"Front Matter". In: Organosilanes in Radical Chemistry - Index of

226 Index
Triethylsilane
as mediator with monosubstituted
alkene 153
reducing agent 70–71
Si w H dissociation enthalpy 22t
with aminyl 39t
with aroyloxyl 42
with benzophenone triplet 44t
with cumylperoxyl 40t
with perfluoroalkyl 36t
with primary alkyl 33t
with [1.1.1]propellane 97
with tert-butoxyl 40t
with tertiary alkyl 36t
with thiocarbonyl derivatives 71
with thiyl 42, 43t
Triethylsilyl radical
addition to alkene 89, 89t
addition to alkyne 98
with alkyl bromide 72t
with alkyl chloride 72t
with alkyl iodide 72t
addition to carbon-nitrogen double
bond 108,109t
addition to carbonyl compound 100,
101, 102t
with polyhalogenated compound 72t
with sulfonyl halide 73
addition to terminal alkene 153
Trimethylsilane
enthalpy of formation 21t
gas-phase acidity 27t
gas-phase basicity 28t
Si w H dissociation enthalpy 21t
Trimethylsilyl radical
addition to alkene 88, 89, 90
addition to cumulene and heterocumulene
109t, 110
electron affinity 27t
enthalpy of formation 21, 21t, 24
ionization potential 28t
self-termination 51
Triphenylsilane
with aminyl 39t
with cumylperoxyl 40t
methylenelactone 95
with monosubstituted acetylene 98
with phenyl 36t
with primary alkyl 33t
with tert-butoxyl 40t
tertiary alkyl 36t
with thiyl 42, 43t
Triphenylsilyl radical with alkyl
chloride 74t
Triphenyltin hydride 125, 126, 131, 136
Triquinane 151, 179
Tris(methylthio)silane
reducing agent 78
Si w H dissociation enthalpy 22t
Tris(trimethylsilyl)silane
autoxidation 190, 191, 192, 192s
gas-phase acidity 27t
reducing agent 53–54, 57
Si w H dissociation enthalpy 22t
with acyl radical 36t
with acid chloride 58
with aldehyde 105
with alkyl chloride 57, 58
with alkyl bromide 55, 56
with alkyl iodide 55
with alkyl isocyanide 67
with alkyl selenide 60
with alkyl sulfide 59, 60
with allyl phenyl sulfide 96
with aminyl radical 39t
with aryloxyl radical 41
with benzophenone triplet 44t
with a-chiral disubstituted olefin 94
with cumylperoxyl radical 40t
with dialkyl ketone 102, 103
with diethyl methyl fumarate 93
with disubstituted acetylene 99
with gem-dichloride 58
with gem-disubstituted olefin 92
with methylmaleic anhydride 93
with monosubstituted acetylene 98, 99
with monosubstituted olefin 92
with nitro derivatives 68
with nitroxide 67
with oxygen 70, 193
with perfluoroalkyl radical 36t
with peroxyl radical 193,
with phenyl radical 36t
with phenyl selenoester 61