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‘ DAF in fish<br />

year-round<br />

processing plants in Europe is generally restricted to plants operating on a<br />

basis (NovaTec, 1993a).<br />

5.3.4 Chemical Treatment<br />

Chemical treatment generally refers to the addition of chemicals to screened effluent. This<br />

is required as emulsified oil and particulate matter suspended in wastewater are generally<br />

negatively charged. The resulting repulsion substantially impedes certain particle removal<br />

processes such as gravity settling, flotation and hydrocyclone separation. Consequently,<br />

coagulant which reduce or eliminate the repulsive forces between particles are often<br />

added to wastewaters prior to employing these processes. Coagulant are generally<br />

used in conjunction with flocculants which are long chain synthetic or natural polymers<br />

and cause the agglomeration of the now neutral particles.<br />

Both coagulant and flocculants require rapid mixing with the wastewater in order to be<br />

effective. Metal salts are the most common coagulant and flocculants in use at full scale<br />

facilities practicing chemical aided treatment. The most widely used coagulant and<br />

coagulant combinations are: ferric chloride and ferric sulphate, aluminum chloride and<br />

aluminum sulphate, sodium hexametaphosphate, anionic polyelectrolyte, and calcium<br />

chloride. Accurate pH control is generally required, as the efficiency of coagulant and<br />

.<br />

flocculants is pH dependent.<br />

A disadvantage of using iron or aluminum salts as coagulant is the increase in sludge<br />

volume, contamination of the resulting sludge with metals which may make the product<br />

unsuitable for reuse, reduce its value, or cause the sludge not to be accepted at landfills.<br />

Water soluble organic polyelectrolytes avoid these problems and have the added<br />

advantages of requiring concentrations of only a few milligrams per Iitre and not<br />

generating extra quantities of waste for disposal (Steiner and Gee, 1992). Nonetheless,<br />

there are very few full scale installations using only organic polyelectrolytes. The major<br />

detriment appears to be lower removal efficiencies (NovaTec, 1993a).<br />

Results of selected jar-test and bench scale studies are reported below. The economics,<br />

however, are unknown.<br />

Numerous processes using coagulation for treating fish processing wastewater have been<br />

reported. Ohhashi (1974) described a process involving heating effluent to 70-100 “C<br />

62

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