200 Bibliography [180] Y. Kobayashi, B. Jacobs, M. D. Allendorf, J. R. Long, Chem. Mater. 2010, 22, 4120- 4122. [181] A. A. Talin, A. Centrone, A. C. Ford, M. E. Foster, V. Stavila, P. Haney, R. A. Kinney, V. Szalai, F. El Gabaly, H. P. Yoon, F. Léonard, M. D. Allendorf, Science 2014, 343, 66- 69. [182] C. Janiak, Dalton Trans. 2003, 2781-2804. [183] M. D. Allendorf, C. A. Bauer, R. K. Bhakta, R. J. T. Houk, Chem. Soc. Rev. 2009, 38, 1330-1352. [184] B. V. Harbuzaru, A. Corma, F. Rey, P. Atienzar, J. L. Jordá, H. García, D. Ananias, L. D. Carlos, J. Rocha, Angew. Chem. Int. Ed. 2008, 47, 1080-1083. [185] M. D. Allendorf, R. J. T. Houk, L. Andruszkiewicz, A. A. Talin, J. Pikarsky, A. Choudhury, K. A. Gall, P. J. Hesketh, J. Am. Chem. Soc. 2008, 130, 14404-14405. [186] B. Chen, Y. Yang, F. Zapata, G. Lin, G. Qian, E. B. Lobkovsky, Adv. Mater. (Weinheim, Ger.) 2007, 19, 1693-1696. [187] P. Horcajada, C. Serre, G. Maurin, N. A. Ramsahye, F. Balas, M. Vallet-Regí, M. Sebban, F. Taulelle, G. Férey, J. Am. Chem. Soc. 2008, 130, 6774-6780. [188] P. Horcajada, C. Serre, M. Vallet-Regí, M. Sebban, F. Taulelle, G. Férey, Angew. Chem. Int. Ed. 2006, 45, 5974-5978. [189] K. Brown, S. Zolezzi, P. Aguirre, D. Venegas-Yazigi, V. Paredes-Garcia, R. Baggio, M. A. Novak, E. Spodine, Dalton Trans. 2009, 1422-1427. [190] A. Dhakshinamoorthy, M. Alvaro, H. Garcia, J. Catal. 2009, 267, 1-4. [191] S. Xiang, W. Zhou, J. M. Gallegos, Y. Liu, B. Chen, J. Am. Chem. Soc. 2009, 131, 12415- 12419. [192] S. Bordiga, L. Regli, F. Bonino, E. Groppo, C. Lamberti, B. Xiao, P. S. Wheatley, R. E. Morris, A. Zecchina, Phys. Chem. Chem. Phys. 2007, 9, 2676-2685. [193] D. Y. Lee, E.-K. Kim, C. Y. Shin, D. V. Shinde, W. Lee, N. K. Shrestha, J. K. Lee, S.-H. Han, RSC Adv. 2014, 4, 12037-12042. [194] U. Mueller, M. Schubert, F. Teich, H. Puetter, K. Schierle-Arndt, J. Pastre, J. Mater. Chem. 2006, 16, 626-636. [195] Y.-K. Seo, G. Hundal, I. T. Jang, Y. K. Hwang, C.-H. Jun, J.-S. Chang, Microporous Mesoporous Mater. 2009, 119, 331-337. [196] M. Schlesinger, S. Schulze, M. Hietschold, M. Mehring, Microporous Mesoporous Mater. 