"Front Matter". In: Organosilanes in Radical Chemistry - Index of

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References 217 37. Akasaka, T., Ando, W., Kobayashi, K., and Nagase, S., J. Am. Chem. Soc., 1993, 115, 10366. 38. Maeda, Y., Sato, R., Wakahara, T., Okamura, M., Akasaka, T., Fujitsuka, M., Ito, O., Kobayashi, K., Nagase, S., Kako, M., Nakadaira, Y., and Horn, E., J. Organomet. Chem., 2000, 611, 414. 39. Han, A., Wakahara, T., Maeda, Y., Niino, Y., Akasaka, T., Yamamoto, K., Kako, M., Nakadaira, Y., Kobayashi, K., and Nagase, S., Chem. Lett., 2001, 974. 40. Wakahara, T., Han, A., Niino, Y., Maeda, Y., Akasaka, T., Suzuki, T., Yamamoto, K., Kako, M., Nakadaira, Y., Kobayashi, K., and Nagase, S., J. Mater. Chem., 2002, 12, 2061. 41. Kusukawa, T., Kabe, Y., Erata, T., Nestler, B., and Ando, W., Organometallics, 1994, 13, 4186. 42. Kusukawa, T., Kabe, Y., and Ando, W., Organometallics, 1995, 14, 2142. 43. Sasaki, Y., Konishi, T., Fujitsuka, M., Ito, O., Maeda, Y., Wakahara, T., Akasaka, T., Kako, M., and Nakadaira, Y., J. Organomet. Chem., 2000, 599, 216. 44. Fujitsuka, M., Ito, O., Maeda, Y., Kako, M., Wakahara, T., and Akasaka, T., Phys. Chem. Chem. Phys., 1999, 1, 3527. 45. Kusukawa, T., Ohkubo, K., and Ando, W., Organometallics, 1997, 16, 2746. 46. Wayner, D.D.M., and Wolkow, R.A., J. Chem. Soc., Perkin Trans. 2, 2002, 23. 47. Buriak, J.M., Chem. Rev., 2002, 102, 1271. 48. Cicero, R.L., Linford, M.R., and Chidsey, C.E.D., Langmuir, 2000, 16, 5688. 49. Harper, J., and Sailor, M.J., Langmuir, 1997, 16, 5688. 50. Hamers, R.J., and Wang, Y., Chem. Rev., 1996, 96, 1261. 51. Miura, T., Niwano, M., Shoji, D., and Miyamoto, N., J. Appl. Phys., 1996, 79, 4373. 52. Wade, C.P., and Chidsey, C.E.D., Appl. Phys. Lett., 1997, 71, 1679. 53. Vezenov, D.V., Gobulev, V.B., and Melnikov, V.P., Macromolecules, 2003, 36, 1819. 54. Bansal, A., Li, X., Lauermann, I., Lewis, N.S., Yi, S.I., and Weinberg, W.H., J. Am. Chem. Soc., 1996, 118, 7225. 55. Okubo, T., Tsuchiya, H., Sadakata, M., Yasuda, T., and Tanaka, K., Appl. Surf. Sci., 2001, 171, 252. 56. Zhu, X.-Y., Boiadjiev, V., Mulder, J.A., Hsung, R.P., and Major, R.C., Langmuir, 2000, 16, 6766. 57. He, J., Patitsas, S.N., Preston, K.F., Wolkow, R.A., and Wayner, D.D.M., Chem. Phys. Lett., 1998, 286, 508. 58. Linford, M.R., Fenter, P., Eisenberger, P.M., and Chidsey, C.E.D., J. Am. Chem. Soc., 1995, 117, 3145. 59. Terry, J., Linford, M.R., Wigren, C., Cao, R., Pianetta, P., and Chidsey, C.E.D., Appl. Phys. Lett., 1997, 71, 1056. 60. Sieval, A.B., van den Hout, B., Zuilhof, H., and Sudhölter, E.J.R., Langmuir, 2001, 17, 2172. 61. Boukherroub, R., Morin, S., Bensebaa, F., and Wayner, D.D.M., Langmuir, 1999, 15, 3831. 62. Cicero, R.L., Chidsey, C.E.D., Lopinski, G.P., Wayner, D.D.M., and Wolkow, R.A., Langmuir, 2002, 18, 305. 63. Boukherroub, R., Morin, S., Sharpe, P., Wayner, D.D.M., and Allongue, P., Langmuir, 2000, 16, 7429. 64. Effenberger, F., Götz, G., Bidlingmaier, B., and Wezstein, M., Angew. Chem. Int. Ed., 1998, 37, 2462. 65. Wolkow, R., Tomietto, M., Boukherroub, R., and Wayner, D.D.M., J. Am. Chem. Soc., 2001, 123, 1535. 66. Sieval, A.B., Demirel, A.L., Nissink, J.W.M., Linford, M.R., van der Maas, J.H., de Jeu, W.H., Zuilhof, H., and Sudhölter, E.J.R., Langmuir, 1998, 14, 1759.
