
1,4-butanediol; 15 – 24 weight % of polylactic acid and 10<br />
– 35 % mineral filler(eg talc). Chain extender is used in the<br />
polyesters to control molecular weight.<br />
The compositions illustrated are tailored to control<br />
HDT, modulus and impact based on application as well<br />
as injection molding cycle time and structure dimensional<br />
stability. Preferred applications are coffee capsules, coffee<br />
cup lids and tableware.<br />
The biodegradability/compostability of the injection<br />
molded article is determined by the polymer matrices<br />
selection.<br />
50 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
U.S. Patent 10,189,989 (January 29, <strong>2019</strong>): “Polyester<br />
Mixture Including Polyethylene-2,5-Furandicarboxylate”,<br />
Anne K. Moeller, Klan Molawi, Motomori Yamamato, (BASF<br />
SE)<br />
Ref: PCT WO2015/150141<br />
This patent teaches poly(cyclohexylenedimethylene-<br />
2,5-furandicarboxylate)(PCF) can be nucleated with<br />
poly(ethylene-2,5-furandicarboxylate). PCF is a semicrystalline<br />
polyester with a Tg of 86 – 87 C, Tm of 267 C and<br />
onset of recrystallization at 217 – 223 C. For the injection<br />
molding process a higher onset of recrystallization is<br />
important for both cycle time and dimensional stability.<br />
Other nucleating agents are shown to increase the onset of<br />
crystallization of PCF by 10 – 12 C while 1 weight % PEF is<br />
shown to increase the onset of nucleation of PCF to 243 C,<br />
an increase of 25 C relative to non-nucleated PCF.<br />
The patent also teaches that PEF can have nucleation<br />
benefits in other renewable polymers such as PBS and<br />
PBAT<br />
U. S. Patent 10,160,857 (December 25, 2018):<br />
“Thermoplastic Resin Composition and Molded Article<br />
Made Therefrom”, Chansu Kim, Kyunghae Lee, Jun Chwae,<br />
Mooho Lee, Kwangmyung Cho, (Samsung Electronics Ltd<br />
Korea)<br />
A thermoplastic composition based on a polylactic<br />
acid and a inorganic-organic particle tailored to improve<br />
impact strength and heat resistance is taught. The particle<br />
consists of an inorganic core and an organic coating layer<br />
on the core. Significant improvement in impact strength and<br />
heat resistance are illustrated when the inorganic-organic<br />
particle is based on organic coating layer that is a block<br />
copolymer for polycaprolactone and PLA. Lower impact<br />
strength and heat resistance are shown when the organic<br />
coating layer is either polycaprolactone or PLA or when the<br />
polycaprolactone/PLA layer is a copolymer and not a block<br />
copolymer. The inorganic particle diameter is less than 100<br />
nm. The thermoplastic composition illustrated is 74 % by<br />
weight PLA, 20 % by weight inorganic-organic particle and<br />
the remainder is a plasticizer and nucleating agent. The<br />
inorganic-organic particle can be ranged from 5 – 40 weight<br />
% to tailor properties.<br />
The organic layer that is taught as a block copolymer<br />
of polycaprolactone and PLA is key to enabling the bulk<br />
composition to offer improved impact strength and heat<br />
resistance compared with the polylactic acid matrix.<br />
U.S. Patent 10,240,007 (March 29, <strong>2019</strong>): “Shaped<br />
Polylactide Article and Method of Preparation”, Siebe<br />
Cornelis De Vos, Robert Edgar Haan, Geraldus Gerardus<br />
Johannes Schennink, (Purac Biochem BV Netherlands)<br />
Ref: PCT WO2016/102163<br />
This patent teaches a method to maximize the formation<br />
of the stereocomplex(sc) crystallinity from mixtures of two<br />
enantiomers PLLA and PDLA. The method consists of<br />
mixing a first homopolylactide with an excess of a second<br />
homopolylactide where the first and second homopolylactide<br />
are poly-L-lactide(PLLA) or poly-D-lactide(PDLA). This<br />
mixing is done in the molten state and the pellets allowed<br />
to cool and crystallize as a blend of the sc-PLA. The pellet<br />
sc-PLA is blended with pellets of the first homolactide and<br />
melt processed into an article where the melt processing<br />
temperatures are above the melting points of the PLLA<br />
and PDLA(Tm= 175 C) but below that of the sc-PLA(Tm =<br />
230 - 240 C). This method maintains the modulus, impact<br />
and elongation while providing an increase in bulk thermal<br />
performance via maximizing the sc-PLA.<br />
bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 51
Brand Owner<br />
Brand-Owner’s perspective<br />
on bioplastics and how to<br />
unleash its full potential<br />
With bioplastics we see an opportunity to increase the renewable content<br />
in our cars, but there are still some concerns regarding availability and<br />
recyclability in some cases. At this stage, we see the use of renewable fibres<br />
for reinforced plastics as the first option to increase bio-content. The addition<br />
of a portion of renewable raw material in normal plastics production, and<br />
calculate the biomass balance, would also be an option for us.<br />
www.volvocars.com<br />
Christina Zander, spokeswoman for Volvo<br />
‘Basics‘ book on bioplastics<br />
This book, created and published by Polymedia Publisher, maker of<br />
bioplastics MAGAZINE is available in English and German language<br />
(German now in the second, revised edition).<br />
The book is intended to offer a rapid and uncomplicated introduction<br />
into the subject of bioplastics, and is aimed at all interested readers, in<br />
particular those who have not yet had the opportunity to dig deeply into<br />
the subject, such as students or those just joining this industry, and lay<br />
readers. It gives an introduction to plastics and bioplastics, explains which<br />
renewable resources can be used to produce bioplastics, what types<br />
of bioplastic exist, and which ones are already on the market. Further<br />
aspects, such as market development, the agricultural land required, and<br />
waste disposal, are also examined.<br />
