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<strong>www</strong>.<strong>fsh</strong>-<strong>welding</strong>.<strong>com</strong>
Expert in Brazing<br />
REBOUD-ROCHE, a Member of<br />
the «FSH WELDING GROUP», presents<br />
the most <strong>com</strong>prehensive range of brazing<br />
alloys available today.<br />
The <strong>com</strong>pany, which exists for more than<br />
half a century, has been the pioneer of<br />
the Copper-Phosphorus Brazing alloys, and<br />
it remains the leader.<br />
Thanks to the “Group”, which is already<br />
represented in more than 70 countries, our<br />
<strong>com</strong>pany pursues its mission to develop its<br />
activity abroad.<br />
Our production capacity allows us great<br />
flexibility and to assure the best service<br />
to our clients.<br />
The product range contains four main families:<br />
- Cooper-Phosphorus brazing alloys, suitable for<br />
general use<br />
- Silver brazing alloys with and without<br />
Cadmium<br />
- Brass brazing alloys<br />
- Fluxes for brazing and braze <strong>welding</strong>.<br />
2
alloys<br />
REBOUD-ROCHE is a privileged interlocutor for<br />
distribution and industry (plumbing, refrigerating<br />
industry, air conditioning, gas heating, fluids<br />
transport).<br />
Our <strong>com</strong>pany is certified ISO 9001, by BVQI.<br />
We aim at giving you the best quality-price ratio,<br />
whilst maintaining customer satisfaction.<br />
Our products can be personalised (colour, marking,<br />
coating, packaging) or tailor-made (dimensions,<br />
shapes).<br />
Do not hesitate to contact us !<br />
3
copper - phosphorus - silver alloys<br />
Reference Melting Composition Characteristics Standards<br />
range Cu P Ag Rm A d NF EN 044 AWS A5-8 EN ISO 3677<br />
% % % MPa % g/cm 3<br />
MANUAL BRAZING<br />
PHOSBRAZ M60 710-860 °C balance 6,0 550 6 8,1 CP 203 B Cu 94 P 710-860<br />
PHOSBRAZ V6 710-845 °C balance 6,3 550 5 8,1 CP 203 B Cu 94 P 710-845<br />
PHOSBRAZ P66 710-825 °C balance 6,6 500 4 8,1 CP 202 B Cu 93 P 710-825<br />
PHOSBRAZ P68 710-815 °C balance 6,8 450 4 8 CP 202 B Cu 93 P 710-815<br />
PHOSBRAZ M70 710-805 °C balance 7,0 450 4 8 CP 202 B Cu P2 B Cu 93 P 710-805<br />
PHOSBRAZ M73 710-785 °C balance 7,3 450 4 8 CP 202 B Cu P2 B Cu 93 P 710-785<br />
PHOSBRAZ E80 710-750 °C balance 7,8 450 3 8 CP 201 B Cu 92 P 710-750<br />
PHOSBRAZ E80+ 710-738°C balance 8,0 400 2 8 CP 201 B Cu 92 P 710-738<br />
OVEN BRAZING Phosbraz 840, 815, 790, 770, 750 et 738 : The alloy designation corresponds to its melting temperature (liquidus).<br />
PHOSBRAZ 840 710-840 °C balance 6,4 520 5 8,1 CP 203 B Cu 94 P 710-840<br />
PHOSBRAZ 815 710-815 °C balance 6,8 450 4 8 CP 202 B Cu 93 P 710-815<br />
PHOSBRAZ 790 710-790 °C balance 7,2 450 4 8 CP 202 B Cu P2 B Cu 93 P 710-790<br />
PHOSBRAZ 770 710-770 °C balance 7,5 450 4 8 -- B Cu P2 B Cu 93 P 710-770<br />
PHOSBRAZ 750 710-750 °C balance 7,8 450 3 8 CP 201 B Cu 92 P 710-750<br />
PHOSBRAZ 738 710-738 °C balance 8 400 2 8 CP 201 B Cu 92 P 710-738<br />
PHOSBRAZ 675Sn 650-700 °C balance 6,75 7%Sn 350 2 8 CP 302 B Cu 86 Sn P 650-700<br />
Cu-P-Ag<br />
PHOSBRAZ M68 710-815 °C balance 6,8 0,2 500 5 8,1 -- B Cu93PAg 710-815<br />
PHOSBRAZ AG4 650-825 ° C balance 6,5 0,4 550 6 8,1 -- B Cu93PAg 650-825<br />