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Organosilanes in Radical Chemistry
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DEDICATION To my parents XrZstoB an
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viii Contents 3.6 Hydrogen Atom: An
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PREFACE A large number of papers de
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ACKNOWLEDGEMENTS I thank Keith U. I
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2 Formation and Structures of Silyl
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10 Formation and Structures of Sily
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2 Thermochemistry 2.1 GENERAL CONSI
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Bond Dissociation Enthalpies 21 Tab
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Bond Dissociation Enthalpies 23 2.2
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Ion Thermochemistry 25 Table 2.4 Re
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Ion Thermochemistry 27 Table 2.5 El
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References 29 3. Goumri, A., Yuan,
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32 Hydrogen Donor Abilities of Sili
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4 Reducing Agents 4.1 GENERAL ASPEC
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General Aspects of Radical Chain Re
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Tris(trimethylsilyl)silane 53 Therm
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Tris(trimethylsilyl)silane 55 4.3.1
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Tris(trimethylsilyl)silane 57 A goo
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Tris(trimethylsilyl)silane 59 C(O)C
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Tris(trimethylsilyl)silane 61 radic
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Tris(trimethylsilyl)silane 63 86% y
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Tris(trimethylsilyl)silane 65 RO RO
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Tris(trimethylsilyl)silane 67 O AcO
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Tris(trimethylsilyl)silane 69 Tris(
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Other Silicon Hydrides 71 The reduc
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Other Silicon Hydrides 73 The decre
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Other Silicon Hydrides 75 Ph MeS O
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Other Silicon Hydrides 77 Table 4.6
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Silicon Hydride / Thiol Mixture 79
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Silylated Cyclohexadienes 81 and (4
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References 83 34. Kawashima, E., Uc
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References 85 104. Gimisis, T., Bal
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88 Addition to Unsaturated Bonds te
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90 Addition to Unsaturated Bonds ap
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92 Addition to Unsaturated Bonds 5.
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94 Addition to Unsaturated Bonds R
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96 Addition to Unsaturated Bonds Ph
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98 Addition to Unsaturated Bonds EP
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100 Addition to Unsaturated Bonds 5
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102 Addition to Unsaturated Bonds T
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104 Addition to Unsaturated Bonds R
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106 Addition to Unsaturated Bonds a
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110 Addition to Unsaturated Bonds S
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112 Addition to Unsaturated Bonds T
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114 Addition to Unsaturated Bonds I
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120 Unimolecular Reactions 1 Si(H)M
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122 Unimolecular Reactions t-Bu t-B
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124 Unimolecular Reactions MeO Si O
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126 Unimolecular Reactions t-Bu t-B
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128 Unimolecular Reactions R 1 R 2
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130 Unimolecular Reactions From the
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132 Unimolecular Reactions rearrang
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134 Unimolecular Reactions H 3 C +
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136 Unimolecular Reactions Br O Si(
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138 Unimolecular Reactions R3Si C C
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140 Unimolecular Reactions Me3Si O
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142 Unimolecular Reactions 43. Albe
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144 Consecutive Radical Reactions c
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146 Consecutive Radical Reactions O
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148 Consecutive Radical Reactions a
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150 Consecutive Radical Reactions d
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152 Consecutive Radical Reactions T
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154 Consecutive Radical Reactions M
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156 Consecutive Radical Reactions F
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162 Consecutive Radical Reactions i
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164 Consecutive Radical Reactions A
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Page 175 and 176: 170 Consecutive Radical Reactions E
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Page 181 and 182: 176 Consecutive Radical Reactions P
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Page 187 and 188: 182 Consecutive Radical Reactions 1
Page 189 and 190: 184 Consecutive Radical Reactions 8
Page 191 and 192: 186 Silyl Radicals in Polymers and
Page 221: 216 Silyl Radicals in Polymers and
Page 225 and 226: 220 List of Abbreviations PED photo
Page 227 and 228: 222 Index Carbonyl sulfide 111 Carb
Page 229 and 230: 224 Index Organosilicon boranes 2,
Page 231 and 232: 226 Index Triethylsilane as mediato
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