An extensive index allows the reader to find specific aspects quickly,<br />
and is complemented by a comprehensive literature list and a guide to<br />
sources of additional information on the Internet.<br />
The author Michael Thielen is editor and publisher bioplastics<br />
MAGAZINE. He is a qualified machinery design engineer with a degree<br />
in plastics technology from the RWTH University in Aachen. He has<br />
written several books on the subject of blow-moulding technology and<br />
disseminated his knowledge of plastics in numerous presentations,<br />
seminars, guest lectures and teaching assignments.<br />
110 pages full color, paperback<br />
ISBN 978-3-9814981-1-0: Bioplastics<br />
ISBN 978-3-9814981-2-7: Biokunststoffe<br />
2. überarbeitete Auflage<br />
Order now for € 18.65 or US-$ 25.00 (+ VAT where applicable, plus shipping and handling, ask for details)<br />
order at www.bioplasticsmagazine.de/books, by phone +49 2161 6884463 or by e-mail books@bioplasticsmagazine.com<br />
Or subscribe and get it as a free gift (see page 61 for details, outside German y only)<br />
52 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
10 Automotive Years ago<br />
10<br />
Years ago<br />
Published in<br />
bioplastics<br />
MAGAZINE<br />
In May <strong>2019</strong>,<br />
Tim Colonnese,<br />
CEO, KTM,<br />
said:<br />
Rigid Packaging<br />
Thermal<br />
Cooler Box<br />
S<br />
andoz, Inc. (Princeton, New Jersey, USA) and KTM<br />
Industries, Inc. (Lansing, Michigan, USA) recently<br />
announced the launch of the Green Cell Cooler<br />
Box - the first 100% biobased and completely compostable/recyclable<br />
thermal cooler to protect pharmaceutical<br />
products during shipment. The Green Cell Cooler Box is<br />
a standard corrugate box outer lined with panels of cornstarch-based<br />
Green Cell Foam, manufactured by KTM.<br />
Green Cell Foam meets ASTM D400 and ISO 108 specifications<br />
for biodegradability under composting conditions.<br />
Led by Mark Kuhl, Packaging Development Manager<br />
for Sandoz, the project was in response to a new way of<br />
thinking at Sandoz where sustainability has become a<br />
top priority. This was a perfect opportunity to shift the<br />
paradigm and find a packaging solution that utilizes<br />
bio-renewable resources and offers an environmentally<br />
responsible end-of-life option.<br />
The typical pharmaceutical insulated shipper is<br />
constructed with polystyrene and is used for 24-2 hours<br />
before it is discarded. Non-renewable polystyrene is<br />
recyclable but the facilities to enable this are limited and<br />
cost prohibitive, thus relegating it to landfills. Sandoz’<br />
mission was to find an effective sustainable alternative<br />
to polystyrene based on biofeedstocks that would<br />
assimilate back into nature after its use. The mission was<br />
accomplished with Green Cell Foam which is compostable<br />
and can be recycled in the paper recycling stream along<br />
www.greencellfoam.com<br />
with the outer box, thereby affording the end user with<br />
flexibility in the end-of-life disposal process.<br />
Mr. Kuhl set out to design, test and validate a cost effective<br />
‘green’ cooler that met the rigorous cold-chain shipping<br />
requirements for protecting sensitive pharmaceutical<br />
products. During his tests he discovered Green Cell Foam not<br />
only insulates as well as polystyrene but it also absorbs excess<br />
condensation that would potentially damage the contents of<br />
the package. Green Cell’s ability to wick out ambient moisture<br />
presents a cleaner package for the customer by eliminating<br />
any pooling of water due to condensation.<br />
Green Cell Foam also provides significantly improved<br />
protection against shock and vibration damage when<br />
compared to traditional shipping coolers. Polystyrene coolers<br />
are somewhat brittle and have the propensity to crack under<br />
stress – even from a single impact. A break in the foam can<br />
compromise the integrity of the cooler by providing a channel<br />
for outside air to flow inside. Green Cell Foam can absorb<br />
multiple hits without cracking or breaking, providing a more<br />
stable thermal barrier while also providing improved impact<br />
protection to the contents. This adds value to the overall<br />
package while reducing damage claims.<br />
Sustainability was a key driver to this project. Sandoz<br />
wanted to see the environmental effects of switching from<br />
polystyrene to Green Cell Foam. KTM turned to Dr. Ramani<br />
Narayan of Michigan State University for the answer.<br />
Dr. Narayan provided life cycle assessment data which<br />
demonstrated a significant improvement in all but one of<br />
the LCA indices (eutrophication is slightly higher with Green<br />
Cell). The key metrics from the LCA comparison are an 80%<br />
reduction in greenhouse gases and a 0% decrease in energy<br />
requirements.<br />
In June 2009, refreshed graphics will grace the outside of<br />
the coolers which will help educate customers recognize and<br />
understand the benefits of the Green Cell Cooler. Mr. Kuhl is<br />
now designing additional sizes of Green Cell Coolers for use<br />
within Sandoz’ North American operations.<br />
It’s a real win-win situation for Sandoz and their customers:<br />
improved performance, improved convenience and a big<br />
improvement for the environment.<br />
A lot can change in 10<br />
years. For KTM, everything<br />
has changed in 10 years. In<br />
2009, bioplastics MAGAZINE<br />
published this article about<br />
the launch of KTM’s Green Cell Cooler Box, a<br />
biobased, compostable alternative to polystyrene<br />
coolers made from KTM”s cornstarchbased<br />
Green Cell Foam. Sandoz, a subsidiary<br />
of Novartis (Basel, Switzerland), was the<br />
first adopter, using the Green Cell Cooler<br />
Box as an effective way to ship pharmaceuticals<br />
while demonstrating environmental<br />
