resolver

Table of Contents
Table of Contents ................................................................................................................................................. I
Abbreviations ....................................................................................................................................................... V
1 Motivation .................................................................................................................................................... 1
2 General introduction ............................................................................................................................... 3
2.1 Origin of MOFs - Coordination polymers ............................................................................... 3
2.2 Definition, Chemistry and features of MOFs ........................................................................ 7
2.2.1 Definition and nomenclature of MOFs ................................................................ 7
2.2.2 MOF features .................................................................................................................. 8
2.3 Synthetic approaches, modification and applications of MOFs ................................ 14
2.3.1 Traditional synthesis approaches ...................................................................... 14
2.3.2 Reticular synthesis ................................................................................................... 15
2.3.3 Way to the modification of MOFs ....................................................................... 16
2.3.4 Application of MOFs ................................................................................................. 23
3 Controlled secondary building unit approach to the formation of the
isostructural Ru II,II and Ru II,III analogs of [M3(BTC)2]n ........................................................... 26
3.1 Preparation and investigation of the Ru II,III -analogs of [M3(BTC)2]n ...................... 28
3.1.1 The family of [M3(BTC)2]n...................................................................................... 28
3.1.2 Background and the state-of-the-art in research on Ru-analogs of
[M3(BTC)2]n.................................................................................................................. 29
3.1.3 [Ru3(BTC)2Yy]n·G g obtained by CSA using [Ru2(OOCR)4X] and
[Ru2(OOCCH3)4]A: synthesis and characterization ..................................... 31
3.1.4 Pre-activation by solvent exchange ................................................................... 37
3.1.5 Study of [Ru3(BTC)2Yy]n·G g after solvent exchange .................................... 38
3.1.6 Summary ....................................................................................................................... 48
3.2 Elaboration of Ru II,II analog of [M3(BTC)2]n........................................................................ 50