2010, 132, 121-127. [197] O. Shekhah, H. Wang, S. Kowarik, F. Schreiber, M. Paulus, M. Tolan, C. Sternemann, F. Evers, D. Zacher, R. A. Fischer, C. Wöll, J. Am. Chem. Soc. 2007, 129, 15118-15119. [198] H. Noei, O. Kozachuk, S. Amirjalayer, S. Bureekaew, M. Kauer, R. Schmid, B. Marler, M. Muhler, R. A. Fischer, Y. Wang, J. Phys. Chem. C 2013, 117, 5658-5666. [199] M. McCann, A. Carvill, C. Cardin, M. Convery, Polyhedron 1993, 12, 1163-1169. [200] F. A. Urbanos, M. C. Barral, R. Jiménez-Aparicio, Polyhedron 1988, 7, 2597-2600. [201] M. C. Barral, R. Jimenez-Aparicio, J. L. Priego, E. C. Royer, M. J. Saucedo, F. A. Urbanos, U. Amador, J. Chem. Soc., Dalton Trans. 1995, 2183-2187. [202] R. W. Mitchell, A. Spencer, G. Wilkinson, J. Chem. Soc., Dalton Trans. 1973, 846-854. [203] T. Togano, M. Mukaida, T. Nomura, Bull. Chem. Soc. Jpn. 1980, 53, 2085-2086. [204] F. D. Cukiernik, A.-M. Giroud-Godquin, P. Maldivi, J.-C. Marchon, Inorg. Chim. Acta 1994, 215, 203-207. [205] T. Düren, F. Millange, G. Férey, K. S. Walton, R. Q. Snurr, J. Phys. Chem. C 2007, 111, 15350-15356. [206] D. Rose, G. Wilkinson, J. Chem. Soc. A 1970, 1791-1795. [207] A. J. Lindsay, G. Wilkinson, M. Motevalli, M. B. Hursthouse, J. Chem. Soc., Dalton Trans. 1985, 2321-2326.
Bibliography 201 [208] W. Zhang, O. Kozachuk, R. Medishetty, A. Schneemann, R. Wagner, K. Khaletskaya, K. Epp, R. A. Fischer, Eur. J. Inorg. Chem. 2015, 2015, 3913-3920. [209] T. Fukushima, S. Horike, Y. Inubushi, K. Nakagawa, Y. Kubota, M. Takata, S. Kitagawa, Angew. Chem. Int. Ed. 2010, 49, 4820-4824. [210] S. Horike, Y. Inubushi, T. Hori, T. Fukushima, S. Kitagawa, Chem. Sci. 2012, 3, 116- 120. [211] M. Lin Foo, S. Horike, T. Fukushima, Y. Hijikata, Y. Kubota, M. Takata, S. Kitagawa, Dalton Trans. 2012, 41, 13791-13794. [212] W. Kleist, M. Maciejewski, A. Baiker, Thermochim. Acta 2010, 499, 71-78. [213] T. Tsuruoka, S. Furukawa, Y. Takashima, K. Yoshida, S. Isoda, S. Kitagawa, Angew. Chem. Int. Ed. 2009, 48, 4739-4743. [214] A. Umemura, S. Diring, S. Furukawa, H. Uehara, T. Tsuruoka, S. Kitagawa, J. Am. Chem. Soc. 2011, 133, 15506-15513. [215] K. M. Choi, H. J. Jeon, J. K. Kang, O. M. Yaghi, J. Am. Chem. Soc. 2011, 133, 11920- 11923. [216] K. Koh, A. G. Wong-Foy, A. J. Matzger, J. Am. Chem. Soc. 2009, 131, 4184-4185. [217] K. Koh, A. G. Wong-Foy, A. J. Matzger, Angew. Chem. Int. Ed. 2008, 47, 677-680. [218] K. Koh, A. G. Wong-Foy, A. J. Matzger, J. Am. Chem. Soc. 2010, 132, 15005-15010. [219] Y. Liao, S. K. Yang, K. Koh, A. J. Matzger, J. S. Biteen, Nano Lett. 2012, 12, 3080-3085. [220] R. A. Beyerlein, C. Choi-Feng, J. B. Hall, B. J. Huggins, G. J. Ray, Top. Catal., 4, 27-42. [221] C. Baerlocher, D. Xie, L. B. McCusker, S.