sustainability. Today, Sandoz and Novartis<br />
are using Green Cell Coolers to protect lifesaving<br />
products in transit. And they’re not<br />
alone: over 36 other pharma-based companies<br />
have integrated Green Cell Coolers into<br />
their operations. And over 200 other companies<br />
in the food, nutritional supplement,<br />
and life sciences industries have jumped on<br />
board, helping Green Cell Coolers develop<br />
and maintain a reputation for consistent,<br />
high-level performance. And the changes<br />
don’t stop there. KTM now offers its customers<br />
access to a team of packaging<br />
engineers equipped with design software,<br />
testing equipment and an ISTA-certified<br />
lab to help design, test and certify custom<br />
packaging using Green Cell Foam.<br />
From a 1,600m² (18,000 sqft) facility in<br />
2009, KTM has recently moved into a<br />
7,900 m² (85,000 sqft) facility in Michigan<br />
and has committed to a 5-200 m²<br />
(56,000 sqft) manufacturing facility in<br />
Nevada to better serve western US<br />
customers, expected to open in August<br />
<strong>2019</strong>. Plans are in process to expand<br />
outside of the US in 2020. Yes, a lot has<br />
changed in 10 years. And we expect<br />
that the changes over the next ten<br />
years will be even greater.<br />
18 bioplastics MAGAZINE [<strong>03</strong>/09] Vol. 4<br />
tinyurl.com/2009foam<br />
bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 53
Basics<br />
Mind the right terms<br />
Biodegradable vs. compostable vs. oxo-degradable plastics:<br />
A straightforward explanation<br />
As consumer demand for sustainable products grows,<br />
bioplastics —which can reduce our reliance on fossil<br />
fuels and decrease greenhouse gas emissions— will<br />
become more prevalent. Production of bioplastics is expected<br />
to grow by as much as 20% by 2022 [1], and as it<br />
does, consumer understanding of bioplastics will need to<br />
grow with it.<br />
A major source of confusion is the difference between<br />
three terms: Biodegradability, compostability and oxodegradability.<br />
Although these terms are often used<br />
interchangeably, they are not synonymous. Confusion<br />
regarding common bioplastics terminology such as these,<br />
especially where it concerns the disposal of bioplastic<br />
products, can have dire consequences. Companies need<br />
to understand the distinctions between each category in<br />
order to accurately and honestly market their products.<br />
And consumers need to understand these terms in order to<br />
make educated purchasing decisions and properly dispose<br />
of bioplastic products at the end of use.<br />
Understanding bioplastics: Biobased vs.<br />
biodegradable<br />
To understand these three terms (i.e., biodegradability,<br />
compostability and oxo-degradability), it is important<br />
first to clearly understand the definition of bioplastics<br />
[2]. Bioplastics refer to a large family of plastics which<br />
are sourced from biomass at the beginning of their life<br />
(biobased), metabolized into organic biomass at the end of<br />
their life (biodegradable), or both.<br />
Based on this, bioplastics can be broken down into three<br />
distinct classifications [3]:<br />
• Fully or partially biobased but NOT biodegradable. (e.g.,<br />
biobased PET, biobased PE, Terratek® SC or Terratek®<br />
WC)<br />
• Fully or partially biobased AND biodegradable (e.g., PLA<br />
or starch blends such as Terratek® BD).<br />
• Biodegradable and petroleum-based (e.g., PCL).<br />
Biodegradable plastics are a relatively small subset<br />
of bioplastics which can be converted into water, carbon<br />
dioxide (CO2) and bio-mass over time with the help of<br />
micro-organisms — this process is called biodegradation.<br />
And because the biodegradability of a plastic lies within the<br />
chemical structure of the polymer —and not the source of<br />
the feedstock— biodegradable plastics can be either bio- or<br />
petroleum-based.<br />
Biodegradable vs. compostable vs. oxodegradable<br />
plastics<br />
Nearly every material will biodegrade, given enough<br />
time. But the length of the biodegradation process is highly<br />
dependent on environmental parameters such as humidity<br />
and temperature, which is why claiming that a plastic is<br />
“biodegradable” without any further context (i.e., in what<br />
timeframe and under what environmental conditions) is<br />
misleading to consumers.<br />
Reputable companies will often make more specific<br />
claims, primarily certifying that their bioplastics are<br />
compostable. Compostable plastics are a subset of<br />
biodegradable plastics, defined by the standard conditions<br />
and timeframe under which they will biodegrade. All<br />
compostable plastics are biodegradable, but not all<br />
biodegradable plastics would be considered compostable.<br />
Certified compostable: A more specific claim of<br />
biodegradability<br />
Compostable plastics are those plastics which have been<br />
tested and certified by a third party (e.g. BPI [4], DIN Certco,<br />
TÜV Austria etc.) to adhere to international standards<br />
such as ASTM D6400 (in the U.S.) or EN 13432 (in Europe)<br />
for biodegradation in an industrial composting facility<br />
environment.<br />
Materials certified according to ASTM D6400 or EN 13432<br />
will disintegrate within 12 weeks and biodegrade at least<br />
90% within 180 days in a municipal or industrial composting<br />
facility. Approximately 10% of solid material will be left<br />
at the end of the six-month-long process in the form of<br />
valuable compost, or biomass and water. These standards<br />
also ensure that the leftover compost will be free of toxins,<br />
so the compost will not cause harm when the facility sells it<br />
for gardening or agricultural applications.<br />
Unless otherwise denoted, certified compostable products<br />
must be disposed of in a designated municipal composting<br />
