8 Bibliography [1] A. J. Ihde, The Development of Modern Chemistry, Harper and Row, 1964. [2] Y. Shibata, J. Coll. Sci., Imp. Univ. Tokyo 1916, 37, 1-17. [3] J. C. Bailar, Jr., Preparative Inorg. Reactions 1964, 1, 1-27. [4] N. G. Connelly, T. Damhus, R. M. Hartshorn, A. T. Hutton, Editors, Nomenclature of Inorganic Chemistry: IUPAC Recommendations 2005, Royal Society of Chemistry, 2005. [5] R. Batten Stuart, R. Champness Neil, X.-M. Chen, J. Garcia-Martinez, S. Kitagawa, L. Öhrström, M. O’Keeffe, M. Paik Suh, J. Reedijk, in Pure Appl. Chem., Vol. 85, 2013, p. 1715. [6] H. J. Choi, M. P. Suh, Inorg. Chem. 1999, 38, 6309-6312. [7] S. Kitagawa, R. Kitaura, S.-i. Noro, Angew. Chem. Int. Ed. 2004, 43, 2334-2375. [8] A. M. A. Ibrahim, E. Siebel, R. D. Fischer, Inorg. Chem. 1998, 37, 3521-3525. [9] A. J. Blake, N. R. Brooks, N. R. Champness, M. Crew, L. R. Hanton, P. Hubberstey, S. Parsons, M. Schroder, J. Chem. Soc., Dalton Trans. 1999, 2813-2817. [10] H. Okamoto, M. Yamashita, Bull. Chem. Soc. Jpn. 1998, 71, 2023-2039. [11] O. M. Yaghi, G. Li, Angew. Chem. Int. Ed. 1995, 34, 207-209. [12] B. Moulton, M. J. Zaworotko, Chem. Rev. 2001, 101, 1629-1658. [13] M. Eddaoudi, D. B. Moler, H. Li, B. Chen, T. M. Reineke, M. O'Keeffe, O. M. Yaghi, Acc. Chem. Res. 2001, 34, 319-330. [14] R. Murugavel, D. Krishnamurthy, M. Sathiyendiran, J. Chem. Soc., Dalton Trans. 2002, 34-39. [15] S. S. Y. Chui, A. Siu, X. Feng, Z. Ying Zhang, T. C. W. Mak, I. D. Williams, Inorg. Chem. Commun. 2001, 4, 467-470. [16] J. Zhang, M. M. Matsushita, X. X. Kong, J. Abe, T. Iyoda, J. Am. Chem. Soc. 2001, 123, 12105-12106. [17] G. J. E. Davidson, S. J. Loeb, Angew. Chem. Int. Ed. 2003, 42, 74-77. [18] H. Li, M. Eddaoudi, M. O'Keeffe, O. M. Yaghi, Nature 1999, 402, 276-279. [19] C. Janiak, Angew. Chem. Int. Ed. 1997, 36, 1431-1434. [20] R. Robson, J. Chem. Soc., Dalton Trans. 2000, 3735-3744. [21] M. Kondo, T. Yoshitomi, H. Matsuzaka, S. Kitagawa, K. Seki, Angew. Chem. Int. Ed. 1997, 36, 1725-1727. [22] Z. R. Herm, E. D. Bloch, J. R. Long, Chem. Mater. 2014, 26, 323-338. [23] J.-R. Li, R. J. Kuppler, H.-C. Zhou, Chem. Soc. Rev. 2009, 38, 1477-1504. [24] L. J. Murray, M. Dinca, J. R. Long, Chem. Soc. Rev. 2009, 38, 1294-1314. [25] M. Eddaoudi, J. Kim, N. Rosi, D. Vodak, J. Wachter, M. O'Keeffe, O. M. Yaghi, Science 2002, 295, 469-472. [26] J. A. Mason, M. Veenstra, J. R. Long, Chem. Sci. 2014, 5, 32-51. [27] D. Farrusseng, S. Aguado, C. Pinel, Angew. Chem. Int. Ed. 2009, 48, 7502-7513. [28] A. Corma, H. García, F. X. Llabrés i Xamena, Chem. Rev. 2010, 110, 4606-4655. [29] J. Liu, L. Chen, H. Cui, J. Zhang, L. Zhang, C.-Y. Su, Chem. Soc. Rev. 2014, 43, 6011- 6061.
