Tokyo Chemical Industries (TCI) Reagents Guide 8th Edition -Synthestic Organic Chemistry,Materials Chemistry_GH

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D2853 2,6-Dimethyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol 1g 5g E0667 Ethyl 2-(5,5-Dimethyl-1,3,2-dioxaborinan-2-yl)benzoate 1g F0531 2-(2-Fluorophenyl)-5,5-dimethyl-1,3,2-dioxaborinane 1g H1280 2-(Hydroxymethyl)phenylboronic Acid Cyclic Monoester 1g 5g I0653 2-(2-Iodophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 1g M2665 Methyl 3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate 1g 5g N0824 2-Nitro-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline 1g P1855 2-Phenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 5g 25g T1950 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)acetanilide 1g T3028 3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)aniline 1g 5g T1951 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)aniline 1g 5g T3196 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)anisole 5g 25g T2923 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde 1g 5g T3162 3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzoic Acid 1g 5g T2841 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzoic Acid 1g T2945 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzyl Bromide 1g 5g T3031 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)biphenyl-4-ol 1g 5g T1952 2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenol 1g 5g T1953 3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenol 1g 5g T1954 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenol 1g 5g T3224 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl Acetate 1g 5g T3218 4,4,5,5-Tetramethyl-2-(1-naphthyl)-1,3,2-dioxaborolane 1g 5g N1006 4,4,5,5-Tetramethyl-2-(2-nitrophenyl)-1,3,2-dioxaborolane 1g 5g T3089 4,4,5,5-Tetramethyl-2-(3-perylenyl)-1,3,2-dioxaborolane 200mg 1g T3219 4,4,5,5-Tetramethyl-2-(m-tolyl)-1,3,2-dioxaborolane 1g 5g T2888 4,4,5,5-Tetramethyl-2-(p-tolyl)-1,3,2-dioxaborolane 1g 5g T3103 4,4,5,5-Tetramethyl-2-[4-(trifl uoromethyl)phenyl]-1,3,2-dioxaborolane (This product is only available in Japan.) 1g 5g T3261 4,4,5,5-Tetramethyl-2-[3-(triphenylen-2-yl)phenyl]-1,3,2-dioxaborolane 200mg 1g T2428 2-[2-(Trifl uoromethyl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 5g B4364 B4158 B3573 CH 3 CH3 O CH 3 B O CH 3 N N CH3 CH3 O B CH3 O CH 3 S S CH3 O CH 3 B O CH 3 CH3 CH3 CH3 CH3 CH3 O O B N N S B O O CH 2 CH3 CH3 CH 3 CH 3 B3363 B3200 B3749 B4051 D3772 CH3 CH3 O B S S CH 3 O CH 3 CH 3 O CH3 B O CH 3 CH 3 CH 3 CH 3 O B S S Br CH 3 O CH3 CH 3 CH 3 O B CH 3 O CH 3 Br N CH3 CH 3 CH 3 O B O CH 3 N O C O CH3 C CH3 CH3 CH 3 CH 3 O CH 3 B CH 3 O CH 3 CH 3 N O D4290 D4291 O0428 H1298 H1294 CH 3 (CH 2 ) 11 O CH 3 (CH 2 ) 5 CH 3 O B S CH3 CH3 CH3 O B O S (CH2)11CH3 CH3 CH3 CH3 O O CH3 B B N CH 3 O O CH 3 CH3 CH3(CH2)7 (CH2)7CH3 CH3 CH 3 O B O S CH 3 CH 3 O B CH 3 O S (CH2)5CH3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 CH 3 M2339 M2650 O N CH3 B OCH 3 CH 3 CH3 CH3 CH 3 O CH3 CH3 CH3 O B O N N M2681 CH 3 CH 3 CH 3 O B O CH 3 N N CH 3 O0439 CH3 CH3 O B CH3 O CH3 N (CH 2) 7CH 3 CH3 O CH3 B O CH3 CH3 O0410 CH 3 (CH 2 ) 7 CH 3 O B CH 3 O CH 3 CH 3 S CH 3 154
O0411 P2277 T3215 T2518 T3117 CH3 CH 3 O B CH3 O CH 3 T3236 T2349 S CH 3 S B O CH 3 CH 3 CH 3 O B CH 3 O CH 3 (CH2)7CH3 O CH 3 CH 3 N CH 3 CH3 O CH 3 B O CH 3 I0590 CH3 CH 3 O CH 3 B O CH 3 T2924 CH 3 CH 3 O B CH 3 O CH 3 N N CH 2 CH 2 CH 3 S N H CH 3 I0739 CH 3 CH 3 O B O CH 3 N N N CH 3 CH 3 O O B O CH3 CH3 CH 3 CH 3 T2756 CH 3 CH 3 CH3 O B O O S CH 3 CH 3 CH 3 B O S N N H T2345 N H CH 3 CH 3 O B CH 3 O CH 3 O B O CH3 CH3 N CH3 CH 3 B4364 1-Benzyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrazole 1g 5g B4158 2,6-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzo[1,2-b:4,5-b ]dithiophene 1g B3573 