facility, not at home. Many certified compostable materials<br />
require the higher temperatures of industrial settings to<br />
biodegrade quickly enough, or in some cases at all.<br />
Other than in many countries (in Europe e.g. Germany,<br />
Italy, France, Sweden, The Netherlands etc.) few areas in<br />
the USA have curbside collection for industrial composting,<br />
which is why certified compostable products are best utilized<br />
in closed systems such as amusement parks, stadiums and<br />
schools, where compostable and organic waste is carefully<br />
monitored and controlled to ensure proper disposal in an<br />
industrial composting facility. San Francisco International<br />
Airport [5] and Safeco Field in Seattle [6] are two good<br />
examples of organizations using composting as a means of<br />
reducing their carbon footprint and diverting organic waste<br />
from landfills. Find more info on the differences in different<br />
countries in bM 05/2018.<br />
A quick note on oxo-degradable plastics<br />
While often confused with biodegradable plastics,<br />
oxo-degradables are a category unto themselves. They<br />
are neither a bioplastic nor a biodegradable plastic, but<br />
rather a conventional plastic mixed with an additive in<br />
order to imitate biodegradation. Oxo-degradable plastics<br />
54 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
By:<br />
Kevin Ireland<br />
Communications Manager<br />
Green Dot Bioplastics<br />
Emporia, Kansas, USA<br />
COMPEO<br />
quickly fragment into smaller and smaller pieces, called<br />
microplastics, but don’t break down at the molecular or<br />
polymer level like biodegradable and compostable plastics.<br />
The resulting microplastics are left in the environment<br />
indefinitely until they maybe eventually fully break down. A<br />
scientifically backed evidence for “bio”degradation was not<br />
presented until today.<br />
The importance of clearly and accurately<br />
labeling plastic products<br />
As bioplastics continue to gain market share in the<br />
coming years, being clear about the environmental benefits<br />
in product and material marketing is imperative. Looking to<br />
the U.S. Federal Trade Commission’s (FTC) Green Guides<br />
[7] is a good place to start. The Green Guides outline best<br />
practices for clearly labeling and marketing green products<br />
to ensure the expectations of the consumer align.<br />
Not only will transparency allow consumers to make<br />
smarter purchasing decisions, but it will ensure bioplastics<br />
are disposed of through the proper channels. Ultimately,<br />
better end-of-life disposal of bioplastics strengthens their<br />
environmental value proposition of diverting organic waste<br />
from landfills, reducing greenhouse gas emissions and<br />
ensuring the sustainable consumption of resources.<br />
For further reading we also suggest previous articles<br />
published in bioplastics MAGAZINE [8, 9, and 10]. They are<br />
available for download at www.bioplasticsmagazine.com/<br />
en/miscellaneous/downloads.php<br />
Leading compounding technology<br />
for heat- and shear-sensitive plastics<br />
References<br />
[1] www.european-bioplastics.org/market/<br />
[2] www.greendotbioplastics.com/bioplastics-101-introduction-key-termssustainable-plastics/<br />
[3] www.european-bioplastics.org/wp-content/uploads/2016/02/2.1_<br />
Material-Koordinatensystem_eng_2015_150109-1.jpg<br />
[4] https://bpiworld.org/CertifiedCompostable<br />
[5] www.sfexaminer.com/news/at-sfo-zero-waste-means-zero-confusion/<br />
[6] www.mlb.com/mariners/ballpark/information/sustainability<br />
[7] www.ftc.gov/news-events/media-resources/truth-advertising/greenguides<br />
[8] Narayan, R.: Biodegradability - Sorting through Facts and Claims;<br />
bioplastics MAGAZINE 01/2009<br />
[9] Narayan, R.: Misleading Claims and Misuse of Standards Continues to<br />
Proliferate in the Bioplastics Industry; bioplastics MAGAZINE 01/2010<br />
[10] Ißbrücker, C.: Can Additives make conventional plastics biodegradable?<br />
bioplastics MAGAZINE 01/2017<br />
www.greendotbioplastics.com<br />
Uniquely efficient. Incredibly versatile. Amazingly flexible.<br />
With its new COMPEO Kneader series, BUSS continues<br />
to offer continuous compounding solutions that set the<br />
standard for heat- and shear-sensitive applications, in all<br />
industries, including for biopolymers.<br />
• Moderate, uniform shear rates<br />
• Extremely low temperature profile<br />
• Efficient injection of liquid components<br />
• Precise temperature control<br />
• High filler loadings<br />
www.busscorp.com<br />
bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 55
Basics<br />
Plastic microparticles<br />
Small particles of plastic were first reported in marine<br />
environments in the early 1970s. However, it wasn’t<br />
until the term ‘microplastics’ was coined in 2004 that<br />
the issue started to generate significant attention.<br />
What are microplastics?<br />
Plastic particles smaller than 5 millimetres are generally<br />
considered to be microplastic. ‘Primary’ microplastics are<br />
purposely made this size. However, most are ‘secondary’<br />
microplastics derived from the degradation and<br />
fragmentation of larger plastic items.<br />
Microbeads used in personal care products, such as<br />
facial cleansers are a well-known example of primary<br />
microplastics. Secondary microplastics are often fibres<br />
originating from the wear and laundering of clothing.<br />
Another major source of secondary microplastics is<br />
vehicles on the road, where normal wear and tear of tyres<br />
and plastic components of the vehicles contribute as well<br />
as wear of paints from road markings. Uncontrolled plastic<br />
waste and litter also break down into microplastics over<br />
time through weathering.<br />
Microplastics frequently end up in the ocean. Secondary<br />
microplastics are often swept there directly during rainfall,<br />
