- Page 1: Controlled Modification of Metal-Or
- Page 5: This thesis is based on the work pe
- Page 8 and 9: Bochum) for the study of XPS and UH
- Page 10 and 11: Zhang, for their continuous support
- Page 12 and 13: II 3.2.1 Synthesis and characteriza
- Page 14 and 15: IV 7.3.4 Synthesis of Cu-DEMOF samp
- Page 16 and 17: VI DMSO dobdc e.g. EA EDX EtOH EXAF
- Page 18 and 19: VIII TOF UHV UiO UMCM vs WCA XANES
- Page 20 and 21: 2 Chapter 1 limitations of the (non
- Page 22 and 23: 4 Chapter 2 For the synthesis of CP
- Page 24 and 25: 6 Chapter 2 cavities is able to rev
- Page 26 and 27: 8 Chapter 2 2.2.2 MOF features Adva
- Page 28 and 29: 10 Chapter 2 Figure 2.5. A series o
- Page 30 and 31: 12 Chapter 2 the material is retain
- Page 32 and 33: 14 Chapter 2 2.3 Synthetic approach
- Page 34 and 35: 16 Chapter 2 Expansion of this stru
- Page 36 and 37: 18 Chapter 2 (H2BPDC) [75] or other
- Page 40 and 41: 22 Chapter 2 Figure 2.14. Schematic
- Page 42 and 43: 24 Chapter 2 adsorbate-surface inte
- Page 44 and 45: 3 Controlled secondary building uni
- Page 46 and 47: 28 Chapter 3 3.1 Preparation and in
- Page 48 and 49: 30 Chapter 3 formula of [Ru3 II,III
- Page 50 and 51: Intensity, a. u. 32 Chapter 3 quali
- Page 52 and 53: 34 Chapter 3 After activating the R
- Page 54 and 55: 36 Chapter 3 presence of the residu
- Page 56 and 57: Intensity, a. u. 38 Chapter 3 the a
- Page 58 and 59: 40 Chapter 3 extent than acetic aci
- Page 60 and 61: 42 Chapter 3 Ru-nodes. Therefore, r
- Page 62 and 63: 44 Chapter 3 decomposition of [BF4]
- Page 64 and 65: deriv. normalized E) 46 Chapter 3 F
- Page 66 and 67: 48 Chapter 3 3.1.6 Summary Applying
- Page 68 and 69: 50 Chapter 3 3.2 Elaboration of Ru
- Page 70 and 71: 52 Chapter 3 with that of the Ru II
- Page 72 and 73: 54 Chapter 3 Figure 3.20. (a) XANES
- Page 74 and 75: 4 Linker-based MOF solid solutions:
- Page 76 and 77: 58 Chapter 4 4.1 Introduction 4.1.1
- Page 78 and 79: 60 Chapter 4 framework [Cu2(ndc)2(d
- Page 80 and 81: 62 Chapter 4 partial replacing of B
- Page 82 and 83: 64 Chapter 4 in the case of ip intr
- Page 84 and 85: 66 Chapter 4 4.2.1.1 Crystallinity
- Page 86 and 87: 68 Chapter 4 suggesting the absence
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70 Chapter 4 Table 4.1. The molar f
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72 Chapter 4 Figure 4.11. IR spectr
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74 Chapter 4 taking into account th
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76 Chapter 4 As quantitative digest
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78 Chapter 4 (Figure 4.16). Notably
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80 Chapter 4 framework Ru-species (
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82 Chapter 4 Figure 4.20. XANES spe
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84 Chapter 4 It is important to not
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86 Chapter 4 Ru δ+ have been obser
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88 Chapter 4 Figure 4.25. UHV-IR sp
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90 Chapter 4 Table 4.5. Possible de
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CO 2 adsorbed, mmol/g 92 Chapter 4
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H 2 adsorbed, mmol/g 94 Chapter 4 F
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CO 2 adsorbed, mmol/g 96 Chapter 4
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H 2 adsorbed, mmol/g 98 Chapter 4 8
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H 2 adsorbed, mmol/g 100 Chapter 4
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102 Chapter 4 presence of H2. [236]
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104 Chapter 4 reactive metal center
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106 Chapter 4 4.2.6 Conclusions App
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108 Chapter 4 4.3 Defects Engineeri
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Intensity, a. u. 110 Chapter 4 as-s
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weight loss, % 112 Chapter 4 100 Cu
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weight loss, % 114 Chapter 4 record
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116 Chapter 4 4.3.2 Composition and
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V, cm 3 /g 118 Chapter 4 500 400 30
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120 Chapter 4 Figure 4.50. From lef
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5 Simultaneous introduction of vari
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124 Chapter 5 preferred like Cu 2+
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126 Chapter 5 5.2 Preparation and S
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128 Chapter 5 Figure 5.5. Pawley Fi
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130 Chapter 5 5.3 Compositional cha
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132 Chapter 5 Table 5.3. The assign
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134 Chapter 5 framework are dominan
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136 Chapter 5 5.4 Synthesis, compos
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138 Chapter 5 obtained Pd-doped sol
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140 Chapter 5 Figure 5.18. Deconvol
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V, cm 3 /g 142 Chapter 5 sorption i
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144 Chapter 5 time as well as the i
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146 Chapter 5 5.6 Conclusions In su
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148 Chapter 6 coordinating anion),
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7 Experimental Section In this Chap
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152 Chapter 7 as water and hydroxyl
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154 Chapter 7 internal standards an
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156 Chapter 7 Uppermost layer is in
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158 Chapter 7 to the more tightly b
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160 Chapter 7 7.2 Experimental data
- Page 180 and 181:
162 Chapter 7 [Ru2(OOCC(CH3)3)4(H2O
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164 Chapter 7 Figure 7.7. The PXRD
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166 Chapter 7 [Ru2(OOCCH3)4(H2O)2]B
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168 Chapter 7 [Ru2(OOCCH3)4](THF)2
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170 Chapter 7 [Ru3(BTC)2(OH)1.5]n·
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172 Chapter 7 [Ru3(BTC)2]n∙(AcOH)
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174 Chapter 7 Table 7.3. Feeding mo
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176 Chapter 7 For comparison of the
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178 Chapter 7 7.3.4 Synthesis of Cu
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180 Chapter 7 D3 The mixture of H3B
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182 Chapter 7 D5 This sample was re
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184 Chapter 7 The synthesis of D7 a
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186 Chapter 7 7.4 Experimental data
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188 Chapter 7 Figure 7.26. PXRD pat
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190 Chapter 7 7.4.2 Hydrogenation o
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192 Chapter 7 7.5 Supplementary det
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8 Bibliography [1] A. J. Ihde, The
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196 Bibliography [61] S. Ma, D. Sun
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198 Bibliography [121] T. K. Prasad
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200 Bibliography [180] Y. Kobayashi
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202 Bibliography [239] A. L. Harreu
- Page 222 and 223:
204 Bibliography [297] A. P. Hammer
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206 Appendix List of Presentations
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208 Appendix 05. 2015 Grant from th