First International Conference on MOLDAVIAN RISKS – FROM ...
First International Conference on MOLDAVIAN RISKS – FROM ...
First International Conference on MOLDAVIAN RISKS – FROM ...
You also want an ePaper? Increase the reach of your titles
YUMPU automatically turns print PDFs into web optimized ePapers that Google loves.
“VASILE ALECSANDRI” UNIVERSITY OF BACAU<br />
“GHEORGHE ASACHI” TECHNICAL UNIVERSITY OF IASI<br />
NATIONAL INSTITUTE FOR EARTH PHYSICS<br />
HABITAT FOR HUMANITY ROMANIA<br />
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong><br />
<strong>MOLDAVIAN</strong> <strong>RISKS</strong> <strong>–</strong> <strong>FROM</strong> GLOBAL TO<br />
LOCAL SCALE<br />
Editors:<br />
Mioara Mandea<br />
Gabriel Lazar<br />
Valentin Nedeff<br />
16-19 May, 2012<br />
Bacau, ROMANIA<br />
BOOK OF ABSTRACTS<br />
Alma Mater Bacau 2012<br />
ISBN: 978-606-527-201-9
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong><br />
<strong>MOLDAVIAN</strong> <strong>RISKS</strong> <strong>–</strong> <strong>FROM</strong> GLOBAL TO<br />
LOCAL SCALE<br />
16-19 May, 2012<br />
Bacau, ROMANIA<br />
<str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> organized under the patr<strong>on</strong>age of:<br />
INTERNATIONAL UNION OF GEODESY & GEOPHYSICS<br />
EUROPEAN GEOSCIENCES UNION<br />
INSTITUTE OF GEODYNAMICS ”SABBA S.<br />
STEFANESCU”, ROMANIAN ACADEMY<br />
With the financial support of<br />
ROMANIAN NATIONAL AUTHORITY FOR SCIENTIFIC<br />
RESEARCH
Editors: Mioara Mandea, Gabriel Lazar, Valentin Nedeff<br />
<str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> Chair<br />
Mioara Mandea <strong>–</strong> Centre Nati<strong>on</strong>al d'Etudes Spatiales, Paris<br />
Scientific Committee Co-chair<br />
Gabriel Lazar <strong>–</strong> „Vasile Alecsandri” University of Bacau, Romania<br />
Scientific Committee<br />
Maricel Agop <strong>–</strong> “Gheorghe Asachi” Technical University of Iasi, Romania<br />
Peter M. Atkins<strong>on</strong> <strong>–</strong> University of Southampt<strong>on</strong>, UK<br />
Crisan Demetrescu <strong>–</strong> Romanian Academy, Institute of Geodynamics Sabba S. Stefanescu,<br />
Romania<br />
Gerald Duma <strong>–</strong> Central Institute for Meteorology and Geodynamics, Austria<br />
Maria Gavrilescu <strong>–</strong> “Gheorghe Asachi” Technical University of Iasi, Romania<br />
Michael Ghil <strong>–</strong> Ecole Normale Supérieure, Paris, France &. University of California, Los<br />
Angeles, USA.<br />
I<strong>on</strong> Giurma <strong>–</strong> “Gheorghe Asachi” Technical University of Iasi, Romania<br />
Victor Mocanu <strong>–</strong> University of Bucuresti, Romania<br />
Valentin Nedeff <strong>–</strong> „Vasile Alecsandri” University of Bacau, Romania<br />
Mirela Praisler <strong>–</strong> “Dunarea de Jos” University of Galati, Romania<br />
Marcel Radu <strong>–</strong> CONVERSMIN, Bucuresti, Romania<br />
Tiberiu Rusu <strong>–</strong> Technical University of Cluj-Napoca, Romania<br />
Carmen Teodosiu <strong>–</strong> “Gheorghe Asachi” Technical University of Iasi, Romania<br />
Borbala Vajda - Nati<strong>on</strong>al Commissi<strong>on</strong> for Nuclear Activities C<strong>on</strong>trol, Romania<br />
Gheorghe Voicu <strong>–</strong> Politehnica University of Bucuresti, Romania<br />
Jochen Zschau <strong>–</strong> GFZ German Research Centre for Geosciences, Potsdam, Germany<br />
Local organizing committee<br />
Chair: Valentin Nedeff<br />
Members: Anghelut Marius, Baciu Gheorghe, Barsan Narcis, Bibire Luminita, Caraman<br />
Iuliana, Chitimus Alexandra-Dana, Cocarcea Andreea, Diac<strong>on</strong>escu Alina, Faciu Ema, Furdu<br />
Iulian, Ifrim Irina, Lazar Gabriel, Lazar Iuliana, Mosnegutu Emilian, Panainte Mirela,<br />
Radulian Mircea, Schnakovszky Carol, Stamate Marius, Teodosiu Carmen, Tirtoaca (Irimia)<br />
Oana, Tomozei Claudia, Vasilache Traian, Zichil Valentin, Zirnea Sorina<br />
Descrierea CIP a Bibliotecii Naţi<strong>on</strong>ale a României<br />
<strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> c<strong>on</strong>ference (2012;<br />
Bacău)<br />
Moldavian risks - from global to local scale : internati<strong>on</strong>al c<strong>on</strong>ference: Bacău, 2012:<br />
book of abstracts / ed.: Mioara Mandea, Gabriel Lazăr, Valentin Nedeff. - Bacău : Alma<br />
Mater, 2012<br />
Index<br />
ISBN 978-606-527-201-9<br />
I. Mandea, Mioara (ed.)<br />
II. Lazăr, Gabriel (ed.)<br />
III. Nedeff, Valentin (ed.)<br />
502.58(498.3)(063)
Envir<strong>on</strong>mental risks come in many forms. Earthquakes<br />
and floods are the best known because they are the most<br />
comm<strong>on</strong>. But modern society is also threatened by<br />
other risks, such as climate change, solar storms, and<br />
the hazard of impacts from outer space. While the<br />
risks from these hazards are worldwide, disasters affect<br />
local communities, and an appropriate resp<strong>on</strong>se to them<br />
must engage local communities. World-renowned<br />
experts in these fields met at Bacau University in May<br />
of 2012 to discuss these hazards, and engage the local<br />
community in addressing them.<br />
This Book of Abstracts c<strong>on</strong>tains the abstracts of the<br />
papers presented with this occasi<strong>on</strong>.
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
ABSTRACTS<br />
INSTABILITY OF THE MANTLE LITHOSPHERE DRIVES INTERMEDIATE-<br />
DEPTH SEISMICITY BENEATH THE VRANCEA REGION OF ROMANIA<br />
G. A. Houseman, P. Lorinczi, Y. Ren, G. W. Stuart ......................................... 15<br />
THE HAZARD OF IMPACTS <strong>FROM</strong> SPACE<br />
M. Purucker ....................................................................................................... 16<br />
CLIMATE VARIABILITY AND COSMIC RAYS<br />
E. Friis-Christensen ........................................................................................... 17<br />
CLUSTERING OF EARTHQUAKE EPICENTER DATA BY DISCRETE<br />
PERFECT SETS ALGORITHM<br />
A.D Gvishian, S.M. Agayan, M.N. Dobrovolsky, Sh. R. Bogoutdinov,<br />
M. Mandea ......................................................................................................... 18<br />
DEVELOPMENT OF EARTHQUAKE-PRONE AREAS PATTERN<br />
RECOGNITION <strong>FROM</strong> 1972 TO 2012<br />
A.D. Gvishiani, A.I. Gorshkov, A. A. Soloviev .................................................. 19<br />
GEODYNAMICS AND INTERMEDIATE-DEPTH SEISMICITY IN VRANCEA<br />
A. I. Zadeh, L. Matenco, M. Radulian, S. Cloetingh, G. Panza ....................... 20<br />
QUESTIONS ABOUT THE GLOBAL WARMING<br />
J.-L. Le Mouël .................................................................................................... 21<br />
GEOMAGNETIC STORMS ─ BETWEEN BEAUTY AND RISK<br />
M. Mandea ......................................................................................................... 22<br />
PROMOTING CARBON CAPTURE AND GEOLOGICAL STORAGE (CCS) IN<br />
ROMANIA<br />
C. S. Sava, C. C<strong>on</strong>stantin, A. Proca, C. Tomescu, A. Dudu, S. Anghel .......... 23<br />
SEISMOGENIC ZONES AND SEISMIC HAZARD AT LOCAL AND<br />
REGIONAL SCALES IN MOLDAVIA<br />
M. Radulian, N. Mandrescu .............................................................................. 24<br />
CLUSTER ANALYSIS TO SELECT THE SEISMIC ZONES OF ROMANIA<br />
B. Rashid ............................................................................................................ 25<br />
STATISTICAL ANALYSIS OF TIME SERIES OF WIND SPEAD AND<br />
TEMPERATURE<br />
B. Rashid, G. Spatari ......................................................................................... 26<br />
IMPROVING MANAGEMENT AND EVALUATION OF <strong>RISKS</strong> AND<br />
NATURAL DISASTERS BY REGIONAL GIS DISTRIBUTED APPLICATION<br />
I. Furdu, C. Tomozei, I. Pandele ....................................................................... 27<br />
VRANCEA ZONE IN THE FRAME OF GLOBAL SEISMICITY<br />
I. Sandu .............................................................................................................. 28<br />
WATER INDUCED GEOHAZARDS MEASURED WITH SPACEBORNE<br />
INTERFEROMETRY TECHNIQUES<br />
F. Serban, M. Radu, D. Teleaga, M. Sorin ....................................................... 29<br />
7
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
SEISMIC HAZARD WITHIN SE CARPATHIANS AND RELATED<br />
FORELAND IN THE GEODYNAMIC CONTEXT OF THE BLACK SEA<br />
OPENING<br />
L. Besutiu ........................................................................................................... 30<br />
WHY IT IS SO HARD TO ASSESS LANDSLIDES’ HAZARD AND RISK IN<br />
ROMANIA?<br />
R. M. Maftei, C. Filipciuc .................................................................................. 32<br />
PLIO-PLEISTOCENE CONNECTION BETWEEN THE ‘VRANCEA ZONE’<br />
AND THE SOUTHERN END OF THE HARGHITA VOLCANIC CHAIN<br />
I. Seghedi, A. Szakács ........................................................................................ 33<br />
THE RELEVANCE OF VOLCANIC HAZARD IN ROMANIA: IS THERE<br />
ANY?"<br />
A. Szakács, I. Seghedi ........................................................................................ 34<br />
UPPER MANTLE STRUCTURES BENEATH THE CARPATHIAN-<br />
PANNONIAN REGION: IMPLICATIONS FOR ITS GEODYNAMICS<br />
Y. Ren, G. W. Stuart, G. A. Houseman, B. Dando, C. I<strong>on</strong>escu, E.Hegedüs, S.<br />
Radovanović, Y. Shen, South Carpathian Project working group ................... 35<br />
SPACE CLIMATE CHARACTERIZATION OF THE HELIOSPHERE-<br />
MAGNETOSPHERE ENVIRONMENT<br />
C. Demetrescu, V.Dobrica ................................................................................. 36<br />
LONG-TERM CHANGES IN THE ROMANIAN CLIMATE<br />
V. Dobrica, C. Demetrescu ................................................................................ 37<br />
THE SURFACE TECTONICS OF LITHOSPHERIC REMOVAL BENEATH<br />
THE SOUTH EAST CARPATHIANS<br />
O. Gogus, G. Houseman .................................................................................... 38<br />
ANALYSIS OF HAZARD POLLUTION ON OLD PESTICIDE STORAGES IN<br />
MOLDOVA<br />
O. Bogdevich, O. Cadocinicov, E. Culighin ...................................................... 39<br />
GEOLOGICAL HAZARDS ASSESMENT IN REPUBLIC OF MOLDOVA<br />
(CASE STUDY PRUT RIVER VALEY)<br />
I. Nicoara, O. Bogdevich.................................................................................... 40<br />
SURLARI GEOMAGNETIC OBSERVATORY: ROLE INTO SPACE AND<br />
EARTH WEATHER CONCEPT<br />
A. Isac, M. Mandea, A. Soare ............................................................................ 41<br />
GEOLOGICAL AND PALEONTOLOGICAL MONUMENTS IN REPUBLIC OF<br />
MOLDOVA (CASE STUDY VILLAGE NASLAVCEA, DISTRICT OCNIŢA)<br />
C. Mogorici, I. Nicoara ...................................................................................... 42<br />
INVESTIGATION OF THE POTENTIAL HAZARDS GENERATORS IN THE<br />
VICINITY OF THE MUNICIPAL LANDFILLS<br />
B. Stanescu, M. Petrescu, G. Batrinescu .......................................................... 43<br />
A COMPARISON OF GPS SOLUTIONS FOR STRAIN AND SKS FAST<br />
DIRECTIONS: IMPLICATIONS FOR MODES OF SHEAR IN THE MANTLE<br />
OF A PLATE BOUNDARY ZONE<br />
8
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
N. Houlié, T. Stern, C. Chamberlain ................................................................. 44<br />
SYNERGISTIC EFFECT FOR THE RETENTION OF METAL CATIONS<br />
OBTAINED BY A COMPLEX ORGANIC - INORGANIC COMPOUND OF<br />
DIFFERENT TYPES OF CLAY<br />
I. D. Nistor, Gh. Surpateanu, N. D. Mir<strong>on</strong>, A. Ciobanu, I. M. Lazar .............. 45<br />
ESENTIAL TOOLS TO MITIGATE OF VRANCEA STRONG EARTHQUAKES<br />
ON <strong>MOLDAVIAN</strong> URBAN ENVIRONMENT<br />
Gh. Marmureanu, C. I<strong>on</strong>escu, A. Marmureanu ............................................... 46<br />
A SEISMIC RISK ANALYSIS FOR VRANCEA AND BACAU COUNTIES,<br />
BASED ON SELENA AND GIS SOFTWARE<br />
D. Toma Danila .................................................................................................. 48<br />
A BAYESIAN APPROACH FOR THE ASSESSMENT OF RISK IMPACT CASE<br />
STUDY FOR DIGITAL RISK IMPACT<br />
E. Nechita, C. V. Muraru, M. Talmaciu .......................................................... 49<br />
A NEW APPROACH OF ATMOSPHERIC VORTEX DYNAMICS BY NON-<br />
DIFFERENTIABILITY<br />
A. Timofte, M. M. Cazacu, D. Gh. Dimitriu, S. O. Gurlui, M. Agop ............... 50<br />
STRESS TESTS FOR CERNAVODA NPP - ASSESSMENT OF PROTECTION<br />
AGAINST EARTHQUAKES<br />
C. Ciurea-Ercau, E. Dinca, M. Tr<strong>on</strong>ea ............................................................. 51<br />
SOME REMARKS ABOUT THE CLIMATE CHANGES IN SUB-ARCTIC<br />
SCANDINAVIA<br />
D. C<strong>on</strong>stantinescu, C. J<strong>on</strong>ass<strong>on</strong>, A. Kristoferss<strong>on</strong>, E. Sirbu .......................... 52<br />
GREENHOUSE GASES EMISSIONS <strong>FROM</strong> WASTEWATER TREATMENT<br />
PLANTS<br />
D. Manea, E. Manea, D. Robescu ..................................................................... 53<br />
ENVIRONMENTAL PROTECTION AND OPPORTUNITIES FOR<br />
HARNESSING JIU VALLEY'S HARD COAL ENERGETIC POTENTIAL<br />
Gh. Chiril, N. Ilias, S. M. Radu, I. Gruneantu, L. Toma, O. Rotea,<br />
L. Codreanu, M. Stefanie, S. Copaescu ............................................................ 54<br />
LINKING WATER ACCOUNTING TOOLS: WATER FOOTPRINT<br />
APPLICATION IN LIFE CYCLE ASSESSMENT<br />
S. A. Ene, I. M. Comandaru, G. Barjoveanu, C. Teodosiu ............................. 55<br />
MODIFFICATION OF GAMMA SPECTROSCOPY ENERGIES IN<br />
ENVIRONMENTAL RADIATIONS<br />
M. Stamate, I. M. Lazar, G. Lazar ..................................................................... 56<br />
USING MULTIVARIATE STATISTICS AND GIS ON ASSESSING HEAVY<br />
METAL POLLUTION OF SOIL IN 22 CITIES OF MOLDAVIA<br />
E. Faciu, I. Lazar, I. Ifrim, G. Lazar ................................................................ 57<br />
RISK OF PHOTOINHIBITION ON BRASSICA NAPUS GROWTH UNDER<br />
SOLAR RADIATION CORRELATE WITH STRUCTURAL CHANGES OF<br />
INFRARED MOLECULAR SPECTRUM IN LIPIDS<br />
I. Lazar, D. Nicuta, I. Ifrim, M. Stamate, G. Lazar .......................................... 58<br />
9
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
MATHEMATICAL MODELS DESIGNED TO ASSESS THE RISK<br />
SITUATIONS CREATED BY RIVER FLOWS<br />
G. Murariu, M. Praisler, S. Ciochina, A. Stoica ............................................... 59<br />
DATA INCOHERENCE FOR COMBINATORIAL OPTIMIZATION<br />
PROBLEMS<br />
G. C. Crisan, C. M. Pintea, C. Chira ................................................................. 60<br />
<strong>RISKS</strong> RELATED TO EXTRACTION OF MINERALS AGGREGATES <strong>FROM</strong><br />
RIVERS<br />
S. Cartacuzencu, G. Lazar ................................................................................. 61<br />
IN SITU SOIL FLUSHING <strong>–</strong> STUDIES ON YIELD OF POLLUTED<br />
REMEDIATION SANDY SOILS WITH ORGANIC COMPOUNDS ACIDS<br />
A. D. Chitimus, V. Nedeff, E. Mosnegutu ......................................................... 62<br />
RESEARCH ON THE HEAT BALANCE COMPONENTS OF A SMALL SBR<br />
BASIN USED FOR DOMESTIC WASTEWATER TREATMENT<br />
N. Barsan, V. Nedeff .......................................................................................... 63<br />
EXPERIMENTING RIGID AND ELASTIC CLAMPING METHODS OF<br />
ACOUSTIC SCREENS<br />
C. Tomozei, V. Nedeff, M. Panainte, G. Andrioai ............................................ 64<br />
COMPARATIVE STUDY VIEWING THE EFFICIENCY OF THE GRANULAR<br />
FILTERS DEPENDING ON THE TYPE OF THE FILTER MATERIAL<br />
O. (Irimia) Tirtoaca , V. Nedeff, M. Panainte .................................................. 65<br />
STUDY UPON THE ADVANTAGES OF PREDICTIVE MAINTENANCE IN<br />
MONITORING OF ROLLING BEARINGS<br />
D. C. Nadabaica, V. Nedeff, L. Bibire, G. Andrioai ......................................... 66<br />
STUDIES AND RESEARCH ON THE INFLUENCE OF THE CLIMATIC<br />
FACTORS ON AMMONIA POLLUTION IN BACAU<br />
D. Capsa, V. Nedeff, M. Panainte, N. Barsan ................................................. 67<br />
STUDIES AND RESEARCH ON THE DETERMINATION OF HEAVY<br />
METALS <strong>FROM</strong> THE BANKS OF THE SIRET RIVER BASIN<br />
C. Radu, V. Nedeff, N. Barsan, A. Dumitrescu ................................................ 68<br />
RESEARCH ON THE CAUSES OF TORRENTIAL RAINS IN THE CENTRAL<br />
SOUTHERN OF <strong>MOLDAVIAN</strong> REGION ON 05 SEPTEMBER 2007<br />
M. Vasilica, D. Capsa, I. Covaci, V. Nedeff, N. Barsan ................................... 69<br />
RESEARCH ON THE USE OF ORGANIC FLOCCULANTS IN TREATING<br />
THE SLUDGE <strong>FROM</strong> THE MUNICIPAL WASTEWATER TREATMENT<br />
PLANTS<br />
M. Turcu, V. Nedeff, N. Barsan ........................................................................ 70<br />
THEORETICAL ASPECTS OF THE RELIABILITY REQUIREMENTS OF<br />
WASTEWATER TREATMENT PLANTS<br />
A. Stoicescu ........................................................................................................ 71<br />
ENVIRONMENTAL RISK DUE TO LEACHATE <strong>FROM</strong> NON-CONFORMING<br />
LANDFILLS<br />
A. Vatra, G. Lazar .............................................................................................. 72<br />
10
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
THE CONSEQUENCES OF REDUCING THE AVAILABILITY OF BIOMASS<br />
IN TIME<br />
P. Voicu .............................................................................................................. 73<br />
STUDIES REGARDING THE BEHAVIOR OF SOLID PARTICLES ON A<br />
FLAT OSCILATING SURFACE<br />
O. B<strong>on</strong>tas, V. Nedeff, E. F. Mosnegutu, M. Panainte, O. Tartoaca (Irimia) .. 74<br />
MODELING HYDRO-MORPHOLOGICAL DATA <strong>FROM</strong> A HYDROGRAPHIC<br />
AREA, USING GIS ARCHYDRO<br />
D. Dascalita ........................................................................................................ 75<br />
THE IMPACT OF HYDROTECHNICAL ARRANGEMENTS ON WATER<br />
COURSES AND AQUATIC ECOSYSTEMS<br />
D. Dascalita ............................................................. Error! Bookmark not defined.<br />
INFLUENCE OF LAND USES ON WATER FLOW AND NUTRIENTS IN THE<br />
WATERSHED TAABO: INTEREST OF A MODELING WITH SWAT<br />
A. Anoh Kouao, J. P. Jourda, K. J. Kouame, J.-J. Tanoh Koua, G. Lazar ..... 77<br />
ENVIRONMENTAL RISK ASSESMENT OF WASTEWATER SLUDGE<br />
DISPOSAL<br />
E. Manea, D. Manea, D. Robescu ..................................................................... 78<br />
VALORIZATION OF WHEY <strong>FROM</strong> DAIRIES AS FERTILIZER. WHEY<br />
INFLUENCE ON GERMINATION AND PLANT GROWTH<br />
L. Grosu, B. Fernandez, C. G. Grigoraş, O. I. Patriciu, I. C. Grig-Alexa, D.<br />
Nicuţa, D. Ciobanu, V. Nedeff, L. Gavrila, A. L. Finaru ................................. 79<br />
ASPECTS OF WATER DEMINERALIZATION WITH MIXED-LAYER ION-<br />
EXCHANGERS<br />
I. Rogoveanu Radosavlevici, D. N. Robescu ..................................................... 80<br />
SUSTAINABLE DEVELOPMENT IN THE CONTEXT OF GLOBALIZATION.<br />
ANALYSIS OF THE REGULATIONS OF THE WORLD TRADE<br />
ORGANIZATION<br />
Gh. Durac, N. H. Tit .......................................................................................... 81<br />
INTERACTION BETWEEN TOXIC LEAD IONS AND MODIFIED CALCIUM<br />
BENTONITES IN ENVIRONMENT DEPOLLUTION<br />
A. M. Georgescu, I. D. Nistor, C. Penot, F. Nardou ......................................... 82<br />
HETEROGENEOUS WATER PHASE CATALYSIS AS AN<br />
ENVIRONMENTAL APPLICATION<br />
N. Plat<strong>on</strong>, I. D. Nistor, I. Siminiceanu .............................................................. 83<br />
ASSESSMENT OF SEDIMENT AND PHOSPHORUS IN BUYO LAKE, COTE<br />
D’IVOIRE, USING SWAT (SOIL AND WATER ASSESSMENT TOOL)<br />
MODEL<br />
J. J. Tanoh Koua, J. P. Jourda, K. J. Kouamé, A. A. Kouao, G. Lazar .......... 84<br />
CLIMATE VARIABILITY AND WATER RESOURCES IN RURAL SENEGAL:<br />
THE CASE OF THE BOROUGH OF FIMELA<br />
P. Ndour, A. Kane, A. Niang, G. Lazar ............................................................. 85<br />
PREVENT MAJOR ACCIDENTS INVOLVING HAZARDOUS SUBSTANCES<br />
11
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
D. C. Felegeanu, V. Nedeff ................................................................................ 86<br />
RISK ASSESSMENT OF HEAVY METALS ON AIR POLLUTANTS IN<br />
BACAU CITY<br />
A. Cocarcea, E. Faciu, I. Lazar, G. Lazar ........................................................ 87<br />
ASSESSING TEMPORAL AND SPATIAL VARIATIONS IN SIZE OF<br />
DIFFERENT FISH POPULATIONS RELATED WITH DIFFERENT BIOTIC<br />
ENVIRONMENTAL ATTRIBUTES<br />
C. Ureche, D. Ureche, I. Lazar .......................................................................... 88<br />
RISK EXPOSURE TO ENVIRONMENTAL STRESS OF SEVERAL FISH<br />
SPECIES REFLECTS ON ALLOMETRIC SCALING DECREASES<br />
D. Ureche, C. Ureche, I. Lazar .......................................................................... 89<br />
INCREASE RISK OF VARY DISEASE FREQUENCY CORRELATED WITH<br />
AIR POLLUTANTS IN BACAU CITY DURING 2011 YEAR<br />
A. Diac<strong>on</strong>escu, I. Lazar, E. Faciu, A. Cocarcea ............................................... 90<br />
AIIIBVI BASED PHOTOVOLTAIC RECEPTORS FOR EXPERIMENTAL<br />
DETERMINATION OF CARBON COMPOUNDS IN ATMOSPHERE<br />
I. Evtodiev, O. Racovet, I. Caraman, M. Stamate ............................................. 91<br />
QUANTITATIVE DETERMINATIONS OF CARBON OXIDES <strong>FROM</strong><br />
ATMOSPHERE AFTER ELECTRONIC ABSORPTION SPECTRA<br />
I. Caraman, O. Racovet, D. Untila, S. Evtodiev, M. Stamate ........................... 92<br />
RISK OF MYOCARDIAL INFARCTION REVEALED BY VARIATION OF<br />
CARDIAC TROPONIN I LEVELS WITH AGE AND GENDER: A STUDY OF<br />
PATIENTS HOSPITALIZED IN THE CARDIOLOGY DEPARTMENT OF<br />
BACAU CITY HOSPITAL DURING THE 2008-2011 PERIOD<br />
L. Vasile, V. Artenie, I. Lazar ............................................................................ 93<br />
ANALYSIS OF ESSENTIAL MINERAL CONTENT IN DIFFERENT TYPES<br />
OF FLOUR<br />
I. Lazar, I. Caraman, A. Moroi.......................................................................... 94<br />
ASSESSING THE CRACKING RISK AT TUBULAR JUNCTIONS OF THE<br />
TECHNOLOGICAL ROUTES USED IN NUCLEAR POWER PLANTS<br />
A. Judele, V. Zichil ............................................................................................. 95<br />
AVOIDING <strong>RISKS</strong> IN SOLID-GAS DEPOLLUTION BY CONTROLLING<br />
PARAMETERS IN FLUIDIZED BED<br />
G. Muntianu, I. D. Nistor, C. Jinescu, G. Djelveh ........................................... 96<br />
FRIENDLY ENVIRONMENTAL TECHNIQUES USED TO IMPROVE THE<br />
EFFICIENCY OF EXTRACTION <strong>FROM</strong> LULA (PERSIA AMERICANA)<br />
B. U. Saha, G. Kansci, E. Fokou, I. M. Lazar, F. X. Etoa ............................... 97<br />
DIABETES MELLITUS COMPLICATIONS RISK ASSESSED BY RED<br />
BLOOD CELL FTIR PARAMETERS<br />
M. Gutu, M. Avadanei, V. Rusu, S. Mir<strong>on</strong>, I. Hurjui, I. Grierosu,<br />
C. Stefanescu ...................................................................................................... 98<br />
12
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
MULTIVARIATE ANALYSIS OF PHYSICO-CHEMICAL DATA<br />
CHARACTERISTICS OF WASTES WITH POTENTIAL RADIOACTIVE RISK<br />
NEAR BACAU CITY<br />
S. Zirnea, I. Lazar, B. U. Saha, G. Lazar .......................................................... 99<br />
STUDY REGARDING THE INFLUENCE OF NUTRIENTS OVER THE<br />
WATER OF BISTRITA RIVER, ON THE HIGHLY MODIFIED SECTOR<br />
BETWEEN PIATRA NEAMT AND BACAU<br />
D. Dascalita, G. Ardeleanu .............................................................................. 100<br />
RISK EXPOSURE ON NONIONIZING RADIATION ASSOCIATED WITH<br />
VARIATION OF LACTOSE AND PROTEIN CONCENTRATION IN DAIRY<br />
PRODUCTS<br />
I. Ifrim, I. Lazar, M. Stamate .......................................................................... 101<br />
PHYSICO-CHEMICAL PROPERTIES DIFFERENCES OF WATER<br />
COLLECTED <strong>FROM</strong> BISTRITA RIVER IN BACAU CITY AREA RELEASED<br />
BY UNIVARIATE ANALYSES<br />
A. Rusu, A. Panaite, I. Moian, R. Iancu, S. Herghelegiu, E. Faciu,<br />
I. Lazar ............................................................................................................. 102<br />
COMPARATIVE STUDY VIEWING THE EFFICIENCY OF THE GRANULAR<br />
FILTERS DEPENDING ON THE TYPE OF THE FILTER MATERIAL<br />
M. Stanila, V. Nedeff, M. Panainte, A.D. Chitimus ....................................... 103<br />
DEFICIENCIES AND POSSIBLE ENVIRONMENTAL <strong>RISKS</strong> OF<br />
PHOTOCATALYSIS USED FOR WATER AND AIR DEPOLLUTION<br />
T. Vasilache, G. Lazar, M. Stamate ................................................................. 104<br />
COMPOSITE MATERIALS WITH CARBON CLUSTERS AS ADSORBED<br />
MICRO-AND MACRO-MOLECULAR ELEMENTS<br />
P. Lozovanu, M. Caraman, A. Cresciuc .......................................................... 105<br />
CYBERDYN: A STATE-OF-THE-ART SUPERCOMPUTER FOR<br />
GEODYNAMIC MODELING OF ACTIVELY SEISMIC ZONES<br />
M. Pomeran, V.C. Manea, M. Manea, L. Besutiu, L. Zlagnean .................... 107<br />
FLOODS - A REPETITIVE RISK ON TROTUS VALLEY<br />
A. Gutas, L. Fedor, A. Balint, L. Misaila ...................................................... 1077<br />
13
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
14
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
INSTABILITY OF THE MANTLE LITHOSPHERE DRIVES<br />
INTERMEDIATE-DEPTH SEISMICITY BENEATH THE<br />
VRANCEA REGION OF ROMANIA<br />
Gregory A. Houseman, Piroska Lorinczi, Y<strong>on</strong>g Ren, Graham W. Stuart<br />
1 School of Earth and Envir<strong>on</strong>ment, University of Leeds, LS2 9JT, Leeds, UK<br />
Corresp<strong>on</strong>ding author: Greg Houseman, G.A.Houseman@leeds.ac.uk<br />
Abstract: The South Carpathian Project, a major seismological experiment carried out<br />
during 2009-2011 by the University of Leeds, the Nati<strong>on</strong>al Institute of Earth Physics in<br />
Bucharest, the Eötvös Loránd Geophysical Institute in Budapest, and the Seismological<br />
Survey of Serbia in Belgrade, has resulted in the most detailed tomographic images yet<br />
obtained of the upper mantle structure beneath the Pann<strong>on</strong>ian <strong>–</strong> Carpathian regi<strong>on</strong> (Ren et<br />
al., 2012). These images illuminate the upper mantle over a wide regi<strong>on</strong>, but they<br />
specifically shed new light <strong>on</strong> the unique geological structure which is resp<strong>on</strong>sible for the<br />
damaging earthquakes that occur in the upper mantle beneath the Vrancea Z<strong>on</strong>e of the<br />
South-east Carpathians. Since 1940 there have been four large earthquakes (M > 6.9) in<br />
this structure. These earthquakes create a major threat to life and infrastructure in<br />
Bucharest and other Romanian cities. The earthquakes occur at the NE end of an<br />
asymmetric high velocity structure that extends upward to the SW, oblique to the southern<br />
edge of the South Carpathians. This sub-vertical high-velocity body is bounded by slow<br />
anomalies to the NW and SE, which extend down to the top of the Mantle Transiti<strong>on</strong> Z<strong>on</strong>e.<br />
With increasing depth, the fast regi<strong>on</strong> becomes more circular in cross-secti<strong>on</strong> until about<br />
400 km where the fast anomaly fades out. The main mass of fast (presumably dense)<br />
material is located directly beneath the seismic activity. The earthquakes are all<br />
characterised by near-vertical T-axes, which means they are caused by vertical stretching.<br />
The seismic moment release rate can be used to estimate vertical strain rates; these strainrates<br />
imply that the mantle at 200 km is moving downward at about 20 mm/yr relative to<br />
the surface. The depth distributi<strong>on</strong> of seismic-moment release rate follows a characteristic<br />
pattern that is most easily explained if this high velocity structure is produced by a<br />
Rayleigh-Taylor instability acting <strong>on</strong> an unstable stratificati<strong>on</strong> of mantle lithosphere above<br />
asthenosphere. Three-dimensi<strong>on</strong>al numerical experiments of viscous flow c<strong>on</strong>firm that the<br />
drip-like structure that we image may be a natural c<strong>on</strong>sequence of a Rayleigh-Taylor<br />
instability triggered by recent c<strong>on</strong>vergence of Adria and Europe acting <strong>on</strong> a relatively weak<br />
Transylvanian lithosphere. The shallow (above 200 km) asymmetry of the fast structure,<br />
which c<strong>on</strong>nects the unstable mass to the relatively rigid Moesian platform, may play a<br />
significant role in enabling the efficient propagati<strong>on</strong> of seismic energy toward the SW<br />
(toward Bucharest). One property of Rayleigh-Taylor instability is that rates of<br />
deformati<strong>on</strong> increase with time during the peak development phase of the instability. The<br />
present high rate of tect<strong>on</strong>ic activity in this regi<strong>on</strong> therefore is probably short-lived <strong>on</strong> a<br />
geological scale (< 1 Myr) but is likely to increase in energy before it is abates.<br />
Key words: South-East Carpathians; Upper Mantle Seismicity; Rayleigh-Taylor instability; Seismic<br />
Moment Rate.<br />
15
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
THE HAZARD OF IMPACTS <strong>FROM</strong> SPACE<br />
Michael Purucker<br />
Planetary Geodynamics Laboratory, GSFC/NASA, Greenbelt, MD USA<br />
Corresp<strong>on</strong>ding author: Michael Purucker, Michael.E.Purucker@nasa.gov<br />
Abstract: Near-earth objects (NEOs) have been implicated in mass extincti<strong>on</strong>s in Earth<br />
history. The most recent mass extincti<strong>on</strong> occurred at the End-Cretaceous, and is associated<br />
with the Chixulub impact structure in Mexico and the Deccan traps in India. NEOs<br />
comprise both the much more abundant asteroid comp<strong>on</strong>ent, with orbits between 0.98 and<br />
1.3 astr<strong>on</strong>omical units, and the much rarer cometary comp<strong>on</strong>ent. NASA has now cataloged<br />
90% of NEOs larger than 1 km (civilizati<strong>on</strong> ending) and has begun the task of identifying<br />
those larger than 140 m (city killers). NEOs are identified by earth-based telescope, but an<br />
infra-red space-based telescope in an orbit between the Earth and Venus would offer<br />
superior viewing geometry for these dim objects. NEOs have no substantial gravity well,<br />
and hence are ideal targets for both NASA’s robotic and human explorati<strong>on</strong> program. The<br />
natural history of NEOs suggests that they originate via planetary res<strong>on</strong>ances from the<br />
main asteroid belt and the trans-Neptunian disk, and that their dynamical lifetimes are <strong>on</strong><br />
the order of 10 Myr. Once identified, their threat can be assessed via precise orbit<br />
determinati<strong>on</strong>, and steps might be c<strong>on</strong>sidered to re-direct them away from Earth. However,<br />
the complex interacti<strong>on</strong> of science, psychology, politics, and m<strong>on</strong>ey has hindered attempts<br />
at an integrated global approach to the problem. The threat from NEOs was much more<br />
comm<strong>on</strong> in the deep past, in what is termed the Late heavy bombardment 4 billi<strong>on</strong> years<br />
ago. This is a period when most of the Mo<strong>on</strong>’s largest impact basins were formed, and by<br />
inference the largest impact basins <strong>on</strong> Mercury and Mars.<br />
Key words: impacts, hazard, extincti<strong>on</strong>, planetary defense.<br />
16
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
CLIMATE VARIABILITY AND COSMIC RAYS<br />
Eigil Friis-Christensen<br />
Techncal University of Denmark, Nati<strong>on</strong>al Space Institute<br />
Eigil Friis-Christensen, efc@space.dtu.dk<br />
Abstract: Our Climate is changing all the time due to a number of various causes, internal<br />
as well as external, natural as well as anthropogenic. In additi<strong>on</strong> to the ice ages, which are<br />
believed to be caused by variati<strong>on</strong>s of the Earth’s orbit, paleoclimate records indicate<br />
significant changes of regi<strong>on</strong>al climate that are str<strong>on</strong>gly correlated with solar activity<br />
variati<strong>on</strong>s - both the 11-year period and l<strong>on</strong>ger periods. Various hypotheses regarding the<br />
physical mechanism have been proposed. In this presentati<strong>on</strong> the hypothesis of an effect <strong>on</strong><br />
global cloud cover of cosmic rays modulated by solar activity will be discussed, based <strong>on</strong><br />
results from observati<strong>on</strong>s, laboratory experiments and theoretical c<strong>on</strong>siderati<strong>on</strong>s. A much<br />
better understanding of the natural variati<strong>on</strong>s of climate is a fundamental requirement for a<br />
credible assessment of the human c<strong>on</strong>tributi<strong>on</strong> to climate change, now and in the future.<br />
Key words: climate, cosmic rays, clouds, atmosphere, observati<strong>on</strong>s, experiments.<br />
17
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
CLUSTERING OF EARTHQUAKE EPICENTER DATA BY<br />
DISCRETE PERFECT SETS ALGORITHM<br />
Gvishiani A.D 1 , Agayan S.M. 1 , Dobrovolsky M.N. 1 , Bogoutdinov Sh. R. 1 ,<br />
Mandea M. 2<br />
1 Geophysical Center of Russian Academy of Sciences (GC RAS), Moscow, Russia<br />
2 CNES - Centre Nati<strong>on</strong>al d'Etudes Spatiales<br />
Corresp<strong>on</strong>ding author: a.gvishiani@gcras.ru<br />
Abstract: In the frame of “Discrete Mathematical Analysis” (DMA), launched by A.<br />
Gvishiani, J. B<strong>on</strong>nin and S. Agayan in early 90s, numerous original fuzzy logic-based<br />
clustering algorithms have been designed. This branch of the DMA is called by DMAclustering.<br />
A new Discrete Perfect Sets (DPS) algorithm efficiently extends the DMAclustering<br />
branch. Algorithms of DMA-clustering deal with very noisy data and do not<br />
require separability of the sets under c<strong>on</strong>siderati<strong>on</strong>. They focus <strong>on</strong> topological filtering of<br />
multidimensi<strong>on</strong>al data sets. This filtering allows efficient cutting off n<strong>on</strong>-essential parts of<br />
subsets. In this sense, DMA-clustering represents a “postcluster” stage in cluster analysis.<br />
A formal definiti<strong>on</strong> of density of a multidimensi<strong>on</strong>al data set in each of its points serves as<br />
a basis of DMA-clustering algorithms. This formal definiti<strong>on</strong> allows us to introduce formal<br />
c<strong>on</strong>cepts of c<strong>on</strong>centrati<strong>on</strong>, cluster and track. The paper is devoted to presentati<strong>on</strong> of the<br />
DPS algorithm, DMA-m<strong>on</strong>itoring of the seismic process in California and some other<br />
geophysical applicati<strong>on</strong>s. Prospectives for Romanian and Moldavian territories will be<br />
depicted as well.<br />
18
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
DEVELOPMENT OF EARTHQUAKE-PRONE AREAS<br />
PATTERN RECOGNITION <strong>FROM</strong> 1972 TO 2012<br />
A.D. Gvishiani 1 , A.I. Gorshkov 2 , A. A. Soloviev 2<br />
1 Geophysical Center, Russian Academy of Sciences, Moscow, Russia<br />
2 Institute of Earthquake Predicti<strong>on</strong> Theory and Mathematical Geophysics, Russian Academy of<br />
Sciences, Moscow, Russia<br />
Corresp<strong>on</strong>ding author: gvi@wdcb.ru<br />
Abstract: Accurate definiti<strong>on</strong> of earthquake sources plays a main role in development of<br />
seismic hazard assessment. We present the history of the development and the results of<br />
l<strong>on</strong>g-term implementati<strong>on</strong> of an original methodology dedicated to pattern recogniti<strong>on</strong> of<br />
earthquake pr<strong>on</strong>e areas. The methodology was initiated by the pi<strong>on</strong>eering work by<br />
I.Gelfand, V.Keilis-Borok, E.Rantsman (1972). It was based <strong>on</strong> the hypothesis, derived<br />
from the observati<strong>on</strong>s, that large earthquakes are associated with nodes, specific structures<br />
forming around the intersecti<strong>on</strong>s of the fault z<strong>on</strong>es. The further development and<br />
implementati<strong>on</strong> of the methodology has been carried out in a close internati<strong>on</strong>al<br />
cooperati<strong>on</strong> with well known geologists, seismologists and geophysicists, including<br />
M.Caputo and G.Panza (Italy), L.Knopoff and F.Press (USA), A.Cisternas, H. Philip,<br />
C.Weber (France), M.Garcia-Fernandez (Spain). Since 1972 over 150 papers <strong>on</strong> the<br />
development and testing the methodology in different seismic regi<strong>on</strong>s of the world have<br />
been published in Russian and internati<strong>on</strong>al journals and have been presented at<br />
internati<strong>on</strong>al c<strong>on</strong>ferences. Seismogenic nodes for different target magnitudes have been<br />
recognized in numerous seismic regi<strong>on</strong>s worldwide including most part of the Alpine belt<br />
from Pyrenees to Himalaya, South America Andes, California, Kamchatka, Iberian<br />
Peninsula and some others. 86 earthquakes of target magnitudes occurred in the regi<strong>on</strong>s<br />
studied with this pattern recogniti<strong>on</strong> approach since 1972 up to now. 71 of them took place<br />
within the nodes recognized to be potential sites for str<strong>on</strong>g earthquakes prior to their<br />
occurrence. Note that 22 out of these 71 earthquakes occurred at nodes, where, at the<br />
moment of the recogniti<strong>on</strong>, events of target magnitude have been unknown yet. Six postpublicati<strong>on</strong><br />
earthquakes took place at nodes defined by pattern recogniti<strong>on</strong> as n<strong>on</strong> potential<br />
sites for target magnitudes. Nine earthquakes happened outside the nodes. This 40 years<br />
implementati<strong>on</strong> provided str<strong>on</strong>g evidences in favor of reliability of the methodology. The<br />
results obtained for the mountain regi<strong>on</strong>s encouraged us to extend the methodology to<br />
intraplate regi<strong>on</strong>s of moderate seismicity, specifically, the interiors of the Iberian Peninsula<br />
and some areas within the Russian and West-European platforms. The paper describes the<br />
stages of development of pattern recogniti<strong>on</strong> of earthquake-pr<strong>on</strong>e areas during these 40<br />
years and shows future prospective of the method. Special attenti<strong>on</strong> is paid to earthquakepr<strong>on</strong>e<br />
nodes in Romania and Moldova.<br />
19
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
GEODYNAMICS AND INTERMEDIATE-DEPTH SEISMICITY<br />
IN VRANCEA<br />
Alik Ismail-Zadeh 1, 2, 3 , Liviu Matenco 4 , Mircea Radulian 5 , Sierd Cloetingh 4 ,<br />
6, 7<br />
Giuliano Panza<br />
1 Geophysikalisches Institut, Karlsruher Institut für Technologie, Germany<br />
2 <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> Institute of Earthquake Predicti<strong>on</strong> Theory and Mathematical Geophysics,<br />
Russian Academy of Sciences, Moscow, Russia<br />
3 Institut de Physique du Globe de Paris, Paris, France<br />
4 Faculty of Geosciences, Utrecht University, Utrecht, The Netherlands<br />
5 Nati<strong>on</strong>al Institute for Earth Physics, Ilfov, Romania<br />
6 Dipartimento di Geoscienze, Università di Trieste, Trieste, Italy<br />
7 The Abdus Salam <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> Centre for Theoretical Physics, Trieste, Italy<br />
Corresp<strong>on</strong>ding author: Alik Ismail-Zadeh Alik.Ismail-Zadeh@kit.edu<br />
Abstract: The Vrancea regi<strong>on</strong> of the south-eastern Carpathians is a remarkable site of<br />
intra-c<strong>on</strong>tinental intermediate-depth seismicity. A large set of geological, geophysical, and<br />
geodetic observati<strong>on</strong>s have been accumulated for the last few decades and utilised to<br />
improve our knowledge of the shallow and deep structures beneath Vrancea, the crustal<br />
and mantle dynamics, and the linkage between deep and surface processes in the regi<strong>on</strong>.<br />
We review geology and tect<strong>on</strong>ics of the Vrancea regi<strong>on</strong> including post-collisi<strong>on</strong>al to recent<br />
deformati<strong>on</strong>s, syn- to post-collisi<strong>on</strong>al magmatism, and orogenic exhumati<strong>on</strong> al<strong>on</strong>g the East<br />
and South Carpathians. The regi<strong>on</strong>al seismicity is analysed, and the recent seismic studies<br />
including reflecti<strong>on</strong>, refracti<strong>on</strong>, body and surface wave tomography are reviewed. We<br />
discuss geodetic measurements of horiz<strong>on</strong>tal and vertical movements in the regi<strong>on</strong>,<br />
geoelectric studies, density/gravity and thermal modelling. Qualitative and quantitative<br />