or, like primary microplastics, which are designed to<br />
be washed into sewers, eventually make it their way via<br />
wastewater treatment systems where they are not captured<br />
due to their small size.<br />
Microplastics downunder<br />
Scientists at Scion (Rotorua, New Zealand) and the<br />
University of Canterbury (Christchurch, New Zealand) have<br />
been identifying, quantifying and characterising plastic<br />
microparticles in Auckland waterways. Auckland is New<br />
Zealand’s largest city with zones of high industry, varying<br />
land use, estuaries, two harbours and western and eastern<br />
coastlines.<br />
Over 170 sediment samples were collected and analysed.<br />
In line with international trends, the majority of the<br />
microparticles recovered were fibres, likely derived from<br />
textiles. Higher counts were observed in samples collected<br />
near the discharge of wastewater treatment plants. Infrared<br />
spectroscopy of the microparticle polymer type showed the<br />
majority of the plastic microparticles to be polyethylene,<br />
polyethylene terephthalate and polypropylene. Around 40%<br />
were found to be cellulose and regenerated cellulose [1].<br />
Effects of microplastics<br />
In the ocean, microplastics can be ingested all along<br />
the food chain up to shellfish and fish. This can cause<br />
physical damage such as obstructions or<br />
abrasions and potentially transfer plastic<br />
additives such as phthalates.<br />
The long-term effects of microplastics<br />
on humans is still unknown. However, it is<br />
believed that ingested microplastics larger<br />
than 150 microns (the size of fine sand<br />
grains) will pass through the body without any<br />
issues. Particles smaller than this can pass<br />
through the gut wall and travel to different parts of<br />
the body. The main ways microplastics are consumed<br />
by humans are through seafood, including salt, or drinking<br />
water and breathing in of household air (or dust).<br />
Expectations of public, industry and government<br />
Many countries have implemented policies to ban plastic<br />
microbeads and reduce single use plastics such as plastic<br />
bags. However, as only a portion of microplastics originate<br />
Plastic and<br />
microplastics on a<br />
Caribbean beach<br />
from these items (the major sources being synthetic<br />
textiles, tyres, city dust, paint…), expectations of a quick fix<br />
are misguided.<br />
Bioplastics as a solution?<br />
Substituting with marine biodegradable polymers<br />
is touted as one potential solution to the microplastic<br />
problem. Unfortunately, the situation in not that simple.<br />
Some polyhydroxyalkanoates (PHA) have been shown to<br />
be marine biodegradable, however the estimated lifetime<br />
of objects made from PHA in a marine environment still<br />
range from 1 to 5 years. Further, the impact of the PHA<br />
microparticles on marine organisms within this period is<br />
56 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
By:<br />
Jamie Bridson and Kate Parker<br />
Biopolymers and Chemical Technologies<br />
Scion<br />
Rotorua, New Zealand<br />
still unknown. As reported by Francesco<br />
Degli Innocenti in Bioplastic Magazine<br />
Vol.14/1, biodegradability reduces the<br />
risk, but ultimately mitigation using<br />
bioplastics should be based on sound<br />
impact and risk assessment methodology.<br />
Oxo-degradable plastics are sometimes<br />
suggested as another possible solution.<br />
However, oxo-degradable plastics are designed<br />
to fragment into microplastics meaning they<br />
actually contribute to the problem.<br />
Turning the tide<br />
A wide range of clean-up strategies have been proposed<br />
by various groups from community litter collections to vast<br />
ocean clean ups. However, preventing microplastics being<br />
generated or reaching the environment in the first place<br />
are better solutions. Improved waste management, circular<br />
Join us at the<br />
14th European Bioplastics<br />
Conference<br />
The leading business forum for the<br />
bioplastics industry<br />
economy principles and new materials will all form part of<br />
the solution to this challenging but extremely important<br />
issue.<br />
Acknowledgements<br />
This work was funded by the New Zealand Ministry for<br />
the Environment through the Waste Minimisation Fund and<br />
Packaging Council of New Zealand (PAC.NZ). Work was<br />
supported by collaborators at Auckland Council, Watercare<br />
and the University of Auckland.<br />
[1] https://www.nzherald.co.nz/nz/news/article.cfm?c_<br />
id=1&objectid=12164041<br />
www.scionresearch.com<br />
3/4 December <strong>2019</strong><br />
Titanic Chaussee Hotel<br />
Berlin, Germany<br />
@EUBioplastics #eubpconf<br />
www.european-bioplastics.org/events<br />
REGISTER<br />
NOW!<br />
For more information email:<br />
conference@european-bioplastics.org<br />
bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14 57
Suppliers Guide<br />
1. Raw Materials<br />
AGRANA Starch<br />
Bioplastics<br />
Conrathstraße 7<br />
A-3950 Gmuend, Austria<br />
bioplastics.starch@agrana.com<br />
www.agrana.com<br />
Xinjiang Blue Ridge Tunhe<br />
Polyester Co., Ltd.<br />
No. 316, South Beijing Rd. Changji,<br />
Xinjiang, 831100, P.R.China<br />
Tel.: +86 994 2716865<br />
Mob: +86 18699400676<br />
maxirong@lanshantunhe.com<br />
http://www.lanshantunhe.com<br />
PBAT & PBS resin supplier<br />
Kingfa Sci. & Tech. Co., Ltd.<br />
No.33 Kefeng Rd, Sc. City, Guangzhou<br />
Hi-Tech Ind. Development Zone,<br />
Guangdong, P.R. China. 510663<br />
Tel: +86 (0)20 6622 1696<br />
info@ecopond.com.cn<br />
www.kingfa.com<br />
39 mm<br />
Simply contact:<br />
Tel.: +49 2161 6884467<br />
suppguide@bioplasticsmagazine.com<br />
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Suppliers Guide with your company<br />
logo and contact information.<br />
For only 6,– EUR per mm, per issue you<br />
can be present among top suppliers in<br />