4,7-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,1,3-benzothiadiazole 1g B3363 5,5-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,2-bithiophene 5g B3200 5-Bromo-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,2-bithiophene 1g B3749 2-Bromo-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine 1g 5g B4051 1-(tert-Butoxycarbonyl)-1,2,3,6-tetrahydro-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine 1g D3772 3,5-Dimethyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)isoxazole 1g 5g D4290 3-Dodecyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophene 1g 5g D4291 4-Dodecyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophene 1g 5g O0428 9-(9-Heptadecanyl)-2,7-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)carbazole 200mg 1g H1298 3-Hexyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophene 1g 5g 25g H1294 4-Hexyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophene 5g M2650 2-Methoxy-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine 1g 5g M2339 1-Methyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrazole 1g 5g M2681 1-Methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrazole 1g 5g O0439 9-n-Octyl-2,7-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)carbazole 200mg O0410 3-n-Octyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophene 1g 5g O0411 4-n-Octyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophene 1g 5g P2277 1-Propyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrazole 1g 5g T3215 1-(Tetrahydropyran-2-yl)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrazole 1g 5g T2518 5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-2,2-bithiophene 1g 5g 25g T3117 3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)carbazole 1g 5g T3236 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)dibenzothiophene 1g 5g I0590 5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-indole 1g 5g I0739 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)isoquinoline 1g 5g T2756 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)pyrazole 1g 5g T2345 3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine 1g 5g 25g T2349 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine 1g 5g T2924 2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)thiophene 1g 5g 155
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sales@greyhoundchrom.com
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Cyclooctyl group [2+3] cycloadditio
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B2134 B1375 B1123 O Se OH CH3O O
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C0357 O C OOH Cl C2223 CH 3 C OOH C
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T2038 CF 3 Cl Bi Cl CF 3 CF 3 T1957
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O OTBS
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B1139 L0186 L0164 P1719 CH 3 P CH
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T1896 T0661 Si H Si H Si H T0398 T1
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R0128 O O O O Ar= R0135 Ar= Ar2 Cl
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1 1 1 NO 2 NO 2 O
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P1758 Potassium Fluoride 300g P1888
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T1382 Benzyltrimethylammonium Tribr
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O + F 3 C SiMe 3 R 1 R 2 [T1570] I
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3 3 O SO O 2 CF 3 Ph CH 3 Ph N S
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B3920 N N N C H O O0187 OCH 2 CH 3
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Pd-catalyzed Cross-coupling Cyanati
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122 341 1 O t-BuO C KOH C NH , M
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P0403 Phthalimide Potassium Salt 25
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Ph Ph Ph Ph P N P P O P N Ph Ph Ph
