Biodeterioration-tests on wood/plastic composites - CHIMICA OGGI ...
Biodeterioration-tests on wood/plastic composites - CHIMICA OGGI ... Biodeterioration-tests on wood/plastic composites - CHIMICA OGGI ...
patterns when feeding in groups using all resources to the maximum (8). Although some preferences for certain wood species may occur (9-11), all cellulose containing material can be used as food and energy sources. Termites, therefore, feed on any wooden material. As termites, especially subterranean termites, search for food, they may penetrate and damage many noncellulose materials as well, including plastics, even if these do not serve as food source and can not be digested (12). The sharp mouth parts of worker termites can abrade or break apart virtually any material and the high reproductive rate in termites instantly replaces workers with blunt mandibles. It is therefore not surprising that most plastics failed in
Biocides 22 The test methods described in TC 15534-1 are intended to be used for the characterization and specification of WPCs. They are derived from existing test methods in the fields of wood protection, plastics and coatings. The methods presented, although used for many years for biocide-treated or untreated material, were not primarily designed for WPCs. In the future it is likely that the test methods will need to be adapted to WPC materials and products. Laboratory
patterns when feeding in groups using all resources to the<br />
maximum (8). Although some preferences for certain <strong>wood</strong><br />
species may occur (9-11), all cellulose c<strong>on</strong>taining material can<br />
be used as food and energy sources. Termites, therefore, feed<br />
<strong>on</strong> any <strong>wood</strong>en material.<br />
As termites, especially subterranean termites, search for<br />
food, they may penetrate and damage many n<strong>on</strong>cellulose<br />
materials as well, including <strong>plastic</strong>s, even if these do not<br />
serve as food source and can not be digested (12). The<br />
sharp mouth parts of worker termites can abrade or break<br />
apart virtually any material and the high<br />
reproductive rate in termites instantly replaces<br />
workers with blunt mandibles.<br />
It is therefore not surprising that most <strong>plastic</strong>s<br />
failed in <str<strong>on</strong>g>tests</str<strong>on</strong>g> for resistance to termites (13-<br />
16). Nevertheless, differences exist between<br />
different <strong>plastic</strong>s and their susceptibility to<br />
termite attack. C<strong>on</strong>densati<strong>on</strong>-<strong>plastic</strong>s like<br />
polyesters appear more resistant than additi<strong>on</strong><strong>plastic</strong>s<br />
like polyethylene, polystyrene and<br />
polyurethane (13). However, it is not <strong>on</strong>ly the<br />
mechanical hardness of <strong>plastic</strong>s that characterises<br />
durability against termite attack, the surface<br />
structure is just as important. Smooth, even<br />
levelled surfaces, are more likely to prevent<br />
termite attack, but the smallest cracks and<br />
crevices or ruffled surfaces and edges provide<br />
immediate access for termite mandibles. The<br />
same holds true for WPCs. Once the surface<br />
is broken, destructi<strong>on</strong> is <strong>on</strong>ly a matter of time<br />
and termite populati<strong>on</strong> density, unless the<br />
material is protected by either an effective<br />
termiticide or a repellent that prevents c<strong>on</strong>tinuous<br />
feeding. Although it was shown that dry<strong>wood</strong><br />
termites are capable of attacking <strong>plastic</strong>s (13),<br />
it is c<strong>on</strong>sidered unlikely that this group of<br />
Wood/<strong>plastic</strong><br />
<strong>composites</strong> (WPC) are a<br />
fairly new category of<br />
materials <strong>on</strong> the market.<br />
The authors point out<br />
biological procedures to<br />
characterise and specify<br />
different WPC-materials.<br />
While moisture is<br />
essential for growths<br />
of algae and fungi,<br />
termites can also attack<br />
dry materials.<br />
Whether biocides<br />
are needed for<br />
protecti<strong>on</strong> of a materials<br />
depends<br />
<strong>on</strong> the envir<strong>on</strong>ment<br />
it will be exposed to<br />
during its use.<br />
termites would infest <strong>plastic</strong>s to establish col<strong>on</strong>ies as they do<br />
in pure <strong>wood</strong>en structures. For WPCs this still needs to be<br />
dem<strong>on</strong>strated.<br />
USE CLASSES FOR WOODEN MATERIALS<br />
Before deciding <strong>on</strong> measures to protect the WPC it is important<br />
to decide where the material has to perform and to what<br />
envir<strong>on</strong>ment it will be exposed. In the field of <strong>wood</strong> protecti<strong>on</strong>,<br />
the definiti<strong>on</strong> of use classes (former hazard<br />
classes) was found to be useful and could now<br />
also be applied to identify the intended use for<br />
WPC-materials (17, 18). These use classes<br />
cover the following general service situati<strong>on</strong>s:<br />
Use class 1 for interior and covered, use class<br />
2 for interior and not covered, use class 3 for<br />
exterior above ground, use class 4 for exterior<br />
in the ground or fresh water and use class 5<br />
for use in salt water. Some minor subdivisi<strong>on</strong>s<br />
in the use classes may occur.<br />
TESTING OF WPCS FOR BIOLOGICAL<br />
DURABILITY<br />
In Europe, CEN with its Technical Committee<br />
249, Working Group 13, has been working <strong>on</strong><br />
laboratory methods to characterise WPCs since<br />
2003. Chapter 8.6 of the technical specificati<strong>on</strong><br />
TS 15534-1released in 2006, “Resistance against<br />
biological agents” (19), deals with the different<br />
forms of microbiological decay (Annex C: termites,<br />
Annex D: <strong>wood</strong> destroying basidiomycetes,<br />
Annex E: soft rotting micro-fungi, Annex F:<br />
discolouring micro-fungi and algae).<br />
Biocides