"Front Matter". In: Organosilanes in Radical Chemistry - Index of
"Front Matter". In: Organosilanes in Radical Chemistry - Index of
"Front Matter". In: Organosilanes in Radical Chemistry - Index of
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224 <strong>In</strong>dex<br />
Organosilicon boranes 2, 97<br />
Oxauracil 162, 163<br />
( )-Pancrac<strong>in</strong>e 166<br />
Pentamethyldisilane<br />
reduc<strong>in</strong>g agent 76<br />
Si w H dissociation enthalpy 22t<br />
Pentamethyldisilyl radical<br />
addition to alkene 89, 89t<br />
addition to carbonyl compound 101<br />
EPR spectrum 7<br />
self-term<strong>in</strong>ation 51<br />
with alkyl bromide 77t<br />
with alkyl chloride 77t<br />
Persistent radical 2, 9, 10, 10t, 109, 112,<br />
121, 189<br />
Phenylselenosilanes 3, 105, 106, 158, 158s<br />
Phenylsilane<br />
as mediator with alkyl bromide 153<br />
dehydrocoupl<strong>in</strong>g polymerization 186<br />
gas-phase acidity 27t<br />
gas-phase basicity 28t<br />
ionization potential 28<br />
SiH dissociation enthalpy 27t<br />
Phenylsilyl radical<br />
electron aff<strong>in</strong>ity 27t<br />
ionization potential 28t<br />
Photoacoustic calorimetry 22<br />
Photochemical addition to C60<br />
cyclotetrasilane 201s, 202<br />
disilacyclobutane 201s, 202<br />
disilane 199<br />
disilirane 201, 201s<br />
polysilane 200<br />
Photochemical <strong>in</strong>itiation 53, 57, 146, 147,<br />
158, 166, 168, 178, 181, 199, 200, 201,<br />
202, 206, 211, 212<br />
Photo<strong>in</strong>duced electron transfer 3, 69, 158<br />
Photolysis <strong>of</strong> silane 1, 2, 103, 137<br />
Polarity-reversal catalysis 42, 79, 79s, 94<br />
Poly(hexylhydrosilane)<br />
polydispersity <strong>in</strong>dex 195<br />
with tert-butoxyl radical 188f, 189<br />
Poly(hydrosilane)<br />
autoxidation 189, 190<br />
dehydrogenative coupl<strong>in</strong>g <strong>of</strong><br />
RSiH3 186<br />
oxidizability value 189, 190<br />
radical-based degradation 188<br />
Poly(phenylhydrosilane)<br />
addition to carbonyl compound 197<br />
addition to alkene 196<br />
GPC analysis 187, 187f<br />
halogenation 195<br />
oxidizability value 190<br />
polydispersity <strong>in</strong>dex 187, 195<br />
radical cha<strong>in</strong> oxidation 191s<br />
reduc<strong>in</strong>g agent 195<br />
with tert-butoxyl radical 187<br />
Poly(phenylsilane), see also<br />
Poly(phenylhydrosilane)<br />
reduc<strong>in</strong>g agent 77<br />
Polyhalogenated compound 70, 72, 73<br />
Polysilane 185–198, 200<br />
Polysiloxane 115<br />
Polysilylene, see Polysilane<br />
Pyrid<strong>in</strong>ium replacement 67<br />
<strong>Radical</strong> annulation 175, 176, 178, 181<br />
<strong>Radical</strong> cha<strong>in</strong> racemization 5, 42, 43s<br />
<strong>Radical</strong> clock methodology 32–38, 126,<br />
195<br />
<strong>Radical</strong> <strong>in</strong>itiators 52–53<br />
<strong>Radical</strong> translocation 34, 125, 180, 147s,<br />
171, 180s, 196s, 206, 207s, 209, 209s,<br />
214s<br />
Reduction, propagation step 50s<br />
R<strong>in</strong>g expansion 32, 35, 38, 126, 127, 152<br />
Rydberg transition 16<br />
Silacycloalkyl radical 5, 9, 120, 121, 122s<br />
Silicon hydride<br />
addition to carbonyl sulfide 111<br />
gas-phase acidity 26, 27t<br />
gas-phase basicity 27, 28t<br />
oxidation to silanol 113,114<br />
with phosph<strong>in</strong>e sulfide 115<br />
Silanethiol 80, 80s, 111, 115, 138<br />
Silyl metal <strong>in</strong> one-electron oxidation 2<br />
Silyl radical<br />
addition to alkene 88<br />
addition to alkyne 97, 98<br />
addition to benzene 90<br />
addition to C60 199