PHOSBRAZ AG10 650-820 °C balance 6,7 1,0 550 6 8,1 -- B Cu93PAg 650-820<br />
PHOSBRAZ AG20 650-820 °C balance 6,7 2,0 550 6 8,1 CP 105 B Cu91PAg 650-820<br />
PHOSBRAZ AG20+ 650-800 °C balance 7,0 2,0 550 6 8,1 -- BCuP6 B Cu91PAg 650-800<br />
PHOSBRAZ AG50 650-810 °C balance 6,0 5,0 650 8 8,2 CP 104 BCuP3 B Cu89PAg 650-810<br />
PHOSBRAZ AG50+ 650-770°C balance 6,6 5,0 600 7 8,2 -- BCuP7 B Cu88PAg 650-770<br />
PHOSBRAZ AG100 650-750 °C balance 6,2 10 650 8 8,3 -- B Cu84AgP 650-750<br />
PHOSBRAZ AG150 650-800 °C balance 5,0 15 530 10 8,4 CP 102 BCuP5 B Cu80AgP 650-800<br />
PHOSBRAZ AG180 645 °C balance 7 18 480 10 8,4 CP 101 B Cu75AgP 645-650<br />
PAG60 650-720 °C balance 7,3 6 450 4 8,2 CP 103 *BCuP4 B Cu87PAg 650-720<br />
PAG 60 : Certified in <strong>com</strong>bination with Gel 60, for high strength capillary brazing of copper tubes used in <strong>com</strong>bustible gas installations.<br />
Nota : the asterisk* in front of the standard means close to the norm.<br />
PHOSBRAZ ® is a registered trademark under which REBOUD-ROCHE manufactures the most<br />
<strong>com</strong>prehensive range of Copper/Phosphorus brazing alloys.<br />
This range is used exclusively for joining of copper and copper alloys.<br />
These alloys are divided in 3 branches, mainly according to their use :<br />
- Copper-Phosphorus alloys (two elements) mainly in plumbing and sanitary industry<br />
- Copper-Phosphorus-Silver alloys (three elements) used in the refrigerating industry (e.g. AG50)<br />
(refrigerators, freezers, <strong>com</strong>pressors); electric motor production (e.g. AG150) and gas water-heaters;<br />
- Copper-Phosphorus alloys (two elements) specifically manufactured for furnace brazing.<br />
Fluidity<br />
High fluidity alloys<br />
Phosbraz AG180; PAG60; Phosbraz E 80;<br />
Phosbraz E80+; Phosbraz 675Sn;<br />
Cu-P-Sn The Cu-P Sn alloys have a low<br />
melting temperature range.<br />
Medium/high fluidity alloys<br />
Phosbraz M 73, Phosbraz M 70;<br />
Phosbraz P68; Phosbraz M68;<br />
Phosbraz Ag20+.<br />
These are frequently used for capillary<br />
brazing.<br />
Medium fluidity alloys<br />
Phosbraz P 66, Phosbraz Ag4,<br />
Phosbraz Ag10, Phosbraz Ag20,<br />
Phosbraz Ag50. Phosbraz Ag150<br />
Low fluidity alloys<br />
Phosbraz V6 and Phosbraz M60,<br />
are re<strong>com</strong>mended for pitting tube brazing<br />
Analysis<br />
Each casting is controlled by thermal analysis.<br />
• PAG 60 : Alloy with 6 % silver and 7.3 % Phosphorus.<br />
• The alloy is certified by the French Ministry of Industry, for high strength copper brazing of tubes used in <strong>com</strong>bustible gas installations.<br />
PAG60 is to be used with the flux Gel 60. They are certified under the registration number 750<br />
Detailed production procedures guarantee the Phosbraz Quality.<br />
4
silver brazing alloys<br />
Reference Melting Composition Characteristics Standards<br />
range Ag Cu Zn Cd Others Rm A d NF EN AWS EN ISO 3677<br />
% % % % % MPa % g/cm 3 1044 A5.8<br />
TERNA YS<br />
BRAZARGENT 1505 820-870 °C 5,0 54,5 40,4 380 15 8,4 AG 208 B Cu55ZnAgSi 820-870<br />
BRAZARGENT 1520 SI 690-810 °C 20,0 46,0 33,8 0,2 Si 400 20 8,4 -- B Cu46ZnAgSi 690-810<br />
