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Neutron Scattering

Neutron Scattering - JuSER - Forschungszentrum Jülich

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----~ Probe<br />

' (Chopper 2)<br />

Zeit<br />

I<br />

Chopper<br />

Figure 10 .4 :<br />

Path-time diagram for a configuration with "Frame overlap choppers", chopper<br />

2 .<br />

using the right hand vertical scale. This diagonal straight Elle intersects the level A o =<br />

0.6nm at the location of the "elastic channel" where neutrons are collected that did not<br />

change their velocity during scattering . Silice in liquid water which was the sample all<br />

molecules may diffuse without restriction only a so called quasielastic line is observed<br />

which corresponds to a Lorentzian with a width proportional to QZ . The maximum of<br />

intensity is nevertheless at the elastic channel (- quasielastic) . The difference between a<br />

solid with atoms/molecules fixed at lattice sites and a liquid is illustrated by the right part<br />

of the figure. Imidazole in the solid state exhibits an intense line at the elastic channel<br />

with a width corresponding to the instrumental resolution. In contrast molten imidazole<br />

(especially for the relatively large scattering angle displayed here ----> large Q) shows only a<br />

broad quasielastic intensity distribution . At shorter times- of-flight corresponding to larger<br />

10-7

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