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[1] Bernier F., Li X.L., Weetjens E, and Sillen, X. (2004). The Praclay Heater Test and the Praclay plug test. Proc. Conference & Workshop on the Experimental Programme of the URF HADES (Jan. 2004). <strong>EU</strong>RIDICE, Mol, Belgium, pp 1-18. 452
NF-PRO – Concrete Degradation and its Influence on the Geochemical Conditions at the Concrete/Bentonite under Repository Conditions. Alicia Escribano, Elena Torres, Mª Jesús Turrero, Pedro Luís Martín, Javier Peña, Paloma Gómez Summary CIEMAT, Madrid, Spain Degradation of concrete can influence the performance of the bentonite barrier, as high-pH lixiviates could affect to the clay properties. The experimental studies conducted by CIEMAT are designed to provide experimental evidences on the physical, chemical and mineralogical changes during the concrete-compacted bentonite interaction. Concrete has been analyzed by SEM-EDS, whereas bentonite samples were studied by means of XRD, FTIR and SEM–EDS. Chemical analysis for exchangeable cations and soluble salts were also performed in clay samples. 1. Introduction Deep geological disposal is the most accepted management option for long-lived and highly radioactive wastes. In the repository, concrete will be used for the reinforcement of the access galleries and in the final sealing of access routes. Concrete degradation caused by external agent can affect its durability, resistance and stability throughout time. Furthermore, concrete degradation generates a diffusive alkaline plume which can affect the swelling and transport properties of bentonite, as well as the properties of the adjacent host rock and groundwater flowing through. The scope of the present study is to provide experimental data about the alteration products at the concrete/bentonite interface and the related changes of both materials during the interaction. 2. Methodology 2.1 Materials Bentonite The tests have been performed with a bentonite (FEBEX) from the Cortijo deArchidona deposit (Almería, Spain). The conditioning of the bentonite prior its use in the laboratory is detailed in [1]. Its main characteristics are detailed in Villar (2002) [2]. 453
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Interested in European research? Re
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LEGAL NOTICE Neither the European C
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TABLE OF CONTENTS FOREWORD iii CONF
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“Impact of advanced fuel cycle sc
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“Sensitivity analysis techniques
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Topic: Support actions SAPIERR-II -
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CONFERENCE SUMMARIES
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supported. The Commission believes
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Ms Monika Hammarström of SKB in Sw
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Dr Bruno of Amphos 21 urged the swi
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measurements of actinides to determ
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Dr Peter Blümling of Nagra in Swit
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Future directions There seemed to b
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1. Introduction Keynote Address Pet
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tive waste management, a considerab
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the decision making process. The se
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All initiatives leading to encourag
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tegrating them as part of advanced
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General introduction and objectives
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Radioactive waste management: Where
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The intense development in nuclear
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Figure 3: Schematic diagram of the
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contributed to enhance knowledge ab
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the first time in French history, a
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PANEL DISCUSSION Summary of the Pan
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With the support of IAEA preliminar
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Assessment of Financial Provisions
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collected in the cost of the nuclea
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erated by Fortum) and one PWR unit
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pected. As to tunnel backfilling, t
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ferent, the technological solutions
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Discussion: As a response to a ques
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Cooperation in the development of g
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During the 1980’s it was realized
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government on the operating license
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tions. EDRAM is another example of
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Discussion: The chairman opened the
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Communicating the safety of radioac
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Communicating the Safety of Radioac
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Geological repositories … Differe
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Geological long-term stability (pla
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Times & doses in perspective (examp
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Trust is generated (by the regulato
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4. The regulators could play a very
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Europe's nuclear industries, theref
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filled - one key example being coll
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Table 2. FP6 Integrated Projects an
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EUROTRANS focuses on the transmutat
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consensus that geological disposal
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102
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104
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significantly reduce the quantities
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Pyrochemical processes rely on refi
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Figure 3: Schematic layout of an el
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Considering pyrochemistry technolog
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agreed for support through an integ
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Table 1: Fuels irradiated in the SU
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lead cooling (see Fig. 5). Alternat
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Figure 6: Principle design characte
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Table 6: FUTURIX FTA fuels Fuel nam
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124
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After a review of the present statu
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suranium elements, “repository av
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nificant fraction of fast reactors.
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high level waste at the considered
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Pu or M.A. by the time it is needed
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of U and Pu only. P&T could complem
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suranium elements, the thermal load
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Phase-Out TRU Transmutation Scenari
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10 nuclear nations (Argentina, Braz
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elease, strong radiation, pressure
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A1 3.79E+08 270 7.12E-07 A2 3.51E+0
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nuclear fission in the reactors. Th
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5. Conclusions The HLW arising from
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152
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tinides (MA) are destined for geolo
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[3] Enrique González: Head of Nucl
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158
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160
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erage level of funding of research
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Prior to NF-PRO, the question wheth
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nant exchangeable cation. This chan
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eal concentration gradient in sampl
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access shafts, providing higher per
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172
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in the European coordinated action
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proved, with amongst others the det
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4. Discussion Tests with dissolved
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though with a slow rate. The data i
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surface. The coupling between water
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nuclear waste within the near-field
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tion of the column [2]. Moreover, t
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case, the iron diffusion front in t
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5.1 Sorption As an example of the t
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corrosion; up-scaling of clay alter
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Bentonite barriers are very importa
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To determine the impact of temperat
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in the underground laboratory in Gr
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under isothermal conditions. If the
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202
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Zones around such openings which ex
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layout of cells developed by ENPC w
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) a) e) d) f) d) e) f) c) Figure 3.