(including retrospective) geodynamic models developed for Vrancea are analysed. The<br />
knowledge of regi<strong>on</strong>al tect<strong>on</strong>ics, geodynamics, seismicity, lithospheric deformati<strong>on</strong>, and<br />
stress regime in the Vrancea earthquake-pr<strong>on</strong>e regi<strong>on</strong> assists in an assessment of str<strong>on</strong>g<br />
ground moti<strong>on</strong>, seismic hazard and risk. The earthquake simulati<strong>on</strong>, seismic hazard, and<br />
earthquake forecasting models have also been reviewed providing a link between deep<br />
geodynamic processes and their manifestati<strong>on</strong> <strong>on</strong> the surface. Finally we discuss<br />
unresolved problems in Vrancea in order to improve our understanding of the regi<strong>on</strong>al<br />
evoluti<strong>on</strong>, present tect<strong>on</strong>ics, mantle dynamics, intermediate-depth seismicity, and surface<br />
manifestati<strong>on</strong>s of the lithosphere dynamics and to enhance our ability to forecast str<strong>on</strong>g<br />
earthquakes in the Vrancea regi<strong>on</strong>.<br />
20
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
QUESTIONS ABOUT THE GLOBAL WARMING<br />
Jean-Louis Le Mouël<br />
Institut de Physique du Globe de Paris, Membre de l'Académie des Sciences<br />
Corresp<strong>on</strong>ding author: Jean-Louis Le Mouël, E-mail address lemouel@ipgp.fr<br />
Abstract: One first gives a brief presentati<strong>on</strong> of the greenhouse effect, as it is generally<br />
understood, and of the c<strong>on</strong>centrati<strong>on</strong> evoluti<strong>on</strong> of <strong>on</strong>e of the greenhouse effect gases<br />
present in the atmosphere, the carb<strong>on</strong> dioxide, CO2. The increase of this c<strong>on</strong>centrati<strong>on</strong> is<br />
due, for an essential part, to the burning of oil, natural gas and coal; it is said<br />
anthropogenic. Is the increase, since 1850, of the global temperature of the lower<br />
atmosphere layers, widely accepted, due to this increase of the CO2 increase? That is<br />
currently the dominant view, harshly defended by the Intergovernmental Panel <strong>on</strong> Climate<br />
Change (IPCC). But this is <strong>on</strong>ly a hypothesis. The climate indeed, varies, and has varied at<br />
all time scales, from day to hundreds of milli<strong>on</strong> years. The two relevant questi<strong>on</strong>s are the<br />
following: i) Is the temperature elevati<strong>on</strong> observed during the 20 th century excepti<strong>on</strong>al? ii)<br />
Does it require anthropogenic causes? The two observati<strong>on</strong>s <strong>on</strong> which the thesis of the<br />
anthropogenic global warming relies up<strong>on</strong> are: a more rapid increase of the mean<br />
temperature during the last half or third part of the 20 th century, and temperatures reaching<br />
higher values over the 20 th century than during the two milenia before. N<strong>on</strong>e of them <strong>–</strong> the<br />
sec<strong>on</strong>d “observati<strong>on</strong>” being hampered by poor data <strong>–</strong> can be c<strong>on</strong>sidered as proving human<br />
global warming. The argument in favor of this thesis relays <strong>on</strong> predicti<strong>on</strong>s obtained from<br />
numerical models. Up to which point can we trust them? The effect of the Sun activity <strong>on</strong><br />
climate variati<strong>on</strong>s is claimed to be fairly small. This is not sure at all, the Sun activity<br />
signature being found in a number of climatological parameters. This aspect is also<br />
underlined during the presentati<strong>on</strong>. Finally, some aspects of a possible impact of global<br />
changes <strong>on</strong> local scales are c<strong>on</strong>sidered.<br />
Key words: climate changes, greenhouse gases, temperature evoluti<strong>on</strong>, Sun activity.<br />
21
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
GEOMAGNETIC STORMS ─ BETWEEN BEAUTY AND RISK<br />
Mioara Mandea<br />
Centre Nati<strong>on</strong>al d'Etudes Spatiales, Directorate for Strategy and Programmes<br />
Corresp<strong>on</strong>ding author: Mioara Mandea, E-mail address mioara.mandea@cnes.fr<br />
Abstract: The main part of the geomagnetic field is generated by a c<strong>on</strong>vective moti<strong>on</strong> in the<br />
Earth’s ir<strong>on</strong>-rich, electrically c<strong>on</strong>ducting, fluid outer core by a process known as the<br />
geodynamo. This mechanism generates a magnetic field known as the core field or main field,<br />
characterized by a temporal variati<strong>on</strong> over time-scales from years to millennia, named secular<br />
variati<strong>on</strong>. The field produced in the core is more than 90% of the field measured at the Earth's<br />
surface. Another internal c<strong>on</strong>tributi<strong>on</strong> is the lithospheric (crustal) magnetic field, with its origin<br />
in the remanent and induced magnetizati<strong>on</strong> parts of the crust and upper mantle, which is not<br />
<strong>on</strong>ly weaker, but also of much smaller spatial scale, when compared to the large scale core<br />
field. The geomagnetic external fields mainly stem from the interacti<strong>on</strong> with the solar wind,<br />
due to the Sun activity. The effect is to compress the main magnetic field lines <strong>on</strong> the sunward<br />
side and stretches them into a l<strong>on</strong>g tail <strong>on</strong> the night side. Generally, solar wind particles do not<br />
cross magnetic field lines and are thus primarily deflected around our planet. They may,<br />
however, enter the magnetosphere when interplanetary and geomagnetic fields merge during<br />
times of increased solar activity, or close to poles where the field-lines are nearly vertical.<br />
Their interacti<strong>on</strong> with the atmosphere then causes the well-known aurora, amazing the viewer<br />
with the beauty of luminosity. The magnetic variati<strong>on</strong>s associated with these phenomena are<br />
known as geomagnetic storms and during their main phase the electric current in the<br />
magnetosphere create a magnetic force which pushes out the boundary between the<br />
magnetosphere and the solar wind. The frequency of geomagnetic storms increases and<br />
decreases with the sunspot cycle, some 11 years. There are several space-weather issues which<br />
tend to be associated with large geomagnetic storms which cause radio and radar scintillati<strong>on</strong>,<br />
disrupti<strong>on</strong> of navigati<strong>on</strong> and spacecraft operati<strong>on</strong>s, and even aurora displays at much lower<br />
latitudes than normal. More interestingly, time-varying geomagnetic external fields induce<br />
electric currents in the c<strong>on</strong>ducting ground. These currents create a sec<strong>on</strong>dary magnetic field,<br />
and an electric field at the Earth’s surface is induced, associated with time variati<strong>on</strong>s of the<br />
magnetic field. The surface electric field causes electrical currents, known as geomagnetically<br />
induced currents (GIC), flowing in any c<strong>on</strong>ducting structure, for example, power or pipeline<br />
grids. Since the largest magnetic field variati<strong>on</strong>s are observed at higher magnetic latitudes, GIC<br />
have been regularly measured in some Northern countries power grids and pipelines since<br />
some decades. However, GIC have also been recorded at mid-latitudes during major storms,<br />
and there may even be a risk to low-latitude areas, especially during a storm commencing<br />
suddenly because of the high, short-period rate of change of the field that occurs <strong>on</strong> the dayside<br />
of the Earth. The GIC hazard to pipelines is that these currents cause swings in the pipe-to-soil<br />
potential, increasing the rate of corrosi<strong>on</strong> during major geomagnetic storms. In these<br />
circumstances, the GIC risks are not of a catastrophic failure, but a reduced service life of the<br />
pipeline grids. C<strong>on</strong>siderati<strong>on</strong>s <strong>on</strong> the globally and regi<strong>on</strong>ally geomagnetic field variati<strong>on</strong>s, with<br />
some particular space-weather effects (aurora borealis and risks) are given. A special attenti<strong>on</strong><br />
is paid to a few risks <strong>on</strong> power grids and pipelines due to geomagnetically induced currents,<br />
and how this situati<strong>on</strong> can be c<strong>on</strong>sidering <strong>on</strong> a regi<strong>on</strong>al scale.<br />
22
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
PROMOTING CARBON CAPTURE AND GEOLOGICAL<br />
STORAGE (CCS) IN ROMANIA<br />
C<strong>on</strong>stantin Stefan Sava 1, 3 , Carmencita C<strong>on</strong>stantin 2 , Amuliu Proca 3 ,<br />
Claudia Tomescu 2 , Alexandra Dudu 1 , Sorin Anghel 1<br />
1 Nati<strong>on</strong>al Institute for Marine Geology and Geoecology - GeoEcoMar,<br />
2 Institute for Studies and Power Engineering - ISPE, 3 - Romanian”CO2 Club” Associati<strong>on</strong> - CO 2 Club<br />
Corresp<strong>on</strong>ding author: savac@geoecomar.ro<br />
Abstract: It is now almost unanimously accepted in the internati<strong>on</strong>al scientific community that<br />
the Earth’s climate changes have anthropogenic causes, first of them being the greenhouse gas<br />
(GHG) emissi<strong>on</strong>s am<strong>on</strong>g which the carb<strong>on</strong> dioxide occupies the main place. Worldwide efforts<br />
are made to reduce such emissi<strong>on</strong>s. The industrial efforts c<strong>on</strong>centrate <strong>on</strong> improving the<br />
efficiency and capturing the emitted CO2. One, probably the <strong>on</strong>ly feasible soluti<strong>on</strong> of disposing<br />
of the captured CO2 is its safe storage for l<strong>on</strong>g periods of time if not forever, the best being the<br />
geological storage. Informati<strong>on</strong> <strong>on</strong> 244 CO2 emissi<strong>on</strong> sources in Romania, totalizing 74,4 Mt<br />
was analyzed. Out of those, 64 sources with the CO2 emissi<strong>on</strong>s exceeding 0,1 Mt per year was<br />
identified. Informati<strong>on</strong> for those sources was loaded in the database. After having analyzed the<br />
whole sedimentary successi<strong>on</strong>, several prospective geological sinks have been identified within<br />
Romanian territory. Some prospective saline aquifer formati<strong>on</strong>s were defined for further<br />
analysis. Relevant data were collected to characterize those formati<strong>on</strong>s. Also, the oil and gas<br />
fields of Romania were inventoried. As almost everywhere in the world the saline aquifers are<br />
poorly known. The Romanian sedimentary basins potentially c<strong>on</strong>taining saline aquifer<br />
formati<strong>on</strong>s have been combined in 4 big z<strong>on</strong>es (Moesian platform and South Carpatians<br />
foredeep, Moldavian platform and East Carpathians foredeep, Transilvanian basin and<br />
Pann<strong>on</strong>ian basin). Out of their total surface areas, the surface with sedimentary cover, thinner<br />
than 800 m, have been eliminated from calculati<strong>on</strong>s as such areas are not suitable for CO2<br />
storage. In December 15, 2011 the European Commissi<strong>on</strong> has adopted the “Energy Roadmap -<br />
2050”. The European Commissi<strong>on</strong> has committed to assure more than 80% GHG reducti<strong>on</strong><br />
until 2050, in comparis<strong>on</strong> with the year 1990. This challenging target puts a high pressure <strong>on</strong><br />
the energy sector, as it is the main GHG producer. In order EU to assure in 2050 a secure,<br />
competitive and decarb<strong>on</strong>ized energy system, there have been established ten structural<br />
changes for the energy system transformati<strong>on</strong> including mainly significant growth of the<br />
energy efficiency, substantial rise of the RES (Renewable Energy Sources) share, nuclear<br />
energy important c<strong>on</strong>tributi<strong>on</strong> and the accelerati<strong>on</strong> of the CO2 Capture and Storage technology<br />
deployment. For Romania, implementing CCS technology is <strong>on</strong>e of the most important<br />
structural changes, which together with significant energy savings and RES use will lead us to<br />
fulfil our assumed obligati<strong>on</strong>s as member state. At nati<strong>on</strong>al level, the electricity producti<strong>on</strong><br />
from fossil power plants will be maintained at a relatively c<strong>on</strong>stant value of 27,6 mil toe to 21,5<br />
mil toe for the period 2011-2030. The future implementati<strong>on</strong> of the CCS technologies in<br />
Romania, as a priority for the energy sector, will c<strong>on</strong>tribute to: maintain operati<strong>on</strong>al the<br />
existing fossil power plants, including related mining exploitati<strong>on</strong>s sites, life extensi<strong>on</strong> for the<br />
oil and gas reserves exploitati<strong>on</strong> capacities, increase the geopolitical security through the<br />
nati<strong>on</strong>al resources c<strong>on</strong>sumpti<strong>on</strong> of oil and natural gas versus import dependence, develop new<br />
power plants running <strong>on</strong> (nati<strong>on</strong>al) coal, maintain the existing jobs in the energy industry based<br />
<strong>on</strong> fossil fuels and create new <strong>on</strong>es (all al<strong>on</strong>g the project stages), integrate Romania within the<br />
European CO2 transport infrastructure, meet the nati<strong>on</strong>al CO2 emissi<strong>on</strong>s mitigati<strong>on</strong> targets.<br />
23
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
SEISMOGENIC ZONES AND SEISMIC HAZARD AT LOCAL<br />
AND REGIONAL SCALES IN MOLDAVIA<br />
Mircea Radulian, Neculai Mandrescu<br />
Nati<strong>on</strong>al Institute for Earth Physics, Magurele, Ilfov, Department of Seismology<br />
Corresp<strong>on</strong>ding author: Mircea Radulian, mircea@infp.ro<br />
Abstract: The paper is presenting an overall characterizati<strong>on</strong> of the seismotect<strong>on</strong>ics and<br />
seismicity in the Moldavia regi<strong>on</strong> as fundamentals to define the seismogenic z<strong>on</strong>es and the<br />
associated seismic hazard for this regi<strong>on</strong>. The hazard level is clearly c<strong>on</strong>trolled by the<br />
earthquake activity in the Vrancea regi<strong>on</strong>. Some effects recorded at the southern boundary<br />
of the Moldavian Platform (Galati <strong>–</strong> Braila) are induced by the shallow seismicity located<br />
al<strong>on</strong>g the system of NW-SE oriented faults (Peceneaga-Camena, Sfantu Gheorghe,<br />
Trotus), crossing the northern Dobrogea and terminating in the Barlad Depressi<strong>on</strong>. The<br />
distributi<strong>on</strong> of the seismic hazard due to the Vrancea earthquakes is analyzed in c<strong>on</strong>necti<strong>on</strong><br />
with the revised macroseismic data and instrumentally recorded accelerograms. The effects<br />
of the focal depth, source directivity and seismic wave attenuati<strong>on</strong> and their impact <strong>on</strong><br />
hazard level are investigated. The amplificati<strong>on</strong> of the ground moti<strong>on</strong> due to the shallow<br />
geological layers and res<strong>on</strong>ance frequency in the Bacau area and surroundings are<br />
estimated <strong>on</strong> the basis of borehole data. Implicati<strong>on</strong>s <strong>on</strong> management strategy to mitigate<br />
earthquake risk are finally discussed.<br />
Key words: seismogenic z<strong>on</strong>e, Vrancea earthquake, seismic hazard, microz<strong>on</strong>ati<strong>on</strong>, Moldavia,<br />
Bacau<br />
24
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
CLUSTER ANALYSIS TO SELECT THE SEISMIC ZONES OF<br />
ROMANIA<br />
Burtiev Rashid<br />
Institute of Geology and Seismology of Academy of Science of Moldova<br />
Corresp<strong>on</strong>ding author: Burtiev Rashid, burtiev_rashid@mail.ru<br />
Abstract: Cluster Analysis is a collecti<strong>on</strong> of objects similar to <strong>on</strong>e another within the same<br />
cluster and dissimilar to the objects in other clusters. The epicenters are tendency for<br />
clustering. Therefore was d<strong>on</strong>e the attempt use cluster analysis forr establishing seismic<br />
z<strong>on</strong>ing of Romania. Applied n<strong>on</strong>-hierarchical k means and agglomerative hierarchical<br />
clustering algorithms. Determining the optimal number of clusters was carried out<br />
according to the minimum of the total variance, the average silhouette width, the maximum<br />
of Calinski-Harabasz; Krzanowski-Lai Index, and the method of Elbow. Methods to<br />
optimize the quality of clustering soluti<strong>on</strong> identified in 4 clusters. Calculated by the<br />
method of silhouettes and the values of Akaike and Bayesian informati<strong>on</strong> criteri<strong>on</strong> optimal<br />
number of clusters is 3. But the dominant decisi<strong>on</strong> be cluster 4. C<strong>on</strong>sequently, in Romania<br />
there are defined 4 seismic regi<strong>on</strong>s.<br />
Cluster analysis identified 34 seismic z<strong>on</strong>es in Italy. The cluster decisi<strong>on</strong> 34 was estimated<br />
the “Two step”.<br />
Key words: Seismic regi<strong>on</strong>s; cluster analysis; informati<strong>on</strong> criteri<strong>on</strong>.<br />
25
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
STATISTICAL ANALYSIS OF TIME SERIES OF WIND SPEAD<br />
AND TEMPERATURE<br />
Burtiev Rashid, Ghenadie Spatari<br />
Institute of Geology and Seismology of Academy of Science of Moldova<br />
Corresp<strong>on</strong>ding author: Burtiev Rashid, burtiev_rashid@mail.ru<br />
Abstract: The time series of air temperature and wind speed are analyzed. Trend and<br />
periodical comp<strong>on</strong>ents are defined for both time series with no significant statistical<br />
relati<strong>on</strong>ship between series. The spectral analysis of temperature series without trend<br />
shows the peak <strong>on</strong> frequency fc=1/12 that corresp<strong>on</strong>ds to seas<strong>on</strong>al periodical comp<strong>on</strong>ent.<br />
The graph of spectral density functi<strong>on</strong> of wind speed time series doesn’t manifest this type<br />
of relati<strong>on</strong>ship. Future behavior forecasting is carried out <strong>on</strong> exp<strong>on</strong>ential smoothing with<br />
moving average window approach and ARIMA model for both time series. Predicti<strong>on</strong> until<br />
2012 is computed using the proposed approach that is based <strong>on</strong> multiplicative winters and<br />
ARIMA models. The patterns could be used in the soluti<strong>on</strong> of the general water balance<br />
equati<strong>on</strong> for a comprehensive assessment of water resources in the regi<strong>on</strong>.<br />
Key words: Time series of wind speed and temperature; autocorrelati<strong>on</strong> functi<strong>on</strong>; spectral analysis;<br />
ARIMA models.<br />
26
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
IMPROVING MANAGEMENT AND EVALUATION OF <strong>RISKS</strong><br />
AND NATURAL DISASTERS BY REGIONAL GIS<br />
DISTRIBUTED APPLICATION<br />
Iulian Furdu, Cosmin Tomozei, Ioana Pandele<br />
“Vasile Alecsandri” University of Bacau, Department of Mathematics, Computer Science and<br />
Educati<strong>on</strong>al Sciences<br />
Corresp<strong>on</strong>ding author: Ioana Pandele, ioana.pandele@ub.ro<br />
Abstract: The aim of this paper is to provide a framework for the improvement of the<br />
processes of management and evaluati<strong>on</strong> of risks in Central East Moldavian Regi<strong>on</strong>,<br />
regarding the natural disasters occurrence, such as floods, earthquakes, forest fires and<br />
landslides. C<strong>on</strong>sequently, a GIS Applicati<strong>on</strong> will be developed, in order to graphically<br />
reflect and analyze these risks. A Geographic Informati<strong>on</strong> System (GIS) is mapping<br />
software which provides spatial data analysis by linking locati<strong>on</strong>s with informati<strong>on</strong> about<br />
them. The main objective of Risk-GIS is the support of decisi<strong>on</strong> making and problem<br />
solving in areas related to community safety and sustainability. Thus, it represents the<br />
analytical engine that manages the process of evaluati<strong>on</strong> of the risks of natural hazards. A<br />
crucial feature in the selecti<strong>on</strong> of a GIS is the identificati<strong>on</strong> of a minimum set of required<br />
capabilities. The most important <strong>on</strong>es include: data retrieval, data capture, data storage,<br />
data management, data analysis, and data display. Recent GIS applicati<strong>on</strong>s for risk<br />
management at U.S. Envir<strong>on</strong>mental Protecti<strong>on</strong> Agency include ORD/ESD, ATtILA, ReVA<br />
etc. Similar products or projects are LATIS for flood risk management in Flanders,<br />
Belgium, AGSO- Natural hazards and risk they pose to South East Queensland<br />
(Geoscience Australia in c<strong>on</strong>juncti<strong>on</strong> with the Bureau of Meteorology)<br />
http://www.agso.gov.au/urban/factsheets/risk_modelling.jsp), FEMID- Project for<br />
strengthening of structures in case of disasters etc. Although the Central East regi<strong>on</strong> of<br />
Moldavia is well known as a source of potential high risks of natural disasters, the<br />
development of software which models such events is still at an early stage. The main<br />
objective is to bring into light the capabilities of our ArcGIS and .NET based software<br />
framework, which has a higher level of usability, so as to be accessed by n<strong>on</strong>-expert users.<br />
Hazard maps have been created in order to indicate landslide hazard, flood hazard or fire<br />
hazard. Software utility and functi<strong>on</strong>ality is extended by using alarms in a distributed<br />
envir<strong>on</strong>ment, by computing the shortest terrestrial path etc. It would be important to have<br />
the support and c<strong>on</strong>tributi<strong>on</strong> of the local authorities, which would increase the level of<br />
efficiency and update our geospatial databases. The development of GIS applicati<strong>on</strong>s<br />
proved to become more and more complex, due to the heterogeneous users’ requirements.<br />
The target group c<strong>on</strong>sists of local authorities, e.g. City Council, Prefecture, and<br />
Inspectorate for Emergency Situati<strong>on</strong>s <strong>–</strong> able to take acti<strong>on</strong>, to inform, to react and solve<br />
these specific situati<strong>on</strong>s. The software may be c<strong>on</strong>sidered as a starting point for a regi<strong>on</strong>al<br />
integrated system, distributed am<strong>on</strong>g the branches of the authorized state instituti<strong>on</strong>s.<br />
27
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
VRANCEA ZONE IN THE FRAME OF GLOBAL SEISMICITY<br />
Ilie Sandu<br />
Institute of Geology and Seismology, Acasemy of Science of Moldova<br />
Corresp<strong>on</strong>ding author: Ilie Sandu, ilie_sandu@yahoo.com<br />
Abstract: Regi<strong>on</strong>al investigati<strong>on</strong> of Vrancea area seismicity, as well as quantitative<br />
estimates of intake in the global seismicity has been d<strong>on</strong>e in the frame of <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g><br />
Seismic Catalogue (ISC) report’s database. The global seismicity has been filtered<br />
according: magnitude (M≥4.5), depth (1000≥H≥0km), time (1965-2008), and regi<strong>on</strong>al<br />
events specify the area framed by coordinate limits of: 48º≥λ≥44º and 29º≥φ≥24º further.<br />
Using recurrence relati<strong>on</strong>s of different scales: M (magnitude), M0 (seismic moment), E<br />
(energy), the coefficients of seismic frecvency-power distributi<strong>on</strong>s were obtained<br />
statistically (at global and regi<strong>on</strong>al scale). The regi<strong>on</strong>al to global seismic activity rate<br />
KR/G=1:1500 (from global: EG≈1.7×10 19 J, during 44 years range, or PG=13±4GW), <strong>on</strong>e of<br />
the high density tect<strong>on</strong>ic power release of the Globe.<br />
Key words: Vrancea seismicity, global statistics, power.<br />
28
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
WATER INDUCED GEOHAZARDS MEASURED WITH<br />
SPACEBORNE INTERFEROMETRY TECHNIQUES<br />
F. Serban 1 , M. Radu 2 , D. Teleaga 1 , M. Sorin 3<br />
1 Advanced Studies and Research Center, Bucharest<br />
2 CONVERSMIN, Bucharest<br />
3 INCDMRR, Bucharest<br />
Corresp<strong>on</strong>ding author: F. Serban, florin.serban@asrc.ro<br />
Abstract: Spaceborne interferometry techniques combined with ground data permit<br />
estimati<strong>on</strong> of the rocks mechanical properties and the development of models and<br />
scenarios to predict disaster events such as cave-ins, landslides or soil liquefacti<strong>on</strong> in the<br />
case of an earthquake. The DInSAR (Differential Interferometric Synthetic Aperture<br />
Radar), Interferograms Stacking and PSI (Persistent Scatterers Interferometry) techniques<br />
have been applied to retrieve the displacement informati<strong>on</strong> as accurate as possible <strong>on</strong> three<br />
sites in Romania, which suffer of ground instability caused by the water comp<strong>on</strong>ent. The<br />
first site is composed of 4 tailing retenti<strong>on</strong> p<strong>on</strong>ds at different stages of their life located in<br />
Bucovina. The tailing p<strong>on</strong>ds are hydrotechnical structures of permeable type designed for<br />
the safe deposit of mining detritus byproducts and disposal of the water c<strong>on</strong>tained in these<br />
byproducts. Since 1998 some 550 mines have been closed and introduced in a c<strong>on</strong>servati<strong>on</strong><br />
process all over the country. In order to prevent ecological and human damages, all these<br />
mines and storage p<strong>on</strong>ds for mining tailings are required to be under c<strong>on</strong>tinuous<br />
m<strong>on</strong>itoring. Using 15 high-resoluti<strong>on</strong> Spotlight TerraSAR-X images, the stability of the<br />
storage p<strong>on</strong>d was m<strong>on</strong>itored over a five-m<strong>on</strong>th period during 2011. Interferometric<br />
stacking and PSI were applied in order to generate deformati<strong>on</strong> maps and deformati<strong>on</strong><br />
profiles. At the same time, GPS measurements and Electrical Tomography for water<br />
c<strong>on</strong>tent were used as independent measurements. The sec<strong>on</strong>d site is Ocnele Mari brine<br />
extracti<strong>on</strong> area. The extracti<strong>on</strong> of salt through dissoluti<strong>on</strong> led to slow ground subsidence<br />
but the flooding and dissoluti<strong>on</strong> of the Roman caves led to catastrophic cave-ins and the<br />
relocati<strong>on</strong> of an entire village. The ground deformati<strong>on</strong> is presently measured with leveling<br />
instrumentati<strong>on</strong> and steps are being made to adopt the interferometric results for a better<br />
spatial and temporal coverage that should refine the existing measurement model. The<br />
third site is the City of Bucharest. Using ERS data collected over 7 years, ground<br />
instability was detected <strong>on</strong> a large area that represents the historical watershed of the<br />
Dambovita river. A network of water wells shows that the ground instability is directly<br />
proporti<strong>on</strong>al to the groundwater depth. The sites that were analyzed and presented reveal<br />
important informati<strong>on</strong> which can also benefit some other risk areas in Moldova, such as<br />
mining sites (Targu Ocna, Cacica) and urban areas.<br />
Key words: spaceborne interferometry, DInSAR, PSI, ground instability.<br />
29
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
SEISMIC HAZARD WITHIN SE CARPATHIANS AND<br />
RELATED FORELAND IN THE GEODYNAMIC CONTEXT OF<br />
THE BLACK SEA OPENING<br />
Lucian Besutiu<br />
Institute of Geodynamics of the Romanian Academy, Solid Earth Dynamics Department<br />
Corresp<strong>on</strong>ding author: Lucian Besutiu, besutiu@geodin.ro<br />
Abstract: The paper mainly deals with two major aspects revealed by the seismicity map<br />
of Romania: the unusual crat<strong>on</strong> seismicity of the E Moesian Platform and the strange<br />
intermediate-depth earthquakes within full c<strong>on</strong>tinental envir<strong>on</strong>ment in the bending<br />
z<strong>on</strong>e of East Carpathians (EC). Both aspects are c<strong>on</strong>sidered to be closely related to the<br />
geodynamic evoluti<strong>on</strong> of the Black Sea inland following the opening of the west sea basin.<br />
Unlike some previous models claiming for the Black Sea opening as a c<strong>on</strong>sequence of an<br />
unique geodynamic event (the extensi<strong>on</strong>al envir<strong>on</strong>ment created behind P<strong>on</strong>tide by<br />
northward subducti<strong>on</strong> of the Neotethys Ocean floor), geophysical evidence advocate for a<br />
distinct opening of the west and east basins. Residual geomagnetic and gravity anomalies<br />
reveal a NE striking rift in the west basin and a NW-SE <strong>on</strong>e in the E Black Sea. Besides,<br />
off-shore seismics show a slight overthrust of E P<strong>on</strong>tide over W P<strong>on</strong>tide advocating for an<br />
earlier opening of W Black Sea. The opening of the west sea basin had important<br />
c<strong>on</strong>sequences <strong>on</strong> the NW inland of the Black Sea. Lithosphere expelled by rifting split the<br />
Moesian Plate (MoP) into several compartments by creating or reactivating major NW<br />
trending faults, well known <strong>on</strong> the territory of Romania, SE Ukraine and Bulgaria (e.g.<br />
Odessa Fault (OdF), Sfântu Gheorghe (Izmail) Fault (SGF), Peceneaga-Camena Fault,<br />
Ostrov-Sinoe Fault (OSF), Capidava-Ovidiu Fault (COF), Intra-Moesian Fault (IMF),<br />
Varna-Giurgiu Fault (VGF). This also explains the occurence of the Dobrogean sector of<br />
the Moesian Platform. Fingerprints of phenomen<strong>on</strong> are revealed in the seismic tomography<br />
images showing the large (lithospheric) in-depth extent of some faults (e.g. PCF, COF,<br />
IMF, VGF). After the Black Sea rifting ended its evoluti<strong>on</strong>, the above menti<strong>on</strong>ed<br />
lithospheric compartments are still pushed towards the Carpathians by northward<br />
displacement of Arabian Plate (due to the Red Sea and Aden Bay rifts). Part of the Arabian<br />
Plate movement is transmitted (through the numerous micro-plates located at the c<strong>on</strong>tact<br />
between the major African Plate and Eurasian Plate) towards the Black Sea and further <strong>on</strong>,<br />
towards the EC bending z<strong>on</strong>e. Therefore, the above menti<strong>on</strong>ed MoP compartments are<br />
pushed towards EC staying together by fricti<strong>on</strong>. However, from time to time, when<br />
tect<strong>on</strong>ic forces overpass the fricti<strong>on</strong>, they may relatively slip each other and crust<br />
earthquakes may occur in their upper, brittle part. Geophysical evidence show three major<br />
lithospheric compartments joining the Vrancea intermediate-depth seismic z<strong>on</strong>e: 130 km<br />
thick MoP, 90 km thick Intra-Alpine micro-plate (IaP) and more than 150 km thick East<br />
European Plate (EEP).The Black Sea opening provided the necessary speed excess to<br />
MoP, thus creating the unstable envir<strong>on</strong>ment for the Vrancea FFT triple juncti<strong>on</strong> (VTJ).<br />
C<strong>on</strong>sequently, the VTJ central compartment has been pushed down into the hotter upper<br />
mantle into a thermo-baric disequilibrium to which intermediate-depth seismicity may be<br />
associated. Am<strong>on</strong>g major phenomena that might generate seismic energy in the upper<br />
30
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
mantle menti<strong>on</strong> should be made to (i) thermal stress and (ii) phase transform processes<br />
(with mineral compacti<strong>on</strong> & fluids release). In depth distributi<strong>on</strong> of earthquakes frequency<br />
(with maxima located at 90 km, 130 km and 150 km) is in full agreement with the<br />
postulated mechanism, as l<strong>on</strong>g as the above menti<strong>on</strong>ed depths corresp<strong>on</strong>d with the locati<strong>on</strong><br />
of the lithosphere-asthenosphere boundary (a well known thermal disc<strong>on</strong>tinuity) in the<br />
three tect<strong>on</strong>ic plates surrounding the area. Numerical modelling revealed the maximum<br />
thermal stress locates at the depth of the most seismic activity. It is worth menti<strong>on</strong>ing that<br />
the presence of an oceanic slab relict (as remnant of a paleo-subducti<strong>on</strong> process) may not<br />
qualify for such earthquakes genesis because phase-transform processes mainly rely <strong>on</strong> the<br />
presence of a large amount of quartz in the seismic body (which is not the case of oceanic<br />
lithosphere). The permanent Vrancea seismicity and large amount of energy released might<br />
be explained through the active sinking of the central VTJ into the upper mantle due to (i)<br />
tect<strong>on</strong>ic forces acting <strong>on</strong> the surrounding plates and (ii) eclogitizati<strong>on</strong> of the lower part of<br />
the crust. The last menti<strong>on</strong>ed aspect seems to be also resp<strong>on</strong>sible for the occurrence of<br />
crustal earthquakes with vertical fault mechanism within VTJ area.<br />
Key words: Black Sea opening, active faults, earthquakes, unstable triple juncti<strong>on</strong>, thermal stress,<br />
phase transforms.<br />
31
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
WHY IT IS SO HARD TO ASSESS LANDSLIDES’ HAZARD<br />
AND RISK IN ROMANIA?<br />
Raluca-Mihaela Maftei, C<strong>on</strong>stantina Filipciuc<br />
Geological Institute of Romania<br />
Corresp<strong>on</strong>ding author: Raluca-Mihaela Maftei, mafteir@yahoo.com<br />
Abstract: The idea of presenting this paper appeared after reading the article of C.J. van<br />
Westen et al., from 2005, c<strong>on</strong>cerning the difficulties encountered in assessing hazard and<br />
risk to landslide. As Romania is located in Europe as <strong>on</strong>e of first places, unfortunately,<br />
regarding the effect of these phenomena, we c<strong>on</strong>sidered appropriate to deal with the<br />
subject. According to van Westen, even though in recent years the literature has shown a<br />
development in hazard and risk estimati<strong>on</strong> with geotechnics, by in situ investigati<strong>on</strong>s,<br />
development of hazard maps and risk assessment to landslides, procedures absolutely<br />
necessary for regulatory and development planning by authorities, this acti<strong>on</strong>s still remain<br />
a far end goal, especially to medium scale (1:10.000- 1:50.000). In this article we try to<br />
illustrate the difficulties encountered in our attempt to develop landslide hazard maps at a<br />
regi<strong>on</strong>al scale. Thus, we present the difficulties arising in the inventory of this kind of<br />
phenomena, including informati<strong>on</strong> <strong>on</strong> the occurrence, type and volume of landslides,<br />
establishment of spatial and temporal probability of release, vulnerability assessment etc.<br />
In light of the above, we illustrate the hazard maps developed by our team, presenting<br />
hence the problems we faced. The major issues to be solved did not regard legislati<strong>on</strong>,<br />
which is by far thick, but access to the necessary informati<strong>on</strong> to elaborate maps, according<br />
to the Methodological Norms in Force, uncertainty about quality and accuracy of these<br />
informati<strong>on</strong> and the list may go <strong>on</strong>.<br />
Key words: landslide hazard, vulnerability, spatial and temporal probability.<br />
32
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
PLIO-PLEISTOCENE CONNECTION BETWEEN THE<br />
‘VRANCEA ZONE’ AND THE SOUTHERN END OF THE<br />
HARGHITA VOLCANIC CHAIN<br />
Seghedi Ioan 1 1, 2<br />
, Szakács Alexandru<br />
1 Institute of Geodynamics, Romanian Academy, Bucharest, Romania<br />
2 Sapientia University, Dept. of Envir<strong>on</strong>mental Sciences, Cluj-Napoca, Romania<br />
Seghedi Ioan, seghedi@geodin.ro<br />
Abstract: Miocene c<strong>on</strong>vergence at ~ 11 Ma of the Eastern Carpathian orogen of Romania<br />
caused the tect<strong>on</strong>ic nappes emplacement of the fold - thrust belt. The following postcollis<strong>on</strong>al<br />
complex tect<strong>on</strong>ic crustal deformati<strong>on</strong> in this area resulted in Late Miocene to<br />
Quaternary formati<strong>on</strong> of the Cǎlimani-Gurghiu-Harghita volcanic chain. This was possibly<br />
related to clockwise rotati<strong>on</strong> and fr<strong>on</strong>t block-fragmentati<strong>on</strong> of the inner Carpathian (Dacia)<br />
crustal block. The Carpathian foreland is characterized by a mechanically str<strong>on</strong>g and cold<br />
European-Scythian Plate welded to the south with weak Moesian plate al<strong>on</strong>g the Trotuş<br />
transverse high angle basement fault system that was reactivated and decoupled from it<br />
during Late Pliocene-Quaternary. This period was characterized by differential vertical<br />
movements of the Moesian plate associated with ~5km of c<strong>on</strong>tracti<strong>on</strong> restricted roughly<br />
between the Trotuş and Intramoesian faults and sustained by the apparently folded, shallow<br />
Moho beneath the orogen and the generati<strong>on</strong> of ‘Vrancea z<strong>on</strong>e’. In the same period after a<br />
time gap Plio-Quaternary magmatic activity in the interior of the Carpathians area, in close<br />
proximity to the ‘Vrancea z<strong>on</strong>e’, shows a shift from normal calc-alkaline to a diverse<br />
compositi<strong>on</strong>s (adakite-like calc-alkaline, K-alkalic, in South Harghita Mountains and mafic<br />
Na-alkalic in Perşani Mountains). This magmatism is interpreted to be in close c<strong>on</strong>necti<strong>on</strong><br />
to steepening of ‘Vrancea z<strong>on</strong>e’ via tearing or delaminati<strong>on</strong> of its eclogitic keel and partial<br />
melting of this material at mantle depths to explain the peculiar chemistry of adakite-like<br />
volcanic rocks as a c<strong>on</strong>sequence of elevated K2O/Na2O in the protolith and high pressure<br />
c<strong>on</strong>diti<strong>on</strong>s of partial melting. The surface projecti<strong>on</strong> of the South Harghita adakite-like<br />
calc-alkaline volcanism at the edge of ‘Vrancea z<strong>on</strong>e’, as a piece of metasomatised<br />
lithosphere can be explained by its heating and partial melting during the horiz<strong>on</strong>tal<br />
asthenospheric flow around the steepening z<strong>on</strong>e. The Na-alkalic mafic magmas were<br />
derived from such an uprised asthenospheric mantle-source by decompressi<strong>on</strong> melting that<br />
correlates with a low-velocity anomaly and with a high attenuati<strong>on</strong> volume, as indicated by<br />
the geophysical observati<strong>on</strong>s. Generati<strong>on</strong> of K and Na alkalic magmas in the similar time<br />
interval, by interrupting the adakite-like volcanism signifies changes in the source and<br />
melting mechanism by renewed c<strong>on</strong>tracti<strong>on</strong> associated with deep mantle processes<br />
facilitated by the generalized tect<strong>on</strong>ic inversi<strong>on</strong> event which started during the latest<br />
Pliocene in the whole Carpathian<strong>–</strong>Pann<strong>on</strong>ian regi<strong>on</strong>.<br />
Key words: Post-collisi<strong>on</strong>al magmatism, slab mechanics, calc-alkaline adakite magmas, K and Na<br />
alkalic magmas.<br />
33
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
THE RELEVANCE OF VOLCANIC HAZARD IN ROMANIA:<br />
IS THERE ANY?"<br />
Szakács Alexandru 1, 2 , Seghedi Ioan 2<br />
1 Sapientia University, Dept. of Envir<strong>on</strong>mental Sciences, Cluj-Napoca, Romania,<br />
2 Institute of Geodynamics, Romanian Academy, Bucharest, Romania<br />
Szakács Alexandru, szakacs@sapientia.ro<br />
Abstract: Volcanic hazard is ignored in natural hazard studies in Romania because no<br />
active volcano is known <strong>on</strong> its territory. However, the 2010 erupti<strong>on</strong> of Eyjafjallajökull<br />
volcano in Iceland and its c<strong>on</strong>sequences <strong>on</strong> air traffic safety across Europe and the whole<br />
northern hemisphere dramatically dem<strong>on</strong>stareted that volcanic hazard in a certain area,<br />
such as a country, is not necessarily related to the presence of active volcanoes in the same<br />
territory. Therefore, target-centered approaches to volcanic hazard should also c<strong>on</strong>sider<br />