Bibliography 195 [30] D. J. Tranchemontagne, J. L. Mendoza-Cortes, M. O'Keeffe, O. M. Yaghi, Chem. Soc. Rev. 2009, 38, 1257-1283. [31] K. S. Park, Z. Ni, A. P. Côté, J. Y. Choi, R. Huang, F. J. Uribe-Romo, H. K. Chae, M. O’Keeffe, O. M. Yaghi, Proc. Natl. Acad. Sci. U.S.A. 2006, 103, 10186-10191. [32] A. Phan, C. J. Doonan, F. J. Uribe-Romo, C. B. Knobler, M. O’Keeffe, O. M. Yaghi, Acc. Chem. Res. 2010, 43, 58-67. [33] J.-P. Zhang, Y.-B. Zhang, J.-B. Lin, X.-M. Chen, Chem. Rev. 2012, 112, 1001-1033. [34] J. L. C. Rowsell, O. M. Yaghi, Microporous Mesoporous Mater. 2004, 73, 3-14. [35] S. S. Y. Chui, S. M. F. Lo, J. P. H. Charmant, A. G. Orpen, I. D. Williams, Science 1999, 283, 1148-1150. [36] D. J. Tranchemontagne, J. R. Hunt, O. M. Yaghi, Tetrahedron 2008, 64, 8553-8557. [37] S. Horike, S. Shimomura, S. Kitagawa, Nat. Chem. 2009, 1, 695-704. [38] S. Kitagawa, M. Kondo, Bull. Chem. Soc. Jpn. 1998, 71, 1739-1753. [39] S. Henke, A. Schneemann, R. A. Fischer, Adv. Funct. Mater. 2013, 23, 5990-5996. [40] S. Kitagawa, K. Uemura, Chem. Soc. Rev. 2005, 34, 109-119. [41] I. Beurroies, M. Boulhout, P. L. Llewellyn, B. Kuchta, G. Férey, C. Serre, R. Denoyel, Angew. Chem. Int. Ed. 2010, 49, 7526-7529. [42] N. Yanai, T. Uemura, M. Inoue, R. Matsuda, T. Fukushima, M. Tsujimoto, S. Isoda, S. Kitagawa, J. Am. Chem. Soc. 2012, 134, 4501-4504. [43] G. Ferey, C. Serre, Chem. Soc. Rev. 2009, 38, 1380-1399. [44] T. Loiseau, C. Serre, C. Huguenard, G. Fink, F. Taulelle, M. Henry, T. Bataille, G. Férey, Chem. Eur. J. 2004, 10, 1373-1382. [45] F. Millange, N. Guillou, R. I. Walton, J.-M. Greneche, I. Margiolaki, G. Ferey, Chem. Commun. 2008, 4732-4734. [46] C. Serre, F. Millange, C. Thouvenot, M. Noguès, G. Marsolier, D. Louër, G. Férey, J. Am. Chem. Soc. 2002, 124, 13519-13526. [47] C. Volkringer, T. Loiseau, N. Guillou, G. Ferey, E. Elkaim, A. Vimont, Dalton Trans. 2009, 2241-2249. [48] E. V. Anokhina, M. Vougo-Zanda, X. Wang, A. J. Jacobson, J. Am. Chem. Soc. 2005, 127, 15000-15001. [49] J. P. S. Mowat, V. R. Seymour, J. M. Griffin, S. P. Thompson, A. M. Z. Slawin, D. Fairen- Jimenez, T. Duren, S. E. Ashbrook, P. A. Wright, Dalton Trans. 2012, 41, 3937-3941. [50] H. Chun, D. N. Dybtsev, H. Kim, K. Kim, Chem. Eur. J. 2005, 11, 3521-3529. [51] K. Uemura, Y. Yamasaki, Y. Komagawa, K. Tanaka, H. Kita, Angew. Chem. Int. Ed. 2007, 46, 6662-6665. [52] B. Chen, S. Ma, E. J. Hurtado, E. B. Lobkovsky, C. Liang, H. Zhu, S. Dai, Inorg. Chem. 2007, 46, 8705-8709. [53] G. Ferey, Chem. Soc. Rev. 2008, 37, 191-214. [54] J. H. Cavka, S. Jakobsen, U. Olsbye, N. Guillou, C. Lamberti, S. Bordiga, K. P. Lillerud, J. Am. Chem. Soc. 2008, 130, 13850-13851. [55] M. Kandiah, M. H. Nilsen, S. Usseglio, S. Jakobsen, U. Olsbye, M. Tilset, C. Larabi, E. A. Quadrelli, F. Bonino, K. P. Lillerud, Chem. Mater. 2010, 22, 6632-6640. [56] V. Colombo, S. Galli, H. J. Choi, G. D. Han, A. Maspero, G. Palmisano, N. Masciocchi, J. R. Long, Chem. Sci. 2011, 2, 1311-1319. [57] N. Stock, S. Biswas, Chem. Rev. 2012, 112, 933-969. [58] A. Rabenau, Angew. Chem. Int. Ed. 1985, 24, 1026-1040. [59] S. T. Meek, J. A. Greathouse, M. D. Allendorf, Adv. Mater. (Weinheim, Ger.) 2011, 23, 249-267. [60] O. M. Yaghi, M. O'Keeffe, N. W. Ockwig, H. K. Chae, M. Eddaoudi, J. Kim, Nature 2003, 423, 705-714.
