Euradwaste '08 - EU Bookshop - Europa
Euradwaste '08 - EU Bookshop - Europa Euradwaste '08 - EU Bookshop - Europa
access shafts, providing higher permeability for water and gases. The EDZ could act as a preferential pathway for radionuclide transport and may play an important role in the overall performance of a repository, particularly in scenarios with early canister and seal failure. The extent and the characteristics of the affected zone may vary significantly. Prior to NF-PRO, a large number of studies were published regarding EDZ in terms of phenomenology in different host rocks. Nevertheless, a need was identified for a deeper knowledge of EDZrelated phenomena in order to establish a better basis for abstracting a PA model of transport in the EDZ from a detailed scientific description of the processes. Characterisation of the EDZ As part of NF-PRO, conventional methods and techniques were applied to study the initiation of the EDZ and to measure key characteristics and associated parameter values of the EDZ. In addition to in situ measurements, laboratory tests on rock samples were performed. Experimental data were compared with results from numerical modelling studies. New techniques for in situ EDZ characterisation were developed and improved: these include seismic-acoustic monitoring, ultra-sonic logging, seismic and geoelectric tomography and very high resolution ultrasonic logging. Short-term evolution of the EDZ Important progress has been made by NF-PRO with respect to investigations of the phase of repository operation (short-term evolution of the EDZ). During this phase, ventilation of drifts may cause desaturation and induce thermo-hydro-mechanical effects and/or chemical perturbations in the host rock. In general, results from experimental work by NF-PRO on indurated and soft clay rocks indicate that the extent of the affected zone in the host is very limited. The size of the altered host rock in the experimental gallery at -445m in the Callovo-Oxfordian formation (Meuse/Haute-Marne URL, Bure, France) and in the ventilation II experiment in the Opalinus Clay (Mont Terri URF) typically is in the range of 20 to 60 centimetres. In situ experiments to study the zone affected by oxidation around the Test Draft in the HADES URF (Mol, Belgium) evidence that the oxidised zone extents less than one metre in the Boom Clay. The affected zone is associated with open fractures that form during excavation. Diffusion of oxygen in the Boom Clay is a very slow process, which is negligible relative to instantaneous oxidation along fractures. Long-term evolution of the EDZ Investigations under NF-PRO on the long-term evolution of the EDZ focussed on self-sealing and gas transport processes in clays and salt host rock. Laboratory and in situ experiments performed under NF-PRO on plastic and indurated clays have provided new quantitative data on self-sealing of the EDZ (i.e. the decrease of permeability with time) and have expanded knowledge on different factors (thermal, mechanical, chemical…) involved. Short-term microscale processes contributing to self-sealing include swelling of smectite minerals, mechanical closing due to the plasticity of clay minerals and creep. In the long term, precipitation of minerals such as carbonates plays a role in self-sealing processes. Other factors such as resaturation and thermal impact will lead to a quasi-complete self sealing of the EDZ. Observations made on plastic clays (e.g. Boom Clay) indicate that self-sealing may result in a progressive restoring of permeability to values comparable to those of undisturbed rock, although residual microscale evidence of features initially formed in the EDZ network may remain. In indurated clays like the Callovo-Oxfordian clay, open fractures of the EDZ progressively close and very low permeability 170