remotely located hazard sources with respect the target territory. This study aims at<br />
compiling an inventory of potential volcanic hazard sources for the territory of Romania,<br />
irrespective of their locati<strong>on</strong> inside or outside the country. External volcanic sources<br />
implying ash-fall hazard from tepha dispersi<strong>on</strong> following explosive volcanic erupti<strong>on</strong>s<br />
include the Central Italian field of active volcanoes (e.g. Campii Flegreii and Vesuvius),<br />
the active Eagean volcanic arc (Greece), the Eifel regi<strong>on</strong> of Central Europe (Germany),<br />
and Iceland. Geologic evidence of thick tephra depositi<strong>on</strong> from Campii Flegrei caldera (its<br />
Campanian ignimbite erupti<strong>on</strong> ca. 39 Ka ago) found in southern Romania clearly indicates<br />
that such type of volcanic hazard is real. On the other hand, study of the most recent<br />
volcanic activity in Romania shows that the last eruptive event, of explosive plinian type,<br />
occurred at Ciomadul volcano at the south-eastern end of the Călimani-Gurghiu-Harghita<br />
(CGH) volcanic range (East Carpathians) in a poorly-c<strong>on</strong>strained time interval of 10.7 to<br />
35 Ka in the c<strong>on</strong>tinuati<strong>on</strong> of a ca. 10.5 Ma southward-shifting volcanic activity al<strong>on</strong>g the<br />
whole CGH range. A number of peculiar features of the Ciomadul volcano and its envir<strong>on</strong>s<br />
str<strong>on</strong>gly suggest that the magma pumbing system of this volcano is not definitely frozen: a<br />
well-focused and str<strong>on</strong>gest-in-Romania heat-flow anomaly, crustal and sub-crustal local<br />
seismic activity, seismic wave attenuati<strong>on</strong> patterns recorded in seismic tompography<br />
images, most intense “post-volcanic activity” including mantle-originated gas emanati<strong>on</strong>s.<br />
Al these symptoms allow <strong>on</strong>e to c<strong>on</strong>sider that future erupti<strong>on</strong>s from this volcano cannot be<br />
ruled out. Dedicated geophysical studies are needed to obtain more basic informati<strong>on</strong> <strong>on</strong><br />
the current status of the magma-generating and plumbing systems of Ciomadul volcano,<br />
which is crucial from the viewpoint of volcanic hazard assesment.<br />
Key words: Volcanic hazard, East Carpathians, Ciomadul volcano, explosive erupti<strong>on</strong>, tephra.<br />
34
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
UPPER MANTLE STRUCTURES BENEATH THE<br />
CARPATHIAN-PANNONIAN REGION: IMPLICATIONS FOR<br />
ITS GEODYNAMICS<br />
Y<strong>on</strong>g Ren 1 , Graham W. Stuart 1 , Gregory A. Houseman 1 , Ben Dando 2 ,<br />
C<strong>on</strong>stantin I<strong>on</strong>escu 3 , Endre Hegedüs 4 , Slavica Radovanović 5 , Yang Shen 6 ,<br />
South Carpathian Project working group<br />
1 School of Earth and Envir<strong>on</strong>ment, University of Leeds, LS2 9JT, Leeds, UK;<br />
2 RockTalk Imaging Ltd, Chacewater, Cornwall TR4 8PN, UK<br />
3 Nati<strong>on</strong>al Institute of Earth Physics, Bucharest, Romania<br />
4 Eötvös Loránd Geophysical Institute, Budapest, Hungary<br />
5 Seismological Survey of Serbia, Belgrade, Serbia<br />
6 Graduate School of Oceanography, University of Rhode Island, USA<br />
Corresp<strong>on</strong>ding author: Y<strong>on</strong>g Ren, earyr@leeds.ac.uk<br />
Abstract: The Carpathian-Pann<strong>on</strong>ian system of Eastern and Central Europe represents a<br />
unique opportunity to study the interacti<strong>on</strong> between surface tect<strong>on</strong>ic processes involving<br />
c<strong>on</strong>vergence and extensi<strong>on</strong> and c<strong>on</strong>vective processes in the upper mantle. Here, we<br />
present high-resoluti<strong>on</strong> images of upper mantle structure beneath the regi<strong>on</strong> obtained using<br />
P- and S-wave finite-frequency teleseismic tomography to help c<strong>on</strong>strain the geodynamical<br />
interpretati<strong>on</strong> of the regi<strong>on</strong>. We have selected earthquakes with magnitude greater than 5.5<br />
in the distance range 30°-95°, which occurred between 2006 and 2011. The data were<br />
recorded <strong>on</strong> 57 temporary stati<strong>on</strong>s deployed in the South Carpathian Project (2009-2011),<br />
56 temporary stati<strong>on</strong>s deployed in the Carpathian Basins Project (2005-2007), and 131<br />
permanent broadband stati<strong>on</strong>s of nati<strong>on</strong>al networks. The relative arrival times are<br />
measured in high and intermediate frequency bands (0.5-2.0 Hz and 0.1-0.5 Hz for Pwaves,<br />
0.1-0.5 Hz and 0.05-0.1 Hz for S-waves), and are inverted to produce P- and Swave<br />
velocity maps in the upper mantle. Our images show a sub-vertical slab of fast<br />
material beneath the eastern Alps which extends eastward across the Pann<strong>on</strong>ian basin at<br />
depths below ~300 km. The fast material extends down into the mantle transiti<strong>on</strong> z<strong>on</strong>e<br />
(MTZ), where it spreads out beneath the entire basin. Above ~300 km, the upper mantle<br />
below the Pann<strong>on</strong>ian basin is dominated by relatively slow velocities, the largest of which<br />
extends down to ~200 km and underlies the >7km thick sediments of the Mako-Békés rift<br />
basins. We suggest that cold mantle lithospheric downwelling occurred below the<br />
Pann<strong>on</strong>ian Basin before detaching in the mid-Miocene. In the Vrancea Z<strong>on</strong>e, intermediatedepth<br />
seismicity occurs at the NE end of an upper mantle high velocity structure that<br />
extends SW oblique to the southern edge of the South Carpathians. This sub-vertical highvelocity<br />
body is bounded by slow anomalies to the NW and SE, which extend down to the<br />
top of the MTZ. No clear evidence of residual slabs is observed in the mid upper mantle<br />
beneath Eastern Carpathians; the eastern Carpathians are underlain by slow velocities<br />
everywhere above the transiti<strong>on</strong> z<strong>on</strong>e. These observati<strong>on</strong>s suggest that intermediate depth<br />
seismicity in the Vrancea Z<strong>on</strong>e is unlikely to be due to slab tearing, but rather could be<br />
explained by either gravitati<strong>on</strong>al instability or delaminati<strong>on</strong> of mantle lithosphere.<br />
35
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
SPACE CLIMATE CHARACTERIZATION OF THE<br />
HELIOSPHERE-MAGNETOSPHERE ENVIRONMENT<br />
Crisan Demetrescu, Venera Dobrica<br />
Institute of Geodynamics, Romanian Academy, Natural Fields Department<br />
Corresp<strong>on</strong>ding author: Crisan Demetrescu, crisan@geodin.ro<br />
Abstract: The space climate c<strong>on</strong>cerns the l<strong>on</strong>g-term change in the Sun and its effects in the<br />
heliosphere and up<strong>on</strong> the Earth, including the atmosphere and climate. Annual means of<br />
measured and rec<strong>on</strong>structed solar, heliospheric, and magnetospheric parameters are used to<br />
infer solar activity signatures at the Hale and Gleissberg cycles timescales. Available open<br />
solar flux, modulati<strong>on</strong> strength, cosmic ray flux, total solar irradiance data, rec<strong>on</strong>structed<br />
back to 1700, solar wind parameters (speed and density) and the magnitude of the<br />
heliospheric magnetic field at 1 AU, rec<strong>on</strong>structed back to 1870, as well as the time series<br />
of geomagnetic activity indices (aa, IDV, IHV), going back to 1870, have been c<strong>on</strong>sidered.<br />
Simple filtering procedures (successive 11-, 22-, and 88-year running averages and<br />
differences between them) and scaling by the standard deviati<strong>on</strong> from the average value for<br />
the comm<strong>on</strong> interval covered by the data show that the l<strong>on</strong>g-discussed variati<strong>on</strong> in the 20 th<br />
century (a pr<strong>on</strong>ounced increase since ~1900, followed by a depressi<strong>on</strong> in the ‘60s and a<br />
new, slower, increase) seen in the 11-year averages of parameters such as geomagnetic<br />
activity indices and rec<strong>on</strong>structed heliospheric magnetic field strength, solar wind speed,<br />
open solar flux, is a result of the superpositi<strong>on</strong> in data of solar activity signatures at Hale<br />
and Gleissberg cycles timescales. The Hale and Gleissberg signals were characterized and<br />
similarities and differences in the temporal behavior of the analyzed parameters at these<br />
timescales are discussed. The similarities in the studied parameters point to the comm<strong>on</strong><br />
pacing source, the solar dynamo.<br />
Key words: heliosphere, magnetosphere, l<strong>on</strong>g-term variati<strong>on</strong>s, space climate.<br />
36
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
LONG-TERM CHANGES IN THE ROMANIAN CLIMATE<br />
Venera Dobrica, Crisan Demetrescu<br />
Institute of Geodynamics, Romanian Academy, Natural Fields Department<br />
Corresp<strong>on</strong>ding author: Venera Dobrica, venera@geodin.ro<br />
Abstract: It is well known that the observed changes in global climate are likely to be due<br />
to a combinati<strong>on</strong> of both natural and human forcings. Solar/geomagnetic variability as<br />
external natural forcing <strong>on</strong> terrestrial climate is investigated in this study, by means of<br />
l<strong>on</strong>g-term statistical correlati<strong>on</strong>s between climatic parameters and solar/geomagnetic<br />
indices at local and regi<strong>on</strong>al scales. For the Romanian territory a robust and reliable data<br />
set of l<strong>on</strong>g records of air temperature and precipitati<strong>on</strong> (14 stati<strong>on</strong>s, 1850-2004) is<br />
available. We analyze these records in c<strong>on</strong>necti<strong>on</strong> with l<strong>on</strong>g-term trends in solar and<br />
geomagnetic activities. The comparis<strong>on</strong> of solar (sunspot number) and geomagnetic (aa<br />
index) parameters with the mean air temperature over the Romanian territory, at<br />
interdecadal timescales, shows positive correlati<strong>on</strong> coefficients, while the comparis<strong>on</strong> with<br />
the mean precipitati<strong>on</strong> shows negative correlati<strong>on</strong> coefficients. The correlati<strong>on</strong> of climatic<br />
parameters seems to be str<strong>on</strong>ger for geomagnetic activity than for solar activity. The<br />
Romanian temperature series are examined in the c<strong>on</strong>text of other European stati<strong>on</strong>s and of<br />
averages <strong>on</strong> the European, northern hemisphere, and global scale, respectively. L<strong>on</strong>g-term<br />
(inter-decadal and centennial) trends and differences between local trends and average<br />
trends for larger areas are discussed. The study indicates that solar and geomagnetic<br />
activity effects are present <strong>on</strong> the 22-year Hale cycle timescale. The temperature variati<strong>on</strong><br />
<strong>on</strong> this timescale lags the solar/geomagnetic <strong>on</strong>es by 5-9 years.<br />
Key words: solar-terrestrial relati<strong>on</strong>ship, solar/geomagnetic activity, surface air temperature and<br />
precipitati<strong>on</strong><br />
37
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
THE SURFACE TECTONICS OF LITHOSPHERIC REMOVAL<br />
BENEATH THE SOUTH EAST CARPATHIANS<br />
Oguz Gogus, Gregory Houseman<br />
University of Leeds, Institute of Geophysics and Tect<strong>on</strong>ics<br />
Corresp<strong>on</strong>ding author: Oguz Gogus, O.Gogus@leeds.ac.uk<br />
Abstract: The lithosphere beneath the South Carpathians-Transylvania-Focsani regi<strong>on</strong> has<br />
been the focus of a number of modeling studies and various geological and geophysical<br />
observati<strong>on</strong>s are provided to understand its evoluti<strong>on</strong>. Namely, lithospheric thinning,<br />
extensi<strong>on</strong>al deformati<strong>on</strong>, widespread volcanism and seismic activity are primary<br />
observati<strong>on</strong>s associated with tect<strong>on</strong>ic deformati<strong>on</strong> in this regi<strong>on</strong>. Using numerical<br />
geodynamic experiments, we test the hypothesis that the tect<strong>on</strong>ic anomalies for the south<br />
east Carpathians are due to the delaminati<strong>on</strong> of the mantle lithosphere. We explore a range<br />
of rheological parameters and boundary c<strong>on</strong>diti<strong>on</strong>s to determine c<strong>on</strong>trols <strong>on</strong> the style of<br />
lithospheric delaminati<strong>on</strong>. Our models predict that tect<strong>on</strong>ic subsidence of 3 km can occur<br />
above the delaminating hinge and surface elevati<strong>on</strong>s as great as 2 km may develop in the<br />
narrow z<strong>on</strong>e of delaminati<strong>on</strong>. The surface topography of delaminating lithosphere is<br />
distinctly asymmetric with a localized and migrating z<strong>on</strong>e of subsidence at the<br />
delaminating hinge as well as surface uplift due to the isostatic/dynamic resp<strong>on</strong>se to the<br />
lithospheric removal. Detachment of the delaminating lithosphere modifies the topography<br />
near the delaminati<strong>on</strong> hinge. Delaminati<strong>on</strong> progresses more rapidly when mantle<br />
lithosphere has higher yield stresses compared to less rigid mantle lithosphere. Our results<br />
are tested against the present day topography and seismic velocities determined by<br />
tomography beneath the Focsani basin and South East Carpathian mountains.<br />
Key words: South East Carpathians, anomalous topography, migrating subsidence, young<br />
volcanism, delaminati<strong>on</strong>.<br />
38
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
ANALYSIS OF HAZARD POLLUTION ON OLD PESTICIDE<br />
STORAGES IN MOLDOVA<br />
Oleg Bogdevich, Oleg Cadocinicov, Culighin Elena<br />
Academy of Science of Moldova, Institute of Geology and Seismology<br />
Corresp<strong>on</strong>ding author: Oleg Bogdevich, bogdevicholeg@yahoo.com<br />
Abstract: The inventory of old pesticide storages in Moldova executed by Ministry of<br />
Envir<strong>on</strong>ment and World Bank showed a large quantity of polluted sites (near 1500)<br />
remains after the repacking and evacuati<strong>on</strong> project. More that 15 % sites were determined<br />
as extra high polluted territory with the POPs c<strong>on</strong>centrati<strong>on</strong> in soil more 50,0 mg/kg. They<br />
include some of the world’s most harmful chemicals including highly toxic pesticides such<br />
as HCH, DDT and industrial chemicals such as PCBs. The aim of this work is to determine<br />
all polluti<strong>on</strong> spectrums <strong>on</strong> 50 polluted sites for Envir<strong>on</strong>mental Risk Assessment procedure<br />
and the remediati<strong>on</strong> acti<strong>on</strong> development. GC and GC/MS equipment and internati<strong>on</strong>al<br />
analytical methods (EPA, ISO, etc.) were used in accredited laboratory by ISO17025 for<br />
the determinati<strong>on</strong> of toxic substances in soil and other envir<strong>on</strong>mental samples. Five POPs<br />
compound groups namely ∑ DDT, ∑ HCH, Chlordane, Heptachlor and Toxaphene have<br />
been found <strong>on</strong> studied sites. They have an additi<strong>on</strong>al polluti<strong>on</strong> by trifluraline, triazines,<br />
perithroids, PAHs and other old pesticides. Small number of sites has high heavy metal<br />
polluti<strong>on</strong>. All sites were distributed <strong>on</strong> five polluti<strong>on</strong> clusters for the risk assessment<br />
procedure and the ranking of investigated sites: 0.10 <strong>–</strong> 1.0 mg/kg; 1.0 <strong>–</strong> 10.0 mg/kg; 10.0 <strong>–</strong><br />
50.0 mg/kg; 50.0 <strong>–</strong> 250.0 mg/kg; and more 250.0 mg/kg. The toxicity level, MAC and<br />
possible synergism effect were used for the risk assessment procedure of polluted sites.<br />
The c<strong>on</strong>clusi<strong>on</strong> is that polluti<strong>on</strong> spectrum is complex <strong>on</strong> investigated sites and it can be<br />
extrapolated for all polluted sites in Moldova. The possible remediati<strong>on</strong> acti<strong>on</strong> should to be<br />
developed after the complex study of polluti<strong>on</strong> spectrum and geotechnical c<strong>on</strong>diti<strong>on</strong>s for<br />
every site. Created database of polluted territories is used actually by local and central<br />
authorities for the waste management and planning of remediati<strong>on</strong> acti<strong>on</strong> in Republic of<br />
Moldova.<br />
Key words: Toxic Substances, GC, GC/MS, Envir<strong>on</strong>mental Impact Assessment.<br />
39
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
GEOLOGICAL HAZARDS ASSESMENT IN REPUBLIC OF<br />
MOLDOVA (CASE STUDY PRUT RIVER VALEY)<br />
Igor Nicoara, Oleg Bogdevich<br />
Academy of Science of Moldova, Institute of Geology and Seismology<br />
Corresp<strong>on</strong>ding author: Igor NICOARA, nicoaraigor@gmail.com<br />
Abstract: The mitigati<strong>on</strong> of the negative impact of geological hazards to the<br />
envir<strong>on</strong>mental, ec<strong>on</strong>omic and populati<strong>on</strong> is very important for the sustainable development<br />
of every country. The risk of natural hazards like landslides, erosi<strong>on</strong>, drought, inundati<strong>on</strong> is<br />
growing last time by the climate change in European country and Moldova. The feasibility<br />
study for the assessment of the possible negative impact of natural hazards, including<br />
geological, was carried out in Republic of Moldova by UNDP project “Moldova Disaster<br />
and Climate Risk Reducti<strong>on</strong>”. The aim of this work is to evaluate a possible risk from<br />
geological hazards <strong>on</strong> example of some villages from Prut river valley. This regi<strong>on</strong> is<br />
characterized by the complex geologic, geomorphologic and climatic c<strong>on</strong>diti<strong>on</strong>s. The<br />
unfavorable geological processes are presented by soil erosi<strong>on</strong>, landslides, and sensitive<br />
rocks to the inundati<strong>on</strong>. Digital maps of natural disasters, including polluti<strong>on</strong> sources, ware<br />
elaborated for every pilot communities by ArcGIS software with the utilizati<strong>on</strong> of the<br />
electr<strong>on</strong>ic map from www.geoportal.md. The evaluati<strong>on</strong> of the spacial distributi<strong>on</strong> of<br />
geological hazards and other geoprocessing was made for the risk assessment and territory<br />
development plans. These maps are proposed for the geodatabase as a part of scientific<br />
support system by the decisi<strong>on</strong> making for emergency preparedness plans in regi<strong>on</strong> for the<br />
preventi<strong>on</strong> and negative impact reducti<strong>on</strong> in the case of natural and anthropogenic<br />
accidents. The complex envir<strong>on</strong>mental data can be used also for transboundary<br />
cooperative projects between Republic of Moldova, Romania and Ukraine in the regi<strong>on</strong>al<br />
m<strong>on</strong>itoring programs by the disaster preventi<strong>on</strong> and envir<strong>on</strong>mental impact assessment. The<br />
c<strong>on</strong>crete proposals for the reducti<strong>on</strong> of soil erosi<strong>on</strong> and landslide hazard are made for pilot<br />
localities <strong>on</strong> the basis of GIS elaborati<strong>on</strong>. The results of the study will be presented to the<br />
local authorities and other interested stakeholders (ecological, hydrological, meteorological<br />
and sanitary service agencies etc).<br />
Key words: ArcGIS, digital map, geological hazards.<br />
40
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
SURLARI GEOMAGNETIC OBSERVATORY: ROLE INTO<br />
SPACE AND EARTH WEATHER CONCEPT<br />
Anca Isac 1 , Mioara Mandea 2 , Andrei Soare 1<br />
1 Geological Institute of Romania, Surlari Geomagnetic Observatory<br />
2 Centre Nati<strong>on</strong>al d'Etudes Spatiale, Earth Observati<strong>on</strong> / Directorate for Strategy and Programmes<br />
Corresp<strong>on</strong>ding author: Anca Isac, margoisac@yahoo.com<br />
Abstract: Surlari (SUA) is the unique nati<strong>on</strong>al magnetic observatory, established near the<br />
capital, Bucharest, in 1943. Since then it is a research facility of the Geological Institute of<br />
Romania. From 1997, SUA is member of the worldwide network of magnetic observatories -<br />
INTERMAGNET, which m<strong>on</strong>itors in real-time the Earth’s magnetic field variati<strong>on</strong>s. Space<br />
weather reflects physical processes, beginning at the Sun’s surface, and can influence the<br />
performance and reliability of space-borne and ground-based technological systems. Space<br />
weather can threat human life or health too, according to the recent studies. The Sun emits<br />
energy (flares of electromagnetic radiati<strong>on</strong>: radio waves, infra-red, light, ultraviolet, X-rays)<br />
and energetic electrically charged particles through cor<strong>on</strong>al mass ejecti<strong>on</strong>s. The<br />
electromagnetic radiati<strong>on</strong> travels at the speed of light and takes minutes to move from the Sun’<br />
surface to the Earth, whereas the charged particles which travel outwards (the solar wind)<br />
travel more slowly, taking from a few hours to several days to reach the Earth. Solar wind<br />
interacts with the Earth's magnetic field and outer atmosphere in complex ways: c<strong>on</strong>centrati<strong>on</strong>s<br />
of energetic particles and electric currents flowing in magnetosphere and i<strong>on</strong>osphere. These can<br />
result in geomagnetic more rapid variati<strong>on</strong>s opposite to the main geomagnetic field, which is<br />
slowly varying and originates within the Earth. The ground-based magnetic observatories<br />
provide a wide range of informati<strong>on</strong>, including the time and intensity of magnetic storms, substorms<br />
and pulsati<strong>on</strong>s. Of particular importance for m<strong>on</strong>itoring space weather c<strong>on</strong>diti<strong>on</strong>s from<br />
a ground observatory is the real-time observati<strong>on</strong> of typical storms, which often start with a<br />
“sudden commencement”, a positive perturbati<strong>on</strong> in the horiz<strong>on</strong>tal magnetic field. The sudden<br />
impulses (SI) usually exert no subsequent storms. The sudden storm commencements (SSC)<br />
are followed by a general increase in the magnetic northward field as an initial phase (that may<br />
c<strong>on</strong>tinue minutes up to several hours), and after that the main and recovery storm magnetic<br />
field pattern are observed, studied and sometimes subject of a warming alert. Scientists,<br />
decisi<strong>on</strong>-makers from aer<strong>on</strong>autics and communicati<strong>on</strong>, and the public are informed about Sun-<br />
Earth system phenomena that might impact human survival. A quantitative analysis of storm<br />
time magnetic disturbance and the local geomagnetic disturbance index K are enabled every<br />
three hours. One of the aims of SUA observatory is to reduce the impact of space weather <strong>on</strong><br />
activities of human interest <strong>on</strong> nati<strong>on</strong>al territory, due to rapid processing and exchange of space<br />
envir<strong>on</strong>ment informati<strong>on</strong>. The field comp<strong>on</strong>ent variati<strong>on</strong>s are recorded at a sampling rate of 2<br />
Hz and the field intensity at 0.2 Hz, c<strong>on</strong>tinuously. A real-time plot showing 24 hours of the<br />
current and previous day, including the delta-F check plot, is updated every 10 minutes. The<br />
nati<strong>on</strong>al geomagnetic observatory plays and will play a role in m<strong>on</strong>itoring of space and Earth<br />
weather c<strong>on</strong>diti<strong>on</strong>s over Romanian territory, mainly nowadays when approaching the next solar<br />
maximum, around 2013. This upcoming burst of solar activity, might affect mobile ph<strong>on</strong>es,<br />
GPSs and many other modern technologies <strong>on</strong> Earth and near-Earth space. A network of<br />
variometer stati<strong>on</strong>s to c<strong>on</strong>tinuously m<strong>on</strong>itor space weather might be a future project of SUA<br />
observatory as well as a major involvement of it in the nati<strong>on</strong>al and internati<strong>on</strong>al space weather<br />
programs.<br />
41
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
GEOLOGICAL AND PALEONTOLOGICAL MONUMENTS IN<br />
REPUBLIC OF MOLDOVA (CASE STUDY VILLAGE<br />
NASLAVCEA, DISTRICT OCNIŢA)<br />
Cristina Mogorici, Igor Nicoara<br />
Academy of Sciences of Moldova, Institute of Geology and Seismology<br />
Corresp<strong>on</strong>ding author: Cristina MOGORICI, cristinamogorici@gmail.com<br />
Abstract: At present in Republic of Moldova, there are 87 geological m<strong>on</strong>uments with<br />
total size 2682 hectares. That are protected by “Law <strong>on</strong> Natural Areas Protected by the<br />
State (1998)”. These protected areas have different management and land use destinati<strong>on</strong><br />
(forest agency “Moldsilva”, local authority and other). The chaotic retrocessi<strong>on</strong> of land<br />
areas in 1990-s to private owners, without any c<strong>on</strong>cern <strong>on</strong> the existing protected areas,<br />
raised new and great difficulties in c<strong>on</strong>servati<strong>on</strong> in protected areas. Under such<br />
circumstances, it is not surprising that the deteriorati<strong>on</strong> of the geological m<strong>on</strong>uments<br />
prevails <strong>on</strong> their protecti<strong>on</strong> and c<strong>on</strong>servancy. We selected small village for this study<br />
named Naslavcea. It situated in northern part of the Republic of Moldova and it is<br />
extrimaly northern point of our c<strong>on</strong>try. This locality is in cany<strong>on</strong> valley of the rivulet<br />
Chisărău right tributary of the Dniester River. Five geological m<strong>on</strong>uments are known from<br />
village Naslvcea: “Outcrops of drainage silica”, valley “Rudii Iar”, valley “Karpov Iar”,<br />
“Tect<strong>on</strong>ic steep slope of the Dniester River near Naslavcea village” and “Outcrops with<br />
Badenian sands”. Assessment of geological m<strong>on</strong>uments in the Republic of Moldova was<br />
c<strong>on</strong>ducted of the UNDP project “Improving coverage and management effectiveness of the<br />
Protected Area System in Moldova”. The aim of this work is to evaluate geological<br />
m<strong>on</strong>uments (revisi<strong>on</strong> of GPS coordinate, administrati<strong>on</strong> of areas, revisi<strong>on</strong> of stratigraphy<br />
and taxa list of remains). The sustainable development of geological and pale<strong>on</strong>tological<br />
m<strong>on</strong>uments are requires interdepartamental coherent strategies, wich must include<br />
buessnes plan of turism development in this areas.<br />
Key words: Geoc<strong>on</strong>servati<strong>on</strong>, Republic of Moldova, geological m<strong>on</strong>uments, Naslavcea.<br />
42
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
INVESTIGATION OF THE POTENTIAL HAZARDS<br />
GENERATORS IN THE VICINITY OF THE MUNICIPAL<br />
LANDFILLS<br />
Bogdan Stanescu, Marinela Petrescu, Gheorghe Batrinescu<br />
Nati<strong>on</strong>al Research and Development Institute for Industrial Ecology - ECOIND, Department for<br />
Envir<strong>on</strong>mental<br />
Polluti<strong>on</strong> Assessment and M<strong>on</strong>itoring<br />
Corresp<strong>on</strong>ding author: Bogdan Stanescu, evmt@incdecoind.ro<br />
Abstract: Areas situated in the proximity to landfills have several features of great<br />
importance in further, as some of these areas can get changing in the future to residential<br />
destinati<strong>on</strong>s. It is therefore important to determine the quality of envir<strong>on</strong>mental<br />
comp<strong>on</strong>ents in these areas and to identify all hazards that may create risks for the area<br />
analyzed. Complex investigati<strong>on</strong>s carried out in the proximity to landfills will have as a<br />
final risk estimati<strong>on</strong>, <strong>on</strong>e of which shows the importance induced by the emissi<strong>on</strong>s of<br />
methane that may migrate into soil / subsoil in the vicinity of the deposit. This paper<br />
presents a methodology for assessing risks with the following steps: the documentary stage<br />
involves collecting relevant informati<strong>on</strong> <strong>on</strong> the landfill site, site history, and the date <strong>on</strong><br />
geomorphology, geology and hydrogeology of the area. In the subsequent stages, it<br />
identifies the potential sources of the gaseous emissi<strong>on</strong>s in soil / subsoil and the potential<br />
migrati<strong>on</strong> pathways and receptors proceed to investigate complex area. As a case study<br />
was chosen site of a landfill in Bucharest, which was crossed methodology of<br />
investigati<strong>on</strong>: they made wells and the gas collecti<strong>on</strong> were measured in situ the<br />
c<strong>on</strong>centrati<strong>on</strong>s of gases (CH4, O2, CO2, CO and H2S) with a portable analyzer, were<br />
made boreholes to determine the groundwater flow c<strong>on</strong>diti<strong>on</strong>s and analytical investigati<strong>on</strong>s<br />
<strong>on</strong> the envir<strong>on</strong>mental quality of comp<strong>on</strong>ents (soil, groundwater, surface water) in the<br />
proximity of the landfill. In terms of the methodology, the risk estimati<strong>on</strong> is based <strong>on</strong> the<br />
identificati<strong>on</strong> and the expressi<strong>on</strong> of two categories of factors, including the likelihood and<br />
effects <strong>on</strong> receptors that highlight risk levels resulting in a scale with five levels of risk, at<br />
a very low risk to high risk levels. The risk can be quantified by the indicator "Gas<br />
Screening Value", which is the product of the maximum c<strong>on</strong>centrati<strong>on</strong> measured in gas<br />
borehole and the measured flow. Applying the methodology for the selected locati<strong>on</strong> as a<br />
case study allowed the identificati<strong>on</strong> of hazards and risk generating, the risk assessment,<br />
elements necessary to development the measures of protecti<strong>on</strong> required are taken in case<br />
the future of locati<strong>on</strong> will be for the residential.<br />
Key words: biogas, landfill, waste, methane, risk, assessment.<br />
43
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
A COMPARISON OF GPS SOLUTIONS FOR STRAIN AND<br />
SKS FAST DIRECTIONS: IMPLICATIONS FOR MODES OF<br />
SHEAR IN THE MANTLE OF A PLATE BOUNDARY ZONE<br />
Nicolas Houlié 1 , Tim Stern 2 , Calum Chamberlain 3<br />
1 University of Leeds, UK <strong>–</strong> ETH, Zurich<br />
2 University of Victoria, Wellingt<strong>on</strong>, NZ<br />
3 University of Leeds, UK<br />
Corresp<strong>on</strong>ding author: Nicolas Houlié, n.houlie@leeds.ac.uk<br />
Abstract: The strain rate field for New Zealand is computed using the GPS dataset from<br />
GEONET (NZ) collected during the last decade. Two c<strong>on</strong>trasting domains for shear in the<br />
mantle are inferred by comparing the principal shortening directi<strong>on</strong> with the fast directi<strong>on</strong><br />
of shear wave splitting. We interpret the mantle beneath the central-southern part of the<br />
South Island to have a significant comp<strong>on</strong>ent of pure shear linked to thickening of both the<br />
crust and mantle lithosphere. To the north, in c<strong>on</strong>trast, simple shear is dominant. We will<br />
present potentials applicati<strong>on</strong>s for the mantle dynamics of Western USA and Central<br />
Europe.<br />
Figure 1: Comparis<strong>on</strong> between shortening axes (GPS, red) and axis of fast polarisati<strong>on</strong> (SKS, blue).<br />
Key words: Lithosphere <strong>–</strong> Seismology <strong>–</strong> GPS <strong>–</strong> Strain <strong>–</strong> SKS -- Deformati<strong>on</strong>.<br />
44
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
SYNERGISTIC EFFECT FOR THE RETENTION OF METAL<br />
CATIONS OBTAINED BY A COMPLEX ORGANIC -<br />
INORGANIC COMPOUND OF DIFFERENT TYPES OF CLAY<br />
Ileana Denisa Nistor, Gheorghe Surpateanu, Neculai Doru Mir<strong>on</strong>, Anca<br />
Ciobanu, Iuliana Mihaela Lazar<br />
1 ”Vasile Alecsandri” University of Bacau, Department of Chemical and Food Engineering<br />
Corresp<strong>on</strong>ding author: Ileana Denisa Nistor, denisanistor@yahoo.com<br />
Abstract: Hybrid materials cover a wide range of compounds with diverse potential<br />
applicati<strong>on</strong>s. Indeed, these materials have the advantage of combining the properties of the<br />
organic comp<strong>on</strong>ent with the inorganic comp<strong>on</strong>ent leading us to expect a synergy between<br />
these two properties.<br />
The inorganic comp<strong>on</strong>ent of the material is formed by cati<strong>on</strong>ic or ani<strong>on</strong>ic clays:<br />
m<strong>on</strong>tmorill<strong>on</strong>ite or layerd double hydroxides and the organic comp<strong>on</strong>ent of hybrid material<br />
is represented by organic compounds like: chitosan, dendrimers, and pharmaceutical<br />
substances. The first part of this works presents a complex organic - inorganic compound<br />
of m<strong>on</strong>tmorill<strong>on</strong>ite and organic substances intercalated like chitosan and poliol dendrimers.<br />
When used simultaneously chitosan and m<strong>on</strong>tmorill<strong>on</strong>ite, there is a str<strong>on</strong>g synergy<br />
phenomen<strong>on</strong>, probably due to interacti<strong>on</strong>s between the main properties. We can have a<br />
first c<strong>on</strong>clusi<strong>on</strong>: the hybrid materials can develop interesting synergistic properties and the<br />
field of hybrid materials deserves all the attenti<strong>on</strong> possible in future. There are a major<br />
c<strong>on</strong>cerns and attempts to capture carb<strong>on</strong> dioxide emissi<strong>on</strong>s released in the majority<br />
industrial and other types of activities. We propose in this work to solve this problem using<br />
hybrid material. The research opens up new prospects for the class of hybrid materials like<br />
organic - inorganic, with an enhanced carb<strong>on</strong> dioxide retenti<strong>on</strong> capacity. Another material<br />
type polyol dendrimers-m<strong>on</strong>tmorill<strong>on</strong>ite has a high retenti<strong>on</strong> capacity for carb<strong>on</strong> dioxide<br />
and it can also be regenerated by heating low. The sec<strong>on</strong>d part presents the hybrid<br />
materials formed by layerd double hydroxides with cloramphenicol and salicylate in the<br />
interlayer space. These materials were analyzed by thermogravimetric analysis, X-ray<br />
diffracti<strong>on</strong> (XRD) and Fourier transform infrared spectroscopy (FTIR), powerful<br />
n<strong>on</strong>destructive. The kinetic parameters (reacti<strong>on</strong> order n) the apparent activati<strong>on</strong> energy<br />
(Ea) and pre-exp<strong>on</strong>ential factor were calculated using the Coats - Redfern. We also<br />
determined the effects of compensati<strong>on</strong>. The prospects of my research are to deepen my<br />
research <strong>on</strong> ani<strong>on</strong>ic clays and design new drugs to treat inflammatory bowel disease<br />
(Crohn's Disease and Ulcerative Colitis) and more particularly associated colitis and<br />
diarrhea.<br />
Key words: ani<strong>on</strong>ic and cati<strong>on</strong>ic clays, dendrimers, chitosan, cloramphenicol, salicylate.<br />
45
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
ESENTIAL TOOLS TO MITIGATE OF VRANCEA STRONG<br />
EARTHQUAKES ON <strong>MOLDAVIAN</strong> URBAN ENVIRONMENT<br />
Gheorghe Marmureanu, C<strong>on</strong>stantin I<strong>on</strong>escu, Alexandru Marmureanu<br />
Nati<strong>on</strong>al Institute for Earth Physics, Bucharest Romania<br />
Corresp<strong>on</strong>ding author: Gheorghe Marmureanu, marmur@infp.ro<br />
Abstract: In a world of uncertainty, the <strong>on</strong>ly c<strong>on</strong>stant is change and rapid change produces<br />
a multitude of diverse facts. Risk is an integral part of life. While no country in the world<br />
is entirely safe, the lack of capacity to limit the impact of hazards remains a major burden<br />
for developing countries and while the world has witnessed an exp<strong>on</strong>ential increase in<br />
human and material losses due to natural disasters , there is a need to reverse trends in<br />
vulnerability to earthquakes.Available data suggest that natural disasters from earthquakes<br />
can cause c<strong>on</strong>siderable damages, with potentially severe effects to urban envir<strong>on</strong>ment.On<br />
the other hand, envir<strong>on</strong>mental degradati<strong>on</strong> increases the intensity of natural disasters, and<br />
is often the factor that transform natural hazards, into a disaster. In World, earthquakes<br />
are resp<strong>on</strong>sible for 15% of total number of events, and 30% of the total damages. Last<br />
str<strong>on</strong>g Vrancea earthquake <strong>on</strong> March 4,1977(Mw=7.4,h=95 km):1578 dead and 11,321<br />
injured (90% of dead and injured 67% of Bucharest), 36 ruined/destroyed blocks in<br />
Bucharest, 32,900 houses collapsed or severely damaged; 35,000 families homeless, tens<br />
of thousands (64,000) of buildings damaged from Iaşi and Bacău to Craiova, many other<br />
damages and destructi<strong>on</strong>s in the industry and ec<strong>on</strong>omy,downtown of Bacău was<br />
completely damaged etc. Rapid urbanizati<strong>on</strong> of cities has caused unbearable<br />
envir<strong>on</strong>mental problems primary in the cities of the developing cauntries.Natural risks<br />
such as earthquakes are largely bey<strong>on</strong>d human c<strong>on</strong>trol. Seismic risk management can <strong>on</strong>ly<br />
be successful when it is fully integrated in global management. This is what is referred to<br />
as integrated safety by using innovative and integrated techniques and methods to the<br />
further development of community risk management policy.In general,safety management<br />
should not be limited to technical preventi<strong>on</strong>, mitigati<strong>on</strong> or preparedness, but must be part<br />
of the general trend toward efficiency, effectiveness and quality improvement of<br />
envir<strong>on</strong>ment. The goal of the paper is to enhance our capability to decrese the effects of<br />
earthquakes occuring in Vrancea regi<strong>on</strong> <strong>on</strong> the urban envir<strong>on</strong>ment, inclusively in<br />
Moldavian area. Specific fundamental and applied researches were developed last years by<br />
Nati<strong>on</strong>al Institute for Earth Physics sustained by „Government Low nr.372/2004 - The<br />
Nati<strong>on</strong>al Program of Seismic Management” and European Programmes like FP-6, FP-7,<br />
Cross-Border etc. are: (i)-New isoseismal map of the maximum credible Vrancea<br />
earthquake or maximum probable Vrancea earthquake, Mw =7.7 (Gh.Mărmureanu et al,<br />
Romanian Reports in Physics,Vol. 63, No.1, P. 226<strong>–</strong>239,2011);(ii)-Seismic microz<strong>on</strong>ati<strong>on</strong><br />
of large populated cities: Iasi, Bacău, Buzău, Craiova, Ploieşti, Timişoara, Sibiu<br />
etc.(CEEX Programme, C<strong>on</strong>tract nr.636/2005-2008 and Nucleus Programme); (iii) - Shake<br />
maps for each str<strong>on</strong>g Vrancea earthquake which allows us to rapidly portray the extent of<br />
shaking in a simplified form suitable for immediate post-earthquake decisi<strong>on</strong><strong>–</strong>making.<br />
Shake map is an instrument of rapid informati<strong>on</strong> about an impeding seismic hazard and<br />
minimizes the impacts to people and ec<strong>on</strong>omic activities and them are used by Civil<br />
46
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
Protecti<strong>on</strong> Departments; (4) - Early warning system (EWS) for industrial facilities and<br />
other installati<strong>on</strong>s of nati<strong>on</strong>al interest at str<strong>on</strong>g intermediary earthquakes made during of<br />
Project SAFER-FP6(2006-2009) and EWS is winner of „2006 IST European<br />
Prize”(A.Mărmureanu et al., Advanced real-time acquisiti<strong>on</strong> of the Vrancea earthquake<br />
early warning system,Soil Dynamics and Earth.Engrg.,Vol.31,Issue 2,SSI,16-169,2011;<br />
A.Mărmureanu: Rapid magnitude determinati<strong>on</strong> for Vrancea early warning system,<br />
Romanian Jornal of Physics,Vol.54,No.9-10,2009); (5)- Seismic tomography of special<br />