- Page 1:
Controlled Modification of Metal-Or
- Page 5:
This thesis is based on the work pe
- Page 8 and 9:
Bochum) for the study of XPS and UH
- Page 10 and 11:
Zhang, for their continuous support
- Page 12 and 13:
II 3.2.1 Synthesis and characteriza
- Page 14 and 15:
IV 7.3.4 Synthesis of Cu-DEMOF samp
- Page 16 and 17:
VI DMSO dobdc e.g. EA EDX EtOH EXAF
- Page 18 and 19:
VIII TOF UHV UiO UMCM vs WCA XANES
- Page 20 and 21:
2 Chapter 1 limitations of the (non
- Page 22 and 23:
4 Chapter 2 For the synthesis of CP
- Page 24 and 25:
6 Chapter 2 cavities is able to rev
- Page 26 and 27:
8 Chapter 2 2.2.2 MOF features Adva
- Page 28 and 29:
10 Chapter 2 Figure 2.5. A series o
- Page 30 and 31:
12 Chapter 2 the material is retain
- Page 32 and 33:
14 Chapter 2 2.3 Synthetic approach
- Page 34 and 35:
16 Chapter 2 Expansion of this stru
- Page 36 and 37:
18 Chapter 2 (H2BPDC) [75] or other
- Page 38 and 39:
20 Chapter 2 Cr III CUSs of MIL-101
- Page 40 and 41:
22 Chapter 2 Figure 2.14. Schematic
- Page 42 and 43:
24 Chapter 2 adsorbate-surface inte
- Page 44 and 45:
3 Controlled secondary building uni
- Page 46 and 47:
28 Chapter 3 3.1 Preparation and in
- Page 48 and 49:
30 Chapter 3 formula of [Ru3 II,III
- Page 50 and 51:
Intensity, a. u. 32 Chapter 3 quali
- Page 52 and 53:
34 Chapter 3 After activating the R
- Page 54 and 55:
36 Chapter 3 presence of the residu
- Page 56 and 57:
Intensity, a. u. 38 Chapter 3 the a
- Page 58 and 59:
40 Chapter 3 extent than acetic aci
- Page 60 and 61:
42 Chapter 3 Ru-nodes. Therefore, r
- Page 62 and 63:
44 Chapter 3 decomposition of [BF4]
- Page 64 and 65:
deriv. normalized E) 46 Chapter 3 F
- Page 66 and 67:
48 Chapter 3 3.1.6 Summary Applying
- Page 68 and 69:
50 Chapter 3 3.2 Elaboration of Ru
- Page 70 and 71:
52 Chapter 3 with that of the Ru II
- Page 72 and 73:
54 Chapter 3 Figure 3.20. (a) XANES
- Page 74 and 75:
4 Linker-based MOF solid solutions:
- Page 76 and 77:
58 Chapter 4 4.1 Introduction 4.1.1
- Page 78 and 79:
60 Chapter 4 framework [Cu2(ndc)2(d
- Page 80 and 81:
62 Chapter 4 partial replacing of B
- Page 82 and 83:
64 Chapter 4 in the case of ip intr
- Page 84 and 85:
66 Chapter 4 4.2.1.1 Crystallinity
- Page 86 and 87:
68 Chapter 4 suggesting the absence
- Page 88 and 89:
70 Chapter 4 Table 4.1. The molar f
- Page 90 and 91:
72 Chapter 4 Figure 4.11. IR spectr
- Page 92 and 93:
74 Chapter 4 taking into account th
- Page 94 and 95:
76 Chapter 4 As quantitative digest
- Page 96 and 97:
78 Chapter 4 (Figure 4.16). Notably
- Page 98 and 99:
80 Chapter 4 framework Ru-species (
- Page 100 and 101:
82 Chapter 4 Figure 4.20. XANES spe
- Page 102 and 103:
84 Chapter 4 It is important to not
- Page 104 and 105:
86 Chapter 4 Ru δ+ have been obser
- Page 106 and 107:
88 Chapter 4 Figure 4.25. UHV-IR sp
- Page 108 and 109:
90 Chapter 4 Table 4.5. Possible de
- Page 110 and 111:
CO 2 adsorbed, mmol/g 92 Chapter 4
- Page 112 and 113:
H 2 adsorbed, mmol/g 94 Chapter 4 F
- Page 114 and 115:
CO 2 adsorbed, mmol/g 96 Chapter 4
- Page 116 and 117:
H 2 adsorbed, mmol/g 98 Chapter 4 8
- Page 118 and 119:
H 2 adsorbed, mmol/g 100 Chapter 4
- Page 120 and 121:
102 Chapter 4 presence of H2. [236]
- Page 122 and 123:
104 Chapter 4 reactive metal center
- Page 124 and 125:
106 Chapter 4 4.2.6 Conclusions App
- Page 126 and 127:
108 Chapter 4 4.3 Defects Engineeri
- Page 128 and 129:
Intensity, a. u. 110 Chapter 4 as-s
- Page 130 and 131:
weight loss, % 112 Chapter 4 100 Cu
- Page 132 and 133:
weight loss, % 114 Chapter 4 record
- Page 134 and 135:
116 Chapter 4 4.3.2 Composition and
- Page 136 and 137:
V, cm 3 /g 118 Chapter 4 500 400 30
- Page 138 and 139:
120 Chapter 4 Figure 4.50. From lef
- Page 140 and 141:
5 Simultaneous introduction of vari
- Page 142 and 143:
124 Chapter 5 preferred like Cu 2+
- Page 144 and 145:
126 Chapter 5 5.2 Preparation and S
- Page 146 and 147:
128 Chapter 5 Figure 5.5. Pawley Fi
- Page 148 and 149:
130 Chapter 5 5.3 Compositional cha
- Page 150 and 151:
132 Chapter 5 Table 5.3. The assign
- Page 152 and 153:
134 Chapter 5 framework are dominan
- Page 154 and 155:
136 Chapter 5 5.4 Synthesis, compos
- Page 156 and 157:
138 Chapter 5 obtained Pd-doped sol
- Page 158 and 159:
140 Chapter 5 Figure 5.18. Deconvol
- Page 160 and 161:
V, cm 3 /g 142 Chapter 5 sorption i
- Page 162 and 163: 144 Chapter 5 time as well as the i
- Page 164 and 165: 146 Chapter 5 5.6 Conclusions In su
- Page 166 and 167: 148 Chapter 6 coordinating anion),
- Page 168 and 169: 7 Experimental Section In this Chap
- Page 170 and 171: 152 Chapter 7 as water and hydroxyl
- Page 172 and 173: 154 Chapter 7 internal standards an
- Page 174 and 175: 156 Chapter 7 Uppermost layer is in
- Page 176 and 177: 158 Chapter 7 to the more tightly b
- Page 178 and 179: 160 Chapter 7 7.2 Experimental data
- Page 180 and 181: 162 Chapter 7 [Ru2(OOCC(CH3)3)4(H2O
- Page 182 and 183: 164 Chapter 7 Figure 7.7. The PXRD
- Page 184 and 185: 166 Chapter 7 [Ru2(OOCCH3)4(H2O)2]B
- Page 186 and 187: 168 Chapter 7 [Ru2(OOCCH3)4](THF)2
- Page 188 and 189: 170 Chapter 7 [Ru3(BTC)2(OH)1.5]n·
- Page 190 and 191: 172 Chapter 7 [Ru3(BTC)2]n∙(AcOH)
- Page 192 and 193: 174 Chapter 7 Table 7.3. Feeding mo
- Page 194 and 195: 176 Chapter 7 For comparison of the
- Page 196 and 197: 178 Chapter 7 7.3.4 Synthesis of Cu
- Page 198 and 199: 180 Chapter 7 D3 The mixture of H3B
- Page 200 and 201: 182 Chapter 7 D5 This sample was re
- Page 202 and 203: 184 Chapter 7 The synthesis of D7 a
- Page 204 and 205: 186 Chapter 7 7.4 Experimental data
- Page 206 and 207: 188 Chapter 7 Figure 7.26. PXRD pat
- Page 208 and 209: 190 Chapter 7 7.4.2 Hydrogenation o
- Page 210 and 211: 192 Chapter 7 7.5 Supplementary det
- Page 214 and 215: 196 Bibliography [61] S. Ma, D. Sun
- Page 216 and 217: 198 Bibliography [121] T. K. Prasad
- Page 218 and 219: 200 Bibliography [180] Y. Kobayashi
- Page 220 and 221: 202 Bibliography [239] A. L. Harreu
- Page 222 and 223: 204 Bibliography [297] A. P. Hammer
- Page 224 and 225: 206 Appendix List of Presentations
- Page 226: 208 Appendix 05. 2015 Grant from th