resolver

168 Chapter 7
[Ru2(OOCCH3)4](THF)2
Single crystal of [Ru2(OOCCH3)4](THF)2 was obtained in accordance to the reported
procedure. [207] In particular, the sample of [Ru2(OOCCH3)4] was dissolved into
tetrahydrofuran (THF) at 74 °C (oil bath) for 10 min with stirring. Subsequently, the stir
was stopped and the solution was slowly cooled down (10 °C/30 min) to room
temperature in a slow stream of Ar. The solution was then stored in a freezer at -20 °C
overnight giving brown crystals.
Table 7.2. Cell parameters of single crystal [Ru II,II 2 (OOCCH 3 ) 4 ](THF) 2 . Single crystal structure was
not given due to the formation of twin crystal.
obtained literature [207]
a = 14.3787 Å, b = 9.6279 Å,
c = 15.4351 Å; α = 90.000°,
β = 90.000°, γ = 90.000°;
V = 2134.5Å 3
c = 14.606(3)Å a = 9.598(2)Å,
b = 15.803(3)Å; α = 90.00°,
β = 90.00°, γ = 90.00°;
V = 2215.4Å 3
7.2.2 Synthesis of Ru-MOFs [Ru3(BTC)2Xx]·Gg
Scheme 7.3. Syntheses scheme of Ru-MOFs (1-4) employing various SBUs. Reaction Conditions
for 1: CH 3 COOH, H 2 O, 160 °C, 72h; 2: CH 3 COOH, H 2 O, 160 °C, 168h; 3: CH 3 COOH, H 2 O, 160 °C, 72h;
4: CH 3 COOH, H 2 O, 120 °C, 72h.