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For a fixed, nondeforming control volume, Eqs. 5.94, 5.95, and 5.96 combine to give<br />

At any instant for steady flow<br />

5.4 Second Law of Thermodynamics—Irreversible Flow 241<br />

0<br />

0t sr dV cs<br />

srV nˆ dA a<br />

a dQ# net<br />

in<br />

cv<br />

T<br />

0<br />

0t cv<br />

sr dV0<br />

(5.97)<br />

(5.98)<br />

If the flow consists of only one stream through the control volume and if the properties are uniformly<br />

distributed 1one-dimensional flow2, Eqs. 5.97 and 5.98 lead to<br />

b cv<br />

m # dQ # net<br />

in<br />

1s out s in 2 a T<br />

For the infinitesimally thin control volume of Fig. 5.8, Eq. 5.99 yields<br />

(5.99)<br />

m # dQ # net<br />

in<br />

ds a T<br />

(5.100)<br />

If all of the <strong>fluid</strong> in the infinitesimally thin control volume is considered as being at a uniform temperature,<br />

T, then from Eq. 5.100 we get<br />

The relationship<br />

between entropy<br />

and heat transfer<br />

rate depends on the<br />

process involved.<br />

or<br />

T ds dq net<br />

in<br />

T ds dq net<br />

in<br />

(5.101)<br />

The equality is for any reversible 1frictionless2 process; the inequality is for all irreversible 1friction2<br />

processes.<br />

0<br />

5.4.3 Combination of the Equations of the First and Second Laws<br />

of Thermodynamics<br />

Combining Eqs. 5.93 and 5.101, we conclude that<br />

c dp r d aV2 2 b g dz d 0<br />

(5.102)<br />

The equality is for any steady, reversible 1frictionless2 flow, an important example being flow for<br />

which the Bernoulli equation 1Eq. 3.7) is applicable. The inequality is for all steady, irreversible<br />

1friction2 flows. The actual amount of the inequality has physical significance. It represents the<br />

extent of loss of useful or available energy which occurs because of irreversible flow phenomena<br />

including viscous effects. Thus, Eq. 5.102 can be expressed as<br />

c dp<br />

r d aV2 2 b g dz d d1loss2 1T ds dq net2<br />

in<br />

(5.103)<br />

The irreversible flow loss is zero for a frictionless flow and greater than zero for a flow with<br />

frictional effects. Note that when the flow is frictionless, Eq. 5.103 multiplied by density,<br />

is identical to Eq. 3.5. Thus, for steady frictionless flow, Newton’s second law of motion 1see<br />

Section 3.12 and the first and second laws of thermodynamics lead to the same differential<br />

equation,<br />

dp<br />

r d aV2<br />

r,<br />

(5.104)<br />

2 b g dz 0

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