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C1500 Cyanomethylenetributylphospho
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B3817 B0832 CH 3 C1988 Cl C0905 N N
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S0836 T1562 T2908 T2929 T2224 F F T
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2002 2002 2003 2004 2004 2007 2003
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A1012 A0862 B2025 B0824 B1206 B1208
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N0701 (4-Nitrobenzyl)triphenylphosp
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D4588 Diethyl (Chloromethyl)phospho
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R CHO Reagent D2547 O ArO ArO P CH
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≈ High reactivity but low stabili
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D Pd II L X palladacycle (stable co
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T1350 Tetrakis(triphenylphosphine)p
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Fe(acac) 3 (5 mol%) (CH 2 ) 5 CH 3
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Liebeskind-Srogl Cross-coupling Rea
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Ar Ar Advantages of vBRIDP ® High
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B1246 1,4-Bis(diphenylphosphino)but
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D3446 CH 3 CH 3 CH 3 N N CH CH Cl 3
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R R X H + or + H M cf. Cross-coupli
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C2461 B1045 CH 2 CH 2 CH 2 CH2 Rh C
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B0034 Nickel(II) Benzenesulfonate H
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I. Ar-H/Ar-X Coupling (Pd, Ni, Cu,
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V0053 CH 2 CHMgBr A0963 Allylmag
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D0223 Dibutyltin Dichloride 25g 500
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B3196 (R,R )-2,2-Bis(diphenylphosph
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B4209 tert-Butyllithium (ca. 18% in
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F0172 Formic Acid Rubidium Salt 5g
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A0244 Aluminum sec-Butoxide 25g 500
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Ph OTMS CHO + HCHO aq. + Yb(OTf) 3
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A0005 B2283 F O F B2281 C0572 C0468
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P0052 Acetylacetone 25mL 500mL A088
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T0147 T1877 CH CH 3 3 N N CH 3 CH 3
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T1358 NH N N HN T1359 NH N N HN T22
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B3502 B3533 B0468 B3859 B2496 O O H
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D1559 D3849 B0985 M2512 M0300 CH 3
Page 107 and 108: M1097 M1183 M2077 M1995 O0370 N CH
Page 109 and 110: Q0076 Q0030 CH3O CH 2 HOCH 2 CH N C
Page 111 and 112: C0015 (+)-10-Camphorsulfonic Acid 2
Page 113 and 114: B1615 B2907 B2908 C1324 C1325 OH HO
Page 115 and 116: Ph Ph N CO 2 Bn + tandem cyclizatio
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Page 119 and 120: D1588 CH 3 L0071 H 2 N N0481 P1118
Page 121 and 122: D2645 CH 3 O C O O O CH 3 C O O O D
Page 123 and 124: M0573 CH CH 3 3 OCH CH 3 M0571 CH 3
Page 125 and 126: T0589 C0306 C2411 D2469 D3135 CH 3
Page 127 and 128: A0480 B3563 CHO OCH 3 A1247 B3577 (
Page 129 and 130: C1131 N-(2-Chlorobenzyloxycarbonylo
Page 131 and 132: B1702 T1071 O C O Br CBr 3 D2504 T1
Page 133 and 134: T2872 4-[2-(Trimethylsilyl)ethoxyca
Page 135 and 136: E0754 E0599 B2708 B2320 N CH 3 N HS
Page 137 and 138: B3104 B2701 CH 3 Br N (CH 2 ) 3 CH
Page 139 and 140: CF 3 (CF 2 ) n CF 3 P0839 (n=4), b.