structures like dams for avoiding catastrophes (Bicaz and Vidraru dams; priority c<strong>on</strong>tracts<br />
with nati<strong>on</strong>al authorities). The seismic hazard assessment is a crucial step and an essential<br />
tool to mitigate the impact of Vrancea str<strong>on</strong>g earthqakes <strong>on</strong> urban envir<strong>on</strong>ment in this part<br />
of the World.Preventi<strong>on</strong> pays off! This may not always become apparent immediately, but,<br />
in the l<strong>on</strong>g run, the benefits from preventi<strong>on</strong> measures will always outweigh their costs by<br />
far (Kofi Annan).<br />
Key words: Seismic hazard, urban envir<strong>on</strong>ment,risk mitigati<strong>on</strong>,early-warning system,shake map.<br />
47
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
A SEISMIC RISK ANALYSIS FOR VRANCEA AND BACAU<br />
COUNTIES, BASED ON SELENA AND GIS SOFTWARE<br />
Dragos Toma Danila<br />
Nati<strong>on</strong>al Institute for Earth Physics, Magurele, Ilfov, Romania<br />
Corresp<strong>on</strong>ding author: Dragos Toma Danila, toma@infp.ro<br />
Abstract: In the last years, thanks to the implementati<strong>on</strong> of the ShakeMap software in realtime<br />
at the Nati<strong>on</strong>al Institute for Earth Physics (NIEP) and within the DACEA Project, a<br />
system that computes damage and loss estimates in (near) real-time for the Romanian-<br />
Bulgarian border regi<strong>on</strong> was installed at NIEP, producing data and maps, <strong>on</strong> Romanian<br />
side - for 7 counties. But the system was also designed so that it has the capability to allow<br />
extending and upgrading the database, for all Romanian counties and taking into<br />
c<strong>on</strong>siderati<strong>on</strong> the permanent evoluti<strong>on</strong> of building stock and populati<strong>on</strong>. The main purpose<br />
of this paper is to present both the integrati<strong>on</strong> mode and the results obtained by adding new<br />
counties into the implemented system, and also to present best ways for a GIS<br />
representati<strong>on</strong> of the estimated damage. Of great interest is that the new counties <strong>–</strong><br />
Vrancea and Bacau, are right <strong>on</strong> top of the active seismic area of Vrancea, compared to the<br />
previous analyzed 7 counties that are more than 100 km away from the epicentral area. For<br />
damage computati<strong>on</strong> it was used the open-source software SELENA (Seismic Loss<br />
Estimati<strong>on</strong> using a Logic Tree Approach), with the real-time module based <strong>on</strong> PGA and Sa<br />
values at 0.3 and 1.0 sec<strong>on</strong>ds, provided by a 10 by 10 km grid produced by ShakeMap. Of<br />
course, for results were simulated significant previously recorded earthquakes: the <strong>on</strong>es <strong>on</strong><br />
4 march 1977 (Mw 7.4), 30 august 1986 (Mw 7.1) and 30 may 1990 (Mw 6.9). The static<br />
database included number of buildings from the 2002 census, at UAT (administrativeterritorial<br />
unity) level. Buildings were classified in 55 individual types, each with a specific<br />
capacity and fragility curve. The method used to obtain damage probabilities was the more<br />
recent Improved Displacement Coefficient Method (I-DCM). The spatial characteristic of<br />
the generated output provided a good basis for the use of GIS tools, which added important<br />
c<strong>on</strong>tributi<strong>on</strong> to how data is visualized and used for planning and interventi<strong>on</strong> purposes.<br />
There are many practical sides of the paper: first of all is that based <strong>on</strong> past events it is<br />
illustrated how the damage might look like nowadays in a very exposed area and what are<br />
the risks to be dealt with. Also, the certain accuracy of the loss assessment is validated, so<br />
that the new counties can be included in the real-time damage estimati<strong>on</strong> system at NIEP.<br />
Key words: seismic risk, Selena software, Bacau & Focsani counties, damage estimati<strong>on</strong>, GIS.<br />
48
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
A BAYESIAN APPROACH FOR THE ASSESSMENT OF RISK<br />
IMPACT CASE STUDY FOR DIGITAL RISK IMPACT<br />
Elena Nechita, Carmen -Violeta Muraru, Mihai Talmaciu<br />
“Vasile Alecsandri” University of Bacau, Department of Mathematics,<br />
Informatics and Educati<strong>on</strong>al Sciences<br />
Corresp<strong>on</strong>ding author: Elena Nechita, enechita@ub.ro<br />
Abstract: Our society faces new challenges and risks, due to the interdependency of the<br />
elements comprising its critical infrastructure (such as energy, transports, and digital). This<br />
paper presents a framework for the impact assessment of the natural or man-made disasters<br />
in Bacău County. C<strong>on</strong>sidering overlapping chains of events that could potentially occur as<br />
c<strong>on</strong>sequences of a disaster and the associated risk probabilities, the model allows its user to<br />
vary certain parameters and observe the effects <strong>on</strong> the global, computed impact. The<br />
analysis behind integrates the design of a semantic graph that includes most of the<br />
hazardous events which have been recorded during the last decades in the targeted area,<br />
and the Bayesian approach of uncertainty. A particular emphasis is placed <strong>on</strong> aspects<br />
c<strong>on</strong>cerning the risks associated to informatics systems. The model could be used to support<br />
the best decisi<strong>on</strong>s in a given situati<strong>on</strong>, facilitating the focus <strong>on</strong> the most significant risks<br />
and especially <strong>on</strong> the protecti<strong>on</strong> of digital infrastructure.<br />
Key words: Bayesian probability, semantic graph, digital infrastructure, risk impact.<br />
49
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
A NEW APPROACH OF ATMOSPHERIC VORTEX<br />
DYNAMICS BY NON-DIFFERENTIABILITY<br />
Adrian Timofte 1, 2 , Marius Mihai Cazacu 1 , Dan Gheorghe Dimitriu 1 , Silviu<br />
Octavian Gurlui 1 , Maricel Agop 3<br />
1 “Alexandru Ioan Cuza” University of Iasi, Faculty of Physics, Romania<br />
2 Nati<strong>on</strong>al Meteorological Administrati<strong>on</strong>, Regi<strong>on</strong>al Forecast Center Bacau, Romania<br />
3 “Gheorghe Asachi” Technical University of Iasi, Romania<br />
Corresp<strong>on</strong>ding author: Maricel Agop, m.agop@yahoo.com<br />
Abstract: Assimilating the atmospheric fluid with a complex fluid and c<strong>on</strong>sidering that the<br />
fluid particles dynamics takes place <strong>on</strong> c<strong>on</strong>tinuous and n<strong>on</strong>-differentiable curves we build<br />
a new theoretical model of atmospheric vortex. This theory enables us to perform a good<br />
approach of dynamics both <strong>on</strong> a predictable scale (that corresp<strong>on</strong>d in our model with a<br />
differentiable scale) and an unpredictable scale (that corresp<strong>on</strong>ding at undifferentiated<br />
scale). The global visi<strong>on</strong> of dynamics is realized into an atmospheric fluid c<strong>on</strong>sidering that<br />
until now was used <strong>on</strong>ly a deterministic models or stochastic models. Furthermore it is<br />
shown that the vortex source is given by a complex fluid dynamics <strong>on</strong> the n<strong>on</strong>differentiable<br />
scale. Validati<strong>on</strong> of the theoretical model was based <strong>on</strong> correlati<strong>on</strong>s with<br />
meteorologically data. An immediate perspective is to taking into account the tropospheric<br />
particles distributi<strong>on</strong> with altitude, such as a LIDAR system (Light Detecti<strong>on</strong> and<br />
Ranging), with a high spatial and temporal resoluti<strong>on</strong> (3.5 meters/ from 30 sec<strong>on</strong>ds to 1 or<br />
5 minutes). Thus, the variati<strong>on</strong> of aerosols distributi<strong>on</strong> in the atmosphere (up to altitudes of<br />
10 - 12 km) and complex variati<strong>on</strong> of the fluid particle distributi<strong>on</strong>s (according to<br />
theoretical model) will be highlighted and correlated for validati<strong>on</strong> of theoretical model.<br />
Key words: vortex, complex fluid, n<strong>on</strong>-differentiability, atmospheric dynamic.<br />
50
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
STRESS TESTS FOR CERNAVODA NPP - ASSESSMENT OF<br />
PROTECTION AGAINST EARTHQUAKES<br />
Cantemir Ciurea-Ercau, Elena Dinca, Madalina Tr<strong>on</strong>ea<br />
Comisia Nati<strong>on</strong>ala pentru C<strong>on</strong>trolul Activitatilor Nucleare (CNCAN), Bucharest, Romania<br />
Corresp<strong>on</strong>ding author: Cantemir Ciurea-Ercau, cantemir.ciurea@cncan.ro<br />
Abstract: On the 11 th of March 2011, the Fukushima Daiichi nuclear power plant in Japan<br />
experienced a seismic event and a subsequent tsunami exceeding the design basis of the<br />
plant. This led to a severe nuclear accident affecting multiple units of the Fukushima<br />
Daiichi plant and resulting in unc<strong>on</strong>trolled radioactive releases. Following the Fukushima<br />
Daiichi accident, the Romanian authorities and the nuclear industry have performed<br />
reassessments of nuclear safety and emergency preparedness arrangements and have<br />
started to implement improvements, in line with the internati<strong>on</strong>al efforts in this directi<strong>on</strong>.<br />
The safety reassessments c<strong>on</strong>ducted in resp<strong>on</strong>se to the Fukushima accident included the<br />
"stress tests" review required by the European Council, in compliance with the<br />
specificati<strong>on</strong>s and criteria issued by the European Commissi<strong>on</strong>, based <strong>on</strong> the work d<strong>on</strong>e by<br />
the European Nuclear Safety Regulators' Group (ENSREG) and the Western European<br />
Nuclear Regulators' Associati<strong>on</strong> (WENRA). A significant effort has been made by the<br />
licensee for Cernavoda nuclear power plant to resp<strong>on</strong>d to the less<strong>on</strong>s learned from the<br />
Fukushima accident in a timely manner. Several potential design and operati<strong>on</strong>al<br />
improvements have been identified and their implementati<strong>on</strong> is in progress to further<br />
enhance the existing safety margins and reduce the risk from severe accidents. The reviews<br />
and inspecti<strong>on</strong>s performed by the Nati<strong>on</strong>al Commissi<strong>on</strong> for Nuclear Activities C<strong>on</strong>trol<br />
(CNCAN) c<strong>on</strong>firmed the licensee is able to support all the claims made in their "stress<br />
test" report and that any issues and opportunities for improvement arising from the stress<br />
test will be adequately addressed. This c<strong>on</strong>clusi<strong>on</strong> is supported also by the results of the<br />
peer review performed by a team of experts coming from the European Commissi<strong>on</strong> and<br />
several nuclear safety authorities from all across Europe. The "stress tests" included an<br />
assessment of the nuclear power plants' capabilities to cope with extreme natural hazards,<br />
such as bey<strong>on</strong>d design basis earthquakes and floods. This paper presents the results of the<br />
"stress tests" for Cernavoda nuclear power plant and the current status of the work<br />
performed by the Nati<strong>on</strong>al Commissi<strong>on</strong> for Nuclear Activities C<strong>on</strong>trol (CNCAN) to review<br />
safety in the light of the less<strong>on</strong>s learned from the Fukushima accident, with a focus <strong>on</strong> the<br />
protecti<strong>on</strong> against seismic events.<br />
Key words: nuclear power, nuclear safety, seismic hazard assessment, stress tests.<br />
51
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
SOME REMARKS ABOUT THE CLIMATE CHANGES IN SUB-<br />
ARCTIC SCANDINAVIA<br />
Dan C<strong>on</strong>stantinescu 1 , Christer J<strong>on</strong>ass<strong>on</strong> 2 , Annika Kristoferss<strong>on</strong> 2 ,<br />
Elena Sirbu 1<br />
1 University Politehnica of Bucharest,<br />
2 Abisko Scientific Research Stati<strong>on</strong>, Sweden<br />
Corresp<strong>on</strong>ding author: Dan C<strong>on</strong>stantinescu, dc<strong>on</strong>stantinescu@ecomet.pub.ro<br />
Abstract: Abisko Natural Reservati<strong>on</strong> is located in the Northern Sweden, about 200 km<br />
north from the Polar Circle, including <strong>on</strong> its territory the “Abisko Scientific Researcher<br />
Stati<strong>on</strong>”, an experienced stati<strong>on</strong> for the studies regarding the evoluti<strong>on</strong> of the climate<br />
changes. The stati<strong>on</strong> is located at, 68 o 28 ’ N, 18 o 28 ’ E, 385m above the sea level, <strong>on</strong> the<br />
shore of Lake Torneträsk. The authors of the article, presents remarks and results of two<br />
years observati<strong>on</strong>s and researches regarding climate data changes and impact <strong>on</strong> the<br />
envir<strong>on</strong>ment in the menti<strong>on</strong>ed area. Graphs and pictures obtained during the activity at the<br />
stati<strong>on</strong> in July and August 2009 and 2010 are included in the article. The structure of the<br />
proposed program for ANS is presented in figure 1.<br />
The paper presents results regarding evoluti<strong>on</strong> of the temperature, humidity and wind<br />
during the last hundred years as well as some effects of the climate changes <strong>on</strong> the<br />
envir<strong>on</strong>ment. The autors have in view the possibility to use the data for a modeling<br />
program regarding the c<strong>on</strong>vecti<strong>on</strong> and radiati<strong>on</strong> in the troposphere.<br />
The Programme<br />
Figure 1: The structure of the program and objectives for ANS<br />
Key words: climate changes, subarctic, temperature, air humidity, wind, rocks.<br />
52
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
GREENHOUSE GASES EMISSIONS <strong>FROM</strong> WASTEWATER<br />
TREATMENT PLANTS<br />
Doru Manea, Elena Manea, Dan Robescu<br />
Politehnica University of Bucharest, Department of Hydraulics, Hydraulic Machines and<br />
Envir<strong>on</strong>mental Engineering<br />
Corresp<strong>on</strong>ding author: Doru Manea, manea_doru@yahoo.com<br />
Abstract: One of the causes of climate change is the accumulati<strong>on</strong> of greenhouse gases,<br />
and <strong>on</strong>e of these greenhouse gases is methane (CH4), which absorbs some of the terrestrial<br />
infrared radiati<strong>on</strong>, otherwise this energy would disperse in outer space. Methane has an<br />
atmospheric lifetime of 9 to 15 years, and its ability to trap heat in Earth's atmosphere is 21<br />
times greater than carb<strong>on</strong> dioxide (CO2) per unit mass and in the same period of time.<br />
Because the lifetime of methane in the atmosphere is relatively short, about 12 years, it is a<br />
greenhouse gas with the potential to be kept under c<strong>on</strong>trol so that global warming is<br />
slowed. Also, to this objective can c<strong>on</strong>tribute the fact that methane itself has a high energy<br />
potential, so that its capture could bring benefits. Methane emissi<strong>on</strong>s are due to both<br />
natural and of anthropogenic sources and <strong>on</strong>e of these sources is the wastewater treatment,<br />
namely fermentati<strong>on</strong> of the sludge resulting from wastewater, resulting biogas which is<br />
c<strong>on</strong>taining a large amount of methane. The paper aims to study and show that in a<br />
wastewater treatment plant (WWTP), methane emissi<strong>on</strong>s in the atmosphere can be<br />
eliminated almost entirely. The optimal soluti<strong>on</strong> is anaerobic digesti<strong>on</strong> of sludge,<br />
collecti<strong>on</strong> of biogas produced, and using methane in the biogas for local producti<strong>on</strong> of<br />
energy required in the WWTP. Was m<strong>on</strong>itored power c<strong>on</strong>sumpti<strong>on</strong> of a WWTP, together<br />
with its producti<strong>on</strong> of biogas, was a calculated electrical and thermal energy need of the<br />
plant and compared with the energy potential of methane in the biogas obtained. Thus, it<br />
was evaluated that an important part of the energy demand of the plant may be covered by<br />
implementing a local soluti<strong>on</strong> to generate energy from burning the biogas. At least in<br />
largeWWTPs, implementati<strong>on</strong> of systems that produce biogas and use it to produce energy<br />
for own c<strong>on</strong>sumpti<strong>on</strong> is an important step towards c<strong>on</strong>trolling the level of methane in the<br />
atmosphere. By burning the biogas and by local producti<strong>on</strong> of energy the carb<strong>on</strong> footprint<br />
of energy c<strong>on</strong>sumpti<strong>on</strong> for WWTP is reduced, by increasing efficiency and eliminating<br />
waste installati<strong>on</strong>s power transmissi<strong>on</strong>.<br />
Key words: greenhouse, energy, wastewater, methane.<br />
53
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
ENVIRONMENTAL PROTECTION AND OPPORTUNITIES<br />
FOR HARNESSING JIU VALLEY'S HARD COAL ENERGETIC<br />
POTENTIAL<br />
Gheorghe Chiril 1 , Nicolae Ilias 2 , Sorin Mihai Radu 2 , Iosif Gruneantu 2 , Lucian<br />
Toma 2 , Oana Rotea 2 , Lucian Codreanu 2 , Maria Stefanie 2 , Sorin Copaescu 3<br />
1 CNH-SA<br />
2 University of Petrosani<br />
3 S.C. CONVERSMIN S.A. Bucureşti<br />
Corresp<strong>on</strong>ding author: Ilias Nicolae, iliasnic@yahoo.com<br />
Abstract: Harnessing the energetic potential of the hard coal stored in Jiu Valley's basin,<br />
estimated at about 800 milli<strong>on</strong> t<strong>on</strong>es, with an equivalent of over 420 milli<strong>on</strong> TEP for the<br />
balance reserves, and should represent a priority for any Nati<strong>on</strong>al Energy Strategy. Even<br />
though the new European legislati<strong>on</strong> sets drastic limitati<strong>on</strong>s for state interventi<strong>on</strong> in this<br />
area, there are real possibilities for valorizing this potential, in the c<strong>on</strong>text of an existing<br />
and coherent strategy assumed by all decisi<strong>on</strong>al parties involved and which would be set<br />
<strong>on</strong> increasing the efficiency of classic exploitati<strong>on</strong> and, <strong>on</strong> the other hand, <strong>on</strong> implementing<br />
unc<strong>on</strong>venti<strong>on</strong>al technologies for valorizing this resource.<br />
54
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
LINKING WATER ACCOUNTING TOOLS: WATER<br />
FOOTPRINT APPLICATION IN LIFE CYCLE ASSESSMENT<br />
Sim<strong>on</strong>a-Andreea Ene, Iulia Maria Comandaru, George Barjoveanu,<br />
Carmen Teodosiu<br />
Department of Envir<strong>on</strong>mental Engineering and Management, Faculty of Chemical Engineering and<br />
Envir<strong>on</strong>mental Protecti<strong>on</strong>,”Gheorghe Asachi” Technical University of Iasi, Romania<br />
Corresp<strong>on</strong>ding author: George Barjoveanu, gb@ch.tuiasi.ro<br />
Abstract: Water accounting tools are urgently needed as supporting instruments for<br />
decisi<strong>on</strong> making processes in water resources management at river basin level to address<br />
both quantitative and qualitative aspects. This paper approaches two such accounting<br />
instruments that have received much attenti<strong>on</strong> in the scientific community in the recent<br />
years: life cycle assessment and water footprint. Most of the efforts for the development of<br />
these two tools as water resources management instruments have mainly been targeted<br />
towards c<strong>on</strong>ceptualizati<strong>on</strong>, but there is still a need to understands how they can be<br />
employed in practice various stakeholders. Furthermore, there is a necessity am<strong>on</strong>g<br />
businesses for an increased operati<strong>on</strong>al efficiency, sustainable manufacturing, and the<br />
identificati<strong>on</strong> of different water-related risks, which could be improved by using these two<br />
proposed instruments. Life Cycle Assessment (LCA) takes into account the use of different<br />
types of natural resources and looks at different types of envir<strong>on</strong>mental impacts over the<br />
whole life cycle of various products. Unfortunately, water resources are viewed in most<br />
LCA studies merely as a transport medium for different other impact producers<br />
(pollutants) and do not take into account other aspects of water resources that are of high<br />
importance for water practiti<strong>on</strong>ers, like water availability. On the other side, the water<br />
footprint (WF), together with the other related instruments (i.e. ecological footprint, carb<strong>on</strong><br />
footprint and embodied energy studies) c<strong>on</strong>siders the perspective of <strong>on</strong>e particular resource<br />
or impact. From this point of view, it seems reas<strong>on</strong>able that the "footprints" to be<br />
c<strong>on</strong>sidered as indicators used in LCA and input-output impact studies. Linking these two<br />
types of instruments could be of great help in improving both assessment methods, the<br />
green, blue and grey WF of a product might be good indicators to assess the water related<br />
impacts in LCA studies. Another advantage of integrating the water footprints into LCA<br />
studies is that, they can be used to assess the water-related impacts (mostly availability<br />
issues) at local level, thus establishing the missing c<strong>on</strong>necti<strong>on</strong> between LCA and water<br />
resources management practice. C<strong>on</strong>clusively, WF accounting and sustainability<br />
assessment can provide to the LCA studies informati<strong>on</strong> as the evaluati<strong>on</strong> of a product WF<br />
might support the life cycle inventory for that product and the WF sustainability<br />
assessment might support the life cycle impact assessment. This work summarizes main<br />
findings of a literature review <strong>on</strong> methods to assess fresh water use in a life cycle<br />
assessment study. It provides LCA practiti<strong>on</strong>ers guidance in choosing an approach for<br />
c<strong>on</strong>ducting such studies given the current state-of-the-art. Finally, it outlines needs for<br />
further development in the methods currently available.<br />
Key words: impact assessment, life cycle assessment, water accounting tools, water footprint, water<br />
resources managemen<br />
55
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
MODIFFICATION OF GAMMA SPECTROSCOPY ENERGIES<br />
IN ENVIRONMENTAL RADIATIONS<br />
Marius Stamate 1 , Iuliana Mihaela Lazar 2 , Gabriel Lazar 1<br />
1 ”Vasile Alecsandri” University of Bacau, Department of Mechanical and Envir<strong>on</strong>mental<br />
Engineering<br />
2 ”Vasile Alecsandri” University of Bacau, Department of Chemical and Food Engineering<br />
Corresp<strong>on</strong>ding author: Marius Stamate, mstamate@ub.ro<br />
Abstract: M<strong>on</strong>itoring the envir<strong>on</strong>mental radioactivity is a very important issue, in relati<strong>on</strong><br />
to the protecti<strong>on</strong> of human health. This is especially the case when there is an accidental<br />
release of radioactivity into the envir<strong>on</strong>ment, as was the case with the Chernobyl and<br />
recently Fukushima accidents. Radi<strong>on</strong>uclides that can be found in the envir<strong>on</strong>ment may be<br />
divided in three groups: naturally occurring radi<strong>on</strong>uclides with very l<strong>on</strong>g half-life;<br />
naturally occurring Radi<strong>on</strong>uclides that have short half-lives <strong>on</strong> a geological time scale and<br />
Radi<strong>on</strong>uclides released into envir<strong>on</strong>ment by the human activity and accidents. The gamma<br />
ray spectroscopy is a powerful tool in order to m<strong>on</strong>itor the envir<strong>on</strong>mental radioactivity.<br />
Multichannel analysers have been used for m<strong>on</strong>itoring the gamma radiati<strong>on</strong> spectra <strong>on</strong> a<br />
daily basis over a l<strong>on</strong>g time. We have recorded during a 4 years period the gamma ray<br />
energy spectrum, and we have found that there are significantly differences between the<br />
compositi<strong>on</strong>s of the spectra. We have observed that the radioactivity spectrum changes<br />
suddenly and keep those characteristics over a l<strong>on</strong>g period. We have observed three such<br />
modificati<strong>on</strong>s and analyse the possible causes and effects.<br />
Keywords: gamma radi<strong>on</strong>uclides, envir<strong>on</strong>mental radioactivity.<br />
56
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
USING MULTIVARIATE STATISTICS AND GIS ON<br />
ASSESSING HEAVY METAL POLLUTION OF SOIL IN 22<br />
CITIES OF MOLDAVIA<br />
Ema Faciu 1 , Iulia Lazar 2 , Irina Ifrim 2 , Gabriel Lazar 1<br />
1 “Vasile Alecsandri” University of Bacau, Department of Mechanical and Envir<strong>on</strong>mental<br />
Engineering<br />
2 “Vasile Alecsandri” University of Bacau, Department of Chemical and Food Engineering<br />
Corresp<strong>on</strong>ding author: Gabriel Lazar, glazar@ub.ro<br />
Abstract: The knowledge of the regi<strong>on</strong>al variability for potential harmful elements in soil<br />
is of critical importance to assess the risks for human health. A series of data <strong>on</strong><br />
c<strong>on</strong>centrati<strong>on</strong> of heavy metals (Pb, Cd, Cr, Cu, Zn, Ni and Mn) in soil, were collected<br />
between years 2006 and 2011 from 22 cities bel<strong>on</strong>ging to the 8 counties of Moldavia.<br />
Geostatistical analysis and multivariate statistical analysis differently revealed correlati<strong>on</strong>s<br />
am<strong>on</strong>g the studied metals, complementing each other. Multivariate statistical analysis<br />
(Correlati<strong>on</strong> Analysis CA and Principal Comp<strong>on</strong>ent Analysis PCA) and spatial distributi<strong>on</strong><br />
showed distinctly different associati<strong>on</strong>s am<strong>on</strong>g the studied metals in different cases. There<br />
have been identified links with different intensities (low, medium and str<strong>on</strong>g) between the<br />
heavy metal c<strong>on</strong>centrati<strong>on</strong>s specific to each county in the analysis. High intensity links<br />
were identified between Pb and Cd in Galati county (R = 0.771, p = 0.000) and Pb and Zn<br />
in Neamt County (R = 0.538, p = 0.000). Our results indicated that the heavy metals, Cd,<br />
Ni, Pb were correlated with populati<strong>on</strong> density (e.g. Cd for Galati, (R = 0.448, p = 0.000),<br />
Ni for Neamt, (R = 0.552, p = 0.000), Pb for Vrancea, (R=-0.596, p = 0.000)). Further<br />
spatial analysis identified the specific factors and the main sources of polluti<strong>on</strong> in the<br />
analyzed area. The aim of Principal Comp<strong>on</strong>ent Analysis is to identify the number of<br />
independent variables of the dependent <strong>on</strong>es that best explain their variati<strong>on</strong>. Orthog<strong>on</strong>al<br />
rotati<strong>on</strong> determined the factorial structure. At the first PC1 factor the largest share was<br />
attributed to Mn (0.901), followed by Ni (0.809) and Cr (0.770). The establishment of<br />
more accurate correlati<strong>on</strong>s between the different heavy metals associated with anthrop<br />
activities or specific local parameters (e.g. populati<strong>on</strong> density) and possible multiple<br />
regressi<strong>on</strong> laws that govern them can predict the dynamics of their c<strong>on</strong>centrati<strong>on</strong> in time<br />
and the possible effect <strong>on</strong> human health.<br />
Keywords: multivariate statistics, GIS, soil, heavy metals.<br />
57
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
RISK OF PHOTOINHIBITION ON BRASSICA NAPUS<br />
GROWTH UNDER SOLAR RADIATION CORRELATE WITH<br />
STRUCTURAL CHANGES OF INFRARED MOLECULAR<br />
SPECTRUM IN LIPIDS<br />
Iuliana Lazar 1 , Daniela Nicuta 2 , Irina Ifrim 1 , Marius Stamate 3 , Gabriel Lazar 3<br />
1 ”Vasile Alecsandri” University of Bacău, Department of Chemical and Food Engineering<br />
2 ”Vasile Alecsandri” University of Bacău, Department of Biology, Ecology and Envir<strong>on</strong>mental<br />
Protecti<strong>on</strong><br />
3 ”Vasile Alecsandri” University of Bacău, Department of Mechanical and Envir<strong>on</strong>mental<br />
Engineering<br />
Corresp<strong>on</strong>ding author Gabriel Lazar, glazar@ub.ro<br />
Abstract: Biophysical and biochemical processes occurring at the cellular level are<br />
influenced by electric fields and potential differences in the membrane induced by external<br />
radiati<strong>on</strong>. The exposure to UV radiati<strong>on</strong> determines changes in the metabolism, within the<br />
growth and development processes, having positive or negative influences <strong>on</strong> plant health<br />
and vitality. Molecular bases of these changes occurred after irradiati<strong>on</strong>s are not yet fully<br />
known. Resp<strong>on</strong>ses can be caused by direct effects of UV radiati<strong>on</strong> <strong>on</strong> essential comp<strong>on</strong>ents<br />
and membranes cellular under the acti<strong>on</strong> of free radicals, reducing mRNA transcripti<strong>on</strong><br />
and effects <strong>on</strong> protein synthesis and enzymatic activity. There are many studies c<strong>on</strong>cerning<br />
the effect of n<strong>on</strong>i<strong>on</strong>izing radiati<strong>on</strong> <strong>on</strong> plants but little is known about the effect of solar<br />
radiati<strong>on</strong> and structural changes of the functi<strong>on</strong>al groups associated with lipid structure in<br />
Brassica napus seed and allometric exp<strong>on</strong>ent variati<strong>on</strong>. The purpose of this study is to<br />
analyze different rapeseed samples in order to identify the molecular vibrati<strong>on</strong> differences<br />
of biomolecules according to solar radiati<strong>on</strong> effect. In our investigati<strong>on</strong> selected canola<br />
seeds were exposed to UV doses by a high pressure discharge lamp with a visible light<br />
similar to that of sunlight and corresp<strong>on</strong>ding to an exhibiti<strong>on</strong> of 160, 280 and 460 minutes.<br />
A relatively simple, reproducible, n<strong>on</strong>destructive vibrati<strong>on</strong>al technique FTIR spectroscopic<br />
investigate the biological tissues of rapeseed to provide the molecular-level informati<strong>on</strong><br />
allowing investigati<strong>on</strong> of functi<strong>on</strong>al groups, b<strong>on</strong>ding types, and molecular c<strong>on</strong>formati<strong>on</strong>s.<br />
A n<strong>on</strong>linear least squares fitter based <strong>on</strong> the Levenberg<strong>–</strong>Marquardt algorithm was used for<br />
curve fitting. Multivariate molecular spectral analyses were able to make correlati<strong>on</strong><br />
between the different lipid functi<strong>on</strong>al groups, and irradiati<strong>on</strong> treatment and ph<strong>on</strong>otypical<br />
parameters. The Pears<strong>on</strong> coefficient reveals a negative lower correlati<strong>on</strong> between<br />
asymmetric ratio and allometric scale (R=-0.485; p=0.000) and a negative medium<br />
correlati<strong>on</strong> between symmetric ratio and allometric scale (R=-0.631; p=0.000). Under solar<br />
radiati<strong>on</strong> statistical differences in rapeseed lipid of the CH3 and CH2 asymmetric and<br />
symmetric stretching regi<strong>on</strong>s in terms of the peak height were found. These results signify<br />
that UV-VIS l<strong>on</strong>g time exposure has a significant impact <strong>on</strong> lipid feature according to<br />
allometric exp<strong>on</strong>ent variati<strong>on</strong>.<br />
Key words: solar radiati<strong>on</strong>; rapeseed; infrared; lipid; allometric scaling; paired-sample T-test.<br />
58
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
MATHEMATICAL MODELS DESIGNED TO ASSESS THE<br />
RISK SITUATIONS CREATED BY RIVER FLOWS<br />
Gabriel Murariu 1 , Mirela Praisler 1 , Stefanut Ciochina 1 , Atanasia Stoica 2<br />
1 “Dunarea de Jos” University of Galati, Department of Chemistry, Physics and Envir<strong>on</strong>ment<br />
2 Institute of Architecture and Urbanism “I<strong>on</strong> Mincu” Bucharest, Department of Urban Planning<br />
Corresp<strong>on</strong>ding author: Mirela Praisler, Mirela.Praisler@ugal.ro<br />
Abstract: In modern investigati<strong>on</strong>s theoretical approaches are used to obtain the<br />
mathematical model characterizing or forecasting the envir<strong>on</strong>mental systems or processes.<br />
In general, the dynamics of the system are deeply n<strong>on</strong>linear, complex or unknown.<br />
Generally speaking, such complex structure is a set of interc<strong>on</strong>nected comp<strong>on</strong>ents. The<br />
comm<strong>on</strong> approach is therefore to start from measurements of the behavior of the system<br />
and the external influences (inputs) and to determine the mathematical correlati<strong>on</strong> between<br />
the influencing factors without going into the details of what is actually happening inside<br />
the system. In this paper we are discussing, in a comparative way, a n<strong>on</strong>-linear water flood<br />
assessment made in a very sensitive area of the Siret River regi<strong>on</strong>. A series of numerical<br />
simulati<strong>on</strong>s for different fluid models are presented. They were obtained by using<br />
historical recorded data sets and computati<strong>on</strong>al fluid dynamics tools. The numerical<br />
approach was chosen in order to build a specific model for water flow evaluati<strong>on</strong>. This<br />
c<strong>on</strong>diti<strong>on</strong> is necessary for predicti<strong>on</strong> and it is the first step towards obtaining a Decisi<strong>on</strong><br />
Support System (DSS) in the area.<br />
Key words: computati<strong>on</strong>al fluid dynamics, n<strong>on</strong>-linear assessment.<br />
59
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
DATA INCOHERENCE FOR COMBINATORIAL<br />
OPTIMIZATION PROBLEMS<br />
Gloria Cerasela Crisan 1 , Camelia-M. Pintea 2 , Camelia Chira 3<br />
1 “Vasile Alecsandri” University of Bacau, Department of Mathematics, Informatics and Educati<strong>on</strong><br />
Sciences<br />
2 Tech Univ Cluj-Napoca, North Univ Center Baia-Mare, Faculty of Science<br />
3 “Babeş-Bolyai” University of Cluj-Napoca, Department of Computer Science<br />
Corresp<strong>on</strong>ding author: Gloria Cerasela Crisan, ceraselacrisan@ub.ro<br />
Abstract: Data collecti<strong>on</strong>s are fundamental in taking correct and <strong>on</strong> time decisi<strong>on</strong>s. In risk<br />
management, the coherence and the integrity of the problem’s data have great impact <strong>on</strong><br />
the quality of the decisi<strong>on</strong>. If the data are biased, the applicati<strong>on</strong>s that assist the manager<br />
can provide poor advices. The real-life problems reflect the complexity and heterogeneity<br />
of our modern society. The applicati<strong>on</strong>s designed for solving them are therefore expensive,<br />
sophisticated and complex; inherently their results are hard to predict. This is why the<br />
influence of the data incoherence over the results is an extremely important issue to<br />
c<strong>on</strong>sider. The a-priori knowledge and its efficient handling are compulsory for modern,<br />
proactive strategy in problem solving. Knowing how a specific algorithm would behave<br />
when input data might be incoherent may help choosing between several algorithms athand<br />
to better deal with real-world problems. We here approach the influence of<br />
incoherent input data when solving Combinatorial Optimizati<strong>on</strong> Problems (COPs). Several<br />
new COP variants are defined and the stability of the corresp<strong>on</strong>ding solving methods under<br />
imperfect input data is investigated. Some parameters are defined and a parameterized<br />
complexity study is performed. Numerical experiments engage the well-known COP<br />
Travelling Salesman Problem in its standard form and a dynamic variant (with and without<br />
errors in the input data for both problem variants). All the problems are solved using Ant<br />
Col<strong>on</strong>y Optimizati<strong>on</strong> algorithms, a biologically-inspired metaheuristic approach. The<br />
adaptati<strong>on</strong> and the resilience of natural systems (Darwinian evoluti<strong>on</strong>, ant col<strong>on</strong>y<br />
behaviour) suggest the same behaviour. We use a natural incoherence measure and we<br />
compare the applicati<strong>on</strong>s results <strong>on</strong> correct and incoherent data. We modify the algorithms<br />
in order to store both the correct and the incoherent data. We extend our numerical<br />
experiments by coupling a new imperfecti<strong>on</strong> dimensi<strong>on</strong>: the uncertainty. The algorithms’<br />
behaviour does not have a pattern: we observe stable, unstable, even catastrophic effects of<br />
input data incoherence. The paper generalizes a metaheuristic approach to a classical<br />
optimizati<strong>on</strong> problem when the data entry has some degree of incoherence.<br />
Key words: combinatorial optimizati<strong>on</strong> problems, parameterized complexity, data incoherence,<br />
heuristics, ant col<strong>on</strong>y optimizati<strong>on</strong>.<br />
60
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
<strong>RISKS</strong> RELATED TO EXTRACTION OF MINERALS<br />
AGGREGATES <strong>FROM</strong> RIVERS<br />
Stelian Cartacuzencu, Gabriel Lazar<br />
“Vasile Alecsandri” University of Bacau, Department of Envir<strong>on</strong>mental Engineering and<br />
Mechanical Engineering<br />
Corresp<strong>on</strong>ding author: Stelian Cartacuzencu, stelian_cartacuzencu@yahoo.com<br />
Abstract: Exploitati<strong>on</strong> of mineral aggregates, mainly for roadbed and c<strong>on</strong>crete, must assure<br />
the protecti<strong>on</strong> of envir<strong>on</strong>ment factors and water quality, avoid of degradati<strong>on</strong> of reserves<br />
and reducti<strong>on</strong> of losses. Before starting the extracti<strong>on</strong> process, the perimeters are delimited<br />
by boundaries whose overcome is not allowed. For the beginning the scraping is d<strong>on</strong>e to<br />
remove the superficial layer of earth. The leached material is usually used to restore the<br />
operati<strong>on</strong> road through which the perimeter is accessed. Extracti<strong>on</strong> is d<strong>on</strong>e from the water<br />
to shore, in l<strong>on</strong>gitudinal strips in c<strong>on</strong>tinuously field. Excavated material is loaded directly<br />
into transportati<strong>on</strong> vehicles or temporary storage deposits that not exceed the requirements<br />
of the working time of the day are made. By exploiting the mineral aggregates is desirable<br />
to assure the proper flow of rivers. After the reserves are depleted the working site is<br />
dismantled and the area is leveled to simulate the typical meadow landscape. Exploitati<strong>on</strong><br />
should be evaluated also in terms of flood management strategy. Operati<strong>on</strong>s should be<br />
performed by clogging and redesign the river bed in functi<strong>on</strong> of the influence of mineral<br />
aggregates exploitati<strong>on</strong>. For proper exploitati<strong>on</strong> the m<strong>on</strong>itoring process should be applied<br />
during mineral aggregates exploitati<strong>on</strong>, and the management decisi<strong>on</strong>s must be taken in<br />
order to promote perimeter regenerati<strong>on</strong>. During the flood the acti<strong>on</strong>s will comply with the<br />
anti-flood plan and after, the perimeter will be cleansed by any materials brought by the<br />
flood. The preferential exploitati<strong>on</strong> and the intermediate deposits that cannot be<br />
transported in <strong>on</strong>e day having as effect creati<strong>on</strong> of artificial elbow sand changes of river’s<br />
flow directi<strong>on</strong> are some negative aspects regarding the management of mineral aggregates.<br />
The influence of the effects of faulty operati<strong>on</strong> may impact breaks of banks, increased<br />
leachate thickness, increasing intensity of fluid erosi<strong>on</strong>, and even flood stimulati<strong>on</strong>. This<br />
paper shows the comparis<strong>on</strong> of two exploitati<strong>on</strong> cases: <strong>on</strong>e made following the standards<br />
and other made in a faulty manner. The study wants to emphasize the need for good<br />
management of mineral aggregates, through a c<strong>on</strong>trolled process, in order to not brutally<br />
affect the envir<strong>on</strong>ment.<br />
