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A Treatise on the Acid Treatment of Silkworm Eggs - Central ...

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Selection of the acid<br />

For consistent good results, stronger inorganic acids have been found in general, better lhan organic<br />

acids. Amongst the inorganic acids again, Nitric acid, Sulphuric acid and Aqua regia (a combination of<br />

Nitric acid and Hydrochloric acid in a ratio of 1:3) have been found to be too strong for use and difficult to<br />

handle. Comparative figures with regard lo concentration (percent by weight) and densities of different<br />

inorganic acids are given in Table 2.<br />

TABLE 2<br />

Specilic gravity and concentration of different acids<br />

Name of the acid<br />

Concentration of acid at<br />

saturation (%)<br />

Density at 20"C<br />

Hydrochloric acid (HCl)<br />

Nitric acid (HNO")<br />

Sulphuric acid (H,SO.)<br />

40<br />

100<br />

100<br />

1.1980<br />

1.5129<br />

1.8305<br />

Evidently, Nitric acid and Sulphuric acid are distinctly stronger in nature and pose handling problems.<br />

Thus, in practice, HCI alone is being exploited forthe acid treatment of silkworm eggs both at commercial<br />

and laboratory levels. lt has been found to be the safest and best medium for treating diapausing eggs<br />

to obtain maximum hatching.<br />

Hydrochloric acid is a by-product obtained while manufacturing soda-ash and is subsequently<br />

purif ied to the required levels. Pure HCI is colourless and emanates strong and obnoxious fumes. The<br />

yellow colour of certain commercial HCI products is often caused by iron and other impurities. lt fumes<br />

in moist air and is very easily soluble in water.' lt has strong acid taste with pungent irritating odour and<br />

attacks the mucous membrane upon inhalation.<br />

HCI is marketed as a solulion containing mostly 28 to 36% Hyirogen Chloride by weight and is<br />

commonly known as concentrated HCl. The concentration and specific gravity of HCI are correlated as<br />

indicated in Table 3.<br />

TABLE 3<br />

Relationship between Specific Gravity and Concentration of HCI<br />

Specific gravity of acid at 20"C<br />

1 .198<br />

1.195<br />

1.190<br />

1.180<br />

1.170<br />

1.160<br />

1.150<br />

'1<br />

.1 40<br />

1.130<br />

1.120<br />

1.1 10<br />

1.100<br />

1.095<br />

1.090<br />

1.085<br />

1.080<br />

1.075<br />

1.O70<br />

Concentration of acid (%)<br />

40<br />

39<br />

38<br />

50<br />

34<br />

32<br />

30<br />

28<br />

zo<br />

24<br />

22<br />

20<br />

19<br />

18<br />

17<br />

16<br />

15<br />

14<br />

9

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