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(12) PATENT APPLICATION PUBLICATION (21) Application No.6476/DELNP/2008 A<br />

(19) INDIA<br />

(22) Date <strong>of</strong> filing <strong>of</strong> Application :24/07/2008 (43) Publication Date : 24/10/2008<br />

(54) Title <strong>of</strong> the invention : "PROCESS FOR PRODUCING PHENOL AND METHYL ETHYL KETONE"<br />

(51) International classification :C07C 37/08 (71)Name <strong>of</strong> Applicant :<br />

(31) Priority Document No :60/773,288 1)EXXONMOBIL CHEMICAL PATENTS, INC.<br />

(32) Priority Date :14/02/2006 Address <strong>of</strong> Applicant :5200 BAYWAY DRIVE, BAYTOWN,<br />

(33) Name <strong>of</strong> priority country :U.S.A.<br />

TX 77520-5200, USA. U.S.A.<br />

(86) International Application No<br />

:PCT/EP07/001206 (72)Name <strong>of</strong> Inventor :<br />

Filing Date<br />

:08/02/2007 1)JIHAD M. DAKKA<br />

(87) International Publication No :WO 2007/093358 2)JON E. STANAT<br />

(61) Patent <strong>of</strong> Addition to Application Number :NA<br />

3)FRANCISCO M. BENITEZ<br />

Filing Date<br />

:NA<br />

4)JOHN S. BUCHANAN<br />

(62) Divisional to Application Number :NA<br />

5)JANE C. CHENG<br />

Filing Date<br />

(57) Abstract :<br />

:NA<br />

6)JEFFREY T. ELKS<br />

A process for producing phenol <strong>and</strong> methyl ethyl ketone comprises contacting benzene <strong>and</strong> a C4 alkylating agent under alkylation<br />

conditions <strong>and</strong> in the presence <strong>of</strong> an alkylation catalyst comprising at least one molecular sieve <strong>of</strong> the MCM-22 family to produce an<br />

alkylation effluent comprising sec-butylbenzene; wherein the contacting is conducted in a plurality <strong>of</strong> reaction zones <strong>and</strong> the C4<br />

alkylating agent is supplied to each <strong>of</strong> the reaction zones. A sec-butylbenzene fraction is recovered <strong>from</strong> the alkylation effluent <strong>and</strong><br />

comprises at least 95 wt% sec-butylbenzene, less than 100 wt ppm <strong>of</strong> C8+ olefins, <strong>and</strong> less than 0.5 wt% <strong>of</strong> isobutylbenzene <strong>and</strong> tertbutylbenzene.<br />

The sec-butylbenzene fraction is then oxidized to produce sec-butylbenzene hydroperoxide <strong>and</strong> the hydroperoxide is<br />

cleaved to produce phenol <strong>and</strong> methyl ethyl ketone.<br />

No. <strong>of</strong> Pages : 38 No. <strong>of</strong> Claims : 25<br />

The Patent Office Journal 24/10/2008 26010

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