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Measurements

Electron Spin Resonance and Transient Photocurrent ... - JuSER

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Chapter A: Algebraic Description of the Multiple Trapping Model<br />

written as<br />

E d (t) = E V + kT ln(νt),<br />

(A.2)<br />

where kT is the temperature in energy units and ν an attempt-to-escape frequency.<br />

It has been shown by Tiedje, Rose, Orenstein, and Kastner that at any time prior<br />

to the transit time and in the absence of recombination the carrier distribution is<br />

determined by the demarcation energy as<br />

∫+∞<br />

g 0 · exp ( − E<br />

N = F(t)<br />

1 + exp ( ) dE. (A.3)<br />

E−E d<br />

kT<br />

−∞<br />

∆E V<br />

)<br />

where F(t) is an occupation factor which acts to conserve the excitation density<br />

N. For the occupancy factor F(t) one derives<br />

F(t) =<br />

N<br />

kT 0 g 0<br />

sin(απ)<br />

απ (νt)α , (A.4)<br />

where α = kT/∆E V , while the time dependent drift mobility can be written as<br />

n(t)<br />

µ(t) ≡ µ 0<br />

N = µ N V<br />

0 · sin(απ)<br />

kT 0 g 0 απ (νt)−1+α , (A.5)<br />

where N V is the effective density of states at the mobility edge, n(t) is the density<br />

of mobile charge carriers, and µ 0 is their mobility. Since µ(t) is defined as<br />

µ(t) = ¯v(t)<br />

F ,<br />

(A.6)<br />

where v(t) is the mean drift-velocity and F is the electric field, one can find the<br />

displacement L(t) by integration:<br />

L(t)<br />

F<br />

= N V<br />

· sin(απ)<br />

kTg 0 απ<br />

( µ0<br />

)<br />

(νt) α<br />

ν<br />

Using Eq. A.1, the effective DOS in the valence band can be written as<br />

N V =<br />

∫ 0<br />

−∞<br />

( E<br />

)<br />

g(E) · exp<br />

kT<br />

(A.7)<br />

(A.8)<br />

For kT < ∆E V and assuming that the integral is dominated by an exponential region<br />

of g(E) below E V one obtains for N V<br />

N V = kTg 0<br />

1 −<br />

∆E kT .<br />

V<br />

(A.9)<br />

108

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