BRAZARGENT 1544 675-735 °C 44,0 30,0 26,0 400 25 8,9 -- BAg-5 B Ag44CuZn 675-735<br />
BRAZARGENT 1545 680-800 °C 45,0 41,5 13,5 470 25 9,3 -- B Ag45CuZn 680-800<br />
CADMIUM BEARING<br />
BRAZARGENT 2017 610-780 °C 17,0 41,0 26,0 16,0 380 30 8,7 -- B Cu41ZnAgCd 610-780<br />
BRAZARGENT 2020 610-780 °C 20,0 40,0 27,0 13,0 380 32 8,5 AG 309 B Cu42ZnAgCd 610-780<br />
BRAZARGENT 2021 610-750 °C 21 34,8 26 17 0,2 Si 380 32 8,6 **AG308 B Cu 35Zn AgCd 610-750<br />
BRAZARGENT 2025 605-720 °C 25,0 30,0 27,5 17,5 380 8,8 AG 307 BAg-33 B Cu 30 Zn Ag Cd 605-720<br />
BRAZARGENT 2030 610-690 °C 30,0 28,0 21,0 21,0 380 30 8,8 AG 306 BAg-2a B Ag30CuZnCd 610-690<br />
BRAZARGENT 2034 610-670 °C 34,0 25,0 20,0 21,0 400 30 8,9 -- B Ag34CuCdZn 610-670<br />
BRAZARGENT 2035 610-700 °C 35,0 26,0 21,0 18,0 420 29 8,9 AG 305 BAg-2 B Ag35CuZnCd 610-700<br />
BRAZARGENT 2040* 595-630 °C 40,0 19,0 21,0 20,0 450 30 9 AG 304 B Ag 40ZnCdCu 595-630<br />
BRAZARGENT 2042 610-620 °C 42 17 16 25 450 30 9,1 AG 303 B Ag 42 Cd Cu Zn 610-620<br />
BRAZARGENT 400 595-630 °C 40,0 19,0 21,0 20,0 450 30 9 AG 304 B Ag 40ZnCdCu 595-630<br />
BRAZARGENT 2045 605-620 °C 45,0 15,0 16,0 24,0 450 30 9,1 AG 302 BAg-1 B Ag45CdZnCu 605-620<br />
BRAZARGENT 2050 625-635 °C 50,0 15,5 16,5 18,0 450 35 9,2 AG 301 BAg-1a B Ag50CdZnCu 625-635<br />
BRAZARGENT 2550 635-660 °C 50,0 15,5 15,5 16,0 3 Ni 450 25 9,2 AG 351 BAg-3 B Ag50CdCuZnNi 635-660<br />
CADMIUM FREE<br />
Sn%<br />
BRAZARGENT 5018 720-790 °C 18 47,2 33 1,8 450 15 8,4 -- B Cu 47 Zn Ag Sn 720-790<br />
BRAZARGENT 5025 680-760 °C 25,0 40,0 33,0 2,0 510 18 8,5 AG 108 BAg-37 B Cu40ZnAgSn 680-760<br />
BRAZARGENT 5030 665-755 °C 30,0 36,0 32,0 2,0 500 18 8,8 AG 107 B Cu36ZnAgSn 665-755<br />
BRAZARGENT 5034* 630-730 °C 34,0 36,0 27,0 3,0 500 20 8,7 AG 106 B Cu36AgZnSn 630-730<br />
BRAZARGENT 5038* 660-700 °C 38,0 31,0 28,8 2,2 520 18 8,8 -- BAg-34 B Ag38CuZnSn 660-700<br />
BRAZARGENT 5040* 650-710 °C 40,0 30,0 28,0 2,0 500 17 9,1 AG 105 BAg-28 B Ag40CuZnSn 650-710<br />
BRAZARGENT 5045* 640-680 °C 45,0 27,0 25,0 3,0 500 14 9,1 AG 104 BAg-36 B Ag45CuZnSn 640-680<br />
BRAZARGENT 5055 630-660 °C 55,0 21,0 22,0 2,0 510 11 9,2 AG 103 B Ag55ZnCuSn 630-660<br />
BRAZARGENT 5056* 620-655 °C 56 22,5 Rest 5,0 350 25 9,5 AG 102 BAg-7 B Ag 56 Zn Cu Sn 620-655<br />
Nota : The asterisk** in front of the standard means close to the norm.<br />
The standards NF and DIN are substituted for the European standard NF EN 1044 of July 1999<br />
REBOUD-ROCHE is continuously developing its silver solder range designated BRAZARGENT.<br />
These alloys are used for brazing steel, brass, bronze, nickel alloys and copper. Brazing Alloys from this range<br />
are used to join most Ferrous and Non-Ferrous metals with the exception of Aluminium and Magnesium.<br />
These Alloys have good Brazing properties and can be pre-positioned prior to heating, or manually applied<br />
during heating. Suitable for all heating methods. Lap joints are re<strong>com</strong>mended, however, butt joints can be<br />
used where conditions are less demanding.<br />
Clearances between 0.05-0.13 mm are re<strong>com</strong>mended, depending on the Fluidity of the alloy used, in order<br />
to achieve capillarity. A flux is necessary when brazing in open atmospheric conditions.<br />
