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Bochum) for the study of XPS and UHV-FTIR and providing the corresponding figures. Dr. Bauke Albada and Martin strack for carrying out the HPLC measurements (Chair of Inorganic Chemistry I - Bioinorganic Chemistry, Prof. Dr. Nils Metzler‐ Nolte, Ruhr‐University Bochum). Noushin Arshadi (group of Prof. Dr. Martin Muhler, Ruhr‐University Bochum) for collecting the N2 sorption isotherms. Dr. Rolf Neuser (Faculty of Geosciences, Institute of Geology, Mineralogy and Geophysics, Ruhr‐University Bochum) for the gold coating on the non-conducting SEM samples. Dr. Kira Khaletskaya and Stefan Cwik for conducting SEM-EDX measurements. Dr. Christian Wiktor for collecting TEM-EDX spectra. Dr. Christian Sternemann (and Andreas Schneemann, Suttipong Wannapaiboon) for helping me to gather X‐ray diffraction patterns at the DELTA facility. Ralph Wagner (and Andreas Schneemann) for assistance of performing XAS on the Ru- (DE)MOF samples and for introducing me to the study of XANES. Karin Bartholomäus for elemental analysis. Prof. Dr. Jeffrey R. Long for the chance to have a research stay in his group, at the Department of Chemistry, University of California, Berkeley (USA). The whole group for an inspiring communication and very nice time during my stay. I address many thanks to Miguel Gonzalez for guiding me on conducting the catalytic reaction in Chapter 4 and assistance on evaluating the data. Last but not the least, Dianne Xiao, Douglas Reed, Julia Oktawiec for their great assistance with sorption studies and help on collecting sorption isotherms. Dr. Francesc X. Llabrés i Xamena (Institute of Chemical Technologies, Polytechnical University of Valencia, Spain) for the collaboration and Konstantin Epp (group of the Prof. Dr. Roland A. Fischer in Technical University of Munich) for performing the catalytic reaction in Chapter 4. Zhihao Chen and Majd Al-Naji (group of Prof. Dr. Roger Gläser, University of Leipzig) for carrying out the catalytic reaction in Chapter 5 and the assistance on study the catalytic activity. I also want to acknowledge the financial support from China Scholarship Council to my whole Ph.D study and Research School Plus at Ruhr-University Bochum for the funding of
attending conferences, my research stay at UC Berkeley and my invitation of Dianne Xiao (from UC Berkeley) for the short visit in ACII group. I am thankful to the master students who work with me during my Ph.D study: Marco Rehosek, Sebastian Kunze, and Konstantin Epp. I am grateful to all ACII members for a nice working atmosphere, the great team spirit and inspiring communications, especially the former and present MOF family. The memorable and wonderful time we spend together in the MOF 2014 conference and the trip in Japan with our MOF guest Takashi Toyao. I express my many thanks to Dr. Christian Wiktor on teaching me skills for my first poster. Also further thanks to Dr. Chuanqiang Li, Suttipong Wannapaiboon, Andreas Schneemann, and Konstantin Epp for the kind accompany during XAS data collecting in DELTA facility. Besides, I address many thanks to my lab neighbor Dr. Raghavender Medishetty and Dr. Arik Puls for the abundant and fruitful discussions. I would like to express my thanks to Dr. Mariusz Molon for affording technical help on my computer, and OM group members for sharing the experience on air-free synthesis. I am grateful to Uschi Hermann for her kindness and great help in the lab. Furthermore, I would like to express my thanks to Jana Weiing, Andreas Schneemann, Jiyeon Kim, Inke Schwedler and Dr. Christian Wiktor for the great time during ACS fall meeting and the nice trip in Boston. I would like to express my warm thanks to Sabine Pankau and Jacinta Essling for their great help with administrative issues. Many thanks to my office colleagues for nice working atmosphere, giving me suggestions and help on the daily life and as translators: Sarah Karle, Mathies Evers, Stefan Cwik, Maximilian Gebhard, Inke Schwedler, Richard O'Donoghue, Jiyeon Kim, Andreas Schneemann, Dr. Christian Wiktor, Dr. Arik Puls, and Dr. Sun Ja Kim. I am also thankful to Dr. Ke Xu for helping me go through a bunch of documents to settle down in Germany. Last but the most important, I would like to deeply thank my parents Denggao Zhang and Chunying Wu, for giving me the freedom and support to study abroad and their endless love and motivation during my studies. Also thank my siblings, Wenjing and Wenbo
