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corrosion; up-scaling of clay alteration processes; and an extension of advances in knowledge of sorption and diffusion to other radionuclides of interest to performance assessment. 7. Acknowledgements Quintessa are grateful for supporting funding from the UK Nuclear Decommissioning Authority (Radioactive Waste Management Directorate) to help prepare this paper. References [1] Eh and pH in compacted MX-80 bentonite. Muurinen, A. and Carlsson, T., NF-PRO RTD2 Deliverable 2.2.14 European Commission, Brussels, Belgium, 2007. [2] Villar, M.V., Fernández, A.M. and Gómez-Espina, R., NF-PRO RTD2 Deliverable 2.2.7 European Commission, Brussels, Belgium, 2006. [3] Experimental studies of the interactions between anaerobically corroding iron and bentonite. Carlson, L., Karnland, O., Oversby, V.M., Rance, A., Smart, N., Snellman, M., Vähänen, M. and Werme, L.O., Physics and Chemistry of the Earth, 32, 334-345, 2007. [4] Geochemical evolution of near field. Process modelling. Arcos, D., Grandia, F. and Tremosa, J., NF-PRO RTD2 Report D2.6.6, European Commission, 2007. [5] Modelling iron-bentonite interactions. Savage, D., Watson, C., Benbow, S. and Wilson, J., Applied Clay Science, in press. [6] Reactivity/transport investigations on the detailed understanding of the chemical reactions at the bentonite-concrete interface. Cuevas, J., Fernández, R., Vigil, R., Rodríguez, M., Leguey, S. and Cuñado, M.A., EC NF-PRO deliverable D2.4.5, European Commission, 2007. [7] The Diffusion of Cementitious Water in Bentonite: A Raiden 3 Simulation. NF-PRO RTD Component 2, WP 2.6. Watson, C.E., Hane, K., Savage, D. and Benbow, S., Quintessa Report QRS-1137AB-1, Quintessa Limited, Henley-on-Thames, UK, 2005. [8] Summary of GRS results in NF-PRO. Herbert, H.-J., Kasbohm, J. and Sprenger, H., NF-PRO RTD2 Deliverable D2.2.4 and D2.4.1 European Commission, Brussels, Belgium, 2007. [9] Effect of carbonate on the sorption of Ni(II), U(VI) and Eu(III) on montmorillonite: Methodology and experimental results for Ni(II). Bradbury, M.H. and Baeyens, B., NF-PRO RTD2 Deliverable D2.5.1, European Commission, Brussels, Belgium, 2005. [10] Report on sorption measurements. Bradbury, M.H. and Baeyens, B., NF-PRO RTD2 Deliverable D2.5.14, European Commission, Brussels, Belgium, 2006. [11] A mechanistic description of Ni and Zn sorption on Na-montmorillonite. Part II: Modelling. Bradbury, M.H. and Baeyens, B., Journal of Contaminant Hydrology, 27, 223-248, 1997. [12] Diffusion and retention of radionuclides in compacted bentonite. Part I: Determination of pore water composition of compacted bentonite for different bulk dry densities. Van Loon, L.R., Müller, W., Glaus, M.A., Baeyens, B. and Bradbury, M.H., NF-PRO RTD2 Deliverable 2.5.4 European Commission, Brussels, Belgium, 2005. [13] Diffusion and retention of radionuclides in compacted bentonite: Part II: Diffusion and retention of 22 Na + and 85 Sr 2+ in compacted bentonite at different bulk dry densities. Van Loon, L.R., NF-PRO RTD2 Deliverable 2.5.13 European Commission, Brussels, Belgium, 2006. [14] Anion exclusion effects in compacted bentonites: towards a better understanding of anion diffusion. Van Loon, L.R., Glaus, M.A. and Müller, W., Applied Geochemistry, 22, 2536-2552, 2007. [15] Diffusion of 22 Na and 85 Sr in Montmorillonite: Evidence of interlayer diffusion being the dominant pathway at high compaction. Glaus, M.A., Baeyens, B., Bradbury, M.H., Jakob, A., Van Loon, L.R. and Yaroshchuck, A., Environmental Science and Technology, 41, 478-485, 2007. 192