-J. Hwang, I. Y. Chan, K. Ong, A. W. Burton, S. I. Zones, Nat. Mater. 2008, 7, 631-635. [222] B. Bonelli, L. Forni, A. Aloise, J. B. Nagy, G. Fornasari, E. Garrone, A. Gedeon, G. Giordano, F. Trifirò, Microporous Mesoporous Mater. 2007, 101, 153-160. [223] F. Schröder, D. Esken, M. Cokoja, M. W. E. van den Berg, O. I. Lebedev, G. Van Tendeloo, B. Walaszek, G. Buntkowsky, H.-H. Limbach, B. Chaudret, R. A. Fischer, J. Am. Chem. Soc. 2008, 130, 6119-6130. [224] E. A. Braude, F. C. Nachod, Editors, Determination of Organic Structures by Physical Methods, Academic Press, 1955. [225] F. Genin, F. Quiles, A. Burneau, Phys. Chem. Chem. Phys. 2001, 3, 932-942. [226] K. Nakamoto, in Infrared and Raman Spectra of Inorganic and Coordination Compounds, John Wiley & Sons, Inc., 2008, pp. 1-273. [227] Z. Wang, J. Liu, B. Lukose, Z. Gu, P. G. Weidler, H. Gliemann, T. Heine, C. Wöll, Nano Lett. 2014, 14, 1526-1529. [228] K. S. W. Sing, D. H. Everett, R. A. W. Haul, L. Moscou, R. A. Pierotti, J. Rouquerol, T. Siemieniewska, Pure Appl. Chem. 1985, 57, 603-619. [229] R. C. Lochan, R. Z. Khaliullin, M. Head-Gordon, Inorg. Chem. 2008, 47, 4032-4044. [230] R. C. Lochan, M. Head-Gordon, Phys. Chem. Chem. Phys. 2006, 8, 1357-1370. [231] S. T. Madrahimov, J. R. Gallagher, G. Zhang, Z. Meinhart, S. J. Garibay, M. Delferro, J. T. Miller, O. K. Farha, J. T. Hupp, S. T. Nguyen, ACS catal. 2015, 5, 6713-6718. [232] D. Yang, S. O. Odoh, J. Borycz, T. C. Wang, O. K. Farha, J. T. Hupp, C. J. Cramer, L. Gagliardi, B. C. Gates, ACS catal. 2016, 6, 235-247. [233] J. Canivet, S. Aguado, Y. Schuurman, D. Farrusseng, J. Am. Chem. Soc. 2013, 135, 4195-4198. [234] E. D. Metzger, C. K. Brozek, R. J. Comito, M. Dincă, ACS Cent. Sci. 2016. [235] I. Ogino, B. C. Gates, Chem. Eur. J. 2009, 15, 6827-6837. [236] I. Ogino, B. C. Gates, J. Am. Chem. Soc. 2008, 130, 13338-13346. [237] G. Laurenczy, A. E. Merbach, J. Chem. Soc., Chem. Commun. 1993, 187-189. [238] J. S. Bass, L. Kevan, J. Phys. Chem. 1990, 94, 1483-1489.