Page 1: Controlled Modification of Metal-Or
Page 5: This thesis is based on the work pe
Page 10 and 11: Zhang, for their continuous support
Page 12 and 13: II 3.2.1 Synthesis and characteriza
Page 14 and 15: IV 7.3.4 Synthesis of Cu-DEMOF samp
Page 16 and 17: VI DMSO dobdc e.g. EA EDX EtOH EXAF
Page 18 and 19: VIII TOF UHV UiO UMCM vs WCA XANES
Page 20 and 21: 2 Chapter 1 limitations of the (non
Page 22 and 23: 4 Chapter 2 For the synthesis of CP
Page 24 and 25: 6 Chapter 2 cavities is able to rev
Page 26 and 27: 8 Chapter 2 2.2.2 MOF features Adva
Page 28 and 29: 10 Chapter 2 Figure 2.5. A series o
Page 30 and 31: 12 Chapter 2 the material is retain
Page 32 and 33: 14 Chapter 2 2.3 Synthetic approach
Page 34 and 35: 16 Chapter 2 Expansion of this stru
Page 36 and 37: 18 Chapter 2 (H2BPDC) [75] or other
Page 38 and 39: 20 Chapter 2 Cr III CUSs of MIL-101
Page 40 and 41: 22 Chapter 2 Figure 2.14. Schematic
Page 42 and 43: 24 Chapter 2 adsorbate-surface inte
Page 44 and 45: 3 Controlled secondary building uni
Page 46 and 47: 28 Chapter 3 3.1 Preparation and in
Page 48 and 49: 30 Chapter 3 formula of [Ru3 II,III
Page 50 and 51: Intensity, a. u. 32 Chapter 3 quali
Page 52 and 53: 34 Chapter 3 After activating the R
Page 54 and 55: 36 Chapter 3 presence of the residu
Page 56 and 57: Intensity, a. u. 38 Chapter 3 the a
Page 58 and 59:
40 Chapter 3 extent than acetic aci
Page 60 and 61:
42 Chapter 3 Ru-nodes. Therefore, r
Page 62 and 63:
44 Chapter 3 decomposition of [BF4]
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deriv. normalized E) 46 Chapter 3 F
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48 Chapter 3 3.1.6 Summary Applying
Page 68 and 69:
50 Chapter 3 3.2 Elaboration of Ru
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52 Chapter 3 with that of the Ru II
Page 72 and 73:
54 Chapter 3 Figure 3.20. (a) XANES
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4 Linker-based MOF solid solutions:
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58 Chapter 4 4.1 Introduction 4.1.1
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60 Chapter 4 framework [Cu2(ndc)2(d
Page 80 and 81:
62 Chapter 4 partial replacing of B
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64 Chapter 4 in the case of ip intr
Page 84 and 85:
66 Chapter 4 4.2.1.1 Crystallinity
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68 Chapter 4 suggesting the absence
Page 88 and 89:
70 Chapter 4 Table 4.1. The molar f
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72 Chapter 4 Figure 4.11. IR spectr
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74 Chapter 4 taking into account th
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76 Chapter 4 As quantitative digest
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78 Chapter 4 (Figure 4.16). Notably
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80 Chapter 4 framework Ru-species (
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82 Chapter 4 Figure 4.20. XANES spe
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84 Chapter 4 It is important to not
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86 Chapter 4 Ru δ+ have been obser
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88 Chapter 4 Figure 4.25. UHV-IR sp
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90 Chapter 4 Table 4.5. Possible de
Page 110 and 111:
CO 2 adsorbed, mmol/g 92 Chapter 4
