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1.5 Ideal Gas Law 13<br />

In the ideal gas law,<br />

absolute pressures<br />

and temperatures<br />

must be used.<br />

an ideal gas. It is known to closely approximate the behavior of real gases under normal conditions<br />

when the gases are not approaching liquefaction.<br />

Pressure in a <strong>fluid</strong> at rest is defined as the normal force per unit area exerted on a plane surface<br />

1real or imaginary2 immersed in a <strong>fluid</strong> and is created by the bombardment of the surface with the <strong>fluid</strong><br />

molecules. From the definition, pressure has the dimension of FL 2 , and in BG units is expressed as<br />

lbft 2 1psf2 or lbin. 2 1psi2 and in SI units as Nm 2 . In SI, 1 Nm 2 defined as a pascal, abbreviated as<br />

Pa, and pressures are commonly specified in pascals. The pressure in the ideal gas law must be expressed<br />

as an absolute pressure, denoted (abs), which means that it is measured relative to absolute<br />

zero pressure 1a pressure that would only occur in a perfect vacuum2. Standard sea-level atmospheric<br />

pressure 1by international agreement2 is 14.696 psi 1abs2 or 101.33 kPa 1abs2. For most calculations these<br />

pressures can be rounded to 14.7 psi and 101 kPa, respectively. In engineering it is common practice<br />

to measure pressure relative to the local atmospheric pressure, and when measured in this fashion it is<br />

called gage pressure. Thus, the absolute pressure can be obtained from the gage pressure by adding the<br />

value of the atmospheric pressure. For example, as shown by the figure in the margin on the next page,<br />

a pressure of 30 psi 1gage2 in a tire is equal to 44.7 psi 1abs2 at standard atmospheric pressure. Pressure<br />

is a particularly important <strong>fluid</strong> characteristic and it will be discussed more fully in the next chapter.<br />

E XAMPLE 1.3<br />

Ideal Gas Law<br />

GIVEN The compressed air tank shown in Fig. E1.3a has a<br />

volume of 0.84 ft 3 . The temperature is 70 °F and the atmospheric<br />

pressure is 14.7 psi 1abs2.<br />

FIND When the tank is filled with air at a gage pressure of 50 psi,<br />

determine the density of the air and the weight of air in the tank.<br />

SOLUTION<br />

The air density can be obtained from the ideal gas law 1Eq. 1.82<br />

so that<br />

r p<br />

RT<br />

r 150 lb in. 2 14.7 lbin. 2 21144 in. 2 ft 2 2<br />

11716 ft # lbslug # °R23170 4602°R4<br />

0.0102 slugsft 3<br />

(Ans)<br />

Note that both the pressure and temperature were changed to absolute<br />

values.<br />

F I G U R E E1.3a<br />

Jenny Products, Inc.)<br />

(Photograph courtesy of<br />

W, lb<br />

0.5<br />

0.4<br />

0.3<br />

0.2<br />

0.1<br />

0<br />

–20 0 20 40<br />

p, psi<br />

F I G U R E E1.3b<br />

(50 psi, 0.276 lb)<br />

60 80 100<br />

The weight, w, of the air is equal to<br />

w rg 1volume2<br />

10.0102 slugft 3 2132.2 ft s 2 210.84 ft 3 2<br />

0.276 slug # fts 2<br />

so that since 1 lb 1 slug # ft s 2<br />

w 0.276 lb<br />

(Ans)<br />

COMMENT By repeating the calculations for various values of<br />

the pressure, p, the results shown in Fig. E1.3b are obtained. Note<br />

that doubling the gage pressure does not double the amount of air<br />

in the tank, but doubling the absolute pressure does. Thus, a scuba<br />

diving tank at a gage pressure of 100 psi does not contain twice the<br />

amount of air as when the gage reads 50 psi.

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