the field of bioplastics.<br />
For Example:<br />
Polymedia Publisher GmbH<br />
Dammer Str. 112<br />
41066 Mönchengladbach<br />
Germany<br />
Tel. +49 2161 664864<br />
Fax +49 2161 631045<br />
info@bioplasticsmagazine.com<br />
www.bioplasticsmagazine.com<br />
Sample Charge:<br />
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Sample Charge for one year:<br />
6 issues x 234,00 EUR = 1,404.00 €<br />
The entry in our Suppliers Guide is<br />
bookable for one year (6 issues) and<br />
extends automatically if it’s not canceled<br />
three month before expiry.<br />
www.facebook.com<br />
www.issuu.com<br />
www.twitter.com<br />
www.youtube.com<br />
BASF SE<br />
Ludwigshafen, Germany<br />
Tel: +49 621 60-9995<br />
martin.bussmann@basf.com<br />
www.ecovio.com<br />
Gianeco S.r.l.<br />
Via Magenta 57 10128 Torino - Italy<br />
Tel.+390119370420<br />
info@gianeco.com<br />
www.gianeco.com<br />
PTT MCC Biochem Co., Ltd.<br />
info@pttmcc.com / www.pttmcc.com<br />
Tel: +66(0) 2 140-3563<br />
MCPP Germany GmbH<br />
+49 (0) 152-018 920 51<br />
frank.steinbrecher@mcpp-europe.com<br />
MCPP France SAS<br />
+33 (0) 6 07 22 25 32<br />
fabien.resweber@mcpp-europe.com<br />
Microtec Srl<br />
Via Po’, 53/55<br />
30<strong>03</strong>0, Mellaredo di Pianiga (VE),<br />
Italy<br />
Tel.: +39 041 5190621<br />
Fax.: +39 041 5194765<br />
info@microtecsrl.com<br />
www.biocomp.it<br />
Tel: +86 351-8689356<br />
Fax: +86 351-8689718<br />
www.jinhuizhaolong.com<br />
ecoworldsales@jinhuigroup.com<br />
Jincheng, Lin‘an, Hangzhou,<br />
Zhejiang 311300, P.R. China<br />
China contact: Grace Jin<br />
mobile: 0086 135 7578 9843<br />
Grace@xinfupharm.comEurope<br />
contact(Belgium): Susan Zhang<br />
mobile: 0<strong>03</strong>2 478 991619<br />
zxh0612@hotmail.com<br />
www.xinfupharm.com<br />
1.1 bio based monomers<br />
1.2 compounds<br />
Cardia Bioplastics<br />
Suite 6, 205-211 Forster Rd<br />
Mt. Waverley, VIC, 3149 Australia<br />
Tel. +61 3 85666800<br />
info@cardiabioplastics.com<br />
www.cardiabioplastics.com<br />
API S.p.A.<br />
Via Dante Alighieri, 27<br />
36065 Mussolente (VI), Italy<br />
Telephone +39 0424 579711<br />
www.apiplastic.com<br />
www.apinatbio.com<br />
BIO-FED<br />
Branch of AKRO-PLASTIC GmbH<br />
BioCampus Cologne<br />
Nattermannallee 1<br />
50829 Cologne, Germany<br />
Tel.: +49 221 88 88 94-00<br />
info@bio-fed.com<br />
www.bio-fed.com<br />
Global Biopolymers Co.,Ltd.<br />
Bioplastics compounds<br />
(PLA+starch;PLA+rubber)<br />
194 Lardproa80 yak 14<br />
Wangthonglang, Bangkok<br />
Thailand 1<strong>03</strong>10<br />
info@globalbiopolymers.com<br />
www.globalbiopolymers.com<br />
Tel +66 81 9150446<br />
FKuR Kunststoff GmbH<br />
Siemensring 79<br />
D - 47 877 Willich<br />
Tel. +49 2154 9251-0<br />
Tel.: +49 2154 9251-51<br />
sales@fkur.com<br />
www.fkur.com<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
Green Dot Bioplastics<br />
226 Broadway | PO Box #142<br />
Cottonwood Falls, KS 66845, USA<br />
Tel.: +1 620-273-8919<br />
info@greendotholdings.com<br />
www.greendotpure.com<br />
NUREL Engineering Polymers<br />
Ctra. Barcelona, km 329<br />
50016 Zaragoza, Spain<br />
Tel: +34 976 465 579<br />
inzea@samca.com<br />
www.inzea-biopolymers.com<br />
Sukano AG<br />
Chaltenbodenstraße 23<br />
CH-8834 Schindellegi<br />
Tel. +41 44 787 57 77<br />
Fax +41 44 787 57 78<br />
www.sukano.com<br />
58 bioplastics MAGAZINE [02/19] Vol. 14
Suppliers Guide<br />
1.5 PHA<br />
3. Semi finished products<br />
3.1 films<br />
Natureplast – Biopolynov<br />
11 rue François Arago<br />
14123 IFS<br />
Tel: +33 (0)2 31 83 50 87<br />
www.natureplast.eu<br />
TECNARO GmbH<br />
Bustadt 40<br />
D-74360 Ilsfeld. Germany<br />
Tel: +49 (0)7062/97687-0<br />
www.tecnaro.de<br />
1.3 PLA<br />
Total Corbion PLA bv<br />
Arkelsedijk 46, P.O. Box 21<br />
4200 AA Gorinchem<br />
The Netherlands<br />
Tel.: +31 183 695 695<br />
Fax.: +31 183 695 604<br />
www.total-corbion.com<br />
pla@total-corbion.com<br />
Zhejiang Hisun Biomaterials Co.,Ltd.<br />
No.97 Waisha Rd, Jiaojiang District,<br />
Taizhou City, Zhejiang Province, China<br />
Tel: +86-576-88827723<br />
pla@hisunpharm.com<br />
www.hisunplas.com<br />
1.4 starch-based bioplastics<br />
BIOTEC<br />
Biologische Naturverpackungen<br />
Werner-Heisenberg-Strasse 32<br />
46446 Emmerich/Germany<br />
Tel.: +49 (0) 2822 – 92510<br />
info@biotec.de<br />
www.biotec.de<br />
Grabio Greentech Corporation<br />
Tel: +886-3-598-6496<br />
No. 91, Guangfu N. Rd., Hsinchu<br />
Industrial Park,Hukou Township,<br />
Hsinchu County 3<strong>03</strong>51, Taiwan<br />
sales@grabio.com.tw<br />
www.grabio.com.tw<br />
Plásticos Compuestos S.A.<br />
C/ Basters 15<br />
08184 Palau Solità i Plegamans<br />
Barcelona, Spain<br />
Tel. +34 93 863 96 70<br />
info@kompuestos.com<br />
www.kompuestos.com<br />
Bio-on S.p.A.<br />
Via Santa Margherita al Colle 10/3<br />
40136 Bologna - ITALY<br />
Tel.: +39 051 392336<br />
info@bio-on.it<br />
www.bio-on.it<br />
Kaneka Belgium N.V.<br />
Nijverheidsstraat 16<br />
2260 Westerlo-Oevel, Belgium<br />
Tel: +32 (0)14 25 78 36<br />
Fax: +32 (0)14 25 78 81<br />
info.biopolymer@kaneka.be<br />
TianAn Biopolymer<br />
No. 68 Dagang 6th Rd,<br />
Beilun, Ningbo, China, 315800<br />
Tel. +86-57 48 68 62 50 2<br />
Fax +86-57 48 68 77 98 0<br />
enquiry@tianan-enmat.com<br />
www.tianan-enmat.com<br />
1.6 masterbatches<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
Albrecht Dinkelaker<br />
Polymer and Product Development<br />
Blumenweg 2<br />
79669 Zell im Wiesental, Germany<br />
Tel.:+49 (0) 7625 91 84 58<br />
info@polyfea2.de<br />
www.caprowax-p.eu<br />
2. Additives/Secondary raw materials<br />
GRAFE-Group<br />
Waldecker Straße 21,<br />
99444 Blankenhain, Germany<br />
Tel. +49 36459 45 0<br />
www.grafe.com<br />
TIPA-Corp. Ltd<br />
Hanagar 3 Hod<br />
Hasharon 4501306, ISRAEL<br />
P.O BOX 7132<br />
Tel: +972-9-779-6000<br />
Fax: +972 -9-7715828<br />
www.tipa-corp.com<br />
