resolver

Chapter 7 169
[Ru3(BTC)2Cl(AcO)0.5]n·(AcOH)1.5(H3BTC)0.1(H2O)4 (1_ex)
This sample was obtained according to the method reported by Kozachuk et al. [82] A
sample of SBU-a (170 mg, 0.36 mmol) and H3BTC (101 mg, 0.48 mmol) were placed in a
20 ml Teflon vessel, and 4 ml of H2O and 0.7 ml of CH3COOH were subsequently added.
The vessel was sealed in an autoclave and kept in a preheated oven at 160 °C for 72 h. The
crude product was filtered and washed several times with distilled water and dried under
ambient conditions (Yield: 171 mg). The obtained powder was further activated by
heating at 150 °C for 24 h under dynamic vacuum (ca. 10 -3 mbar).
[Ru3(BTC)2Cl1.2(OH)0.3]n·(H3BTC)0.15(AcOH)2.4(PivOH)0.45 (2_ex)
The sample was prepared in accordance to the reported procedure. [83] A sample of SBUb
(270 mg, 0.42 mmol) and H3BTC (120 mg, 0.57 mmol) were placed in a Teflon vessel,
and then 6 ml of H2O and 0.1 ml of CH3COOH were added. The vessel was sealed in an
autoclave and kept in the preheated oven at 160 °C for 120 h. As a result, a powdered
product was obtained. It was filtered, washed several times with ethanol and dried at
ambient temperature first (Yield: 223 mg). The sample was activated by heating under
dynamic vacuum (ca. 10 -3 mbar) at 150 °C for 24 h.
[Ru3(BTC)2F0.7(OH)0.8]n·(AcOH)1.5(H3BTC)0.2 (3_ex)
A sample of SBU-c (241 mg, 0.36 mmol) and H3BTC (101 mg, 0.48 mmol) were mixed in a
20 ml Teflon vessel with 4 ml of H2O and 0.7 ml of CH3COOH. The vessel was subsequently
sealed in an autoclave and placed in the preheated oven at 160 °C for 72 h. The final brown
product was collected, washed several times with distilled water, and dried under
ambient conditions first (Yield: 265 mg). The sample was further activated by heating at
150 °C for 24 h under dynamic vacuum (ca. 10 -3 mbar).