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7 HANDLING AND STORAGE SAFETY DATA SHEET Page: 2 (Conform Reach) Date of creation: 03/02/2009 Date of update: 05/08/2009 A GUARDTECHREMOVER ® 25 Ready to use Handling Advice on safe handling : Avoid inhalation. Avoid contact with skin, eyes and clothing. Wash hands before breaks and .immediately after handling the product. Storage Requirements for storage areas and containers : Keep container tightly closed in a dry and well-ventilated place. Advice on common storage : Keep away from food, drink and animal feeding stuffs. Other <strong>data</strong> : No decomposition if stored and applied as directed. 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Components with workplace control parameters : (2- Méthoxyméthylethoxy) propanol (N° CAS 34590-94-8) : 308 mg/m3, 50 ppm. .Can be absorbed through the skin. Engineering measures : Ensure adequate ventilation, especially in confined areas. Personal protective equipment Hand protection : Impervious gloves. Eye protection : Safety goggles. Skin and body protection : Rubber apron Boots. Hygiene measures : Avoid contact with the skin and the eyes. Wash hands before breaks and immediately after .handling the product. Wash contaminated clothing before reuse. 9 PHYSICAL AND CHEMICAL PROPERTIES Physical appearance : Liquid. Colour : Light yellow. Odour : Mild. pH value : 2.2 Density : 1,05 g/cm3 at 22 °C Solubility in water [vol/vol] : Totally Flash point [°C] : Not applicable. 10 STABILITY AND REACTIVITY Conditions to avoid : Stable at normal temperatures and storage conditions. Material to avoid : Strong acids and bases (slowly hydrolyzes), oxidizing agents (strong). Hazardous reactions : No decomposition if used as directed. 11 TOXICOLOGICAL INFORMATION Acute oral toxicity : Hydroxyacetic Acid : DL50/ rat = 1 938 mg/kg. (2-Méthoxyméthylethoxy) propanol: DL50/ rat = 5 382 mg/kg. Acute inhalation toxicity : Hydroxyacetic Acid : CL50/ 4H/ rat female > 5,2 mg/l. Méthod: aerosol. Acute dermal toxicity : (2-Méthoxyméthylethoxy) propanol : DL50/ rabbit = 9 510 mg/kg. Skin irritation : Hydroxyacetic Acid : rabbit. Résult: Corrosif. Eye irritation : Hydroxyacetic Acid : rabbit. Résult: Corrosif. Sensitisation : Hydroxyacetic Acid : guinea pig. Did not cause sensitization on laboratory animals. Human experience : Excessive exposures may affect human health, as follows. Inhalation : Cough, shortness of breath, pain, local irritation. Skin contact : Discomfort, Irritation, Rash, Necrosis. Eye contact : Severe irritation, corrosion, ulceration. Ingestion : Diarrhoea, vomiting, gastrointestinal disturbance, abdominal pain.
12 ECOLOGICAL INFORMATION SAFETY DATA SHEET Page: 3 (Conform Reach) Date of creation: 03/02/2009 Date of update: 05/08/2009 A GUARDTECHREMOVER ® 25 Ready to use Elimination information (persistence and degradability) Biodegradability : Taking into consideration the properties of several components, the product is estimated to 0be biodegradable according to OECD classification. Bioaccumulation : No <strong>data</strong> available. Toxicity to fish : Hydroxyacetic Acid: CL50 / 96h / Fathead minnow : 164 mg/l. 0(2-Méthoxyméthylethoxy) propanol : CL50 / Pimephales promelas (Fathead minnow) : 0 > 1 000 mg/l. Toxicity to algae : Hydroxyacetic Acid: / CE50 / Algae : 21,6 mg/l. Aquatic Toxicity : Hydroxyacetic Acid : / CE50 / 48h / Daphia : 141 mg/l. 0(2-Méthoxyméthylethoxy) propanol : Static test / CE50 / 48h / Daphia : 1 919 mg/l. 0Mehod: No information available. 13 DISPOSAL CONSIDERATIONS Product : Dispose of as hazardous waste in compliance with local and national regulations. Contaminated packaging : If recycling is not practicable, dispose of in compliance with local regulations. 14 TRANSPORT INFORMATION Further information : Not classified as dangerous in the meaning of transport regulations. 15 REGULATORY INFORMATION Labelling according to EC Directives Symboles : Xi – Irritant. R Phrases : R36/38 Irritating to eyes and skin. S Phrases : S24/25 Avoid contact with skin and eyes. .S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical .advice. .S28 After contact with skin, wash immediately with plenty of water. .S37 Wear suitable gloves. .S60 This material and its container must be disposed of as hazardous waste. Sensitising components contains : 1-Octanol reaction product with epichlorohydrin and 2-mercaptoethanol. .May produce an allergic reaction. 16 OTHER INFORMATION Text of R-phrases mentioned in Section 3 : R22 Harmful if swallowed. .R34 Causes burns. .R36 Irritating to eyes. .R43 May cause sensitization by skin contact. .R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic .environment. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The above information relates only to the specific material(s) designated herein and may not be valid for such material(s) used in combination with any other materials or in any process or if the material is altered or processed, unless specified in the text. End of document
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