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First International Conference on MOLDAVIAN RISKS – FROM ...

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<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />

16-19 May 2012, Bacau, Romania<br />

IN SITU SOIL FLUSHING <strong>–</strong> STUDIES ON YIELD OF<br />

POLLUTED REMEDIATION SANDY SOILS WITH ORGANIC<br />

COMPOUNDS ACIDS<br />

Alexandra-Dana Chitimus, Valentin Nedeff, Emilian Mosnegutu<br />

“Vasile Alecsandri” University of Bacau, Department of Envir<strong>on</strong>mental Engineering and<br />

Mechanical Engineering<br />

Corresp<strong>on</strong>ding author: Alexandra-Dana Chiţimuş, dana.chitimus@ub.ro<br />

Abstract: Producti<strong>on</strong> activities have affected soils in time, by means of: mining,<br />

excavati<strong>on</strong>s, waste deposits, landslides, erosi<strong>on</strong>, salting, acidificati<strong>on</strong> etc. Currently, at an<br />

internati<strong>on</strong>al level, approximately 20 % of the soils are acidified, and in Romania there are<br />

approximately 2 milli<strong>on</strong> hectares. The soil depolluti<strong>on</strong> process is very complex due to the<br />

great number of factors which influence it, such as:<br />

- properties of the soil, of geological formati<strong>on</strong>s or of subterraneous waters;<br />

- pollutant’s properties;<br />

- properties of the media with which the pollutant interacts.<br />

After permeating the geological medium, pollutants go through some phenomena related<br />

to: transport, transformati<strong>on</strong>, transfer, accumulati<strong>on</strong> and fixati<strong>on</strong>. These phenomena<br />

c<strong>on</strong>tribute to the spreading within, and distributi<strong>on</strong> of, pollutants in the elements of the<br />

geological envir<strong>on</strong>ment and to the alterati<strong>on</strong> of the chemical structure of the geological<br />

medium. Techniques for the treatment of polluted soils have as an objective the<br />

destructi<strong>on</strong>, eliminati<strong>on</strong> or immobilizati<strong>on</strong> of pollutants. Depolluti<strong>on</strong> techniques can be<br />

classified depending <strong>on</strong> the nature of procedures employed, as follows:<br />

- physical procedures, which c<strong>on</strong>sist in the extracti<strong>on</strong> of the pollutant from the<br />

c<strong>on</strong>taminated envir<strong>on</strong>ment;<br />

- biological procedures, which make use of microorganisms acti<strong>on</strong>s in order to eliminate<br />

organic or mineral pollutants present in soil, silt, sediments or liquid effluents;<br />

- thermal procedures, in which heat is used so as to neutralize the pollutant, to isolate it,<br />

or to make it inert.<br />

- chemical or electrochemical procedures using the chemical properties of pollutants in<br />

order to make them inert, to destroy, or to separate from the polluted envir<strong>on</strong>ment with<br />

the help of adapted reacti<strong>on</strong>s.<br />

For a soil remediati<strong>on</strong> installati<strong>on</strong> functi<strong>on</strong> <strong>on</strong> the principle soil flushing in situ for ensure a<br />

high degree of treatment must be correctly identified correlati<strong>on</strong>s between: soil properties<br />

that influence the treatment process, structural characteristics of the installati<strong>on</strong> of<br />

remediati<strong>on</strong> and work factors. The theoretical and experimental research of the soil<br />

depolluti<strong>on</strong> process presented in this dissertati<strong>on</strong> c<strong>on</strong>stitute an attempt to offer, by means<br />

of detailed analysis, the c<strong>on</strong>structive and functi<strong>on</strong>al relati<strong>on</strong>s of dependence which can set<br />

the basis of new depolluti<strong>on</strong> installati<strong>on</strong>s, created by way of modernizing the old <strong>on</strong>es, or<br />

by devising new models, models which should be competitive with internati<strong>on</strong>al <strong>on</strong>es.<br />

Keywords: remediati<strong>on</strong> of soil, organic acid compounds, in situ soil flushing, yield.<br />

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