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Controlled Modification of Metal-Or
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This thesis is based on the work pe
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Bochum) for the study of XPS and UH
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Zhang, for their continuous support
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II 3.2.1 Synthesis and characteriza
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IV 7.3.4 Synthesis of Cu-DEMOF samp
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VI DMSO dobdc e.g. EA EDX EtOH EXAF
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VIII TOF UHV UiO UMCM vs WCA XANES
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2 Chapter 1 limitations of the (non
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4 Chapter 2 For the synthesis of CP
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6 Chapter 2 cavities is able to rev
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8 Chapter 2 2.2.2 MOF features Adva
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10 Chapter 2 Figure 2.5. A series o
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12 Chapter 2 the material is retain
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14 Chapter 2 2.3 Synthetic approach
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16 Chapter 2 Expansion of this stru
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18 Chapter 2 (H2BPDC) [75] or other
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20 Chapter 2 Cr III CUSs of MIL-101
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22 Chapter 2 Figure 2.14. Schematic
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24 Chapter 2 adsorbate-surface inte
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3 Controlled secondary building uni
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28 Chapter 3 3.1 Preparation and in
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30 Chapter 3 formula of [Ru3 II,III
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Intensity, a. u. 32 Chapter 3 quali
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34 Chapter 3 After activating the R
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36 Chapter 3 presence of the residu
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Intensity, a. u. 38 Chapter 3 the a
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40 Chapter 3 extent than acetic aci
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42 Chapter 3 Ru-nodes. Therefore, r
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44 Chapter 3 decomposition of [BF4]
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deriv. normalized E) 46 Chapter 3 F
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48 Chapter 3 3.1.6 Summary Applying
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50 Chapter 3 3.2 Elaboration of Ru
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52 Chapter 3 with that of the Ru II
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54 Chapter 3 Figure 3.20. (a) XANES
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4 Linker-based MOF solid solutions:
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58 Chapter 4 4.1 Introduction 4.1.1
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60 Chapter 4 framework [Cu2(ndc)2(d
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62 Chapter 4 partial replacing of B
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64 Chapter 4 in the case of ip intr
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66 Chapter 4 4.2.1.1 Crystallinity
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68 Chapter 4 suggesting the absence
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70 Chapter 4 Table 4.1. The molar f
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72 Chapter 4 Figure 4.11. IR spectr
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74 Chapter 4 taking into account th
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76 Chapter 4 As quantitative digest
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78 Chapter 4 (Figure 4.16). Notably
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80 Chapter 4 framework Ru-species (
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82 Chapter 4 Figure 4.20. XANES spe
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84 Chapter 4 It is important to not
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86 Chapter 4 Ru δ+ have been obser
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88 Chapter 4 Figure 4.25. UHV-IR sp
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90 Chapter 4 Table 4.5. Possible de
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CO 2 adsorbed, mmol/g 92 Chapter 4
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H 2 adsorbed, mmol/g 94 Chapter 4 F
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CO 2 adsorbed, mmol/g 96 Chapter 4
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H 2 adsorbed, mmol/g 98 Chapter 4 8
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H 2 adsorbed, mmol/g 100 Chapter 4
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102 Chapter 4 presence of H2. [236]
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104 Chapter 4 reactive metal center
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106 Chapter 4 4.2.6 Conclusions App
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108 Chapter 4 4.3 Defects Engineeri
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Intensity, a. u. 110 Chapter 4 as-s
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weight loss, % 112 Chapter 4 100 Cu
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weight loss, % 114 Chapter 4 record
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116 Chapter 4 4.3.2 Composition and
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V, cm 3 /g 118 Chapter 4 500 400 30
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120 Chapter 4 Figure 4.50. From lef
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5 Simultaneous introduction of vari
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124 Chapter 5 preferred like Cu 2+
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126 Chapter 5 5.2 Preparation and S
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128 Chapter 5 Figure 5.5. Pawley Fi
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130 Chapter 5 5.3 Compositional cha
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132 Chapter 5 Table 5.3. The assign
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134 Chapter 5 framework are dominan
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136 Chapter 5 5.4 Synthesis, compos
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138 Chapter 5 obtained Pd-doped sol
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140 Chapter 5 Figure 5.18. Deconvol
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V, cm 3 /g 142 Chapter 5 sorption i
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144 Chapter 5 time as well as the i
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146 Chapter 5 5.6 Conclusions In su
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148 Chapter 6 coordinating anion),
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- Page 212 and 213: 8 Bibliography [1] A. J. Ihde, The
- Page 214 and 215: 196 Bibliography [61] S. Ma, D. Sun
- Page 216 and 217: 198 Bibliography [121] T. K. Prasad
- Page 220 and 221: 202 Bibliography [239] A. L. Harreu
- Page 222 and 223: 204 Bibliography [297] A. P. Hammer
- Page 224 and 225: 206 Appendix List of Presentations
- Page 226: 208 Appendix 05. 2015 Grant from th