Page 141 and 142: H 2 Pd / (PSi-Al 2 O 3 ) [P1944]
Page 143 and 144: B0529 C2188 C2893 B(OH) 2 CH 3 B(OH
Page 145 and 146: B(OH) 2 CN B3726 B3739 B2251 B2589
Page 147 and 148: B(OH) 2 CH 2 OH E0720 F0785 F0954
Page 149 and 150: P2158 N N B(OH) 2 P2162 CH 3CH 2CH
Page 151 and 152: C2571 4-Chloro-3-(trifl uoromethyl)
Page 153 and 154: T2792 5-m-Terphenylboronic Acid (co
Page 155 and 156: F0859 5-Fluoropyridine-3-boronic Ac
Page 157: N0824 CH 3 CH 3 O NO 2 B CH 3 O T31
Page 161 and 162: C1663 C2738 C1365 C1372 C1371 C1655
Page 163 and 164: T1901 CF 3 O HO CH 3 OH A1299 (S
Page 165 and 166: M1354 O O OH B4083 OH O N Boc O T00
Page 167 and 168: E0469 Ethyl (R)-(+)-1-Ethyl-2-pyrro
Page 169 and 170: I0465 O CH 3 OCH 3 NCO I0336 CH 3 N
Page 171 and 172: B1953 B2174 B2123 B3662 HO N C O B
Page 173 and 174: H0975 H1032 H0969 H0950 H0951 OH O
Page 175 and 176: H0969 (2S,5S)-2,5-Hexanediol 1g 5g
Page 177 and 178: C1189 D4035 D4036 D2827 D2828 H 2 N
Page 179 and 180: P0793 (S)-(-)-1-Phenylethylamine 25
Page 181 and 182: B2238 B2239 E0893 B4111 O G0363 G0
Page 183 and 184: M0963 P1504 V0117 CH 3 CH 3 M2091 O
Page 185 and 186: B3242 4-Bromo-1-butyne 5g C1195 3-C
Page 187 and 188: H0823 HC C CH P0528 OH O C O HC C C
Page 189 and 190: B4472 B2393 T2046 T1224 O CH3 S O
Page 191 and 192: B3693 (2R,3R,5S,6S)-5,6-Bis(azidome
Page 193 and 194: M1638 4-Methoxyphenyl 3-O-Allyl-2-a
Page 195 and 196: B1641 B1660 P2013 B4576 O (CH 2) 3
Page 197 and 198: C3133 Carbon Nanotube Single-walled
Page 199 and 200: 2004 2008 2009 2005 2005 201
Page 201 and 202: 2011 2005 2013 2011 2012 2004 2
Page 203 and 204: Corannulene [C2572] Truxene [T2752]
Page 205 and 206: Donors S n P3HT [P2018] O O F S S S
Page 207 and 208: B4342 2,4-Bis[4-(diethylamino)-2-hy
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M2589 CH 3 NH 2 . HBr M2556 CH 3 NH
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B4703 B3321 C1858 C0041 C0053 P052
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P1021 P0264 P0265 CH 3 (CH 2 ) 4 O
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E0191 CH 2CH 2CH 3 CH 3CH 2 N CH 2C
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Cathode Electron injection Electron
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T2274 4,4,4-Tri-9-carbazolyltriphen
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B2080 1,4-Bis[4-(di-p-tolylamino)st
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Top-contact Source Drain Organic se
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N0755 N0369 O O O T2206 O O O F F F
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S S S S S S S S BEDT-TTF [B1200]
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P1006 Copper(II) Phthalocyanine (-f
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D1070 D2021 M1045 T1503 (CH3)3C O (
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T1357 Tetrabutylammonium Diiodoaura
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Low Band Gap Polymers O O F O S S S
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A2051 B2805 B4348 D4563 D3932 Br D
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D4219 2,5-Dibromo-N-n-octyl-3,4-thi
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O0245 P1127 S S (CH 2 ) 17 CH 3 (CH
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C3021 C2715 D4373 D4057 D4777 S S D
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B4439 B3908 B3554 B4452 C0032 C1031
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B4441 CH3(CH2)3 CH CH2 CH2CH3 B4450
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B3442 B4451 B4426 B3977 B4475 B0816
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A0632 1-Aminopyrene 1g 5g 25g A2180
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B2803 B4664 B2685 B3949 D0632 CH 3
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D2172 I0776 CH3O T1724 I O C H N I
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A2789 3-Aminofl uoranthene 1g 5g B4
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P1671 N O C H T1228 N CH 3 B0088
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A0267 2-Aminobenzenethiol 25mL 100m
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N O Spiropyran [T0366] NO 2 hν NO
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A2869 CH 3 O CH 3 A2869 Aberchro
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H0812 C1606 C2618 A1828 CH 3(CH 2
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E0254 E0262 E0240 M0602 O CH 3CH 2O
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C0618 C1260 C0671 C0672 H 3C CH 3 H
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H1449 2,3,6,7,10,11-Hexakis(hexylox
