- Page 1: Controlled Modification of Metal-Or
- Page 5: This thesis is based on the work pe
- Page 9 and 10: attending conferences, my research
- Page 11 and 12: Table of Contents Table of Contents
- Page 13 and 14: III 5.4 Synthesis, compositional ch
- Page 15 and 16: V Abbreviations 4-btapa 5-Br-ip 5-B
- Page 17 and 18: VII MTV Mw NMR NP PAP PivO PivOH PN
- Page 19 and 20: 1 Motivation Looking through the es
- Page 21 and 22: 2 General introduction The aim of t
- Page 23 and 24: Chapter 2 5 On the other hand, link
- Page 25 and 26: Chapter 2 7 2.2 Definition, Chemist
- Page 27 and 28: Chapter 2 9 inorganic SBU can be co
- Page 29 and 30: Chapter 2 11 Figure 2.7. a, Three c
- Page 31 and 32: Chapter 2 13 concentrated sodium hy
- Page 33 and 34: Chapter 2 15 afford a good way to s
- Page 35 and 36: Chapter 2 17 concentrations (e.g. 8
- Page 37 and 38: Chapter 2 19 the rection of H2dacob
- Page 39 and 40: Chapter 2 21 metal-precursors are e
- Page 41 and 42: Chapter 2 23 appealing perspectives
- Page 43 and 44: Chapter 2 25 asymmetric catalysis.
- Page 45 and 46: Chapter 3 27 which are structural a
- Page 47 and 48: Chapter 3 29 between gas molecules
- Page 49 and 50: Chapter 3 31 In this Chapter CSA is
- Page 51 and 52: Chapter 3 33 All Ru-MOFs 1-4 of the
- Page 53 and 54: Intensity, a. u. Chapter 3 35 3.1.3
- Page 55 and 56: Chapter 3 37 Table 3.1. Comparison
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Chapter 3 39 Figure 3.9. IR spectra
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Chapter 3 41 exchange. This might s
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Chapter 3 43 Figure 3.12. Possible
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Chapter 3 45 m 2 /mmol (based on th
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deriv. normalized E) Chapter 3 47 I
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Chapter 3 49 were investigated as w
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Intensity, a. u. Chapter 3 51 and a
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Chapter 3 53 3.2.2 Investigation on
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V, cm 3 /g Chapter 3 55 400 350 300
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Chapter 4 57 techniques. Interestin
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Chapter 4 59 This is the most strai
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Chapter 4 61 active catalytic cente
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Chapter 4 63 compared with the pare
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Chapter 4 65 4.2 Ruthenium Metal-Or
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Chapter 4 67 incorporated 5-X-ip li
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Chapter 4 69 4.2.1.2 The incorporat
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Chapter 4 71 molecule in the pores
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Chapter 4 73 ii) owing to the compe
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Chapter 4 75 the Cl-amount was subs
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Chapter 4 77 Figure 4.15. N 2 sorpt
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Chapter 4 79 increasing feeding of
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Chapter 4 81 XANES spectra (Figure
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Chapter 4 83 Interestingly, the pos
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Chapter 4 85 Figure 4.23. Deconvolu
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Chapter 4 87 evidence on the valenc
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Chapter 4 89 explains the observed
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Chapter 4 91 appear to dominate ove
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CO uptake, mmol/g Chapter 4 93 Tabl
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-Q st , kJ/mol Chapter 4 95 DEMOFs
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CO 2 adsorbed, mmol/g H 2 adsorbed,
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CO 2 adsorbed, mmol/g Chapter 4 99
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Chapter 4 101 samples 1a (8% of 5-O
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Chapter 4 103 reaction of benzyl am
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Yield, % Chapter 4 105 Table 4.8. C
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Chapter 4 107 performance reasonabl
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Intensity, a. u. Chapter 4 109 4.3.
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Chapter 4 111 H 3 BTC H 2 ip D4 D3
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Intensity, a. u. Intensity, a.u. Ch
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Chapter 4 115 H 3 BTC H 2 ip D8 D7
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V, cm 3 /g Chapter 4 117 more) in c
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Chapter 4 119 (e.g. H2ip, H3BTC, et
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Chapter 4 121 DEMOFs. Moreover, as
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Chapter 5 123 5.1 Introduction on t
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Chapter 5 125 pm) [257] via solid s
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Chapter 5 127 (Figure 5.3). This is
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Chapter 5 129 Figure 5.6. Crystal s
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Chapter 5 131 NPs, as no typical O
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Chapter 5 133 spectra of all prepar
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Chapter 5 135 Figure 5.12. N 2 sorp
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Chapter 5 137 The phase purity and
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Chapter 5 139 it is hard to disting
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weight loss, % Chapter 5 141 Table
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Chapter 5 143 5.5 Catalytic test re
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Chapter 5 145 Surprisingly, the nor
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6 Summary and Outlook Among all MOF
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Chapter 6 149 DEMOFs). These result
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Chapter 7 151 Single crystal XRD da
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Chapter 7 153 Figure 7.2. Schematic
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Chapter 7 155 measured under Ar. At
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Chapter 7 157 adsorbed at different
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Chapter 7 159 Buffers: A: water/MeC
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Chapter 7 161 Figure 7.3. PXRD patt
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Chapter 7 163 Table 7.1. Cell param
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Chapter 7 165 [Ru2(OOCCH3)4(THF)2]B
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Chapter 7 167 hours, a deep red bro
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Chapter 7 169 [Ru3(BTC)2Cl(AcO)0.5]
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Chapter 7 171 Figure 7.12. PXRD pat
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Chapter 7 173 7.3 Experimental data
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Chapter 7 175 Table 7.4. BET surfac
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Chapter 7 177 7.3.2 Catalytic react
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Chapter 7 179 D2 This sample was pr
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Chapter 7 181 D4 This sample was pr
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Chapter 7 183 D6 This sample was ob
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Chapter 7 185 Figure 7.23. PXRD pat
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Chapter 7 187 Figure 7.24. XPS surv
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Chapter 7 189 Cu/Pd-BTC_4 For sampl
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Absorbance, a. u. Chapter 7 191 O 2
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Chapter 7 193 Figure 7.30. PXRD pat
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Bibliography 195 [30] D. J. Tranche
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Bibliography 197 [90] W. Ouellette,
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Bibliography 199 [146] M. J. Cliffe
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Bibliography 201 [208] W. Zhang, O.
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Bibliography 203 [266] I. Cabria, M
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Appendix List of Publications Sever
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Appendix 207 Curriculum Vitae Perso