Impact of Thermo-Hydro-Mechanical Processes on Repository Performance Summary Patrik Sellin 1 , Hans-Joachim Alheid 2 1 SKB, Sweden 2 BGR, Germany The purpose of the RTD C3 in the NF-Pro project was to improve the degree of understanding of the thermo-hydro-mechanical and geochemical (THM(C)) processes in the near-field in an integrated way to enhance the predictive capability of the existing models, especially in relation to their link with safety functions and the assessment of long-term safety. The focus was put on a few selected THM(C) processes: The saturation of a bentonite buffer Gas migration in/through a bentonite buffer Compaction properties of a crushed salt backfill The main focus of the work was to improve the handling these processes in long term performance assessment, but issues on EBS manufacturing has also been addressed. 1. Introduction The primary aim of the engineered barriers is to isolate the radioactive waste from the rock and particularly from the groundwater. Buffers and backfills (of some disposal concepts) will be exposed to high temperature, significant temperature gradients, and pressure exerted by the canisters and by the convergence of the emplacement drift. These factors combine to create conditions that determine the short- and long-term performance and chemical stability and form the basis of the design of the buffer/backfill with respect to composition, density and dimensions. A number of projects and large scale experiments carried out prior to NF-Pro (for example FEBEX, PROTOTYPE, OPHELIE, BAMBUS) have provided very valuable information and a significant amount of data that is being used for the validation of THM numerical models. However the duration of these tests has been yet relatively short compared with the slow evolution of the processes involved. Also a number of questions remained in relation with some aspects such as the long-term evolution of the bentonite properties and the effects of gas generation in a clay buffer. In the case of buffers made with compacted salt grit, there are still open questions concerning the compaction process at low porosities and development of permeability in the buffer. Clay-salt mixtures may help to guarantee an instant sealing of the buffer even at times when compaction is not yet completed but the THMC behaviour of such mixtures were not well analysed. Joints between blocks and with the rock are possible pathways that also may have to be considered. For these reasons, a comprehensive analysis of the THM (C) processes in the EBS have been carried out in RTD Component 3 in NF-Pro, considering different types of buffer material (bentonite, salt), different scales (from laboratory to repository scale), and different degrees of saturation and thermal states. This paper is a brief summary of some of the activities and conclusions from the work within the RTDC [1]. 2. Objectives 193

Impact of Thermo-Hydro-Mechanical Processes on Repository Performance<br />

Summary<br />

Patrik Sellin 1 , Hans-Joachim Alheid 2<br />

1 SKB, Sweden<br />

2 BGR, Germany<br />

The purpose of the RTD C3 in the NF-Pro project was to improve the degree of understanding<br />

of the thermo-hydro-mechanical and geochemical (THM(C)) processes in the near-field in an<br />

integrated way to enhance the predictive capability of the existing models, especially in relation<br />

to their link with safety functions and the assessment of long-term safety. The focus was<br />

put on a few selected THM(C) processes:<br />

The saturation of a bentonite buffer<br />

Gas migration in/through a bentonite buffer<br />

Compaction properties of a crushed salt backfill<br />

The main focus of the work was to improve the handling these processes in long term performance<br />

assessment, but issues on EBS manufacturing has also been addressed.<br />

1. Introduction<br />

The primary aim of the engineered barriers is to isolate the radioactive waste from the rock and particularly<br />

from the groundwater. Buffers and backfills (of some disposal concepts) will be exposed to<br />

high temperature, significant temperature gradients, and pressure exerted by the canisters and by the<br />

convergence of the emplacement drift. These factors combine to create conditions that determine<br />

the short- and long-term performance and chemical stability and form the basis of the design of the<br />

buffer/backfill with respect to composition, density and dimensions.<br />

A number of projects and large scale experiments carried out prior to NF-Pro (for example FEBEX,<br />

PROTOTYPE, OPHELIE, BAMBUS) have provided very valuable information and a significant<br />

amount of data that is being used for the validation of THM numerical models. However the duration<br />

of these tests has been yet relatively short compared with the slow evolution of the processes<br />

involved. Also a number of questions remained in relation with some aspects such as the long-term<br />

evolution of the bentonite properties and the effects of gas generation in a clay buffer. In the case of<br />

buffers made with compacted salt grit, there are still open questions concerning the compaction<br />

process at low porosities and development of permeability in the buffer. Clay-salt mixtures may<br />

help to guarantee an instant sealing of the buffer even at times when compaction is not yet completed<br />

but the THMC behaviour of such mixtures were not well analysed. Joints between blocks<br />

and with the rock are possible pathways that also may have to be considered.<br />

For these reasons, a comprehensive analysis of the THM (C) processes in the EBS have been carried<br />

out in RTD Component 3 in NF-Pro, considering different types of buffer material (bentonite,<br />

salt), different scales (from laboratory to repository scale), and different degrees of saturation and<br />

thermal states. This paper is a brief summary of some of the activities and conclusions from the<br />

work within the RTDC [1].<br />

2. Objectives<br />

193

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