Key words: explorati<strong>on</strong>, mineral aggregate, rivers flow, landscape, m<strong>on</strong>itoring.<br />
61
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
IN SITU SOIL FLUSHING <strong>–</strong> STUDIES ON YIELD OF<br />
POLLUTED REMEDIATION SANDY SOILS WITH ORGANIC<br />
COMPOUNDS ACIDS<br />
Alexandra-Dana Chitimus, Valentin Nedeff, Emilian Mosnegutu<br />
“Vasile Alecsandri” University of Bacau, Department of Envir<strong>on</strong>mental Engineering and<br />
Mechanical Engineering<br />
Corresp<strong>on</strong>ding author: Alexandra-Dana Chiţimuş, dana.chitimus@ub.ro<br />
Abstract: Producti<strong>on</strong> activities have affected soils in time, by means of: mining,<br />
excavati<strong>on</strong>s, waste deposits, landslides, erosi<strong>on</strong>, salting, acidificati<strong>on</strong> etc. Currently, at an<br />
internati<strong>on</strong>al level, approximately 20 % of the soils are acidified, and in Romania there are<br />
approximately 2 milli<strong>on</strong> hectares. The soil depolluti<strong>on</strong> process is very complex due to the<br />
great number of factors which influence it, such as:<br />
- properties of the soil, of geological formati<strong>on</strong>s or of subterraneous waters;<br />
- pollutant’s properties;<br />
- properties of the media with which the pollutant interacts.<br />
After permeating the geological medium, pollutants go through some phenomena related<br />
to: transport, transformati<strong>on</strong>, transfer, accumulati<strong>on</strong> and fixati<strong>on</strong>. These phenomena<br />
c<strong>on</strong>tribute to the spreading within, and distributi<strong>on</strong> of, pollutants in the elements of the<br />
geological envir<strong>on</strong>ment and to the alterati<strong>on</strong> of the chemical structure of the geological<br />
medium. Techniques for the treatment of polluted soils have as an objective the<br />
destructi<strong>on</strong>, eliminati<strong>on</strong> or immobilizati<strong>on</strong> of pollutants. Depolluti<strong>on</strong> techniques can be<br />
classified depending <strong>on</strong> the nature of procedures employed, as follows:<br />
- physical procedures, which c<strong>on</strong>sist in the extracti<strong>on</strong> of the pollutant from the<br />
c<strong>on</strong>taminated envir<strong>on</strong>ment;<br />
- biological procedures, which make use of microorganisms acti<strong>on</strong>s in order to eliminate<br />
organic or mineral pollutants present in soil, silt, sediments or liquid effluents;<br />
- thermal procedures, in which heat is used so as to neutralize the pollutant, to isolate it,<br />
or to make it inert.<br />
- chemical or electrochemical procedures using the chemical properties of pollutants in<br />
order to make them inert, to destroy, or to separate from the polluted envir<strong>on</strong>ment with<br />
the help of adapted reacti<strong>on</strong>s.<br />
For a soil remediati<strong>on</strong> installati<strong>on</strong> functi<strong>on</strong> <strong>on</strong> the principle soil flushing in situ for ensure a<br />
high degree of treatment must be correctly identified correlati<strong>on</strong>s between: soil properties<br />
that influence the treatment process, structural characteristics of the installati<strong>on</strong> of<br />
remediati<strong>on</strong> and work factors. The theoretical and experimental research of the soil<br />
depolluti<strong>on</strong> process presented in this dissertati<strong>on</strong> c<strong>on</strong>stitute an attempt to offer, by means<br />
of detailed analysis, the c<strong>on</strong>structive and functi<strong>on</strong>al relati<strong>on</strong>s of dependence which can set<br />
the basis of new depolluti<strong>on</strong> installati<strong>on</strong>s, created by way of modernizing the old <strong>on</strong>es, or<br />
by devising new models, models which should be competitive with internati<strong>on</strong>al <strong>on</strong>es.<br />
Keywords: remediati<strong>on</strong> of soil, organic acid compounds, in situ soil flushing, yield.<br />
62
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
RESEARCH ON THE HEAT BALANCE COMPONENTS OF A<br />
SMALL SBR BASIN USED FOR DOMESTIC WASTEWATER<br />
TREATMENT<br />
Narcis Barsan, Valentin Nedeff<br />
“Vasile Alecsandri” University of Bacau, Department of Envir<strong>on</strong>mental Engineering and<br />
Mechanical Engineering<br />
Corresp<strong>on</strong>ding author: Narcis Barsan, narcis.barsan@ub.ro<br />
Abstract: In the nati<strong>on</strong>ally and internati<strong>on</strong>ally c<strong>on</strong>text, the problem of wastewater<br />
treatment is no l<strong>on</strong>ger seen as a specific objective for urban agglomerati<strong>on</strong>s and<br />
industrialized areas. Thus, the two general methods of wastewater treatment in centralized<br />
or decentralized systems remain complementary in solving envir<strong>on</strong>mental polluti<strong>on</strong><br />
problems due to wastewater. In Romania, over 40 % of the populati<strong>on</strong> lives in rural areas<br />
where wastewater infrastructures are poor or missing. Development of infrastructure in<br />
water supply and sewerage is essential for improving living c<strong>on</strong>diti<strong>on</strong>s and human health.<br />
To solve the problem of domestic wastewater treatment in the areas where can be<br />
implemented <strong>on</strong>ly decentralized sewage treatment systems, can be used the compact<br />
installati<strong>on</strong> that operating by Sequencing Batch Reactor (SBR) process. Unlike the<br />
c<strong>on</strong>venti<strong>on</strong>al biological mechanical wastewater treatment systems, in which the process<br />
(aerobic and/or anaerobic) is divided into several basins, the treatment system that uses the<br />
SBR process divide the treatment process by working times. Thus the compact installati<strong>on</strong><br />
that uses SBR process is the most effective alternative to the c<strong>on</strong>venti<strong>on</strong>al wastewater<br />
treatment with low flow. To ensure a high degree of treatment in the small treatment plants<br />
which operates by SBR process is essential to identify the correlati<strong>on</strong>s between qualitative<br />
and quantitative characteristics of the influent, treatment system c<strong>on</strong>structi<strong>on</strong><br />
characteristics and working factors. The main directi<strong>on</strong> of research aims to identify the<br />
mathematical equati<strong>on</strong>s that describe the heat balance for a Sequencing Batch Reactor<br />
(SBR) used in a small municipal wastewater treatment plant. Also in this research the<br />
theoretical model was correlated with the numerical values obtained in 30 days of<br />
measurements and m<strong>on</strong>itoring of a small wastewater treatment plant use to treat real<br />
municipal wastewater. The installati<strong>on</strong> used in this research was used in real c<strong>on</strong>diti<strong>on</strong> to<br />
obtain the values as close to reality for the comp<strong>on</strong>ent of the heat balance.<br />
Key words: wastewater treatment, sequencing batch reactor, heat balance.<br />
63
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
EXPERIMENTING RIGID AND ELASTIC CLAMPING<br />
METHODS OF ACOUSTIC SCREENS<br />
Claudia Tomozei, Valentin Nedeff, Mirela Panainte, Gabriela Andrioai<br />
“Vasile Alecsandri” University of Bacau, Department of Envir<strong>on</strong>mental Engeneering and<br />
Mechanical Engeneering<br />
Corresp<strong>on</strong>ding author: Tomozei Claudia, claudia.tomozei@ub.ro<br />
Abstract: Noise transmissi<strong>on</strong> in enclosures can be c<strong>on</strong>trolled by treating the acoustic<br />
enclosures in such a way as to limit inside and outside sound propagati<strong>on</strong>. The industrial<br />
noise can be c<strong>on</strong>trolled either by eliminating noise generating factors or by using<br />
soundproofing materials to attenuate noise <strong>on</strong> propagati<strong>on</strong> pathways. The attenuati<strong>on</strong> of<br />
acoustic wave propagati<strong>on</strong> in industrial envir<strong>on</strong>ments is a very important issue that may be<br />
studied in different envir<strong>on</strong>ments and may receive different soluti<strong>on</strong>s. One way to<br />
attenuate sound pressure level/ SPL propagati<strong>on</strong> is by using acoustic screens.<br />
This article investigates two methods of noise reducti<strong>on</strong> in industrial enclosures with the<br />
help of acoustic screens which are composed of multiple walls. The results of the<br />
experiments are charted and presented in the paper. The proposed method c<strong>on</strong>sisted in<br />
using work variants that presuppose the rigid and elastic clamping of the walls to the<br />
metallic frame.The rigid clamping was d<strong>on</strong>e by using screws to attach the walls to the<br />
metal while the elastic <strong>on</strong>e was d<strong>on</strong>e by attaching the walls to the metal with the help of<br />
sanitary silic<strong>on</strong>e.Acoustic screens were made of OSB (Oriented Strand Board), a material<br />
available for use in both clamping modalities.The experiments were performed for two<br />
types of wall positi<strong>on</strong>ing, a variant with three walls and cover and a variant with five walls<br />
(cabin). The two variants were chosen because the number of walls was useful in<br />
identifying the differences between the values of the sound pressure level for both types of<br />
experiments.The results obtained at the end of the experiments showed better values for<br />
the rigid clamping of walls, with a reducti<strong>on</strong> in the sound pressure level of up to 3 dB.The<br />
differences between the values of sound pressure level for the two types of clamping were<br />
quite small, sometimes minor.<br />
Key words: industrial noise, acoustic screen, rigid clamping, elastic clamping.<br />
64
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
COMPARATIVE STUDY VIEWING THE EFFICIENCY OF<br />
THE GRANULAR FILTERS DEPENDING ON THE TYPE OF<br />
THE FILTER MATERIAL<br />
Oana (Irimia) Tirtoaca, Valentin Nedeff, Mirela Panainte<br />
“Vasile Alecsandri” University of Bacau, Department of Envir<strong>on</strong>mental Engineering and<br />
Mechanical Engineering<br />
Corresp<strong>on</strong>ding author: Tirtoaca (Irimia) Oana, oana.tartoaca@ub.ro<br />
Abstract: Water’s quality can be defined through a series of properties that limit the<br />
water’s exploitati<strong>on</strong>. In order to accomplish the accordance with quality standards required<br />
for a specific demand (potable water, industrial water of different categories, ultrapure<br />
water), the c<strong>on</strong>tinental surface water is treated through a sequence of operati<strong>on</strong>s and unit<br />
processes. The technological installati<strong>on</strong> of treatment accomplishes, partially or totally, the<br />
disposal of the pollutants, every treatment proceeding being used for improving <strong>on</strong>e or<br />
more qualitative parameter. The chosen treatment proceeding is specific to the type of the<br />
alimentati<strong>on</strong> source and to the followed purpose (the producti<strong>on</strong> of the potable water, of<br />
industrial water for different categories). One of the basic proceedings for treating water is<br />
represented by the mechanical filtrati<strong>on</strong> of the water. The operati<strong>on</strong> of filtering is<br />
influenced by a series of parameters, from which, the <strong>on</strong>es characteristic to the filter layer<br />
have a very special importance: nature, surface, thickness, pores dimensi<strong>on</strong>, the shape of<br />
the granular particles, hydrodynamic resistance, chemical resistance, mechanical<br />
resistance. The present paper aims to identify the type of granular filtering material that has<br />
the highest degree of retenti<strong>on</strong> c<strong>on</strong>cerning the storage of the solid particles. For<br />
discharging the solid suspensi<strong>on</strong>s that are found in water in c<strong>on</strong>centrati<strong>on</strong>s between 5 <strong>–</strong> 50<br />
mg/L, granular filtering materials are the most used (quartz sand, anthracite, perlite, barite,<br />
granate). In order to accomplish the experiments (the separati<strong>on</strong> of the liquid <strong>–</strong> solid<br />
mixture) were carried out studies for three types of filtering materials with granular shape<br />
particles, respectively: quartz sand, perlite and anthracite. Using this types of materials<br />
were c<strong>on</strong>stituted granular filters with different thicknesses and the water passed through<br />
these filters with different intake flows in order to be filtrated. From the experiments<br />
accomplished for the three types of filtering materials it was identified the type of granular<br />
filtering material with the highest degree of retenti<strong>on</strong> in water’s mechanical filtering<br />
process.<br />
Key words: potable water, water’s mechanical treatment, filtrati<strong>on</strong>, filter materials.<br />
65
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
STUDY UPON THE ADVANTAGES OF PREDICTIVE<br />
MAINTENANCE IN MONITORING OF ROLLING BEARINGS<br />
Dumitru-Cristinel Nadabaica, Valentin Nedeff, Luminita Bibire, Gabriela<br />
Andrioai<br />
“Vasile Alecsandri” University of Bacau, Department of Envir<strong>on</strong>mental Engineering and<br />
Mechanical Engineering<br />
Corresp<strong>on</strong>ding author: Dumitru-Cristinel Nadabaica, nadabaica.dumitru@ub.ro<br />
Abstract: This paper presents a theoretical study of the applicati<strong>on</strong> of vibrati<strong>on</strong> envelope<br />
technique in the diagnosis of rolling bearings with the purpose of estimating their<br />
remaining lifetime and of determining the most advantageous time to perform the<br />
replacement of rolling bearings in the maintenance activity. Rolling bearings are the most<br />
comm<strong>on</strong> comp<strong>on</strong>ents of dynamic equipments and they are also the most sensitive to<br />
stresses during operati<strong>on</strong>. The increasing of level vibrati<strong>on</strong> c<strong>on</strong>tributes to the reducti<strong>on</strong> of<br />
the rolling bearings lifetime. The envelope is a technique of vibrati<strong>on</strong> signal processing<br />
which is required for the extracti<strong>on</strong> of the defect characteristic frequency from the<br />
frequency spectrums. By using the envelope technique the premature wear of rolling<br />
bearings can be m<strong>on</strong>itored. Rolling bearings are predisposed to a premature wear due to<br />
the executi<strong>on</strong> and mounting quality, to the loading c<strong>on</strong>diti<strong>on</strong>s during operati<strong>on</strong>, to the very<br />
numerous cycles of operati<strong>on</strong> etc. The premature wear is manifested by:<br />
1. the generati<strong>on</strong> of noise (noise polluti<strong>on</strong>);<br />
2. the loss of lubricant (high c<strong>on</strong>sumpti<strong>on</strong> of raw materials, envir<strong>on</strong>mental polluti<strong>on</strong>);<br />
3. the failure of other comp<strong>on</strong>ents (leading to the out of use of the rolling bearing, in a<br />
premature stage, which means both supplementary c<strong>on</strong>sumpti<strong>on</strong> of materials and energy<br />
for producing new comp<strong>on</strong>ents, and indirectly for increasing the amount of waste);<br />
4. extra energy c<strong>on</strong>sumpti<strong>on</strong> (<strong>on</strong>e third of all energy is c<strong>on</strong>sumed to defeating of unwanted<br />
fricti<strong>on</strong>).<br />
This study also presents the benefits of the predictive maintenance applicati<strong>on</strong> in direct<br />
c<strong>on</strong>necti<strong>on</strong> to the minimizati<strong>on</strong> of waste quantities and to the envir<strong>on</strong>mental polluti<strong>on</strong>. In<br />
the same time, by c<strong>on</strong>diti<strong>on</strong> m<strong>on</strong>itoring and diagnostic of process equipment, the<br />
predictive maintenance has an important role about costs of maintenance activity because<br />
<strong>on</strong>e third of these costs are lost because the applicati<strong>on</strong> of improper or unnecessary<br />
maintenance. Damages made by an improper maintenance can cause disasters at a large<br />
scale, having negative c<strong>on</strong>sequences for people and for the envir<strong>on</strong>ment.<br />
Keywords: predictive maintenance, enveloping technique of vibrati<strong>on</strong>, noise polluti<strong>on</strong>, minimizati<strong>on</strong><br />
of waste quantities, c<strong>on</strong>sumpti<strong>on</strong> of materials and energy.<br />
66
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
STUDIES AND RESEARCH ON THE INFLUENCE OF THE<br />
CLIMATIC FACTORS ON AMMONIA POLLUTION IN<br />
BACAU<br />
Doina Capsa 1 , Valentin Nedeff 2 , Mirela Panainte 2 ,<br />
Narcis Barsan 2<br />
1 Regi<strong>on</strong>al weather forecasting service Bacau<br />
2 “Vasile Alecsandri" University of Bacau, Department of Envir<strong>on</strong>mental Engineering and<br />
Mechanical Engineering<br />
Corresp<strong>on</strong>ding author: Capsa Doina, doina_capsa@yahoo.com<br />
Abstract: Air polluti<strong>on</strong> occurs after eliminati<strong>on</strong> in the air, especially over large urban areas,<br />
of three categories of substances: gas (carb<strong>on</strong> dioxide, carb<strong>on</strong> m<strong>on</strong>oxide, unburned<br />
hydrocarb<strong>on</strong>s, hydrogen sulphide, sulfur dioxide, amm<strong>on</strong>ia, fluorine, and chlorine),<br />
particulate matter and oxides metals (Pb, Hg and others). The quality of the air in the urban<br />
areas it depends especially <strong>on</strong> the type and the size of the industrial activities, the intensity<br />
of the traffic, and the quality of waste management both domestic and industrial. Besides<br />
these factors we could add the populati<strong>on</strong> density, the size and the quality of the open<br />
spaces, the geographical and climatologically c<strong>on</strong>diti<strong>on</strong>s. In Bacau County the air quality<br />
is c<strong>on</strong>tinuous m<strong>on</strong>itored by measurements of three automatic stati<strong>on</strong>s located in areas<br />
representative of the types of existing stati<strong>on</strong>s. This m<strong>on</strong>itoring system was implemented<br />
by Romanian Nati<strong>on</strong>al Agency for Envir<strong>on</strong>mental Protecti<strong>on</strong> to measure the variable<br />
values of the principal pollutants from air. These types of systems are in c<strong>on</strong>cordance with<br />
nati<strong>on</strong>al legislati<strong>on</strong> <strong>on</strong> protecti<strong>on</strong> of the atmosphere and comply with the requirements of<br />
European regulati<strong>on</strong>s. Using the data from the meteorological stati<strong>on</strong> in Bacau and the<br />
reports of the Regi<strong>on</strong>al Agency for Envir<strong>on</strong>mental Protecti<strong>on</strong> Bacau, the influence of the<br />
climatic factors is analyzed under the maximum allowable limits that are exceeded for<br />
amm<strong>on</strong>ia. The main source of the amm<strong>on</strong>ia air polluti<strong>on</strong> in the city of Bacau is the industry<br />
but we also have the intensive animal breeding. The scope of the polluti<strong>on</strong> accidents is<br />
given by the variati<strong>on</strong> in time of the climatic factors, that can promote rapid dispersi<strong>on</strong> of<br />
the pollutant, and thus reducing the negative effects but they can adversely affect air<br />
quality. Excesses of the limit value of 0,3 mg\m 3 NH3 with values of 10 - 100 % they are<br />
persisted in air in different life times according to the different meteorological c<strong>on</strong>diti<strong>on</strong>s.<br />
The mesoscale analysis of the climatic factors in terms of an excess of 10 till 100 the<br />
maximum permissible value of the pollutant lead to the c<strong>on</strong>clusi<strong>on</strong> that the intensity and<br />
the wind directi<strong>on</strong>, the air temperature, the gradient barre and the weather, the fog and the<br />
precipitati<strong>on</strong>s are factors that determine the variati<strong>on</strong> amount pollutant in time.<br />
Key words: air polluti<strong>on</strong>, m<strong>on</strong>itoring system, amm<strong>on</strong>ia air polluti<strong>on</strong>, climatic factors.<br />
67
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
STUDIES AND RESEARCH ON THE DETERMINATION OF<br />
HEAVY METALS <strong>FROM</strong> THE BANKS OF THE<br />
SIRET RIVER BASIN<br />
Cristian Radu 1 , Valentin Nedeff 2 , Narcis Barsan 2 , Anca Dumitrescu 3<br />
1 “Romanian Waters” Nati<strong>on</strong>al Administrati<strong>on</strong> Siret Branch<br />
2 “Vasile Alecsandri" University of Bacau, Department of Envir<strong>on</strong>mental Engineering and<br />
Mechanical Engineering<br />
3 “Alexandru Ioan Cuza” University of Iasi<br />
Corresp<strong>on</strong>ding author: Radu Cristian, cristofor_radu@yahoo.com<br />
Abstract: By its characteristics, the soil is the main “reservoir” of most substances with<br />
polluti<strong>on</strong> risk. Soil polluti<strong>on</strong> can be produced by a number of substances which have a<br />
disruptive acti<strong>on</strong> for a shorter or l<strong>on</strong>g time. Polluti<strong>on</strong> with effects <strong>on</strong> l<strong>on</strong>g period of time is<br />
known as residual polluti<strong>on</strong>. It c<strong>on</strong>cerns at period in which harmful substances remain<br />
(persist) in soil degrading him to clean up and restoring are impossible. Depending <strong>on</strong><br />
extend, residual polluti<strong>on</strong> may influence the natural cycles, dynamics and compositi<strong>on</strong> of<br />
the hydrosphere and atmosphere, biosphere etc., with major socio-ec<strong>on</strong>omic implicati<strong>on</strong>s.<br />
The substances with the highest risk of residual polluti<strong>on</strong> for all envir<strong>on</strong>mental factors and<br />
populati<strong>on</strong> are heavy metals. In Romania, the residual effect of polluti<strong>on</strong> with heavy metals<br />
is a major envir<strong>on</strong>mental problem. This is due to ec<strong>on</strong>omic activities which were<br />
c<strong>on</strong>ducted and/or carried out. For m<strong>on</strong>itoring envir<strong>on</strong>mental quality and the c<strong>on</strong>tent of<br />
heavy metals have developed a number of methods based <strong>on</strong> sampling techniques, sample<br />
preparati<strong>on</strong> and analysis. Because the human settlements and the main ec<strong>on</strong>omic activities<br />
are developed mainly <strong>on</strong> a watercourse, this paper analyzes the c<strong>on</strong>tent of heavy metals<br />
from alluvial sediment and banks Siret Basin respectively. Sediments are known as<br />
”reservoirs” of elements in aquatic systems and is recognized as <strong>on</strong>e of the largest sources<br />
of polluti<strong>on</strong>. Sediments accumulate different types of pollutants. By analyzing of<br />
sediments can obtain informati<strong>on</strong> about various transport phenomena, transformati<strong>on</strong> and<br />
recovery of pollutants. Also, analysis of sediments can be a means to achieve<br />
rec<strong>on</strong>structi<strong>on</strong> of historical changes (natural or anthropogenic) that have occurred over the<br />
time and understanding anthropogenic impact <strong>on</strong> natural ecosystems. Research focused <strong>on</strong><br />
certain secti<strong>on</strong>s (points) of m<strong>on</strong>itoring from Siret River Basin. These secti<strong>on</strong>s were chosen<br />
taking into account of the number and importance of polluti<strong>on</strong> points (ec<strong>on</strong>omic activities<br />
and urban agglomerati<strong>on</strong>s).<br />
Key words: soil polluti<strong>on</strong>, residual polluti<strong>on</strong>, sediment, heavy metals.<br />
68
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
RESEARCH ON THE CAUSES OF TORRENTIAL RAINS IN<br />
THE CENTRAL SOUTHERN OF <strong>MOLDAVIAN</strong> REGION<br />
ON 05 SEPTEMBER 2007<br />
Maria Vasilica 1 , Doina Capsa 1 , Irina Covaci 1 , Valentin Nedeff 2 ,<br />
Narcis Barsan 2<br />
1 Regi<strong>on</strong>al weather forecasting service Bacau<br />
2 “Vasile Alecsandri" University of Bacau, Department of Envir<strong>on</strong>mental Engineering and<br />
Mechanical Engineering<br />
Corresp<strong>on</strong>ding author: Capsa Doina, doina_capsa@yahoo.com<br />
Abstract: Precipitati<strong>on</strong> is defined as water falling from atmospheric layers to the surface of<br />
the earth. All precipitati<strong>on</strong> c<strong>on</strong>tributes to the water circuit in nature. At the nati<strong>on</strong>al level<br />
the atmospheric precipitati<strong>on</strong> increases from east to west and from the lowlands to the<br />
highlands. Mean annual precipitati<strong>on</strong> in the Danube Delta and <strong>on</strong> the seashore hardly<br />
reaches 400 mm per year, increasing to 500 - 600 mm per year in the lowlands and<br />
exceeding 1000 mm per year in the highlands. The mean annual precipitati<strong>on</strong> varies a lot<br />
from <strong>on</strong>e year to another. Even if mean annual precipitati<strong>on</strong> doesn’t exceed the<br />
multiannual average, the most important problems occur when a large quantity of<br />
precipitati<strong>on</strong> falls in a very short period of time. This paper studies the main causes that<br />
determined the torrential rains <strong>on</strong> the 5th of September 2007. The main characteristics of<br />
that day c<strong>on</strong>sisted in the torrential rains that occurred over the central-south part of<br />
Moldavia between 9 am and 12 pm. The c<strong>on</strong>vective clouds developing above the northern<br />
part of the Romanian plain followed a certain path over the central-south part of Moldavia,<br />
finally leading to quantitatively significant torrential rains. Synoptic situati<strong>on</strong> in the<br />
c<strong>on</strong>text of floods that occurred in the south of Moldavia in the period studied is as follows:<br />
<strong>on</strong> 05.09.2007 in the area where floods have occurred under the influence of a depressi<strong>on</strong><br />
from Minor Asia. At c<strong>on</strong>tinental level has occurred a particularly barometric phenomen<strong>on</strong><br />
from NE to SW of Europe. The Azores anticycl<strong>on</strong>e was extended <strong>on</strong> the western half of<br />
the c<strong>on</strong>tinent and the European part of Russia was under the influence of an anticycl<strong>on</strong>e<br />
nucleus. Under the Azores anticycl<strong>on</strong>e dorsal there has been a c<strong>on</strong>necti<strong>on</strong> between two<br />
active cores, <strong>on</strong>e located in the SW part of Bulgaria, Greece's N and NW Russia's. Six<br />
hours after producti<strong>on</strong>, this phenomen<strong>on</strong> has moved from west to east and in this time the<br />
Azores anticycl<strong>on</strong>e has expanded a dorsal to the north central parts of Europe.Also, this<br />
paper presents the social and ec<strong>on</strong>omic impact of significant floods <strong>on</strong> the local<br />
communities from the affected areas.<br />
Key words: precipitati<strong>on</strong>, c<strong>on</strong>vective clouds, torrential rains.<br />
69
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
RESEARCH ON THE USE OF ORGANIC FLOCCULANTS IN<br />
TREATING THE SLUDGE <strong>FROM</strong> THE MUNICIPAL<br />
WASTEWATER TREATMENT PLANTS<br />
Mariana Turcu 1, 2 , Valentin Nedeff 2 , Narcis Barsan 2<br />
1 SC ECO SISTEM PROIECT SRL<br />
2 “Vasile Alecsandri" University of Bacau, Department of Envir<strong>on</strong>mental Engineering and<br />
Mechanical Engineering<br />
Corresp<strong>on</strong>ding author: Turcu Mariana, ecosistemproiect@yahoo.com<br />
Abstract: The quality of the water represents the c<strong>on</strong>venti<strong>on</strong>al assembly of values of<br />
certain physical, chemical and biological properties which differ according to the<br />
c<strong>on</strong>sumpti<strong>on</strong> type. The water polluti<strong>on</strong> involves changes of the functi<strong>on</strong>al specificati<strong>on</strong>s<br />
due to the presence of the physical chemical and biological compounds, which have values<br />
over a limit imposed under the standard regulati<strong>on</strong>s. After any type of use, the water is<br />
transformed in what we can call it, under a general tern “wastewater”. The classificati<strong>on</strong> of<br />
the wastewater is made up<strong>on</strong> two main directi<strong>on</strong>s, depending <strong>on</strong> the source of their origin<br />
it is classified in domestic wastewater and industrial wastewater. Sequence to any<br />
treatment process of the domestic wastewater results residual sludge, which is classified<br />
according to the type of water use and to the treatment procedure type applied. Mainly, the<br />
sludge come from the primary and sec<strong>on</strong>dary decantati<strong>on</strong> of the wastewater, and their<br />
physical, chemical, biological and bacteriological specificati<strong>on</strong> highly depend <strong>on</strong> their<br />
origin. In the sludge treatment process, three important phases are to be noted: the<br />
preliminary phase, for the sludge thickening, the stabilizati<strong>on</strong> phase and the dehydrati<strong>on</strong><br />
phase. In the present work the identificati<strong>on</strong> of the most efficient organic cati<strong>on</strong>ic<br />
flocculants was studied, which may be used in the process of the thickening and<br />
dehydratati<strong>on</strong> of the sludge result from the municipal wastewater treatment plants. The<br />
organic synthesis flocculants are macromolecules with l<strong>on</strong>g chains, obtained by associating<br />
synthetic m<strong>on</strong>omers having electrical loads or i<strong>on</strong>isable groups. Also the organic synthesis<br />
flocculants are like solid products, emulsi<strong>on</strong>s or soluti<strong>on</strong>s (20 g/L in water). Before using<br />
the organic flocculants for specific industrial applicati<strong>on</strong>s, it is necessary the achievement<br />
of a testing stage at the laboratory level. Any testing procedure in a laboratory aims the<br />
simulati<strong>on</strong> of the industrial c<strong>on</strong>diti<strong>on</strong>s. In this sense, the present research has aimed the<br />
testing of the organic cati<strong>on</strong>ic flocculants, Zetag type, to identify the most efficient<br />
flocculant from this category. The main parameters followed during the laboratory tests<br />
were: the reacti<strong>on</strong> time; flocculants dimensi<strong>on</strong>; sedimentati<strong>on</strong> time; clearing; mixing and<br />
strength of the flocculants. After the result of the laboratory tests can be specifying that the<br />
laboratory tests are sufficiently precise to extrapolate the results to industrial applicati<strong>on</strong>s.<br />
Key words: sludge treatment process, organic cati<strong>on</strong>ic flocculants, laboratory tests.<br />
70
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
THEORETICAL ASPECTS OF THE RELIABILITY<br />
REQUIREMENTS OF WASTEWATER TREATMENT PLANTS<br />
Andrei Stoicescu<br />
“Politehnica” University of Bucharest, Department of Hydraulics, Hydraulical Machinery and<br />
Envir<strong>on</strong>mental Engineering<br />
Corresp<strong>on</strong>ding author: Andrei Stoicescu, andrei.stoicescu@skivirus.com<br />
Abstract: Reliability engineering is an engineering field that designs the works with the<br />
ability of a system or comp<strong>on</strong>ent to perform its required functi<strong>on</strong>s. Reliability is often<br />
measured with terms such as probability of failure, mean time between failures, measure of<br />
availability, and maintainability. Reliability engineering for complex systems, such as<br />
wastewater treatment works, requires a more elaborate systems approach than reliability<br />
for a simpler system. Reliability engineers should have broad skills and knowledge of the<br />
processes within a works most industries (such as wastewater treatment) do not have<br />
specialized reliability engineers, and the reliability task becomes a part of the design<br />
engineer’s resp<strong>on</strong>sibility. Reliability engineering is an emerging discipline that refers to<br />
the process of including reliability into products and systems. One of the most important<br />
design techniques is redundancy or backup. This means that if <strong>on</strong>e part of the system fails,<br />
there is an alternate path, such as a backup system. The reas<strong>on</strong> why this is the preferred<br />
choice is related to the fact that to provide absolute reliability is often very costly. By<br />
creating redundancy, al<strong>on</strong>g with a high level of c<strong>on</strong>trol and the intent of this article is to<br />
augment the local authorities, and establish local design guidelines for wastewater<br />
treatment facilities with regard to minimum standards for reliability for systems and their<br />
comp<strong>on</strong>ents. Although each jurisdicti<strong>on</strong> will have its own requirements, the criteri<strong>on</strong> set<br />
forth in this article is of a general nature and should be adapted to individual jurisdicti<strong>on</strong><br />
requirements. A healthy discussi<strong>on</strong> <strong>on</strong> definiti<strong>on</strong>s and terms comm<strong>on</strong> to the works and<br />
reliability will be included. This porti<strong>on</strong> is to aid the diverse engineering disciplines<br />
associated with a wastewater treatment system with the comm<strong>on</strong> terminology of the<br />
reliability design criteria. Reliability will be defined and its classificati<strong>on</strong>s will be<br />
discussed. Examples of each classificati<strong>on</strong> will be included. The reliability design criteria<br />
will then be transposed up<strong>on</strong> the works design. Items such as locati<strong>on</strong>, expansi<strong>on</strong>, piping,<br />
and maintenance will be presented. Systems such as wastewater treatment, sludge<br />
handling, electrical power, and c<strong>on</strong>trol systems will be included.<br />
71
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
ENVIRONMENTAL RISK DUE TO LEACHATE <strong>FROM</strong><br />
NON-CONFORMING LANDFILLS<br />
Adriana Vatra, Gabriel Lazar<br />
“Vasile Alecsandri” University of Bacau, Department of Envir<strong>on</strong>mental Engineering and<br />
Mechanical Engineering<br />
Corresp<strong>on</strong>ding author: Adriana Vatra, adriana.vatra@ub.ro<br />
Abstract: The major potential envir<strong>on</strong>mental risk related to landfill leachate is the<br />
c<strong>on</strong>taminati<strong>on</strong> of groundwater and surfacewaters. The leachate c<strong>on</strong>tains a range of organic<br />
and inorganic compounds that may be either dissolved or suspended. When the leachate is<br />
discharged from older sites made before modern standards it becomes a great risk for the<br />
envir<strong>on</strong>ment. In Romania most of the municipality’s landfills are not c<strong>on</strong>forming with the<br />
European Uni<strong>on</strong> standards. This paper describes the risks and the impact of leachate<br />
generated by these landfills for the envir<strong>on</strong>ment by using mathematical and spatial<br />
modeling. Described method was used to study an old landfill that has started from 1960,<br />
located in Roman, Romania, near to Moldova River, and to distances less than 500 meters<br />
of private homes. Over time here were stored household waste and n<strong>on</strong>-hazardous<br />
industrial waste collected from the Roman city; the landfill capacity is exceeded at this<br />
moment by about 2.2 times. Disposal of n<strong>on</strong>selective waste was made in layers compacted<br />
<strong>on</strong>ly with a bulldozer. For simulating <strong>on</strong>e-dimensi<strong>on</strong>al c<strong>on</strong>taminant transport and<br />
groundwater flow through unsaturated z<strong>on</strong>es a popular software, UnSat Suite, was used.<br />
Software package include SESOIL, VS2DT, VLEACH, PESTAN, and the <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g><br />
Weather Generator. The combinati<strong>on</strong> of models offers the ability for simulating the<br />
downward vertical flow of water and the migrati<strong>on</strong> of dissolved c<strong>on</strong>taminants through the<br />
vadose z<strong>on</strong>e. UnSat Suite software includes tools for project management, generating<br />
synthetic weather data, modeling flow and c<strong>on</strong>taminants through the unsaturated z<strong>on</strong>e,<br />
estimating groundwater recharge and c<strong>on</strong>taminant loading rates, and preparing compliance<br />
reports. Geographic Informati<strong>on</strong> System was also used to generate spatial data necessary to<br />
asses the risk.<br />
Key words: landfill leachate, older sites, mathematical modeling, spatial modelling.<br />
72
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
THE CONSEQUENCES OF REDUCING THE AVAILABILITY<br />
OF BIOMASS IN TIME<br />
Paula Voicu<br />
“Politehnica” University of Bucharest, Department of Power engineering<br />
Corresp<strong>on</strong>ding author: Voicu Paula, paulavoicu85@yahoo.com<br />
Abstract: In an era where reserves by c<strong>on</strong>venti<strong>on</strong>al fuel are in diminishing, leading to a<br />
rapid increase in prices, people are heading the attenti<strong>on</strong> to new sources of primary energy<br />
to supply a energy of industry cleaner and safer <strong>on</strong> a l<strong>on</strong>g time. Biomass is a renewable<br />
source, n<strong>on</strong>-fossil, from which can be obtained fuels, which can be used in power<br />
generati<strong>on</strong> systems. The main difference of fossil fuels is the availability biomass in nature<br />
and that it is in c<strong>on</strong>tinue "reproducti<strong>on</strong>". The use its enable the use of materials that could<br />
be destined destructi<strong>on</strong>, as a source of energy "renewable", trough result with many<br />
ecological values. The use of biomass for energy does not c<strong>on</strong>tribute to the greenhouse<br />
effect because the same amount of carb<strong>on</strong> dioxide supplied during combusti<strong>on</strong> is<br />
reabsorbed during the process of growth of biomass through photosynthesis process itself.<br />
In this c<strong>on</strong>text, therefore, increase the share of energy produced trough the use biomass, at<br />
the expense of fossil fuels can lead to reduce CO² emitted into the atmosphere. In this<br />
paper it put just the problem the reducti<strong>on</strong> of available biomass in time, and what<br />
c<strong>on</strong>sequences it brings this. It will analyze the results this trough the variati<strong>on</strong> of net<br />
updated income according to the nominal cogenerati<strong>on</strong> thermal coefficient and which it<br />
will be new optimal coefficient of cogenerati<strong>on</strong>. It will c<strong>on</strong>sider the case of use of biomass<br />
in the cogenerati<strong>on</strong> installati<strong>on</strong> and natural gas in thermal installati<strong>on</strong> of peak. Starting<br />
from the last European Council Directives <strong>on</strong> the cogenerati<strong>on</strong> by high efficiency and<br />
those <strong>on</strong> in the use of renewable energy resources, it will highlight the advantages of<br />
granting green certificates for electricity generati<strong>on</strong> using renewable energy resources. It<br />
will analyze the case of highly efficient plants, cogenerati<strong>on</strong> plants, where for the<br />
producti<strong>on</strong> of electricity from renewable energy resources it get 4 green certificates,<br />
according to Law 220/2008, republished in the Official 577 of 13.August.2010.<br />
Key words: biomass, cogenerati<strong>on</strong>, green certificati<strong>on</strong>s, updated net income, optimal coefficient of<br />
cogenerati<strong>on</strong>.<br />
73
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
STUDIES REGARDING THE BEHAVIOR OF SOLID<br />
PARTICLES ON A FLAT OSCILATING SURFACE<br />
Ovidiu B<strong>on</strong>tas 1 , Valentin Nedeff 2 , Emilian Florin Mosnegutu 2 ,<br />
Mirela Panainte 2 , Oana (Irimia) Tirtoaca 2<br />
1 “George Bacovia” University of Bacau<br />
2 “Vasile Alecsandri” University of Bacau<br />
Corresp<strong>on</strong>ding author: B<strong>on</strong>tas Ovidiu, ovidiu.b<strong>on</strong>tas@ugb.ro<br />
Abstract: In many industrial applicati<strong>on</strong>s much of the solid particles are separated by size<br />