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H 2 adsorbed, mmol/g 94 Chapter 4 F
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CO 2 adsorbed, mmol/g 96 Chapter 4
Page 116 and 117:
H 2 adsorbed, mmol/g 98 Chapter 4 8
Page 118 and 119:
H 2 adsorbed, mmol/g 100 Chapter 4
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102 Chapter 4 presence of H2. [236]
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104 Chapter 4 reactive metal center
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106 Chapter 4 4.2.6 Conclusions App
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108 Chapter 4 4.3 Defects Engineeri
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Intensity, a. u. 110 Chapter 4 as-s
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weight loss, % 112 Chapter 4 100 Cu
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weight loss, % 114 Chapter 4 record
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116 Chapter 4 4.3.2 Composition and
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V, cm 3 /g 118 Chapter 4 500 400 30
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120 Chapter 4 Figure 4.50. From lef
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5 Simultaneous introduction of vari
Page 142 and 143:
124 Chapter 5 preferred like Cu 2+
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126 Chapter 5 5.2 Preparation and S
Page 146 and 147:
128 Chapter 5 Figure 5.5. Pawley Fi
Page 148 and 149:
130 Chapter 5 5.3 Compositional cha
Page 150 and 151:
132 Chapter 5 Table 5.3. The assign
Page 152 and 153:
134 Chapter 5 framework are dominan
Page 154 and 155:
136 Chapter 5 5.4 Synthesis, compos
Page 156 and 157:
138 Chapter 5 obtained Pd-doped sol
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140 Chapter 5 Figure 5.18. Deconvol
Page 160 and 161:
V, cm 3 /g 142 Chapter 5 sorption i
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144 Chapter 5 time as well as the i
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146 Chapter 5 5.6 Conclusions In su
Page 166 and 167:
148 Chapter 6 coordinating anion),
Page 168 and 169:
7 Experimental Section In this Chap
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152 Chapter 7 as water and hydroxyl
Page 172 and 173:
154 Chapter 7 internal standards an
Page 174 and 175:
156 Chapter 7 Uppermost layer is in
Page 176 and 177:
158 Chapter 7 to the more tightly b
Page 178 and 179:
160 Chapter 7 7.2 Experimental data
Page 180 and 181:
162 Chapter 7 [Ru2(OOCC(CH3)3)4(H2O
Page 182 and 183:
164 Chapter 7 Figure 7.7. The PXRD
Page 184 and 185:
166 Chapter 7 [Ru2(OOCCH3)4(H2O)2]B
Page 186 and 187:
168 Chapter 7 [Ru2(OOCCH3)4](THF)2
Page 188 and 189:
170 Chapter 7 [Ru3(BTC)2(OH)1.5]n·
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172 Chapter 7 [Ru3(BTC)2]n∙(AcOH)
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174 Chapter 7 Table 7.3. Feeding mo
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176 Chapter 7 For comparison of the
Page 196 and 197:
178 Chapter 7 7.3.4 Synthesis of Cu
Page 198 and 199:
180 Chapter 7 D3 The mixture of H3B
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182 Chapter 7 D5 This sample was re
Page 202 and 203:
184 Chapter 7 The synthesis of D7 a
Page 204 and 205:
186 Chapter 7 7.4 Experimental data
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188 Chapter 7 Figure 7.26. PXRD pat
Page 208 and 209:
190 Chapter 7 7.4.2 Hydrogenation o
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192 Chapter 7 7.5 Supplementary det
Page 212 and 213:
8 Bibliography [1] A. J. Ihde, The
Page 214 and 215:
196 Bibliography [61] S. Ma, D. Sun
Page 216 and 217:
198 Bibliography [121] T. K. Prasad
Page 218 and 219:
200 Bibliography [180] Y. Kobayashi
Page 220 and 221:
202 Bibliography [239] A. L. Harreu
Page 222 and 223:
204 Bibliography [297] A. P. Hammer
Page 224 and 225:
206 Appendix List of Presentations
Page 226:
208 Appendix 05. 2015 Grant from th
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