close to values of the undisturbed host rock may be attained although, locally, the porosity may remain greater than in the undisturbed rock. In the very long-term, a reconsolidation may occur along fissures and/or micro-fissured zones. Investigations concerning gas transfer along the EDZ Work in the framework of NF-PRO on gas transfer along the EDZ focussed on the characterisation of gas transfer properties, in particular gas permeability, gas threshold pressure, capillary curves of the EDZ before, during and after hydro-mechanical self-sealing. Also, studies were performed to investigate the consequences of impairments due to an excessive gas pressure. These investigations focussed on gas transfer processes in plastic and indurated clay and rock salt. Results obtained have demonstrated that fast self-sealing of the EDZ occurs in plastic clays. At the microstructural level, preferential pathways for gas migration may exist. However, effective hydro-mechanical selfsealing is expected to occur relatively rapidly during resaturation, in particular before significant gas pressure build-up occurs. 4.5 Advances in research related to process couplings and integration in Performance Assessment NF-PRO has carried out integrated analyses of the near-field evolution. These analyses have been performed for different reference disposal concepts and host rocks and have confirmed that the near-field displays a high degree of robustness and redundancy. Results from these evaluations are summarised in [5] and have allowed identifying remaining key uncertainties and priority areas in future research for these systems. 5. Conclusion Experimental studies and modelling work by NF-PRO have provided new insights in and information on key process affecting the overall performance of the near-field system. NF-PRO has a major strategic impact on European disposal-related research since the Integrated Project has effectively contributed to strengthening the scientific-technical basis for geological disposal. References [1] Grambow et al. 2008: RTDC-1 Final Synthesis Report, Dissolution and release from the waste matrix. EU NF-PRO Project FI6W-CT-2003-02389. [2] Arcos, D., Hernán, P., De La Cruz, B., Herbert, H.-J., Savage, D., Smart, N.R., Villar, M.V., Van Loon, L.R. 2008: NF-PRO RTDC-2 Synthesis Report, Deliverable (D-N°:D2.6.4) EU NF-PRO Project FI6W-CT-2003-02389. [3] Villar et al. 2008: RTDC-3 Synthesis Report. EU NF-PRO Project FI6W-CT-2003-02389. [4] Aranyossy J-F., Mayor, J.C., Marschall, & Plas, F. 2008: EDZ development and evolution. RTDC-4 Synthesis Report. EU NF-PRO Project FI6W-CT-2003-02389. [5] Johnson, L. et al. 2008: RTDC-5 Synthesis Report, Deliverable (D-N°:5.2.3), EU NF-PRO Project FI6W-CT-2003-02389. [6] Poinssot, C. et al. Final report of the European Project Spent Fuel Stability under Repository Conditions. CEA-R-6093. ISSN 0429-3460, 2005, pp. 103. 171
- Page 136 and 137: Figure 6: Principle design characte
- Page 138 and 139: Table 6: FUTURIX FTA fuels Fuel nam
- Page 140 and 141: 124
- Page 142 and 143: After a review of the present statu
- Page 144 and 145: suranium elements, “repository av
- Page 146 and 147: nificant fraction of fast reactors.
- Page 148 and 149: high level waste at the considered
- Page 150 and 151: Pu or M.A. by the time it is needed
- Page 152 and 153: of U and Pu only. P&T could complem
- Page 154 and 155: suranium elements, the thermal load
- Page 156 and 157: Phase-Out TRU Transmutation Scenari
- Page 158 and 159: 10 nuclear nations (Argentina, Braz
- Page 160 and 161: elease, strong radiation, pressure
- Page 162 and 163: A1 3.79E+08 270 7.12E-07 A2 3.51E+0
- Page 164 and 165: nuclear fission in the reactors. Th
- Page 166 and 167: 5. Conclusions The HLW arising from
- Page 168 and 169: 152
- Page 170 and 171: tinides (MA) are destined for geolo
- Page 172 and 173: [3] Enrique González: Head of Nucl
- Page 174 and 175: 158
- Page 176 and 177: 160
- Page 178 and 179: erage level of funding of research
- Page 180 and 181: Prior to NF-PRO, the question wheth
- Page 182 and 183: nant exchangeable cation. This chan
- Page 184 and 185: eal concentration gradient in sampl
- Page 188 and 189: 172
- Page 190 and 191: in the European coordinated action
- Page 192 and 193: proved, with amongst others the det
- Page 194 and 195: 4. Discussion Tests with dissolved
- Page 196 and 197: though with a slow rate. The data i
- Page 198 and 199: surface. The coupling between water
- Page 200 and 201: nuclear waste within the near-field
- Page 202 and 203: tion of the column [2]. Moreover, t
- Page 204 and 205: case, the iron diffusion front in t
- Page 206 and 207: 5.1 Sorption As an example of the t
- Page 208 and 209: corrosion; up-scaling of clay alter
- Page 210 and 211: Bentonite barriers are very importa
- Page 212 and 213: To determine the impact of temperat
- Page 214 and 215: in the underground laboratory in Gr
- Page 216 and 217: under isothermal conditions. If the
- Page 218 and 219: 202
- Page 220 and 221: Zones around such openings which ex
- Page 222 and 223: layout of cells developed by ENPC w
- Page 224 and 225: ) a) e) d) f) d) e) f) c) Figure 3.