and for this purpose are used oscillating sieves. The separati<strong>on</strong> <strong>on</strong> site is a complex process<br />
that depends <strong>on</strong> several factors, such as:<br />
- the properties of solids particle which will be separate;<br />
- operating regimes of separati<strong>on</strong> equipment.<br />
To streamline the process of separati<strong>on</strong> there has been studied the behavior of solid<br />
particles <strong>on</strong> the grain surface, by drawing up a series of mathematical models aimed at<br />
identifying the solid particle trajectory. This paper presents a study realized at the "Vasile<br />
Alecsandri" University in Bacau, which aimed to determine the ideal particle travel path<br />
and for the different types of real particles. To highlight just the oscillating behavior of<br />
solid surfaces in the experimental measurements there has been used a blind screen. The<br />
experimental determinati<strong>on</strong>s were performed <strong>on</strong> a laboratory bench with flat oscilating<br />
sieves. The movement of the solid particle <strong>on</strong> the working surface has been m<strong>on</strong>itored by<br />
two cameras positi<strong>on</strong>ed in perpendicular planes, the system aimed at obtaining the spatial<br />
trajectory of the particle <strong>on</strong> the stage. Films obtained from experimental measurements<br />
were processed using the software SynthEyes, obtaining files *.txt which c<strong>on</strong>tain the data<br />
to visualize the trajectory of a particle studied <strong>on</strong> <strong>on</strong>e working plan. By combining the two<br />
paths obtained <strong>on</strong>e can view the three-dimensi<strong>on</strong>al trajectory of the solid particle. The<br />
present study aimed to determine the trajectory for different types of particles, namely:<br />
ideal spherical particle, particle with cube form, various other forms of real particles: soy,<br />
pod and grain. Within the experimental measurements, we also studied the solid particle<br />
behavior for different operating c<strong>on</strong>diti<strong>on</strong>s, namely:<br />
- different angles of work surfaces;<br />
- different operating modes of the block sieves.<br />
After processing the data obtained from experimental measurements <strong>on</strong>e could calculate<br />
the velocity of solid particle <strong>on</strong> a flat oscillating surface.<br />
Key words: solid particle, fricti<strong>on</strong> coefficient, block sieves.<br />
74
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
MODELING HYDRO-MORPHOLOGICAL DATA <strong>FROM</strong> A<br />
HYDROGRAPHIC AREA, USING GIS ARCHYDRO<br />
Dan Dascalita<br />
“Vasile Alecsandri” University of Bacau, Department of the Envir<strong>on</strong>ment Engineering and<br />
Mechanical Engineering<br />
Corresp<strong>on</strong>ding author: Dan Dascalita, dan_dsclt@yahoo.com<br />
Abstract: An effective flood protecti<strong>on</strong> system requires the producti<strong>on</strong> of a computer based<br />
subsystem, able to model characteristic hydro-morphological data and a technological<br />
subsystem using the informati<strong>on</strong> received from the computer based subsystem (parameters<br />
needed by quick interventi<strong>on</strong> devices to avoid flood damage). In this paper I present the<br />
stages of digital modeling using GIS ARCHYDRO comp<strong>on</strong>ents. To exemplify, I chose an<br />
experimental area, the hydrographic space of Trebes River, right affluent of Bistrita River.<br />
In the design process I used a basemap c<strong>on</strong>taining geographic data <strong>on</strong> water leakage from<br />
the Hydrographic Area Siret, which includes the catchment boundaries, water courses and<br />
bodies shape files. We also used a geographic database that keeps all data layers and create<br />
relati<strong>on</strong>ships within the geographical database and a set of features for each of the<br />
m<strong>on</strong>itoring stati<strong>on</strong>s, part of the geographical database. Through the processing of hydromorphological<br />
database, I determined:<br />
- the length secti<strong>on</strong>s of streams in specified secti<strong>on</strong>s of interest;<br />
- the areas of river sectors, where all the water leaks are drained from.<br />
Modeling is very useful for flood forecasting, for the interpretati<strong>on</strong> of other phenomena<br />
produced al<strong>on</strong>g the water courses, but also for quick interventi<strong>on</strong> in order to prevent flood<br />
damages, accidental polluti<strong>on</strong>, water use restricti<strong>on</strong>s in times of low water, etc. This model<br />
can be optimized and can become an expert system in critical cases of damage preventi<strong>on</strong><br />
and defense against waterways emergencies.<br />
Key words: Geographic Informati<strong>on</strong> System, hydro-morphological, flood.<br />
75
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
THE IMPACT OF HYDROTECHNICAL ARRANGEMENTS ON<br />
WATER COURSES AND AQUATIC ECOSYSTEMS<br />
Dan Dascalita<br />
“Vasile Alecsandri” University of Bacau, Department of the Envir<strong>on</strong>ment Engineering and<br />
Mechanical Engineering<br />
Corresp<strong>on</strong>ding author: Dan Dascalita, dan_dsclt@yahoo.com<br />
Abstract: Hydrotechnical arrangements are complex projects, arranged <strong>on</strong> water courses,<br />
with an important role in water management, water c<strong>on</strong>trol, water protecti<strong>on</strong>, underwater<br />
ecosystems protecti<strong>on</strong>, and over the social-ec<strong>on</strong>omical development of the areas they are<br />
built in. They are designed to c<strong>on</strong>trol the benefits and the damages produced by big waters,<br />
slope erosi<strong>on</strong> or land slips. At present, we cannot imagine a sustainable development of<br />
water resources without integrating the hydrographical basins arrangements in a larger<br />
system. Hydrotechnical set-ups include big size works, which come with both positive and<br />
negative effects over the natural regime of water courses, as well as over other<br />
envir<strong>on</strong>mental factors. We can distinguish hydrotechnical works with the following<br />
effects:<br />
- functi<strong>on</strong>al: water supply, defence against floods, riverbeds regularizati<strong>on</strong>s, producing<br />
electrical power, navigati<strong>on</strong>;<br />
- underwater and land ecosystems protecti<strong>on</strong>: to ensure the fauna and flora species a<br />
suitable life envir<strong>on</strong>ment;<br />
- social ec<strong>on</strong>omical: affecting some human settlements, some land destinati<strong>on</strong>s, some<br />
traditi<strong>on</strong>al crafts, or even historical or archeological sites;<br />
- geo-hydro-morphological: modifying some riverbeds of water courses, the land and the<br />
climate, the hydrological or geological regimes;<br />
- modifying the quality of the water, and other envir<strong>on</strong>mental factors in the affect area.<br />
The negative effects produced by hydrotechnical works over water courses and ecosystems<br />
can be diminished and even avoided in some situati<strong>on</strong>s, if regulati<strong>on</strong> and directives that<br />
establish envir<strong>on</strong>mental objectives at regi<strong>on</strong>al and nati<strong>on</strong>al levels are respected. In this<br />
paper, I presented some aspects regarding hydrotechnical arrangements and their impact<br />
over the water courses and aquatic ecosystems, with special regard over the Siret<br />
Hydrographic Basin.<br />
Key words: hydrotechnical arrangements, impact, aquatic ecosystem<br />
76
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
INFLUENCE OF LAND USES ON WATER FLOW AND<br />
NUTRIENTS IN THE WATERSHED TAABO: INTEREST OF A<br />
MODELING WITH SWAT<br />
Armand Anoh Kouao 1, 2 , Jean Patrice Jourda 2 , Kan Jean Kouame 2 ,<br />
Tanoh Jean-Jacques Koua 1,2 , Gabriel Lazar 1<br />
1 "Vasile Alecsandri" University of Bacau, Envir<strong>on</strong>ment and Mechanical Engineering Dept.<br />
Romania<br />
2 University of Cocody-Abidjan, Laboratory for Remote Sensing and Spatial Analysis<br />
Applied to Hydrogeology, Cote d’Ivoire<br />
Corresp<strong>on</strong>ding author: anohkouaoarmand@yahoo.fr /anohkoua@gmail.com<br />
Abstract: In Cote d’Ivoire, as in most developing countries, the combinati<strong>on</strong> of poverty<br />
and populati<strong>on</strong> growth in the watershed c<strong>on</strong>tribute with many problems in terms of natural<br />
resource degradati<strong>on</strong>, such as soil, forests and water. The river system in Cote d’Ivoire has<br />
four major basins, including Bandama wich represents 32% of the total reservoir of the<br />
country. Created in 1975, Lake Watershed Taabo (sub Bandama basin) has made available<br />
to Ivorians and rural people in particular, a vast expanse of water to multiple uses. The<br />
core activity of most indigenous peoples remains agriculture which occupies almost 85%<br />
of land in the basin. Moreover, since lake creati<strong>on</strong>, the forest cover has been reduced from<br />
78% to 25% in early 1990. This reducti<strong>on</strong> in forest area favored by the agriculture<br />
intensificati<strong>on</strong> increased tenfold the leaching phenomena and soil erosi<strong>on</strong>. However,<br />
leaching and soil erosi<strong>on</strong> associated with increasing fertilizer inputs result in losses of<br />
nutriments to the river system resulting eutrophicati<strong>on</strong> problems experienced by 26% of<br />
the total area of the lake since 1990s. University studies c<strong>on</strong>ducted <strong>on</strong> the Taabo retenti<strong>on</strong><br />
in 2002 and 2007 show that it is attacked by many anthropogenic activities of local<br />
residents. It also present at level of physical-chemical characteristics, an overall annual<br />
input and output flows of suspended solids of approximately 8812 t<strong>on</strong>s or 16% of<br />
particulate flows. Therefore, the protecti<strong>on</strong> of this water is imperative because of its<br />
susceptibility to exploitati<strong>on</strong> and polluti<strong>on</strong>. Unfortunately, in Cote d’Ivoire, no surface<br />
water has benefit yet of an envir<strong>on</strong>mental protecti<strong>on</strong> program. It would therefore be<br />
advisable that sustainable management of water resources is integrated into development<br />
of Cote d’Ivoire for an ec<strong>on</strong>omic and social development in the l<strong>on</strong>g term. A palliative<br />
soluti<strong>on</strong> for water polluti<strong>on</strong> will be agro-hydrological modeling with SWAT model to<br />
reflect the complexity of the interacti<strong>on</strong>s between climate, soils and plants. The purpose of<br />
this study is to evaluate the feasibility of an agro-hydrological modeling of the Taabo<br />
watershed, to quantify the phenomena of diffuse polluti<strong>on</strong>, appreciate their origins, and<br />
suggest priority areas for acti<strong>on</strong> for acti<strong>on</strong>s restorati<strong>on</strong> of the water quality.<br />
Keywords: Hydrologie, nutrient, eutrophicati<strong>on</strong>, river basin management, Modeling, SWAT.<br />
77
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
ENVIRONMENTAL RISK ASSESMENT OF WASTEWATER<br />
SLUDGE DISPOSAL<br />
Elena Manea, Doru Manea, Dan Robescu<br />
“Politehnica” University of Bucharest, Department of Hydraulics, Hydraulic Machines and<br />
Envir<strong>on</strong>mental Engineering<br />
Corresp<strong>on</strong>ding author: Elena Manea, estreitferdt@yahoo.com<br />
Abstract: Important envir<strong>on</strong>mental risks can come from any human activities. C<strong>on</strong>sidering<br />
wastewater treatment, all stages must be attentively studied and evaluated. The final<br />
disposal of wastewater treatment sludge is a disputed subject. In most cases, in Romania,<br />
the sludge is stored, and not reused. Many countries, as Switzerland, Sweden and<br />
Germany, already have laws and regulati<strong>on</strong>s against sludge storage. The immediate<br />
c<strong>on</strong>clusi<strong>on</strong> is that a soluti<strong>on</strong> for final disposal for each wastewater treatment plant has to be<br />
found and applied. An envir<strong>on</strong>mental risk assessment for sludge disposal was elaborated.<br />
Using sludge with dangerous substances c<strong>on</strong>tent as an agricultural fertilizer can provide<br />
risks for humans and all envir<strong>on</strong>mental comp<strong>on</strong>ents. An important risk factor that had to be<br />
taken into account is the combinati<strong>on</strong> of sludge usage as a fertiliser and agriculture<br />
activities that has its own c<strong>on</strong>sequences. The most important risk factors in the studied<br />
case, wastewater sludge usage as an agriculture fertilizer, comes from heavy metal<br />
c<strong>on</strong>tents, nutrients c<strong>on</strong>tents, the existence and types of irrigati<strong>on</strong> systems for the land <strong>on</strong><br />
which the fertilizer will be applied <strong>on</strong>, climate c<strong>on</strong>diti<strong>on</strong>s and others. Sludge samples from<br />
a wastewater treatment plant were analyzed in order to determine their quality as fertilizer<br />
and the c<strong>on</strong>taminants c<strong>on</strong>tents. The results showed that the heavy metals c<strong>on</strong>tent is low,<br />
according to the 86/278 EEC Directive requirements. The Calcium, Nitrogen and<br />
Magnesium c<strong>on</strong>tent resulted as being comparable to the sludge c<strong>on</strong>tents in other EU<br />
countries. In exchange, the main nutrients, Potassium and Phosphorus have low<br />
c<strong>on</strong>centrati<strong>on</strong>s in the analyzed sludge. From an ecological point of view, the best way<br />
would be to eliminate the organic matter and nutrients from the envir<strong>on</strong>ment. Heavy<br />
metals, medical wastes and pathogens often found in wastewater sludge represent a<br />
c<strong>on</strong>siderable risk against human health and envir<strong>on</strong>mental protecti<strong>on</strong>. The results led to the<br />
c<strong>on</strong>clusi<strong>on</strong> that the envir<strong>on</strong>mental risks of using sludge as a fertilizer weren’t high if a<br />
careful m<strong>on</strong>itoring of substances c<strong>on</strong>tents takes place.<br />
Key words: risk assessment, sludge, agriculture, wastewater.<br />
78
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
VALORIZATION OF WHEY <strong>FROM</strong> DAIRIES AS FERTILIZER.<br />
WHEY INFLUENCE ON GERMINATION AND PLANT<br />
GROWTH<br />
L. Grosu 1 , B. Fernandez 2 , C. G. Grigoras 1 , O. I. Patriciu 1 , I. C. Grig-Alexa 1 , D.<br />
Nicuta 3 , D. Ciobanu 1 , V. Nedeff 4 , L. Gavrila 1 , A. L. Finaru 1<br />
1 ”Vasile Alecsandri” University of Bacau, Department of Chemical and Food Engineering, Romania,<br />
2 Ecole Polytechnique Universitaire de Lille, Département Génie Biologique <strong>–</strong> Industries<br />
Agro-alimentaires, Avenue Paul Langevin, 59655 Villeneuve d’Ascq Cedex, France, 3 ”Vasile<br />
Alecsandri” University of Bacau, Department of Biology, Ecology and Envir<strong>on</strong>mental Protecti<strong>on</strong>,<br />
Romania, 4 ”Vasile Alecsandri” University of Bacau, Department of Mechanical and Envir<strong>on</strong>mental<br />
Engineering, Romania<br />
Corresp<strong>on</strong>ding author: L. Grosu, lumig@ub.ro,<br />
Abstract: Whey is the main by-product of the dairy industry, the acid whey being seen as a<br />
waste product. Each kg of produced cheese generates 8 to 12 kg of whey that c<strong>on</strong>tents most of<br />
the saccharydes and minerals from the raw milk. Despite the fact that whey is an important raw<br />
material for producing dietary food products, proteic c<strong>on</strong>centrates, nutraceuticals, specialty<br />
chemicals, etc., large quantities of whey are still unused, being a burden for the wastewater<br />
treatment plants. The use of whey as crops fertilizer may enhance agricultural producti<strong>on</strong>, thus<br />
minimizing the food security risks. The literature c<strong>on</strong>cerning recovery and/or valorizati<strong>on</strong> of<br />
the by-products from the dairy industry reveals that whey represents a product of major<br />
interest. From the researches c<strong>on</strong>ducted to date has been found that spread as fertilizer <strong>on</strong><br />
cultivated lands, whey affords the improvement of nutrients flux from plants. Indeed, nitrogen,<br />
phosphorus, sulfur, calcium, sodium and magnesium, lactose and proteins from whey can play<br />
this role and lead to increased crop productivity. The amounts of these compounds from whey<br />
can be c<strong>on</strong>sidered sufficient for plant growth. In the present paper, the possibility of direct<br />
valorizati<strong>on</strong> of whey as fertilizer was investigated. For this study, the experiments were carried<br />
out <strong>on</strong> three species of plants: broccoli (Brassica oleracea L., var botrytis, subvar. cymosa.),<br />
soy (Glicine max (L) Merr) and wheat (Triticum aestivum L.). The acid whey used for these<br />
experiments became from the manufacturing process of traditi<strong>on</strong>al „telemea” cheese and was<br />
provided by a local company. The seeds were wetted with distilled water (for the blank<br />
sample), with distilled water/whey mixtures in different ratios (1:1, 1:4) and with whey <strong>on</strong>ly.<br />
The germinati<strong>on</strong> capacity of seeds was examined. The highest values for the germinati<strong>on</strong> were<br />
obtained in the case of the broccoli seeds, and the most favorable water/whey ratio was 1:1,<br />
followed by the mixture 1:4. The accumulati<strong>on</strong> of the fresh and dry biomass after the pot<br />
development phase was analyzed. Aerial parts of wheat, soy and broccoli plants and soy roots<br />
were harvested, measured, counted and weighed in order to estimate the effect produced by the<br />
additi<strong>on</strong> of whey <strong>on</strong> plants growth and development. The results obtained in the case of the<br />
three studied species suggested the positive effect of the whey additi<strong>on</strong>. Harvested plant<br />
material was extracted in order to perform qualitative and quantitative analyses c<strong>on</strong>cerning the<br />
chemical compositi<strong>on</strong>. The extracti<strong>on</strong> of plant material was realized by classical methods and<br />
under microwaves. The preliminary results of thin layer chromatography (TLC) and UV-VIS<br />
spectroscopy analysis of the extracts c<strong>on</strong>firmed the positive influence of whey additi<strong>on</strong>,<br />
encouraging further research.<br />
79
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
ASPECTS OF WATER DEMINERALIZATION WITH MIXED-<br />
LAYER ION-EXCHANGERS<br />
Iuliana Rogoveanu Radosavlevici, Dan Niculae Robescu<br />
Politehnica University of Bucharest, Power Engineering Faculty<br />
Iuliana Rogoveanu Radosavlevici, rad_iu@yahoo.com<br />
Abstract: I<strong>on</strong> exchange is used for water treatment <strong>on</strong> a large number of separati<strong>on</strong>s from<br />
water-based and n<strong>on</strong>-water-based media, it has a special use in chemical synthesis, medical<br />
research, agriculture and food processing. The utility of i<strong>on</strong> exchange is primarily that the<br />
i<strong>on</strong>-exchanger can be regenerated and reused. I<strong>on</strong> exchange is being used more often in the<br />
nuclear industry for recuperati<strong>on</strong> and separati<strong>on</strong> of radioactive elements such as Uranium,<br />
Plut<strong>on</strong>ium, fissi<strong>on</strong> products and other impurities. This experimental applicati<strong>on</strong> sets to<br />
investigate total water demineralizati<strong>on</strong> for the public water distributi<strong>on</strong> network in<br />
Bucharest, Romania, which is achieved through a method of passing the water flow<br />
through an acid cati<strong>on</strong> mixed layer (Purolite C100) and an alkaline ani<strong>on</strong> (Purolite A400).<br />
For this purpose, the qualitative and quantitative influence of the flow speed through the<br />
layer, the total volume of i<strong>on</strong> exchangers and working temperature over the process<br />
dynamics and the quantitative characterizati<strong>on</strong> of the investigated process using a 3-factor<br />
experimental research plan were tracked. A mathematical model was elaborated in order to<br />
describe the process dynamics for i<strong>on</strong> exchange in fixed and mixed layer with i<strong>on</strong><br />
exchanging resin. In order to achieve this objective some simplifying assumpti<strong>on</strong>s were<br />
made:<br />
- The cati<strong>on</strong> and ani<strong>on</strong> particles are identical, sphere shaped objects with a diameter of dp;<br />
- I<strong>on</strong> exchange takes place between H+ i<strong>on</strong>s that are initially found in the cati<strong>on</strong>ite and the<br />
j cati<strong>on</strong>ites in water and the ani<strong>on</strong>s exchange takes place between the OH- ani<strong>on</strong>s initially<br />
found in the ani<strong>on</strong>ite and the k ani<strong>on</strong>s in water; for simplicity c<strong>on</strong>sider j=Ca2+, k=HCO3-;<br />
- The i<strong>on</strong> exchange process takes place <strong>on</strong> the i<strong>on</strong> changer’s particles’ surface;<br />
- The global i<strong>on</strong> exchange speed depends <strong>on</strong> the speeds of elemental surface retenti<strong>on</strong> and<br />
release processes;<br />
- The i<strong>on</strong> retenti<strong>on</strong> process speed is directly proporti<strong>on</strong>al to the number of active loci in the<br />
exchanger and the i<strong>on</strong> c<strong>on</strong>centrati<strong>on</strong> in liquid state;<br />
- The i<strong>on</strong> release process speed is directly proporti<strong>on</strong>al to the c<strong>on</strong>centrati<strong>on</strong> of i<strong>on</strong> in solid<br />
state;<br />
- Pist<strong>on</strong> flow with axial dispersi<strong>on</strong> of the liquid state;<br />
- The axial dispersi<strong>on</strong> coefficient is determined with the Levenspiel formula;<br />
- The i<strong>on</strong> exchange process is isothermal.<br />
Keywords: I<strong>on</strong> exchange, demineralizati<strong>on</strong>, cati<strong>on</strong>ite, ani<strong>on</strong>ite, axial dispersi<strong>on</strong>.<br />
80
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
SUSTAINABLE DEVELOPMENT IN THE CONTEXT OF<br />
GLOBALIZATION. ANALYSIS OF THE REGULATIONS OF<br />
THE WORLD TRADE ORGANIZATION<br />
Gheorghe Durac, Nicolae-Horia Tit<br />
„Alexandru Ioan Cuza” University of Iasi, Faculty of Law<br />
Corresp<strong>on</strong>ding author: Nicolae Horia Tit horia.tit@gmail.com<br />
Abstract: The effects of the phenomen<strong>on</strong> of globalizati<strong>on</strong> are, <strong>on</strong> the <strong>on</strong>e hand, an<br />
unprecedented disseminati<strong>on</strong> of the producti<strong>on</strong> factors (there are situati<strong>on</strong>s when the final<br />
product is the result of a producti<strong>on</strong> performed <strong>on</strong> the territory of over twenty countries),<br />
and <strong>on</strong> the other hand, a true “explosi<strong>on</strong>” of the services provided at a world level.<br />
Globalizati<strong>on</strong> is manifested at an ec<strong>on</strong>omic, social, cultural, and educati<strong>on</strong>al level. From an<br />
instituti<strong>on</strong>al point of view, globalizati<strong>on</strong> implies the appearance of entities with<br />
competences at a world scale, through which rules and disciplines are regulated and<br />
applied, which influence the socio-human activities. Such internati<strong>on</strong>al instituti<strong>on</strong>s are the<br />
World Trade Organizati<strong>on</strong>, the <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> M<strong>on</strong>etary Fund, and the World Bank. The<br />
fundamental objectives of the World Trade Organizati<strong>on</strong>, established through the Preamble<br />
to the Marrakesh Agreement of April 15th 1994, refer to increasing the standard of life, the<br />
integral use of the labor force, increasing real income and demand, enhancing the<br />
producti<strong>on</strong> and trade with goods and services. However, meeting these objectives must<br />
take into account the need to protect the envir<strong>on</strong>ment and the special needs of the<br />
developing countries. The Preamble also stresses the importance of sustainable ec<strong>on</strong>omic<br />
development, respectively an ec<strong>on</strong>omic development taking into account the natural and<br />
social envir<strong>on</strong>ment, and the integrati<strong>on</strong> of the developing countries and especially the less<br />
advanced in the world ec<strong>on</strong>omic system. Fulfilling the objectives shown above implies two<br />
sets of rules: some c<strong>on</strong>centrated around the fundamental principles of internati<strong>on</strong>al trade,<br />
respectively the treatment of the most favored nati<strong>on</strong>, nati<strong>on</strong>al treatment and rules<br />
c<strong>on</strong>cerning the access to the market; the others, built for excepti<strong>on</strong>al situati<strong>on</strong>s and meant<br />
to insure the flexibility of regulati<strong>on</strong>s in case it is necessary to protect certain fundamental<br />
values, such as the protecti<strong>on</strong> of the life or health of people, animals or plants, or the<br />
envir<strong>on</strong>ment. This article aims to analyze the manner in which the regulati<strong>on</strong>s of the World<br />
Trade Organizati<strong>on</strong> reflect the balance between the commercial interests and those<br />
referring to the protecti<strong>on</strong> of life and the envir<strong>on</strong>ment, in the directi<strong>on</strong> of the sustainable<br />
development of human society, also stressing the criticism brought to the organizati<strong>on</strong><br />
from this perspective.<br />
81
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
INTERACTION BETWEEN TOXIC LEAD IONS AND<br />
MODIFIED CALCIUM BENTONITES IN ENVIRONMENT<br />
DEPOLLUTION<br />
Ana-Maria Georgescu 1, 2 , Ileana Denisa Nistor 1 , Claude Penot 2 ,<br />
Francoise Nardou 2<br />
1 “Vasile Alecsandri” University of Bacau, Romania<br />
2 University of Limoges, France<br />
Corresp<strong>on</strong>ding author: Ileana Denisa Nistor, dnistor@ub.ro, denisanistor@yahoo.com<br />
Abstract: Nowadays the dec<strong>on</strong>taminati<strong>on</strong> of waters c<strong>on</strong>taining heavy metals has become<br />
<strong>on</strong>e of the most serious envir<strong>on</strong>mental problems, especially in the case of accidental<br />
polluti<strong>on</strong> and unc<strong>on</strong>trolled discharges of wastewater from metallurgical, chemical,<br />
galvanic and mechanical engineering. Heavy metals are not biodegradable and therefore<br />
tend to accumulate in living organisms, many heavy metal i<strong>on</strong>s being toxic and<br />
carcinogenic. Toxic heavy metals of particular c<strong>on</strong>cern in the treatment of industrial<br />
wastewater are: mercury, lead, cadmium, zinc, chromium (IV), nickel, arsenic, cobalt.<br />
Different methods used for heavy metals removal from wastewaters were studied in the<br />
last years, like: chemical precipitati<strong>on</strong>, i<strong>on</strong>ic exchange, adsorpti<strong>on</strong>, electrolytic recover,<br />
extracti<strong>on</strong> with solvents, reverse osmosis, membrane separati<strong>on</strong>, ultrafiltrati<strong>on</strong>, flotati<strong>on</strong><br />
etc. Adsorpti<strong>on</strong> is a simple and efficient operati<strong>on</strong> which permits the recover of adsorbent<br />
and of retained comp<strong>on</strong>ents and its subsequent reusing. This paper presents the synthesis<br />
and characterizati<strong>on</strong> of porous materials using different pillars as Al (III) and Cr (III)<br />
intercalated between the layers of m<strong>on</strong>tmorill<strong>on</strong>ite. The starting material used to prepare<br />
the pillared clays was calcium natural bent<strong>on</strong>ite from Orasu Nou deposit (Romania). The<br />
adsorpti<strong>on</strong> studies of lead i<strong>on</strong>s <strong>on</strong> the obtained bent<strong>on</strong>ites were realized using<br />
disc<strong>on</strong>tinuous batch technique, the main parameters that were varied being: c<strong>on</strong>tact time<br />
between the adsorbent and the aqueous soluti<strong>on</strong> of Pb (II), adsorbent / adsorbat ratio, Pb<br />
(II) i<strong>on</strong>s c<strong>on</strong>centrati<strong>on</strong> of initial soluti<strong>on</strong>. The raw material and pillared bent<strong>on</strong>ites were<br />
characterized by: BET (Brunauer-Emmet-Teller) method and XRD (X-ray diffracti<strong>on</strong>)<br />
analysis. Determinati<strong>on</strong> of i<strong>on</strong>ic metallic c<strong>on</strong>centrati<strong>on</strong> retained <strong>on</strong> materials after the<br />
c<strong>on</strong>tact with the metallic i<strong>on</strong>s was realized using the atomic absorpti<strong>on</strong> spectrophotometer.<br />
The values of correlati<strong>on</strong> coefficients (R2) obtained for linear dependencies showed that<br />
adsorpti<strong>on</strong> of Pb (II) i<strong>on</strong>s <strong>on</strong> studied materials is better described by Langmuir model,<br />
compared with Freundlich model. Freundlich model c<strong>on</strong>stant n > 1, suggested that<br />
adsorpti<strong>on</strong> of Pb (II) <strong>on</strong> bent<strong>on</strong>ite is a favorable process. The textural analysis of<br />
nanomaterials obtained c<strong>on</strong>firmed that pillaring process leads to the development of<br />
optimal porosity with good adsorpti<strong>on</strong> properties, which can be sucessfully adapted for use<br />
in the process of removal of heavy metals occuring in wastewaters.<br />
Key words: bent<strong>on</strong>ite, pillaring, lead, adsorpti<strong>on</strong>.<br />
82
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
HETEROGENEOUS WATER PHASE CATALYSIS AS AN<br />
ENVIRONMENTAL APPLICATION<br />
Nicoleta Plat<strong>on</strong> 1 , Ileana Denisa Nistor 1 , Ilie Siminiceanu 2<br />
1 ”Vasile Alecsandri” University of Bacau, Department of Chemical and Food Engineering<br />
2 “Gh. Asachi” Technical University of Iaşi, Department of Chemical Engineering<br />
Corresp<strong>on</strong>ding author: Ileana Denisa Nistor, dnistor@ub.ro, denisanistor@yahoo.com<br />
Abstract: The urban distributi<strong>on</strong> of qualitative water for human c<strong>on</strong>sumpti<strong>on</strong>, domestic<br />
activities and industrial use is a fundamental objective in what c<strong>on</strong>cerns the sustainability<br />
of life quality for the populati<strong>on</strong>. However, many industrial processes generate a series of<br />
pollutants, which have a negative impact <strong>on</strong> ecosystems and <strong>on</strong> humans (toxic,<br />
carcinogenic and mutagenic properties). Particularly, phenol is c<strong>on</strong>sidered as <strong>on</strong>e of the<br />
most toxic pollutants, especially for human health but also for the aquatic fauna and flora,<br />
causing an increase in the demand of oxygen in water sources and causing unpleasant taste<br />
and smell in drinking water even when it is found in very small quantities. Catalytic wet<br />
peroxide oxidati<strong>on</strong> (CWPO) is part of the advanced oxidati<strong>on</strong> processes (AOP) and is an<br />
efficient process because H2O2 is a str<strong>on</strong>g oxidative agent. Pillared clays are successfully<br />
used as catalysts in these processes. Study <strong>on</strong> chemically modified clays by pillaring in<br />
Fent<strong>on</strong> and Fent<strong>on</strong> type processes were investigated due to its low cost, to its mild<br />
c<strong>on</strong>diti<strong>on</strong>s (room temperature, atmospheric pressure) and to lack of toxicity for the<br />
envir<strong>on</strong>ment of clays, hydrogen peroxide and ir<strong>on</strong> salts. In this work, catalysts based <strong>on</strong><br />
chemically modified clays by pillaring process with Al (III) and Fe (III) using as raws<br />
materials: commercial bent<strong>on</strong>ite, KSF m<strong>on</strong>tmorill<strong>on</strong>ite and K10 m<strong>on</strong>tmorill<strong>on</strong>ite from<br />
Aldrich were synthesized. After, these catalysts were tested in wet oxidati<strong>on</strong> with<br />
peroxides using the phenol as target compound. Experimental results show that Fe<br />
chemically modified clay from bent<strong>on</strong>ite presented a higher activity than the Al-Fe <strong>on</strong>e.<br />
The raw materials and chemically modified clays were characterized by: BET (Brunauer-<br />
Emmet-Teller) method, XRD (X-ray diffracti<strong>on</strong>) analysis and EDAX-SEM (energydispersive<br />
X-ray) spectroscopy. By testing the derived catalyst from sodium bent<strong>on</strong>ite, a<br />
100% c<strong>on</strong>versati<strong>on</strong> of phenol was obtained after 50 minutes; by testing the KSF catalyst, a<br />
c<strong>on</strong>versi<strong>on</strong> of 98 % was obtained and by testing the catalyst obtained from K10 a 28%<br />
c<strong>on</strong>versi<strong>on</strong> was realized. The catalytic activity was evaluated by rate c<strong>on</strong>stant, c<strong>on</strong>sidering<br />
a first order reacti<strong>on</strong>. Verifying the hypothesis that the reacti<strong>on</strong> is of order 1, we observe<br />
that the value of the rate c<strong>on</strong>stant K increases with the decrease of the phenol<br />
c<strong>on</strong>centrati<strong>on</strong>.<br />
Key words: pillared clay, m<strong>on</strong>tmorill<strong>on</strong>it, phenol, catalytic oxidati<strong>on</strong>.<br />
83
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
ASSESSMENT OF SEDIMENT AND PHOSPHORUS IN BUYO<br />
LAKE, COTE D’IVOIRE, USING SWAT (SOIL AND WATER<br />
ASSESSMENT TOOL) MODEL<br />
Tanoh Jean-Jacques Koua 1, 2 , Jean Patrice Jourda 1 , Kan Jean Kouamé 1 ,<br />
Armand Anoh Kouao 1, 2 , Gabriel Lazar 2<br />
1 University of Cocody-Abidjan, Laboratory for Remote Sensing and Spatial Analysis<br />
Applied to Hydrogeology, Cote d’Ivoire<br />
2 “Vasile Alecsandri" University of Bacau, Department of Envir<strong>on</strong>mental Engineering and<br />
Mechanical Engineering, Romania<br />
Corresp<strong>on</strong>ding author: Jean-Jacques Koua Tanoh, kouatanohjeanjacques@yahoo.fr<br />
Abstract: The changes in land use in the last 30 years in the territory of agro-forest<br />
watershed of Lake Buyo resulted in significant sediment into the lake. Sediments are a<br />
preferred means of transportati<strong>on</strong> for certain pollutants, like phosphorus. By mapping the<br />
source areas of erosi<strong>on</strong>, we can determine risk areas and help prioritize interventi<strong>on</strong>s in the<br />
territory. This mapping is d<strong>on</strong>e using the SWAT (Soil and Water Assessment Tool) model.<br />
Several types of datas, including topography, land use, soil and climate data are needed to<br />
run the model. In this paper are presented all different steps, from the designing of<br />
Hydrological Resp<strong>on</strong>se Units (HRU), basic units to run the SWAT model until the<br />
simulati<strong>on</strong>s. The establishment of Hydrological Resp<strong>on</strong>ses Units (HRU) has three (3) main<br />
stages: Space Discretizati<strong>on</strong>, Land use and soil data integrati<strong>on</strong> and HRU distributi<strong>on</strong>:<br />
- Space Discretizati<strong>on</strong> which c<strong>on</strong>sist in extracting the limits and the water network of the<br />
watershed from the DEM (Digital Elevati<strong>on</strong> Model) and to subdivide them into subbasins;<br />
- Landuse and soil data integrati<strong>on</strong>: it c<strong>on</strong>sists in digitizing the physical maps of land use<br />
and of soils under Mapinfo 7.5 and in keeping them in ".Shape" format;<br />
- HRU distributi<strong>on</strong>: it leads to subdivide the sub-watersheds in small units that combine a<br />
single soil type and <strong>on</strong>e type of land use.<br />
It appears from this study to obtain 23 sub-watersheds and 100 HRU. Once the HRU<br />
designed, it is necessary to integrate climate data, data <strong>on</strong> physico-chemical characteristics<br />
of soils and agricultural practices, before starting the simulati<strong>on</strong>s. This will allow the<br />
model to assess the risk of sedimentati<strong>on</strong> and eutrophicati<strong>on</strong> of the lake using the the<br />
Modified Universal Soil Loss Equati<strong>on</strong> (MUSLE) and phosphorus cycle.<br />
Key words: SWAT, landuse, sediment, phosphorus, erosi<strong>on</strong>, model.<br />
84
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
CLIMATE VARIABILITY AND WATER RESOURCES IN<br />
RURAL SENEGAL: THE CASE OF THE BOROUGH OF<br />
FIMELA<br />
Pierre Ndour 1, 2 , Alioune Kane 1 , Awa Niang 1 , Gabriel Lazar 2<br />
1 University Cheikh Anta Diop of Dakar, Graduate School, "Water,<br />
Quality and Uses of Water", Senegal<br />
2 “Vasile Alecsandri" University of Bacau, Department of Envir<strong>on</strong>mental Engineering and<br />
Mechanical Engineering, Romania<br />
Corresp<strong>on</strong>ding author: Pierre Ndour, nd_pierre@hotmail.fr<br />
Abstract: Split between the mainland and the Atlantic Ocean, the Borough of Fimela<br />
c<strong>on</strong>stitutes the northern boundary of the Regi<strong>on</strong> of the Saloum islands. The increase of its<br />
populati<strong>on</strong> (49 075 inhabitants) causes an increased demand for water quality and quantity<br />
while the reducti<strong>on</strong> in rainfall has put a great pressure <strong>on</strong> the local producti<strong>on</strong> system. Our<br />
study aims to analyze the impacts of climate variability <strong>on</strong> water resources and their uses.<br />
We collected climatic data from the Nati<strong>on</strong>al Agency of Aviati<strong>on</strong> and Meteorology of<br />
Senegal. The exploitati<strong>on</strong> of local development plans, the report of General Census of<br />
Populati<strong>on</strong> and Housing (1976, 1988 and 2002) and a survey of farmers in the Boyar<br />
valley allowed us to collect socioec<strong>on</strong>omic data and determine the public percepti<strong>on</strong> in<br />
relati<strong>on</strong> to the variabilté climate and its implicati<strong>on</strong>s <strong>on</strong> water resources. In the Borough of<br />
Fimela, high mean temperatures (28.6°C) combined with wind speed (2.3 m/s) and<br />
durati<strong>on</strong> of sun exposure (10.5 h/day), promote a high level of evapotranspirati<strong>on</strong> (188<br />
mm/year) and that is why the seas<strong>on</strong>al p<strong>on</strong>ds dry prematurely. The rural areas of Fimela<br />
are all vulnerable to climate variability because the ec<strong>on</strong>omy, based <strong>on</strong> rainfed agriculture,<br />
occupies 80% of the populati<strong>on</strong>. Moreover, marked by the existence of two c<strong>on</strong>trasting<br />
seas<strong>on</strong>s, the Borough of Fimela lies between 400 and 600 mm isohyets where rain comes<br />
from squall lines and the m<strong>on</strong>so<strong>on</strong>. However, the rainfall deficit (-25.34% between 1979<br />
and 2007) has favored the extensi<strong>on</strong> of the salt flats that have led to a loss of arable land,<br />
degradati<strong>on</strong> of vegetati<strong>on</strong> and water quality. Thus, low yields caused by increased<br />
frequency of lean seas<strong>on</strong>s promote migrati<strong>on</strong> of more than 58% of the populati<strong>on</strong>. Fimela<br />
also faces problems of water availability in adequate quantity while tablecloths are<br />
experiencing a str<strong>on</strong>g acidity and mineralizati<strong>on</strong>. The electrical c<strong>on</strong>ductivity is everywhere<br />
greater than 1000 µS/cm, chlorine is above 500mg/l and Fluore far exceeds 1.5 mg/l. This<br />
results in staining of teeth and fluoreuse oseuese in some places. In c<strong>on</strong>clusi<strong>on</strong>, this study<br />
highlights the problem of water in rural Senegal. Socioec<strong>on</strong>omic development and<br />
envir<strong>on</strong>mental stability are closely related to the quantity and quality of available water<br />
resources, hence the need to know the causes and indicators of climate variability for<br />
proper development of local adaptati<strong>on</strong> strategie.<br />
Key words: Climate Variability, Water, Senegal, Fimela, Borough.<br />
85
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
PREVENT MAJOR ACCIDENTS INVOLVING HAZARDOUS<br />
SUBSTANCES<br />
Daniel-Catalin Felegeanu, Valentin Nedeff<br />
“Vasile Alecsandri“University of Bacau, Romania<br />