4. Bioplastics products<br />
Bio-on S.p.A.<br />
Via Santa Margherita al Colle 10/3<br />
40136 Bologna - ITALY<br />
Tel.: +39 051 392336<br />
info@bio-on.it<br />
www.bio-on.it<br />
Bio4Pack GmbH<br />
D-48419 Rheine, Germany<br />
Tel.: +49 (0) 5975 955 94 57<br />
info@bio4pack.com<br />
www.bio4pack.com<br />
BeoPlast Besgen GmbH<br />
Bioplastics injection moulding<br />
Industriestraße 64<br />
D-40764 Langenfeld, Germany<br />
Tel. +49 2173 84840-0<br />
info@beoplast.de<br />
www.beoplast.de<br />
INDOCHINE C, M, Y , K BIO C , M, Y, K PLASTIQUES<br />
45, 0,90, 0<br />
10, 0, 80,0<br />
(ICBP) C, M, Y, KSDN BHD<br />
C, M, Y, K<br />
50, 0 ,0, 0<br />
0, 0, 0, 0<br />
12, Jalan i-Park SAC 3<br />
Senai Airport City<br />
81400 Senai, Johor, Malaysia<br />
Tel. +60 7 5959 159<br />
marketing@icbp.com.my<br />
www.icbp.com.my<br />
Minima Technology Co., Ltd.<br />
Esmy Huang, COO<br />
No.33. Yichang E. Rd., Taipin City,<br />
Taichung County<br />
411, Taiwan (R.O.C.)<br />
Tel. +886(4)2277 6888<br />
Fax +883(4)2277 6989<br />
Mobil +886(0)982-829988<br />
esmy@minima-tech.com<br />
Skype esmy325<br />
www.minima.com<br />
Natur-Tec ® - Northern Technologies<br />
4201 Woodland Road<br />
Circle Pines, MN 55014 USA<br />
Tel. +1 763.404.8700<br />
Fax +1 763.225.6645<br />
info@natur-tec.com<br />
www.natur-tec.com<br />
NOVAMONT S.p.A.<br />
Via Fauser , 8<br />
28100 Novara - ITALIA<br />
Fax +39.<strong>03</strong>21.699.601<br />
Tel. +39.<strong>03</strong>21.699.611<br />
www.novamont.com<br />
6. Equipment<br />
6.1 Machinery & Molds<br />
Buss AG<br />
Hohenrainstrasse 10<br />
4133 Pratteln / Switzerland<br />
Tel.: +41 61 825 66 00<br />
Fax: +41 61 825 68 58<br />
info@busscorp.com<br />
www.busscorp.com<br />
6.2 Degradability Analyzer<br />
MODA: Biodegradability Analyzer<br />
SAIDA FDS INC.<br />
143-10 Isshiki, Yaizu,<br />
Shizuoka,Japan<br />
Tel:+81-54-624-6155<br />
Fax: +81-54-623-8623<br />
info_fds@saidagroup.jp<br />
www.saidagroup.jp/fds_en/<br />
7. Plant engineering<br />
EREMA Engineering Recycling<br />
Maschinen und Anlagen GmbH<br />
Unterfeldstrasse 3<br />
4052 Ansfelden, AUSTRIA<br />
Phone: +43 (0) 732 / 3190-0<br />
Fax: +43 (0) 732 / 3190-23<br />
erema@erema.at<br />
www.erema.at<br />
bioplastics MAGAZINE [02/19] Vol. 14 59
Suppliers Guide<br />
9. Services (continued)<br />
Uhde Inventa-Fischer GmbH<br />
Holzhauser Strasse 157–159<br />
D-13509 Berlin<br />
Tel. +49 30 43 567 5<br />
Fax +49 30 43 567 699<br />
sales.de@uhde-inventa-fischer.com<br />
Uhde Inventa-Fischer AG<br />
Via Innovativa 31, CH-7013 Domat/Ems<br />
Tel. +41 81 632 63 11<br />
Fax +41 81 632 74 <strong>03</strong><br />
sales.ch@uhde-inventa-fischer.com<br />
www.uhde-inventa-fischer.com<br />
9. Services<br />
Osterfelder Str. 3<br />
46047 Oberhausen<br />
Tel.: +49 (0)208 8598 1227<br />
thomas.wodke@umsicht.fhg.de<br />
www.umsicht.fraunhofer.de<br />
Innovation Consulting Harald Kaeb<br />
narocon<br />
Dr. Harald Kaeb<br />
Tel.: +49 30-28096930<br />
kaeb@narocon.de<br />
www.narocon.de<br />
nova-Institut GmbH<br />
Chemiepark Knapsack<br />
Industriestrasse 300<br />
5<strong>03</strong>54 Huerth, Germany<br />
Tel.: +49(0)2233-48-14 40<br />
E-Mail: contact@nova-institut.de<br />
www.biobased.eu<br />
Bioplastics Consulting<br />
Tel. +49 2161 664864<br />
info@polymediaconsult.com<br />
10. Institutions<br />
10.1 Associations<br />
BPI - The Biodegradable<br />
Products Institute<br />
331 West 57th Street, Suite 415<br />
New York, NY 10019, USA<br />
Tel. +1-888-274-5646<br />
info@bpiworld.org<br />
European Bioplastics e.V.<br />
Marienstr. 19/20<br />
10117 Berlin, Germany<br />
Tel. +49 30 284 82 350<br />
Fax +49 30 284 84 359<br />
info@european-bioplastics.org<br />
www.european-bioplastics.org<br />
10.2 Universities<br />
Institut für Kunststofftechnik<br />
Universität Stuttgart<br />
Böblinger Straße 70<br />
70199 Stuttgart<br />
Tel +49 711/685-62831<br />
silvia.kliem@ikt.uni-stuttgart.de<br />
www.ikt.uni-stuttgart.de<br />
Michigan State University<br />
Dept. of Chem. Eng & Mat. Sc.<br />
Professor Ramani Narayan<br />
East Lansing MI 48824, USA<br />
Tel. +1 517 719 7163<br />
narayan@msu.edu<br />
IfBB – Institute for Bioplastics<br />
and Biocomposites<br />
University of Applied Sciences<br />
and Arts Hanover<br />
Faculty II – Mechanical and<br />
Bioprocess Engineering<br />
Heisterbergallee 12<br />
30453 Hannover, Germany<br />
Tel.: +49 5 11 / 92 96 - 22 69<br />
Fax: +49 5 11 / 92 96 - 99 - 22 69<br />
lisa.mundzeck@hs-hannover.de<br />
www.ifbb-hannover.de/<br />
10.3 Other Institutions<br />
Green Serendipity<br />
Caroli Buitenhuis<br />
IJburglaan 836<br />
1087 EM Amsterdam<br />
The Netherlands<br />
Tel.: +31 6-24216733<br />
www.greenseredipity.nl<br />
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60 bioplastics MAGAZINE [02/19] Vol. 14
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26 th Anniversary meeting of the Bio-Environmental<br />
Polymer Society (BEPS)<br />
05.06.<strong>2019</strong> - 07.06.<strong>2019</strong> - Greenville, SC, USA<br />
http://www.beps.org/meetings/<br />
Biobased Coatings Europe <strong>2019</strong><br />
19.06.<strong>2019</strong> - 20.06.<strong>2019</strong> - Duesseldorf, Germany<br />
https://www.wplgroup.com/aci/crce2_agenda_mkg/<br />
Plastics beyond Petroleum - BioMass & Recycling<br />
25.06.<strong>2019</strong> - 27.06.<strong>2019</strong> - New York City Area, USA<br />
http://innoplastsolutions.com/conference.html<br />
Plastic Free World<br />
27.06.<strong>2019</strong> - 28.06.<strong>2019</strong> - Frankfurt, Germany<br />
https://plasticfree-world.com/<br />
EcoComunicazione.it<br />
ISSN 1862-5258<br />
Highlights<br />
Rigid packaging / Theromforming | 12<br />
Building & Construction | 23<br />
Basics<br />
Biobased Packaging | 46<br />
bioplastics MAGAZINE Vol. 14<br />
Mar / Apr<br />
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Basics<br />
Microplastics | 56<br />
Mind the right terms | 54<br />