- Page 226 and 227: EDZ removal by additional excavatio
- Page 228 and 229: [7] Wenk H.-R., Voltolini, M., Mazu
- Page 230 and 231: that provided by various national s
- Page 232 and 233: system robustness, rather than as s
- Page 234 and 235: Regarding diffusion studies perform
access shafts, providing higher permeability for water and gases. The EDZ could act as a preferential<br />
pathway for radionuclide transport and may play an important role in the overall performance of<br />
a repository, particularly in scenarios with early canister and seal failure. The extent and the characteristics<br />
of the affected zone may vary significantly.<br />
Prior to NF-PRO, a large number of studies were published regarding EDZ in terms of phenomenology<br />
in different host rocks. Nevertheless, a need was identified for a deeper knowledge of EDZrelated<br />
phenomena in order to establish a better basis for abstracting a PA model of transport in the<br />
EDZ from a detailed scientific description of the processes.<br />
Characterisation of the EDZ<br />
As part of NF-PRO, conventional methods and techniques were applied to study the initiation of the<br />
EDZ and to measure key characteristics and associated parameter values of the EDZ. In addition to<br />
in situ measurements, laboratory tests on rock samples were performed. Experimental data were<br />
compared with results from numerical modelling studies. New techniques for in situ EDZ characterisation<br />
were developed and improved: these include seismic-acoustic monitoring, ultra-sonic logging,<br />
seismic and geoelectric tomography and very high resolution ultrasonic logging.<br />
Short-term evolution of the EDZ<br />
Important progress has been made by NF-PRO with respect to investigations of the phase of repository<br />
operation (short-term evolution of the EDZ). During this phase, ventilation of drifts may cause<br />
desaturation and induce thermo-hydro-mechanical effects and/or chemical perturbations in the host<br />
rock. In general, results from experimental work by NF-PRO on indurated and soft clay rocks indicate<br />
that the extent of the affected zone in the host is very limited. The size of the altered host rock<br />
in the experimental gallery at -445m in the Callovo-Oxfordian formation (Meuse/Haute-Marne<br />
URL, Bure, France) and in the ventilation II experiment in the Opalinus Clay (Mont Terri URF)<br />
typically is in the range of 20 to 60 centimetres. In situ experiments to study the zone affected by<br />
oxidation around the Test Draft in the HADES URF (Mol, Belgium) evidence that the oxidised<br />
zone extents less than one metre in the Boom Clay. The affected zone is associated with open fractures<br />
that form during excavation. Diffusion of oxygen in the Boom Clay is a very slow process,<br />
which is negligible relative to instantaneous oxidation along fractures.<br />
Long-term evolution of the EDZ<br />
Investigations under NF-PRO on the long-term evolution of the EDZ focussed on self-sealing and<br />
gas transport processes in clays and salt host rock.<br />
Laboratory and in situ experiments performed under NF-PRO on plastic and indurated clays have<br />
provided new quantitative data on self-sealing of the EDZ (i.e. the decrease of permeability with<br />
time) and have expanded knowledge on different factors (thermal, mechanical, chemical…) involved.<br />
Short-term microscale processes contributing to self-sealing include swelling of smectite<br />
minerals, mechanical closing due to the plasticity of clay minerals and creep. In the long term, precipitation<br />
of minerals such as carbonates plays a role in self-sealing processes. Other factors such as<br />
resaturation and thermal impact will lead to a quasi-complete self sealing of the EDZ. Observations<br />
made on plastic clays (e.g. Boom Clay) indicate that self-sealing may result in a progressive restoring<br />
of permeability to values comparable to those of undisturbed rock, although residual microscale<br />
evidence of features initially formed in the EDZ network may remain. In indurated clays like the<br />
Callovo-Oxfordian clay, open fractures of the EDZ progressively close and very low permeability<br />
170