Measurements
Electron Spin Resonance and Transient Photocurrent ... - JuSER
Electron Spin Resonance and Transient Photocurrent ... - JuSER
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Chapter A: Algebraic Description of the Multiple Trapping Model<br />
written as<br />
E d (t) = E V + kT ln(νt),<br />
(A.2)<br />
where kT is the temperature in energy units and ν an attempt-to-escape frequency.<br />
It has been shown by Tiedje, Rose, Orenstein, and Kastner that at any time prior<br />
to the transit time and in the absence of recombination the carrier distribution is<br />
determined by the demarcation energy as<br />
∫+∞<br />
g 0 · exp ( − E<br />
N = F(t)<br />
1 + exp ( ) dE. (A.3)<br />
E−E d<br />
kT<br />
−∞<br />
∆E V<br />
)<br />
where F(t) is an occupation factor which acts to conserve the excitation density<br />
N. For the occupancy factor F(t) one derives<br />
F(t) =<br />
N<br />
kT 0 g 0<br />
sin(απ)<br />
απ (νt)α , (A.4)<br />
where α = kT/∆E V , while the time dependent drift mobility can be written as<br />
n(t)<br />
µ(t) ≡ µ 0<br />
N = µ N V<br />
0 · sin(απ)<br />
kT 0 g 0 απ (νt)−1+α , (A.5)<br />
where N V is the effective density of states at the mobility edge, n(t) is the density<br />
of mobile charge carriers, and µ 0 is their mobility. Since µ(t) is defined as<br />
µ(t) = ¯v(t)<br />
F ,<br />
(A.6)<br />
where v(t) is the mean drift-velocity and F is the electric field, one can find the<br />
displacement L(t) by integration:<br />
L(t)<br />
F<br />
= N V<br />
· sin(απ)<br />
kTg 0 απ<br />
( µ0<br />
)<br />
(νt) α<br />
ν<br />
Using Eq. A.1, the effective DOS in the valence band can be written as<br />
N V =<br />
∫ 0<br />
−∞<br />
( E<br />
)<br />
g(E) · exp<br />
kT<br />
(A.7)<br />
(A.8)<br />
For kT < ∆E V and assuming that the integral is dominated by an exponential region<br />
of g(E) below E V one obtains for N V<br />
N V = kTg 0<br />
1 −<br />
∆E kT .<br />
V<br />
(A.9)<br />
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