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(12) PATENT APPLICATION PUBLICATION (21) Application No.6795/DELNP/2008 A<br />

(19) INDIA<br />

(22) Date <strong>of</strong> filing <strong>of</strong> Application :07/08/2008 (43) Publication Date : 24/10/2008<br />

(54) Title <strong>of</strong> the invention : "PHOTOSENSITIZER DYE"<br />

(51) International classification :H0IM 14/00 (71)Name <strong>of</strong> Applicant :<br />

(31) Priority Document No :2006-031320 1)SHIMANE PERFECTURAL GOVERNMENT<br />

(32) Priority Date :08/02/2006<br />

Address <strong>of</strong> Applicant :1, TONO-MACHI, MATSUE-SHI,<br />

(33) Name <strong>of</strong> priority country :Japan<br />

SHIMANE 690-8501, JAPAN Japan<br />

(86) International Application No :PCT/JP2007/051939 2)OSAKA UNIVERSITY<br />

Filing Date<br />

:05/02/2007 (72)Name <strong>of</strong> Inventor :<br />

(87) International Publication No :WO 2007/091525 1)KE-JIAN JIANG<br />

(61) Patent <strong>of</strong> Addition to Application<br />

Number<br />

Filing Date<br />

:NA<br />

:NA<br />

2)SHUJI NODA<br />

3)SHOZO YANAGIDA<br />

(62) Divisional to Application Number :NA<br />

Filing Date<br />

:NA<br />

(57) Abstract :<br />

A theme <strong>of</strong> the present invention is to provide a new' transition metal complex, useful as a photosensitizer dye for a photoelectric<br />

conversion element having an excellent durability <strong>and</strong> a high photoelectric conversion characteristic. The present invention provides a<br />

bivalent transition metal complex constituted <strong>of</strong> (i) a bipyridyl polyacidlc lig<strong>and</strong>, such as a d1carboxybipyridyl (dcbpy) llg<strong>and</strong>, as an<br />

adsorption site for adsorption onto titanium dioxide <strong>part</strong>icle surfaces; (ii) a lig<strong>and</strong>, selected <strong>from</strong> the group consisting <strong>of</strong> an<br />

isothiocyanato group, an isocyanato group, <strong>and</strong> an isoselenocyanato group <strong>and</strong> enabling absorption <strong>and</strong> excitation at long wavelengths<br />

<strong>and</strong> charge transfer; <strong>and</strong> (ill) a bipyridyl (bpy) lig<strong>and</strong>, having an alkyl group or an alkoxy group, preferably a long-chain alkyl group,<br />

<strong>and</strong> a conjugately bonded thienylvinylene group, arainophenylenevinylene group, etc. , <strong>and</strong> improving an absorbance <strong>of</strong> a transition<br />

metal complex <strong>and</strong> im<strong>part</strong>ing stability against nucleophlle to a sensitizer dye that improves an absorption bathochromlc effect.<br />

No. <strong>of</strong> Pages : 43 No. <strong>of</strong> Claims : 7<br />

The Patent Office Journal 24/10/2008 26262

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