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Neutron Scattering

Neutron Scattering - JuSER - Forschungszentrum Jülich

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In this contribution, however, we will exclusively focus on the positive aspects of prefened<br />

orientations in polycrystalline material in view ofthe characterization and changes ofthe bulk<br />

material properties. In material science, mechanical treatment and deformation is artificially<br />

applied to generate prefened orientation and, thus, well defined material properties . In earth<br />

sciences, preferred orientation exists in rocks by natural deformations over millions of years<br />

and, thus, bears important information on longtime geological processes . The study of preferred<br />

orientations in bulk polycrystalline material is an independent scientific discipline : the<br />

texture analysis [1, 2] .<br />

2 .0 Anisotropy by Structure and Texture<br />

Texture is a property of condensed crystalline matter. In our daily life, we are offen in contact<br />

wich solid state crystalline matter, e .g . minerals and rocks being the fundamental components<br />

ofthe earth's crust, or metals and ceramics which are manufactured and used as technological<br />

products . Ciystalline matter is characterized by its specific crystal structure which is defined<br />

by a unit cell with its symmetrical atomic arangement and by its three-dimensional<br />

periodicity . This crystal structure essentially determines the physical, chemical and technological<br />

properties of a material, at least on a microscopic scale . The microscopic unit is<br />

considered to bc a monocrystalline aggregate .<br />

Generally, the properties of a single crystal are anisotropic, i.e . they are different in<br />

different crystallographic directions . The thermal conductivity of graphite represents a typical<br />

example of such a direction-dependent crystalline property . The sheet-like hexagonal crystal<br />

structure built up by plane layers of carbon atoms with small interatomic distances inside the<br />

layers and large distances between neighbouring layers (Fig . 18 .2) is responsible for a strong<br />

anisotropy . The thermal conductivity within the layers is about four times larger compared to<br />

the conductivity perpendicular to the layers along the hexagonal axis .<br />

[1001<br />

Fig. 18 .2 : Graphite structure built up<br />

byplane sheets ofC atours (hatched)<br />

arranged perdendicular to the hexagonal<br />

c-axis<br />

Fig . 18.3 : Property surface of the Young<br />

modulus ofiron (left)for any directions [UI]<br />

of the cubic crystal system (right)<br />

18- 2

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