"Front Matter". In: Organosilanes in Radical Chemistry - Index of

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LIST OF ABBREVIATIONS AES Auger electron spectroscopy AFM atomic force microscopy AH2 ascorbic acid AIBN 2’,2’-azobisisobutyronitrile AMVN 2’,2’-azobis-(4-methoxy)-3,4-dimethyl-valeronitrile APPH 2’,2’-azobis-(2-methylpropionamide) AO atomic orbital Boc tert-butyloxycarbonyl c- cyclic Cp Z5-cyclopentadienyl Cp * Z5-pentamethylcyclopentadienyl de diastereomeric excess DFT density functional theory DMA 9,10-dimethoxyanthracene DNA deoxyribonucleic acid ds diastereomeric ratio EA electron affinity ee enantiomeric excess EPR electron paramagnetic resonance FTIR Fourier transform infrared HALS hindered amines light stabilizer HMQC heteronuclear multiple-quantum coherence HOMO highest occupied molecular orbital HREELS high resolution electron energy loss spectroscopy hfs hyperfine splitting GC gas chromatography GPC gel permeation chromatography i- iso IP ionization potential INEPT insensitive nuclei enhanced by polarization transfer LFP laser flash photolysis LUMO lowest unoccupied molecular orbital MO molecular orbital n- normal NEXAFS near-edge X-ray absorption fine structure NMR nuclear magnetic resonance Organosilanes in Radical Chemistry C. Chatgilialoglu # 2004 John Wiley & Sons, Ltd ISBN: 0-471-49870-X
220 List of Abbreviations PED photoelectron diffraction PMB p-methoxybenzyl s- secondary SOMO singly occupied molecular orbital STM scanning tunneling microscope (or microscopy) t- or-t tertiary TEMPO 2,2,6,6-tetramethylpiperidine TFA trifluoroacetic acid THF tetrahydrofuran TMS trimethylsilyl Ts p-toluenesulfonyl XPS X-ray photoemission spectroscopy UV ultraviolet
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Organosilanes in Radical Chemistry
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DEDICATION To my parents XrZstoB an
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viii Contents 3.6 Hydrogen Atom: An
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PREFACE A large number of papers de
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ACKNOWLEDGEMENTS I thank Keith U. I
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2 Formation and Structures of Silyl
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10 Formation and Structures of Sily
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2 Thermochemistry 2.1 GENERAL CONSI
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Bond Dissociation Enthalpies 21 Tab
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Bond Dissociation Enthalpies 23 2.2
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Ion Thermochemistry 25 Table 2.4 Re
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Ion Thermochemistry 27 Table 2.5 El
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References 29 3. Goumri, A., Yuan,
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32 Hydrogen Donor Abilities of Sili
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4 Reducing Agents 4.1 GENERAL ASPEC
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General Aspects of Radical Chain Re
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Tris(trimethylsilyl)silane 53 Therm
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Tris(trimethylsilyl)silane 55 4.3.1
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Tris(trimethylsilyl)silane 57 A goo
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Tris(trimethylsilyl)silane 59 C(O)C
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Tris(trimethylsilyl)silane 61 radic
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Tris(trimethylsilyl)silane 63 86% y
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Tris(trimethylsilyl)silane 65 RO RO
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Tris(trimethylsilyl)silane 67 O AcO
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Tris(trimethylsilyl)silane 69 Tris(
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Other Silicon Hydrides 71 The reduc
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Other Silicon Hydrides 73 The decre
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Other Silicon Hydrides 75 Ph MeS O
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Other Silicon Hydrides 77 Table 4.6
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Silicon Hydride / Thiol Mixture 79
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Silylated Cyclohexadienes 81 and (4
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References 83 34. Kawashima, E., Uc
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References 85 104. Gimisis, T., Bal
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88 Addition to Unsaturated Bonds te
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90 Addition to Unsaturated Bonds ap
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92 Addition to Unsaturated Bonds 5.
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94 Addition to Unsaturated Bonds R
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96 Addition to Unsaturated Bonds Ph
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98 Addition to Unsaturated Bonds EP
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100 Addition to Unsaturated Bonds 5
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102 Addition to Unsaturated Bonds T
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104 Addition to Unsaturated Bonds R
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106 Addition to Unsaturated Bonds a
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110 Addition to Unsaturated Bonds S
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112 Addition to Unsaturated Bonds T
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114 Addition to Unsaturated Bonds I
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120 Unimolecular Reactions 1 Si(H)M
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122 Unimolecular Reactions t-Bu t-B
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124 Unimolecular Reactions MeO Si O
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126 Unimolecular Reactions t-Bu t-B
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128 Unimolecular Reactions R 1 R 2
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130 Unimolecular Reactions From the
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132 Unimolecular Reactions rearrang
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134 Unimolecular Reactions H 3 C +
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136 Unimolecular Reactions Br O Si(
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138 Unimolecular Reactions R3Si C C
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140 Unimolecular Reactions Me3Si O
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142 Unimolecular Reactions 43. Albe
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144 Consecutive Radical Reactions c
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146 Consecutive Radical Reactions O
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148 Consecutive Radical Reactions a
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150 Consecutive Radical Reactions d
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152 Consecutive Radical Reactions T
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154 Consecutive Radical Reactions M
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156 Consecutive Radical Reactions F
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162 Consecutive Radical Reactions i
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164 Consecutive Radical Reactions A
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Page 173 and 174: 168 Consecutive Radical Reactions r
Page 175 and 176: 170 Consecutive Radical Reactions E
Page 177 and 178: 172 Consecutive Radical Reactions O
Page 179 and 180: 174 Consecutive Radical Reactions A
Page 181 and 182: 176 Consecutive Radical Reactions P
Page 183 and 184: 178 Consecutive Radical Reactions f
Page 185 and 186: 180 Consecutive Radical Reactions O
Page 187 and 188: 182 Consecutive Radical Reactions 1
Page 189 and 190: 184 Consecutive Radical Reactions 8
Page 191 and 192: 186 Silyl Radicals in Polymers and
Page 223: 218 Silyl Radicals in Polymers and
Page 227 and 228: 222 Index Carbonyl sulfide 111 Carb
Page 229 and 230: 224 Index Organosilicon boranes 2,
Page 231 and 232: 226 Index Triethylsilane as mediato
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