Corresp<strong>on</strong>ding author: catalin.felegeanu@isubacau.ro<br />
Abstract: Worldwide are ec<strong>on</strong>omic operators who use in the producti<strong>on</strong> process<br />
hazardous substances, and as a result of that process can produce major accidents with<br />
serious c<strong>on</strong>sequences <strong>on</strong> the health and safety of humans as well as <strong>on</strong> the envir<strong>on</strong>ment.<br />
Worldwide took place a series of serious major accidents in the chemical industry. In<br />
Europe, the accident in Seveso, Italy in 1976 had caused the adopti<strong>on</strong> of the legislati<strong>on</strong><br />
that is aimed to prevent and c<strong>on</strong>trol this type of disasters. In 1982 was adopted a<br />
Directive by the Council of Europe, no. 501/EC, June 24, 1982, regarding risks of major<br />
accidents of certain industrial activities <strong>–</strong> SEVESO I Directive had been replaced with<br />
SEVESO II Directive- Directive by the Council of Europe no. 82/EC December 9, 1996<br />
related with the c<strong>on</strong>trol of major accidents involving hazardous substances, extended by<br />
SEVESO III Directive <strong>–</strong> Directive by the Council of Europe no. 105/EC December 16,<br />
2003. Serious accidents that happened in Toulouse <strong>–</strong> France, Enschede <strong>–</strong> Holland,<br />
Bhopal <strong>–</strong> India, Baia Mare <strong>–</strong> Romania have been depply studied by experts of the<br />
European Uni<strong>on</strong>, resulting the need to change legislati<strong>on</strong> in this domain, with immediate<br />
effects <strong>on</strong> the activities of the ec<strong>on</strong>omic operators, who use hazardous substances in the<br />
process of producti<strong>on</strong> or transporting hazardous substances. In accordance with the<br />
stipulati<strong>on</strong>s of Directive SEVESO, all the operators (companies/enterprises) with this<br />
purpose of activity, should sent to the competent authorities a notice and elaborate a plan<br />
to prevent major accidents. More, the operator is required to elaborate following<br />
documents: Safety Report, The system of risk management and Emergency Plan.<br />
Introducing the obligati<strong>on</strong> regulati<strong>on</strong> of risk management system has resulted from the<br />
development of new methods of management and organizati<strong>on</strong>, and in particular, from<br />
the significant changes made by industrial practice in the last 10 years in the domain of<br />
risk management. The project describes a part of measures imposed by the European<br />
legislati<strong>on</strong> for the preventi<strong>on</strong>, training and resp<strong>on</strong>sibility for owners of such technologies<br />
for identificati<strong>on</strong>, estimate of risks and to limit c<strong>on</strong>sequences of major accidents in which<br />
hazardous substances are involved. It is also a guide to provide informati<strong>on</strong> for the<br />
companies engaged in transporting dangerous goods (both internal and internati<strong>on</strong>al<br />
traffic), for knowing and complying the most recent regulati<strong>on</strong>s included in the new<br />
structure of the European Agreement regarding to internati<strong>on</strong>al road transport of<br />
dangerous substances as well as for the performance of activities who can may influent<br />
the transport safety.<br />
86
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
RISK ASSESSMENT OF HEAVY METALS ON AIR<br />
POLLUTANTS IN BACAU CITY<br />
Andreea Cocarcea 1 , Ema Faciu 1 , Iuliana Lazar 2 , Gabriel Lazar 1<br />
1 “Vasile Alecsandri" University of Bacau, Department of Envir<strong>on</strong>mental Engineering and<br />
Mechanical Engineering<br />
2 “Vasile Alecsandri” University of Bacau, Department of Chemical and Food Engineering<br />
Corresp<strong>on</strong>ding author: Iuliana Lazar, ilazar@ub.ro<br />
Abstract: Heavy metals released from different sources in urban envir<strong>on</strong>ment get adsorbed<br />
by humans <strong>on</strong> respirable particulate matter less than 10 μm in size (PM10) and are<br />
important from public health point of view. The compositi<strong>on</strong> of PM10 varies, as they can<br />
absorb and transfer a multitude of pollutants: metals, organic compounds, material of<br />
biologic origin, i<strong>on</strong>s, reactive gases, and the particle carb<strong>on</strong> core. The c<strong>on</strong>centrati<strong>on</strong>s of<br />
PM10, Pb, Cd and Ni from the air of Bacau City are measured daily by the Regi<strong>on</strong>al<br />
Agency of Envir<strong>on</strong>mental Protecti<strong>on</strong> Bacau (ARPM Bacau) and published in their m<strong>on</strong>thly<br />
reports. The relati<strong>on</strong>s and correlati<strong>on</strong>s between c<strong>on</strong>centrati<strong>on</strong>s of PM10, Pb, Cd and Ni<br />
measured during year 2011 and number of patients <strong>on</strong> disease categories registered in 2011<br />
were analyzed using descriptive statistics and bivariate correlati<strong>on</strong>s. It was shown a similar<br />
trend in variati<strong>on</strong> during the period of all four trimesters for PM10 and Pb, and a maximum<br />
for all type of particles during the trimester IV. Another method for analyze the data used<br />
in this study was the multivariate statistics which shown a dependency of 53% between<br />
PM10 and Pb, of 52% between PM10 and Ni and of 38% between PM10 and Cd with a<br />
significant factor less than 0.05. The influence of these air pollutants <strong>on</strong> human health was<br />
analyzed using statistic data provided by IBM SPSS 20.0 software <strong>on</strong> number of registered<br />
ill pers<strong>on</strong>s by disease type and trimester during year 2011. The str<strong>on</strong>gest Bivariate<br />
Correlati<strong>on</strong>s were shown between urological diseases and PM10 (R=0.60, p
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
ASSESSING TEMPORAL AND SPATIAL VARIATIONS IN<br />
SIZE OF DIFFERENT FISH POPULATIONS RELATED WITH<br />
DIFFERENT BIOTIC ENVIRONMENTAL ATTRIBUTES<br />
Camelia Ureche 1 , Dorel Ureche 2 , Iuliana Lazar 3<br />
1 “Vasile Alecsandri” University of Bacau, Department of Biology, Ecology and<br />
Envir<strong>on</strong>mental Protecti<strong>on</strong><br />
2 “Vasile Alecsandri”University of Bacau, Department of Envir<strong>on</strong>mental Engineering and<br />
Mechanical Engineering<br />
3 “Vasile Alecsandri”University of Bacau, Department of Chemical and Food Engineering<br />
Corresp<strong>on</strong>ding author: Iuliana Lazar, ilazar@ub.ro<br />
Abstract: A total of 2789 fish specimens from the basin of River Casin were caught in<br />
September 1999, in August and September 2004 and in September 2008 by electrofishing<br />
in order to investigate inter-relati<strong>on</strong>ships between growth and c<strong>on</strong>diti<strong>on</strong> expressed by<br />
physical envir<strong>on</strong>ment parameters. A Factor Analysis extracting the Principal Comp<strong>on</strong>ents<br />
(PCA) and Cluster Analysis, was also applied in order to identify variables that maximizes<br />
the dispersi<strong>on</strong> or correlati<strong>on</strong> criteria assigned to investigated samples and their associati<strong>on</strong><br />
in order to compare with other studies. At the first factor PC1 the dimensi<strong>on</strong> of total length<br />
Lt (cm) and standard length l (cm) have the highest percentage (0.975) followed by head<br />
length Lc (cm) (0.953) and height H (cm) (0.934), at the sec<strong>on</strong>d factor PC2 the largest<br />
share is attributed to air temperature (0.946) followed by the water temperature (0.912) and<br />
at the third factor PC3 water c<strong>on</strong>ductivity has the largest share of (-0.914) followed by<br />
water pH (0.863). A complex analysis using One Way ANOVA was performed to compare<br />
the frequency distributi<strong>on</strong>s of the lengths and weights of different fish populati<strong>on</strong>s related<br />
with different biotic envir<strong>on</strong>mental attributes and their evoluti<strong>on</strong> in time and in space. At<br />
Sabanejewia balcanica, Barbatula barbatula and Gobio obtusirostris species, there were<br />
statistically significant differences especially in 2008 al<strong>on</strong>g the investigated areas. This<br />
indicates that physical factors of the envir<strong>on</strong>ment, especially air and water temperature,<br />
can influence with propensity these species.<br />
Key words: envir<strong>on</strong>ment, fish, PCA, cluster, ANOVA.<br />
88
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
RISK EXPOSURE TO ENVIRONMENTAL STRESS OF<br />
SEVERAL FISH SPECIES REFLECTS ON ALLOMETRIC<br />
SCALING DECREASES<br />
Dorel Ureche 1 , Camelia Ureche 2 , Iuliana Lazar 3<br />
1 “Vasile Alecsandri” University of Bacau, Department of Mechanical and<br />
Envir<strong>on</strong>mental Engineering<br />
2 “Vasile Alecsandri” University of Bacau, Department of Biology, Ecology and<br />
Envir<strong>on</strong>mental Protecti<strong>on</strong><br />
3 “Vasile Alecsandri” University of Bacau, Department of Chemical and Food Engineering<br />
Corresp<strong>on</strong>ding author: Iuliana Lazar, ilazar@ub.ro<br />
Abstract: In view of a sustainable development it is necessary to identify species of fish<br />
with an increased risk of being affected by envir<strong>on</strong>mental quality. For this, specimens of<br />
Salmo trutta fario, Squalius cephalus, Phoxinus phoxinus, Alburnoides bipunctatus, Gobio<br />
obtusirostris, Barbus Barbus, Barbus petenyi, Barbatula barbatula, Sabanejewia<br />
balcanica, and Cottus gobio were collected at 8 previously determined points from the<br />
Casin River basin in August and September 2004, and September 2008, and grouped into<br />
two areas: upstream Casin regi<strong>on</strong> c<strong>on</strong>sidered an unpolluted area and downstream Casin<br />
regi<strong>on</strong> c<strong>on</strong>sidered a high polluti<strong>on</strong> area. The purpose of this study is to determine the<br />
allometric exp<strong>on</strong>ent for identified species of fish, specific to the habitat, and the estimati<strong>on</strong><br />
of correlati<strong>on</strong>s between this parameter and the degree of polluti<strong>on</strong>, in order to identify<br />
species with a high risk to envir<strong>on</strong>mental stress. Analyzing allometric scaling values (α)<br />
with specific analytical methods for captured fish populati<strong>on</strong>s in these areas we c<strong>on</strong>cluded<br />
that the characteristic values of this parameter for some species is str<strong>on</strong>gly affected in time<br />
by the presence of pollutants factors. For some species, the allometric parameter decreased<br />
between 2004 and 2008, but in the polluted z<strong>on</strong>e, the decrease was higher than in the<br />
unpolluted z<strong>on</strong>e. For example, for Squalius cephalus the parameter’s value was<br />
3.0319/3.342 (unpolluted/polluted z<strong>on</strong>e) in 2004 and 2.9888/2.7934 in 2008 and for<br />
Barbus petenyi α was 3.2050/3.2468 in 2004 and 2.7486/2.6217 in 2008. For some species<br />
the changes in the development process were significant, the important decrease of<br />
allometric scaling value indicating that these species were affected by the envir<strong>on</strong>mental<br />
stress. In this category must be presented the case of Sabanejewia balcanica, with<br />
remarkable changes: from 3.9547 in 2008 in unpolluted area α value drops to 0.9066 in the<br />
polluted area in the same year. Significant interacti<strong>on</strong> between envir<strong>on</strong>mental c<strong>on</strong>diti<strong>on</strong>s<br />
and a certain type of species was c<strong>on</strong>firmed by Three-Way ANOVA test (F=3.893, df = 4,<br />
p = 0.019).<br />
Key words: allometry, fish, regressi<strong>on</strong>, polluti<strong>on</strong>.<br />
89
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
INCREASE RISK OF VARY DISEASE FREQUENCY<br />
CORRELATED WITH AIR POLLUTANTS IN BACAU CITY<br />
DURING 2011 YEAR<br />
Alina Diac<strong>on</strong>escu 1 , Iuliana Lazar 2 , Ema Faciu 1 , Andreea Cocarcea 1<br />
1 “Vasile Alecsandri” University of Bacau, Department of Mechanical and<br />
Envir<strong>on</strong>mental Engineering<br />
2 “Vasile Alecsandri” University of Bacau, Department of Chemical and Food Engineering<br />
Corresp<strong>on</strong>ding author: Iuliana Lazar, ilazar@ub.ro<br />
Abstract: Potential effects of climate variability can be felt in the distributi<strong>on</strong>, transport<br />
and c<strong>on</strong>centrati<strong>on</strong> of air pollutants. Epidemiological studies have shown that air pollutants,<br />
differing in their chemical compositi<strong>on</strong>, reacti<strong>on</strong> properties, emissi<strong>on</strong>, and persistence in<br />
the envir<strong>on</strong>ment, ability to be transported in l<strong>on</strong>g or short distances are associated with a<br />
wide range of effects <strong>on</strong> human health, such as respiratory system, cardiovascular system,<br />
nervous system, urinary system and digestive system. This study evaluated the associati<strong>on</strong><br />
between daily levels of air pollutants, such as NO, NOx, NO2, CO, SO, O3, NH3, PM2.5,<br />
PM10 and meteorological data (wind directi<strong>on</strong>, wind speed, air temperature, air pressure,<br />
humidity) <strong>on</strong> cases of illness, from January 2011 to December 2011. Using a descriptive<br />
statistics in SPSS program (Statistical Package for the Social Sciences), we analyzed<br />
possible associati<strong>on</strong>s between the mean air pollutants and the rate of cases of health effects<br />
during the year 2011. The statistics data was performed using ANOVA One-away method<br />
with Tukey’s-b test. The results using these method show the following aspect: the mean<br />
of pollutants (NO, NOx, NO2, CO, PM2.5, PM10), meteorological parameters (wind<br />
directi<strong>on</strong>, air humidity and air pressure) and health diseases (rheumatics, heart diseases,<br />
infectious disease, diabetes) was recorded maximum values in winter time (1 january-30<br />
marts2011). In the case of oz<strong>on</strong>e and sulphur dioxide did not shown links between their<br />
maximum values with cases of health diseases. This data study has shown how daily<br />
variati<strong>on</strong> of air pollutants have significantly effects <strong>on</strong> people’s health. Another method for<br />
analyze the statistics data used in this study was the bivariate correlati<strong>on</strong>. In the case of<br />
positive values generated, can observe a significant correlati<strong>on</strong> between health diseases<br />
and air pollutants as follows: rheumatics and NO2; heart diseases and NOx, NO, NO2, O3,<br />
PM10, CO; diabetes and NO, Ox, NO2, O3;, infectious disease and NO2, PM10;<br />
respiratory diseases and SO, NO2, air temperature, air humidity; urology diseases and SO,<br />
NO, PM10, air temperature, air humidity. A very significant correlati<strong>on</strong> resulted of<br />
analysis between O3 and neurology, endocrinology, gastrointestinal disease. There is no<br />
correlati<strong>on</strong> between PM 2.5 and endocrinology disease and gastrointestinal disease. In the<br />
case of negative values generated, it has revealed a very significant correlati<strong>on</strong> between air<br />
pressure and all health disease analyzed in this study. Between CO and diabetes,<br />
respiratory diseases and urology diseases not found any correlati<strong>on</strong>. Results presented here<br />
suggests that elevated levels of air pollutants (below the current limits set by the<br />
Envir<strong>on</strong>mental Protecti<strong>on</strong> Agency), are associated with an increase in the rate of health<br />
effects; but some results presented above also reveal a n<strong>on</strong> correlati<strong>on</strong> between some air<br />
pollutants such as CO, air pressure, PM 2.5 and health diseases.<br />
90
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
AIIIBVI BASED PHOTOVOLTAIC RECEPTORS FOR<br />
EXPERIMENTAL DETERMINATION OF CARBON<br />
COMPOUNDS IN ATMOSPHERE<br />
Igor Evtodiev 1 , Oxana Racovet 1 , Iuliana Caraman 2 , Marius Stamate 2<br />
1 The Laboratory of Scientific Research "Phot<strong>on</strong>ics and Metrology Physics",<br />
Moldova State University<br />
2 “Vasile Alecsandri” University of Bacau<br />
Corresp<strong>on</strong>ding author: Oxana Racoveţ, racovetoxana@gmail.com<br />
Abstract: C<strong>on</strong>sequently there are emitting enormous quantities of carb<strong>on</strong> toxic compounds<br />
(CO, CO2, CN). The development rhythm of human activity sets significant envir<strong>on</strong>ment<br />
problems. After estimati<strong>on</strong>s made at XX century end [1] humanity uses <strong>on</strong>ly energetic<br />
resources, more than 2*10 17 kJ, except other activities which degrades the envir<strong>on</strong>ment.<br />
That this why it’s an important actuality problem the c<strong>on</strong>trol of atmosphere compositi<strong>on</strong><br />
modificati<strong>on</strong>s through elaborating of new diagnostic methods. In the paper work we<br />
examine the perspective of photovoltaic cells of stratified semic<strong>on</strong>ductors A III B VI using as<br />
light selective receptors. Carb<strong>on</strong> compounds in gaseous stare forms solar radiati<strong>on</strong><br />
absorpti<strong>on</strong> bands into a large spectrum domain (200÷100000) cm -1 . The intensity of<br />
absorbed light in these bands is direct proporti<strong>on</strong>al with the respective molecules<br />
c<strong>on</strong>centrati<strong>on</strong>, but the frequency corresp<strong>on</strong>ding to the maximals of these bands are values<br />
characteristic to absorbed molecules. Thus by light intensity measuring from sun spectrum<br />
(or another light source) is obtained the informati<strong>on</strong> about the light type and absorpti<strong>on</strong><br />
c<strong>on</strong>centrati<strong>on</strong>. The main scheme of an optic measurement of gases c<strong>on</strong>sists of the light<br />
source and a selective receptor of radiati<strong>on</strong>. The identificati<strong>on</strong> accuracy of the molecules<br />
type from the column through which is spreading the radiati<strong>on</strong> is determined by the width<br />
of the light outline band recorded and by the integral sensibility. Fundamental absorpti<strong>on</strong><br />
bands of CO, CO2, CN carb<strong>on</strong>ate are in domain of IR medium (1000÷3500) cm -1 . The<br />
harm<strong>on</strong>ics from the superior order of these gases atoms vibrati<strong>on</strong> are at the red limit of the<br />
visible (780÷900) nm, regi<strong>on</strong> which correlates well with fundamental absorpti<strong>on</strong> band of<br />
indium selenide. In the paper work is studded the dependence of the photocurrent<br />
generated by the heterojuncti<strong>on</strong> In2O3-InSe with interferential filter (Δλ=12 nm)<br />
independence of the CO and CN molecules c<strong>on</strong>centrati<strong>on</strong> in normal atmosphere. It was<br />
established that for the light source of A (T=2870 K) type, InSe- In2O3 receptor and filter<br />
with the width 12 nm at λ0=798,5 nm is obtaining a photocurrent linear dependence of CO<br />
molecules pressure in (10÷100) mm Hg limits. Investigati<strong>on</strong>s were made in the Laboratory<br />
of Scientific Research "Phot<strong>on</strong>ics and Metrology Physics", Moldova State University.<br />
Key words: absorpti<strong>on</strong> band, receptor, sensibility, energy, light.<br />
91
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
QUANTITATIVE DETERMINATIONS OF CARBON OXIDES<br />
<strong>FROM</strong> ATMOSPHERE AFTER ELECTRONIC ABSORPTION<br />
SPECTRA<br />
Iuliana Caraman 1 , Oxana Racovet 2 , Dumitru Untila 2 , Silvia Evtodiev 2 ,<br />
Marius Stamate 1<br />
1 “Vasile Alecsandri” University of Bacau. Romania<br />
2 Laboratory of Scientific Research "Phot<strong>on</strong>ics and Metrology Physics",<br />
Moldova State University<br />
Corresp<strong>on</strong>ding author: Iuliana Caraman, iucaraman@yahoo.ca<br />
Abstract: In the process of carb<strong>on</strong>ates burning and different chemical reacti<strong>on</strong>s with<br />
organic compounds participating are forming diverse CO2 and CO carb<strong>on</strong> oxides. These<br />
gases c<strong>on</strong>centrati<strong>on</strong> relati<strong>on</strong> determines in a meaningful measure the level of alimentary<br />
products fermentati<strong>on</strong> process. So, different technologic processes c<strong>on</strong>ducting are<br />
necessary quantitative determinati<strong>on</strong>s of carb<strong>on</strong> oxides c<strong>on</strong>centrati<strong>on</strong> (CO2, CO). In<br />
present are elaborated chemical methods of measuring, but these need much time and<br />
special equipment. This shortcoming it is not characteristic for optical methods after<br />
absorpti<strong>on</strong> spectrums. As it was dem<strong>on</strong>strated through experimental measurements, CO2<br />
and CO molecules d<strong>on</strong>’t posed absorpti<strong>on</strong> electr<strong>on</strong>ic bands in visible domain and UV near<br />
spectrum. The first electr<strong>on</strong>ic stare, absolute gap, of CO2 molecule (stare 2 Σ + g) is found at<br />
45320cm -1 higher than fundamental stare 2 П3/2. Thus, fundamental absorpti<strong>on</strong> band of this<br />
molecule is in the vacuum UV regi<strong>on</strong> (70000 ÷64000) cm -1 . In the paperwork it is analyzed<br />
the intensity of the first overt<strong>on</strong>e of the vibrati<strong>on</strong> bands v”=0 → v’=1 in dependence of the<br />
CO2 and CO molecules c<strong>on</strong>centrati<strong>on</strong> in atmosphere. These bands for CO2 and CO<br />
molecules are situated respectively at ~ 4260 cm -1 and ~ 4700 cm -1 . Both absorpti<strong>on</strong> bands<br />
<strong>on</strong> the 2168 cm - 1and 2347 cm -1 basis respective for CO2 and CO molecules and first<br />
overt<strong>on</strong>e represent bands with two branches P and R. for quantitative determinati<strong>on</strong>s of<br />
these gases c<strong>on</strong>centrati<strong>on</strong> in atmosphere was took the intensities ratio in the P branch<br />
maximum of the R branch and the absorpti<strong>on</strong> intensity at 50 cm -1 from these maximums in<br />
dependence of the gases c<strong>on</strong>centrati<strong>on</strong> in atmosphere. Also, for verificati<strong>on</strong> there were<br />
analyzed the P and R branches intensity ratio from the CO2 and CO molecules absorpti<strong>on</strong><br />
spectrums and the intensity at the maximum of vibrati<strong>on</strong>-rotati<strong>on</strong> band of water vapors<br />
from atmosphere. It was established the c<strong>on</strong>centrati<strong>on</strong>s interval in which take place linear<br />
dependence of the intensities ratio of CO2 and CO molecules c<strong>on</strong>centrati<strong>on</strong> in normal<br />
atmosphere. Investigati<strong>on</strong>s were made in the Laboratory of Scientific Research "Phot<strong>on</strong>ics<br />
and Metrology Physics", Moldova State University.<br />
Key words: carb<strong>on</strong>, c<strong>on</strong>centrati<strong>on</strong>, absorpti<strong>on</strong> band, vibrati<strong>on</strong>-rotati<strong>on</strong>.<br />
92
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
RISK OF MYOCARDIAL INFARCTION REVEALED BY<br />
VARIATION OF CARDIAC TROPONIN I LEVELS WITH AGE<br />
AND GENDER: A STUDY OF PATIENTS HOSPITALIZED IN<br />
THE CARDIOLOGY DEPARTMENT OF BACAU CITY<br />
HOSPITAL DURING THE 2008-2011 PERIOD<br />
Laura Vasile 1 , Vlad Artenie 1 , Iuliana Lazar 2<br />
1 ”Al. I. Cuza” University, Department of Molecular Biology and Biochemistry<br />
2 ”Vasile Alecsandri” University of Bacau, Department of Chemical and Food Engineering<br />
Corresp<strong>on</strong>ding author: Iuliana Lazar, ilazar@ub.ro<br />
Abstract Cardiac trop<strong>on</strong>in (cTn) is a reference biomarker for the diagnosis of myocardial<br />
necrosis. Cardiac trop<strong>on</strong>in I (cTnI) is a key regulatory protein in cardiac muscle<br />
c<strong>on</strong>tracti<strong>on</strong> linking Ca2+-cTn combining it with cross-bridge activati<strong>on</strong> reacti<strong>on</strong> between<br />
thin and thick filaments. The cTn inhibits actomyosin ATP leading to muscle relaxati<strong>on</strong> by<br />
disrupting the actin-myosin b<strong>on</strong>d. Due to cor<strong>on</strong>ary absolute specificity and high sensitivity,<br />
cardiac Trop<strong>on</strong>in I helps to c<strong>on</strong>firm, even when the acute event happened two weeks ago.<br />
Our study includes 65 patients with myocardial infarcti<strong>on</strong>, hospitalized in the cardiology<br />
department of Bacau City Hospital, of which 20 patients are women and 45 patients are<br />
men. The purpose of this study was to compare the value of cTnI between the two sexes<br />
with the same diagnosis and early diagnosis of myocardial infarcti<strong>on</strong>. High values of<br />
trop<strong>on</strong>in in patients revealed a higher risk for development of cardiac events during short<br />
and l<strong>on</strong>g term, therefore being necessary the use of this test. Most healthy people have not<br />
detectable cTnI. Values between 0.3 µg/L and 2.0 µg/L are c<strong>on</strong>sidered limit values. Values<br />
higher than 2.0 µg/L are c<strong>on</strong>sidered as signs of myocardial infarcti<strong>on</strong>. In our study cardiac<br />
Trop<strong>on</strong>in was analyzed by immuno-analyzer Pathfast compact device. Parametric One-<br />
Sample Tests and Error Bar T test are used to compare the mean of cTnI values by age and<br />
sex that differ significantly from the 2.0 mg/L limit value. Following trop<strong>on</strong>in level in<br />
subjects grouped by gender shows that in women the cTnl level increases progressively<br />
with age, approaching normal at the 36-50 years age group and that of 51-65 years. In the<br />
>65 years group there are registered values above the maximum allowable (ie mean of 3.56<br />
µg / L). The minimum values are registered at the female patients between 51-65 years,<br />
where the average is 0.08 µg / L, so is within normal limits. The highest risk was observed<br />
with predilecti<strong>on</strong> in males. The performed analysis shows warning for the 36-50 years age<br />
groups and 51-65 years for males as being at risk of myocardial ischemia. In c<strong>on</strong>clusi<strong>on</strong>,<br />
this study shows the age and gender of patients with an increased risk of myocardial<br />
infarcti<strong>on</strong> hospitalized in the cardiology department of Bacau City Hospital, and in men<br />
the age from which a much lower potential risk can occur (i.e. over 35 years) compared to<br />
women (i.e. over 65).<br />
Keywords: Cardiac Trop<strong>on</strong>in I, myocardial infarcti<strong>on</strong>, dispersi<strong>on</strong> parameter, age, gender.<br />
93
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
ANALYSIS OF ESSENTIAL MINERAL CONTENT IN<br />
DIFFERENT TYPES OF FLOUR<br />
Iuliana Lazar 1 , Iuliana Caraman 2 , Alina Moroi 1<br />
1 ”Vasile Alecsandri” University of Bacau, Department of Chemical and Food Engineering<br />
2 ”Vasile Alecsandri” University of Bacau, Department of Mechanical and Envir<strong>on</strong>mental<br />
Engineering<br />
Corresp<strong>on</strong>ding author: Iuliana Caraman, iuliana.caraman@ub.ro<br />
Abstract: Wheat grains c<strong>on</strong>tain a significant amount of minerals unevenly distributed in<br />
parts of the grain. Peripheral layers which usually are removed in the process of grinding<br />
as brans are richer in mineral c<strong>on</strong>tent. Magnesium Mg is <strong>on</strong>e of the vital minerals in the<br />
development of many metabolic functi<strong>on</strong>s, its deficiency accelerating the aging process.<br />
Calcium also plays an important role in intracellular and extracellular metabolism that<br />
c<strong>on</strong>trols processes such as nerve c<strong>on</strong>ducti<strong>on</strong>, muscle c<strong>on</strong>tracti<strong>on</strong>, coagulati<strong>on</strong>, regulati<strong>on</strong> of<br />
electrolytes and enzymes and horm<strong>on</strong>e release. Another inorganic element that is found in<br />
flour is phosphorus, which occurs in metabolism. The value of the c<strong>on</strong>tent in the ash, both<br />
in wheat but especially in flour is a basic quality index which varies depending <strong>on</strong> the flour<br />
extracti<strong>on</strong>. However, there are few studies that report data about the type and quantities of<br />
inorganic substances c<strong>on</strong>tained in flour ash. In this study we propose to detail some of the<br />
existing minerals in the ash by methods of emissi<strong>on</strong> and infrared spectroscopy, and<br />
multivariate analysis. The differentiati<strong>on</strong> of the PO4 groups’ c<strong>on</strong>tent was emphasized in<br />
chemometric analysis of infrared spectra. There were analyzed three sets of samples: group<br />
1 provided by Agricultural Research Center Secuieni, Neamţ (Romania): Crina, Dropia,<br />
Flamura, Gruia, Haiduc, and group 2 provided by local market (FAB Baneasa white flour,<br />
dark flour Careffour FNC and dark flour Baneasa FNB) and group 3 provided by wheat<br />
from Vaslui area. The flour samples assigned to group 1 and group 3 were obtained by<br />
milling the wheat at the ZM 200 RETSCH ultracentrifuge mill. Hierarchical cluster<br />
analysis procedure identifies relatively homogeneous groups of cases after certain features<br />
are selected, using an algorithm that starts with each case in a separate group, combining<br />
groups until <strong>on</strong>ly <strong>on</strong>e remains. Distance or similar measures are generated by the<br />
Proximities procedure. Between group linkage cluster method and Euclidean distance<br />
interval were used. Chemometric analysis emphasizes that the evidence FAB, FNC and<br />
FNB are associated through the Mg c<strong>on</strong>tent. In Ca case, for samples from group 2 <strong>on</strong>ly<br />
FNC and FNB show comm<strong>on</strong> characteristics. Chemometric analysis results indicate that<br />
the FNC sample has high phosphorus c<strong>on</strong>tent. Two samples of group 1 were identified<br />
with a low Ca and Mg c<strong>on</strong>tent. In our opini<strong>on</strong> the identificati<strong>on</strong> of the Mg, Ca, P amount<br />
from flour in additi<strong>on</strong> to ash c<strong>on</strong>tent may be very useful for health.<br />
Keywords: mineral, spectroscopy, cluster analysis, metabolism.<br />
94
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
ASSESSING THE CRACKING RISK AT TUBULAR<br />
JUNCTIONS OF THE TECHNOLOGICAL ROUTES USED IN<br />
NUCLEAR POWER PLANTS<br />
Adrian Judele, Valentin Zichil<br />
“Vasile Alecsandri” University of Bacau, Department of Engineering and Management of<br />
Mechanical Systems<br />
Corresp<strong>on</strong>ding author: Valentin Zichil, valentinz@ub.ro<br />
Abstract: In the United States there were at least 56 accidents in nuclear power plants until<br />
2010 <strong>–</strong> according to the Associati<strong>on</strong> of Energy Services Professi<strong>on</strong>als Survey. Tubular<br />
branched structures are a comm<strong>on</strong> alternative for technological pipe systems, used for<br />
transportati<strong>on</strong> of fuel elements and the primary coolant of a nuclear reactor. All nuclear<br />
power plants have an emergency makeup water system with the following major<br />
comp<strong>on</strong>ents: water supplies (tanks), pumps, interc<strong>on</strong>necting piping. Reactor pressure tubes<br />
- the tubes that are specially designed or prepared to c<strong>on</strong>tain fuel elements and the primary<br />
coolant of a nuclear reactor <strong>–</strong> forms many kilometers of cascade piping, incorporating<br />
thousands of welds that present a high degree of repetiti<strong>on</strong>. Most part of those tubes is<br />
buried, supporting no other external force, except the ground weight. The tubular branched<br />
structures works at 5.1 MPa (or higher) internal pressure. The Nuclear Regulatory<br />
Commissi<strong>on</strong> imposes inspecti<strong>on</strong> and testing requirements laid out in agency regulati<strong>on</strong>s<br />
and standards from the American Society of Mechanical Engineers. The nuclear plant in<br />
Cernavoda is based <strong>on</strong> the CANDU system (Canada Deuterium Uranium). The fuel<br />
channels c<strong>on</strong>taining fuel and heavy water used as coolant are underground located and<br />
higher in calandria tubes. The safety standards call for regular flow testing and other<br />
surveillance for buried safety-related pipes. If leaks are detected, the risk of c<strong>on</strong>taminati<strong>on</strong><br />
is high. Tubular branched structures, under specific loads, due to geometrical<br />
disc<strong>on</strong>tinuities, they show str<strong>on</strong>g c<strong>on</strong>centrati<strong>on</strong> of mechanical stresses. The presence of<br />
welded surfaces involves a more complicated distributi<strong>on</strong> of the mechanical stress,<br />
compared with the corresp<strong>on</strong>ding distributi<strong>on</strong> for the typical elements, even at low<br />
pressures. There are some studies and researches showing the stress c<strong>on</strong>centrator in the<br />
middle of the welding rim, but the authors shows in this paper the influence of the<br />
geometrical disc<strong>on</strong>tinuities in the variati<strong>on</strong> of the stress c<strong>on</strong>centrator in the immediate<br />
vicinity. An experimental research was c<strong>on</strong>ducted up<strong>on</strong> the pipelines at 45 0 branched. The<br />
experimental results up<strong>on</strong> stress and strain were used to validate a numerical model that<br />
was used to analyze other angles for branched structures, low pressurized. The<br />
c<strong>on</strong>sequences of this paper are given by the possibility to determinate the risk of leak due<br />
to the crack appearance at buried tubular branched structures with less informati<strong>on</strong>: the<br />
geometry of the structure and the internal pressure.<br />
Keywords: tubular branched structures, crack risk, geometrical disc<strong>on</strong>tinuities.<br />
95
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
AVOIDING <strong>RISKS</strong> IN SOLID-GAS DEPOLLUTION BY<br />
CONTROLLING PARAMETERS IN FLUIDIZED BED<br />
Gabriela Muntianu 1 , Ileana Denisa Nistor 1 , Cosmin Jinescu 2 ,<br />
Gholamreza Djelveh 3<br />
1 “Vasile Alecsandri” University of Bacau, Department of Chemical and Food Engineering,<br />
Romania<br />
2 Politehnica University of Bucharest, Departament of Mechanical Engineering, Romania<br />
3 ENSCCF, LGCB, BP 206, Clerm<strong>on</strong>t Universite´, France<br />
Corresp<strong>on</strong>ding author: Ileana Denisa Nistor, denisanistor@yahoo.com; dnistor@ub.ro<br />
Abstract: The paper aims to avoid possible and emerging risk in gas depolluti<strong>on</strong> processes.<br />
To achieve this desiderate the main technological parameters used in gas-solid depolluti<strong>on</strong><br />
processes with process intensificati<strong>on</strong> by using fluidizati<strong>on</strong> bed are studied. The use of the<br />
fluidizati<strong>on</strong> bed as intensificati<strong>on</strong> technique in gas depolluti<strong>on</strong> provides higher<br />
performance but also inc<strong>on</strong>veniences in the bed granular structure. At higher flow<br />
velocities of the fluidizati<strong>on</strong> agent gas bubbles that are distributed uniformly in the column<br />
appear and their diameter increases slightly with the gas velocity. Gas bubbles create a<br />
str<strong>on</strong>g turbulence in the bed, which induces a str<strong>on</strong>g mixing of solid phase and determines<br />
permanent fluctuati<strong>on</strong>s of the fluidized bed height. Al<strong>on</strong>g with the increasing gas flow,<br />
pist<strong>on</strong>s appear, leading to turbulent fluidizati<strong>on</strong> regime. Bed structure vitiati<strong>on</strong>s, pist<strong>on</strong>s<br />
and total or intermediate channels appear as particular aspect of n<strong>on</strong>-homogeneous<br />
fluidizati<strong>on</strong>. The structure of the fluidizati<strong>on</strong> bed that is the main characterizati<strong>on</strong> index of<br />
this technique also represents the main obstacle that limits the applicati<strong>on</strong>s in gas<br />
remediati<strong>on</strong>. Practical applicati<strong>on</strong>s of fluidized bed and the difficulties created by the<br />
uneven structure of the bed, directed the research efforts towards the realizati<strong>on</strong> of a<br />
fluidized homogeneous structure, increasing the efficiency of this technique in the<br />
remediati<strong>on</strong> of gasses. Homogeneous fluidizati<strong>on</strong> is characterized by a single and uniform<br />
distributi<strong>on</strong> of solid particles in bed and a uniform expansi<strong>on</strong> of it. The distance between<br />
solid particle increases with the velocity of the flow agent and the homogeneous fluidized<br />
bed can be assimilated as a boiling liquid. Hydrodynamic parameters c<strong>on</strong>trolled in the<br />
fluidized bed were diameter and density of solid particles, velocity of the fluidizati<strong>on</strong> agent<br />
and the ratio between the height of fixed bed and diameter of fluidizati<strong>on</strong> column. The<br />
paper proposes combining the advantages possessed by the natural clays (calcium and<br />
sodium clay) as solid particles through the fluidizati<strong>on</strong> technique in order to improve the<br />
gas remediati<strong>on</strong> process.<br />
Keywords: process intensificati<strong>on</strong>, fluidizati<strong>on</strong> properties, solid particle, fixed bed, fluidized bed.<br />
96
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
FRIENDLY ENVIRONMENTAL TECHNIQUES USED TO<br />
IMPROVE THE EFFICIENCY OF EXTRACTION <strong>FROM</strong> LULA<br />
(PERSIA AMERICANA)<br />
B. U. Saha 1, 2 , G. Kansci 1 , E. Fokou 1 , I. M. Lazar 2 , F. X. Etoa 1<br />
1 University of Yaoundé I, Camero<strong>on</strong>, Department of Biochemistry<br />
1 ”Vasile Alecsandri” University of Bacau, Department of Chemical and Food Engineering,<br />
Romania<br />
Corresp<strong>on</strong>ding author: Brice Ulrich Saha Foudjo, sahabrice@yahoo.fr<br />
Abstract: Camero<strong>on</strong> is <strong>on</strong>e of the best avocado producers in Africa. However, for a few<br />
years, it has been noticed that local markets have oriented their demands towards some<br />
specific varieties, leaving aside others that are less appreciated by c<strong>on</strong>sumers. If nothing is<br />
d<strong>on</strong>e, the c<strong>on</strong>sequence will be the increase of Camero<strong>on</strong>-grown avocado post-harvest<br />
losses. Therefore, redefining an existing extracti<strong>on</strong> method that takes in c<strong>on</strong>siderati<strong>on</strong> the<br />
financial worries of producers, the envir<strong>on</strong>ment related issues of solvent use and the<br />
balance that should exist between having a high yield and gaining excellent functi<strong>on</strong>al<br />
properties will be a breakthrough for Camero<strong>on</strong>. Am<strong>on</strong>g extracti<strong>on</strong> techniques, the<br />
aqueous extracti<strong>on</strong> method, less expensive and n<strong>on</strong>-pollutant, leads unfortunately to a very<br />
low yield. This study aims to improve the yield of avocado oil extracti<strong>on</strong> with this<br />
aforementi<strong>on</strong>ed friendly envir<strong>on</strong>mental technique. The avocado cultivar Lula, harvested <strong>on</strong><br />
the farm of the Nati<strong>on</strong>al Research Institute of Agriculture and Development in Foumbot<br />
(Camero<strong>on</strong>), was used for oil extracti<strong>on</strong>. Lipid c<strong>on</strong>tent was first assessed with the Soxhlet<br />
method, and then water extracti<strong>on</strong> process, relying <strong>on</strong> Bizimana et al. method (1993), was<br />
performed. From it, the oil yield was obtained and the extracti<strong>on</strong> efficiency EE, oil yield to<br />
lipid c<strong>on</strong>tent, was deduced. The effect of four factors <strong>on</strong> water oil extracti<strong>on</strong>, namely:<br />
temperature (T), time (t), pH and water-to-pulp ratio (WPR), was investigated. A two-level<br />
full factorial design 2 4 , was c<strong>on</strong>ducted to describe a first order mechanism of the extracti<strong>on</strong><br />
kinetic under the resp<strong>on</strong>se surface methodology (Barros et al., 1996). The results showed<br />
that T, WPR and t had a positive effect <strong>on</strong> the yield whereas the pH had a negative effect<br />
<strong>on</strong> the entire process. The mathematical model that fitted a first order regressi<strong>on</strong> equati<strong>on</strong><br />
