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Aviation and the Global Atmosphere

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<strong>Aviation</strong> <strong>and</strong> <strong>the</strong> <strong>Global</strong> <strong>Atmosphere</strong><br />

<strong>Aviation</strong> <strong>and</strong> <strong>the</strong> <strong>Global</strong> <strong>Atmosphere</strong><br />

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O<strong>the</strong>r reports in this collection<br />

Figure 2-1: Net ozone production (24-hr average) as a function of NO x in <strong>the</strong> upper troposphere (adapted from<br />

Jaeglé et al., 1998). During <strong>the</strong> NASA-sponsored SUCCESS campaign (April-May 1996), simultaneous<br />

measurements of HO 2 <strong>and</strong> NO were obtained from <strong>the</strong> NASA DC-8 aircraft. These observations define <strong>the</strong> rate of<br />

ozone production via <strong>the</strong> chemistry outlined in Section 2.1.2.1. Also shown in this figure are three calculations for<br />

average tropospheric conditions experienced above 11 km during SUCCESS. Case 0 illustrates <strong>the</strong> production<br />

rate expected if <strong>the</strong> only primary source of HO x is <strong>the</strong> reaction of O1D with H 2 O <strong>and</strong> CH 4 . Case 1 is <strong>the</strong> rate<br />

calculated by assuming acetone is present at 510 ppbv, consistent with recent airborne measurements (Singh et<br />

al., 1995; Arnold et al., 1997). Case 2 assumes that a convective source of peroxides <strong>and</strong> formaldehyde provides<br />

additional HO x production. These non-traditional HO x sources dramatically increase <strong>the</strong> ozone production rate in<br />

<strong>the</strong> dry (

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