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Neutron Scattering

Neutron Scattering - JuSER - Forschungszentrum Jülich

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measurements can be performed in transmission geometiy on spherical, cylindrical or even<br />

inegular shaped specimens and complete pole figures are obtained without applying any<br />

intensity corrections . <strong>Neutron</strong> diffraction measurements can be carried out at a rauch higher<br />

degree ofaccuracy than other techniques to calculate the orientation distribution function.<br />

5.0 Pole Figures and ODF<br />

An experimental pole figure Pal yields the orientation distribution of the crystallites with<br />

respect to one particular crystallographic direction [hkl] which represents the actual scattering<br />

vector s ofthe diffraction experiment. There is no information, however, on the orientation of<br />

Fig. 19 .18 : <strong>Scattering</strong> experimment with scattering vector c = [hkl] perpendicular to scattering<br />

plane (hkl) (hatched) yields no information on the orientation ofany [uvw] inside theplane<br />

the crystallites perpendicular to the scattering vector, i .e . inside the plane (hkl) (compare Fig .<br />

18 .18) . As the pole figure represents a two-dimensional orientation distribution, it is thus an<br />

integral of the three-dimensional orientation distribution function f(g) taken over a rotation<br />

about scattering vector s = [hkl] :<br />

Phki(y) = 1 f f(g)dy with y = ta, R} (5).<br />

2;r<br />

Equation (5) may bc called the fundamental relation of texture analysis. It is evident that the<br />

ODF f(g) is generally not completely determined by one pole figure. One needs the additional<br />

information of other crystallographic directions, i.e . other pole figures . The factor 1/2ir in<br />

equation (5) results from a normalization wich respect to the definition of a statistical<br />

orientation distribution :<br />

f(g)eatistical = 1, ff(g)dy = 1, Phkl(a> R)statistical = 1 (6) .<br />

Pole densities are expressed in multiples of the random density (m.r .d.) .

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