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(12) PATENT APPLICATION PUBLICATION (21) Application No.6393/DELNP/2008 A<br />

(19) INDIA<br />

(22) Date <strong>of</strong> filing <strong>of</strong> Application :22/07/2008 (43) Publication Date : 24/10/2008<br />

(54) Title <strong>of</strong> the invention : "TRANSITION METAL CATALYSTS"<br />

(51) International classification :B01J 31/18 (71)Name <strong>of</strong> Applicant :<br />

(31) Priority Document No :06250599.5<br />

1)INEOS EUROPE LIMITED<br />

(32) Priority Date :03/02/2006<br />

Address <strong>of</strong> Applicant :HAWKSLEASE, CHAPEL LANE,<br />

(33) Name <strong>of</strong> priority country :EPO<br />

LYNDHURST, HAMPSHIRE SO43 7FG, GREAT BRITAIN.<br />

(86) International Application No :PCT/GB2007/000268 U.K.<br />

Filing Date<br />

:25/01/2007 (72)Name <strong>of</strong> Inventor :<br />

(87) International Publication No :WO 2007/088329 1)STEFAN KLAUS SPITZMESSER<br />

(61) Patent <strong>of</strong> Addition to Application<br />

Number<br />

Filing Date<br />

:NA<br />

:NA<br />

2)PAUL RICHARD ELOWE<br />

3)JOHN E. BERCAW<br />

(62) Divisional to Application Number :NA<br />

Filing Date<br />

:NA<br />

(57) Abstract :<br />

Transition metal catalysts comprise (a) a source <strong>of</strong> a Group 3 to 10 transition metal, (b) a lig<strong>and</strong> having the formula: R1 R2 X-Y-XR3<br />

R4 wherein X is phosphorus, arsenic or antimony, Y is a bridging group having the formula: Z-(A)-D-Rm wherein Z is the moiety<br />

linking the X groups, A is a linear or cyclic hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl<br />

linking group wherein the number <strong>of</strong> atoms directly linking Z to D is 1, 2 or 3, D is N, P, As, O, S or Se, R is hydrogen, alky],<br />

hydrocarbyl, substituted hydrocarbyl, heteroalkyl, heterohydrocarbyl or substituted heterohydrocarbyl, <strong>and</strong> m is 1 or 2, R1 ,R2 ,R3 ,<br />

<strong>and</strong> R4 are the same or different <strong>and</strong> represent hydrocarbyl or functionalized hydrocarbyl moieties with the proviso that if D is<br />

nitrogen, R is not a cyclic ether, <strong>and</strong> optionally an activator. The transition metal catalysts are suitable for the selective trimerisafion or<br />

tetramerisation <strong>of</strong> olefins in <strong>part</strong>icular ethylene.<br />

No. <strong>of</strong> Pages : 35 No. <strong>of</strong> Claims : 26<br />

The Patent Office Journal 24/10/2008 25855

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