High silver contents in brazing alloys allow to work at relatively low temperatures.<br />
3 MAIN FAMILIES:<br />
BRAZARGENT 15... A ternary range Silver-Copper-Zinc, with melting ranges above 720°C, and good<br />
ductility.<br />
BRAZARGENT 20... A quaternary family containing the previously mentioned metal and Cadmium.<br />
They are suitable for low temperature and good fit-up applications due to their excellent penetration.<br />
These alloys have a high mechanical strength and they are re<strong>com</strong>mended when a low melting point is<br />
required : low tenor in zinc and cadmium.<br />
BRAZARGENT 50... Cadmium-free A specially developed range created to replace the BRAZARGENT 20..<br />
when the use of Cadmium is not permitted (food and sanitary industry, Middle East and Northern European<br />
countries).<br />
PRESENTATION Bare or Flux Coated rods, wire in coils or on spools. Under special request: Tubular Brazing<br />
Wires (TBW*) in wire, rods, rings and pre-forms.<br />
5
flux<br />
Reference<br />
Powder Paste Use interval<br />
Standard<br />
EN1045<br />
Main applications<br />
Flux for braze-<strong>welding</strong> and brazing. Allows large clearances to be used.<br />
CUPRO-FLUX X X 800-1000°C FH20 Main application on carbon steel. For use with CUPROX, SUPER-CUPROX<br />
and BRAZARGENT 1505.<br />
Promotes the flow of filler metal. Extremely efficient, it permits brazing<br />
POLY-FLUX X X 800-1000°C FH20 even on dirty surfaces. For use with CUPROX, SUPER-CUPROX and<br />
BRAZARGENT 1505.<br />
PHOSBRAZ-FLUX X 600-850°C FH20<br />
Flux powder re<strong>com</strong>mended for brazing brass connections on copper<br />
piping with our Phosbraz alloy range.<br />
Certified by ATG (French Ministry of Industry) it is suitable<br />
GEL 60 600-850°C FH10 on copper piping for <strong>com</strong>bustible gas installations.<br />
To be used with our PAG 60, registration n° 750.<br />
Certified by ATG (French Ministry of Industry) for <strong>com</strong>bustible<br />
GEL 400 500-800°C FH10 gas installations. To be used in <strong>com</strong>bination with<br />
our BRAZARGENT 400, registration n° 1512.<br />
AGFLUX X X 500-800°C FH10<br />
High quality flux. Well suited for brazing steels and copper-based alloys,<br />
as well as on piping for <strong>com</strong>bustible gas installations.<br />
Certified with BRAZARGENT 400 and PAG 60,<br />
registration n° 1529 and n° 1530.<br />
WHY TO USE A FLUX?<br />
Nearly all metals exposed to the atmosphere get easily oxidized. The higher the temperature, the higher<br />
the oxidation !<br />
Certain brazing <strong>welding</strong> alloys, such as PHOSBRAZ® are self-fluxing at the brazing temperature, when<br />
used on pure copper. Phosphorus in the filler material reduces the copper oxide. In all other cases, the use<br />
of a flux is necessary.<br />
The flux is used to permit proper formation of the joint due to three main actions: protection of joint<br />
surfaces against oxidizing during heating, dissolution of metallic oxides and removal of residues generated<br />
during the process, wetting of the surfaces to be assembled to permit adequate migration of the filler<br />
metal in the joint.<br />
For each operation, the flux must be selected, according to :<br />