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EDZ removal by additional excavatio
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[7] Wenk H.-R., Voltolini, M., Mazu
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that provided by various national s
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system robustness, rather than as s
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Regarding diffusion studies perform
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7. EDZ characterization and evoluti
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[4] Alonso, J. et al. 2004: Bentoni
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There has been a significant change
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226
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228
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2. Methodology ESDRED has been focu
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Figure 3: Reduced scale mock-up aft
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Figure 8: Demonstration of emplacem
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The various reports produced by the
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238
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2. Methodology In general, the work
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limitations of the selected press.
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Figure 3.2.1 Schematic representati
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which was relatively homogeneous in
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Figure 3.3.1 Emplacement of SF-Cani
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1.650 1.600 1.550 1.500 1.450 1.400
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the outlet with some pressure and f
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A experiment, using cross-hole seis
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This seal will be implemented as ri
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[6] Miehe, R., Kröhn, P., Moog, H.
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dence. For waste canister transport
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The main waste canister characteris
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placement borehole. The BSK 3 canis
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Figure 6: Sketch of the Pushing Rob
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268
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1.1 Water Cushion Application SKB (
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In the case of SKB and Posiva, the
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Deposition machine tests with load
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Figure 10: Details of electrical pu
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the very heavy weight (43 ton) of t
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is no experience in either the work
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the case of the long plug elaborate
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values measured in the percolated w
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plug the concrete was mixed manuall
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2.3 Testing of low-pH shotcrete for
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290
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energy is produced by fission of ur
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3.2. Integration 3.2.1. Pool Facili
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3.4. Education and Training Apart f
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298
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Fig. 1.1: EU Member States involved
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Fig. 1.3: Stakeholders and interest
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- Present state of scientific level
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6. Training courses Key events of t
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308
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materials, the essential aspects of
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2.1 Geological formation scale (10
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porosity outside the clay interlaye
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eduction in De with increasing prop
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well-defined profile, with the high
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Th(IV) sorption on montmorillonite
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RN migration experiments and model
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tion/organization and its Cu(II) re
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326
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ganic/organic colloids”; WP 4.5
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Figure 1: Schematic of the FEBEX dr
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within feldspars in the three grani
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Colloid Concentration (ppm) 160 140
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form. Clay colloids were detected i
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References [1] Retrock (2005). Trea
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vance on radionuclide migration. Ma
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342
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The Ruprechtov site, located in the
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Colloid Concentration / μg/l 10000
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exists as a stable mineral phase in
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pared to other sites with SOC-beari
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[3] Hauser, W. Geckeis, H., Götz,
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The science and technology group, r
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FEPCAT RTDC 1 RTDC 2 RTDC 3 Clay-ri
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A1: Transport mechanisms Diffusivit
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360
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maintaining and develop competence
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A project would be justified to det
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366
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368
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The main goal of RTDC-1 is to provi
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3. RTDC3 In RTD component 3 methodo
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lower depths are less saline. For t
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[3] Marivoet, J., Beuth, T., Alonso
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certainty, conducted in RTDC-1 as W
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A simplistic summary might place PA
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There are at least three non-numeri
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10-11 June 2008. The workshop was a
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Close dialogue between a regulator
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ony, interactions, etc., and to che
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specific sampling strategy, with th
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2.2.3 Graphical methods Let us call
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3. The sensitivity analysis benchma
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4. Discussion and conclusions Three
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398
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2. Methodology The project particip
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Page 420 and 421: 4.3 Structure The TP structure must
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Page 426 and 427: � What steps should be taken to m
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Page 432 and 433: materials. For attaining the stated
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Page 440 and 441: focuses on the study of the combine
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Page 446 and 447: 2.1 Laboratory experiment The dispo
Page 448 and 449: 3. Results 3.1 Laboratory experimen
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Page 454 and 455: sented in the accompanying poster,
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Page 458 and 459: situ stress to model the gallery ex
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Page 464 and 465: ous reasons, SCK•CEN chose to foc
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Page 476 and 477: 2. Methodology In the case of cylin
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Page 486 and 487: [4] Gens, A. & Alonso, E. 1992. A f
Page 488 and 489: 2. Experimental Methodology A salt
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Page 494 and 495: obtained experimental results [1].
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Page 502 and 503: Figure 3: Left: Spent fuel surface
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Page 506 and 507: 1. Data compilation and evaluation
Page 508 and 509: Volumetric deformation [%] 20 18 16
Page 510 and 511: An overview of the test procedure w
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Page 514 and 515: The works performed within RTDC-1 p
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502
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The Ruprechtov natural analogue sit
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esults and integrated to develop a
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508
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510
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from 12.5 to 13.5, have high ionic
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elative intensity (cps) 8000 6000 4
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516
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518
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2. SAPIERR I and II In Europe, the
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after extensive interactions have t
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eing partners if an ERDO is formall
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526
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2. Methodology Based on existing da
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external funds ensuring the indepen
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532
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534
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Mr Jozef BALAZ JAVYS, a.s. - Nuclea
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Prof. Gunnar Johan BUCKAU Forschung
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Dr Mario DIONISI APAT - Dipartiment
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Dr Paloma GÓMEZ GONZÁLEZ CIEMAT -
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Ms Aurélie JESTIN SOGEDEC Z.I. Dig
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Dr Patrick MAJERUS Ministry of Heal
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Mr Zoltán NAGY PURAM - Department
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Ms Katerina PTACKOVA European Commi
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Prof. Christian SCHRÖDER Universit
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Dr Ján TIMUL'ÁK DECOM Slovakia, s
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Dr. Eng. Shuichi YAMAMOTO Obayashi
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