is EE=29.6821+ 3.7291*T + 1.0229*t <strong>–</strong> 3.9868*pH + 2.3599*WPR. It shows the effect of<br />
the individual parameters. The optimal c<strong>on</strong>diti<strong>on</strong>s for oil extracti<strong>on</strong> WPR=4, pH=4.5,<br />
T=55°C and t=180 min were found. The highest extracti<strong>on</strong> efficiency obtained was<br />
40.78%. The model obtained in this study has well defined the extracti<strong>on</strong> procedure and<br />
the aqueous medium was found to be suitable for avocado oil producti<strong>on</strong> with good<br />
efficiency with respect to our criteria.<br />
Keywords: avocado, oil yield, extracti<strong>on</strong>, optimizati<strong>on</strong>, resp<strong>on</strong>se surface methodology, envir<strong>on</strong>ment.<br />
97
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
DIABETES MELLITUS COMPLICATIONS RISK ASSESSED<br />
BY RED BLOOD CELL FTIR PARAMETERS<br />
M. Gutu 1 , M. Avadanei 2 , V. Rusu 1 , S. Mir<strong>on</strong> 1 , I. Hurjui 1 , I. Grierosu 1 ,<br />
C. Stefanescu 1<br />
1 University of Medicine and Pharmacy Iasi “Gr. T. Popa”, Faculty of Medicine, Department of<br />
Biophysics and Medical Physics, Iasi<br />
2 “ Petru P<strong>on</strong>i” Institute of Macromolecular Chemistry, Iasi<br />
Corresp<strong>on</strong>ding author: Mihai Gutu, misugutu@yahoo.com<br />
Abstract: The aim of our study was to determine whether informati<strong>on</strong> obtained by FTIR<br />
spectral analysis, may be correlated to serum parameters that can be used for diabetes<br />
mellitus complicati<strong>on</strong>s risk evaluati<strong>on</strong>.<br />
Material and methods: Two study groups were analyzed. Group 1 c<strong>on</strong>sists of 43 subjects<br />
clinically healthy, for which analytical blood counts (red blood cell number, leukocyte<br />
number, hematocrit (Hct), hemoglobin (Hb), erythrocyte mean volume (MCV), mean<br />
erythrocyte hemoglobin (HEM) and some serum biochemical compounds were dosed<br />
(serum cholesterol, serum triglycerides, glucose). Group 2 c<strong>on</strong>sists of 21 patients<br />
diagnosed with complicated type II diabetes. Patients were hospitalized at the Diabetes and<br />
nutriti<strong>on</strong> diseases clinic, County Emergency Hospital "St. Spirid<strong>on</strong>" Iasi in 2011 as<br />
emergency. Besides the usual biochemical serum parameters (cholesterol, triglycerides,<br />
glucose) we c<strong>on</strong>sidered serum fibrinogen and glycosilated hemoglobin determinati<strong>on</strong>.<br />
Erythrocyte samples were analyzed by FTIR spectroscopy by performing erythrocyte films<br />
made of 5 µL sample <strong>on</strong> the support KRS-5 (thallium bromide ioyide), by drying in<br />
vacuum (5 mmHg at 20˚C). Correlati<strong>on</strong>s between serum parameters, age and FTIR spectral<br />
parameters of erythrocyte membrane were assessed.<br />
Results show that erythrocyte membrane could be related to the degree of c<strong>on</strong>trol of<br />
diabetes by following spectral parameters and serum parameters specific to diabetes<br />
(glycosylated hemoglobin and glucose). There is a relati<strong>on</strong> between ν(=CH)/ν(CHtotal)<br />
(global degree of unsaturati<strong>on</strong> lipid) str<strong>on</strong>gly and significantly correlated with blood<br />
glucose (r = -0.624, p
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
MULTIVARIATE ANALYSIS OF PHYSICO-CHEMICAL<br />
DATA CHARACTERISTICS OF WASTES WITH POTENTIAL<br />
RADIOACTIVE RISK NEAR BACAU CITY<br />
Sorina Zirnea 1 , Iuliana Lazar 2 , Brice Ulrich Saha Foudjo 2, 3 , Gabriel Lazar 1<br />
1 “Vasile Alecsandri” University of Bacau, Department of Mechanical and Envir<strong>on</strong>mental<br />
Engineering<br />
2 “Vasile Alecsandri” University of Bacau, Department of Chemical and Food Engineering<br />
3 University of Yaoundé I, Camero<strong>on</strong> , Dep. of Biochemistry<br />
Corresp<strong>on</strong>ding author: Sorina Zirnea, sorina.zirnea@ub.ro<br />
Abstract: An important envir<strong>on</strong>mental issue for Romania is the industrial wastes and their<br />
reintroducti<strong>on</strong> in business and in all its sectors. The problem of valorizati<strong>on</strong> of these wastes<br />
is currently discussed under technical and ec<strong>on</strong>omic, and in particular ecological aspects.<br />
A specific case of hazardous waste is the radioactive waste. Am<strong>on</strong>g the main types of<br />
hazardous waste present in appreciable quantities in our country are those generated by the<br />
chemical industry sector prevailing the waste of soda ash (Alba, Dolj and Valcea County)<br />
and phosphogypsum (Bacau County). Phosphogypsum is a waste by-product of phosphoric<br />
acid (H3PO4), an essential comp<strong>on</strong>ent used in the fertilizer industry is mostly disposed of<br />
without any treatment, usually being disposed in phosphogypsum dumps in close to<br />
phosphoric acid plants or being thrown into water or recycled. Per t<strong>on</strong>ne of phosphoric<br />
acid produced are generated about five t<strong>on</strong>es of phosphogypsum. In 2007, the study of<br />
characterizati<strong>on</strong> of phosphogypsum from Platform Sofert S.A. Bacau, made by I.C.I.M.<br />
Bucharest, shows that in terms of chemical compositi<strong>on</strong>, the waste is not hazardous<br />
because it c<strong>on</strong>tains heavy metals (0.1%) and mineral compounds of phosphorus (0.367 to<br />
0.473%). Thus, in 2007 following physico-chemical parameters of phosphogypsum<br />
samples: humidity, loss <strong>on</strong> calcinati<strong>on</strong>s and silica, phosphorus c<strong>on</strong>tent, alkali metals<br />
c<strong>on</strong>tent, alkaline earth and heavy metals after specific mineralizati<strong>on</strong> for each metal were<br />
analyzed in accordance to applicable standards. Until now, such analysis was not repeated.<br />
Further investigati<strong>on</strong> was c<strong>on</strong>ducted by Regi<strong>on</strong>al Agency of Envir<strong>on</strong>mental Protecti<strong>on</strong><br />
Bacau (RAEP) and was limited to measuring β radioactivity of phosphogypsum and soil<br />
samples using the CMR beta measuring system with ND-304 scintillati<strong>on</strong> probe. In this<br />
study our aim is to analyze public data from this area in order to be able to make a<br />
descriptive statistics interpretati<strong>on</strong> and perform a cluster analysis to identify potential risks<br />
and correlati<strong>on</strong>s. Evaluati<strong>on</strong> of potential characteristics of taken samples was performed<br />
using analytical hierarchy process (AHP) and cluster analysis. The results obtained<br />
revealed a marked reducti<strong>on</strong> of radioactivity in the soil in 2011 but also an increase over<br />
the average radioactivity in the phosphogypsum during the years 2007-2010. From this<br />
preliminary analysis we notice the need to resume a complex analysis at the envir<strong>on</strong>ment<br />
level in the area of the potential risk of radioactive c<strong>on</strong>taminati<strong>on</strong>.<br />
Keywords: phosphogypsum, β radioactivity, descriptive statistics, cluster analysis.<br />
99
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
STUDY REGARDING THE INFLUENCE OF NUTRIENTS<br />
OVER THE WATER OF BISTRITA RIVER, ON THE HIGHLY<br />
MODIFIED SECTOR BETWEEN PIATRA NEAMT AND<br />
BACAU<br />
Dan Dascalita 1 , Greta Ardeleanu 2<br />
1 “Vasile Alecsandri” University of Bacau, Department of the Envir<strong>on</strong>ment Engineering and<br />
Mechanical Engineering<br />
2 Administrati<strong>on</strong> of Siret Basinal Water<br />
Corresp<strong>on</strong>ding author: Dan Dascalita, dan_dsclt@yahoo.com<br />
Abstract: Industrial activities and human c<strong>on</strong>gesti<strong>on</strong>s produce significant quantities of<br />
specific pollutants, which, unless highly purified, get into surface water resources and<br />
influence their quality. When the quantity of pollutants exceed some limits, the natural self<br />
defence procedures can no l<strong>on</strong>ger take place and the underwater and terrestrial<br />
envir<strong>on</strong>ment are affected for a l<strong>on</strong>g and very l<strong>on</strong>g term. In this paper we studied the<br />
evoluti<strong>on</strong> of the quality of water in Bistrita River, <strong>on</strong> the Piatra Neamt <strong>–</strong> Bacau segment.<br />
This river sector is totally regulated and al<strong>on</strong>g it are several hydro-electrical plants that<br />
produce electrical energy. These set-ups, created after the 1960’s, modified the<br />
c<strong>on</strong>figurati<strong>on</strong> of the old riverbed. Both the l<strong>on</strong>gitudinal and the transversal c<strong>on</strong>nectivity of<br />
the natural river course were affected. The permanent flow regime of the river underwent<br />
important changes, due to the special, disc<strong>on</strong>tinuous water treatments <strong>on</strong> hydro-electrical<br />
channels, placed parallel to the natural riverbed of Bistrita River. A negative influence over<br />
the quality of water in Bistrita River, upstream Piatra Neamt and the chemical platform in<br />
Savinesti, is the evacuati<strong>on</strong> of nutrients in high quantities. This negative influence<br />
correlated with the disc<strong>on</strong>tinuous water treatment in hydro-electrical plants. In time, this<br />
led to an imbalance of the underwater envir<strong>on</strong>ment, which recovers extremely slow. In this<br />
paper, we also presented the results of several studies c<strong>on</strong>cerning the influence of nutrients<br />
over the quality of water in Bistrita River, <strong>on</strong> the specific sector between 1990 and 2000,<br />
taking into account that the sector is hydro-morphologically affected by the hydroelectrical<br />
plants. In our study, it can be seen that in the last years the quantities of<br />
pollutants evacuated in Bistrita River <strong>on</strong> this segment have dropped, as a result of rigorous<br />
c<strong>on</strong>trols from water management authorities, and of advanced treatment of nutrients at<br />
tertiary purificati<strong>on</strong> levels. The disc<strong>on</strong>tinuous water treatment in hydro-electrical plants<br />
between Piatra Neamt and Bacau still influence the quality of water in Bistrita River, by<br />
not providing adequate diluti<strong>on</strong> volumes. These negative influences are obvious during<br />
periods when affluent natural debits are smaller than multiannual debits. In this study we<br />
used a complex data base from the Administrati<strong>on</strong> of Siret Basinal Water archive and our<br />
own experience in this area..<br />
Key words: nutrients, hydro-technical arrangements, highly modified surface water body.<br />
100
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
RISK EXPOSURE ON NONIONIZING RADIATION<br />
ASSOCIATED WITH VARIATION OF LACTOSE AND<br />
PROTEIN CONCENTRATION IN DAIRY PRODUCTS<br />
Irina Ifrim 1 , Iuliana Lazar 1 , Marius Stamate 2<br />
1 ”Vasile Alecsandri” University of Bacau, Department of Chemical and Food Engineering<br />
2 ”Vasile Alecsandri” University of Bacau, Department of Mechanical and Envir<strong>on</strong>mental<br />
Engineering<br />
Corresp<strong>on</strong>ding author: Iuliana Lazar, ilazar@ub.ro<br />
Abstract: The quantity of carbohydrates, fats or proteins is important for the metabolic<br />
process of bodies. There are some of carbohydrates that have a special role in the body.<br />
For example, lactose helps the absorpti<strong>on</strong> of calcium and ribose and is a part of the<br />
important compounds DNA-2 and RNA-3. Under the acti<strong>on</strong> of lactic bacteria, lactose is<br />
subjected to fermentati<strong>on</strong> processes, the most important being: lactic, alcoholic, propi<strong>on</strong>ic<br />
and butyric fermentati<strong>on</strong> thus resulting in important changes in physical, chemical and<br />
organoleptic properties of milk products. The aim of our study is to highlight the<br />
c<strong>on</strong>diti<strong>on</strong>s in which might appear alterati<strong>on</strong> of lactose and protein in the presence of milk<br />
inoculated with lactic acid bacteria (LAB) and n<strong>on</strong>i<strong>on</strong>izing radiati<strong>on</strong> exposure. The<br />
analysis was achieved for milk inoculated with LAB ranging from 0.1g/l to 0.5g/l and<br />
under UV-VIS radiati<strong>on</strong> doses (D) that varies between 29kJ/m 2 and 165kJ/m 2 . HATR-<br />
FTIR spectral interpretati<strong>on</strong> of vibrati<strong>on</strong>al group frequencies was performed with OPUS<br />
6.0 Bruker and ORIGIN 8.50 software. Data mining in correlati<strong>on</strong> with spectral data<br />
technique provides us the informati<strong>on</strong> about the lactose and proteins variati<strong>on</strong> in the<br />
samples exposed to stress factors. The degree of proteins denaturati<strong>on</strong> depending <strong>on</strong> the<br />
temperature and durati<strong>on</strong> of its acti<strong>on</strong> is observed. At a c<strong>on</strong>centrati<strong>on</strong> of 0.1g/l of lactic<br />
acid bacteria we have found a maximum of the relative amount of lactose (L) and at 0.4g/l<br />
a minimum <strong>on</strong>e. Up to a dose of 97kJ/m 2 the L growth is slow, after which the exp<strong>on</strong>ential<br />
growth occurs. The relative amount of protein (P) shows a minimum at a c<strong>on</strong>centrati<strong>on</strong><br />
LAB at 0.2g/l and a maximum at 0.5g/l. Also it was observed that exposure dose variati<strong>on</strong><br />
fits very well <strong>on</strong> a logistic regressi<strong>on</strong> curve. MANOVA test reveals that there is a<br />
significant multivariate effect of LAB <strong>on</strong> L (Pillai coefficient F = 3.978, p
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
PHYSICO-CHEMICAL PROPERTIES DIFFERENCES OF<br />
WATER COLLECTED <strong>FROM</strong> BISTRITA RIVER IN BACAU<br />
CITY AREA RELEASED BY UNIVARIATE ANALYSES<br />
Andrei Rusu 1 , Adrian Panaite 1 , Irina Moian 1 , Roxana Iancu 1 , Sim<strong>on</strong>a<br />
Herghelegiu 1 , Ema Faciu 1 , Iulia Lazar 2<br />
1 “Vasile Alecsandri” University of Bacau, Department of Mechanical and Envir<strong>on</strong>mental<br />
Engineering<br />
2 “Vasile Alecsandri” University of Bacau, Department of Chemical and Food Engineering<br />
Corresp<strong>on</strong>ding author: Ema Faciu, ema.faciu@ub.ro<br />
Abstract: Water quality analyzes is useful for assessing the envir<strong>on</strong>mental influence al<strong>on</strong>g<br />
a river, in our case the Bistrita River. Measurements <strong>on</strong> different indicators and targets of<br />
this river, are made every m<strong>on</strong>th (for slow flow) and daily (for fast flow), by Siret Water<br />
Directorate (ABA) Bacau. Our sampling locati<strong>on</strong>s in this study are different from those<br />
which are regulary used by the ABA. The aims of the study are to assess the physicochemical<br />
parameters of water al<strong>on</strong>g the Bistrita River course through Bacau City area, and<br />
to evaluate the differences caused by envir<strong>on</strong>mental influence. Thus, seven different<br />
sampling points were established using GPS coordinates al<strong>on</strong>g both the Bistrita River<br />
course and the two canals derived from the barrier lakes. Sampling was performed at a<br />
c<strong>on</strong>siderable distance, without disturbing or influence, the surface water c<strong>on</strong>diti<strong>on</strong>s.<br />
Samples were stored at a temperature of 5-6°C, transported and handled with sterile<br />
c<strong>on</strong>tainers, compliant to ISO 5667-6.2009 standard. The performed analyzes determined<br />
the pH, c<strong>on</strong>ductivity, turbidity and oxygen c<strong>on</strong>tent. The multiparameter type inoLab<br />
terminal device 740/750 WTW GmbH, Weilheim, Germany was used for analysis of pH,<br />
c<strong>on</strong>ductivity and oxygen, and the WTW Photoflex / pHotoTurb appliance, from WTW<br />
GmbH, Weilheim, Germany, was used for the measurement of the turbidity. The pH was<br />
determined in the same day as the sampling procedure. The other parameters were<br />
measured at lead times of <strong>on</strong>e week. The software used for analyzing and interpreting the<br />
results was IBM v20.0 SPSS Statistics. One way ANOVA with post hoc Games-Howell<br />
test were used. Interpretati<strong>on</strong> of results indicates significant differences between the seven<br />
samples for c<strong>on</strong>ductivity, possibly because of high c<strong>on</strong>centrati<strong>on</strong>s of i<strong>on</strong>s. Similar results<br />
were obtained for values of turbidity but <strong>on</strong>ly in 4 of the 7 samples. For further study,<br />
measurements using the same sampling locati<strong>on</strong>s will be c<strong>on</strong>ducted, and it will be<br />
completed with spectroscopic and chemometric measurements.<br />
Key words: water, physico-chemical properties, univariate analyses, ANOVA.<br />
102
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
COMPARATIVE STUDY VIEWING THE EFFICIENCY OF<br />
THE GRANULAR FILTERS DEPENDING ON THE TYPE OF<br />
THE FILTER MATERIAL<br />
Marius Stanila, Valentin Nedeff, Mirela Panainte, Alexandra Dana Chitimus<br />
“Vasile Alecsandri” University of Bacau, Department of Envir<strong>on</strong>mental and Mechanical<br />
Engineering<br />
Corresp<strong>on</strong>ding author: Stanila Marius, mstanila63@gmail.com<br />
Abstract: The paper presents several aspects regarding the operati<strong>on</strong> optimizati<strong>on</strong>, during<br />
the warm seas<strong>on</strong>, for a mixed cycle gas turbine, type Titan 130S, installed at S.C. CET<br />
S.A. Bacau. The operati<strong>on</strong> optimizati<strong>on</strong> at partial loads for the mixed cycle gas turbine,<br />
type Titan 130S, has been d<strong>on</strong>e using the multicriteria analysis, taking into c<strong>on</strong>siderati<strong>on</strong><br />
the operati<strong>on</strong>’s restricti<strong>on</strong>s required for this type of gas turbine. The criteria taken into<br />
c<strong>on</strong>siderati<strong>on</strong> for the multicriteria analysis are: the thermic energy demand, the global<br />
efficiency in high efficiency cogenerati<strong>on</strong> operating c<strong>on</strong>diti<strong>on</strong>s, the electric energy price,<br />
NOx emissi<strong>on</strong>s level, CO2 emissi<strong>on</strong>s level. These criteria have been applied to several gas<br />
turbine operating c<strong>on</strong>diti<strong>on</strong>s, after analysing this data the optimum operati<strong>on</strong> c<strong>on</strong>diti<strong>on</strong> was<br />
chosen, that was corresp<strong>on</strong>dent to a predefined forecast period. These scenarios have taken<br />
into c<strong>on</strong>siderati<strong>on</strong> the need to ensure the forecast thermic energy demand for hot tap water<br />
supply to the domestic and n<strong>on</strong>-domestic clients in Bacau city during the warm seas<strong>on</strong>,<br />
with both energy and financial efficiency and with a low level of pollutant emissi<strong>on</strong>s.<br />
There are two operating restricti<strong>on</strong>s c<strong>on</strong>sidered for the gas turbine, the first is of a technical<br />
nature and the sec<strong>on</strong>d regards the admissible level for NOx emissi<strong>on</strong>s. The restricti<strong>on</strong>s with<br />
a technical nature take into discussi<strong>on</strong> the maximum number of turbine start-ups, the daily<br />
number of start-ups and the annual number of start-ups for this type of turbine being<br />
limited. This limitati<strong>on</strong> is due to the stress of the equipments during the turbine start-up<br />
drive, and exceeding the allowed number of start-ups leads to premature wearing and to the<br />
growth of the maintenance expenses. The restricti<strong>on</strong>s regarding the NOx emissi<strong>on</strong>s level<br />
derive from the installati<strong>on</strong> of a SoLoNOx combusti<strong>on</strong> system for this type of turbine. The<br />
SoLoNOx combusti<strong>on</strong> system ensures a low level of NOx emissi<strong>on</strong>s, and the c<strong>on</strong>sidered<br />
restricti<strong>on</strong> is due to this type of combusti<strong>on</strong> start-up operati<strong>on</strong> at loads higher than 60% of<br />
this type of gas turbine rated power. The SoLoNOx combusti<strong>on</strong> system uses powerful<br />
swirl injectors that produce an intense circulating area for the mix-fuel in the combusti<strong>on</strong><br />
chamber, with low oxygen level so as the combusti<strong>on</strong> takes place at a low temperature,<br />
thus blocking the formati<strong>on</strong> of thermic NOx.<br />
Key words: gas turbine, optimizati<strong>on</strong>, emissi<strong>on</strong>, combusti<strong>on</strong> system.<br />
103
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
DEFICIENCIES AND POSSIBLE ENVIRONMENTAL <strong>RISKS</strong><br />
OF PHOTOCATALYSIS USED FOR WATER AND AIR<br />
DEPOLLUTION<br />
Traian Vasilache, Gabriel Lazar, Marius Stamate<br />
“Vasile Alecsandri” University of Bacau, Department of Mechanical and Envir<strong>on</strong>mental<br />
Engineering<br />
Corresp<strong>on</strong>ding author: Traian Vasilache, traian.vasilache@ub.ro<br />
Abstract: This short review presents some deficiencies regarding photocatalysis use in<br />
water and air depolluti<strong>on</strong>, because the envir<strong>on</strong>mental risks have to be c<strong>on</strong>sidered in order<br />
to minimize negative effects of the future applicati<strong>on</strong>s. Since photocatalysis was<br />
discovered a couple of decades ago, it was intensively studied and many applicati<strong>on</strong>s were<br />
developed. In the envir<strong>on</strong>mental engineering depolluti<strong>on</strong> ex-situ of water and air it seems<br />
to be revoluti<strong>on</strong>ary. Especially coupled processes involving photocatalysis coupled with<br />
oz<strong>on</strong>izati<strong>on</strong>, membrane filtrati<strong>on</strong> and microfiltrati<strong>on</strong>, adsorpti<strong>on</strong>, s<strong>on</strong>olysis, pulse<br />
discharge, flocculati<strong>on</strong>, photolysis and microwave energy, were proving best results and<br />
possibilities for future commercial uses in industry and envir<strong>on</strong>mental protecti<strong>on</strong>.<br />
Deficiencies of these processes are c<strong>on</strong>cerning in formati<strong>on</strong> of undesirable sec<strong>on</strong>dary<br />
products. In water depolluti<strong>on</strong> using membranes and photocatalysis the problem of<br />
presence of colloidal particles even after washing of membranes it was signalized. Another<br />
study found as problem the formati<strong>on</strong> of cake layer <strong>on</strong> membrane surface. Adsorpti<strong>on</strong> <strong>on</strong><br />
nanoporuos materials and photocatalysis used for wastewaters treatment was an acceptable<br />
method, but formati<strong>on</strong> of colloidal particles decreased the efficiency of the process.<br />
Diclofenac is the disseminated medicine in water, potentially toxic for aquatic life and<br />
photocatalysis degraded it successfully; some of sec<strong>on</strong>dary products resulted are toxic,<br />
even more pois<strong>on</strong>ous as primary pollutant. Degradati<strong>on</strong> of 4-clorophenol under microwave<br />
energy couplet with photocatalysis in aqueous soluti<strong>on</strong>s occurs with formati<strong>on</strong> of<br />
chlorobenzene, phenol, hydroquin<strong>on</strong>e, benzoquin<strong>on</strong>e and 4-chlorocatechol which are<br />
undesirable products. Textile dye Acid Red 88 was degraded by s<strong>on</strong>olysis and<br />
photocatalysis, but some intermediate products were not mineralized. The same problem<br />
occurred <strong>on</strong> degradati<strong>on</strong> of diphenylamine from polluted water. Regarding air depolluti<strong>on</strong>,<br />
photocatalysis was applying in nasty smells removal; 2-butan<strong>on</strong>e and methyl-ethyl-ket<strong>on</strong>e<br />
were successfully oxidized, but acetaldehyde results as sec<strong>on</strong>dary product. A pulse<br />
discharge system combined with photocatalysis degraded phenols and the problem of sub<br />
products appears <strong>on</strong>ce again. Some insecticides as malathi<strong>on</strong>, isomalathi<strong>on</strong> and malaox<strong>on</strong><br />
were decomposed by photolysis coupled with photocatalysis and some undesirable<br />
sec<strong>on</strong>dary products formed. Also, trichoroethylene was decomposed succesfully by<br />
photocatalysis, but it results fosgene, chloroform and carb<strong>on</strong> tetrachoride. All the methods<br />
need improvement and future researches will find those materials and chemical reacti<strong>on</strong>s<br />
which have to be eco-friendly.<br />
Key words: photocatalysis, water depolluti<strong>on</strong>, air depolluti<strong>on</strong>, sec<strong>on</strong>dary products, envir<strong>on</strong>mental<br />
risk.<br />
104
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
COMPOSITE MATERIALS WITH CARBON CLUSTERS AS<br />
ADSORBED MICRO-AND MACRO-MOLECULAR ELEMENTS<br />
Petru Lozovanu, Mihail Caraman, Alexandru Cresciuc<br />
Laboratory of Scientific Research "Phot<strong>on</strong>ics and Metrology Physics",<br />
Moldova State University<br />
Corresp<strong>on</strong>ding author: Petru Lozovanu, p_lozovanu@yahoo.com<br />
Abstract: Discovery of the new allotropic forms of carb<strong>on</strong> (fullerenes and nanotubes) led<br />
to broadening fields of practical use of carb<strong>on</strong>. Valence b<strong>on</strong>ds of carb<strong>on</strong> atoms in<br />
fullerenes macromolecules (C60, C70...) are closed, but a small external excitati<strong>on</strong> which<br />
can be induced by a molecule or cluster can lead to the formati<strong>on</strong> of free b<strong>on</strong>ds and their<br />
adsorpti<strong>on</strong>, respectively. A totally different interacti<strong>on</strong> mechanism with external molecular<br />
envir<strong>on</strong>ment have some modificati<strong>on</strong>s so-called nanotubes. Having free valence b<strong>on</strong>ds at<br />
the edge, these attract str<strong>on</strong>gly molecules and even polar clusters, and after their i<strong>on</strong>izati<strong>on</strong><br />
it can be accumulated in large amounts by carb<strong>on</strong> clusters. These properties of carb<strong>on</strong><br />
modificati<strong>on</strong> have been put into the basis of elaborati<strong>on</strong> of the adsorbent elements with<br />
carb<strong>on</strong> clusters. Modern technologies allow to obtain industrial quantities of carb<strong>on</strong> cluster<br />
of different orders which have a wide range of physical properties. The paper presents<br />
experimental and technological research <strong>on</strong> the results about manufacturing the active filter<br />
elements to purify liquids and gases. By directing the carb<strong>on</strong> comp<strong>on</strong>ent c<strong>on</strong>centrati<strong>on</strong> <strong>on</strong>e<br />
can obtain the tiles, electrical c<strong>on</strong>ductivity of which varied in quite wide range from tens to<br />
hundreds of MOhms. We have d<strong>on</strong>e research <strong>on</strong> the variati<strong>on</strong> of electrical c<strong>on</strong>ductivity for<br />
these micrometer elements made by these materials with different atmospheric pollutants<br />
(carb<strong>on</strong> and sulfur oxides and nitrites, vapor of organic compounds). A link between<br />
pollutant c<strong>on</strong>centrati<strong>on</strong> in the atmosphere and the size of the electrical c<strong>on</strong>ductivity<br />
variati<strong>on</strong> was established. As a result, experimental investigati<strong>on</strong>s of composites based <strong>on</strong><br />
nanotubes and fullerenes, as well as the experimental methods form the basis of the work<br />
presented.<br />
Investigati<strong>on</strong>s were made in the Laboratory ”Metrology of the Envir<strong>on</strong>ment and<br />
Astr<strong>on</strong>omy”, Moldova State University<br />
Key words: cluster, fullerenes, nanotubes.<br />
105
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
CYBERDYN: A STATE-OF-THE-ART SUPERCOMPUTER<br />
FOR GEODYNAMIC MODELING OF ACTIVELY SEISMIC<br />
ZONES<br />
M. Pomeran 1 , V.C. Manea 2, 1 , M. Manea 2, 1 , L. Besutiu 1 , L. Zlagnean 1<br />
1 Solid Earth Dynamics Department, Institute of Geodynamics of the Romanian Academy, Romania<br />
2 Computati<strong>on</strong>al Geodynamics Laboratory, Centro de Geociencias, Universidad Naci<strong>on</strong>al Aut<strong>on</strong>oma<br />
de Mexico, Mexico<br />
Corresp<strong>on</strong>ding author: Mihai Pomeran, mihai.pomeran@gmail.com<br />
Abstract: In recent years, modeling and computati<strong>on</strong> have come to play an central key role<br />
in modern earth sciences, and <strong>on</strong>e of the reas<strong>on</strong>s is due to their dependence <strong>on</strong> fine spatial<br />
grids and small time steps for integrati<strong>on</strong> used for solving numerically systems of<br />
equati<strong>on</strong>s that express mathematically a physical process. Presently, the solid earth<br />
sciences started to move towards implementing high performance computati<strong>on</strong>al research<br />
facilities. Today’s scientists need access to new informati<strong>on</strong> technology capabilities, able<br />
to perform high-resoluti<strong>on</strong> complex computing simulati<strong>on</strong>s in a reas<strong>on</strong>able time frame.<br />
Sophisticated simulati<strong>on</strong> tools allow us to study phenomena that can never be observed or<br />
replicated by standard laboratory experiments. Modeling complex natural processes in<br />
general, and numerical computati<strong>on</strong> in particular, represents today an essential need of<br />
research, and all modern research centers benefit from a computing center of <strong>on</strong>e form or<br />
another. Computati<strong>on</strong>al modeling represents a powerful tool in the field of Earth Sciences,<br />
in particular in modeling large-scale processes inside the solid Earth. In this study we<br />
introduce the newly implemented state-of-the-art CyberDyn parallel machine, a High<br />
Performance Computing Cluster (HPCC) with 1344 computing cores and high-speed<br />
network c<strong>on</strong>nectivity available at the Institute of Geodynamics of the Romanian Academy.<br />
This computati<strong>on</strong>al infrastructure targets large-scale high-resoluti<strong>on</strong> geodynamic<br />
simulati<strong>on</strong>s. We measured the performance of HPCC CyberDyn using the parallelized<br />
open source code CitcomS, which is widely used in the solid earth community<br />
(www.geodynamics.org). The benchmark tests are performed using a series of 4D<br />
geodynamic settings ranging from regi<strong>on</strong>al to full-spherical models. The benchmark results<br />
show that the HPCC CyberDyn offers the opportunity to perform fast geodynamic<br />
simulati<strong>on</strong>s modeling with parallelized codes that scale well <strong>on</strong> 100s or even 1000s of<br />
processors. In the same time the high-speed QDR Infiniband interc<strong>on</strong>nect offers the<br />
possibility to exploit the full potential of large clusters, and represents a key comp<strong>on</strong>ent<br />
that positively influence both, scalability and performance <strong>on</strong> large HPC systems. Since<br />
presently we are moving towards high-resoluti<strong>on</strong> simulati<strong>on</strong>s for geodynamic predicti<strong>on</strong>s<br />
that require the same scale as observati<strong>on</strong>s (from several to thousands of kilometers), HPC<br />
facilities used in earth sciences should benefit from larger up-fr<strong>on</strong>t investment in future<br />
systems that are based <strong>on</strong> high-speed interc<strong>on</strong>nects.<br />
Key words: geodynamics, HPC, computati<strong>on</strong>al modeling, informati<strong>on</strong> technology.<br />
106
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
FLOODS - A REPETITIVE RISK ON TROTUS VALLEY<br />
Alexandru Gutas, Lavinia Fedor, Alexandra Balint, Lavinia Misaila<br />
”Dimitrie Ghika” High School Comanesti, Romania<br />
Misaila Lavinia, misaila_lavinia@yahoo.com<br />
Abstract: Comanesti has experienced many floods, causing huge material damage and<br />
losses of life. The work main purpose is to outline the major factor risks enhancing<br />
Nature’s protest “against the global warming”: poor sewage within the towns, illegal<br />
deforestati<strong>on</strong> of hills or mountains slopes, dirty river banks, lack of citizens ‘educati<strong>on</strong> and<br />
resp<strong>on</strong>sibility, slow communicati<strong>on</strong> between different authorities, absence of specialized<br />
equipment, and in some cases, political or ec<strong>on</strong>omical interests which caused the floods<br />
al<strong>on</strong>g the Trotus river during the years 2003, 2004, 2005, 2008 and 2010. The town<br />
Comanesti and the surrounding area had been suffered major damages due to lack of care<br />
for reforesting the cut woods, laying up closed boards and chambers of the coal closed<br />
mines, summed up with the minimum investment for the improvement of the water course<br />
regulati<strong>on</strong> and disregards for the envir<strong>on</strong>mental area. Romanian authorities, having in mind<br />
the floods of 2005 and 2006, try to prevent these disasters or to mitigate their effects, but<br />
up to now there has been a big gap between theory and practice, mainly because of the<br />
complexity of the acti<strong>on</strong>s to be taken, which require time and m<strong>on</strong>ey. The brief descripti<strong>on</strong><br />
of the foods episodes and the human influence may reveal the aspects like as: after many<br />
years of neglecting the hydro technical works (not building new <strong>on</strong>es or letting the old<br />
<strong>on</strong>es to be damaged), heavy rains exceeded the defence capacity of these with disastrous<br />
c<strong>on</strong>sequences; the absence of clear laws and the means to enforce the existing <strong>on</strong>es has to<br />
led to massive deforestati<strong>on</strong> within certain watersheds, thus enhancing the effects of the<br />
heavy rains. It is good that the causes were discovered, but it takes effort, time and m<strong>on</strong>ey<br />
to c<strong>on</strong>trol floods. With authority’s effort and enlarging citizens educati<strong>on</strong> for the<br />
envir<strong>on</strong>ment such negative episodes can be avoided in future.The work includes recent<br />
measures taken by local administrati<strong>on</strong> to regularize the Trotus course and dam up its<br />
banks together with afforestati<strong>on</strong> of the slopes. All the research work was d<strong>on</strong>e by high<br />
school students from “Dimitrie Ghika” High School who worked collaboratively with the<br />
insurance companies in the area to estimate the damages caused by the floods.<br />
107
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
AUTHORS INDEX<br />
A<br />
Agayan S.M. 18<br />
Agop M. 50<br />
Andrioai G. 64, 66<br />
Anghel S. 23<br />
Anoh Kouao A. 77, 84<br />
Ardeleanu G. 100<br />
Artenie V. 93<br />
Avadanei M. 98<br />
B<br />
Balint A. 107<br />
Barjoveanu G. 55<br />
Barsan N. 63, 67, 68, 69, 70<br />
Batrinescu Ghe. 43<br />
Besutiu L. 30, 106<br />
Bibire L. 66<br />
Bogdevich O. 39, 40<br />
Bogoutdinov Sh. R. 18<br />
B<strong>on</strong>tas O. 74<br />
C<br />
Cadocinicov O. 39<br />
Capsa D. 67, 69<br />
Caraman I. 91, 92, 94<br />
Caraman M. 105<br />
Cartacuzencu S. 61<br />
Cazacu M. M. 50<br />
Chamberlain C. 44<br />
Chira C. 60<br />
Chiril Ghe. 54<br />
Chitimus A. .D. 62, 103<br />
Christensen E. F. 17<br />
Ciobanu A. 45<br />
Ciobanu D. 79<br />
Ciochina S. 59<br />
Ciurea-Ercau C. 51<br />
Cloetingh S. 20<br />
Cocarcea A. 87, 90<br />
Codreanu L. 54<br />
Comandaru I. M. 55<br />
C<strong>on</strong>stantin C. 23<br />
C<strong>on</strong>stantinescu D. 52<br />
Copaescu S. 54<br />
Covaci I. 69<br />
Cresciuc A. 105<br />
Crisan G. C. 60<br />
D<br />
Dando B. 35<br />
Dascalita D. 75, 76, 100<br />
Demetrescu C. 36, 37<br />
Diac<strong>on</strong>escu A. 90<br />
Dimitriu Ghe. D. 50<br />
Dinca E. 51<br />
Djelveh G. 96<br />
Dobrica V. 36, 37<br />
Dobrovolsky M.N. 18<br />
Dudu A. 23<br />
Dumitrescu A. 68<br />
Durac Ghe. 81<br />
E<br />
E. Nechita 49<br />
Ene S. A. 55<br />
Etoa F. X. 97<br />
Evtodiev I. 91<br />
Evtodiev S. 92<br />
F<br />
Faciu E. 57, 87, 90, 102<br />
Fedor L. 107<br />
Felegeanu D. C. 86<br />
Fernandez B. 79<br />
Filipciuc C. 32<br />
Finaru A. L. 79<br />
Fokou E. 97<br />
Furdu I. 27<br />
G<br />
Gavrila L. 79<br />
Georgescu A. M. 82<br />
Gogus O. 38<br />
Gorshkov A. I. 19<br />
Grierosu I. 98<br />
Grig-Alexa I. C. 79<br />
Grigoras C. G. 79<br />
Grosu L. 79<br />
Gruneantu I. 54<br />
Gurlui S. G. 50<br />
Gutas A. 107<br />
Gutu M. 98<br />
Gvishiani A. D. 18, 19<br />
H<br />
Hegedüs E. 35<br />
Herghelegiu S. 102<br />
108
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
Houlié N. 44<br />
Houseman G. A. 15, 35, 38<br />
Hurjui I. 98<br />
I<br />
Iancu R. 102<br />
Ifrim I. 57, 58, 101<br />
Ilias N. 54<br />
I<strong>on</strong>escu Ctin. 35, 46<br />
Isac A. 41<br />
Ismail-Zadeh A.<br />
J<br />
20<br />
Jean-Louis Le Mouël 21<br />
Jinescu C. 96<br />
J<strong>on</strong>ass<strong>on</strong> C. 52<br />
Jourda J. P. 77, 84<br />
Judele A.<br />
K<br />
95<br />
Kane A. 85<br />
Kansci G. 97<br />
Koua T. J. J. 77, 84<br />
Kouamé K. J. 77, 84<br />
Kristoferss<strong>on</strong> A.<br />
L<br />
52<br />
Lazar G. 56, 57, 58, 61, 72, 77, 84, 85, 87, 99,<br />
104<br />
Lazar I. M. 45, 56, 57, 58, 87, 88, 89, 90, 93,<br />
94, 97, 99, 101, 102<br />
LorincziP. 15<br />
Lozovanu P. 105<br />
M<br />
MafteiM.R.. 32<br />
Mandea M. 18, 22, 41<br />
Mandrescu N. 24<br />
Manea D. 53, 78<br />
Manea E. 53, 78<br />
Manea M. 106<br />
Manea V.C. 106<br />
Marmureanu A. 46<br />
Marmureanu Ghe. 46<br />
Matenco L. 20<br />
Mir<strong>on</strong> N. D. 45<br />
Mir<strong>on</strong> S. 98<br />
Misaila L. 107<br />
Mogorici C. 42<br />
Moian I. 102<br />
Moroi A. 94<br />
Mosnegutu E. F. 62, 74<br />
Muntianu G. 96<br />
Murariu G. 59<br />
Muraru C.V. 49<br />
N<br />
Nadabaica D. C. 66<br />
Nardou F. 82<br />
Ndour P. 85<br />
Nedeff V. 62, 63, 64, 65, 66, 67, 68, 69, 70,<br />
74, 79, 86, 103<br />
Niang A. 85<br />
Nicoara I. 40, 42<br />
Nicuta D. 58, 79<br />
Nistor I. D. 45, 82, 83, 96<br />
P<br />
Panainte M. 64, 65, 67, 74, 103<br />
Panaite A. 102<br />
Pandele I. 27<br />
Patriciu O. I. 79<br />
Penot C. 82<br />
Petrescu M. 43<br />
Pintea C. M. 60<br />
Plat<strong>on</strong> N. 83<br />
Pomeran M. 106<br />
Praisler M. 59<br />
Proca A. 23<br />
Purucker M.<br />
R<br />
16<br />
Racovet O. 91, 92<br />
Radovanović S. 35<br />
Radu C. 68<br />
Radu M. 29<br />
Radu S. M. 54<br />
Radulian M. 20, 24<br />
Rashid B. 25, 26<br />
Ren Y. 15, 35<br />
Robescu D. 53, 78<br />
Robescu D. N. 80<br />
Rogoveanu Radosavlevici I. 80<br />
Rotea O. 54<br />
Rusu A. 102<br />
Rusu V.<br />
S<br />
98<br />
Saha B. U. 97, 99<br />
Sandu I. 28<br />
Sava C. S. 23<br />
Seghedi I. 33, 34<br />
Serban F. 29<br />
Shen Y. 35<br />
109
<str<strong>on</strong>g>First</str<strong>on</strong>g> <str<strong>on</strong>g>Internati<strong>on</strong>al</str<strong>on</strong>g> <str<strong>on</strong>g>C<strong>on</strong>ference</str<strong>on</strong>g> <strong>on</strong> <strong>MOLDAVIAN</strong> <strong>RISKS</strong> - <strong>FROM</strong> GLOBAL TO LOCAL SCALE<br />
16-19 May 2012, Bacau, Romania<br />
Siminiceanu I. 83<br />
Sirbu E. 52<br />
Soare A. 41<br />
Soloviev A. A. 19<br />
Sorin M. 29<br />
South Carpathian Project working group 35<br />
Spatari G. 26<br />
Stamate M. 56, 58, 91, 92, 101, 104<br />
Stanescu B. 43<br />
Stanila M. 103<br />
Stefanescu C. 98<br />
Stefanie M. 54<br />
Stern T. 44<br />
Stoica A. 59<br />
Stoicescu A. 71<br />
Stuart G. W. 15, 35<br />
Surpateanu Ghe. 45<br />
Szakács A.. 33, 34<br />
T<br />
Talmaciu M. 49<br />
Teleaga D. 29<br />
Teodosiu C. 55<br />
Timofte A. 50<br />
Tirtoaca (Irimia) O. 65<br />
Tit N. H. 81<br />
Toma Danila D. 48<br />
Toma L. 54<br />
Tomescu C. 23<br />
Tomozei C. 27, 64<br />
Tr<strong>on</strong>ea M. 51<br />
Turcu M.<br />
U<br />
70<br />
Untila D. 92<br />
Ureche C. 88, 89<br />
Ureche D.<br />
V<br />
88, 89<br />
Vasilache T. 104<br />
Vasile L. 93<br />
Vasilica M. 69<br />
Vatra A. 72<br />
Voicu P.<br />
Z<br />
73<br />
Zichil V. 95<br />
Zirnea S. 99<br />
Zlagnean L. 106<br />
110
Sp<strong>on</strong>sors of the c<strong>on</strong>ference<br />
Sodexo Pass<br />
SC NITECH SRL<br />
SC DEDEMAN SRL<br />
Banca Transilvania<br />
SC ROMTEXO SRL<br />
SC SELGROS SRL<br />
SC CHEMICAL COMPANY SRL<br />
SC LA FANTANA SRL<br />
SC NOVITEC OFFICE SRL<br />
SC INVEST MILENIUM SRL
SC SIGMA SECURITY SRL<br />
SC REEAKYS SRL