Captured CO 2 vs. biobased | 48<br />
Highlights<br />
Toys | 10<br />
Injection Moulding | 30<br />
bioplastics MAGAZINE Vol. 12<br />
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Cover Story<br />
bio-PE truck ride-on<br />
<strong>03</strong> | <strong>2019</strong><br />
4th International Conference on Bio-polymers &<br />
Polymer Chemistry<br />
11.07.<strong>2019</strong> - 12.07.<strong>2019</strong> - Las Vegas, NV, USA<br />
https://scientificfederation.com/icbpc-<strong>2019</strong>/index.php#sessions<br />
9th World Congress on Biopolymers & Bioplastics<br />
26.08.<strong>2019</strong> - 27.08.<strong>2019</strong> - London, Great Britain<br />
https://biopolymers.insightconferences.com/<br />
SPC Engage:London<br />
23.10.<strong>2019</strong> - 24.10.<strong>2019</strong> - London, Great Britain<br />
https://sustainablepackaging.org/events/spc-engage-london/<br />
+<br />
or<br />
Mention the promotion code ‘watch‘ or ‘book‘<br />
and you will get our watch or the book 3)<br />
Bioplastics Basics. Applications. Markets. for free<br />
(new subscribers only)<br />
1) Offer valid until 31 July <strong>2019</strong><br />
3) Gratis-Buch in Deutschland nicht möglich, no free book in Germany<br />
bioplastics MAGAZINE [02/19] Vol. 14 61
Companies in this issue<br />
Company Editorial Advert Company Editorial Advert Company Editorial Advert<br />
5 Gyres 14<br />
Global Biopolymers 8 58 nova-Institute 8, 23 19, 39, 60<br />
Aakar Innovations 8<br />
Aeropowder 46<br />
Agrana Starch Bioplastics 21, 58<br />
AIJU 22<br />
Alterra Plastics 14<br />
API 58<br />
arbo Plastic 6<br />
Arctic Biomaterials 30<br />
Arkema 6<br />
Audi 28<br />
Balaenos 44<br />
BASF 7 58<br />
BeoPlast Besgen 59<br />
Beta Analytic 48<br />
Bio4Pack 59<br />
Bioblo 12, 26<br />
Biobuddi 23<br />
Bio-Fed Branch of Akro-Plastic 58<br />
Bio-on 43 59<br />
Bioserie 12, 16<br />
Biotec 59<br />
BPI 60<br />
Braskem 12, 18, 40<br />
Buss 55, 59<br />
Caprowachs, Albrecht Dinkelaker 59<br />
Cardia Bioplastics 58<br />
Cove 5<br />
dantoy 18, 23<br />
DIN Certco 5, 40<br />
DowDuPont 7<br />
Dr. Heinz Gupta Verlag 60<br />
DuPont 12, 14<br />
eKoala 12, 20, 23<br />
Emballator Tectubes 40<br />
Erema 59<br />
European Bioplastics 24, 47 57, 60<br />
Farrel Pomini 2 27<br />
Ferbedo 1, 4,28<br />
FKuR 12,18,28,40,40 2, 58<br />
Fraunhofer IAP 25<br />
Fraunhofer Silicat Research 46<br />
Fraunhofer UMSICHT 32 60<br />
Gianeco 58<br />
Golden Compound 8<br />
GRABIO Greentech Corporation 59<br />
Grafe 58, 59<br />
Green Bottomline 48<br />
Green Dot Bioplastics 12, 25, 34, 54 58<br />
Green Serendipity 60<br />
Habermaaß 12<br />
Hands on Veggies 41<br />
Hape 23<br />
Hexpol TPE 12, 42<br />
Hötter Spiel 26<br />
Indochine Bio Plastiques 59<br />
Infraserv Knapsak 8<br />
Inst. F. Bioplastics & Biocomposites 35 60<br />
Institut f. Kunststofftechnik, Stuttgart 60<br />
Jaguar 28<br />
Janod 23<br />
JenCaps 46<br />
JinHui Zhaolong 58<br />
Kaneka 5 59<br />
Kartell 43<br />
Kikadu 23<br />
Kingfa 58<br />
Kompuestos 6 59<br />
KTM 53<br />
Lactips, 7<br />
Lageen Tubes 40<br />
Lego 11<br />
Light my Fire 42<br />
Lipura 26<br />
Luke's Toy Factory 23<br />
MAN 28<br />
Mattel 12<br />
Messe Düsseldorf (K'<strong>2019</strong>) 31<br />
Michigan State University 48 60<br />
Microtec 58<br />
Minima Technology 59<br />
Multitubes 41<br />
narocon InnovationConsulting 10 60<br />
nature2need 32<br />
Natureplast-Biopolynov 59<br />
Natur-Tec 59<br />
Neste 12<br />
Novamont 20 59, 64<br />
Novartis 53<br />
Nuova Erreplast 46<br />
Nurel 58<br />
Ochis Coffee 43<br />
plastickjer 46<br />
Playmobil 12<br />
polymediaconsult 60<br />
Polymerfornt 40<br />
Pottery Barn Kids 14<br />
PTT MCC Biochem 58<br />
Ravensburger 12<br />
Saida 59<br />
Sandoz 53<br />
Schmiderer & Schendl 26<br />
Scion 5, 56<br />
SK Chemicals 42<br />
SKZ 35, 47<br />
SLK 35<br />
Spinnova 8<br />
Südpack Packaging 46<br />
Sukano 36 58<br />
Swox 41<br />
Tecnaro 12, 13, 47 59<br />
Teijin 7<br />
TianAn Biopolymer 59<br />
TicToys 12, 13<br />
TIPA 59<br />
Total-Corbion 12 59<br />
Trevira 46<br />
Tubex 41<br />
TÜV Austria 40<br />
Uhde Inventa-Fischer 60<br />
Univ Chemnitz 35<br />
Univ. Stuttgart (IKT) 60<br />
Volvo Cars 28, 52<br />
Wiener Spielkarten 26<br />
Xinjiang Blue Ridge Tunhe Polyester 58<br />
Zapf Creatiuon 12<br />
Zeijiang Hisun Biomaterials 59<br />
Zhejiang Hangzhou Xinfu Pharm. 58<br />
Zoë B Organic 12, 14<br />
<strong>Issue</strong><br />
Editorial Planner<br />
Month<br />
Publ.<br />
Date<br />
edit/ad/<br />
Deadline<br />
<strong>2019</strong><br />
02/<strong>2019</strong> Mar/Apr 08 Apr 19 08 Mrz 19 Thermoforming /<br />
Rigid Packaging<br />
Edit. Focus 1 Edit. Focus 2 Basics<br />
Building &<br />
construction<br />
Bioplastics in packaging<br />
(update)<br />
Trade-Fair<br />
Specials<br />
Subject to changes<br />
Chinaplas Preview<br />
<strong>03</strong>/<strong>2019</strong> May/Jun <strong>03</strong> Jun 19 <strong>03</strong> May 19 Injection moulding Toys Microplastics Chinaplas Review<br />
04/<strong>2019</strong> Jul/Aug 05 Aug 19 05 Jul 19 Blow Moulding Biocomposites incl.<br />
thermoset<br />
Home composting<br />
05/<strong>2019</strong> Sep/Oct 07.10.19 06.09.19 Fiber / Textile /<br />
Nonwoven<br />
Barrier materials<br />
Land use for bioplastics<br />
(update)<br />
K'<strong>2019</strong> Preview<br />
06/<strong>2019</strong> Nov/Dec 02.12.19 01.11.19 Films/Flexibles/<br />
Bags<br />
Consumer & office<br />
electronics<br />
Multilayer films<br />
K'<strong>2019</strong> Review<br />
62 bioplastics MAGAZINE [<strong>03</strong>/19] Vol. 14
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YOUR NEEDS.<br />
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HOME<br />
FOOD-CONTACT<br />
GRADE<br />
GMO FREE<br />
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member of the SPHERE<br />
group of companies<br />
LJ Corporate – © JB Mariou – BIOTEC HRA 1183
WWW.MATERBI.COM<br />
EcoComunicazione.it<br />
r1_05.2017