"Front Matter". In: Organosilanes in Radical Chemistry - Index of
"Front Matter". In: Organosilanes in Radical Chemistry - Index of
"Front Matter". In: Organosilanes in Radical Chemistry - Index of
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222 <strong>In</strong>dex<br />
Carbonyl sulfide 111<br />
Carbonylation 147, 148<br />
Cascade radical reaction 125, 126, 174,<br />
175, 176, 178, 179, 180, 181<br />
Cobalt catalysis 113, 114, 115<br />
Cram’s rule for radical reaction 104<br />
Cumylperoxyl radical with silicon<br />
hydrides 40t, 41<br />
Cyclic am<strong>in</strong>e 162, 163, 164, 165, 172<br />
Cyclic ether<br />
five-membered 154, 155, 156, 157<br />
six-membered 154, 157<br />
seven-membered 154, 157<br />
Cyclization <strong>of</strong> carbon-centred radical, see<br />
also Macrocyclization<br />
5-endo 35, 166, 179<br />
5-exo 32, 37, 38, 150, 151, 152, 153, 154,<br />
155, 156, 157, 159, 160, 161, 162,<br />
163, 164, 165, 166, 167, 176, 177,<br />
178, 179, 181<br />
6-endo 152, 161, 165, 176, 177, 179<br />
6-exo 153, 161, 157, 162, 163, 164, 167,<br />
176, 179, 181<br />
7-exo 154, 157, 162<br />
Cyclization <strong>of</strong> silyl radical<br />
3-exo 121<br />
5-endo 121, 122s, 123, 125<br />
5-exo 123,<br />
6-endo 120, 123, 126<br />
7-endo 123<br />
Cyclohexadienyl radical 81, 91, 129, 130,<br />
200, 202<br />
Cyclotetrasilenyl radical 11, 12f<br />
Dactomelynes 58<br />
Deoxygenation <strong>of</strong> alcohol<br />
am<strong>in</strong>oacid analogues 63, 71<br />
Barton and McCombie reaction 62–66,<br />
66s, 71, 74, 75, 76<br />
steroid derivative 63, 71, 75<br />
nucleosides 64, 65, 71<br />
polycycle 64<br />
selenocarbonate route 61<br />
sugar derivative 63, 66, 67, 71, 74, 75, 76<br />
Diastereoselection 56, 93, 148, 151, 152,<br />
154, 155, 156, 157, 160, 161, 162, 163,<br />
166, 180<br />
Dideoxygenation 62, 63, 65, 66, 71, 75<br />
Dihydrobenz<strong>of</strong>uran 160<br />
Diphenylsilane 33t, 36t, 39t, 40t<br />
as mediator with alkyl bromide 153<br />
with alkyl halide 74<br />
with a-chiral disubstituted olef<strong>in</strong> 95<br />
with thiocarbonyl derivatives 74, 75<br />
Diqu<strong>in</strong>ane 151<br />
9,10-Disilaanthracene 5, 33, 33t, 75, 76<br />
Disilane 134s, 199<br />
Disilene with carbonyl compounds 104,<br />
105s<br />
Displacement reactions, see Homolytical<br />
substitution<br />
Di-tert-butyl hyponitrite 95, 96, 111, 120,<br />
121, 123, 147, 187<br />
Di-tert-butyl peroxide 6, 22, 40, 53, 94,<br />
120, 121, 132, 153, 173, 187, 188<br />
Enthalpy <strong>of</strong> formation<br />
silanes 21t, 24t<br />
silyl radicals 21t<br />
other radicals 24t<br />
EPR spectroscopy 6–11, 38, 41, 88, 98, 100,<br />
107, 108, 109, 110, 112, 115, 120, 121,<br />
130, 132, 188f, 189, 194, 196, 198, 199<br />
Exocyclic alkene 152, 159, 160<br />
Felk<strong>in</strong>-Ahn<br />
model 103<br />
transition state 93, 95<br />
Fused cyclic ether 155, 160, 161<br />
( )-Gelsem<strong>in</strong>e 167<br />
Group migration<br />
1,2-acyloxy 132, 133<br />
1,4-phenyl 130, 131<br />
1,5-phenyl 129<br />
1,2-silyl 138, 138s, 139, 193, 206<br />
1,4-silyl 139<br />
1,5-silyl 140<br />
Halogenated silyl radical 7t, 14<br />
Hedaregen<strong>in</strong> 74<br />
Hexabutyldit<strong>in</strong> 147<br />
Hexamethyldisilane<br />
enthalpy <strong>of</strong> formation 21