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H0695 HO P1037 CH 3CH 2CH 2 COOH CO
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H0695 4-(4-Hydroxyphenyl)benzoic Ac
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N0117 N0540 N NH 2 NO 2 N0119 N NO
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Triangular Lattice of Dimer [Pd(dmi
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T1861 [5,10,15,20-Tetrakis(4-methox
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O 2 N O N N O NPNN [D2295] CH 3 CH
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N N (CH 2 ) 3 CH 3 CH 3 FeCl 4 [B26
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B2111 3-(2-Benzimidazolyl)-7-(dieth
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M1338 P0996 T1495 RO T1360 N NH N N
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O O O O Imidation R O N 3 2 1 12 11
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N X N n n = 1: cyanine n = 2: carbo
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B4400 CH3 CH3 CH3 (CH 3) 3C C(CH 3)
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F0143 A0601 T0450 P0572 R0040 CH2CH
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D4780 (CH2)3CH3 O N O N (CH2)3CH3 D
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OSi(CH 3 ) 3 O O CH 3 CH 3 CH 3 OH
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S0850 OH T1937 N CH N N CH N N N N
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≥ Inorganic Layer (2D Perovs
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Y R Si X 3
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D2632 Diethoxy(3-glycidyloxypropyl)
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B4123 1,2-Bis(triethoxysilyl)ethane
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C2700 Chlorodimethyl[3-(2,3,4,5,6-p
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2005 A0623 B0041 B2888 NH 2 SH
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P0861 Pentafl uorobenzenethiol 5g 2
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C0045 Carboxymethyl Cellulose Sodiu
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319
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A1671 A0680 O CH 3 CH 3 O HO C
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B1231 O C COOCH 3 M2028 O N CH 3 O
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D3307 CH3 D3321 D4100 C1994 Cl Ti
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B1291 B1784 D1313 D0134 D0688 T053
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C1634 Methyl (S)-(-)-2-Chloropropio
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O0266 4-Oxo-2,2,6,6-tetramethylpipe
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B2715 O C C O OCH 2 OC 9 H 19 mixtu
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P0270 Triethyl Phosphate 25g 500g P
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B0496 CH 3O O O OCH3 D1230 Dieth
Page 343 and 344:
B1970 4,4-Bis(,-dimethylbenzyl)diph
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B2108 O D3380 CH 2 OCH 2 B4269 O CH
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D2877 D1533 D2878 D1830 D2684 D2321
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H0889 CH3 CH2 O C CH 3 n O n = 6,8
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A2122 3A-Amino-3A-deoxy-(2AS,3AS)--
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D0570 D2554 HO D1534 CH 3 O H1412 M
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P0055 P1177 A0445 CH 3 NH 2 B0628 U
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E1031 E0120 E0122 E0126 E0127 CH 3
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D0980CH 3 (CH 2 ) 11 NH 2 D1452 CH
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B0599 1-Bromohexadecane 25g 500g B4
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359
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PPTS PTSA py Salen SDS TBAB TBAD TB
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Organic Solvents bp°C mp°C d20/4
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365
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367
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369
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371
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373
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375
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Tokyo Chemical Industries (TCI) Reagents Guide 8th Edition -Synthestic Organic Chemistry,Materials Chemistry_GH

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