• joint materials,<br />
• filler alloy selected,<br />
• temperatures, heating mode and duration.<br />
This means no «universal» flux exists, for all applications. The REB® flux range makes it possible to meet<br />
most problems encountered.<br />
REMARKS<br />
All brazing fluxes contain aggressive<br />
products. Therefore, we suggest the<br />
following:<br />
• Work place : remove all flux waste to<br />
avoid further corrosion. Our fluxes<br />
are soluble in hot water or slightly<br />
alkaline solutions.<br />
• Personnel: avoid fume breathing, use<br />
safety glasses and glove protection,<br />
use enough ventilation.<br />
Flux dosing depends on the property<br />
and the oxidation of pieces.<br />
PACKAGING<br />
• Units of 200 g.<br />
• Units of 400 g.<br />
• Units of 1000 g.<br />
• Units of 5 liter<br />
• Units of 10 liter<br />
6
ass alloys<br />
Reference Melting Composition Characteristics Standards<br />
range Cu Zn Ni Ag Others Rm A d NF EN 1044 EN ISO 3677<br />
% % % % Mpa % g/cm 3<br />
CUPROX 870-890 °C 59,7 balance 0,2 Si,Mn,Sn. 450 35 8,4 CU 304 B Cu 60 Zn Si 870-890<br />
SUPER-CUPROX 850-870 °C 58,0 balance 1,0 Si,Mn,Sn. 480 30 8,5 -- B Cu 59 Zn Ag Si 850-870<br />
506 890-900 °C 51,0 balance 6,0 Si. 550 30 8,5 -- B Cu 50 Zn Ni Si 890-900<br />
NICROX 49 C1 890-920 °C 49,9 balance 9,0 Si. 750 25 8,7 CU 305 B Cu 49 Zn Ni Si 890-920<br />
SUPER-NICROX 870-900 °C 49,0 balance 9,0 1,0 Si,Mn,Sn. 750 25 8,7 -- B Cu 48 Zn Ni Ag Si 870-900<br />
Brass <strong>welding</strong> alloys are generally used on steel, notably for the assembly of<br />
steel tubes (bicycles, metal furniture), nickel silver, coach-building, lock-smithing,<br />
maintenance.<br />
Suitable for hand, furnace or carousel use.<br />
The main element of this range is Copper, to which other metals are added.<br />
ZINC…<br />
Lowers the melting point and produces a corrosion-resistant and ductile brass, up<br />
to a 40 % Zinc content.<br />
NICKEL…<br />
Used in conjunction with the previous two metals to form nickel silvers; high<br />
strength alloys with good corrosion resistance.<br />
SILVER…<br />
Combines nearly all the qualities, except price. A small silver content in an alloy<br />
considerably improves its fluidity and strengthens a brazed joint.<br />
MANGANESE, TIN, IRON…<br />
Improve the characteristics of certain alloys.<br />
FORMS<br />
Bare, work-hardened or annealed wires.<br />
Bare, coated rods.<br />
Flux-cored rods or wires.<br />
Rings<br />
Preforms<br />
Blasting grit<br />
Powders.<br />
remark<br />
In the absence of an inert atmosphere,<br />
the use of a flux is necessary, except when<br />
using coated or flux-cored products.<br />
Flux dosing depends on the properties and<br />
degree of oxidation of the <strong>com</strong>ponents.<br />
Cuprox® and Nicrox® are registered trade<br />
marks.<br />
7
moving forward together in a<br />
bicentennial<br />
industrial group<br />
FSH WELDING GROUP Headquarter - France<br />
<strong>www</strong>.<strong>fsh</strong>-<strong>welding</strong>.<strong>com</strong><br />
info@reboud-roche.<strong>com</strong><br />
BP 1 - F 25220 ROCHE-LEZ-BEAUPRE - FRANCE<br />
Tel. +33 (0)3 81 60 51 70 - Fax +33 (0)3 81 55 67 07<br />
EUROSAGA 33 (0)3 84 21 01 12